EP2091741A1 - Method of forming openings in substrates and inkjet printheads fabricated thereby - Google Patents
Method of forming openings in substrates and inkjet printheads fabricated therebyInfo
- Publication number
- EP2091741A1 EP2091741A1 EP06839169A EP06839169A EP2091741A1 EP 2091741 A1 EP2091741 A1 EP 2091741A1 EP 06839169 A EP06839169 A EP 06839169A EP 06839169 A EP06839169 A EP 06839169A EP 2091741 A1 EP2091741 A1 EP 2091741A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ink feed
- substrate
- feed hole
- elements
- area
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1601—Production of bubble jet print heads
- B41J2/1603—Production of bubble jet print heads of the front shooter type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/14—Structure thereof only for on-demand ink jet heads
- B41J2/14016—Structure of bubble jet print heads
- B41J2/14032—Structure of the pressure chamber
- B41J2/1404—Geometrical characteristics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/1626—Manufacturing processes etching
- B41J2/1629—Manufacturing processes etching wet etching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/1631—Manufacturing processes photolithography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/1632—Manufacturing processes machining
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/1632—Manufacturing processes machining
- B41J2/1634—Manufacturing processes machining laser machining
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/16—Production of nozzles
- B41J2/1621—Manufacturing processes
- B41J2/164—Manufacturing processes thin film formation
- B41J2/1645—Manufacturing processes thin film formation thin film formation by spincoating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
- B41J2/135—Nozzles
- B41J2/14—Structure thereof only for on-demand ink jet heads
- B41J2002/14403—Structure thereof only for on-demand ink jet heads including a filter
Definitions
- This invention relates generally to forming openings in substrates and more particularly to using such techniques to fabricate inkjet printheads.
- InkJet printheads are one of the many types of articles fabricated on silicon wafer substrates using photolithography techniques.
- a printhead is a drop-generating device having a plurality of nozzles or orifices through which drops of ink are selectively ejected. Ejection of an ink drop through a nozzle is accomplished using any suitable ejection mechanism, such as thermal bubble or piezoelectric pressure wave.
- One common architecture for a thermal inkjet printhead has a plurality of thin film resistors provided on a semiconductor substrate. An orifice plate is deposited over the thin film layer on the substrate.
- the orifice plate defines firing chambers about each of the resistors, a nozzle corresponding to each firing chamber, and an ink feed channel fluidly connected to each firing chamber.
- Ink is provided through an ink feed hole or slot formed in the substrate and flows through the ink feed channels to the firing chambers. Actuation of the resistor by a "fire signal" causes ink in the corresponding firing chamber to be heated and expelled through the corresponding nozzle.
- Fabricating such inkjet printheads generally comprises forming an orifice plate on the frontside of a silicon wafer substrate and then forming an ink feed hole in the substrate.
- One known operation for forming ink feed holes comprises a hybrid laser micromachining and wet chemical etch slotting process.
- a laser micromachining operation makes hardmask openings in a backside oxide layer and then laser micromachines blind trenches in the hardmask openings. The laser trenches must be machined to a specified depth, within a given margin.
- a wet chemical etch process completes the ink feed holes by etching from both the backside and frontside to meet the final critical dimension (FCD).
- FCD critical dimension
- this hybrid slotting process does experience occasional yield defects.
- One common yield defect seen with this process is the so-called "under-etch” defect in which insufficient etching occurs and the ink feed hole fails to meet its final critical dimension (FCD).
- FCD final critical dimension
- a major contributor to the under-etch defect is poor frontside etching in the center region of the ink feed hole. Because the frontside etching occurs in the substantially closed chambers formed by the orifice plate, the hydrogen produced by the chemical reaction does not have space to escape and therefore impedes the etching process. Thus, frontside etch only initiates and etches along the edges of the ink feed hole, and the center region experiences minimal etching. As a result, it takes longer for the frontside and backside etches to meet and break through, thereby resulting in more under-etch defects.
- laser punch-through of the orifice plate. That is, breaking through the frontside of the substrate while laser micromachining the backside trench and damaging the orifice plate.
- the major contributor to laser punch-through of the orifice plate is the laser trench depth being targeted too deep and with small margin. In other words, to achieve desired etching, the backside trench is machined very deep, and thus very close to the frontside of the substrate, which can result in occasional punch through to the orifice plate.
- the present invention provides a method of forming an opening through a substrate having first and second opposing planar surfaces.
- the method includes defining an area on the first surface where the opening is to be formed, the area having a center region flanked by edge regions.
- a top layer having a substantially closed space located over the area is formed on the first surface.
- Means for promoting etching of the center region are provided, and the first surface of the substrate is etched in the area.
- the present invention provides a method of fabricating an inkjet printhead.
- This method includes providing a substrate having first and second opposing planar surfaces and defining an ink feed hole area on the first surface.
- the ink feed hole area has a center region flanked by edge regions.
- An orifice plate is formed on the first surface, and a substantially closed space is formed in the orifice plate.
- the space is located over the ink feed hole area.
- a plurality of etch promoting elements is provided in the space. The etch promoting elements are in contact with the first surface in the center region.
- the first surface of the substrate in the ink feed hole area is then wet etched.
- the present invention provides a method of fabricating an inkjet printhead in which a substrate having first and second opposing planar surfaces is provided.
- a first ink feed hole area is defined on the first surface; the first ink feed hole area has a center region flanked by edge regions.
- a chamber layer is applied on the first surface, and portions of the chamber layer are removed to define firing chambers and ink feed channels and to form etch promoting elements in the center region.
- a nozzle layer is applied over the chamber layer, and a plurality of nozzles is formed in the nozzle layer.
- a second ink feed hole area is defined on the second surface, and a backside trench is machined in the second ink feed hole area.
- An ink feed hole is formed in the substrate by wet etching the first ink feed hole area on first surface and the second ink feed hole area on the second surface.
- FIG. 1 is cross-sectional side view of a thermal inkjet printhead.
- FIG. 3 is a cross-sectional side view of a partially fabricated printhead provided with a chamber layer.
- FIG. 7 is a cross-sectional side view of a partially fabricated printhead provided with a nozzle layer.
- FIG. 9 is an enlarged side view of a printhead showing bubble formation at the interface of a substrate and a particle tolerance or etch promoting element.
- FIG. 13 is cross-sectional side view of a portion of another embodiment of a thermal inkjet printhead.
- FIG. 15 is a partial top view of the printhead of FIG. 13 showing another configuration of particle tolerance or etch promoting elements.
- FIG. 16 is a partial top view of the printhead of FIG. 13 showing yet another configuration of particle tolerance or etch promoting elements.
- FIGS. 1-8 illustrate one embodiment of a method for forming an opening through a substrate.
- FIGS. 1-8 depict a process of fabricating a thermal inkjet printhead; wherein the opening formed in a substrate is an ink feed hole.
- This is simply one possible application of a method for forming an opening through a substrate given by way of example to illustrate the present invention.
- the process of forming an opening in a substrate can be used in many applications other than fabricating inkjet printheads.
- FIGS. 1-8 are schematics for a very small region of a substrate that may be many orders of magnitude greater in dimension to the shown region, and that the various structural features shown for purposes of illustration are not necessarily to scale.
- FIG. 1 shows an exemplary inkjet printhead 10 fabricated from the process described below; that is, a finished product of the process.
- the printhead 10 includes a substrate 12 having at least one ink feed hole 14 formed therein with a plurality of ink drop generators 16 arranged around the ink feed hole 14.
- Each ink drop generator 16 includes a nozzle 18, a firing chamber 20 in fluid communication with the nozzle 18, an ink feed channel 22 establishing fluid communication between the ink feed hole 14 and the firing chamber 20, and a resistor or similar heating element 24 disposed in the firing chamber 20.
- the thermally actuated resistors are described here by way of example, the present invention could include other types of fluid ejection devices such as piezoelectric actuated devices.
- FIG. 1 depicts one common printhead configuration, namely, two rows of ink drop generators about a common ink feed hole, other configurations useful in inkjet printing may also be formed in the practice of the present invention.
- ink is introduced into the firing chamber 20 from the ink feed hole 14 (which is in fluid communication with a conventional ink source (not shown)) via the ink feed channel 22.
- Selectively passing current through the resistor 24 superheats the ink in the associated firing chamber 20 to a cavitation point such that an ink bubble's expansion and collapse ejects a droplet through the associated nozzle 18.
- the firing chamber 20 is then refilled with ink from the ink feed hole 14 via the ink feed channel 22 for the next operation.
- the particle tolerance elements 28, 30 operate to trap particles that may be present in the ink and prevent such particles from clogging the ink feed channels 22 and the nozzles 18.
- the fabrication process starts with a substrate 12, which is typically a silicon wafer.
- the substrate 12 has a first planar surface 32 (also referred to herein as the frontside surface) and a second planar surface 34 (also referred to herein as the backside surface), opposite the first surface 32.
- a first oxide layer 36 which can be, for example, a field oxide layer, is grown or deposited on the frontside surface 32, and a second oxide layer 38, which can also be a field oxide layer, is grown or deposited on the backside surface 34.
- a thin film stack 40 is applied on top of the first oxide layer 36.
- the film stack 40 which is generally well known in the art, includes, for example, a conductive metal layer, forming the resistors 24 and conductive traces, and one or more passivation layers.
- the passivation layers are generally formed, for example, of tantalum, silicon dioxide, silicon carbide, silicon nitride, polysilicon glass, or any other suitable material.
- the conductive metal layers are generally formed, for example, of aluminum, gold or other metal or metal alloy.
- the thin film stack 40 and the first oxide layer 36 are patterned and etched using known photolithography techniques to define an opening 42 that delineates an area 44 on the frontside surface 32 of the substrate 12 where the frontside portion of the ink feed hole 14 is to be formed. This area 44 is referred to herein as the ink feed hole area.
- the orifice plate 26 (not shown in FIG. 2) is formed on top of the thin film stack 40.
- the orifice plate 26 is preferably, although not necessarily, formed of a photoimagable epoxy such as SU8 available from several sources including MicroChem Corporation of Newton, Massachusetts.
- One possible approach to forming the orifice plate 26 includes generating three individual layers: a primer layer, a chamber layer and a nozzle layer.
- a primer layer (not shown) is first applied over the thin film stack 40.
- the primer layer can comprise a combination of an adhesion promoter, such as a Silane Coupling Agent (SCA), and a thin layer of material conforming to the material that the orifice plate 26 is to be made from.
- SCA Silane Coupling Agent
- this thin layer could be a 2-8 ⁇ m layer of SU8 having a low viscosity of about 10-250 centipoise.
- a chamber layer 48 is then applied over the primer layer (not shown).
- the chamber layer 48 can comprise higher viscosity (e.g., viscosity of approximately 2000-4000 centipoise) SU8 that is spun on.
- the chamber layer thickness varies between about 9-25 ⁇ m depending on desired drop size and fluidics performance. The more viscous SU8 allows for thicker coatings and better uniformity.
- the assembly is baked and then photoimaged using an appropriately formed chamber level mask, which masks the areas of the chamber layer 48 that are to be removed and does not mask the areas that are to remain.
- the SU8 behaves as a negative photoresist, meaning SU8 remains in areas that are exposed to light.
- the chamber layer 48 is developed using an appropriate agent, such as propylene glycol monomethyl ether acetate (PGMEA) or ethyl lactate, to remove the unexposed SU8. That is, the developing agent removes the chamber layer material from areas that did not receive light, thereby creating voids 50 as seen in FIGS. 4 and 5.
- the voids 50 left from the removed chamber layer material will form the firing chambers 20 and the ink feed channels 22. That is, portions of the chamber layer 48 not removed in the develop step will constitute sidewalls of the firing chambers 20 and the ink feed channels 22, as best seen in FIG. 5.
- Portions of the chamber layer 48 overlying the ink feed hole area 44 are also not removed in the develop step so as to form the particle tolerance elements 28, 30.
- the particle tolerance elements 28, 30 are upstanding from, and in contact with, the substrate surface in the ink feed hole area 44.
- the ink feed hole area 44 is divided across its width W into a center region 52 and two edge regions 54 flanking the center region 52.
- the particle tolerance elements thus comprise a number of first particle tolerance elements 28 located in each of the two edge regions 54 and a number of second particle tolerance elements 30 located in the center region 52.
- the first particle tolerance elements 28 define pillars preferably positioned adjacent a corresponding ink feed channel 22 and will function to trap particles and to prevent clogging of the ink flow channels 22 and the nozzles 18.
- the second particle tolerance elements 30 located in the center region 52 of the ink feed hole area 44 will also help to trap particles and prevent clogging. As will be described in more detail below, the second particle tolerance elements 30 also function to promote etching of the substrate 12 in the center region 52 during fabrication of the printhead 10. [0034] Turning to FIG. 6, a lost wax process is used to preserve the voids 50 (not shown in FlG. 6) during subsequent processing.
- a fill material 56 such as a standard positive photoresist or an inert fill material, is applied over the chamber layer 48 so as to fill the voids 50.
- the fill material 56 which initially overfills the voids 50, is then planarized, such as through a resist etch back (REB) process or a chemical mechanical polishing (CMP) process. This planarization process removes excess fill material to bring the fill material 56 in the voids 50 flush with the chamber layer 48.
- REB resist etch back
- CMP chemical mechanical polishing
- a nozzle layer 58 is applied on top of the chamber layer 48.
- the fill material 56 holds the shape of the filled voids 50 while the nozzle layer 58 is added.
- the nozzle layer 58 is preferably, although not necessarily, made of the same material as the chamber layer 48, such as SU8.
- the nozzle layer 58 is photoimaged using an appropriately formed nozzle level mask.
- the SU8 behaves as a negative photoresist, meaning SU8 remains in areas that are exposed to light. An appropriate developing agent is used again, this time to remove the areas of the nozzle layer 58 not exposed to light and thereby form the nozzles 18.
- the fill material 56 filling the voids 50 in the chamber layer 48 is also removed, leaving the now substantially closed space defining the firing chambers 20, the ink feed channels 22, and the void above the ink feed hole area 44.
- This space is “substantially closed” in that it is completely enclosed except for the nozzles 18.
- the primer layer (not shown), the chamber layer 48 and the nozzle layer 58 collectively make up the orifice plate 26, which can also be referred to as the "top layer.”
- the completed structure is cured at elevated temperature (e.g., 150-220 0 C) and then exposed to an oxygen plasma ash to clean any residues from the surfaces.
- the next step is to form a backside hard mask in the second oxide layer 38, which determines the desired configuration of the ink feed hole 14 on the backside surface 34.
- the backside hard mask defines an exposed area on the backside surface 34 referred to herein as the backside ink feed hole area 60.
- the backside ink feed hole area 60 can be formed through laser ablation of appropriate portions of the second oxide layer 38.
- a backside trench 62 is then created in the backside ink feed hole area 60 via laser micromachining.
- the ink feed hole 14 is finished by a combined frontside and backside bulk wet etching process using a wet etchant such as tetramethyl ammonium hydroxide (TMAH), potassium hydroxide (KOH), or the like.
- TMAH tetramethyl ammonium hydroxide
- KOH potassium hydroxide
- the backside etch is accomplished by introducing the etchant to the backside ink feed hole area 60 and the backside trench 62.
- the frontside etch is accomplished by introducing the etchant to the frontside ink feed hole area 44.
- the etchant flows through the nozzles 18, the chambers 20 and the ink feed channels 22 to reach the ink feed hole area 44.
- the etchant floods the frontside ink feed hole area 44, surrounding the particle tolerance elements 28, 30, and begins to etch exposed substrate material.
- the etch promoting elements 30 are again circular in shape, but are arranged in two parallel lines in the center region 52. The lines are staggered with respect to one another.
- the second particle tolerance or etch promoting elements 30 are designed so as to best promote center region etching while still providing a particle tolerance function in the finished printhead 10.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Geometry (AREA)
- Particle Formation And Scattering Control In Inkjet Printers (AREA)
Abstract
Description
Claims
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2006/046759 WO2008069798A1 (en) | 2006-12-07 | 2006-12-07 | Method of forming openings in substrates and inkjet printheads fabricated thereby |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2091741A1 true EP2091741A1 (en) | 2009-08-26 |
| EP2091741B1 EP2091741B1 (en) | 2011-08-24 |
Family
ID=38283525
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06839169A Not-in-force EP2091741B1 (en) | 2006-12-07 | 2006-12-07 | Method of forming openings in substrates |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP2091741B1 (en) |
| CN (1) | CN101568435A (en) |
| AT (1) | ATE521477T1 (en) |
| WO (1) | WO2008069798A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014018008A1 (en) | 2012-07-24 | 2014-01-30 | Hewlett-Packard Company, L.P. | Fluid ejection device with particle tolerant thin-film extension |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5463413A (en) * | 1993-06-03 | 1995-10-31 | Hewlett-Packard Company | Internal support for top-shooter thermal ink-jet printhead |
| US6132033A (en) * | 1999-04-30 | 2000-10-17 | Hewlett-Packard Company | Inkjet print head with flow control manifold and columnar structures |
| US6419346B1 (en) | 2001-01-25 | 2002-07-16 | Hewlett-Packard Company | Two-step trench etch for a fully integrated thermal inkjet printhead |
| US6554403B1 (en) * | 2002-04-30 | 2003-04-29 | Hewlett-Packard Development Company, L.P. | Substrate for fluid ejection device |
| JP3862624B2 (en) * | 2002-07-10 | 2006-12-27 | キヤノン株式会社 | Liquid discharge head and method for manufacturing the head |
| US7285226B2 (en) | 2004-07-22 | 2007-10-23 | Hewlett-Packard Development Company, L.P. | Method for fabricating a fluid ejection device |
-
2006
- 2006-12-07 CN CNA2006800565689A patent/CN101568435A/en active Pending
- 2006-12-07 AT AT06839169T patent/ATE521477T1/en not_active IP Right Cessation
- 2006-12-07 WO PCT/US2006/046759 patent/WO2008069798A1/en not_active Ceased
- 2006-12-07 EP EP06839169A patent/EP2091741B1/en not_active Not-in-force
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2008069798A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2091741B1 (en) | 2011-08-24 |
| WO2008069798A1 (en) | 2008-06-12 |
| ATE521477T1 (en) | 2011-09-15 |
| CN101568435A (en) | 2009-10-28 |
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