EP2185747B1 - Method and device for secondary descaling steel strip with low pressure water jets - Google Patents
Method and device for secondary descaling steel strip with low pressure water jets Download PDFInfo
- Publication number
- EP2185747B1 EP2185747B1 EP08843858.5A EP08843858A EP2185747B1 EP 2185747 B1 EP2185747 B1 EP 2185747B1 EP 08843858 A EP08843858 A EP 08843858A EP 2185747 B1 EP2185747 B1 EP 2185747B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- descaling
- water
- nozzles
- strip
- bars
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 26
- 238000000034 method Methods 0.000 title claims description 20
- 229910000831 Steel Inorganic materials 0.000 title claims description 18
- 239000010959 steel Substances 0.000 title claims description 18
- 238000001816 cooling Methods 0.000 claims description 11
- 239000002352 surface water Substances 0.000 claims description 10
- 238000011144 upstream manufacturing Methods 0.000 claims description 7
- 238000005098 hot rolling Methods 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 description 14
- 230000004907 flux Effects 0.000 description 10
- 238000005096 rolling process Methods 0.000 description 9
- 239000002184 metal Substances 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 229940105847 calamine Drugs 0.000 description 6
- 229910052864 hemimorphite Inorganic materials 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 235000014692 zinc oxide Nutrition 0.000 description 6
- 239000011787 zinc oxide Substances 0.000 description 6
- CPYIZQLXMGRKSW-UHFFFAOYSA-N zinc;iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+3].[Fe+3].[Zn+2] CPYIZQLXMGRKSW-UHFFFAOYSA-N 0.000 description 6
- 238000012423 maintenance Methods 0.000 description 5
- 239000000498 cooling water Substances 0.000 description 4
- 240000000966 Allium tricoccum Species 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000008602 contraction Effects 0.000 description 3
- 235000021183 entrée Nutrition 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000009434 installation Methods 0.000 description 2
- 230000002262 irrigation Effects 0.000 description 2
- 238000003973 irrigation Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 241000897276 Termes Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001595 contractor effect Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 230000008521 reorganization Effects 0.000 description 1
- 238000010405 reoxidation reaction Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 238000012549 training Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G3/00—Apparatus for cleaning or pickling metallic material
- C23G3/02—Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously
- C23G3/023—Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously by spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/02—Cleaning by the force of jets or sprays
- B08B3/022—Cleaning travelling work
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/04—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing
- B21B45/08—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing hydraulically
Definitions
- the present invention relates to the descaling operation of a metal strip, in particular steel, scrolling during hot rolling before entering the milling or finishing cages of the rolling mill
- the secondary descaling of the steel strips is intended to rid the surface of the band of the so-called secondary scale, which is formed by rapid reoxidation of the hot metal during the stay of the strip in the open air after its primary descaling on leaving the oven. It thus intervenes doubly during the rolling, first before the entry of the strip in the roughing, and before entering the finisher rolling mill.
- secondary descaling at the finisher inlet it being understood that what is said in this connection applies essentially also to secondary descaling at the entrance. of roughing.
- the secondary scale is generally in the form of an adherent layer of metal oxides, typically between 50 and 100 microns thick, rather irregular in appearance.
- the secondary descaling is successful when it provides at the entrance of the finisher a steel strip having on the surface a uniform layer of residual scale of 20 to 30 microns thick just beyond, to avoid encrustations of oxides on rolling rolls.
- the descaling operation consists schematically in impacting the surface of the moving strip by powerful water jets delivered by spray bars placed at a short distance and provided with injection nozzles fed under high pressure, typically above 130-150 bars, or even more than 200 bars in some cases. It is thus intended to combine a thermal effect (the surface temperature of the strip, around 1100 ° C at the inlet of the descaling, drops almost instantly to near 600 ° C) with a mechanical effect due to the high amount of movement of water jets at impact to crack the scale and eliminate the surface by the effect of hunting.
- a thermal effect the surface temperature of the strip, around 1100 ° C at the inlet of the descaling, drops almost instantly to near 600 ° C
- a mechanical effect due to the high amount of movement of water jets at impact to crack the scale and eliminate the surface by the effect of hunting.
- This operation is conventionally carried out in a descaling box, about 1 to 2 m long, placed some 5 m upstream of the finishing cages, crossed by the steel strip in rapid rectilinear scrolling and sheltering the upper irrigation booms and lower ones with nozzles inclined counter-current of about ten degrees.
- the object of the invention is to provide an immediately operational response to the question of reducing the costs of the secondary descaling operation, that is to say a response compatible with a simple reorganization of existing equipment, so without necessarily involve the relocation of a new complete secondary descaling equipment.
- the subject of the invention is a method for the secondary descaling of metal strips, in particular steel, in scrolling during their hot rolling by spraying water at their surface by means of watering ramps.
- nozzles fed with pressurized water characterized in that the nozzles are fed under low hydraulic pressure, not exceeding 30 bars (and preferably below 10 bars, but not less than about 3 bars), and that, and that the said nozzles are adjusted so that the density of the heat flux extracted from the band (HF) resulting from the cooling of its surface by the projected water is between 6.5 and 20 MW / m 2 for a strip temperature between 900 and 1100 ° C.
- the heat flux density is between 10 and 11 MW / m for a strip temperature between 900 and 1100 ° C.
- said nozzles are dimensioned so that they deliver a surface water flow rate on the strip similar to the surface water flow delivered by said high pressure method.
- the surface water flow rate is greater than 2500 l / min / m 2 and preferably 7500 l / min / m 2 .
- the invention is based on the discovery that it is even more the thermal effect of the jets of water on the cooling of the oxide crust that acts in favor of the secondary descaling that their mechanical effect on the fragmentation of this crust of oxides on the surface of the band, or, in other words, the effect of "high-pressure cleaning" of the powerful jets on their impact, as previously thought.
- thermo effect of cooling and “thermal efficiency” are equivalent. They express the fact that, during the brief residence time of the strip in the descaling box (of the order of one second only), it is a question of ensuring a fall of the temperature of the oxide layer up to about 600 ° C, whatever its temperature at the entrance of this box. It is known that the underlying physical quantity, and ordinarily measurable on a rolling train, is the extracted caloric flux density.
- the reference curve is curve A.
- This curve A results from a conventional secondary descaling carried out using powerful water jets from nozzles fed at 130 bar pressure.
- the other two curves B and C are representative of "low pressure" jets of 8 bars each, one (curve B) resulting from tests carried out with a flow rate of water equal to that of the curve A to jets "high pressure", namely 7,500 l / min / m 2 , the other, curve C, resulting from tests conducted with a significantly lower surface flow rate: 1500 l / min / m 2 .
- the criterion for setting a successful "low pressure” secondary descaling according to the invention lies in the maintenance in the oxide layer of a thermal effect similar to that conventionally achieved with jets "high pressure” (curve A). This must ultimately result in a drop in the temperature of the blank from 20 to 100 ° C (depending on the grade of steel to be rolled) between its entry into the watering box (typically 1100 ° C approximately for a carbon steel for example) and its entry into the finishing cages of the mill (typically about 1030 ° C).
- This thermal effect which is thus expressed by a high rate of momentary cooling of the surface of the strip (several hundred degrees / sec) has been expressed, for the parameterization of the three curves of the graph, by a classically accessible physical quantity. from the measurement, namely the density of heat flux extracted from the product being rolled by the projected water (Heat Flux in English abbreviated, or HF), magnitude expressed in MW / m 2 .
- this characteristic quantity is particularly suitable for dimensioning a plant.
- the descaling because it is correlated to the cooling water flow rate per m 2 of strip (the surface water flow), which is a parameter that can easily be obtained from the definition of the operation of the descaling: schematically, at a value of HF corresponds a surface flow rate of cooling water.
- the HF of the "High Pressure" descaling of reference (curve A) was kept constant around 10 MW / m 2 all along the watering operation (surface temperature ranging from 1100 to 600 ° C).
- Those of the "low pressure" descaling according to the invention were maintained respectively over the same temperature range between 10 and 18 MW / m 2 in the experimental case representative of curve B and between 6 and 10 MW / m 2 for the case. of curve C.
- the HF value is actually calculated from data specific to each descaling equipment that are, to mention only the most important, the temperature of the cooling water (here at 20 ° C for all tests) , the type of projection nozzles, the water outlet pressure of these nozzles, the distance separating the nozzle nose of the surface of the band to be descaled, as well as the opening angle of the jet at the outlet of the nozzle.
- the low-pressure curve C which displays a significantly lower HF (slightly less than 7 MW / m 2 ), reflects a correlatively lower quality of descaling.
- the descaling according to the invention can be carried out for a heat flux density extracted from the product of between 6.5 and 20 MW / m 2 and, when referring to the flow rate of surface water, for a flow rate higher than 2500 l / min / m2.
- the flux densities expressed above are measured under the ramp in the impact zone of the descaling jets.
- the choice of the level of the low pressure to maintain is indeed of second order importance with respect to maintaining the HF, this, of course, as long as we do not go down too low in pressure, say around 3 -5 bars minimum. Otherwise the required surface water flows, therefore the required HF levels (of the order of 10 MW / m 2 ) could no longer be achieved, except to multiply the watering ramps, but with the risk nevertheless of not being to be able to ensure the thermal contraction effect of the oxide crust necessary for its unhooking of the metal support surface.
- the invention can easily be implemented by operating with pumps supplied at low pressure, thereby saving energy and reducing maintenance costs, provided that the conformation of the nozzles is adapted as necessary. to ensure a flow of surface water equivalent to that which would have been practiced in high pressure configuration.
- the nozzles used for the implementation of the method of the invention will be arranged at the same distance from the strip as the distance applied during the known descaling process at high pressure.
- the invention can not be limited to the examples described above, but applies to multiple variants and equivalents.
- it is recalled that it relates to any form of secondary descaling, that is to say removal of calamine previously formed by hot oxidation of a metal surface in contact with the ambient air.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Metal Rolling (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Cleaning By Liquid Or Steam (AREA)
Description
La présente invention a trait à l'opération de décalaminage d'une bande métallique, en acier notamment, en défilement en cours de laminage à chaud avant son entrée dans les cages dégrossisseuses ou finisseuses du train de laminageThe present invention relates to the descaling operation of a metal strip, in particular steel, scrolling during hot rolling before entering the milling or finishing cages of the rolling mill
On rappelle que cette opération est plus couramment appelée "décalaminage secondaire", par opposition au décalaminage "primaire" qui lui intervient sur les brames d'acier à leur sortie du four de réchauffage avant laminage.It is recalled that this operation is more commonly called "secondary descaling", as opposed to the "primary" descaling which intervenes on the steel slabs at the exit of the reheating furnace before rolling.
On rappelle également que le décalaminage secondaire des bandes d'acier vise à débarrasser la surface de la bande de la calamine, dite secondaire, qui s'est formée par réoxydation rapide du métal chaud au cours du séjour de la bande à l'air libre après son décalaminage primaire à sa sortie du four. Il intervient donc doublement au cours du laminage, d'abord avant l'entrée de la bande dans le dégrossisseur, puis avant son entrée dans le finisseur du train de laminage. Par souci de simplicité, on se référera dans ce qui suit uniquement au cas du décalaminage secondaire à l'entrée du finisseur, étant entendu que ce qui est dit à ce propos s'applique pour l'essentiel également au décalaminage secondaire à l'entrée du dégrossisseur.It is also recalled that the secondary descaling of the steel strips is intended to rid the surface of the band of the so-called secondary scale, which is formed by rapid reoxidation of the hot metal during the stay of the strip in the open air after its primary descaling on leaving the oven. It thus intervenes doubly during the rolling, first before the entry of the strip in the roughing, and before entering the finisher rolling mill. For the sake of simplicity, reference will be made hereinafter only to the case of secondary descaling at the finisher inlet, it being understood that what is said in this connection applies essentially also to secondary descaling at the entrance. of roughing.
La calamine secondaire se présente en général sous la forme d'une couche adhérente d'oxydes métalliques, classiquement entre 50 et 100 µm d'épaisseur, plutôt irrégulière d'aspect. Le décalaminage secondaire est réussi quand il fournit à l'entrée du finisseur une bande d'acier comportant en surface une couche uniforme de calamine résiduelle de 20 à 30 µm d'épaisseur à peine, guère au delà pour éviter des incrustations d'oxydes sur les cylindres de laminage.The secondary scale is generally in the form of an adherent layer of metal oxides, typically between 50 and 100 microns thick, rather irregular in appearance. The secondary descaling is successful when it provides at the entrance of the finisher a steel strip having on the surface a uniform layer of residual scale of 20 to 30 microns thick just beyond, to avoid encrustations of oxides on rolling rolls.
Pour ce faire, l'opération de décalaminage consiste schématiquement à impacter la surface de la bande en défilement par des jets d'eau puissants délivrés par des rampes d'arrosage placées à faible distance et dotées de buses d'injection alimentées sous haute pression, classiquement au dessus de 130-150 bars, voire à plus de 200 bars dans certains cas. On vise ainsi à conjuguer un effet thermique (la température de surface de la bande, autour de 1 100 °C à l'entrée du décalaminage, chute quasi instantanément à près de 600 °C) avec un effet mécanique dû à la forte quantité de mouvement des jets d'eau à l'impact afin de fissurer la calamine et de l'éliminer de la surface par effet de chasse. Cette opération a classiquement lieu dans une boîte de décalaminage, longue de 1 à 2 m environ, placée à quelques 5 m en amont des cages finisseuses, traversée par la bande d'acier en défilement rectiligne rapide et abritant les rampes d'arrosage supérieures et inférieures dotées de buses inclinées à contre-courant d'une dizaine de degrés.To do this, the descaling operation consists schematically in impacting the surface of the moving strip by powerful water jets delivered by spray bars placed at a short distance and provided with injection nozzles fed under high pressure, typically above 130-150 bars, or even more than 200 bars in some cases. It is thus intended to combine a thermal effect (the surface temperature of the strip, around 1100 ° C at the inlet of the descaling, drops almost instantly to near 600 ° C) with a mechanical effect due to the high amount of movement of water jets at impact to crack the scale and eliminate the surface by the effect of hunting. This operation is conventionally carried out in a descaling box, about 1 to 2 m long, placed some 5 m upstream of the finishing cages, crossed by the steel strip in rapid rectilinear scrolling and sheltering the upper irrigation booms and lower ones with nozzles inclined counter-current of about ten degrees.
Quoique maillon indispensable à toute chaine d'élaboration de l'acier incorporant une phase chaude (sauf à vouloir placer le train de laminage dans son entier sous atmosphère non oxydante-ce qui n'est évidemment guère envisageable), le décalaminage secondaire reste une opération onéreuse, moins d'ailleurs par les importantes quantités d'eau qu'elle implique (l'eau utilisée est recyclée) qu'en raison des équipements à haute pression hydraulique qui la serve, et à l'égard de laquelle il convient de s'interroger sur les possibilités d'en réduire le coût, particulièrement en termes de maintenance des pompes et des circuits, et de consommation électrique:Although essential link to any chain of development of steel incorporating a hot phase (except to want to place the rolling mill in its non-oxidizing atmosphere - which is obviously not feasible), secondary descaling remains an expensive operation, less by the large amounts of water it involves (the water used is recycled) that because of the hydraulic high-pressure equipment that serves it, and for which it is necessary to question the possibilities of reducing the cost, particularly in terms of maintenance of pumps and circuits, and of electricity consumption:
Le but de l'invention est d'apporter une réponse immédiatement opérationnelle à la question de la réduction des coûts de l'opération de décalaminage secondaire, c'est-à-dire une réponse compatible avec un simple réaménagement des équipements existants, donc sans impliquer nécessairement la réinstallation d'un nouveau matériel complet de décalaminage secondaire.The object of the invention is to provide an immediately operational response to the question of reducing the costs of the secondary descaling operation, that is to say a response compatible with a simple reorganization of existing equipment, so without necessarily involve the relocation of a new complete secondary descaling equipment.
A cet effet, l'invention a pour objet un procédé de décalaminage secondaire des bandes métalliques, en acier notamment, en défilement au cours de leur laminage à chaud par projection d'eau à leur surface à l'aide de rampes d'arrosage à buses alimentées en eau sous pression, caractérisé en ce que l'on alimente les buses sous basse pression hydraulique, ne dépassant pas 30 bars (et de préférence en dessous de 10 bars, mais sans aller à moins de 3 bars environ), et en ce que, et en ce que l'on règle lesdites buses afin que la densité du flux de chaleur extraite de la bande (HF) résultant du refroidissement de sa surface par l'eau projetée soit comprise entre 6,5 et 20 MW/m2 pour une température de bande comprise entre 900 et 1100°C.To this end, the subject of the invention is a method for the secondary descaling of metal strips, in particular steel, in scrolling during their hot rolling by spraying water at their surface by means of watering ramps. nozzles fed with pressurized water, characterized in that the nozzles are fed under low hydraulic pressure, not exceeding 30 bars (and preferably below 10 bars, but not less than about 3 bars), and that, and that the said nozzles are adjusted so that the density of the heat flux extracted from the band (HF) resulting from the cooling of its surface by the projected water is between 6.5 and 20 MW / m 2 for a strip temperature between 900 and 1100 ° C.
Avantageusement, la densité de flux de chaleur est comprise entre 10 et 11 MW/m pour une température de bande comprise entre 900 et 1100°C. De plus, dans le but d'assurer un effet thermique de l'eau projeté sur la surface à décalaminer quantitativement analogue à l'effet thermique obtenu avec la méthode de décalaminage secondaire connue habituelle à haute pression (i.e. un refroidissement de la bande qui abaisse la température de sa surface oxydée à 600°C environ), on dimensionne lesdites buses afin qu'elles délivrent un débit d'eau surfacique sur la bande analogue au débit d'eau surfacique délivré par ladite méthode à haute pression.Advantageously, the heat flux density is between 10 and 11 MW / m for a strip temperature between 900 and 1100 ° C. In addition, in order to ensure a thermal effect of the water sprayed on the surface to be descaled quantitatively analogous to the thermal effect obtained with the usual known high-pressure secondary descaling method (ie a cooling of the strip which lowers the temperature of its oxidized surface at 600 ° C approximately), said nozzles are dimensioned so that they deliver a surface water flow rate on the strip similar to the surface water flow delivered by said high pressure method.
De préférence, le débit d'eau surfacique est supérieur à 2500 l/mn/m2 et avantageusement de 7500 l/mn/m2.Preferably, the surface water flow rate is greater than 2500 l / min / m 2 and preferably 7500 l / min / m 2 .
Le procédé selon l'invention peut également comprendre différentes caractéristiques, prises seules ou en combinaison :
- on alimente les buses avec une pression hydraulique inférieure à 10 bars, sans toutefois descendre en deca de 3 bars,
- le procédé de l'invention est mené en amont des cages finisseuses d'un train de laminage à chaud de bandes d'acier,
- le procédé de l'invention est mené en amont des cages dégrossisseuses d'un train de laminage à chaud de bandes d'acier.
- the nozzles are fed with a hydraulic pressure of less than 10 bar, without however falling below 3 bars,
- the process of the invention is carried out upstream of the finishing stands of a hot rolling mill of steel strips,
- the process of the invention is carried out upstream of the roughing cages of a hot rolling mill of steel strips.
Comme on l'aura sans doute déjà compris, l'invention repose sur la découverte que c'est bien plus l'effet thermique des jets d'eau sur le refroidissement de la croute d'oxydes qui agit en faveur du décalaminage secondaire que leur effet mécanique sur la fragmentation de cette croute d'oxydes à la surface de la bande, ou, dit autrement, que l'effet "nettoyage haute pression" des jets puissants à leur impact, comme on le pensait jusqu'ici.As will have probably already been understood, the invention is based on the discovery that it is even more the thermal effect of the jets of water on the cooling of the oxide crust that acts in favor of the secondary descaling that their mechanical effect on the fragmentation of this crust of oxides on the surface of the band, or, in other words, the effect of "high-pressure cleaning" of the powerful jets on their impact, as previously thought.
Pour caractériser cette similarité d'effet thermique entre le procédé de l'invention et le procédé classique haute pression, on parlera en densité de flux de chaleur extraite de la bande qui intègre à la fois les paramètres de température de bande et de débit d'eau surfacique, étant entendu que ce débit doit être réglé selon la température de la bande à l'entrée du décalaminage.To characterize this similarity of thermal effect between the process of the invention and the conventional high-pressure process, it will be referred to as the heat flux density extracted from the strip which integrates both the temperature and flow rate parameters. surface water, it being understood that this flow rate must be adjusted according to the temperature of the strip at the inlet of the descaling.
Pour caractériser le procédé, il s'agit de la même considération de base à savoir l'utilisation de la basse pression en préservant l'effet thermique engendré par l'utilisation de jets haute pression.To characterize the process, it is the same basic consideration namely the use of low pressure while preserving the thermal effect generated by the use of high pressure jets.
Tant en amont des cages finisseuses qu'en amont des cages dégrossisseuses, la réussite du décalaminage secondaire se trouve être en fait directement et quasiment uniquement liée à l'efficacité thermique du refroidissement de la couche d'oxydes à éliminer, ce indépendamment donc de la pression d'alimentation des buses des rampes d'arrosage. Dit autrement, à efficacité thermique égale, la qualité du décalaminage secondaire obtenu sera la même, que l'on décalamine à jets haute pression ou non.Both upstream of the finishing cages and upstream of the roughing cages, the success of the secondary descaling is in fact directly and almost solely related to the thermal efficiency of the cooling of the oxide layer to be eliminated, independently of the supply pressure of the spray boom nozzles. In other words, with equal thermal efficiency, the quality of the secondary descaling obtained will be the same whether it is depressurized with high pressure jets or not.
On souligne, pour éviter toute confusion, que les expressions utilisées ici d"'effet thermique du refroidissement" et d"'efficacité thermique" sont équivalentes. Elles expriment le fait que, au cours du bref temps de séjour de la bande dans la boîte de décalaminage (de l'ordre de la seconde à peine), il s'agit d'assurer une chute de la température de la couche d'oxydes jusqu'à environ 600°C, ce quelque soit sa température à l'entrée de cette boîte. On sait que la grandeur physique sous-jacente, et ordinairement mesurable sur un train de laminage, est la densité de flux calorique extrait.It is pointed out, to avoid any confusion, that the expressions used here of "thermal effect of cooling" and "thermal efficiency" are equivalent. They express the fact that, during the brief residence time of the strip in the descaling box (of the order of one second only), it is a question of ensuring a fall of the temperature of the oxide layer up to about 600 ° C, whatever its temperature at the entrance of this box. It is known that the underlying physical quantity, and ordinarily measurable on a rolling train, is the extracted caloric flux density.
Dès lors, le remplacement des jets puissants habituels (100 bars et au delà) par des jets "basse pression" (moins de 30 bars) suffit à assurer la contraction thermique de la croute d'oxydes, contraction qui va se traduire par des décollements de cette croute, parachevés par l'énergie des jets qui, quoique modeste, suffit ici amplement à la tâche pour rendre alors aisé l'enlèvement de la calamine par simple action de balayage et d'entrainement à l'eau ruisselant à la surface.Therefore, the replacement of the usual strong jets (100 bars and beyond) by jets "low pressure" (less than 30 bars) is enough to ensure the thermal contraction of the oxide crust, a contraction that will result in detachments of this crust, completed by the energy of the jets which, although modest, suffices here amply to the task to make then easy the removal of calamine by simple action of sweeping and training with the water streaming on the surface.
Ces effets en cascade sont obtenus avec des jets "basse pression", conformément à l'invention, pour peu, comme on l'a déjà dit, qu'on leur fasse assurer le même niveau de refroidissement de la couche d'oxydes sur la bande qu'avec les jets "haute pression", niveau de refroidissement qui sera en fait atteint en conservant tout simplement le débit surfacique d'eau de refroidissement sur la bande.These cascade effects are obtained with "low pressure" jets, in accordance with the invention, as soon as, as we have already said, they are made to ensure the same level of cooling of the oxide layer on the band that with the jets "high pressure", cooling level that will actually be achieved by simply keeping the surface flow rate of cooling water on the band.
Ainsi, le remplacement de l'alimentation en eau habituelle "haute pression" par une alimentation "basse pression", devient une solution immédiatement applicable industriellement pour bénéficier ainsi d'un avantage économique considérable sans concéder sur la qualité de décalaminage.Thus, the replacement of the usual water supply "high pressure" by a "low pressure" supply, becomes a solution immediately applicable industrially to thus enjoy a considerable economic advantage without conceding on the quality of descaling.
L'invention sera bien comprise et d'autres aspects et avantages apparaîtront plus clairement au vu de la description qui suit donnée en référence à la planche unique jointe de figures sur laquelle:
- la
figure 1 est un tracé de courbes, dites d'ébullition, issues de l'expérience et montrant, en fonction de la température de surface de la bande, l'efficacité thermique comparée d'un décalaminage secondaire avant l'entrée au finisseur mené avec des pressions hydrauliques d'eau projeté différentes. Cette efficacité thermique est traduite quantitativement en ordonnée par la densité surfacique de flux thermique extrait (HF), donnée en MW/m2 de surface de bande métallique; - la
figure 2 montre l'efficacité de ce décalaminage secondaire, en termes d'épaisseur résiduelle de la couche de calamine en micromètres (ec) dans une plage de températures de surface de la bande d'acier décalaminée (900-1050 °C) délibérément choisie conforme aux températures d'entrée dans les cages finisseuses.
- the
figure 1 is a plot of curves, called boiling curves, resulting from the experiment and showing, as a function of the surface temperature of the strip, the comparative thermal efficiency of a secondary descaling before the entry to the paver driven with pressures different projected water hydraulics. This thermal efficiency is quantitatively translated in ordinate by the surface density of extracted heat flux (HF), given in MW / m2 of metal strip surface; - the
figure 2 shows the effectiveness of this secondary descaling, in terms of the residual thickness of the calamine layer in micrometers (e c ) in a surface temperature range of the descaled steel strip (900-1050 ° C) deliberately chosen to comply at the inlet temperatures in the finishing cages.
Sur la
Il importe de rappeler à nouveau ici que le critère de réglage d'un décalaminage secondaire "basse pression" réussi, conformément à l'invention, réside dans le maintien dans la couche d'oxyde d'un effet thermique analogue à celui réalisé classiquement avec des jets "haute pression" (courbe A). Celui-ci doit se traduire au final par une baisse de la température de l'ébauche de 20 à 100 °C (selon la nuance d'acier à laminer) entre son entrée dans la boîte d'arrosage (classiquement 1100 °C environ pour un acier au carbone par exemple) et son entrée dans les cages finisseuses du laminoir (classiquement 1030 °C environ).It is important to recall here again that the criterion for setting a successful "low pressure" secondary descaling according to the invention lies in the maintenance in the oxide layer of a thermal effect similar to that conventionally achieved with jets "high pressure" (curve A). This must ultimately result in a drop in the temperature of the blank from 20 to 100 ° C (depending on the grade of steel to be rolled) between its entry into the watering box (typically 1100 ° C approximately for a carbon steel for example) and its entry into the finishing cages of the mill (typically about 1030 ° C).
Pour y parvenir, compte tenu du faible temps de séjour de la bande sous les rampes d'arrosage (de l'ordre de la seconde), il convient donc d'assurer sous ces rampes un refroidissement qui fasse brutalement chuter la surface de la bande jusqu'à 600 °C environ, afin, d'une part, que la vitesse de refroidissement de la croute d'oxydes soit suffisamment élevée pour que la contraction thermique différentielle oxydes-métal qui en résulte parvienne à décoller cette croute en la fragmentant le plus possible et, d'autre part, que l'inévitable apport calorifique ultérieur du coeur de la bande vers la surface fasse atteindre à cette dernière la température souhaitée à l'entrée des cages finisseuses.To achieve this, given the low residence time of the band under the irrigation ramps (of the order of one second), it is therefore necessary to ensure under these ramps a cooling which causes the surface of the band to fall sharply. up to about 600 ° C, so that, on the one hand, the cooling rate of the oxide crust is high enough that the differential thermal contraction oxides-metal resulting from it succeeds in detaching this crust by fragmenting it. moreover possible, and on the other hand, that the inevitable subsequent heat input of the core of the strip towards the surface makes the latter reach the desired temperature at the entrance of the finishing cages.
Cet effet thermique, qui s'exprime donc par une vitesse élevée de refroidissement momentané de la surface de la bande (de plusieurs centaines de degrés/sec) a été exprimé, pour le paramétrage des trois courbes du graphe, par une grandeur physique classiquement accessible à partir de la mesure, à savoir la densité de flux de chaleur extrait du produit en cours de laminage par l'eau projetée (Heat Flux en anglais abrégé, ou HF), grandeur exprimée en MW/m2. Or, cette grandeur caractéristique est particulièrement seyante pour dimensionner une installation de. décalaminage, car elle est corrélée au débit d'eau de refroidissement par m2 de bande (le débit d'eau surfacique) qui, lui, est un paramètre qui peut être obtenu facilement à partir de la définition du fonctionnement du décalaminage: schématiquement, à une valeur de HF correspond un débit surfacique d'eau de refroidissement.This thermal effect, which is thus expressed by a high rate of momentary cooling of the surface of the strip (several hundred degrees / sec) has been expressed, for the parameterization of the three curves of the graph, by a classically accessible physical quantity. from the measurement, namely the density of heat flux extracted from the product being rolled by the projected water (Heat Flux in English abbreviated, or HF), magnitude expressed in MW / m 2 . However, this characteristic quantity is particularly suitable for dimensioning a plant. descaling because it is correlated to the cooling water flow rate per m 2 of strip (the surface water flow), which is a parameter that can easily be obtained from the definition of the operation of the descaling: schematically, at a value of HF corresponds a surface flow rate of cooling water.
Ainsi, comme on le voit, le HF du décalaminage "Haute Pression" de référence (courbe A) a été maintenu constant autour de 10 MW/m2 tout du long de l'opération d'arrosage (température de surface allant de 1100 à 600 °C). Ceux des décalaminages "Basse Pression" selon l'invention ont été maintenus respectivement sur la même plage de températures entre 10 et 18 MW/ m2 dans le cas expérimental représentatif de la courbe B et entre 6 et 10 MW/ m2 pour le cas de la courbe C.Thus, as can be seen, the HF of the "High Pressure" descaling of reference (curve A) was kept constant around 10 MW / m 2 all along the watering operation (surface temperature ranging from 1100 to 600 ° C). Those of the "low pressure" descaling according to the invention were maintained respectively over the same temperature range between 10 and 18 MW / m 2 in the experimental case representative of curve B and between 6 and 10 MW / m 2 for the case. of curve C.
On notera que la valeur HF se calcule en fait à partir de données propres à chaque équipement de décalaminage que sont, pour ne citer que les plus importantes, la température de l'eau de refroidissement (ici à 20°C pour tous les essais), le type de buses de projection, la pression de sortie de l'eau de ces buses, la distance séparant le nez de buse de la surface de la bande à décalaminer, ainsi que l'angle d'ouverture du jet à la sortie de la buse.Note that the HF value is actually calculated from data specific to each descaling equipment that are, to mention only the most important, the temperature of the cooling water (here at 20 ° C for all tests) , the type of projection nozzles, the water outlet pressure of these nozzles, the distance separating the nozzle nose of the surface of the band to be descaled, as well as the opening angle of the jet at the outlet of the nozzle.
On observera que l'allure générale est la même pour la courbe B et la courbe C: une montée commune jusqu'à une température de surface de bande de 450°C environ, suivie d'une bosse ayant son maximum entre 550 et 600°C pour les deux, mais avec intensités différenciées cette fois. Ensuite, la décroissance s'opère quasiment en parallèle entre les deux courbes jusqu'à 1100°C, qui est la température commune d'entrée des bandes d'essais dans les boites de décalaminageIt will be observed that the general appearance is the same for the curve B and the curve C: a common rise up to a strip surface temperature of about 450 ° C, followed by a bump having a maximum between 550 and 600 ° C for both, but with differentiated intensities this time. Then, the decay takes place almost in parallel between the two curves up to 1100 ° C, which is the common input temperature of the test strips in the descaling boxes.
On remarquera que c'est précisément à ce niveau là de la plage en températures (1100 à 900 °C pour être large) que l'intérêt industriel du procédé selon l'invention doit être surtout apprécié puisque la quasi-totalité des trains de laminage à chaud de bandes d'acier fonctionnent avec des températures de bande à l'entrée des cages finisseuses situées entre 900 et 1100 °C.It will be noted that it is precisely at this level of the temperature range (1100 to 900 ° C to be wide) that the industrial interest of the process according to the invention must be especially appreciated since almost all the rolling trains hot-rolled steel belts work with belt temperatures at the entrance of finishing cages between 900 and 1100 ° C.
Or, c'est précisément dans cette plage en températures que l'on observe une qualité de décalaminage quasiment équivalente entre la courbe de référence à haute pression A et la courbe basse pression B, équivalence à corréler bien entendu à celle des valeurs de HF sur le graphe (entre 10 et 11 MW/m2). Par contre, par rapport à elles, la courbe basse pression C, qui affiche un HF sensiblement inférieur (un peu moins de 7 MW/m2), traduit une qualité de décalaminage corrélativement moins bonne.However, it is precisely in this temperature range that we observe an almost equivalent quality of descaling between the reference curve at high pressure A and the low pressure curve B, equivalent to correlate of course with that of the values of HF on the graph (between 10 and 11 MW / m 2 ). On the other hand, with respect to them, the low-pressure curve C, which displays a significantly lower HF (slightly less than 7 MW / m 2 ), reflects a correlatively lower quality of descaling.
Comme le montre en effet les essais menés sur un pilote industriel et consignés sur
Il est précisé que ces essais ont été menés sur une bande d'acier bas carbone de type ISF avec une distance "buse-bande d'acier" de 160 mm identique dans chaque cas, de même pour ce qui concerne le débit d'eau projeté par buse, à savoir 110 l/min, de même encore pour ce qui concerne la vitesse de défilement de la bande d'acier à 60 m/min et la température de l'eau projetée (20°C). L'efficacité du décalaminage a été évaluée (en ordonnées) à partir de la mesure de l'épaisseur de calamine résiduelle à la surface de la bande par observation de coupes micrographiques du produit décalaminé.It is specified that these tests were conducted on a strip of low carbon steel type ISF with a distance "nozzle-steel strip" of 160 mm identical in each case, the same with respect to the flow of water jet-sprayed, namely 110 l / min, also with regard to the speed of travel of the steel strip at 60 m / min and the temperature of the projected water (20 ° C). The efficiency of the descaling was evaluated (on the ordinate) from the measurement of the residual calamine thickness at the surface of the strip by observation of micrographic sections of the descaled product.
De façon plus générale, il a été évaluée que le décalaminage selon l'invention peut être mené pour une densité de flux de chaleur extraite du produit comprise entre 6,5 et 20 MW/m2 et, lorsque l'on se réfère au débit d'eau surfacique, pour un débit supérieur à 2500 l/mn/m2.More generally, it has been evaluated that the descaling according to the invention can be carried out for a heat flux density extracted from the product of between 6.5 and 20 MW /
Les densités de flux exprimées plus haut sont mesurées sous la rampe dans la zone d'impact des jets du décalaminage.The flux densities expressed above are measured under the ramp in the impact zone of the descaling jets.
On retrouve là, chiffres à l'appui, ce qui a été déjà souligné auparavant, à savoir l'importance de travailler avec une efficacité thermique (HF) conservée par rapport à ce qui se pratique traditionnellement, lorsque l'on passe d'un décalaminage "haute pression" à un décalaminage "basse pression" conformément à l'invention.Here we find, in figures, what was already stressed before, namely the importance of working with a thermal efficiency (HF) preserved compared to what is traditionally practiced, when we go from a "high pressure" descaling at a "low pressure" descaling according to the invention.
Le choix du niveau de la basse pression à maintenir s'avère en effet d'importance du second ordre par rapport au maintien du HF, ceci, bien entendu, tant que l'on ne descend pas trop bas en pression, disons autour de 3-5 bars minimum. Sinon les débits d'eau surfaciques requis, donc les niveaux de HF requis (de l'ordre de 10 MW/m2) ne pourraient plus être atteints, sauf à multiplier les rampes d'arrosage, mais avec le risque néanmoins de ne plus pouvoir assurer l'effet de contraction thermique de la croute d'oxydes nécessaire à son décrochage de la surface métallique support.The choice of the level of the low pressure to maintain is indeed of second order importance with respect to maintaining the HF, this, of course, as long as we do not go down too low in pressure, say around 3 -5 bars minimum. Otherwise the required surface water flows, therefore the required HF levels (of the order of 10 MW / m 2 ) could no longer be achieved, except to multiply the watering ramps, but with the risk nevertheless of not being to be able to ensure the thermal contraction effect of the oxide crust necessary for its unhooking of the metal support surface.
Inversement, l'intérêt économique de travailler industriellement avec une "basse pression" qui se situerait à plus de 30 bars s'estompe brutalement à ce niveau de pression puisque les équipements nécessaires y sont ceux, ou proches de ceux, que l'on utilise déjà aujourd'hui pour les "hautes pressions".Conversely, the economic interest of working industrially with a "low pressure" that would be more than 30 bar suddenly fades to this level of pressure since the necessary equipment are those, or close to those, that are used already today for "high pressures".
On aura compris que l'invention pourra être aisément mise en oeuvre en fonctionnant avec des pompes alimentées à basse pression, économisant ainsi de l'énergie et réduisant les coûts de maintenance, pour peu que l'on adaptera au besoin la conformation des buses afin d'assurer un débit d'eau surfacique équivalent à celui qui aurait été pratiqué en configuration haute pression.It will be understood that the invention can easily be implemented by operating with pumps supplied at low pressure, thereby saving energy and reducing maintenance costs, provided that the conformation of the nozzles is adapted as necessary. to ensure a flow of surface water equivalent to that which would have been practiced in high pressure configuration.
Les buses utilisées pour la mise en oeuvre du procédé de l'invention seront disposées à la même distance de la bande que la distance appliquée lors du procédé de décalaminage connu à haute pression.The nozzles used for the implementation of the method of the invention will be arranged at the same distance from the strip as the distance applied during the known descaling process at high pressure.
On notera d'autres avantages supplémentaires liés à l'utilisation de rampes basse pression à la place de la haute pression pour réaliser le décalaminage secondaire, comme:
- la possibilité de fractionner les rampes basse pression à faible cout. Le fractionnement des rampes permettra d'arroser au plus juste, à savoir la bande à décalaminer uniquement et non pas toute la largeur du train de laminage, ce qui induit des économies d'eau, une réduction de la masse d'eau qui circule en boucle et donc une réduction corrélative du coût énergétique supplémentaire;
- la possibilité d'utiliser les rampes "basse pression" comme un actionneur de réglage de la thermique de la bande à son entrée dans le finisseur;
- l'usure moindre des buses de projection d'eau;
- la réduction globale des coûts de maintenance de l'installation (pompes, vannes, circuits...).
- the possibility of splitting the low pressure ramps at low cost. The splitting of the ramps will make it possible to water as accurately as possible, namely the strip to be de-scaled only and not the entire width of the rolling mill, which induces water savings, a reduction in the mass of water flowing through. loop and therefore a correlative reduction of the additional energy cost;
- the possibility of using the "low pressure" ramps as an actuator for adjusting the thermal of the strip as it enters the finisher;
- less wear of the water spray nozzles;
- the overall reduction of maintenance costs of the installation (pumps, valves, circuits ...).
Il va de soi que l'invention ne saurait se limiter aux exemples décrits ci-avant, mais s'applique à de multiples variantes et équivalents. En particulier, on rappelle qu'elle concerne toute forme de décalaminage secondaire, c'est à dire d'enlèvement de calamine préalablement formée par oxydation à chaud d'une surface métallique au contact de l'air ambiant.It goes without saying that the invention can not be limited to the examples described above, but applies to multiple variants and equivalents. In particular, it is recalled that it relates to any form of secondary descaling, that is to say removal of calamine previously formed by hot oxidation of a metal surface in contact with the ambient air.
Claims (7)
- A method for secondary descaling running steel strips during their hot rolling, by projecting water at their surface by means of spraying ramps with nozzles supplied with pressurized water, characterized in that it consists of supplying said nozzles under low hydraulic pressure, not exceeding 30 bars and in that said nozzles are adjusted so that the heat flow density extracted from the strip (HF) resulting from the cooling of its surface by the projected water is comprised between 6.5 and 20 MW/m2 for a strip temperature comprised between 900 and 1,100°C.
- The method according to claim 1, characterized in that the heat flow density is comprised between 10 and 11 MW/m2 for a strip temperature comprised between 900 and 1,100°C.
- The method according to claim 1 or 2, characterized in that said nozzles are adjusted so that they deliver a surface water flow rate of more than 2,500L/min/m2.
- The method according to claim 3, characterized in that the surface water flow rate is 7,500L/min/m2.
- The method according to any of claims 1 to 3, characterized in that the nozzles are supplied with a hydraulic pressure of less than 10 bars, without however going below 3 bars.
- The method according to any of the preceding claims, characterized in that it is conducted upstream from finishing stands of a hot roll train for steel strips.
- The method according to any of the preceding claims, characterized in that it is conducted upstream from roughing stands of a hot roll train for steel strips.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL08843858T PL2185747T3 (en) | 2007-08-21 | 2008-08-20 | Method and device for secondary descaling steel strip with low pressure water jets |
EP08843858.5A EP2185747B1 (en) | 2007-08-21 | 2008-08-20 | Method and device for secondary descaling steel strip with low pressure water jets |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07291027A EP2028290A1 (en) | 2007-08-21 | 2007-08-21 | Method and device for secondary descaling steel strip with low pressure water jets |
PCT/FR2008/001200 WO2009056712A2 (en) | 2007-08-21 | 2008-08-20 | Method and equipment for secondary descaling of metallic strips by hydraulic low-pressure spraying of water |
EP08843858.5A EP2185747B1 (en) | 2007-08-21 | 2008-08-20 | Method and device for secondary descaling steel strip with low pressure water jets |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2185747A2 EP2185747A2 (en) | 2010-05-19 |
EP2185747B1 true EP2185747B1 (en) | 2016-12-21 |
Family
ID=39002981
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07291027A Withdrawn EP2028290A1 (en) | 2007-08-21 | 2007-08-21 | Method and device for secondary descaling steel strip with low pressure water jets |
EP08843858.5A Active EP2185747B1 (en) | 2007-08-21 | 2008-08-20 | Method and device for secondary descaling steel strip with low pressure water jets |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07291027A Withdrawn EP2028290A1 (en) | 2007-08-21 | 2007-08-21 | Method and device for secondary descaling steel strip with low pressure water jets |
Country Status (13)
Country | Link |
---|---|
US (1) | US10378115B2 (en) |
EP (2) | EP2028290A1 (en) |
JP (1) | JP5150888B2 (en) |
KR (1) | KR101240100B1 (en) |
CN (1) | CN101821429B (en) |
AU (1) | AU2008320723B2 (en) |
BR (1) | BRPI0815716B1 (en) |
ES (1) | ES2618498T3 (en) |
MX (1) | MX2010001998A (en) |
PL (1) | PL2185747T3 (en) |
RU (1) | RU2441725C2 (en) |
UA (1) | UA97853C2 (en) |
WO (1) | WO2009056712A2 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5136609B2 (en) | 2010-07-29 | 2013-02-06 | Jfeスチール株式会社 | High-strength hot-dip galvanized steel sheet excellent in formability and impact resistance and method for producing the same |
DE102012214298A1 (en) | 2012-08-10 | 2014-02-13 | Sms Siemag Ag | Process for the purification and / or descaling of a slab or slag by means of a scale scrubber and scale scrubber |
FR3024058B1 (en) * | 2014-07-23 | 2016-07-15 | Constellium France | METHOD AND EQUIPMENT FOR COOLING |
CN112139335B (en) * | 2020-09-09 | 2022-02-01 | 山东钢铁集团日照有限公司 | Preparation method of high-corrosion-resistance easy-to-weld hot-pressed part |
CN113751410B (en) | 2021-09-14 | 2022-07-22 | 山东钢铁集团日照有限公司 | Hot bath forming process for high-corrosion-resistance and easy-welding hot-pressed parts |
Family Cites Families (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3054162A (en) * | 1957-02-16 | 1962-09-18 | August Seuthe Maschf | Method and apparatus for descaling strip material, especially strip iron |
US3174491A (en) * | 1963-10-23 | 1965-03-23 | Kolene Corp | Molten salt spray apparatus for descaling stainless steel |
NL131553C (en) * | 1965-05-28 | 1900-01-01 | ||
US3779054A (en) | 1972-03-02 | 1973-12-18 | Wean United Inc | Coolant control for hot strip mill |
JPS5831247B2 (en) | 1980-12-17 | 1983-07-05 | 株式会社神戸製鋼所 | Descaling equipment for hot rolled steel plates |
US4507949A (en) * | 1982-02-12 | 1985-04-02 | Republic Steel Corporation | Apparatus for cooling a hot-rolled product |
JPS5976615A (en) * | 1982-10-25 | 1984-05-01 | Nippon Steel Corp | Method and device for descaling steel material in low pressure |
JPS6061114A (en) | 1983-09-13 | 1985-04-08 | Sumitomo Metal Ind Ltd | Rolling method of free-cutting steel |
JPS60184409A (en) * | 1984-03-02 | 1985-09-19 | Sumitomo Metal Ind Ltd | Rolling method of seamless steel pipe |
US4617815A (en) | 1984-12-24 | 1986-10-21 | Wean United, Inc. | Apparatus for descaling hot strip in a rolling mill |
JPS61269925A (en) * | 1985-05-24 | 1986-11-29 | Kawasaki Steel Corp | Descaling method in hot rolling |
JP2585529B2 (en) | 1986-04-14 | 1997-02-26 | 株式会社日立製作所 | Method and apparatus for reducing the thickness of hot slabs |
JPH0763751B2 (en) * | 1987-01-24 | 1995-07-12 | 株式会社日立製作所 | Hot rolling line |
JPH07115060B2 (en) * | 1992-01-07 | 1995-12-13 | 新日本製鐵株式会社 | Descaling method for steel |
ES2108170T3 (en) * | 1992-07-31 | 1997-12-16 | Danieli Off Mecc | DECHARGING DEVICE USING WATER. |
US5272798A (en) * | 1992-08-05 | 1993-12-28 | Kolene Corporation | Method and apparatus for descaling metal strip |
JPH07171610A (en) | 1993-10-26 | 1995-07-11 | Sumitomo Metal Ind Ltd | Method and device for rolling hot rolled steel sheet |
JP2897652B2 (en) | 1994-09-05 | 1999-05-31 | 住友金属工業株式会社 | Mandrel mill and tube rolling method using the same |
AUPM826394A0 (en) * | 1994-09-20 | 1994-10-13 | Bhp Steel (Jla) Pty Limited | Descaling metal strip |
JP3390584B2 (en) | 1995-08-31 | 2003-03-24 | 川崎製鉄株式会社 | Hot rolled steel sheet and method for producing the same |
DE69625997T2 (en) * | 1995-10-11 | 2004-01-22 | Nisshin Steel Co., Ltd. | METHOD FOR DESCALING STEEL COILS BY ROLLING WITH HIGH ROLLING PRESSURE |
JP3094911B2 (en) * | 1996-04-11 | 2000-10-03 | 住友金属工業株式会社 | Descaling method of hot rolled steel sheet |
JPH10128425A (en) * | 1996-10-31 | 1998-05-19 | Nippon Steel Corp | Descaling method |
JPH1147820A (en) * | 1997-08-04 | 1999-02-23 | Nireco Corp | Slab cut surface descaling device and descaling/marking device using the same |
JP4057786B2 (en) | 1999-01-26 | 2008-03-05 | 新日本製鐵株式会社 | Steel material scale removal and control method and apparatus |
JP2000246325A (en) | 1999-02-24 | 2000-09-12 | Mitsubishi Heavy Ind Ltd | Device and method for preventing scale flaw at hot rolling |
DE19938705A1 (en) * | 1999-08-14 | 2001-02-15 | Sms Demag Ag | Descaling device for a continuously cast metal strip |
JP3491605B2 (en) * | 2000-07-14 | 2004-01-26 | 住友金属工業株式会社 | Manufacturing method and equipment for hot rolled steel sheet with excellent surface properties |
DE10110324A1 (en) * | 2001-03-03 | 2002-09-05 | Sms Demag Ag | Process for descaling tapes |
DE10143868A1 (en) * | 2001-09-07 | 2003-03-27 | Sms Demag Ag | Device for removing loose cinder from the surface of a thin slab of a mini mill has a spray unit arranged before a temperature compensation oven and connected to a water supply |
DE10146113A1 (en) * | 2001-09-19 | 2003-04-03 | Sms Demag Ag | Spray bar for a hydraulic descaling system |
-
2007
- 2007-08-21 EP EP07291027A patent/EP2028290A1/en not_active Withdrawn
-
2008
- 2008-08-20 US US12/674,165 patent/US10378115B2/en active Active
- 2008-08-20 BR BRPI0815716-2A patent/BRPI0815716B1/en active IP Right Grant
- 2008-08-20 PL PL08843858T patent/PL2185747T3/en unknown
- 2008-08-20 CN CN2008801096273A patent/CN101821429B/en active Active
- 2008-08-20 WO PCT/FR2008/001200 patent/WO2009056712A2/en active Application Filing
- 2008-08-20 RU RU2010110616/02A patent/RU2441725C2/en active
- 2008-08-20 ES ES08843858.5T patent/ES2618498T3/en active Active
- 2008-08-20 EP EP08843858.5A patent/EP2185747B1/en active Active
- 2008-08-20 UA UAA201003056A patent/UA97853C2/en unknown
- 2008-08-20 KR KR1020107006056A patent/KR101240100B1/en active IP Right Grant
- 2008-08-20 MX MX2010001998A patent/MX2010001998A/en active IP Right Grant
- 2008-08-20 JP JP2010525383A patent/JP5150888B2/en active Active
- 2008-08-20 AU AU2008320723A patent/AU2008320723B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
KR20100058573A (en) | 2010-06-03 |
EP2185747A2 (en) | 2010-05-19 |
ES2618498T3 (en) | 2017-06-21 |
UA97853C2 (en) | 2012-03-26 |
MX2010001998A (en) | 2010-05-27 |
CN101821429A (en) | 2010-09-01 |
US20110146706A1 (en) | 2011-06-23 |
CN101821429B (en) | 2012-05-30 |
AU2008320723B2 (en) | 2012-03-29 |
WO2009056712A3 (en) | 2009-07-16 |
KR101240100B1 (en) | 2013-03-07 |
JP5150888B2 (en) | 2013-02-27 |
WO2009056712A8 (en) | 2010-03-18 |
PL2185747T3 (en) | 2017-06-30 |
BRPI0815716B1 (en) | 2021-03-30 |
EP2028290A1 (en) | 2009-02-25 |
RU2441725C2 (en) | 2012-02-10 |
US10378115B2 (en) | 2019-08-13 |
BRPI0815716A2 (en) | 2015-02-10 |
WO2009056712A2 (en) | 2009-05-07 |
RU2010110616A (en) | 2011-09-27 |
JP2010536581A (en) | 2010-12-02 |
AU2008320723A1 (en) | 2009-05-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2185747B1 (en) | Method and device for secondary descaling steel strip with low pressure water jets | |
CA2954830C (en) | Hot-rolled steel sheet and associated production process | |
FR2498092A1 (en) | INSTALLATION FOR THE DIRECT ROLLING OF A CAST STEEL CASTING AND PRODUCTION THEREOF OF A STEEL FINISHED PRODUCT | |
FR2763960A1 (en) | PROCESS FOR THE MANUFACTURE OF THIN STRIPS OF FERRITIC STAINLESS STEEL, AND THIN STRIPS THUS OBTAINED | |
FR2798871A1 (en) | METHOD FOR MANUFACTURING CARBON STEEL STRIPS, IN PARTICULAR STEEL FOR PACKAGES, AND STRIPS THUS PRODUCED | |
JP5758970B2 (en) | Method and apparatus for in-line surface treatment of slabs | |
JP2013517138A5 (en) | ||
EP0046423B2 (en) | Method of executing the skin pass at a regulated rate in the rolling of steel strips annealed in a furnace | |
WO2006053996A1 (en) | Method for feeding lubricant during a hot rolling process | |
CA2907632C (en) | Pre-cooling system having controlled internal adjustment | |
JP5577654B2 (en) | Manufacturing method of high-strength hot-rolled steel strip | |
RU2344010C2 (en) | Method of sectional bar rolling | |
FR2792857A1 (en) | PROCESS FOR THE CONTINUOUS MANUFACTURE OF A METAL STRIP | |
JP4764135B2 (en) | Mechanical descaling method for steel | |
EP1266041A1 (en) | Method for making a multiphase hot-rolled steel strip | |
FR2513548A1 (en) | HOT ROLLED METHOD OF STRIP AND HOT ROLLED FOR STRIPS | |
RU2365442C1 (en) | Method for protection of hot rolled breakdown surface against oxidation in process of rolling | |
EP1204770B1 (en) | Method for making a continuous steel strip | |
WO2019043073A1 (en) | Industrial facility comprising a contactless wiper | |
FR2648825A1 (en) | METHOD AND FACILITY FOR TREATING ANIMAL SKIN | |
CH214439A (en) | Process and installation for the manufacture of metal profiles. | |
EP0382702A2 (en) | Method of manufacturing a thin steel slab by continuous casting | |
BE894339A (en) | Clean cold-rolled steel strip prodn. - by weak lubricant emulsion injection at last mill stand | |
FR2532203A1 (en) | Method for producing a clean, cold-rolled strip | |
BE460087A (en) |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20100322 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL BA MK RS |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: MATET, PATRICE Inventor name: MIALOT, SYLVAIN Inventor name: BOREAN, JEAN-LUC Inventor name: LEBLANC, VALERIE Inventor name: DUSSART, GILLES Inventor name: MIKLER, NATHALIE |
|
DAX | Request for extension of the european patent (deleted) | ||
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: ARCELORMITTAL |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
INTG | Intention to grant announced |
Effective date: 20160713 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: MATET, PATRICE Inventor name: LEBLANC, VALERIE Inventor name: MIALOT, SYLVAIN Inventor name: MIKLER, NATHALIE Inventor name: DUSSART, GILLES Inventor name: BOREAN, JEAN-LUC |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 855602 Country of ref document: AT Kind code of ref document: T Effective date: 20170115 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602008048045 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161221 |
|
REG | Reference to a national code |
Ref country code: RO Ref legal event code: EPE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: FP |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161221 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170321 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170322 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161221 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161221 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2618498 Country of ref document: ES Kind code of ref document: T3 Effective date: 20170621 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 10 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170421 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161221 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170421 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170321 |
|
REG | Reference to a national code |
Ref country code: SK Ref legal event code: T3 Ref document number: E 23623 Country of ref document: SK |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602008048045 Country of ref document: DE |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20170922 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161221 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161221 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161221 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170831 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170831 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170820 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 11 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170820 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20161221 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: UEP Ref document number: 855602 Country of ref document: AT Kind code of ref document: T Effective date: 20161221 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20080820 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20161221 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230427 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: TR Payment date: 20230727 Year of fee payment: 16 Ref country code: RO Payment date: 20230731 Year of fee payment: 16 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20240723 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FI Payment date: 20240724 Year of fee payment: 17 Ref country code: DE Payment date: 20240723 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20240723 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20240723 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20240723 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20240902 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CZ Payment date: 20240726 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: AT Payment date: 20240725 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: PL Payment date: 20240726 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SK Payment date: 20240726 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20240723 Year of fee payment: 17 |