EP2231350A2 - Sintering of briquettes by dfi burners - Google Patents

Sintering of briquettes by dfi burners

Info

Publication number
EP2231350A2
EP2231350A2 EP08869608A EP08869608A EP2231350A2 EP 2231350 A2 EP2231350 A2 EP 2231350A2 EP 08869608 A EP08869608 A EP 08869608A EP 08869608 A EP08869608 A EP 08869608A EP 2231350 A2 EP2231350 A2 EP 2231350A2
Authority
EP
European Patent Office
Prior art keywords
dfi
metal powder
briquettes
sintering
flame
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP08869608A
Other languages
German (de)
French (fr)
Other versions
EP2231350B1 (en
Inventor
Jonas Adolfi
Henrik Gripenberg
Kosti JYLHÄ
David Muren
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linde GmbH
Original Assignee
Linde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde GmbH filed Critical Linde GmbH
Priority to EP08869608A priority Critical patent/EP2231350B1/en
Publication of EP2231350A2 publication Critical patent/EP2231350A2/en
Application granted granted Critical
Publication of EP2231350B1 publication Critical patent/EP2231350B1/en
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10—Sintering only
    • B22F3/1003—Use of special medium during sintering, e.g. sintering aid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy

Definitions

  • the invention relates to a method for sintering a metal powder, especially a green body briquette of a metal powder.
  • the invention relates to the field of sintering of briquettes from metal powder.
  • Sintering is defined as the thermal treatment of a powder or compact at a temperature below the melting point of the main constituent, for the purpose of increasing its strength by bonding together of the particles.
  • the metal powder is pressed into so called green body briquettes and these are sintered at an elevated temperature. During the sintering process atomic diffusion takes place and the powder particles are welded together. The reason for the sintering is to produce a briquette that has enough strength to resist transportation to and handling by the end user.
  • a typical weight of such a briquette is 100 g.
  • a long continuous mesh belt furnace is normally used.
  • such a furnace can be 30 m long and consists of three temperature zones, a 5 m pre-heating zone, a 10 m sintering zone and a 15 m cooling zone.
  • the furnace is electrically heated.
  • the mesh belt transports the briquettes through the furnace at e.g. a speed of 10 m/hour, that is the total process time is about 3 hours.
  • the prior art sintering is a slow process. Due to the inefficient heating the mesh belt has to be operated at a low speed of and the furnace must have a long length, for example 30 m. Such large furnaces represent a significant investment. In order to increase the productivity of such a furnace, the furnace would have to be built even longer.
  • the Ni briquettes start to oxidize in air at temperatures over 400 0 C. As oxidation is time dependent a long exposure time to temperatures over 400 0 C as it is necessary in the prior art furnaces is a disadvantage. Therefore, depending on quality requirements, in the prior art sintering furnaces a nitrogen rich atmosphere is sometimes being used to protect the briquettes from oxidation.
  • a further object of the invention is to provide a method for sintering metal briquettes which avoids or at least reduces the oxidation of the briquettes during sintering.
  • a method for sintering a metal powder especially a green body briquette of a metal powder, which is characterized in that said metal powder is heated by means of at least one DFI burner and that said metal powder is directly exposed to the flame(s) of said DFI burner(s).
  • the invention relates to a method for sintering metal powder and in particular to a method for sintering of metal powders which are pressed into so called green body briquettes.
  • briquette shall also cover any kind of a body or compact of metal powder.
  • the invention will be explained with reference to the preferred embodiment of sintering briquettes of metal powders.
  • the invention as described in the following can also be used for sintering of metal powders in any other form rather than briquettes.
  • this is achieved by heating the metal powder or the briquette by means of DFI burners where "DFI” is an abbreviation for "direct flame impingement".
  • the DFI burners are located such that the metal powder or the briquette are exposed to the flame (DFI flame) of the DFI burner, that is the DFI flame directly impinges the surface of the briquette.
  • the DFI flame or the DFI flames completely enclose the briquette such that the whole briquette is within the DFI flame.
  • said DFI bumer(s) are fed with a gaseous or liquid fuel and an oxidant containing more than 80% per weight of oxygen, preferably more than 90 %, more preferred more than 95 %.
  • an oxyfuel burner is used as DFI burner.
  • the heat treatment by means of the DFI burners is carried out while the briquettes are in motion. Therefore, the briquettes are loaded on a transport system, especially on a conveyor belt, mesh belt or link belt, and passed through the flame(s) of said DFI burner(s).
  • DFI burners For heating the briquette one or more DFI burners can be used.
  • the number of DFI burners depends among others on the required or desired heating power.
  • the sintering process is carried out in a short furnace and said DFI bumer(s) are located at the roof of the furnace.
  • the dimensions of a typical furnace for carrying out the invention are: length between 2 and 4 m, width between 0.5 and 1.5 m and height between 1.5 and 2.5 m.
  • the flame of the DFI burner directly hits the surface of the briquette or metal powder and heats it up. Thereby a high heat transfer to the metal powder and a high heating rate are achieved. As a consequence the exposure time, that is the time the metal powder or briquette is subjected to heat, can be considerably decreased. As an example a load of 1 ton briquettes per hour can be heated using DFI burners with a heating power of 100 to 300 kW.
  • the metal powder is exposed to the flame(s) of said DFI burner(s) for less than 5 minutes, preferably less than 2 minutes, more preferred between 30 and 90 seconds. It has been found that within that during that heating time and during the subsequent cooling to room temperature the sintering process can be completed and briquettes are produced which have enough strength to resist transportation and further handling by the end user.
  • the sintered briquette is preferably transported to a silo or other storage system for cooling and storage. Since the briquette might leave the DFI flames at a temperature above 400 0 C there is a certain risk that the briquette starts to oxidize. Therefore, it is preferred to inert that silo or storage system by an inert gas, preferably nitrogen or argon.
  • the invention can be used for sintering of any kinds of metal powders, however the preferred field of application is the sintering of briquettes of nickel powder.
  • the Ni powder is for example produced via reduction of NiSO 4 with hydrogen.
  • a typical weight of such nickel briquettes is between 50 and 500 grams, preferably between 100 and 200 grams.
  • the inventive heating process is preferably used to carry out the complete sintering process. That is the briquettes leaving the DFI flames have received and/or accumulated enough energy to achieve the required strength.
  • the DFI burners it is also possible to use the DFI burners only for pre-heating the metal powder or briquettes and subsequently pass the pre-heated briquettes to a conventional sintering furnace which might be heated by eletrical means as described in the introductory part of this specification.
  • FIG. 1 shows a first embodiment of the invention
  • Nickel powder is produced by reduction of NiSO 4 with hydrogen. The nickel powder is then pressed to green body briquettes 1. The green body briquettes 1 are placed onto a conveyor belt 2 and transported to a short furnace 3 with a length of 2 to 4 m. The furnace 3 is heated by means of DFI oxyfuel burners 4 which are fed with a fuel gas and an oxidant containing more than 90 weigth-% oxygen.
  • the DFI oxyfuel burners 4 are located in the roof of the furnace 3 and its flame is directed vertically from above onto the conveyor belt 2.
  • the briquettes 1 pass through the furnace 3. Within the furnace 3 the surface of the briquettes 1 is directly impinged by the flame of the DFI burner 4.
  • the speed of the conveyor belt 2 is such that the briquettes 1 are exposed to the flames of the DFI burners 4 for about 1 minute. After that time the sintering process is completed.
  • the sintered briquettes 5 leave the furnace 3 and fall off the conveyor belt 2.
  • FIG. 2 shows an alternative embodiment of the invention.
  • the embodiment according to figure 2 differs from the one according to figure 1 in that the sintered briquettes 5 fall into a silo 6 for cooling and storage. Within the silo 6 an inert atmosphere is created by feeding gaseous nitrogen from a nitrogen storage container 7 into the silo 6. Thus, the sintered briquettes 5 are kept in an inert atmosphere in order to avoid oxidation.
  • Tests were made in lab scale to pre-heat loads of 2 kg briquettes using DFI oxyfuel burners with a heating power of 20 to 50 kW.
  • the residence times of the briquettes in the flame were between 12 and 54 seconds.
  • the abrasive strength of the heated briquettes was evaluated.
  • the abrasive strength was found to be the same as for briquettes sintered in a furnace according to prior art. It was found that the DFI process had not only preheated the briquettes but had also completed the sintering process. Surprisingly the complete sintering process could be made during this exceptional short time by using the DFI process. This was also confirmed by studying the macro structure of cut through briquettes. Also no significant oxidation occurred, there was only a slight discoloration of the surface.

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Inert Electrodes (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

There is provided a method for sintering a metal powder, such as a green body briquette of a metal powder, which includes heating the metal powder by at least one DFI burner providing a flame for contacting said metal powder which is directly exposed to the flame of the at least one DFI burner.

Description

Sintering of Briquettes
The invention relates to a method for sintering a metal powder, especially a green body briquette of a metal powder.
The invention relates to the field of sintering of briquettes from metal powder. Sintering is defined as the thermal treatment of a powder or compact at a temperature below the melting point of the main constituent, for the purpose of increasing its strength by bonding together of the particles.
The metal powder is pressed into so called green body briquettes and these are sintered at an elevated temperature. During the sintering process atomic diffusion takes place and the powder particles are welded together. The reason for the sintering is to produce a briquette that has enough strength to resist transportation to and handling by the end user. A typical weight of such a briquette is 100 g.
It is state of the art to sinter metal briquettes, for example nickel briquettes, at a temperature between 700 and 1000 0C. A long continuous mesh belt furnace is normally used. As an example, such a furnace can be 30 m long and consists of three temperature zones, a 5 m pre-heating zone, a 10 m sintering zone and a 15 m cooling zone. The furnace is electrically heated. The mesh belt transports the briquettes through the furnace at e.g. a speed of 10 m/hour, that is the total process time is about 3 hours.
Thus, the prior art sintering is a slow process. Due to the inefficient heating the mesh belt has to be operated at a low speed of and the furnace must have a long length, for example 30 m. Such large furnaces represent a significant investment. In order to increase the productivity of such a furnace, the furnace would have to be built even longer.
It is an object of the invention to provide a method for sintering metal briquettes which is faster than the prior art sintering processes and which requires less investments. The Ni briquettes start to oxidize in air at temperatures over 400 0C. As oxidation is time dependent a long exposure time to temperatures over 400 0C as it is necessary in the prior art furnaces is a disadvantage. Therefore, depending on quality requirements, in the prior art sintering furnaces a nitrogen rich atmosphere is sometimes being used to protect the briquettes from oxidation.
Thus, a further object of the invention is to provide a method for sintering metal briquettes which avoids or at least reduces the oxidation of the briquettes during sintering.
These objects are achieved by a method for sintering a metal powder, especially a green body briquette of a metal powder, which is characterized in that said metal powder is heated by means of at least one DFI burner and that said metal powder is directly exposed to the flame(s) of said DFI burner(s).
The invention relates to a method for sintering metal powder and in particular to a method for sintering of metal powders which are pressed into so called green body briquettes. The term "briquette" shall also cover any kind of a body or compact of metal powder. In the following the invention will be explained with reference to the preferred embodiment of sintering briquettes of metal powders. However, for the man skilled in the art it is obvious that the invention as described in the following can also be used for sintering of metal powders in any other form rather than briquettes.
According to the invention this is achieved by heating the metal powder or the briquette by means of DFI burners where "DFI" is an abbreviation for "direct flame impingement". The DFI burners are located such that the metal powder or the briquette are exposed to the flame (DFI flame) of the DFI burner, that is the DFI flame directly impinges the surface of the briquette. Preferably, the DFI flame or the DFI flames completely enclose the briquette such that the whole briquette is within the DFI flame.
According to a preferred embodiment said DFI bumer(s) are fed with a gaseous or liquid fuel and an oxidant containing more than 80% per weight of oxygen, preferably more than 90 %, more preferred more than 95 %. Thus, preferably an oxyfuel burner is used as DFI burner. Preferably, the heat treatment by means of the DFI burners is carried out while the briquettes are in motion. Therefore, the briquettes are loaded on a transport system, especially on a conveyor belt, mesh belt or link belt, and passed through the flame(s) of said DFI burner(s).
For heating the briquette one or more DFI burners can be used. The number of DFI burners depends among others on the required or desired heating power.
Preferably, the sintering process is carried out in a short furnace and said DFI bumer(s) are located at the roof of the furnace. The dimensions of a typical furnace for carrying out the invention are: length between 2 and 4 m, width between 0.5 and 1.5 m and height between 1.5 and 2.5 m.
The flame of the DFI burner directly hits the surface of the briquette or metal powder and heats it up. Thereby a high heat transfer to the metal powder and a high heating rate are achieved. As a consequence the exposure time, that is the time the metal powder or briquette is subjected to heat, can be considerably decreased. As an example a load of 1 ton briquettes per hour can be heated using DFI burners with a heating power of 100 to 300 kW.
According to a preferred embodiment the metal powder is exposed to the flame(s) of said DFI burner(s) for less than 5 minutes, preferably less than 2 minutes, more preferred between 30 and 90 seconds. It has been found that within that during that heating time and during the subsequent cooling to room temperature the sintering process can be completed and briquettes are produced which have enough strength to resist transportation and further handling by the end user.
Due to the short exposure time oxidation of the metal powder does not constitute a problem. Consequently it becomes possible to carry out the heating by means of said DFI burner(s) in an atmosphere containing the products of combustion.
After the inventive heating process by means of the DFI burners the sintered briquette is preferably transported to a silo or other storage system for cooling and storage. Since the briquette might leave the DFI flames at a temperature above 400 0C there is a certain risk that the briquette starts to oxidize. Therefore, it is preferred to inert that silo or storage system by an inert gas, preferably nitrogen or argon.
The invention can be used for sintering of any kinds of metal powders, however the preferred field of application is the sintering of briquettes of nickel powder. The Ni powder is for example produced via reduction of NiSO4 with hydrogen. A typical weight of such nickel briquettes is between 50 and 500 grams, preferably between 100 and 200 grams.
The inventive heating process is preferably used to carry out the complete sintering process. That is the briquettes leaving the DFI flames have received and/or accumulated enough energy to achieve the required strength. However, it is also possible to use the DFI burners only for pre-heating the metal powder or briquettes and subsequently pass the pre-heated briquettes to a conventional sintering furnace which might be heated by eletrical means as described in the introductory part of this specification.
The invention as well as preferred embodiments of the invention will be described in more detail below with reference to the attached drawings, where:
- figure 1 shows a first embodiment of the invention and
- figure 2 shows an alternative embodiment of the invention.
Nickel powder is produced by reduction of NiSO4 with hydrogen. The nickel powder is then pressed to green body briquettes 1. The green body briquettes 1 are placed onto a conveyor belt 2 and transported to a short furnace 3 with a length of 2 to 4 m. The furnace 3 is heated by means of DFI oxyfuel burners 4 which are fed with a fuel gas and an oxidant containing more than 90 weigth-% oxygen.
The DFI oxyfuel burners 4 are located in the roof of the furnace 3 and its flame is directed vertically from above onto the conveyor belt 2. The briquettes 1 pass through the furnace 3. Within the furnace 3 the surface of the briquettes 1 is directly impinged by the flame of the DFI burner 4. The speed of the conveyor belt 2 is such that the briquettes 1 are exposed to the flames of the DFI burners 4 for about 1 minute. After that time the sintering process is completed. The sintered briquettes 5 leave the furnace 3 and fall off the conveyor belt 2.
Figure 2 shows an alternative embodiment of the invention. In both figures the same reference numbers refer to the same parts. The embodiment according to figure 2 differs from the one according to figure 1 in that the sintered briquettes 5 fall into a silo 6 for cooling and storage. Within the silo 6 an inert atmosphere is created by feeding gaseous nitrogen from a nitrogen storage container 7 into the silo 6. Thus, the sintered briquettes 5 are kept in an inert atmosphere in order to avoid oxidation.
Example:
Tests were made in lab scale to pre-heat loads of 2 kg briquettes using DFI oxyfuel burners with a heating power of 20 to 50 kW. The residence times of the briquettes in the flame were between 12 and 54 seconds.
The abrasive strength of the heated briquettes was evaluated. The abrasive strength was found to be the same as for briquettes sintered in a furnace according to prior art. It was found that the DFI process had not only preheated the briquettes but had also completed the sintering process. Surprisingly the complete sintering process could be made during this exceptional short time by using the DFI process. This was also confirmed by studying the macro structure of cut through briquettes. Also no significant oxidation occurred, there was only a slight discoloration of the surface.

Claims

Claims
1. Method for sintering a metal powder (1), especially a green body briquette of a metal powder, characterized in that said metal powder (1) is heated by means of at least one DFI burner (4) and that said metal powder (1) is directly exposed to the flame(s) of said DFI burner (4).
2. Method according to claim 1 characterized in that said DFI burner(s) (4) are fed with a gaseous or liquid fuel and an oxidant containing more than 80% per weight of oxygen.
3. Method according to any of claims 1 or 2 characterized in that said metal powder (1) is loaded on a transport system (2), especially a conveyor belt, mesh belt or link belt, and passed through the flame(s) of said DFI bumer(s) (4).
4. Method according to any of claims 1 to 3 characterized in that said DFI burner(s) (4) are located at the roof of a furnace (3).
5. Method according to any of claims 1 to 4 characterized in that said metal powder (1) is exposed to the flame(s) of said DFI burner(s) (4) for less than 5 minutes, preferably less than 2 minutes, more preferred between 30 and 90 seconds.
6. Method according to any of claims 1 to 5 characterized in that nickel powder is sintered by means of said DFI bumer(s) (4).
7. Method according to any of claims 1 to 6 characterized in that said heating by means of said DFI burner(s) (4) is carried out in air atmosphere.
8. Method according to any of claims 1 to 7 characterized in that said metal powder (1) are subjected to an inert atmosphere (6, 7) after being heated by means of said DFI burner(s) (4).
9. Method according to any of claims 1 to 8 characterized in that said metal powder (1) is first heated by means of said DFI burner(s) (4) and then heated in an electrically heated furnace.
EP08869608A 2008-01-10 2008-09-30 Sintering of briquettes by dfi burners Not-in-force EP2231350B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP08869608A EP2231350B1 (en) 2008-01-10 2008-09-30 Sintering of briquettes by dfi burners

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP08000390 2008-01-10
EP08869608A EP2231350B1 (en) 2008-01-10 2008-09-30 Sintering of briquettes by dfi burners
PCT/EP2008/008297 WO2009086854A2 (en) 2008-01-10 2008-09-30 Sintering of briquettes by dfi burners

Publications (2)

Publication Number Publication Date
EP2231350A2 true EP2231350A2 (en) 2010-09-29
EP2231350B1 EP2231350B1 (en) 2012-01-18

Family

ID=39365732

Family Applications (1)

Application Number Title Priority Date Filing Date
EP08869608A Not-in-force EP2231350B1 (en) 2008-01-10 2008-09-30 Sintering of briquettes by dfi burners

Country Status (7)

Country Link
US (1) US20100303664A1 (en)
EP (1) EP2231350B1 (en)
CN (1) CN101909788A (en)
AT (1) ATE541658T1 (en)
BR (1) BRPI0821670A2 (en)
ES (1) ES2380277T3 (en)
WO (1) WO2009086854A2 (en)

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1938606B2 (en) * 1968-08-01 1972-05-04 Nippon Steel Corp , Tokio Sintering process for iron ore in powder form and sintering apparatus for carrying out this process
JPS57192202A (en) * 1981-05-22 1982-11-26 Toyota Motor Corp Rapid manufacturing method of sintered product
US5009842A (en) * 1990-06-08 1991-04-23 Board Of Control Of Michigan Technological University Method of making high strength articles from forged powder steel alloys
JP3248505B2 (en) * 1999-02-12 2002-01-21 相田化学工業株式会社 Noble metal sintered product and method for producing the same
JP2000026903A (en) * 1999-06-28 2000-01-25 Aida Kagaku Kogyo Kk Sintering method of noble metal-containing clay
SE531077C2 (en) * 2006-04-11 2008-12-09 Aga Ab Method of heating metal material
SE530353C2 (en) * 2006-04-25 2008-05-13 Aga Ab DFI burner comprising a metal block and two nozzles extending from the metal block

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2009086854A2 *

Also Published As

Publication number Publication date
US20100303664A1 (en) 2010-12-02
ATE541658T1 (en) 2012-02-15
WO2009086854A3 (en) 2009-10-01
CN101909788A (en) 2010-12-08
BRPI0821670A2 (en) 2015-06-16
WO2009086854A2 (en) 2009-07-16
ES2380277T3 (en) 2012-05-10
EP2231350B1 (en) 2012-01-18

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