EP1961053A1 - Redox systems for stabilization and life extension of polymer semiconductors - Google Patents
Redox systems for stabilization and life extension of polymer semiconductorsInfo
- Publication number
- EP1961053A1 EP1961053A1 EP06829489A EP06829489A EP1961053A1 EP 1961053 A1 EP1961053 A1 EP 1961053A1 EP 06829489 A EP06829489 A EP 06829489A EP 06829489 A EP06829489 A EP 06829489A EP 1961053 A1 EP1961053 A1 EP 1961053A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- oxidizing
- reducing
- organic
- redox system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004065 semiconductor Substances 0.000 title description 10
- 230000006641 stabilisation Effects 0.000 title description 3
- 238000011105 stabilization Methods 0.000 title description 3
- 229920000642 polymer Polymers 0.000 title description 2
- 239000010410 layer Substances 0.000 claims abstract description 65
- 230000001590 oxidative effect Effects 0.000 claims abstract description 29
- 239000000654 additive Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 27
- 239000000758 substrate Substances 0.000 claims description 10
- 230000000996 additive effect Effects 0.000 claims description 9
- 239000002346 layers by function Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 150000004053 quinones Chemical class 0.000 claims description 3
- 125000002524 organometallic group Chemical group 0.000 claims description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 claims 1
- 239000011229 interlayer Substances 0.000 abstract description 5
- 238000012986 modification Methods 0.000 abstract description 5
- 230000004048 modification Effects 0.000 abstract description 5
- 238000010348 incorporation Methods 0.000 abstract description 4
- 239000008204 material by function Substances 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 239000002184 metal Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 229920000123 polythiophene Polymers 0.000 description 4
- 239000010949 copper Substances 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 125000000687 hydroquinonyl group Chemical class C1(O)=C(C=C(O)C=C1)* 0.000 description 3
- 229910001020 Au alloy Inorganic materials 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000002800 charge carrier Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 230000005669 field effect Effects 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000003353 gold alloy Substances 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 239000013110 organic ligand Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical class O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 239000002879 Lewis base Substances 0.000 description 1
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000013500 data storage Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 150000007527 lewis bases Chemical class 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
- H10K10/20—Organic diodes
- H10K10/23—Schottky diodes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/30—Doping active layers, e.g. electron transporting layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
- H10K10/40—Organic transistors
- H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
- H10K10/462—Insulated gate field-effect transistors [IGFETs]
- H10K10/464—Lateral top-gate IGFETs comprising only a single gate
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
- H10K10/40—Organic transistors
- H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
- H10K10/462—Insulated gate field-effect transistors [IGFETs]
- H10K10/466—Lateral bottom-gate IGFETs comprising only a single gate
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
- H10K10/40—Organic transistors
- H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
- H10K10/462—Insulated gate field-effect transistors [IGFETs]
- H10K10/468—Insulated gate field-effect transistors [IGFETs] characterised by the gate dielectrics
- H10K10/471—Insulated gate field-effect transistors [IGFETs] characterised by the gate dielectrics the gate dielectric comprising only organic materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
- H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
Definitions
- the invention relates to an organic electronic component with improved voltage stability and a method for producing the same, wherein the voltage stability in the device is improved by targeted addition of additives and / or by formation of interlayers.
- Organic electronic components are known not only in the form of the most advanced organic light emitting diode OLEDs, but also in the form of field effect.
- Transistors OFETs
- diodes diodes
- capacitors photocells
- DE 10033112 and DE 100 44 842 disclose both an organic field-effect transistor and an organic rectifier.
- a disadvantage of the known organic electronic components is that the functional materials used to construct the components only limited stability at higher voltages, due to the electrochemical degradation of the materials in the electric field, have.
- the object of the present invention is therefore to provide a functional material for an organic electronic component which ensures high stability even at higher voltages.
- the invention relates to an organic electronic component, at least one substrate, a lower electrode
- BEST ⁇ T1GUNGSKOPIE Layer an upper electrode layer and in between at least one layer of an organic functional material comprising, wherein at least in one layer a reducing, oxidizing and / or redox system is contained as an additive or as main component.
- organic electronic component all types of hitherto known or future components that comprise a functional layer of organic material, wherein the functionality of the functional layer is triggered by applying or generating a voltage.
- organic electronic components such as thin-film transistors (TFTs), FeId-effect transistors (OFETs), organic photosensitive components,
- Rectifiers, data storage devices, sensors, optocouplers, displays, solar cells and / or similar organic-based devices this implies all the materials that have been used in the last 10-15 years under a variety of names such as polymer semiconductors, inorganic-organic electronics, small molecules , were published as well as the newly emerging in the future for these applications materials, into consideration.
- the substrate it is possible to use glasses, in particular the thinnest glasses, quartz, foils, thin foils or others.
- the reducing, oxidizing and / or redox system according to the invention can also be present or only in the substrate.
- the lower / upper electrode layer of the component may also vary, it may be metallic and / or organic and / or organic-inorganic hybrid material, wherein the reducing, oxidizing and / or redox system according to a preferred embodiment of the invention also or may be contained only in one of the two and / or in both electrode layers and / or as an intermediate layer between the electrode layer and an adjacent layer.
- the reducing, oxidizing and / or redox system is contained in the organic functional layer arranged between the two electrode layers as an additive or in the form of an adjacent intermediate layer.
- the reducing, oxidizing and / or redox system is contained in an insulating intermediate layer of the organic component as an additive or as an adjacent intermediate layer.
- the reducing, oxidizing and / or redox system is contained, for example, when it is added to a, in turn, for example, from solution processable material in an amount of 1 to 50 wt% and particularly preferably from 1 to 25 wt% as an additive.
- the reducing, oxidizing and / or redox system is the main constituent of a layer when it is processable as an interlayer, for example in solution, and is contained in the organic electronic component as an intermediate layer or "interlayer" with a layer thickness of approximately 1 ⁇ m to 1 ⁇ m ,
- electrochemically stable redox systems have excess charge carriers in the electric field and especially at high voltages, traps and thus protects these materials from irreversible degradation.
- Preferred redox systems are, for example, organometallic ⁇ complexes in which, on the one hand, an interaction of the ⁇ electrons of the organic ligands with the unoccupied metal valence orbitals takes place and, on the other hand, an acceptor bond which can transfer charge from the filled metal d orbitals into unoccupied ligand orbitals.
- organometallic ⁇ complexes in which, on the one hand, an interaction of the ⁇ electrons of the organic ligands with the unoccupied metal valence orbitals takes place and, on the other hand, an acceptor bond which can transfer charge from the filled metal d orbitals into unoccupied ligand orbitals.
- These systems have many possibilities to stabilize additional positive or negative charges and are easily miscible with organic materials because of their large organic ligands. Examples of such systems are all substituted and unsubstituted metallocenes, which have already been successfully used here.
- a classic representative of metallocenes is ferrocene, which is inexpensive on the market.
- redox systems are the group of quinones and hydroquinones and their derivatives. These redox systems are also very stable and light with other organic solvents
- redox systems are, for example, Lewis acids and bases.
- the lowest layer 1 is the substrate layer, there is the lower electrode layer 2, for example of a metal and / or an alloy such as a gold alloy or gold, thereon the semiconductive layer 3 of polythiophene with a reducing, oxidizing and / or redox additive to the upper electrode layer 4, again of a metal or an alloy, for example of copper, follows.
- the layer structure is shown in FIG. 2: Below the substrate layer 1, for example made of a PET film, with the adjacent lower electrode layer 2, for example made of metal and / or an alloy, such as a gold alloy or pure gold, this layer is surrounded first of the semiconducting layer 3 comprising the modified material as described above, adjacent thereto, the insulating layer 5 followed by the upper electrode layer 4, again of a metal or an alloy, for example of copper.
- the substrate layer for example made of a PET film
- the adjacent lower electrode layer 2 for example made of metal and / or an alloy, such as a gold alloy or pure gold
- the insulator material for example PMMA or the substrate material, for example PET
- the reducing, oxidizing or redox system it is possible, when using polymeric electrode layers, for example from PEDOT or PANI, to stabilize one or both electrode materials additionally or in isolation also with the reducing, oxidizing and / or redox system.
- the reducing, oxidizing and / or redox systems can also, as an alternative or in addition to the modification of one or more materials, be introduced as intermediate layers into the organic electronic component.
- Intermediate layers are preferably layers which lie between functional layers of the organic electronic component.
- Figure 3 shows a structure for a transistor, such as that of Figure 2, wherein between the substrate 1 and the semiconducting layer 3, an intermediate layer 6 is arranged from a reducing, oxidizing and / or redox system.
- Figure 4 shows a similar structure as Figure 3 with the difference that here the intermediate layer 6 is arranged between the semiconductive and the insulating layer.
- FIG. 5 again shows the structure similar to FIG. 3 or FIG. 4, the intermediate layer 6 being arranged between the insulator layer 5 and the upper electrode layer 4 this time.
- FIGS. 6 and 7 show the possible arrangement of intermediate layers in organic electronic diodes:
- FIG. 6 shows the arrangement of the intermediate layer 6 in a diode, as is known from FIG. 1, between the substrate 1 and the semiconducting layer 3.
- FIG. 7 shows, in a similar diode structure, the arrangement of the intermediate layer 6 between the semiconducting layer 3 and the upper electrode layer 4.
- FIGS 8 and 9 show the measurement results made with diodes made of modified semiconductor material, in this case PHT mixed with 10-30% of a hydroquinone derivative.
- PHT modified semiconductor material
- FIG. 8 and 9 show the measurement results made with diodes made of modified semiconductor material, in this case PHT mixed with 10-30% of a hydroquinone derivative.
- the invention makes it possible for the first time to modify organic electronic components by modification with a reducing, oxidizing and / or redox system of one or more functional materials and / or by incorporation of one or more intermediate layers which contain a reducing, oxidizing and / or Redox systems include, especially in the area of higher voltages to stabilize.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Thin Film Transistor (AREA)
- Led Devices (AREA)
- Formation Of Insulating Films (AREA)
Abstract
The invention relates to an organic electronic component with better voltage stability, and to a method for its production, with the voltage stability of the device being improved by deliberate addition of additives and/or by formation of an interlayer. The invention for the first time makes it possible to stabilize organic electronic components by modification with a reducing, oxidizing and/or redox system comprising one and/or more functional materials and/or by incorporation of one or more intermediate layers which, as a major component, comprises a reducing, oxidizing and/or redox system, particularly in the area of relatively high voltages.
Description
Redoxsysteme zur Stabilisierung und Lebensdauerverlängerung von polymeren Halbleitern Redox systems for stabilization and lifetime extension of polymeric semiconductors
Organisches elektronisches Bauelement mit verbesserter Spannungsstabilität und Verfahren zur Herstellung dazuOrganic electronic device with improved voltage stability and method of manufacture therefor
Die Erfindung betrifft ein organisches elektronisches Bauelement mit verbesserter Spannungsstabilität und ein Verfahren zur Herstellung dazu, wobei durch gezielte Zugabe von Additiven und/oder durch Bildung von Interlayern die Spannungsstabilität im Device verbessert ist.The invention relates to an organic electronic component with improved voltage stability and a method for producing the same, wherein the voltage stability in the device is improved by targeted addition of additives and / or by formation of interlayers.
Bekannt sind organische elektronische Bauelemente nicht nur in Form der am weitesten entwickelten Organischen Leuchtdioden OLEDs, sondern auch in Form von Feld-Effekt Transistoren (OFETs) , Dioden, Kondensatoren und Photozellen hat die organische Elektronik längst in Forschung und Entwicklung Fuß ge- fasst . Beispielsweise sind aus der DE 10033112 und aus der DE 100 44 842 sowohl ein organischer Feld-Effekt-Transistor als auch ein organischer Gleichrichter bekannt.Organic electronic components are known not only in the form of the most advanced organic light emitting diode OLEDs, but also in the form of field effect. Transistors (OFETs), diodes, capacitors and photocells have long since entered the field of organic electronics in research and development. For example, DE 10033112 and DE 100 44 842 disclose both an organic field-effect transistor and an organic rectifier.
Nachteilig an den bekannten organischen elektronischen Bauteilen ist, dass die zum Aufbau der Bauelemente eingesetzten Funktionsmaterialien nur eine begrenzte Stabilität bei höheren Spannungen, bedingt durch die elektrochemische Degradation der Materialien im elektrischen Feld, haben.A disadvantage of the known organic electronic components is that the functional materials used to construct the components only limited stability at higher voltages, due to the electrochemical degradation of the materials in the electric field, have.
Aufgabe der vorliegenden Erfindung ist es daher, ein Funkti- onsmaterial für ein organisches elektronisches Bauelement zur Verfügung zu stellen, das eine hohe Stabilität auch bei höheren Spannungen gewährleistet ist.The object of the present invention is therefore to provide a functional material for an organic electronic component which ensures high stability even at higher voltages.
Gegenstand der Erfindung ist ein organisches elektronisches Bauelement, zumindest ein Substrat, eine untere Elektroden-The invention relates to an organic electronic component, at least one substrate, a lower electrode
BESTÄT1GUNGSKOPIE
Schicht, eine obere Elektrodenschicht und dazwischen zumindest eine Schicht aus einem organischen Funktionsmaterial umfassend, wobei zumindest in einer Schicht ein reduzierendes, oxi- dierendes und/oder Redox-System als Additiv oder als Hauptbe- standteil enthalten ist.BESTÄT1GUNGSKOPIE Layer, an upper electrode layer and in between at least one layer of an organic functional material comprising, wherein at least in one layer a reducing, oxidizing and / or redox system is contained as an additive or as main component.
Als organisches elektronisches Bauelement können alle Arten der bislang bekannten oder zukünftigen Bauelemente, die eine Funktionsschicht aus organischem Material umfassen, wobei die Funktionalität der Funktionsschicht durch Anlegen oder Erzeugen einer Spannung ausgelöst wird.As an organic electronic component, all types of hitherto known or future components that comprise a functional layer of organic material, wherein the functionality of the functional layer is triggered by applying or generating a voltage.
Insbesondere kommen dabei organische elektronische Bauelemente wie Dünnfilmschichttransistoren (TFTs) , FeId-Effekt- Transistoren (OFETs) organische photosensitive Bauelemente,In particular, organic electronic components such as thin-film transistors (TFTs), FeId-effect transistors (OFETs), organic photosensitive components,
Gleichrichter, Datenspeicher, Sensoren, Optokoppler, Displays, Solarzellen und/oder ähnliche Bauelemente auf organischer Basis - dies impliziert alle Materialien, die in den letzten 10- 15 Jahren unter verschiedensten Bezeichnungen wie polymer- Halbleiter, anorganisch-organische Elektronik, small molecu- les, publiziert wurden ebenso wie die zukünftig für diese Einsatzgebiete neu herauskommenden Materialien, in Betracht.Rectifiers, data storage devices, sensors, optocouplers, displays, solar cells and / or similar organic-based devices - this implies all the materials that have been used in the last 10-15 years under a variety of names such as polymer semiconductors, inorganic-organic electronics, small molecules , were published as well as the newly emerging in the future for these applications materials, into consideration.
Als Substrat werden dabei verschiedene Materialien eingesetzt, es können Gläser, insbesondere dünnste Gläser, Quarz, Folien, dünne Folien oder anderes eingesetzt werden. Das reduzierende, oxidierende und/oder Redox-System gemäß der Erfindung kann auch oder nur im Substrat enthalten sein.Various materials are used as the substrate, it is possible to use glasses, in particular the thinnest glasses, quartz, foils, thin foils or others. The reducing, oxidizing and / or redox system according to the invention can also be present or only in the substrate.
Die untere/obere Elektrodenschicht des Bauteils kann ebenso variieren, sie kann metallisch und/oder aus organischem und/oder aus organisch-anorganischem Hybrid- Material sein, wobei das reduzierende, oxidierende und/oder Redox-System nach einer bevorzugten Ausführungsform der Erfindung auch oder nur in einer der beiden und/oder in beiden Elektrodenschichten und/oder als Zwischenschicht zwischen der Elektrodenschicht und einer angrenzenden Schicht enthalten sein kann.
Nach einer bevorzugten Ausführungsform ist das reduzierende, oxidierende und/oder Redox-System in der zwischen den beiden Elektrodenschichten angeordneten organischen Funktionsschicht als Additiv oder in Form einer angrenzenden Zwischenschicht enthalten.The lower / upper electrode layer of the component may also vary, it may be metallic and / or organic and / or organic-inorganic hybrid material, wherein the reducing, oxidizing and / or redox system according to a preferred embodiment of the invention also or may be contained only in one of the two and / or in both electrode layers and / or as an intermediate layer between the electrode layer and an adjacent layer. According to a preferred embodiment, the reducing, oxidizing and / or redox system is contained in the organic functional layer arranged between the two electrode layers as an additive or in the form of an adjacent intermediate layer.
Nach einer weiteren bevorzugten Ausführungsform ist das reduzierende, oxidierende und/oder Redox-System in einer isolierenden Zwischenschicht des organischen Bauteils als Additiv oder als angrenzende Zwischenschicht enthalten.According to a further preferred embodiment, the reducing, oxidizing and / or redox system is contained in an insulating intermediate layer of the organic component as an additive or as an adjacent intermediate layer.
Als Additiv ist das reduzierende, oxidierende und/oder Redox- System beispielsweise dann enthalten, wenn es zu einem, wiederum beispielsweise aus Lösung prozessierbarem Material in einer Menge von 1 bis 50Gew% und insbesondere bevorzugt von 1 bis 25 Gew% als Additiv zugegeben wird.As an additive, the reducing, oxidizing and / or redox system is contained, for example, when it is added to a, in turn, for example, from solution processable material in an amount of 1 to 50 wt% and particularly preferably from 1 to 25 wt% as an additive.
Das reduzierende, oxidierende und/oder Redox-System ist der Hauptbestandteil einer Schicht, wenn es als Interlayer, bei- spielsweise in Lösung prozessierbar ist und mit einer Schichtdicke von ungefähr lnm bis lμm als Zwischenschicht oder „Interlayer" in dem organischen elektronischen Bauteil enthalten ist.The reducing, oxidizing and / or redox system is the main constituent of a layer when it is processable as an interlayer, for example in solution, and is contained in the organic electronic component as an intermediate layer or "interlayer" with a layer thickness of approximately 1 μm to 1 μm ,
Als reduzierendes, oxidierendes und/oder Redox-System kommen zunächst alle im Zusammenhang mit den anderen Materialien stabilen und/oder mischbaren bekannten reduzierenden, oxidieren- den und/oder Redox-Systeme, also chemische Verbindungen, die sowohl Elektronen aufnehmen als auch abgeben können, in Frage. Im Gegensatz zu den bisher üblicherweise eingesetzten Interlayer die entweder Loch- oder Elektronen-stabilisierend wirken, also wie Puffer für Löcher oder Elektronen einsetzbar sind, wirkt die Einführung z.B. eines Redox-Systems auf beide Ladungsträger, Löcher wie Elektronen, stabilisierend.As a reducing, oxidizing and / or redox system, first of all all known reducing, oxidizing and / or redox systems which are stable and / or miscible in connection with the other materials, ie chemical compounds which can absorb and release both electrons, in question. In contrast to the hitherto commonly used interlayers which either have hole- or electron-stabilizing action, ie how buffers can be used for holes or electrons, the introduction has an effect, for example. of a redox system on both charge carriers, holes such as electrons, stabilizing.
Der Vorteil elektrochemisch stabiler Redox-Systeme ist auch, dass sie Überschussladungsträger, die im elektrischen Feld und
vor allem bei hohen Spannungen gebildet werden, abfängt und somit diese Materialien vor irreversibler Degradation schützt.The advantage of electrochemically stable redox systems is also that they have excess charge carriers in the electric field and especially at high voltages, traps and thus protects these materials from irreversible degradation.
Bevorzugte Redox-Systeme sind beispielsweise metallorganische π-Komplexe, bei denen zum einen eine Wechselwirkung der π- Elektronen der organischen Liganden mit den unbesetzten Metallvalenzorbitalen stattfindet und zum anderen eine Akzeptorbindung, die Ladung aus den gefüllten Metall d-Orbitalen in unbesetzte Ligandenorbitale übertragen kann. Diese Systeme ha- ben viele Möglichkeiten, zusätzliche positive oder negative Ladungen zu stabilisieren und sind wegen ihrer großen organischen Liganden problemlos mit organischen Materialien mischbar. Beispiele solcher Systeme sind alle substituierten und unsubstituierten Metallocene, die hier schon erfolgreich ein- gesetzt wurden. Ein klassischer Vertreter der Metallocene ist Ferrocen, das kostengünstig auf dem Markt ist.Preferred redox systems are, for example, organometallic π complexes in which, on the one hand, an interaction of the π electrons of the organic ligands with the unoccupied metal valence orbitals takes place and, on the other hand, an acceptor bond which can transfer charge from the filled metal d orbitals into unoccupied ligand orbitals. These systems have many possibilities to stabilize additional positive or negative charges and are easily miscible with organic materials because of their large organic ligands. Examples of such systems are all substituted and unsubstituted metallocenes, which have already been successfully used here. A classic representative of metallocenes is ferrocene, which is inexpensive on the market.
Eine weitere Gruppe der Redox-Systeme bilden die Gruppe der Chinone und Hydrochinone sowie deren Derivate. Diese Redoxsy- steme sind auch sehr stabil und leicht mit anderen organischenAnother group of redox systems are the group of quinones and hydroquinones and their derivatives. These redox systems are also very stable and light with other organic solvents
Materialien mischbar. Durch die aromatische Struktur mit den beiden para-ständigen elektronegativen Elementen lassen sich auch hier Ladungen gut stabilisieren. Diese Funktionalität der Chinone kann unter Umständen durch höher kondensierte aromati- sehe Systeme noch verstärkt werden.Materials mixable. The aromatic structure with the two para-electronegative elements can also stabilize charges well here. This functionality of quinones may be enhanced by higher condensed aromatic systems.
Weiter mögliche Redoxsysteme sind beispielsweise Lewis Säuren und Basen.Further possible redox systems are, for example, Lewis acids and bases.
Im Folgenden wird die Erfindung noch anhand beispielhafterIn the following, the invention will be described by way of example
Ausführungsformen näher erläutert:Embodiments explained in more detail:
Beispiel 1 :Example 1 :
Modifizieren des Halbleitermaterials bei einer organischen elektronischen Diode:Modifying the semiconductor material in an organic electronic diode:
Zur Herstellung der Halbleiterlösung werden 70-90 Gew% polymerer Feststoff (Polythiophen, PAT) mit 10-30Gew% eines Hydro-
chinon-Derivates gemischt und in Lösung gebracht . Die Dioden werden dann mit einem Standardprozess prozessiert . (Elektroden: Au/Cu; Halbleiter: Polythiophen; Dioden auf PET-Folie)To prepare the semiconductor solution, 70-90% by weight of polymeric solid (polythiophene, PAT) with 10-30% by weight of a hydro- mixed chinon derivative and brought into solution. The diodes are then processed using a standard process. (Electrodes: Au / Cu, semiconductors: polythiophene, diodes on PET film)
Dabei wird ein Schichtaufbau, wie in Figur 1 gezeigt, realisiert :In this case, a layer structure as shown in FIG. 1 is realized:
Unterste Schicht 1 ist die Substratschicht, darauf liegt die untere Elektrodenschicht 2, beispielsweise aus einem Metall und/oder einer Legierung wie einer Goldlegierung oder Gold, darauf die halbleitende Schicht 3 aus Polythiophen mit einem reduzierenden, oxidierenden und/oder Redox-Additiv auf die die obere Elektrodenschicht 4, wiederum aus einem Metall oder einer Legierung, beispielsweise aus Kupfer, folgt.The lowest layer 1 is the substrate layer, there is the lower electrode layer 2, for example of a metal and / or an alloy such as a gold alloy or gold, thereon the semiconductive layer 3 of polythiophene with a reducing, oxidizing and / or redox additive to the upper electrode layer 4, again of a metal or an alloy, for example of copper, follows.
Beispiel 2 :Example 2:
Modifizieren des Halbleitermaterials bei einem organischen FeId-Effekt-Transistor:Modifying the Semiconductor Material in an Organic FeId Effect Transistor:
Zur Herstellung der Halbleiterlösung werden 70-90Gew% Feststoff (Polythiophen, PAT) mit 10-30Gew% eines Hydrochinon- Derivates gemischt und in Lösung gebracht. Die Transistoren werden wieder mit einem Standardprozess prozessiert.To prepare the semiconductor solution, 70-90 wt% solids (polythiophene, PAT) are mixed with 10-30 wt% of a hydroquinone derivative and dissolved. The transistors are processed again with a standard process.
Der Schichtaufbau ist in Figur 2 gezeigt: Unten die Substrat- Schicht 1, beispielsweise aus einer PET-Folie, mit der angrenzenden unteren Elektrodenschicht 2, beispielsweise aus Metall und/oder einer Legierung, wie einer Goldlegierung oder reines Gold, diese Schicht ist umgeben zunächst von der halbleitenden Schicht 3, die das wie oben beschriebenen modifizierten Material umfasst, daran angrenzend die isolierende Schicht 5 auf die die obere Elektrodenschicht 4, , wiederum aus einem Metall oder einer Legierung, beispielsweise aus Kupfer, folgt.
Beispiel 3 :The layer structure is shown in FIG. 2: Below the substrate layer 1, for example made of a PET film, with the adjacent lower electrode layer 2, for example made of metal and / or an alloy, such as a gold alloy or pure gold, this layer is surrounded first of the semiconducting layer 3 comprising the modified material as described above, adjacent thereto, the insulating layer 5 followed by the upper electrode layer 4, again of a metal or an alloy, for example of copper. Example 3:
Modifizierung anderer Funktionsschichten außer der Halbleiter- Schicht und/oder des Substratmaterials zur Anwendung in organischen elektronischen Bauteilen.Modification of functional layers other than the semiconductor layer and / or the substrate material for use in organic electronic devices.
Zur Stabilisierung der Funktionsschichten zur Anwendung in organischen elektronischen Bauteilen und/oder zur Anpassung der jeweiligen Energieniveaus zueinander können auch das Isolatormaterial, beispielsweise PMMA oder das Substratmaterial, beispielsweise PET, mit dem reduzierenden, oxidierenden oder Re- dox-System modifiziert werden. Des Weiteren besteht die Möglichkeit, bei Verwendung polymerer Elektrodenschichten, beispielsweise aus PEDOT oder PANI, eine oder beide Elektrodenmaterialien ergänzend oder in Alleinstellung ebenfalls mit dem reduzierenden, oxidierenden und/oder Redox-System stabilisieren.To stabilize the functional layers for use in organic electronic components and / or to adapt the respective energy levels to one another, it is also possible to modify the insulator material, for example PMMA or the substrate material, for example PET, with the reducing, oxidizing or redox system. Furthermore, it is possible, when using polymeric electrode layers, for example from PEDOT or PANI, to stabilize one or both electrode materials additionally or in isolation also with the reducing, oxidizing and / or redox system.
Beispiel 4:Example 4:
Des Weiteren können die reduzierenden, oxidierenden und/oder Redox-Systeme auch, alternativ oder ergänzend zu der Modifikation einer oder mehrerer Materialien, als Zwischenschichten in das organische elektronische Bauteil eingebracht werden. Als Zwischenschichten werden dabei bevorzugt Schichten bezeichnet, die zwischen funktionellen Schichten des organischen elektronischen Bauteils liegen.Furthermore, the reducing, oxidizing and / or redox systems can also, as an alternative or in addition to the modification of one or more materials, be introduced as intermediate layers into the organic electronic component. Intermediate layers are preferably layers which lie between functional layers of the organic electronic component.
Beispielsweise können folgende Zwischenschichten eingeführt werden wie in den Figuren 3 bis 7 beispielhaft gezeigt .For example, the following intermediate layers can be introduced as shown by way of example in FIGS. 3 to 7.
Figur 3 zeigt einen Aufbau für einen Transistor, wie dem aus Figur 2, wobei zwischen das Substrat 1 und der halbleitenden Schicht 3 eine Zwischenschicht 6 aus einem reduzierenden, oxidierenden und/oder Redox-System angeordnet ist.
Figur 4 zeigt einen ähnlichen Aufbau wie Figur 3 mit dem Unterschied, dass hier die Zwischenschicht 6 zwischen der halbleitenden und der isolierenden Schicht angeordnet ist.Figure 3 shows a structure for a transistor, such as that of Figure 2, wherein between the substrate 1 and the semiconducting layer 3, an intermediate layer 6 is arranged from a reducing, oxidizing and / or redox system. Figure 4 shows a similar structure as Figure 3 with the difference that here the intermediate layer 6 is arranged between the semiconductive and the insulating layer.
Figur 5 zeigt schließlich wieder den Aufbau ähnlich Figur 3 oder Figur 4, wobei die Zwischenschicht 6 diesmal zwischen der Isolatorschicht 5 und der oberen Elektrodenschicht 4 angeordnet ist.Finally, FIG. 5 again shows the structure similar to FIG. 3 or FIG. 4, the intermediate layer 6 being arranged between the insulator layer 5 and the upper electrode layer 4 this time.
Figuren 6 und 7 zeigen die mögliche Anordnung von Zwischenschichten bei organischen elektronischen Dioden:FIGS. 6 and 7 show the possible arrangement of intermediate layers in organic electronic diodes:
Figur 6 zeigt die Anordnung der Zwischenschicht 6 in einer Diode, wie sie aus Figur 1 bekannt ist, zwischen dem Substrat lund der halbleitenden Schicht 3.FIG. 6 shows the arrangement of the intermediate layer 6 in a diode, as is known from FIG. 1, between the substrate 1 and the semiconducting layer 3.
Figur 7 schließlich zeigt in einem ähnlichen Diodenaufbau die Anordnung der Zwischenschicht 6 zwischen der halbleitenden Schicht 3 und der oberen Elektrodenschicht 4.Finally, FIG. 7 shows, in a similar diode structure, the arrangement of the intermediate layer 6 between the semiconducting layer 3 and the upper electrode layer 4.
Obwohl in den Figuren und den Beispielen immer nur die Modifikation eines Schichtmaterials oder der Einbau einer Zwischenschicht aus reduzierendem, oxidierendem und/oder Redox-System beschrieben und gezeigt ist, so ist doch ein wesentlicher Aspekt der Erfindung, dass die Zugabe eines reduzierenden, oxidierenden und/oder Redox-Systems zu einem Material und/oder der Einbau einer reduzierenden, oxidierenden und/oder Redox- Systems enthaltenden Zwischenschicht beliebig kombinierbar sind. Es können mehrere Zwischenschichten aus mehreren redu- zierenden, oxidierenden und/oder Redox-Systemen und/oder mehrere mit gegebenenfalls verschiedenen reduzierenden, oxidierenden und/oder Redox-Systeme modifizierte Materialschichten im organischen elektronischen Bauteil nebeneinander vorliegen.Although in the figures and the examples always only the modification of a layer material or the incorporation of an intermediate layer of reducing, oxidizing and / or redox system described and shown, it is an essential aspect of the invention that the addition of a reducing, oxidizing and / or redox system to a material and / or the incorporation of a reducing, oxidizing and / or redox system-containing intermediate layer can be combined as desired. Several intermediate layers of a plurality of reducing, oxidizing and / or redox systems and / or a plurality of material layers modified with optionally different reducing, oxidizing and / or redox systems may be present side by side in the organic electronic component.
Figuren 8 und 9 zeigen die Messergebnisse, die mit Dioden, die aus modifiziertem Halbleitermaterial, in dem Fall aus PHT gemischt mit 10-30% eines Hydrochinon-Derivates, gefertigt wurden.
Hier ist ganz deutlich die Stabilisierung der Diode in einem Villard-Gleichrichter bis zu 16 V EingangsSpannung über mehrere Cyclen zu erkennen.Figures 8 and 9 show the measurement results made with diodes made of modified semiconductor material, in this case PHT mixed with 10-30% of a hydroquinone derivative. Here is clearly the stabilization of the diode in a Villard rectifier to recognize up to 16 V input voltage over several cycles.
Die Ergebnisse einer solchen Diode, die in einen polymeren, einfachen Gleichrichter eingebaut wurde ist in Figur 9 zu sehen.The results of such a diode incorporated in a polymeric simple rectifier can be seen in FIG.
Durch die Erfindung ist es erstmals möglich, organische elek- tronische Bauteile durch Modifikation mit einem reduzierenden, oxidierenden und/oder Redox-System eines oder mehrerer Funktionsmaterialien und/oder durch Einbau einer oder mehrerer Zwischenschichten, die als Hauptbestandteil ein reduzierendes, oxidierendes und/oder Redox-System umfassen, vor allem im Be- reich höherer Spannungen zu stabilisieren.
The invention makes it possible for the first time to modify organic electronic components by modification with a reducing, oxidizing and / or redox system of one or more functional materials and / or by incorporation of one or more intermediate layers which contain a reducing, oxidizing and / or Redox systems include, especially in the area of higher voltages to stabilize.
Claims
1. Organisches elektronisches Bauelement, zumindest ein Sub- strat, eine untere Elektrodenschicht, eine obere Elektrodenschicht und dazwischen zumindest eine Schicht aus einem organischen Funktionsmaterial umfassend, wobei zumindest in einer Schicht ein reduzierendes, ein oxidierendes und/oder ein Re- dox-Material als Additiv oder als Hauptbestandteil enthalten ist.1. organic electronic component, at least one substrate, a lower electrode layer, an upper electrode layer and between at least one layer of an organic functional material comprising at least in one layer, a reducing, an oxidizing and / or redox material Additive or as a main component is included.
2. Bauelement nach Anspruch 1, bei dem das reduzierende, oxi- dierende und/oder Redox-Material zumindest eine Verbindung aus der Klasse der Chinone/Hydrochinone und/oder eine Verbindung aus der Klasse der metallorganischen π-Komplexe, insbesondere der Metallocene, umfasst .2. Component according to claim 1, wherein the reducing, oxidizing and / or redox material comprises at least one compound from the class of quinones / hydroquinones and / or a compound from the class of organometallic π-complexes, in particular the metallocenes ,
3. Bauelement nach einem der Ansprüche 1 oder 2, bei dem das reduzierende, oxidierende und/oder Redox-System als Additiv zur Modifikation der organischen halbleitenden Funktionsschicht eingesetzt ist.3. Component according to one of claims 1 or 2, wherein the reducing, oxidizing and / or redox system is used as an additive for modifying the organic semiconductive functional layer.
4. Bauelement nach einem der Ansprüche 1 bis 3, wobei das reduzierende, oxidierende und/oder Redox-System in einer Zwi- schenschicht zwischen einer der Elektrodenschichten und der isolierenden oder der halbleitenden Funktionsschicht des organischen elektronischen Bauelements angeordnet ist.4. The component according to one of claims 1 to 3, wherein the reducing, oxidizing and / or redox system is arranged in an intermediate layer between one of the electrode layers and the insulating or the semiconducting functional layer of the organic electronic component.
5. Verfahren zur Herstellung eines organischen elektronischen Bauelements, bei dem auf eine SubstratSchicht eine untere und eine obere Elektrodenschicht und dazwischen zumindest eine organische Funktionsschicht angeordnet wird, wobei zumindest einer der Schichten ein reduzierendes, oxidierendes und/oder Redox System als Additiv zur Modifikation des Schichtmaterials zugesetzt wird und/oder zumindest eine zusätzliche Zwischenschicht aus einem reduzierenden, oxidierenden und/oder Redox- System umfassenden Material gebildet wird. 5. A process for the production of an organic electronic component, in which a lower and an upper electrode layer and at least one organic functional layer are arranged therebetween, wherein at least one of the layers comprises a reducing, oxidizing and / or redox system as an additive for modifying the layer material is added and / or at least one additional intermediate layer of a reducing, oxidizing and / or redox system comprising material is formed.
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DE102010008469A1 (en) | 2010-02-18 | 2012-02-16 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | New copolythiophene containing thiophene integrated in the polymer chain, useful in the form of a field effect transistor, a diode, a photovoltaic cell, an integrated circuit, a capacitor or a sensor |
DE102010047086A1 (en) | 2010-10-01 | 2012-04-05 | Heraeus Clevios Gmbh | Layered structures with improved electrical characteristics including PEDOT / PSS and a stabilizer |
US9336921B2 (en) | 2013-12-17 | 2016-05-10 | Dow Global Technologies Llc | Electrically conducting composites, methods of manufacture thereof and articles comprising the same |
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US7655961B2 (en) * | 2003-10-02 | 2010-02-02 | Maxdem Incorporated | Organic diodes and materials |
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