EP2059622A1 - Temperature-stable cast-iron alloy and its use - Google Patents
Temperature-stable cast-iron alloy and its useInfo
- Publication number
- EP2059622A1 EP2059622A1 EP20070766720 EP07766720A EP2059622A1 EP 2059622 A1 EP2059622 A1 EP 2059622A1 EP 20070766720 EP20070766720 EP 20070766720 EP 07766720 A EP07766720 A EP 07766720A EP 2059622 A1 EP2059622 A1 EP 2059622A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- iron alloy
- cast
- temperature
- alloy according
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 32
- 239000000956 alloy Substances 0.000 title claims abstract description 32
- 229910001018 Cast iron Inorganic materials 0.000 title claims abstract description 23
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 11
- 239000011651 chromium Substances 0.000 claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000356 contaminant Substances 0.000 claims abstract description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 6
- 239000011572 manganese Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 6
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 6
- 239000010703 silicon Substances 0.000 claims abstract description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005864 Sulphur Substances 0.000 claims abstract description 5
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052742 iron Inorganic materials 0.000 claims abstract description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 239000011733 molybdenum Substances 0.000 claims abstract description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 4
- 239000001301 oxygen Substances 0.000 claims abstract description 4
- 239000004568 cement Substances 0.000 claims description 6
- 239000011159 matrix material Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009533 lab test Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- -1 chromium carbides Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910000734 martensite Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- FXNGWBDIVIGISM-UHFFFAOYSA-N methylidynechromium Chemical compound [Cr]#[C] FXNGWBDIVIGISM-UHFFFAOYSA-N 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
- C22C37/06—Cast-iron alloys containing chromium
- C22C37/08—Cast-iron alloys containing chromium with nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
- C22C37/10—Cast-iron alloys containing aluminium or silicon
Definitions
- the present invention relates to a temperature-stable cast-iron alloy having a high wear resistance at temperatures ranging between 500 and 900°C.
- clinker cooler is used for cooling cement clinker which is introduced to the clinker cooler from a preceding kiln at a temperature ranging between 1300 and 1450° C.
- the cement clinker is directed through the clinker cooler by means of appropriate means of conveyance which are typically made up of some form of elements which are reciprocated in the direction of movement of the cement clinker, and thus exposed to significant wear at temperatures ranging between 500 and 900 °C.
- a wear-resistant cast-iron alloy having the following composition expressed in weight percentages: chromium: 12-25 %, carbon: 1.5-6 %, manganese: 2-7 %, silicon: up to 1.5%, molybdenum: up to 2 %, nickel: up to 4 %, micro alloying elements selected from the group consisting of titanium, zirconium, niobium, boron, vanadium, and tungsten: up to 2 % of each of one or more of the elements, and balance iron.
- the alloy is subjected to heat treatment in order to give it a martensitic matrix.
- This type of matrix is very hard and brittle, and machine elements manufactured from such material are prone to cracking if subjected to impacts or blows. Furthermore, this type of matrix lacks thermal stability due to its softening at temperatures in excess of 400° C.
- the applicant of the present patent application also has experience with regard to a cast-iron alloy according to European standard 10295 (2002), material: G-X40 CrNiSi25-12, Material No.
- both materials tend to form a sigma phase which is a brittle inter-metallic phase consisting of equal parts of iron and chromium, and hence be brittle, and that they are not particular wear resistant.
- a cast-iron alloy according to the invention having the following composition expressed in weight percentages: chromium: 15.0-20.0 %, carbon: 1.0-2.0 %, manganese: 1.5-2.0 %, silicon: 0.8-1.2 %, nickel: 8.0-10.0 %, molybdenum: 0.8-1.2 % balance iron and unavoidable metallic and non-metallic contaminants, where the non-metallic contaminants comprise nitrogen, oxygen, phosphorous and sulphur.
- the alloy according to the invention has significantly improved wear characteristics compared to the alloy according to the European standard 10295 and the modified version hereof, both defined above.
- the test results show that the alloy according to the invention has a wear resistance which is approximately four times higher than that of the alloy according to European standard 10295 and twice as high as that of the modified version hereof.
- the improved wear resistance is mainly ascribable to the optimization of the carbon-chromium ratio, resulting in optimum formation of chromium carbides which constitute the wear-resistant component of the alloy.
- the cast-iron alloy according to the invention preferably comprises 16.5-19.5 weight percentage, most preferably 17.0-19.0 weight percentage chromium.
- the cast-iron alloy according to the invention preferably comprises 1.25-1.85 weight percentage carbon, most preferably 1.5- 1.7 weight percentage carbon.
- the cast-iron alloy according to the invention preferentially has an austenitic matrix.
- the cast-iron alloy can be manufactured and cast into blanks using generally known techniques.
- the described cast-iron alloy is particularly suitable for use in connection with machine parts in clinker coolers for cooling cement clinker.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Heat Treatment Of Articles (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
Abstract
A description is given of a temperature-stable cast-iron alloy having high wear resistance at temperatures between 500 and 900° C. The alloy is characterized in that it has the following composition expressed in weight percentages: chromium: 15.0-20.0 %, carbon: 1.0-2.0 %, manganese: 1.5-2.0 %, silicon: 0.8-1.2 %, nickel: 8.0-10.0 %, molybdenum: 0.8-1.2 % balance iron and unavoidable metallic and non-metallic contaminants where the non-metallic contaminants comprise nitrogen, oxygen, phosphorous and sulphur. Hereby is obtained a cast-iron alloy which has a higher wear resistance and a reduced tendency to form the undesirable sigma phase when heated to temperatures between 500 and 900 °C as compared to the known allows.
Description
TEMPERATURE-STABLE CAST-IRON ALLOY AND ITS USE
The present invention relates to a temperature-stable cast-iron alloy having a high wear resistance at temperatures ranging between 500 and 900°C.
Many industries use machines containing machine parts which incur significant wear at relatively high temperatures in excess of 500 °C. For example, in the cement manufacturing industry a so-called clinker cooler is used for cooling cement clinker which is introduced to the clinker cooler from a preceding kiln at a temperature ranging between 1300 and 1450° C. The cement clinker is directed through the clinker cooler by means of appropriate means of conveyance which are typically made up of some form of elements which are reciprocated in the direction of movement of the cement clinker, and thus exposed to significant wear at temperatures ranging between 500 and 900 °C.
From WO 2004/104253 is known a wear-resistant cast-iron alloy having the following composition expressed in weight percentages: chromium: 12-25 %, carbon: 1.5-6 %, manganese: 2-7 %, silicon: up to 1.5%, molybdenum: up to 2 %, nickel: up to 4 %, micro alloying elements selected from the group consisting of titanium, zirconium, niobium, boron, vanadium, and tungsten: up to 2 % of each of one or more of the elements, and balance iron.
According to the publication, the alloy is subjected to heat treatment in order to give it a martensitic matrix. This type of matrix is very hard and brittle, and machine elements manufactured from such material are prone to cracking if subjected to impacts or blows. Furthermore, this type of matrix lacks thermal stability due to its softening at temperatures in excess of 400° C.
The applicant of the present patent application also has experience with regard to a cast-iron alloy according to European standard 10295 (2002), material: G-X40 CrNiSi25-12, Material No. :1.4837, which has the following composition expressed in weight percentages: chromium: 24.0-27.0 %, carbon: 0.3-0.5 %, manganese: up to 2.0 %, silicon: 1.0-2.5 %, molybdenum: up to 0.5 %, nickel: 1 1.0-14.0 %, phosphorous: up to 0.040 % and sulphur: up to 0.030 %
and a modified version hereof having the following composition expressed in weight percentages: chromium: 24.0-26.0 %, carbon: 0.7-0.9 %, manganese: 0.6-1.0 %, silicon: 1.5-2.0 % and nickel: 2.5-3.5 %
Experience with these two materials has shown that after prolonged heating to temperatures between 500 and 900 °C both materials tend to form a sigma phase which is a brittle inter-metallic phase consisting of equal parts of iron and chromium, and hence be brittle, and that they are not particular wear resistant.
It is the objective of the present invention to provide a cast-iron alloy having a higher wear resistance and a reduced tendency to form a sigma phase at temperatures between 500 and 900 °C as compared to the cast-iron alloys currently available.
According to the invention this is achieved by a cast-iron alloy according to the invention having the following composition expressed in weight percentages:
chromium: 15.0-20.0 %, carbon: 1.0-2.0 %, manganese: 1.5-2.0 %, silicon: 0.8-1.2 %, nickel: 8.0-10.0 %, molybdenum: 0.8-1.2 % balance iron and unavoidable metallic and non-metallic contaminants, where the non-metallic contaminants comprise nitrogen, oxygen, phosphorous and sulphur.
Hereby is obtained a cast-iron alloy having a higher wear resistance and a reduced tendency to form the undesired sigma phase when heated to temperatures between 500 and 900 °C as compared to the previously mentioned known alloys.
Laboratory experiments carried out by the applicant of the present patent application have indicated that the alloy according to the invention has significantly improved wear characteristics compared to the alloy according to the European standard 10295 and the modified version hereof, both defined above. The test results show that the alloy according to the invention has a wear resistance which is approximately four times higher than that of the alloy according to European standard 10295 and twice as high as that of the modified version hereof. The improved wear resistance is mainly ascribable to the optimization of the carbon-chromium ratio, resulting in optimum formation of chromium carbides which constitute the wear-resistant component of the alloy.
Furthermore, laboratory experiments during which the alloy according to the invention over a period of 8 weeks underwent heat treatment at a temperature of 500 °C with a subsequent microscopy examination, have shown that the alloy exhibits significant heat stability, given the absence of any signs of sigma phase formation.
In order to avoid significant deterioration of the mechanical characteristics of the iron alloy, the non-metallic contaminants comprising nitrogen, oxygen, phosphorous and sulphur should not exceed the maximum limits specified below: maximum 0.020 N, maximumi O ppm O, maximum 0.040 P, and maximum 0.030 S.
The cast-iron alloy according to the invention preferably comprises 16.5-19.5 weight percentage, most preferably 17.0-19.0 weight percentage chromium.
Furthermore, the cast-iron alloy according to the invention preferably comprises 1.25-1.85 weight percentage carbon, most preferably 1.5- 1.7 weight percentage carbon.
The cast-iron alloy according to the invention preferentially has an austenitic matrix.
The cast-iron alloy can be manufactured and cast into blanks using generally known techniques.
The described cast-iron alloy is particularly suitable for use in connection with machine parts in clinker coolers for cooling cement clinker.
Claims
1. Temperature-stable cast-iron alloy having high wear resistance at temperatures between 500 - 900 °C, characterized in that it has the following composition expressed in weight percentages: chromium: 15.0-20.0 %, carbon: 1.0-2.0 %, manganese: 1.5-2.0 %, silicon: 0.8-1.2 %, nickel: 8.0-10.0 %, molybdenum: 0.8-1.2 % balance iron and unavoidable metallic and non-metallic contaminants where the non-metallic contaminants comprise nitrogen, oxygen, phosphorous and sulphur.
2. Temperature-stable cast-iron alloy according to claim 1 , characterized in that it comprises 16.5-19.5 weight percentage chromium.
3. Temperature-stable cast-iron alloy according to claim 2, characterized in that it comprises 17.0-19.0 weight percentage chromium.
4. Temperature-stable cast-iron alloy according to any of the preceding claims, characterized in that it comprises 1.25-1.85 weight percentage carbon.
5. Temperature-stable cast-iron alloy according to claim 4, characterized in that it comprises 1.5 - 1.7 weight percentage carbon.
6. Temperature-stable cast-iron alloy according to any of the preceding claims, characterized in that it has an austenitic matrix.
7. Use of cast-iron alloy according to any of the preceding claims for machine parts in clinker coolers for cooling of cement clinker.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200601155A DK176960B1 (en) | 2006-09-08 | 2006-09-08 | Temperature stable cast iron alloy and its use |
| PCT/IB2007/052214 WO2008029305A1 (en) | 2006-09-08 | 2007-06-12 | Temperature-stable cast-iron alloy and its use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2059622A1 true EP2059622A1 (en) | 2009-05-20 |
Family
ID=39156875
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP20070766720 Withdrawn EP2059622A1 (en) | 2006-09-08 | 2007-06-12 | Temperature-stable cast-iron alloy and its use |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20110042051A1 (en) |
| EP (1) | EP2059622A1 (en) |
| CN (1) | CN101512031B (en) |
| BR (1) | BRPI0716636B1 (en) |
| DK (1) | DK176960B1 (en) |
| MX (1) | MX2009002119A (en) |
| RU (1) | RU2430182C2 (en) |
| UA (1) | UA93557C2 (en) |
| WO (1) | WO2008029305A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102230123B (en) * | 2011-06-17 | 2013-10-02 | 湖南长高新材料股份有限公司 | Chromium-based modified wear-resistant cast iron and preparation method thereof |
| CN103741011A (en) * | 2013-12-27 | 2014-04-23 | 黄忠波 | Cast iron alloy with high wear resistance and temperature stability |
| CN103741015A (en) * | 2013-12-27 | 2014-04-23 | 黄忠波 | Cast iron alloy with high wear resistance and high-temperature stability |
| IT201900012738A1 (en) * | 2019-07-24 | 2021-01-24 | Freni Brembo Spa | CAST IRON, ESPECIALLY FOR DISC BRAKE COMPONENTS |
| EA037998B1 (en) * | 2020-01-10 | 2021-06-22 | Физули Расул оглы Расулов | Alloyed material for obtaining wear-resistant and corrosion-resistant parts |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3543413A (en) * | 1968-12-18 | 1970-12-01 | Hanford Foundry Co | Removable clinker cooler grate plates and support frame therefor |
| DE2818734A1 (en) * | 1978-04-28 | 1979-10-31 | Wahl Verschleiss Tech | Low cost armour plating - comprises chilled cast iron layers opt. contg. hard inserts |
| FR2447753A1 (en) * | 1979-02-05 | 1980-08-29 | Thome Cromback Acieries | PROCESS FOR MANUFACTURING GRINDING BODIES WITH AXIAL SYMMETRY IN FERROUS ALLOY AND NEW GRINDING BODIES OBTAINED BY THIS PROCESS |
| SU960297A1 (en) * | 1980-06-23 | 1982-09-23 | Всесоюзный научно-исследовательский и проектно-технологический институт угольного машиностроения | Cast iron |
| US4477283A (en) * | 1981-07-21 | 1984-10-16 | Eddie K. Wilson, Sr. | Process and apparatus for producing hydraulic cements |
| SU1541299A1 (en) * | 1988-05-12 | 1990-02-07 | Научно-производственное объединение по механизации, роботизации труда и совершенствованию ремонтного обеспечения на предприятиях черной металлургии "Черметмеханизация" | Cast iron |
| CN1027548C (en) * | 1989-05-06 | 1995-02-01 | 机械电子工业部沈阳铸造研究所 | Wear-corrosion resistant austenitic cast iron and manufacturing technique |
| US5202087A (en) * | 1992-07-31 | 1993-04-13 | The Carondelet Corporation | Cement cooler grate alloy |
| CN1028376C (en) * | 1993-06-11 | 1995-05-10 | 山东省冶金研究所 | Low-carbon high-chromium cast iron wear-resistant material |
| US5674449A (en) * | 1995-05-25 | 1997-10-07 | Winsert, Inc. | Iron base alloys for internal combustion engine valve seat inserts, and the like |
| AU2003902535A0 (en) * | 2003-05-22 | 2003-06-05 | Weir Warman Ltd | Wear resistant cast iron |
-
2006
- 2006-09-08 DK DKPA200601155A patent/DK176960B1/en not_active IP Right Cessation
-
2007
- 2007-06-12 UA UAA200901098A patent/UA93557C2/en unknown
- 2007-06-12 MX MX2009002119A patent/MX2009002119A/en active IP Right Grant
- 2007-06-12 BR BRPI0716636-2B1A patent/BRPI0716636B1/en not_active IP Right Cessation
- 2007-06-12 EP EP20070766720 patent/EP2059622A1/en not_active Withdrawn
- 2007-06-12 US US12/377,043 patent/US20110042051A1/en not_active Abandoned
- 2007-06-12 RU RU2009106999A patent/RU2430182C2/en not_active IP Right Cessation
- 2007-06-12 CN CN2007800329727A patent/CN101512031B/en not_active Expired - Fee Related
- 2007-06-12 WO PCT/IB2007/052214 patent/WO2008029305A1/en not_active Ceased
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2008029305A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| DK176960B1 (en) | 2010-07-26 |
| WO2008029305A1 (en) | 2008-03-13 |
| BRPI0716636A2 (en) | 2012-12-25 |
| DK200601155A (en) | 2008-03-09 |
| RU2430182C2 (en) | 2011-09-27 |
| UA93557C2 (en) | 2011-02-25 |
| BRPI0716636B1 (en) | 2014-10-29 |
| CN101512031B (en) | 2010-12-08 |
| CN101512031A (en) | 2009-08-19 |
| MX2009002119A (en) | 2009-03-09 |
| US20110042051A1 (en) | 2011-02-24 |
| RU2009106999A (en) | 2010-10-20 |
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