EP2010313A1 - Method and device for the controlled regeneration of a catalyst and a reactor - Google Patents
Method and device for the controlled regeneration of a catalyst and a reactorInfo
- Publication number
- EP2010313A1 EP2010313A1 EP07727975A EP07727975A EP2010313A1 EP 2010313 A1 EP2010313 A1 EP 2010313A1 EP 07727975 A EP07727975 A EP 07727975A EP 07727975 A EP07727975 A EP 07727975A EP 2010313 A1 EP2010313 A1 EP 2010313A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- burner
- catalyst
- reactor
- burners
- regeneration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/02—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/12—Treating with free oxygen-containing gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00504—Controlling the temperature by means of a burner
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00716—Means for reactor start-up
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00157—Controlling the temperature by means of a burner
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/90—Regeneration or reactivation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Definitions
- the invention relates to a process for the regeneration of a catalyst in a reactor, which is equipped with at least one burner, as well as a device for carrying out the method.
- the catalytic conversion of the hydrocarbon-containing feed into the desired olefin products proceeds under heat absorption (endothermic).
- endothermic In order to maintain the temperatures required for an endothermic catalytic reaction in a reactor, it is usually provided with one or more burners.
- the catalytic reaction usually by-products, such as. As carbon, which precipitate on the catalyst and disable it. For this reason, the catalyst has to be regenerated, for which the supply of starting materials is interrupted in a batch process and, for example, oxidizing gas is passed over the catalyst (see H. Bölt, F. Walser, Linde Reports on Science and Technology 49, 3-8 (1991)).
- the burners of the reactor are kept at minimum load (German Patent, DE 34 39 166). This can lead to the occurrence of temperature peaks, which can irreparably damage the catalyst. This leads to a reduction of the catalyst activity and thus to a reduction of the product yield in the catalysis cycle along with a reduction of the catalyst lifetime.
- This object is achieved in that the burners are turned off during the regeneration phase of the catalyst.
- the burners switched off are re-ignited after the regeneration phase via at least one pilot burner.
- the flame of the pilot burner and the burner is monitored.
- An adaptation of the heat output of the pilot burner to compensate for heat losses of the reactor is also appropriate.
- the deactivated burners are activated again by means of electronic ignition. On the device side, this object is achieved in that the burners have a shut-off device in the reactor.
- the reactor is expediently equipped with at least one pilot burner as well as with a pilot burner monitoring device and the burners.
- a means for controlling the performance of the pilot burner is also useful.
- the device contains a device for the electronic reignition of the burner.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The invention relates to a method and a device for the controlled regeneration of a catalyst and of a fired reactor, especially a catalyst and a reactor in a plant for producing olefins from a hydrocarbon-containing charge. During the regeneration phase of the catalyst for recovering the catalytic activity, the burners of the reactor are switched off. After the regeneration phase, the burners are re-ignited by means of inbuilt pilot burners. The pilot burners are monitored and their capacity is adjusted in such a manner that the heat loss of the reactor during the regeneration phase of the catalyst is compensated for.
Description
Verfahren und Vorrichtung zur kontrollierten Regeneration eines Katalysators und ReaktorsMethod and apparatus for controlled regeneration of a catalyst and reactor
Beschreibungdescription
Die Erfindung betrifft ein Verfahren zur Regeneration eines Katalysators in einem Reaktor, der mit mindestens einem Brenner ausgestattet ist, sowie eine Vorrichtung zur Durchführung des Verfahrens.The invention relates to a process for the regeneration of a catalyst in a reactor, which is equipped with at least one burner, as well as a device for carrying out the method.
In einer Anlage zur Herstellung von Olefinen aus kohlenwasserstoffhaltigem Einsatz läuft die katalytische Umsetzung des kohlenwasserstoffhaltigen Einsatzes in die gewünschten Olefinprodukte unter Wärmeaufnahme (endotherm) ab. Um die für eine endotherme katalytische Umsetzung erforderlichen Temperaturen in einem Reaktor aufrecht zu halten, ist dieser üblicherweise mit einem oder mehreren Brennern verse- hen. Während der katalytischen Reaktion entstehen normalerweise Nebenprodukte, wie z. B. Kohlenstoff, die sich auf dem Katalysator niederschlagen und diesen deaktivieren. Aus diesem Grunde muss der Katalysator regeneriert werden, wozu in einem diskontinuierlichen Verfahren die Zufuhr der Einsatzstoffe unterbrochen und zum Beispiel oxidierendes Gas über den Katalysator geleitet wird (siehe H. Bölt, F. Walser, Linde Reports on Science and Technology 49, 3-8 (1991 )). Nach dem Stand der Technik werden dabei die Brenner des Reaktors auf Mindestlast gehalten (Deutsches Patent, DE 34 39 166). Dabei kann es zum Auftreten von Temperaturspitzen kommen, welche den Katalysator irreparabel schädigen können. Dies führt zu einer Verringerung der Katalysatoraktivität und damit zu einer Verringerung der Produktausbeute im Kata- lysezyklus einhergehend mit einer Verringerung der Katalysatorlebensdauer.In a plant for the production of olefins from hydrocarbon-containing use, the catalytic conversion of the hydrocarbon-containing feed into the desired olefin products proceeds under heat absorption (endothermic). In order to maintain the temperatures required for an endothermic catalytic reaction in a reactor, it is usually provided with one or more burners. During the catalytic reaction usually by-products, such as. As carbon, which precipitate on the catalyst and disable it. For this reason, the catalyst has to be regenerated, for which the supply of starting materials is interrupted in a batch process and, for example, oxidizing gas is passed over the catalyst (see H. Bölt, F. Walser, Linde Reports on Science and Technology 49, 3-8 (1991)). According to the state of the art, the burners of the reactor are kept at minimum load (German Patent, DE 34 39 166). This can lead to the occurrence of temperature peaks, which can irreparably damage the catalyst. This leads to a reduction of the catalyst activity and thus to a reduction of the product yield in the catalysis cycle along with a reduction of the catalyst lifetime.
Der vorliegenden Erfindung liegt die Aufgabe zugrunde, ein Verfahren der eingangs genannten Art sowie eine Vorrichtung zur Durchführung des Verfahren so auszugestalten, dass das Auftreten von unzulässig hohen Temperaturspitzen und die damit ver- bundene Schädigung des Katalysators vermieden bzw. minimiert wird.It is an object of the present invention to provide a method of the aforementioned type and a device for carrying out the method such that the occurrence of impermissibly high temperature peaks and the associated damage to the catalyst is avoided or minimized.
Diese Aufgabe wird erfindungsgemäß dadurch gelöst, dass die Brenner während der Regenerationsphase des Katalysators ausgeschaltet werden.This object is achieved in that the burners are turned off during the regeneration phase of the catalyst.
Gemäß einer besonders bevorzugten Ausführung der Erfindung werden die ausgeschalteten Brenner nach der Regenerationsphase über mindestens einen Pilotbrenner neugezündet. Vorteilhafterweise wird die Flamme des Pilotbrenners und der Brenner überwacht. Eine Anpassung der Wärmeleistung des Pilotbrenners zur Kompensation von Wärmeverlusten des Reaktors ist ebenfalls zweckmäßig.According to a particularly preferred embodiment of the invention, the burners switched off are re-ignited after the regeneration phase via at least one pilot burner. Advantageously, the flame of the pilot burner and the burner is monitored. An adaptation of the heat output of the pilot burner to compensate for heat losses of the reactor is also appropriate.
In einer weiteren Ausführungsform der Erfindung werden die abgeschalteten Brenner mittels elektronischer Zündung wieder aktiviert.
Vorrichtungsseitig wird die gestellte Aufgabe dadurch gelöst, dass die Brenner im Reaktor über eine Abschaltvorrichtung verfügen.In a further embodiment of the invention, the deactivated burners are activated again by means of electronic ignition. On the device side, this object is achieved in that the burners have a shut-off device in the reactor.
Der Reaktor ist zweckmäßigerweise mit mindestens einem Pilotbrenner ebenso wie mit einer Überwachungseinrichtung für den Pilotbrenner und die Brenner ausgestattet. Eine Einrichtung zur Steuerung der Leistung des Pilotbrenners ist ebenfalls zweckmäßig. Gemäß einer weiteren Ausführungsform der Erfindung enthält die Vorrichtung eine Einrichtung zur elektronischen Neuzündung der Brenner.The reactor is expediently equipped with at least one pilot burner as well as with a pilot burner monitoring device and the burners. A means for controlling the performance of the pilot burner is also useful. According to a further embodiment of the invention, the device contains a device for the electronic reignition of the burner.
Mit der Erfindung gelingt es insbesonders unzulässig hohe Temperaturspitzen während der Regenerationsphase eines Katalysators in einem befeuerten Reaktor und die damit einhergehende Katalysatorschädigung zu vermeiden und die Lebensdauer des Katalysators zu erhöhen.
With the invention it is possible in particular to avoid excessively high temperature peaks during the regeneration phase of a catalyst in a fired reactor and the associated catalyst damage and to increase the service life of the catalyst.
Claims
1. Verfahren zur Regeneration eines Katalysators in einem Reaktor, der mit mindestens einem Brenner ausgestattet ist, dadurch gekennzeichnet, dass der Brenner während der Regenerationsphase abgeschaltet wird.A process for the regeneration of a catalyst in a reactor equipped with at least one burner, characterized in that the burner is switched off during the regeneration phase.
2. Verfahren nach Anspruch 1 , dadurch gekennzeichnet, dass Reaktor und Katalysator Bestandteil einer Anlage zur Herstellung von Olefinen aus kohlenwasser- stoffhaltigem Einsatz sind.2. The method according to claim 1, characterized in that the reactor and catalyst are part of a plant for the production of olefins from hydrocarbon-containing use.
3. Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass der Brenner nach der Regenerationsphase über mindestens einen eingebauten Pilotbrenner wieder gezündet wird.3. The method according to claim 1 or 2, characterized in that the burner is ignited after the regeneration phase via at least one built-in pilot burner again.
4. Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Flamme der/des Pilotbrenner/s und des Brenners überwacht werden.4. The method according to any one of claims 1 to 3, characterized in that the flame of the pilot burner / s and the burner are monitored.
5 Verfahren nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass der Wärmeverlust des Reaktors in der Regenerationsphase durch die entsprechend angepasste Wärmeleistung der/des Pilotbrenner/s kompensiert wird.5 Method according to one of claims 1 to 4, characterized in that the heat loss of the reactor in the regeneration phase is compensated by the correspondingly adapted heat output of the / the pilot burner / s.
6. Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass der Brenner über eine elektronische Zündeinrichtung neu gezündet wird.6. The method according to claim 1 or 2, characterized in that the burner is re-ignited via an electronic ignition device.
7. Vorrichtung zur Regeneration eines Katalysators in einem Reaktor, der mit mindestens einem Brenner ausgestattet ist, dadurch gekennzeichnet, dass sie eine Abschaltvorrichtung des Brenners aufweist.7. A device for regenerating a catalyst in a reactor which is equipped with at least one burner, characterized in that it comprises a shutdown device of the burner.
8. Vorrichtung nach Anspruch 7, dadurch gekennzeichnet, dass sie mindestens einen Pilotbrenner aufweist.8. Apparatus according to claim 7, characterized in that it comprises at least one pilot burner.
9. Vorrichtung nach Anspruch 8, dadurch gekennzeichnet, dass sie eine Überwachungseinrichtung der Flamme/n der/des Pilotbrenner/s und des Brenners aufweist.Device according to claim 8, characterized in that it comprises a monitoring device of the flame (s) of the pilot burner (s) and of the burner.
10. Vorrichtung nach Anspruch 8 oder 9, dadurch gekennzeichnet, dass sie eine Einrichtung zur Steuerung der Wärmeleistung der/des Pilotbrenner/s aufweist.10. Apparatus according to claim 8 or 9, characterized in that it comprises a device for controlling the heat output of the / of the pilot burner / s.
1 1. Vorrichtung nach Anspruch 7, dadurch gekennzeichnet, dass sie eine elektroni- sehe Zündvorrichtung des Brenners aufweist. 1 1. A device according to claim 7, characterized in that it comprises an electronic ignition device see the burner.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006017908A DE102006017908A1 (en) | 2006-04-18 | 2006-04-18 | Method and apparatus for controlled regeneration of a catalyst and reactor |
PCT/EP2007/053507 WO2007118825A1 (en) | 2006-04-18 | 2007-04-11 | Method and device for the controlled regeneration of a catalyst and a reactor |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2010313A1 true EP2010313A1 (en) | 2009-01-07 |
Family
ID=38222699
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07727975A Withdrawn EP2010313A1 (en) | 2006-04-18 | 2007-04-11 | Method and device for the controlled regeneration of a catalyst and a reactor |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP2010313A1 (en) |
KR (1) | KR20080112345A (en) |
CN (1) | CN101426570A (en) |
DE (1) | DE102006017908A1 (en) |
RU (1) | RU2008145106A (en) |
WO (1) | WO2007118825A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009012663B3 (en) * | 2009-03-13 | 2010-09-16 | Uhde Gmbh | Process and device for the uniform production of steam from the waste heat of an alkane dehydrogenation |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3087797A (en) * | 1961-04-24 | 1963-04-30 | Lummus Co | Regenerative furnace |
FR2511671A1 (en) * | 1981-08-18 | 1983-02-25 | Davy Mckee Ag | DEHYDROGENATION PROCESS |
ES2078688T3 (en) * | 1991-05-06 | 1995-12-16 | Inst Francais Du Petrole | PROCEDURE AND DEVICE FOR DEHYDROGENATION OF ALIPHATIC HYDROCARBONS IN OLEPHINIC HYDROCARBONS. |
DE102004059647B4 (en) * | 2004-12-10 | 2008-01-31 | Webasto Ag | Process for regenerating a reformer |
-
2006
- 2006-04-18 DE DE102006017908A patent/DE102006017908A1/en not_active Withdrawn
-
2007
- 2007-04-11 RU RU2008145106/15A patent/RU2008145106A/en not_active Application Discontinuation
- 2007-04-11 CN CNA2007800138471A patent/CN101426570A/en active Pending
- 2007-04-11 EP EP07727975A patent/EP2010313A1/en not_active Withdrawn
- 2007-04-11 WO PCT/EP2007/053507 patent/WO2007118825A1/en active Application Filing
- 2007-04-11 KR KR1020087026385A patent/KR20080112345A/en not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO2007118825A1 * |
Also Published As
Publication number | Publication date |
---|---|
RU2008145106A (en) | 2010-05-27 |
WO2007118825A1 (en) | 2007-10-25 |
KR20080112345A (en) | 2008-12-24 |
DE102006017908A1 (en) | 2007-10-25 |
CN101426570A (en) | 2009-05-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2653528C (en) | Catalytic hydrodeoxygenation of an oxygenate feedstock | |
Lloyd | Handbook of industrial catalysts | |
US8784645B2 (en) | Process for producing hydrocarbon oil | |
US8912374B2 (en) | Process for producing paraffinic hydrocarbons | |
JP5863878B2 (en) | Olefin production process | |
DE202009019033U1 (en) | Energy recovery | |
EP3938337B1 (en) | Method and installation for the production of one or more olefins | |
WO2010149585A1 (en) | System and process for treating gas from a biomass gasification | |
CA2833204A1 (en) | Catalytic process and apparatus for producing hydrocarbons from biooils | |
Singh et al. | Hydrodesulfurization of dibenzothiophene on NiMo/γ-Al2O3 washcoated monoliths | |
JP6336081B2 (en) | A cocurrent adiabatic reaction system for converting raw materials rich in triacylglycerol | |
WO2007118825A1 (en) | Method and device for the controlled regeneration of a catalyst and a reactor | |
CN102041047B (en) | Heavy oil hydrogenation modifying method | |
DE3608611C2 (en) | ||
EP2595944B1 (en) | Method for producing acetylene according to the sachsse-bartholome method | |
DE19620378C2 (en) | pyrolysis | |
US7741501B2 (en) | Process for heterogeneously catalyzed hydrogenation | |
DE102010042678B4 (en) | Apparatus and method for generating mechanical and electrical energy from a fuel | |
WO2018041728A1 (en) | Method and device for removing organic sulphur compounds from hydrogen-rich gases | |
EP2217685A1 (en) | Method for desulfurizing ingredient materials containing olefin | |
DE3422348C2 (en) | ||
WO2004078343A1 (en) | Method for regenerating re2o7 doped catalyst supports | |
DE1005219B (en) | Process for the oxidative regeneration of a catalyst loaded with carbon-containing deposits | |
EP2836572B1 (en) | Methods of deoxygenation of tall oil and production of polymerizable monomers therefrom | |
DE102004055826A1 (en) | Process and apparatus for fully hydrogenating a hydrocarbon stream |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20081118 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL BA HR MK RS |
|
17Q | First examination report despatched |
Effective date: 20090428 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 20091110 |