EP2298947A1 - High strength casting aluminium alloy material - Google Patents

High strength casting aluminium alloy material Download PDF

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Publication number
EP2298947A1
EP2298947A1 EP09793824A EP09793824A EP2298947A1 EP 2298947 A1 EP2298947 A1 EP 2298947A1 EP 09793824 A EP09793824 A EP 09793824A EP 09793824 A EP09793824 A EP 09793824A EP 2298947 A1 EP2298947 A1 EP 2298947A1
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EP
European Patent Office
Prior art keywords
rare earth
aluminum alloy
alloy material
strength
earth elements
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP09793824A
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German (de)
French (fr)
Other versions
EP2298947A4 (en
EP2298947B1 (en
Inventor
Yun CHE
Jinde Lu
Zhongke Zhang
De'en Zhang
Xiaoyan Zhang
Guangpu Yan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guizhou Academy Of Sciences
Guizhou Aluminums Factory
Guizhou University
Original Assignee
Guizhou Academy Of Sciences
Guizhou Aluminums Factory
Guizhou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN2008103026690A external-priority patent/CN101363093B/en
Priority claimed from CN2008103026703A external-priority patent/CN101319287B/en
Priority claimed from CN2008103026686A external-priority patent/CN101363092B/en
Priority claimed from CN2008103026718A external-priority patent/CN101363094B/en
Application filed by Guizhou Academy Of Sciences, Guizhou Aluminums Factory, Guizhou University filed Critical Guizhou Academy Of Sciences
Publication of EP2298947A1 publication Critical patent/EP2298947A1/en
Publication of EP2298947A4 publication Critical patent/EP2298947A4/en
Application granted granted Critical
Publication of EP2298947B1 publication Critical patent/EP2298947B1/en
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/057—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with copper as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/12—Alloys based on aluminium with copper as the next major constituent

Definitions

  • the invention relates to an aluminum alloy material, in particular to a high strength casting aluminum alloy material.
  • the aluminum alloy as a younger metal material was not put into industrial use until early in the twentieth century.
  • the aluminum material was mainly used to manufacture military aircraft.
  • the sharp drop in the demand for the aluminum material in the military industry led the aluminum industry to turn to the development of the aluminum alloy for civil use, so as to extend the applicable range thereof from aviation industry to various fields of national economy such as construction industry, container packaging industry, transportation industry, power industry, electronic industry, mechanical manufacturing industry, petrochemical industry and so on and apply the aluminum alloy to daily life.
  • the aluminum material ranks second next to steel in metal materials.
  • the aluminum alloy can be dated back to 1906 when Alfred Wilm Duralumin discovered the age hardening by chance in Berlin and then the Duralumin was developed and applied to the structural parts of aircraft.
  • Various Al-Cu alloys were developed based on the Duralumin.
  • ZL204A, ZL205A and other grades of casting aluminum alloy are developed in China, wherein the tensile strength of the ZL204A ( ⁇ 5 >4%) under the T5 state is 440Mpa, however, the ZL204A has the poorest fluidity and hot-cracking resistance among the Al-Cu based casting alloys; the tensile strengths of ZL205A under the T5 state and T6 state are 435MPa and 465MPa respectively according to the technical standard ( GB 1173-86 ), and the tensile strength of ZL205A (T6) is 470MPa according to the standard ( GB/F1173-1995 ), so the ZL205A is one of casting aluminum alloy materials having highest strength worldwide at present.
  • ZL205A (T5) is good, and the coefficient of elongation thereof reaches 7%, so ZL205A has been widely applied in the field of aerospace, however, ZL205A contains precious metal V as an element and is high in cost; meanwhile, ZL205A is based on refined aluminum or high-purity aluminum as a base metal, thus increasing the cost and limiting the material supply. Additionally, ZL209, which is made by adding RE to ZL205A, is still subject to the limitation of high cost due to the addition of the element V.
  • the aluminum alloy developed by LV Jie, BIAM (Beijing Institute of Aeronautical Materials) is similar to ZL205A in the aspect of main components, however, the aluminum alloy contains 0.1% to 0.25% of V in the trace elements, has a tensile strength of 385MPa to 405MPa and the coefficient of elongation reaching 19% to 23%, and it is disclosed only in document study, the tensile strength of the aluminum alloy is lower, and the raw materials include high-cost element V.
  • the existing research on the field of high-strength casting aluminum alloy at home and aboard has the following problems: the strength of the aluminum alloy is not high enough, more particularly, few of casting aluminum alloys has the tensile strength higher than 450MPa; precious metals and rare elements (Ag, V and Be) are added in an amount higher than 1 ⁇ , and high-impurity aluminum is used as the base metals, thus increasing the cost, limiting the material source and making the aluminum alloy difficult to be popularized and put into civil use; the problem of the ratio between strength and plasticity is yet to be solved, and the contradiction between the strength and castability of the alloy is serious; and the fatigue life is short, and the resistance to stress corrosion is poor.
  • the invention intends to solve the technical problems that the existing high-strength casting aluminum alloy has the disadvantages of high formula cost, low strength, poor castability, short fatigue life and poor resistance to stress corrosion and to develop a high-strength, high-toughness and high-corrosion-resistance casting aluminum alloy material for both military and civil uses by optimizing the common formula and the processes of casting and purifying.
  • the invention provides a high-strength casting aluminum alloy material comprising the following components by weight percentage: 2.0% to 6.0% of Cu, 0.05% to 1.0% of Mn, 0.01% to 0.5% of Ti, 0.01% to 0.2% of Cr, 0.01% to 0.4% of Cd, 0.01% to 0.25% of Zr, 0.005% to 0.04% of B, 0.05% to 0.3% of rare earth element and the balancing amount of Al and trace impurities.
  • the rare earth element may be Pr, Ce, La or mixed rare earth elements RE.
  • the total content of various rare earth elements in the mixed rare earth elements RE is not lower than 98% (based on the total weight of the mixed rare earth elements RE).
  • the mixed rare earth elements RE may contain 40wt% to 50wt% of Ce (based on the total weight of the mixed rare earth elements RE).
  • the method for preparing the high-strength casting aluminum alloy material comprises the following steps:
  • the invention has the following advantages:
  • the high-strength casting aluminum alloy material comprises the following components by weight percentage: 2.0% to 6.0% of Cu, 0.05% to 1.0% of Mn, 0.01% to 0.5% of Ti, 0.01% to 0.2% of Cr, 0.01% to 0.4% of Cd, 0.01% to 0.25% of Zr, 0.005% to 0.04% of B, 0.05% to 0.3% of Pr, Ce, La or mixed rare earth elements RE and the balancing amount of Al and trace impurities.
  • the total content of various rare earth elements in the mixed rare earth elements RE is not lower than 98%, and the content of Ce in the mixed rare earth elements is 45% by weight percentage.
  • the rare earth elements (Because the ionic radius and oxidation state of the rare earth elements are similar to those of other elements, the rare earth elements generally coexist with other elements in minerals.)

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Continuous Casting (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

A high strength casting aluminum alloy material comprises (in weight %) Cu 2.0-6.0%, Mn 0.05-1.0%, Ti 0.01-0.5%,Cr0.01-0.2%, Cd 0.01-0.4%, Zr 0.01-0.25%, B 0.005-0.04%, rare earth 0.05-0.3%, and balance aluminum and trace impurities. The alloy has reduced cost.

Description

    Technical Field
  • The invention relates to an aluminum alloy material, in particular to a high strength casting aluminum alloy material.
    • Background
  • The aluminum alloy as a younger metal material was not put into industrial use until early in the twentieth century. During the World War II, the aluminum material was mainly used to manufacture military aircraft. In the post-war years, the sharp drop in the demand for the aluminum material in the military industry led the aluminum industry to turn to the development of the aluminum alloy for civil use, so as to extend the applicable range thereof from aviation industry to various fields of national economy such as construction industry, container packaging industry, transportation industry, power industry, electronic industry, mechanical manufacturing industry, petrochemical industry and so on and apply the aluminum alloy to daily life. Nowadays, owing to high consumption and wide range, the aluminum material ranks second next to steel in metal materials. The aluminum alloy can be dated back to 1906 when Alfred Wilm Duralumin discovered the age hardening by chance in Berlin and then the Duralumin was developed and applied to the structural parts of aircraft. Various Al-Cu alloys were developed based on the Duralumin. Early in the twentieth century, aluminum alloy A-U5GT ((W)Si<0.05%, (W)Fe<0.10% and tensile strength (T4) ≥ 275MPa according to SAE J452-1989), which has been listed in France's national standards and aerospace standards, was developed and put into use and production; aluminum alloys 201.0 (1968) and 206.0 (1967) according to the Aluminum Association were based on the A-U5GT, and aluminum alloy 204.0 (1974) was equivalent to A-U5GT; aluminum alloy 201.0 (AlCu4AgMgMn) containing Ag (0.4% to 1.0%) and having high cost is commercially named KO-1 (with the tensile strength (T7) thereof being 415MPa and the coefficient of elongation thereof being 3% according to ASTM B26/B26(M)-1999) and protected by US patent; BAJI10 is equivalent to ZL204 for domestic use in the aspect of major element components but its trace elements is under secret and it is only used in the military field or other fields having high requirements.
  • ZL204A, ZL205A and other grades of casting aluminum alloy are developed in China, wherein the tensile strength of the ZL204A (δ5>4%) under the T5 state is 440Mpa, however, the ZL204A has the poorest fluidity and hot-cracking resistance among the Al-Cu based casting alloys; the tensile strengths of ZL205A under the T5 state and T6 state are 435MPa and 465MPa respectively according to the technical standard ( GB 1173-86 ), and the tensile strength of ZL205A (T6) is 470MPa according to the standard ( GB/F1173-1995 ), so the ZL205A is one of casting aluminum alloy materials having highest strength worldwide at present.
  • The plasticity of ZL205A (T5) is good, and the coefficient of elongation thereof reaches 7%, so ZL205A has been widely applied in the field of aerospace, however, ZL205A contains precious metal V as an element and is high in cost; meanwhile, ZL205A is based on refined aluminum or high-purity aluminum as a base metal, thus increasing the cost and limiting the material supply. Additionally, ZL209, which is made by adding RE to ZL205A, is still subject to the limitation of high cost due to the addition of the element V. The aluminum alloy developed by LV Jie, BIAM (Beijing Institute of Aeronautical Materials) is similar to ZL205A in the aspect of main components, however, the aluminum alloy contains 0.1% to 0.25% of V in the trace elements, has a tensile strength of 385MPa to 405MPa and the coefficient of elongation reaching 19% to 23%, and it is disclosed only in document study, the tensile strength of the aluminum alloy is lower, and the raw materials include high-cost element V.
  • In conclusion, the existing research on the field of high-strength casting aluminum alloy at home and aboard has the following problems: the strength of the aluminum alloy is not high enough, more particularly, few of casting aluminum alloys has the tensile strength higher than 450MPa; precious metals and rare elements (Ag, V and Be) are added in an amount higher than 1‰, and high-impurity aluminum is used as the base metals, thus increasing the cost, limiting the material source and making the aluminum alloy difficult to be popularized and put into civil use; the problem of the ratio between strength and plasticity is yet to be solved, and the contradiction between the strength and castability of the alloy is serious; and the fatigue life is short, and the resistance to stress corrosion is poor.
    • Summary of the Present Invention
  • The invention intends to solve the technical problems that the existing high-strength casting aluminum alloy has the disadvantages of high formula cost, low strength, poor castability, short fatigue life and poor resistance to stress corrosion and to develop a high-strength, high-toughness and high-corrosion-resistance casting aluminum alloy material for both military and civil uses by optimizing the common formula and the processes of casting and purifying.
  • In order to solve the problems, the invention provides a high-strength casting aluminum alloy material comprising the following components by weight percentage: 2.0% to 6.0% of Cu, 0.05% to 1.0% of Mn, 0.01% to 0.5% of Ti, 0.01% to 0.2% of Cr, 0.01% to 0.4% of Cd, 0.01% to 0.25% of Zr, 0.005% to 0.04% of B, 0.05% to 0.3% of rare earth element and the balancing amount of Al and trace impurities.
  • The rare earth element may be Pr, Ce, La or mixed rare earth elements RE.
  • The total content of various rare earth elements in the mixed rare earth elements RE is not lower than 98% (based on the total weight of the mixed rare earth elements RE).
  • The mixed rare earth elements RE may contain 40wt% to 50wt% of Ce (based on the total weight of the mixed rare earth elements RE).
  • The method for preparing the high-strength casting aluminum alloy material comprises the following steps:
    1. (1) adding a proper amount of aluminum ingots or molten aluminum liquid to a melting furnace, heating until the aluminum ingots or molten aluminum liquid is melted down, and holding at 660 to 850 DEG C;
    2. (2) adding the alloying elements of Cu and Mn by formula ratio and evenly stirring, and then adding trace elements Ti, Cr, Cd, Zr, B, rare earth element Pr, Ce, La or rare earth RE and evenly stirring;
    3. (3) then, refining the alloy melt in the melting furnace, adding a refining agent (chlorine gas, hexachloroethane, manganese chloride and the like may be selected as the refining agent according to different working conditions) to the alloy melt and evenly stirring, wherein the melt should be refined in a closed environment as possible, in order to prevent the melt from water absorption and melting loss;
    4. (4) pouring the alloy liquid out of the melting furnace, and carrying out the online treatment of filtering, degassing and deslagging;
    5. (5) permanent mold casting; and
    6. (6) finally, carrying out solid-solution precipitation strengthening thermal treatment at lower than 620 DEG C within 72 hours.
  • Compared with the prior art, the invention has the following advantages:
    1. (1) Advanced designs of alloying and micro-alloying. By determining the reasonable design of micro-alloying elements (Ti, Cr, B, Zr, Pr, Ce, La and mixed rare earth elements) and composition range thereof based on the main components of Al-Cu-Mn, the invention can achieve the effect of substituting for precious metals, such as Ag and V and reduce the formula cost by 5% to 10%.
    2. (2) Advanced techniques for melting and impurity removal. The invention can effectively break through the technical bottleneck in impurity removal and ensure that the tensile strength of the material is higher than 450MPa and the coefficient of elongation is higher than 5% at the same time.
    3. (3) The invention can maintain the high strength of the material and obviously increase the plasticity thereof at the same time.
  • According to the novelty research concluded by the novelty research center of the Southwest Information Center, MOST (Ministry of Science and Technology), the development and industrialization of the novel high-strength casting aluminum alloy 1, in which the parameters of the element components can be achieved by using the project, are not disclosed in documents or reports at home and abroad. Therefore, the disputes and conflicts can be avoided in the intellectual property and research achievement of the project.
  • The characterization of the composition and performance parameters of the novel materials: the comparison of mechanical properties between some Al-Cu alloys and the high-strength casting aluminum alloy material based on national standards is listed in the following table.
    • Comparison of mechanical properties between Al-Cu alloys and high-strength casting aluminum alloy material 1 based on national standards
  • Alloy Grade Alloy Code Thermal Treatment Conditions Tensile Strength σb/MPa Elongation after Fracture δζ(%)
    ≥
    ZAlCu5Mn ZL201 T5 335 4
    ZAlCu5MnA ZL201A T5 390 8
    ZAlCu10 ZL202 T6 163 -
    ZAlCu4 ZL203 T5 225 3
    ZAlCu5MnCdA ZL204A T5 440 4
    ZAlCu5MnCdVA ZL205A T5 440 7
    T6 470 3
    T7 460 2
    ZAlRE5Cu3Si2 ZL207 T1 175 -
    AlCu4AgMgMn (US) 201.0 T7 415 3
    AlCu4MgTi (US) 206.0 T4 275 8
    Unknown components except Al and Cu (RUS) BAJI10 T4-T7 Maximum 500, minimum 320 Worst 4 (corr. MINσb),
    Optimum 12 (corr. MAXσb)
    AlCuMnTiCrCdZrBRE Novel high-toughness 1 ≤ 620 DEG C ≤ 72h 450 5
    • Detailed Description
  • Example: the high-strength casting aluminum alloy material comprises the following components by weight percentage: 2.0% to 6.0% of Cu, 0.05% to 1.0% of Mn, 0.01% to 0.5% of Ti, 0.01% to 0.2% of Cr, 0.01% to 0.4% of Cd, 0.01% to 0.25% of Zr, 0.005% to 0.04% of B, 0.05% to 0.3% of Pr, Ce, La or mixed rare earth elements RE and the balancing amount of Al and trace impurities.
  • The total content of various rare earth elements in the mixed rare earth elements RE is not lower than 98%, and the content of Ce in the mixed rare earth elements is 45% by weight percentage.
  • (Because the ionic radius and oxidation state of the rare earth elements are similar to those of other elements, the rare earth elements generally coexist with other elements in minerals.)
    1. (1) adding a proper amount of aluminum ingots or molten aluminum liquid to a melting furnace, heating until the aluminum ingots or molten aluminum liquid is melted down, and holding at 660 to 850 DEG C.
    2. (2) adding the alloying elements of Cu and Mn by formula ratio and evenly stirring, and then adding trace elements Ti, Cr, Cd, Zr, B, rare earth elements Pr, Ce, La or RE and evenly stirring.
    3. (3) then, refining the alloy melt in the melting furnace, adding a refining agent (chlorine gas, hexachloroethane, manganese chloride and the like may be selected as the refining agent according to different working conditions) to the alloy melt and evenly stirring, wherein the melt should be refined in a closed environment as possible, in order to prevent the melt from water absorption and melting loss.
    4. (4) pouring the alloy liquid out of the melting furnace, and carrying out the online treatment of filtering, degassing and deslagging.
    5. (5) permanent mold casting.
    6. (6) finally, carrying out solid-solution precipitation strengthening thermal treatment at lower than 620 DEG C within 72 hours.

Claims (4)

  1. A high-strength casting aluminum alloy material, comprising the following components by weight percentage: 2.0% to 6.0% of Cu, 0.05% to 1.0% of Mn, 0.01% to 0.5% of Ti, 0.01% to 0.2% of Cr, 0.01% to 0.4% of Cd, 0.01% to 0.25% of Zr, 0.005% to 0.04% of B, 0.05% to 0.3% of rare earth element and the balancing amount of Al and trace impurities.
  2. The high-strength casting aluminum alloy material according to Claim 1, wherein the rare earth element is Pr, Ce, La or mixed rare earth elements RE.
  3. The high-strength casting aluminum alloy material according to Claim 1, wherein the total content of various rare earth elements in the mixed rare earth elements RE is not lower than 98wt%.
  4. The high-strength casting aluminum alloy material according to Claim 2 or Claim 3, wherein the content of Ce in the mixed rare earth elements RE is 40wt% to 50wt%.
EP09793824.5A 2008-07-09 2009-07-02 High strength casting aluminium alloy material Not-in-force EP2298947B1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CN2008103026690A CN101363093B (en) 2008-07-09 2008-07-09 High-strength cast aluminium alloy material
CN2008103026703A CN101319287B (en) 2008-07-09 2008-07-09 High-strength cast aluminium alloy material
CN2008103026686A CN101363092B (en) 2008-07-09 2008-07-09 High-strength cast aluminium alloy material
CN2008103026718A CN101363094B (en) 2008-07-09 2008-07-09 High-strength cast aluminium alloy material
PCT/CN2009/072603 WO2010003349A1 (en) 2008-07-09 2009-07-02 High strength casting aluminium alloy material

Publications (3)

Publication Number Publication Date
EP2298947A1 true EP2298947A1 (en) 2011-03-23
EP2298947A4 EP2298947A4 (en) 2011-08-03
EP2298947B1 EP2298947B1 (en) 2015-01-28

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EP09793824.5A Not-in-force EP2298947B1 (en) 2008-07-09 2009-07-02 High strength casting aluminium alloy material

Country Status (5)

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US (1) US20110176957A1 (en)
EP (1) EP2298947B1 (en)
JP (1) JP2011526967A (en)
CA (1) CA2729251C (en)
WO (1) WO2010003349A1 (en)

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CN103436743A (en) * 2013-07-16 2013-12-11 安徽省天马泵阀集团有限公司 High-strength casting aluminum alloy material for pump cover and manufacturing method thereof

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US9347558B2 (en) 2010-08-25 2016-05-24 Spirit Aerosystems, Inc. Wrought and cast aluminum alloy with improved resistance to mechanical property degradation
US10266933B2 (en) 2012-08-27 2019-04-23 Spirit Aerosystems, Inc. Aluminum-copper alloys with improved strength
GB201713005D0 (en) 2017-08-14 2017-09-27 Univ Brunel The alloy and manufacturing method of Al-Si-Mg castings for improved mechanical performance
CN112951474A (en) * 2021-02-26 2021-06-11 安徽阿尔泰克铝业材料科技有限公司 Aluminum alloy conductor for aerospace cable
CN114277293B (en) * 2021-12-30 2022-07-26 山西汤荣机械制造股份有限公司 Lightweight composite brake disc and preparation method thereof

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CN103436743A (en) * 2013-07-16 2013-12-11 安徽省天马泵阀集团有限公司 High-strength casting aluminum alloy material for pump cover and manufacturing method thereof

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CA2729251A1 (en) 2010-01-14
JP2011526967A (en) 2011-10-20
EP2298947A4 (en) 2011-08-03
US20110176957A1 (en) 2011-07-21
CA2729251C (en) 2014-04-15
EP2298947B1 (en) 2015-01-28
WO2010003349A1 (en) 2010-01-14

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