EP2247832A2 - Intégration d'un appareil de séparation d'air et d'un cycle à réchauffage de vapeur - Google Patents
Intégration d'un appareil de séparation d'air et d'un cycle à réchauffage de vapeurInfo
- Publication number
- EP2247832A2 EP2247832A2 EP09711757A EP09711757A EP2247832A2 EP 2247832 A2 EP2247832 A2 EP 2247832A2 EP 09711757 A EP09711757 A EP 09711757A EP 09711757 A EP09711757 A EP 09711757A EP 2247832 A2 EP2247832 A2 EP 2247832A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- turbine
- pressure
- separation apparatus
- compressor
- steam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000926 separation method Methods 0.000 title claims abstract description 52
- 238000003303 reheating Methods 0.000 title claims description 11
- 230000010354 integration Effects 0.000 title description 3
- 238000000034 method Methods 0.000 claims abstract description 18
- 239000012530 fluid Substances 0.000 claims abstract description 11
- 239000007789 gas Substances 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000002737 fuel gas Substances 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 238000009628 steelmaking Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 230000005611 electricity Effects 0.000 claims description 4
- 238000005086 pumping Methods 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 3
- 239000000446 fuel Substances 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000002912 waste gas Substances 0.000 claims description 3
- 230000001419 dependent effect Effects 0.000 claims 1
- 238000009835 boiling Methods 0.000 description 7
- 239000003517 fume Substances 0.000 description 7
- 238000003723 Smelting Methods 0.000 description 1
- 238000010793 Steam injection (oil industry) Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
- F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
- F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
- F01K23/10—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle with exhaust fluid of one cycle heating the fluid in another cycle
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
- F25J3/04018—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of main feed air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
- F25J3/04024—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of purified feed air, so-called boosted air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
- F25J3/0403—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
- F25J3/04036—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of oxygen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04109—Arrangements of compressors and /or their drivers
- F25J3/04115—Arrangements of compressors and /or their drivers characterised by the type of prime driver, e.g. hot gas expander
- F25J3/04121—Steam turbine as the prime mechanical driver
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04109—Arrangements of compressors and /or their drivers
- F25J3/04145—Mechanically coupling of different compressors of the air fractionation process to the same driver(s)
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
- F25J3/04612—Heat exchange integration with process streams, e.g. from the air gas consuming unit
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04866—Construction and layout of air fractionation equipments, e.g. valves, machines
- F25J3/04951—Arrangements of multiple air fractionation units or multiple equipments fulfilling the same process step, e.g. multiple trains in a network
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/20—Integrated compressor and process expander; Gear box arrangement; Multiple compressors on a common shaft
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/24—Multiple compressors or compressor stages in parallel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/40—Processes or apparatus involving steps for increasing the pressure of gaseous process streams the fluid being air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2240/00—Processes or apparatus involving steps for expanding of process streams
- F25J2240/70—Steam turbine, e.g. used in a Rankine cycle
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2240/00—Processes or apparatus involving steps for expanding of process streams
- F25J2240/80—Hot exhaust gas turbine combustion engine
- F25J2240/82—Hot exhaust gas turbine combustion engine with waste heat recovery, e.g. in a combined cycle, i.e. for generating steam used in a Rankine cycle
Definitions
- the present invention relates to the integration of an air separation apparatus and a steam heating cycle.
- a booster of an air separation apparatus is a tablet that compresses air already compressed to a pressure of at least 5 bar.
- water vapor 7 enters the high-pressure turbine T1 at 130 bar and 540 ° C. and is then expanded to 30 bar and approximately 300 ° C. forming the flow rate 9.
- the flow 9 returns then in a boiler B where it is heated up to about 540 ° C before being sent to the low-pressure turbine T2 where it is expanded to the pressure of the condenser R typically 150 mbar, then the condensates 11 are pumped by the pump P and returned as flow 5 to the boiler B where they are de-subcooled to their boiling point, then vaporized, and finally superheated to 540 ° C. by heat exchange with a residual flow rate 1 from a gas turbine and possibly an afterburner.
- the fumes 3 are discharged from the boiler.
- the high-pressure turbine T1 and the low-pressure turbine T2 can not be combined into a single body.
- the alternator G equipped with a double-ended shaft is driven by the two turbines the high-pressure turbine T1 rotates at a higher speed than the low-pressure turbine T2
- a reheat cycle is a cycle in which water vapor at high pressure HP (typically over 50 bar) and superheated (typically at a temperature of about 400 to 500 ° C) is relaxed in a first time.
- turbine at a first pressure IP typically less than 50 bar
- IP typically less than 50 bar
- a temperature close to the temperature of the HP vapor before expansion typically the temperature difference between these two vapors is less than 100 0 C
- a second turbine at a pressure less than atmospheric pressure (typically equivalent to 0.2 bar abs.)
- a steam-cycle work generation method in which: a) the water vapor is expanded in a first turbine from a high pressure, generally at above 50 bar, and a high temperature to an intermediate pressure b) the steam is heated to intermediate pressure without substantially changing its pressure c) is expanded in a second turbine water vapor heated to the intermediate pressure up to a low pressure, typically subatmospheric, and a low temperature d) at least a portion of the expanded flow rate is condensed in the second turbine to form a condensed flow; e) two or more steps are optionally pressurized; condensed flow to form a pressurized flow rate f) at least a portion of the pressurized flow is heated to form a heated flow rate g) at least a portion of the heated flow rate is sent to the first turbine h) a fluid for or from an air separation apparatus is compressed in at least one compressor coupled to at least one of the first and second turbines.
- At least part of the work generated by at least one of the first and second turbines is used to generate electricity
- the first turbine drives a main compressor of an air separation apparatus and / or an air booster of an air separation apparatus and / or a product compressor of an air separation apparatus
- the second turbine drives a main compressor of an air separation apparatus and / or an air booster of an air separation apparatus and / or a product compressor of an air separation apparatus ;
- the first turbine and the second turbine are on the same shaft line and drive an air compressor of an air separation apparatus or a product compressor of a separating apparatus and possibly also a generator;
- one or more auxiliary turbines are installed in parallel with the first turbine or the second turbine, the auxiliary turbine or turbines possibly driving a generator and / or a fuel gas compressor and / or a gas compressor produced by the unit of air separation;
- step b) and / or f) takes place at least partially in at least one boiler
- At least one boiler is supplied with a waste gas from a gas turbine, the gas turbine possibly being supplied with a gas coming from the air separation apparatus and possibly fed with a gas coming from a steelmaking process ;
- the steelmaking process is a "smelting reduction" process such as COREX®, FINEX® or a process derived from one of these two processes;
- At least one boiler is heated by combustion of a fuel, possibly from a steelmaking process, in the presence of an oxygen-containing gas;
- the first and second turbines are not on the same shaft line
- At least one of the first and second turbines drives a first compressor that compresses fluid for or from a first air separation apparatus and a second compressor that compresses a fluid for or from a second separation apparatus air;
- At least one of the first and second turbines is on the same shaft as a third turbine forming part of an independent steam cycle;
- the independent steam cycle is a Rankine cycle with reheating;
- the intermediate-pressure water vapor is heated without substantially modifying its pressure in a first boiler, part of the steam intended for the first turbine comes from a second boiler and the steam is expanded at a low pressure in the first turbine is returned to the second boiler after cooling and pumping.
- the invention comprises a steam cycle comprising a first and a second turbine, means for sending a flow of water at high pressure in the first turbine, means for heating the flow relaxed in the first turbine, these means possibly comprising a boiler, means for sending the heated water vapor to the second turbine to relax it to a low pressure, typically subatmospheric, and a low temperature, means for and means for compressing a fluid for or from an air separation apparatus in at least one compressor coupled to at least one of the first and second turbines.
- the cycle may include:
- an electricity generator coupled to at least one of the first and second turbines
- the first turbine drives a main compressor of an air separation apparatus and / or an air booster of an air separation apparatus and / or a product compressor of an air separation apparatus ;
- the second turbine drives a main compressor of an air separation apparatus and / or an air booster of an air separation apparatus and / or a product compressor of an air separation apparatus ;
- the first turbine and the second turbine are on the same shaft line and drive an air compressor of an air separation apparatus or a product compressor of a separating apparatus and possibly also a generator;
- the means for heating the expanded flow rate in the first turbine comprise at least one boiler; at least one boiler is supplied with a waste gas from a gas turbine, the gas turbine possibly being supplied with a gas coming from the air separation apparatus;
- At least one boiler is heated by combustion of a fuel in the presence of an oxygen-containing gas
- the first and second turbines are not on the same shaft line
- At least one of the first and second turbines drives a first compressor that compresses fluid for or from a first air separation apparatus and a second compressor that compresses a fluid for or from a second separation apparatus air;
- At least one of the first and second turbines is on the same shaft as at least one third turbine forming part of an independent steam cycle;
- the independent steam cycle is a Rankine cycle with reheating
- the cycle comprises a first boiler for heating the steam at intermediate pressure without substantially modifying its pressure, a second boiler, means for sending steam from the second boiler to the first turbine, means for cooling steam; expanded at a low pressure in the first turbine, means for pumping the condensed vapor and means for returning the condensed vapor to the second boiler.
- a heating-reheat cycle is used as described above for mechanically driving at least one compressor of an air separation apparatus.
- the condensates 11 are pumped by the pump P and returned as flow 5 to the boiler B where they are de-subcooled to their boiling point, then vaporized, and finally superheated to 540 0 C. by heat exchange with a residual flow 1 from a gas turbine and possibly an afterburner or the burner of a conventional boiler.
- the fumes 3 are discharged from the boiler.
- the two turbines T1, T2 are attached to a double-ended shaft which drives the generator G and the compressor 13 of an air separation apparatus C producing an air flow 13 at a pressure between 5 and 12 bar.
- an air booster BC of an air separation apparatus can be driven by the two turbines T1, T2 and produces an air flow 15 at between 12 and 40 bar.
- the compression of the condensates can be done in two steps: a first step where the condensates are pumped to a pressure of about 5 bar, then partially de-cooled and then deaerated (removal of air dissolved) by steam injection, and finally pumped down to the inlet pressure of the High Pressure turbine (-130 bar).
- the condensates 11 are pumped by the pump P and returned as flow 5 to the boiler B where they are de-subcooled to their boiling point, then vaporized, and finally superheated to 540 0 C by heat exchange with a residual flow from a gas turbine and possibly an afterburner or the burner of a conventional boiler ..
- the fumes are rejected from Boiler.
- the first turbine T1 is coupled to a generator G and the second turbine T2 is attached to a shaft which drives the compressor 13 of an air separation apparatus C producing an air flow 13 at a pressure between 5 and 12 bar .
- an air booster BC of an air separation apparatus may be driven by the second turbine T2 and produce an air flow of between 12 and 40 bar.
- a generator G is driven by the turbine T2. With this arrangement, machines can be maintained independently.
- one (or more) auxiliary turbine T3 can be installed in parallel with the turbine T2 and relax the excess steam not consumed by the turbine T2. This turbine T3 can drive a generator and / or a fuel gas compressor (which feeds a gas turbine).
- the condensates 11 are pumped by the pump P and returned as flow 5 to the boiler B where they are de-subcooled to their boiling point, then vaporized, and finally superheated to 540 ° C. heat exchange with a residual flow from a gas turbine and possibly afterburner or the burner of a conventional boiler.
- the fumes are discharged from the boiler.
- the first turbine T1 is coupled to the compressor 13 of an air separation apparatus C producing an air flow 13 at a pressure between 5 and 12 bar and possibly a generator G.
- a The air booster BC of an air separation apparatus can be driven by the first turbine T1 and produces an air flow 15 at between 12 and 40 bar.
- the second turbine T2 drives a generator G.
- auxiliary turbine T3 can be installed in parallel with the turbine T1 and relax the excess steam not consumed by the turbine T1.
- This turbine T1 can drive a generator and / or a fuel gas compressor (which feeds a gas turbine).
- the condensates 11 are pumped by the pump P and returned as flow 5 to the boiler B where they are subcooled to their boiling point, then vaporized, and finally superheated to 540 0 C by exchange heat with a residual flow from a gas turbine and possibly afterburner or the burner of a conventional boiler.
- the fumes are discharged from the boiler.
- the first turbine T1 is coupled to the air booster BC of an air separation apparatus and produces an air flow of between 12 and 40 bar. It is optionally also coupled to a generator G.
- the second turbine T2 drives the compressor 13 of an air separation apparatus C producing an air flow 13 at a pressure between 5 and 12 bar and possibly a generator G.
- auxiliary turbine T3 can be installed in parallel with the turbine T1 and relax the excess steam not consumed by the turbine T1.
- This turbine T1 can drive a generator and / or a fuel gas compressor (which feeds a gas turbine).
- auxiliary turbine T4 can be installed in parallel with the turbine T2 and relax the excess steam. consumed by the turbine T2.
- This turbine T4 can drive a generator and / or a fuel gas compressor (which feeds a gas turbine).
- the condensates 11 are pumped by the pump P and returned as flow 5 to the boiler B where they are de-subcooled to their boiling point, then vaporized, and finally superheated to 540 ° C. heat exchange with a residual flow from a gas turbine and possibly afterburner or the burner of a conventional boiler.
- the fumes are discharged from the boiler.
- the first turbine T1 is coupled to the compressor 13 of an air separation apparatus C producing an air flow 13 at a pressure between 5 and 12 bar and possibly a generator G.
- the air booster BC of a Air separation apparatus is driven by the second turbine T2 and produces an air flow 15 at between 12 and 40 bar.
- the second turbine T2 possibly drives a generator G.
- auxiliary turbine T3 can be installed in parallel with the turbine T1 and relax the excess steam not consumed by the turbine T1.
- This turbine T1 can drive a generator and / or a fuel gas compressor (which feeds a gas turbine).
- auxiliary turbine T4 can be installed in parallel with the turbine T2 and relax the excess steam not consumed by the turbine T2.
- This turbine T4 can drive a generator and / or a fuel gas compressor (which feeds a gas turbine).
- the condensates 11 are pumped by the pump P and returned as flow 5 to the boiler B where they are de-subcooled to their boiling point, then vaporized, and finally superheated to 540 ° C. by heat exchange with a residual flow from a gas turbine and possibly an afterburner or the burner of a conventional boiler.
- the fumes are discharged from the boiler.
- the first turbine T1 is coupled to the compressor of a first air separation apparatus C producing an air flow 13 at a pressure between 5 and 12 bar and possibly a generator G.
- the second turbine T1 is coupled to the compressor C of a second air separation unit, producing an air flow 13 'at a pressure between 5 and 12 bar, and possibly a generator G.
- Figure 8 illustrates a cycle where two boilers B 1 B 'are integrated.
- FIG. 9 illustrates a cycle in which two boilers B1, B2 are used.
- high pressure steam 101 from a first boiler B1 is mixed with high pressure steam 107 from a second boiler B2 to form a flow 109.
- This common flow 109 is expanded in a turbine T1.
- a flow of steam 103 is withdrawn intermediate the turbine T1 and a flow 105 expanded throughout the turbine T1 is cooled, pumped and recycled in the second boiler B2.
- the flow 103 is returned to the first boiler B1 where it heats up.
- the heated flow rate 9 is expanded in a turbine T2 which drives at least one compressor C of an air separation apparatus.
- the expanded steam is recycled to the first boiler after cooling R 'and pumping P'.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Control Of Turbines (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0851004A FR2927654A1 (fr) | 2008-02-18 | 2008-02-18 | Integration d'un appareil de separation d'air et d'un cycle a rechauffage de vapeur |
| FR0852296A FR2929696A1 (fr) | 2008-04-07 | 2008-04-07 | Integration d'un appareil de separation d'air et d'un cycle a rechauffage de vapeur |
| PCT/FR2009/050248 WO2009103926A2 (fr) | 2008-02-18 | 2009-02-17 | Intégration d'un appareil de séparation d'air et d'un cycle à réchauffage de vapeur |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2247832A2 true EP2247832A2 (fr) | 2010-11-10 |
Family
ID=40985984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09711757A Withdrawn EP2247832A2 (fr) | 2008-02-18 | 2009-02-17 | Intégration d'un appareil de séparation d'air et d'un cycle à réchauffage de vapeur |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20100314888A1 (fr) |
| EP (1) | EP2247832A2 (fr) |
| JP (1) | JP2011518269A (fr) |
| KR (1) | KR20100127755A (fr) |
| CN (1) | CN102046929A (fr) |
| AU (1) | AU2009216592B2 (fr) |
| BR (1) | BRPI0906658A2 (fr) |
| CA (1) | CA2714624A1 (fr) |
| EA (1) | EA201070977A1 (fr) |
| MX (1) | MX2010008888A (fr) |
| WO (1) | WO2009103926A2 (fr) |
| ZA (1) | ZA201005540B (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8587138B2 (en) * | 2009-06-04 | 2013-11-19 | Kevin Statler | Systems for the recovery of gas and/or heat from the melting of metals and/or the smelting of ores and conversion thereof to electricity |
| JP6087196B2 (ja) * | 2012-12-28 | 2017-03-01 | レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード | 低温圧縮ガスまたは液化ガスの製造装置および製造方法 |
| JP6267028B2 (ja) * | 2014-03-24 | 2018-01-24 | 三菱日立パワーシステムズ株式会社 | 排熱回収装置、これを備えているガスタービンプラント、及び排熱回収方法 |
| US20160297694A1 (en) * | 2015-04-07 | 2016-10-13 | General Electric Company | Hybrid vapor compression membrane distillation drive assemblyand method of use |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE820600C (de) * | 1950-05-21 | 1951-11-12 | Grosskraftwerk Mannheim A G | Dampfkraftanlage, deren Kessel seine Verbrennungsluft aus einer Luftturbine erhaelt |
| SE8003793L (sv) * | 1979-10-05 | 1981-04-06 | Wallace Murray Corp | Kombination av en konventionell forbrenningsmotor och en rankinecykelmotor |
| FI86435C (fi) * | 1983-05-31 | 1992-08-25 | Siemens Ag | Medellastkraftverk med en integrerad kolfoergasningsanlaeggning. |
| JPH08291291A (ja) * | 1995-04-21 | 1996-11-05 | Hitachi Ltd | ガス化プラント及びガス化発電プラント |
| JPH1135950A (ja) * | 1996-12-26 | 1999-02-09 | Mitsubishi Heavy Ind Ltd | 発電方法及び発電装置 |
| US6003298A (en) * | 1997-10-22 | 1999-12-21 | General Electric Company | Steam driven variable speed booster compressor for gas turbine |
| WO2003049122A2 (fr) * | 2001-12-03 | 2003-06-12 | Clean Energy Systems, Inc. | Systemes de production alimente en charbon et en gaz de synthese a emission atmospherique zero |
| DE102005026534B4 (de) * | 2005-06-08 | 2012-04-19 | Man Diesel & Turbo Se | Dampferzeugungsanlage |
| DE102006008600A1 (de) * | 2006-02-13 | 2007-08-16 | Helmut Nopper | Effizientes Niedertemperatur-Energieerzeugungsverfahren mit integriertem Energiespeicher |
-
2009
- 2009-02-17 WO PCT/FR2009/050248 patent/WO2009103926A2/fr not_active Ceased
- 2009-02-17 AU AU2009216592A patent/AU2009216592B2/en not_active Expired - Fee Related
- 2009-02-17 MX MX2010008888A patent/MX2010008888A/es not_active Application Discontinuation
- 2009-02-17 JP JP2010546385A patent/JP2011518269A/ja active Pending
- 2009-02-17 EA EA201070977A patent/EA201070977A1/ru unknown
- 2009-02-17 CN CN2009801056092A patent/CN102046929A/zh active Pending
- 2009-02-17 KR KR1020107017986A patent/KR20100127755A/ko not_active Withdrawn
- 2009-02-17 EP EP09711757A patent/EP2247832A2/fr not_active Withdrawn
- 2009-02-17 BR BRPI0906658A patent/BRPI0906658A2/pt not_active IP Right Cessation
- 2009-02-17 CA CA2714624A patent/CA2714624A1/fr not_active Abandoned
- 2009-02-17 US US12/866,489 patent/US20100314888A1/en not_active Abandoned
-
2010
- 2010-08-03 ZA ZA2010/05540A patent/ZA201005540B/en unknown
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2009103926A3 * |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2010008888A (es) | 2010-08-31 |
| EA201070977A1 (ru) | 2011-04-29 |
| ZA201005540B (en) | 2011-12-28 |
| WO2009103926A2 (fr) | 2009-08-27 |
| WO2009103926A3 (fr) | 2011-03-03 |
| BRPI0906658A2 (pt) | 2016-10-11 |
| CN102046929A (zh) | 2011-05-04 |
| WO2009103926A4 (fr) | 2011-03-24 |
| AU2009216592B2 (en) | 2012-11-01 |
| US20100314888A1 (en) | 2010-12-16 |
| AU2009216592A1 (en) | 2009-08-27 |
| CA2714624A1 (fr) | 2009-08-27 |
| JP2011518269A (ja) | 2011-06-23 |
| KR20100127755A (ko) | 2010-12-06 |
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