EP1948727B1 - Device for illuminating using blue, green, yellow, or red light emitting diodes - Google Patents
Device for illuminating using blue, green, yellow, or red light emitting diodes Download PDFInfo
- Publication number
- EP1948727B1 EP1948727B1 EP06819357A EP06819357A EP1948727B1 EP 1948727 B1 EP1948727 B1 EP 1948727B1 EP 06819357 A EP06819357 A EP 06819357A EP 06819357 A EP06819357 A EP 06819357A EP 1948727 B1 EP1948727 B1 EP 1948727B1
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- European Patent Office
- Prior art keywords
- light
- led
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V3/00—Globes; Bowls; Cover glasses
- F21V3/04—Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
- F21K9/00—Light sources using semiconductor devices as light-generating elements, e.g. using light-emitting diodes [LED] or lasers
- F21K9/60—Optical arrangements integrated in the light source, e.g. for improving the colour rendering index or the light extraction
- F21K9/64—Optical arrangements integrated in the light source, e.g. for improving the colour rendering index or the light extraction using wavelength conversion means distinct or spaced from the light-generating element, e.g. a remote phosphor layer
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V9/00—Elements for modifying spectral properties, polarisation or intensity of the light emitted, e.g. filters
- F21V9/08—Elements for modifying spectral properties, polarisation or intensity of the light emitted, e.g. filters for producing coloured light, e.g. monochromatic; for reducing intensity of light
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F13/00—Illuminated signs; Luminous advertising
- G09F13/04—Signs, boards or panels, illuminated from behind the insignia
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21Y—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES F21K, F21L, F21S and F21V, RELATING TO THE FORM OR THE KIND OF THE LIGHT SOURCES OR OF THE COLOUR OF THE LIGHT EMITTED
- F21Y2115/00—Light-generating elements of semiconductor light sources
- F21Y2115/10—Light-emitting diodes [LED]
Definitions
- the invention relates to a device for lighting with blue, green, yellow or red light emitting diodes (LEDs), consisting essentially of an LED light source and a light scattering cover of colored plastic associated with the light source.
- LEDs blue, green, yellow or red light emitting diodes
- Illuminable devices eg. B. for billboards, consisting essentially of a light source and the light source associated light-diffusing cover of colored plastic are known in principle (sz B. JP 61159440 ).
- incandescent or fluorescent tubes are used as light sources, which have a good luminosity and emit a wide spectrum of light. Due to the wide spectrum of light corresponding colored plastic covers appear in unlit condition, ie z. B. in daylight, in the same color impression, which can be perceived even with backlighting by means of said light sources.
- Light-emitting diodes are of significantly lower luminance compared to light sources such as incandescent lamps or fluorescent tubes. However, colored light-emitting diodes are nevertheless very noticeable in the dark, since they radiate a substantially or almost monochromatic light, which in turn is relatively intense in the respective wavelength range. Corresponding colored LEDs are available from several manufacturers z. B. in the colors red, green, blue and yellow available.
- WO 03/052315 describes an illuminable device consisting essentially of a light source and a light-diffusing cover made of colored plastic associated with the light source, characterized in that the light source consists of one or more light-emitting diodes (LEDs) emitting a colored substantially monochromatic light and the associated light-scattering Cover at the wavelength of the relative energy maximum of the LED has a transmission (DIN 5036) of at least 35% and a reflection (DIN 5036) of at least 15%.
- LEDs light-emitting diodes
- the coloring of the light-scattering cover takes place by means of non-fluorescent dyes or colorants.
- the device allows optically in about the same color impression in incident light, so z. B. in daylight, as well as fluoroscopy.
- the device also allows devices with a smaller overall depth and lower power consumption compared to conventionally illuminated devices due to the use of LEDs.
- Illuminable devices according to the WO 03/052315 allow optically in about the same color impression in reflected light, so z. B. in daylight, as well as fluoroscopy. It has been seen as an object the devices according to the WO 03/052315 develop so that the color impression appears even more brilliant in daylight, as well as in fluoroscopy, without there being noticeable deviations of the two color impressions.
- the task is solved by a
- the invention is based on the transmission and the reflection of the light-diffusing plastic cover similar to that in the WO 03/052315 described, so adapt to the monochromatic light of the LED used that almost the same color impression can be obtained in reflected light and in transmitted light.
- the color location of the transmission of the light-scattering cover will simplify with the color location of the LED (x LED / y LED ) equated, since the light of the LED is monochromatic and is virtually unchanged by the light-scattering cover.
- the invention achieves, by the addition of the fluorescent dye with simultaneous adjustment of Basiseinfärbung, one on the WO 03/052315
- a person skilled in the art can make the appropriate adjustments to the coloring.
- Corresponding advertising or information boards appear optically approximately the same both during the day and in the backlit state.
- the reflection values are generally significantly increased and always closer to the corresponding color location of the LED, while the values for the transmission and its color location are not or only slightly changed.
- the visually perceived appearance is noticeably brighter, more brilliant, and therefore more attractive to the user, both during the day and at night.
- the inventive equipment it is possible to make the device appear much brighter and more brilliant with the same power consumption or reduced power consumption at least an equivalent effect as that of WO 03/052315 to achieve.
- the inventively illuminable devices require smaller depths, as LEDs are smaller than corresponding incandescent or fluorescent tubes. Opposite the WHERE 03/052315 It is possible to reduce the number of LEDs included, making complex shapes even easier to realize.
- the power consumption is lower, with almost the same visibility in the backlit state. Since LEDs can be operated with low voltages, the electrical safety of the devices according to the invention is considered to be higher or easier to ensure. The maintenance is also lower, since LEDs usually have to be replaced less often than other bulbs, such. B. fluorescent tubes.
- the invention is based on the amount of the difference of the x-value of the light-diffusing cover with the x-value of the LED and the amount of the difference of the y-value of the light-diffusing cover with the y-value of the LED.
- illuminable devices which convey a largely coincident and at the same time very brilliant color impression in the unlit and in the illuminated state.
- the invention relates to an illuminable device comprising a light source in the form of one or more colored light-emitting diodes (LEDs) and a light-scattering cover of colored plastic associated with the light source.
- the device thus consists essentially of the components indispensable for the function, namely the light source and the light-scattering cover of colored plastic associated with the light source.
- uncritical elements such as a frame, housing or fasteners, etc. may be present.
- the device may be designed such that the LEDs and the light-diffusing cover are associated with each other at a distance of 3 to 12, preferably 4 to 10 cm. At this distance a good illumination is achieved. If the distance is too short, the position of the LED will be visible as a bright spot. If the distance is too great, the brightness decreases too much.
- the LEDs can z. B. in a box or frame, of the light-diffusing cover, z. B. in plate form, is covered.
- the cover may be provided with an information-bearing layer, e.g. As a film provided or even already have the form of information, for. B. in letter or number form.
- the following general example illustrates a device according to the invention for yellow LED lighting and is mutatis mutandis applicable to blue, green or red LED lighting.
- the amounts x diff and y diff can be calculated for other colors.
- the light source consists of one or more or a plurality of colored light-emitting diodes (LEDs). Optionally, LEDs of different colors can be used simultaneously.
- Colored LEDs are of significantly lower luminance compared to light sources such as incandescent or fluorescent tubes. However, colored LEDs are still very noticeable in the dark, as they radiate a substantially or almost monochromatic light, which in the respective. Wavelength range is again relatively intense. Corresponding colored LEDs are available from several manufacturers z. B. in the colors red, green, blue and yellow available. Unsuitable for the purposes of the invention are white LEDs, since they do not produce a nearly monochromatic but a broad spectrum of light, similar to a conventional light bulb.
- Colored LEDs emit almost or substantially monochromatic light.
- the term "almost or substantially" monochromatic light is meant to express that the light of commercially available colored LEDs is simplified and often referred to as monochromatic in comparison to other normal light sources, but strictly speaking it is not.
- the wavelength spectrum of a colored LED has a narrow, peak-like distribution.
- adjacent wavelengths with lower intensity are always found.
- One skilled in the art would therefore call the light of colored LEDs almost or substantially monochromatic.
- the color of the LED depends on the wavelength of its relative energy maximum. This relative energy maximum can z. B. be determined spectrophotometrically and drawn in a wavelength spectrum. You can see the light source z. B. in a Ulbricht'sche ball (see DIN 5036) bring and measure the exiting light. The highest point (peak) of the curve indicates the wavelength of the relative energy maximum.
- LEDs depends on the size of the device, the luminosity of the LEDs used and the overall desired brightness of the device in the transilluminated state. LEDs are z. B as modules of 4 LEDs in each a holder available, from which optionally a variety can be installed in the device.
- LEDs Light emitting diodes
- Suitable LEDs are z. For example, commercially available red, blue, yellow or green LEDs.
- a red LED has a relative energy maximum in the range of about 610 to 640 nm.
- the red LED (Osram LM03-BA) has z. B. a relative energy maximum at about 620 nm.
- a blue LED has a relative energy maximum in the range of about 440 to 500 nm.
- the blue LED (Osram LM03-BB) has z.
- B is an energy maximum at about 460 nm.
- the blue LED (ESS Blue) has z.
- B is an energy maximum at about 475 nm.
- a yellow LED has a relative energy maximum in the range of about 570 to 610 nm.
- the yellow LED (Osram LM03-BY) has z.
- B is an energy maximum at about 590 nm.
- a green LED has a relative energy maximum in the range of approximately 500 to 540 nm.
- the green LED (Osram LM03-BT) has z.
- B is an energy maximum at about 520 nm.
- the light-diffusing plastic cover has a base coloring, ie a coloring by means of one or more non-fluorescent dyes.
- a base coloring ie a coloring by means of one or more non-fluorescent dyes.
- This type of coloring is known in principle WO 03/052315 , Not however, in the inventive adaptation described herein in connection with a fluorescent dye or fluorescent dyes.
- WO 03/052315 has a light-scattering cover, which is provided with a base coloring by means of one or more non-fluorescent dyes, at the wavelength of the relative energy maximum of the LED used a transmission (DIN 5036) of at least 35% and a reflection (DIN 5036) of at least 15% ,
- base staining with respect to WO 03/052315 adapt.
- the plastic light-diffusing cover contains a base stain, which is preferably adapted due to the presence of the fluorescent dye over a base stain of the prior art.
- the adapted basic coloring with the associated fluorescent dye causes as a dye mixture that the light-scattering cover at the wavelength of the energy maximum of the LED used has a reflection (DIN 5036), which is at least 28, preferably at least 30, more preferably at least 35% and at least at least 50% above the value that would be achieved with a (non-matched) base stain without a fluorescent dye.
- a reflection DIN 5036
- the color appears much more brilliant than with a coloring according to the WO 03/052315 is reachable.
- the color location of the reflection is closer to the color locus of the LED than to a corresponding cover of the prior art.
- Suitable fluorescent dyes are in particular those fluorescent dyes which emit fluorescent light in the range of the wavelength of the energy maximum of the colored LEDs used.
- the effect according to the invention can be achieved with surprisingly small amounts, for. B. with 0.001 to 0.01 wt .-%, based on the plastic of the light-scattering covers,
- Suitable fluorescent dyes are, for. B. perylene-based or Perylenderivate, for example, under the trade name Lumogen® BASF available fluorescent dyes.
- a yellow-fluorescent dye preferably a yellow-fluorescent perylene dye, in particular the fluorescent dye Lumogen® F Yellow 170, is suitable.
- red-fluorescent dye preferably a red-fluorescent perylene dye, in particular the fluorescent dye Lumogen® F Red 305 or Lumogen® F Rosa 285 is suitable.
- a green fluorescent dye preferably a green fluorescent perylene dye, in particular the fluorescent dyes Lumogen® F Yellow 083 or Lumogen® F Yellow 170, is suitable.
- a blue-fluorescent dye preferably a blue-fluorescent perylene dye, in particular the fluorescent dyes Lumogen® F Violet 570 or Lumogen® F Blue 650 is suitable.
- the WO 03/052315 Opposite the WO 03/052315
- the main difference is that the reflection at the wavelength of the maximum energy of the LED used, due to the color mixture of base coloring and at least one, the base coloring associated fluorescent dye is significantly increased. It is surprising that this succeeds without or with only a slight change in the values for the transmission or the color locus.
- the light-diffusing cover used according to the invention appears opposite to one according to FIG WO 03/052315 once again much more brilliant. The color as such appears virtually unchanged when viewed with the naked eye.
- the plastic light-scattering cover thus assigned according to the invention preferably has a transmission (DIN 5036, see parts 1 and 3) of at least 20%, preferably at least 35%, preferably at least 38%, particularly preferably at least 41, at the wavelength of the relative energy maximum of the light-emitting diode % and a reflection (DIN 5036, parts 1 and 3, reflection or remission) of at least 28%, preferably at least 40%, particularly preferably at least 50%.
- the reflection is advantageously at least 50%, preferably at least 75%, more preferably at least 100% above the value that would be achieved with a corresponding base coloring of the prior art without fluorescent dye.
- the transmission of a light-diffusing cover according to the invention is higher than that of a corresponding light-diffusing cover of the prior art (see Tables 4 and 5).
- a yellow-colored light-diffusing cover according to the invention the transmission increases by approximately 1 to 2% in comparison.
- the transmission increases by about 30 to 35% in comparison.
- the transmission increases by about 15 to 25% in comparison.
- the transmission increases by about 7 to 15% in comparison.
- the transmission of a light-diffusing cover associated with a yellow LED can be at least 50%, preferably at least 60%. be.
- the corresponding reflection can be at least 28%, preferably at least 30%, in particular at least 40%.
- the transmission of a light-scattering cover assigned to a red LED can amount to at least 40%, preferably at least 45%.
- the corresponding reflection can be at least 28%, preferably at least 45%.
- the transmission of a light-diffusing cover associated with a green LED can amount to at least 40%, preferably at least 42%.
- the corresponding reflection can be at least 28%, preferably at least 30%, in particular at least 40%.
- the transmission of a light-diffusing cover assigned to a blue LED can amount to at least 40%, preferably at least 42%.
- the corresponding reflection can be at least 25%, preferably at least 30%.
- the associated light-diffusing plastic cover at least at the wavelength of the relative energy maximum of one of the LEDs used, ie, for.
- the above-required reflection values and preferably also have the above-mentioned transmission values.
- the associated light-diffusing cover consists of a plastic which is a plastic which is transparent in the non-colored state and without scattering agent, or preferably a transmittance (DIN 5036, s. Parts 1 and 3 / D65) of at least 50%, preferably at least 70, particularly preferably from 75 to 92%.
- a transmittance DIN 5036, s. Parts 1 and 3 / D65
- the transmittance may favorably be at least 40%, more preferably at least 50%.
- Suitable plastics are z. Polymethyl methacrylate plastic, impact modified polymethyl methacrylate, polycarbonate plastic, polystyrene plastic, styrene-acrylonitrile plastic, polyethylene terephthalate plastic, glycol-modified polyethylene terephthalate plastic, polyvinyl chloride plastic, transparent polyolefin plastic, acrylonitrile-butadiene-styrene ( ABS) plastic or blends of various thermoplastics.
- ABS acrylonitrile-butadiene-styrene
- polymethyl methacrylate plastics from cast or extruded polymethylmethacrylate z. B. with a methyl methacrylate content of 85 to 100 wt .-%, preferably.
- a methyl methacrylate content 85 to 100 wt .-%, preferably.
- up to 15 wt .-% of suitable comonomers such as.
- esters of methacrylic acid eg, ethyl methacrylate, butyl methacrylate, hexyl methacrylate, cyclohexyl methacrylate
- esters of acrylic acid eg, methyl acrylate, ethyl acrylate, butyl acrylate, hexyl acrylate, cyclohexyl acrylate
- styrene and styrene derivatives such as ⁇ -methylstyrene or p-butyl methacrylate.
- Methylstyrene be polymerized or contained in the polymer.
- the light scattering capacity of the cover can, measured according to DIN 5036, preferably have a value of at least 0.5, more preferably of at least 0.6, in particular at least 0.7.
- the better the light scattering capability the smaller the spacing of the LEDs from the cover and the associated depths of the device can be realized.
- a light scattering agent z As a light scattering agent z.
- BaSO 4 polystyrene or Lichtstreuperlen be used from a crosslinked plastic.
- BaSO 4 or polystyrene are preferred and are preferably introduced in an amount of 1.5 to 2.5 wt .-% in the plastic.
- Lichtstreuperlen of a crosslinked plastic are preferably introduced in an amount of 0.1 to 10 wt .-% in the plastic.
- crosslinked polymer particles for example polymer beads of crosslinked polystyrene or crosslinked copolymers of methyl methacrylate with phenyl (meth) acrylate or benzyl (meth) acrylate.
- Dispersants and colorants can the plastic in the production by polymerization in the polymerizable mixture (casting) or during thermoplastic processing of the polymer in the melt state, for. B. by extrusion or injection, in a conventional manner added or incorporated.
- any profiles, such as pipes, rods, etc. can be manufactured.
- z. B. with a thickness of z. B. 0.5 to 10, preferably 1 to 5 mm are obtained, which can be used as covers for illuminable devices according to the invention with rectangular boxes, frame or bracket.
- Corresponding pieces can be converted and adapted as required by cutting, milling, sawing or other processing in virtually any shape and adapted.
- Non-fluorescent colorants for base coloration are preferably non-fluorescent organic colorants for the purposes of the invention, since they have high brilliance and luminosity both in reflected light and in transmitted light.
- light stabilizers, UV absorbers, antioxidants, etc. can be added.
- the standard color chart according to DIN 5033 is well known to the person skilled in the art.
- the standard color chart according to DIN 5033 makes it possible to clearly classify the colors of light sources and body colors (eg for spreads, light filters, etc.) according to their color.
- the classification presupposes a measurement of the standard color value components x, y;
- the coordinates thus uniquely determine the color location of a color type (eg red, green, yellow or blue or color mixtures).
- Corresponding color measurements can be carried out with commercially available colorimeters. Such colorimeters usually allow a non-contact measurement of light sources and object colors. Suitable is z.
- the standard color chart represents a shoe sole-like area in an x, y coordinate system. Each point on this shoe sole-like area of the color chart clearly represents a color type. Colors of the same color type have the same color location with identical x and y coordinates and can only differ in their brightness.
- the achromatic point represents white, gray to black depending on the brightness.
- Between the achromatic point and the edge curve of the shoe sole-like surface of the standard color chart are all other (colorful) color grades.
- the rays emanating from the uncoloured point each contain the same hue colors in increasing saturation or increasing brilliance, ie from pale to saturated or brilliant.
- the standard color chart is based on this rule.
- the boundary curve of the shoe sole-like surface of the standard color chart is composed of the spectral color train and the so-called purple line.
- a chromaticity defined by its x, y coordinates, is at the edge of the shoe sole-like surface of the standard color chart, the more brilliant it appears.
- the invention is based on the consideration that the closer the color point of the reflection of the colored cover at the color location of the LED, the match of the color impression in reflected light and fluoroscopy should be even better.
- a match of a coloring with a given LED color point practically only is approximately feasible.
- the color locations are located as far as possible at the edge of the color standard table (see, for example, DIN 5033 or corresponding standard literature), since the color brilliance here is the maximum. This is also due to the fact that the color locations of the LEDs are also due to the monochromatic light at the edge or near the edge of the standard color chart.
- the color locus of the reflection of the light-scattering cover is measured by placing the light-scattering cover against a white background (eg a box painted white, see the examples) with a 150 W daylight lamp (D65 according to DIN 6173, quality class 1, eg Siemens) is illuminated from above at a distance of 60 cm and the color measurement is also performed from above at a distance of 100 cm.
- a white background eg a box painted white, see the examples
- a 150 W daylight lamp D65 according to DIN 6173, quality class 1, eg Siemens
- the color measurement can z. B. be carried out with the colorimeter Chroma Meter CS-100 Minolta.
- the color location of the LED can z. B. are calculated from their emission spectrum or is known from the manufacturer.
- the plastic of the cover in this case may be a base color of a mixture of 0.075 to 0.09, preferably 0.081 to 0.084 wt .-% pyrazolone yellow and 0.002 to 0.004, preferably 0.0028 to 0.0032 wt .-% perinone orange exhibit.
- a fluorescent dye preferably a perylene-based fluorescent dye, more preferably the fluorescent dye Lumogen® F Yellow 170 (BASF), preferably in a concentration of 0.005 to 0.015 wt .-%, be contained.
- the plastic of the cover in this case may have a base coloring of 0.2 to 0.3, preferably 0.22 to 0.28 wt .-% pyrazolone yellow.
- a fluorescent dye preferably a perylene-based fluorescent dye, more preferably the fluorescent dye Lumogen® F Red 305 (BASF), preferably in a concentration of 0.0025 to 0.0075 wt .-%, be included.
- the plastic of the cover in this case may have a base color of 0.03 to 0.05, preferably 0.035 to 0.045 wt .-% Cu-phthalocyanine green.
- a fluorescent dye preferably a perylene-based fluorescent dye, more preferably the fluorescent dye fluorescent dye Lumogen® F Yellow 083 (BASF), preferably in a concentration of 0.01 to 0.03 wt .-%, may be included.
- the plastic of the cover may also be colored with 0.005 to 0.015, preferably 0.007 to 0.012 wt .-% anthraquinone blue.
- a fluorescent dye preferably a perylene-based fluorescent dye, more preferably the fluorescent dye fluorescent dye Lumogen® F Violet 570 (BASF), preferably in a concentration of 0.05 to 0.15 wt .-%, be contained.
- the plastic of the cover additionally contains TiO 2 in a concentration of 0.001 to 0.05 wt .-%.
- the luminance Y is measured in Cd / m 2 of the light-scattering cover by placing the light-scattering cover against a white background (eg a box painted white, see the examples) with a 150 W daylight lamp (D65 according to DIN 6173, quality class 1, eg from Siemens) is illuminated from above at a distance of 60 cm and the luminance measurement is also carried out from above at a distance of 100 cm.
- a white background eg a box painted white, see the examples
- a 150 W daylight lamp D65 according to DIN 6173, quality class 1, eg from Siemens
- the luminance measurement can be z.
- use the Chroma Meter CS-100 colorimeter from Minolta which measures color locations and luminance.
- the remission measurement can z. B. under determination of the mixed reflection, ie, the proportions of the directed reflection and the scattered reflection are detected (DIN 5036, Part 1 point 6).
- the transmission measurement z. B. can be done by determining the mixed transmission, ie, the proportions of the directional transmission and the scattered transmission are recorded (DIN 5036, Part 1 point 7).
- the chosen arrangement of the measuring geometry is preferably directional / semi-spatial (DIN 5036, Part 3, Item 2 or 3 and Tab.1)
- the construction of the measuring arrangement (two-beam measuring instrument with integrating sphere) is preferably carried out according to DIN EN ISO 13468-2 and DIN 5036, Part 3, Item. 4)
- the measurement of the scattering value is preferably carried out by determining the luminance at different angles (DIN 5036, Part 1, Point 5.1)
- the measurement setup can z. B. according to ASTM E 2387-05.
- the measurement result is practically independent of the choice of the light source. However, this should be such that in the desired wavelength range (usually in the entire visible range between 380nm and 780nm) light is emitted.
- a person skilled in the art will be familiar with the measured variables, measuring methods and relevant standards mentioned in the invention. He can select suitable conditions and arrangements for all necessary measurements due to his expertise. In some cases, the person skilled in the art may make adjustments to the requirements of the samples to be measured or usefully modify given measurement conditions. In principle, it is also possible that in individual cases several measuring methods or modifications of measuring methods for determining the measured variables mentioned in the context of the invention are equally suitable. On the basis of his specialist knowledge and based on the information and instructions disclosed here, the person skilled in the art independently obtains reliable and reproducible measurement results in the sense of the present invention.
- Metylmethacrylat syrup (viscosity about 1000 cP) are 1 part of 2,2'-azobis- (2,4-dimethylvaleronitrile) dissolved.
- a color paste consisting of 3 parts of a soluble polymethylmethacrylate resin, 20 parts of barium sulfate and the colorants according to Table 1 , which in 30 parts of methyl methacrylate with a high-speed dispersant (Rotor / stator principle) is dispersed, added.
- the mixture is stirred vigorously, filled into a silicate glass chamber which is distanced with 3 mm thick cord and polymerized in a water bath at 45 ° C. for about 16 hours.
- the final polymerization is carried out in a tempering at 115 ° C for about 4 hours.
- the transmitted light test is carried out in a darkened room with activated LEDs according to the above operating information. Color measurements are taken using the Chroma-Meter CS-100 colorimeter from Minolta. This device allows non-contact measurements of light sources and object colors. The distance sample / device is 1 m. The luminance Y in Cd / m 2 is also measured with this device.
- Table 4 (inventive colorings of Examples 1 and 2) colour LED ⁇ max in nm Transmission at LED ⁇ max Reflection at LED ⁇ max Y in Cd / m 2 x y Yellow 1 590 64% 40% 130 0,550 0.449 Yellow 2 590 63% 46% 133 0,550 0,448 Red 1 620 80% 56% 165 0.687 0.312 Red 2 620 79% 63% 162 0.687 0.312 Green 1 520 66% 46% 38.8 0.143 0,780 Green 2 520 61% 52% 36.1 0.143 0.782 Blue 1 440 56% 36% 6.32 0.138 0.046 Blue 2 440 52% 41% 6.34 0.138 0,045
- Table 5 (colorings not according to the invention, see Example 3) colour LED ⁇ max in nm Transmission at LED ⁇ max Reflection at LED ⁇ max Y in Cd / m 2 x y Yellow 3 590 62% 26% 127 0.545 0.453 Red 3 620 48% 23% 165 0.684 0.315 Green 3 520 43% 19% 36.3 0.143 0.782 Blue 3 440 43% 21% 6.34 0.138 0,045
- Table 6 (inventive colorings of Examples 1 and 2) colour Y in Cd / m 2 x y Amount x LED x sample Amount y LED-y sample LED blue ---- 0.14 0.06 Blue 1 12.6 0.168 0,107 0.028 0.047 Blue 2 13.1 0.166 0.105 0.026 0,045 LED green --- 0.16 0.73 Green 1 59.3 0.194 0.661 0.034 0,069 Green 2 62.3 0.19 0.673 0,030 0.057 LED yellow --- 0.5 0.5 Yellow 1 123 0.498 0.485 0,002 0,015 Yellow 2 126 0.499 0.485 0.001 0,015 LED red --- 0.67 0.33 Red 1 41.8 0,655 0.328 0,015 0,002 Red 2 43.1 0.66 0,329 0,010 0.001
Abstract
Description
Die Erfindung betrifft eine Vorrichtung zur Beleuchtung mit blauen, grünen, gelben oder roten Leuchtdioden (LEDs), bestehend im wesentlichen aus einer LED-Lichtquelle und einer der Lichtquelle zugeordneten lichtstreuenden Abdeckung aus eingefärbtem Kunststoff.The invention relates to a device for lighting with blue, green, yellow or red light emitting diodes (LEDs), consisting essentially of an LED light source and a light scattering cover of colored plastic associated with the light source.
Beleuchtbare Vorrichtungen, z. B. für Werbetafeln, bestehend im wesentlichen aus einer Lichtquelle und der Lichtquelle zugeordneten lichtstreuenden Abdeckung aus eingefärbtem Kunststoff sind im Prinzip bekannt (s. z. B.
Leuchtdioden sind im Vergleich zu Lichtquellen wie Glühlampen oder Leuchtstoffröhren von deutlich geringerer Leuchtkraft. Farbige Leuchtdioden sind jedoch trotzdem bei Dunkelheit sehr gut wahrnehmbar, da sie ein im Wesentlichen bzw. ein nahezu monochromatisches Licht abstrahlen, das in jeweiligen Wellenlängenbereich wiederum relativ intensiv ist. Entsprechende farbige Leuchtdioden sind von mehreren Herstellern z. B. in den Farben rot, grün, blau und gelb verfügbar.Light-emitting diodes are of significantly lower luminance compared to light sources such as incandescent lamps or fluorescent tubes. However, colored light-emitting diodes are nevertheless very noticeable in the dark, since they radiate a substantially or almost monochromatic light, which in turn is relatively intense in the respective wavelength range. Corresponding colored LEDs are available from several manufacturers z. B. in the colors red, green, blue and yellow available.
Einfärbungen und Einfärbeverfahren für Kunststoffe wie z. B. Polymethylmethacrylat sind hinlänglich bekannt z. B. aus
Beleuchtbare Vorrichtungen gemäß der
Vorrichtung zur Beleuchtung mit blauen, grünen, gelben oder roten Leuchtdioden (LEDs), enthaltend eine oder mehrere farbige LEDs und eine der LED Farbe zugeordnete, lichtstreuende Abdeckung aus eingefärbtem Kunststoff, die eine Basiseinfärbung mittels eines oder mehrerer nicht fluoreszierender Farbstoffe aufweist, dadurch gekennzeichnet, dass die lichtstreuende Abdeckung zusätzlich zur Basiseinfärbung mindestens einen der Basiseinfärbung farblich zugeordneten fluoreszierenden Farbstoff enthält, wobei die Farbstoffmischung so eingestellt ist, dass die lichtstreuende Abdeckung bei der Wellenlänge des Energiemaximums der verwendeten LED bzw. LEDs eine Reflexion von mindestens 28 % aufweist,
wobei, bezogen auf die Normfarbtafel und die Farborte der Reflexion der lichtstreuenden Abdeckung und den Farbort der verwendeten LED bzw. LEDs, der Betrag der Differenz des x-Wertes der lichtstreuenden Abdeckung mit dem x-Wert der LED und der Betrag der Differenz des y-Wertes der lichtstreuenden Abdeckung mit dem y-Wert der LED sich alternativ wie folgt verhält:
- a) für blaue LED-Beleuchtung: Betrag x kleiner 0,03 / Betrag y kleiner 0,05
- b) für grüne LED-Beleuchtung: Betrag x kleiner 0,05 / Betrag y kleiner 0,08
- c) für gelbe LED-Beleuchtung: Betrag x kleiner 0,0025 / Betrag y kleiner 0,02
- d) für rote LED-Beleuchtung: Betrag x kleiner 0,03 / Betrag y kleiner 0,003
wherein, based on the standard color chart and the color loci of the reflection of the light-diffusing cover and the color location of the LEDs or LEDs used, the amount of the difference of the x value of the light-diffusing cover with the x value of the LED and the amount of the difference of the y Value of the light-diffusing cover with the y-value of the LED behaves alternatively as follows:
- a) for blue LED illumination: amount x less than 0.03 / amount y less than 0.05
- b) for green LED illumination: amount x less than 0.05 / amount y less than 0.08
- c) for yellow LED illumination: amount x less 0.0025 / amount y less 0.02
- d) for red LED lighting: amount x less than 0.03 / amount y less 0.003
Die Erfindung beruht darauf, die Transmission und die Reflexion von der lichtstreuenden Abdeckung aus Kunststoff ähnlich wie in der
Durch die erfindungsgemäße Ausstattung ist es möglich, die Vorrichtung bei gleichem Stromverbrauch deutlich heller und brillianter erscheinen zu lassen oder bei reduziertem Stromverbrauch einen zumindest gleichwertigen Effekt wie den der
Die Erfindung wird durch die nachstehenden Figuren erläutert, ohne jedoch auf die dargestellten Ausführungsformen beschränkt zu sein.The invention is illustrated by the following figures, but without being limited to the illustrated embodiments.
Reflexionsspektrum von drei eingefärbten, lichtstreuenden Kunststoffscheiben bei Beleuchtung mit einer grünen LED mit relativem Energiemaximum bei etwa 520 nm. (Zusammensetzungen: s. die Beispiele 1 - 3, Grün 1 -3)
- 3 = Grün 3: Nur Basiseinfärbung (Stand der Technik, gemäß
WO 03/052315 - 1 = Grün 1: Basiseinfärbung + Fluoreszenzfarbstoff (erfindungsgemäß)
- 2 = Grün 2: Basiseinfärbung + Fluoreszenzfarbstoff + TiO2-Zusatz
(erfindungsgemäß)
- 3 = green 3: only basic coloring (prior art, according to
WO 03/052315 - 1 = green 1: basic coloring + fluorescent dye (according to the invention)
- 2 = green 2: base stain + fluorescent stain + TiO 2 added
(Invention)
Schematische Darstellung der Normfarbtafel.
- U = Unbuntpunkt (x/y = 0,33/0,33)
- LED = Farbort einer grünen LED (xLED/yLED)
- R = Farbort der Reflexion einer lichtstreuenden Abdeckung (xReflexion/yReflexion)
- U = achromatic point (x / y = 0.33 / 0.33)
- LED = color location of a green LED (x LED / y LED )
- R = color location of the reflection of a light-scattering cover (x reflection / y reflection )
Die Erfindung betrifft eine
Vorrichtung zur Beleuchtung mit blauen, grünen, gelben oder roten Leuchtdioden (LEDs), enthaltend eine oder mehrere farbige LEDs und eine der LED-Farbe bzw. dem Farbort der LED im leuchtenden Zustand zugeordnete, lichtstreuende Abdeckung aus eingefärbtem Kunststoff, die eine Basiseinfärbung mittels eines oder mehrerer nicht fluoreszierender Farbstoffe aufweist, dadurch gekennzeichnet, dass
die lichtstreuende Abdeckung zusätzlich zur Basiseinfärbung mindestens einen der Basiseinfärbung farblich zugeordneten fluoreszierenden Farbstoff enthält, wobei die Farbstoffmischung bewirkt bzw. so eingestellt ist, dass die lichtstreuende Abdeckung bei der Wellenlänge des Energiemaximums der verwendeten LED bzw. LEDs eine Reflexion von mindestens 28 % aufweist, wobei, bezogen auf die Normfarbtafel (DIN 5033) und den Farbort der Reflexion der lichtstreuenden Abdeckung ((xReflexion/yReflexion) im Auflicht) und den Farbort der LED ((xLED/yLED) im leuchtenden Zustand), der Betrag der Differenz (Betrag xDiff) des x-Wertes der lichtstreuenden Abdeckung (xReflexion) mit dem x-Wert der LED (xLED) und der Betrag der Differenz (Betrag yDiff) des y-Wertes der lichtstreuenden Abdeckung (yReflexion) mit dem y-Wert der LED (yLED) sich alternativ wie folgt verhält:
- a) für blaue LED-Beleuchtung: Betrag xDiff kleiner 0,03 / Betrag yDiff kleiner 0,05
- b) für grüne LED-Beleuchtung: Betrag xDiffkleiner 0,05 / Betrag yDiff kleiner 0,08
- c) für gelbe LED-Beleuchtung: Betrag xDiff kleiner 0,0025/ Betrag yDiff kleiner 0,02
- d) für rote LED-Beleuchtung: Betrag xDiff kleiner 0,03 / Betrag yDiff kleiner 0,003 '
Device for lighting with blue, green, yellow or red light-emitting diodes (LEDs), containing one or more colored LEDs and one of the LED color or the color of the LED in the luminous state associated, light-diffusing cover made of colored plastic, a base coloring by means of a or more non-fluorescent dyes, characterized in that
the light-scattering cover contains, in addition to the base coloration, at least one colorant associated with the base coloration, wherein the colorant coverage has a reflectance of at least 28% at the energy maximum wavelength of the LED or LEDs used , relative to the standard color chart (DIN 5033) and the color locus of the reflection of the light diffusing cover ((x reflection / y reflection ) in incident light) and the color locus of the LED ((x LED / y LED ) in the illuminated state), the amount of the difference (Amount x diff ) of the x value of the light scattering cover (x reflection ) with the x value of the LED (x LED ) and the amount of difference (amount y diff ) of the y value of the light scattering cover (y reflection ) with the y value of the LED (y LED ) alternatively behaves as follows:
- a) for blue LED illumination: amount x diff less than 0.03 / amount y diff less than 0.05
- b) for green LED illumination: amount x diff less than 0.05 / amount y diff less than 0.08
- c) for yellow LED illumination: Amount x Diff less 0.0025 / Amount y Diff less 0.02
- d) for red LED illumination: amount x diff less 0.03 / amount y diff less 0.003 '
Es kommt dabei lediglich auf die absolute Differenz bzw. die Entfernung der x-bzw. y-Werte zueinander an, nicht auf deren relative Lage auf der Normfarbtafel. Diese Differenz bzw. Entfernung soll möglichst gering sein, im Idealfall nahezu oder gleich Null betragen. Sie soll jedoch zumindest die oben angegebenen Obergrenzen nicht überschreiten. Es ist zudem unerheblich, ob die Bildung der Differenz der korrespondierenden x- bzw. y-Werte mathematisch zu einem positiven oder zu einem negativen Wert führt. Aus diesem Grund legt die Erfindung den Betrag der Differenz des x-Wertes der lichtstreuenden Abdeckung mit dem x-Wert der LED und den Betrag der Differenz des y-Wertes der lichtstreuenden Abdeckung mit dem y-Wert der LED zugrunde. Unter Anwendung der vorliegenden Erfindung wird es vorteilhafterweise möglich, eine sehr enge Anpassung des Farborts der Reflexion der lichtstreuenden Abdeckung an den Farbort der verwendeten LEDs im leuchtenden Zustand vorzunehmen. Auf diese Weise werden beleuchtbare Vorrichtungen bereitgestellt, die im unbeleuchteten und im beleuchteten Zustand einen weitgehend übereinstimmenden und zugleich sehr brillianten Farbeindruck vermitteln.It comes only to the absolute difference or the distance of the x or. y values to each other, not their relative position on the standard color chart. This difference or distance should be as small as possible, ideally close to or equal to zero. However, it should at least not exceed the upper limits specified above. It is also irrelevant whether the formation of the difference of the corresponding x or y values leads mathematically to a positive or to a negative value. For this reason, the invention is based on the amount of the difference of the x-value of the light-diffusing cover with the x-value of the LED and the amount of the difference of the y-value of the light-diffusing cover with the y-value of the LED. Using the present invention, it advantageously becomes possible to make a very close adaptation of the color locus of the reflection of the light-diffusing cover to the color locus of the LEDs used in the luminous state. In this way, illuminable devices are provided, which convey a largely coincident and at the same time very brilliant color impression in the unlit and in the illuminated state.
Die Erfindung betrifft eine beleuchtbare Vorrichtung, enthaltend eine Lichtquelle in Form einer oder mehrerer farbiger Leuchtdioden (LEDs) und eine der Lichtquelle zugeordnete lichtstreuende Abdeckung aus eingefärbten Kunststoff. Die Vorrichtung besteht somit im Wesentlichen aus den für die Funktion unerlässlichen Bestandteilen, nämlich der Lichtquelle und der der Lichtquelle zugeordneten lichtstreuenden Abdeckung aus eingefärbtem Kunststoff. Darüber hinaus können noch weitere, für die erfindungsgemäße Funktionalität jedoch unkritische Elemente, wie ein Rahmen, Gehäuse oder Befestigungselemente etc. vorhanden sein.The invention relates to an illuminable device comprising a light source in the form of one or more colored light-emitting diodes (LEDs) and a light-scattering cover of colored plastic associated with the light source. The device thus consists essentially of the components indispensable for the function, namely the light source and the light-scattering cover of colored plastic associated with the light source. In addition, further, for the functionality of the invention, however, uncritical elements, such as a frame, housing or fasteners, etc. may be present.
Die Vorrichtung kann so gestaltet sein, dass die LEDs und die lichtstreuende Abdeckung einander in einem Abstand von 3 bis 12, bevorzugt 4 bis 10 cm zugeordnet sind. In diesem Abstand wird eine gute Ausleuchtung erreicht. Bei zu geringem Abstand wird die Position der LED in Form eines hellen Flecks sichtbar. Bei zu großem Abstand nimmt die Helligkeit zu stark ab.The device may be designed such that the LEDs and the light-diffusing cover are associated with each other at a distance of 3 to 12, preferably 4 to 10 cm. At this distance a good illumination is achieved. If the distance is too short, the position of the LED will be visible as a bright spot. If the distance is too great, the brightness decreases too much.
Die LEDs können sich z. B. in einem Kasten oder Rahmen befinden, der von der lichtstreuenden Abdeckung, z. B. in Plattenform, abgedeckt wird. Die Abdeckung kann mit einer informationstragenden Schicht, z. B. einer Folie, versehen werden oder selbst bereits die Form einer Information aufweisen, z. B. in Buchstaben- oder Zahlenform.The LEDs can z. B. in a box or frame, of the light-diffusing cover, z. B. in plate form, is covered. The cover may be provided with an information-bearing layer, e.g. As a film provided or even already have the form of information, for. B. in letter or number form.
Das folgende allgemeine Beispiel verdeutlicht eine erfindungsgemäße Vorrichtung für gelbe LED-Beleuchtung und ist sinngemäß auch auf blaue, grüne oder rote LED-Beleuchtung anwendbar.The following general example illustrates a device according to the invention for yellow LED lighting and is mutatis mutandis applicable to blue, green or red LED lighting.
Der Farbort einer gelb leuchtenden LED kann z. B. bei xLED = 0,5/yLED = 0,5 liegen. Der Farbort der Reflexion einer erfindungsgemäß im Farbbort angepassten, gelb eingefärbten, lichtstreuenden Abdeckung (z. B. Gelb 1 mit einem Reflexionswert von 40 %, s. insbesondere Beispiel 1 und Tabellen 4 und 6) kann z. B. bei xReflexion = 0,498/yReflexion=0,485 liegen. Der Betrag der Differenz, Betrag xDiff, des x-Wertes der lichtstreuenden Abdeckung (xReflexion) mit dem x-Wert der LED (xLED) und der Betrag der Differerenz, Betrag yDiff, des y-Wertes der lichtstreuenden Abdeckung (yReflexion) mit dem y-Wert der LED (yLED) verhält sich wie folgt:
- Betrag xDiff = xReflexion minus xLED = 0,498 - 0,5 = 0,002. Der Wert
ist kleiner als 0,0025 und liegt damit im erfindungsgemäß geforderten Bereich. - Betrag yDiff = YReflexion minus yLED = 0,485 - 0,5 = 0,015. Der Wert
ist kleiner als 0,02 und liegt damit ebenfalls im erfindungsgemäß geforderten Bereich. Die entsprechende Vorrichtung ist demnach erfindungsgemäß.
- Amount x Diff = x Reflection minus x LED = 0.498 - 0.5 = 0.002. The value is less than 0.0025 and is therefore within the range required by the invention.
- Amount y Diff = Y Reflection minus y LED = 0.485 - 0.5 = 0.015. The value is less than 0.02 and is thus also in the invention required range. The corresponding device is accordingly according to the invention.
In analoger Weise können die Beträge xDiff und yDiff für andere Einfärbungen berechnet werden.In an analogous manner, the amounts x diff and y diff can be calculated for other colors.
Die Lichtquelle besteht aus einer oder mehreren bzw. einer Vielzahl von farbigen Leuchtdioden (LEDs). Gegebenenfalls können auch LEDs unterschiedlicher Farbe gleichzeitig verwendet werden.The light source consists of one or more or a plurality of colored light-emitting diodes (LEDs). Optionally, LEDs of different colors can be used simultaneously.
Farbige LEDs sind im Vergleich zu Lichtquellen wie Glühlampen oder Leuchtstoffröhren von deutlich geringerer Leuchtkraft. Farbige LEDs sind jedoch trotzdem bei Dunkelheit sehr gut wahrnehmbar, da sie ein im Wesentlichen bzw. ein nahezu monochromatisches Licht abstrahlen, das im jeweiligen. Wellenlängenbereich wiederum relativ intensiv ist. Entsprechende farbige Leuchtdioden sind von mehreren Herstellern z. B. in den Farben rot, grün, blau und gelb verfügbar. Ungeeignet für die Zwecke der Erfindung sind weiß leuchtende LEDs, da diese kein nahezu monochromatisches sondern ein breites Leuchtspektrum, ähnlich einer konventionellen Glühbirne, erzeugen.Colored LEDs are of significantly lower luminance compared to light sources such as incandescent or fluorescent tubes. However, colored LEDs are still very noticeable in the dark, as they radiate a substantially or almost monochromatic light, which in the respective. Wavelength range is again relatively intense. Corresponding colored LEDs are available from several manufacturers z. B. in the colors red, green, blue and yellow available. Unsuitable for the purposes of the invention are white LEDs, since they do not produce a nearly monochromatic but a broad spectrum of light, similar to a conventional light bulb.
Farbige Leuchtdioden (LEDs) senden ein nahezu oder im Wesentlichen monochromatisches Licht aus. Der Begriff "nahezu oder im wesentlichen" monochromatisches Licht soll dabei ausdrücken, dass das Licht handelsüblicher farbiger LEDs vereinfachend und im Vergleich zu anderen, normalen Lichtquellen häufig als monochromatisch bezeichnet wird, es aber streng genommen nicht ist. In der Praxis weist das Wellenlängenspektrum einer farbigen LED eine enge, peak-ähnliche Verteilung auf. Neben der für die jeweilige LED charakteristischen Wellenlänge des relativen Energiemaximums (Peakmaximums) finden sich immer auch benachbarte Wellenlängen mit geringerer Intensität. Ein Fachmann würde das Licht farbiger LEDs daher als nahezu oder im Wesentlichen monochromatisch bezeichnen.Colored LEDs emit almost or substantially monochromatic light. The term "almost or substantially" monochromatic light is meant to express that the light of commercially available colored LEDs is simplified and often referred to as monochromatic in comparison to other normal light sources, but strictly speaking it is not. In practice, the wavelength spectrum of a colored LED has a narrow, peak-like distribution. In addition to the wavelength of the relative energy maximum (peak maximum) characteristic of the respective LED, adjacent wavelengths with lower intensity are always found. One skilled in the art would therefore call the light of colored LEDs almost or substantially monochromatic.
Die Farbe der LED hängt dabei von der Wellenlänge ihres relativen Energiemaximums ab. Dieses relative Energiemaximum kann z. B. spektralphotometrisch ermittelt werden und in einem Wellenlängen-Spektrum eingezeichnet werden. Man kann die Lichtquelle z. B. in eine Ulbricht'sche Kugel (s. DIN 5036) einbringen und das austretende Licht vermessen. Der höchste Punkt (Peak) der Kurve kennzeichnet dabei die Wellenlänge des relativen Energiemaximums.The color of the LED depends on the wavelength of its relative energy maximum. This relative energy maximum can z. B. be determined spectrophotometrically and drawn in a wavelength spectrum. You can see the light source z. B. in a Ulbricht'sche ball (see DIN 5036) bring and measure the exiting light. The highest point (peak) of the curve indicates the wavelength of the relative energy maximum.
Die Zahl der LEDs hängt von der Größe der Vorrichtung, der Leuchtkraft der verwendeten LEDs und der insgesamt gewünschten Helligkeit der Vorrichtung in durchleuchteten Zustand ab. LEDs sind z. B als Module von je 4 LEDs in einer Halterung erhältlich, von denen gegebenenfalls eine Vielzahl in die Vorrichtung eingebaut werden kann.The number of LEDs depends on the size of the device, the luminosity of the LEDs used and the overall desired brightness of the device in the transilluminated state. LEDs are z. B as modules of 4 LEDs in each a holder available, from which optionally a variety can be installed in the device.
Geeignete LEDs sind z. B. handelsübliche rote, blaue, gelbe oder grüne LEDs.Suitable LEDs are z. For example, commercially available red, blue, yellow or green LEDs.
Eine rote LED hat ein relatives Energiemaximum im Bereich von etwa 610 bis 640 nm. Der Farbort einer rot leuchtenden LED im leuchtenden Zustand kann z. B. bei ca. x = 0,67 und y = 0,33 liegen.
Die rote LED (Osram LM03-B-A) hat z. B. ein relatives Energiemaximum bei etwa 620 nm. A red LED has a relative energy maximum in the range of about 610 to 640 nm. The color locus of a red-emitting LED in the luminous state can, for. B. at about x = 0.67 and y = 0.33.
The red LED (Osram LM03-BA) has z. B. a relative energy maximum at about 620 nm.
Eine blaue LED hat ein relatives Energiemaximum im Bereich von etwa 440 bis 500 nm. Der Farbort einer blau leuchtenden LED im leuchtenden Zustand kann z. B. bei ca. x = 0,14 und y = 0,06 liegen.
Die blaue LED (Osram LM03-B-B) hat z. B ein Energiemaximum bei etwa 460 nm.
Die blaue LED (ESS Blau) hat z. B ein Energiemaximum bei etwa 475 nm. A blue LED has a relative energy maximum in the range of about 440 to 500 nm. The color locus of a blue-emitting LED in the illuminated state can, for. B. at about x = 0.14 and y = 0.06.
The blue LED (Osram LM03-BB) has z. B is an energy maximum at about 460 nm.
The blue LED (ESS Blue) has z. B is an energy maximum at about 475 nm.
Eine gelbe LED hat ein relatives Energiemaximum im Bereich von etwa 570 bis 610 nm. Der Farbort einer gelb leuchtenden LED im leuchtenden Zustand kann z. B. bei ca. x = 0,5 und y = 0,5 liegen. A yellow LED has a relative energy maximum in the range of about 570 to 610 nm. The color locus of a yellow glowing LED in the illuminated state can, for. B. at about x = 0.5 and y = 0.5.
Die gelbe LED (Osram LM03-B-Y) hat z. B ein Energiemaximum bei etwa 590 nm.The yellow LED (Osram LM03-BY) has z. B is an energy maximum at about 590 nm.
Eine grüne LED hat ein relatives Energiemaximum im Bereich von etwa 500 bis 540 nm. Der Farbort einer grün leuchtenden LED im leuchtenden Zustand kann z. B. bei ca. x = 0,16 und y = 0,73 liegen.
Die grüne LED (Osram LM03-B-T) hat z. B ein Energiemaximum bei etwa 520 nm. A green LED has a relative energy maximum in the range of approximately 500 to 540 nm. The color locus of a green-emitting LED in the luminous state can, for. B. at about x = 0.16 and y = 0.73.
The green LED (Osram LM03-BT) has z. B is an energy maximum at about 520 nm.
Die lichtstreuende Abdeckung besteht aus Kunststoff, bevorzugt einem thermoplastischen oder einem thermoelastischem Kunststoff. Bevorzugt soll der verwendete Kunststoff im nicht eingefärbten Zustand transparent oder transluzent sein. Geeignete Kunststoffe können z. B. sein:
- Polymethylmethacrylat-Kunststoff (gegossen oder extrudiert), schlagzäh modifiziertes Polymethylmethacrylat, Polycarbonat-Kunststoff, Polystyrol-Kunststoff, Styrol-Acryl-Nitril-Kunststoff, Polyethylentherephthalat-Kunststoff, glykolmodifizierter Polyethylentherephthalat-Kunststoff, Polyvinylchlorid-Kunststoff, transparenter Polyolefin-Kunststoff, Acrylnitril-Butadien-Stryrol (ABS)-Kunststoff oder Mischungen (Blends) verschiedener thermoplastischer Kunststoffe.
- Polymethyl methacrylate plastic (cast or extruded), impact modified polymethyl methacrylate, polycarbonate plastic, polystyrene plastic, styrene-acrylonitrile plastic, polyethylene terephthalate plastic, glycol-modified polyethylene terephthalate plastic, polyvinyl chloride plastic, transparent polyolefin plastic, acrylonitrile butadiene -Stryrol (ABS) plastic or mixtures (blends) of various thermoplastics.
Die lichtstreuende Abdeckung aus Kunststoff weist eine Basiseinfärbung, d. h. eine Einfärbung mittels eines oder mehrerer nicht fluoreszierender Farbstoffe auf. Diese Art der Einfärbung ist im Prinzip bekannt aus
Gemäß der
Bei erfindungsgemäßem Zusatz eines oder mehrerer Fluoreszenzfarbstoffe empfiehlt es sich bevorzugterweise, die Basiseinfärbung gegenüber der
Ein Fachmann kann eine solche Anpassung leicht vornehmen, indem er die Konzentration der nicht fluoreszierenden Farbstoffe entsprechend anpasst, in der Regel in Summe leicht herabsetzt oder z. B. statt zweier nicht fluoreszierender Farbstoffe nur noch einen verwendet und die Konzentration des verbleibenden entsprechend ändert. Geeignete Anpassungen gehen auch aus dem Vergleich der hier offenbarten erfindungsgemäßen Beispiele mit nicht den erfindungsgemäßen Beispielen hervor.A person skilled in the art can make such an adjustment easily by adapting the concentration of the non-fluorescent dyes accordingly, as a rule, slightly decreasing them in total or z. B. instead of two non-fluorescent dyes only one used and the concentration of the remaining changes accordingly. Suitable adaptations are also apparent from the comparison of the inventive examples disclosed herein with those of the inventive examples.
Die lichtstreuende Abdeckung aus Kunststoff enthält eine Basiseinfärbung, die bevorzugterweise aufgrund der Anwesenheit des Fluoreszenzfarbstoffs gegenüber einer Basiseinfärbung des Standes der Technik angepasst ist.The plastic light-diffusing cover contains a base stain, which is preferably adapted due to the presence of the fluorescent dye over a base stain of the prior art.
Die angepasste Basiseinfärbung mit dem zugeordneten fluoreszierenden Farbstoff bewirkt als Farbstoffmischung, dass die lichtstreuende Abdeckung bei der Wellenlänge des Energiemaximums der verwendeten Leuchtdiode eine Reflexion (DIN 5036) aufweist, die mindestens 28, bevorzugt mindestens 30, besonders bevorzugt mindestens 35 % beträgt und zugleich um mindestens 50 % über dem Wert liegt, der mit einer (nicht angepassten) Basiseinfärbung ohne einen fluoreszierenden Farbstoff erreicht werden würde. Dadurch wirkt der Farbton wesentlich brillianter als mit einer Einfärbung gemäß der
Geeignete Fluoreszenzfarbstoffe sind insbesondere solche Fluoreszenzfarbstoffe, die fluoreszierendes Licht im Bereich der Wellenlänge des Energiemaximums der verwendeten farbigen LEDs emittieren. Der erfindungsgemäße Effekt kann dabei mit überraschend geringen Einsatzmengen, z. B. mit 0,001 bis 0,01 Gew.-%, bezogen auf den Kunststoff der lichtstreuende Abdeckungen erzielt werden,Suitable fluorescent dyes are in particular those fluorescent dyes which emit fluorescent light in the range of the wavelength of the energy maximum of the colored LEDs used. The effect according to the invention can be achieved with surprisingly small amounts, for. B. with 0.001 to 0.01 wt .-%, based on the plastic of the light-scattering covers,
Geeignete Fluoreszenzfarbstoffe sind z. B. solche auf Perylenbasis bzw. Perylenderivate, z.B. unter dem Handelsnamen Lumogen® der BASF erhältliche Fluoreszenzfarbstoffe.Suitable fluorescent dyes are, for. B. perylene-based or Perylenderivate, for example, under the trade name Lumogen® BASF available fluorescent dyes.
Für in der Basiseinfärbung gelb eingefärbte lichtstreuende Abdeckungen ist der Zusatz eines gelb fluoreszierenden Farbstoffs, bevorzugt eines gelb fluoreszierenden Perylen-Farbstoffs, insbesondere des Fluoreszenzfarbstoffs Lumogen® F Gelb 170 geeignet.For light-scattering coverings dyed yellow in the base coloration, the addition of a yellow-fluorescent dye, preferably a yellow-fluorescent perylene dye, in particular the fluorescent dye Lumogen® F Yellow 170, is suitable.
Für in der Basiseinfärbung rot eingefärbte lichtstreuende Abdeckungen ist der Zusatz eines rot fluoreszierenden Farbstoffs, bevorzugt eines rot fluoreszierenden Perylen-Farbstoffs, insbesondere der Fluoreszenzfarbstoff Lumogen® F Rot 305 oder Lumogen® F Rosa 285 geeignet.For light-scattering coverings colored red in the base coloring, the addition of a red-fluorescent dye, preferably a red-fluorescent perylene dye, in particular the fluorescent dye Lumogen® F Red 305 or Lumogen® F Rosa 285 is suitable.
Für in der Basiseinfärbung grün eingefärbte lichtstreuende Abdeckungen ist der Zusatz eines grün fluoreszierenden Farbstoffs, bevorzugt eines grün fluoreszierenden Perylen-Farbstoffs, insbesondere der Fluoreszenzfarbstoffe Lumogen® F Gelb 083 oder Lumogen® F Gelb 170 geeignet.For light-diffusing covers dyed green in the base coloring, the addition of a green fluorescent dye, preferably a green fluorescent perylene dye, in particular the fluorescent dyes Lumogen® F Yellow 083 or Lumogen® F Yellow 170, is suitable.
Für in der Basiseinfärbung blau eingefärbte lichtstreuende Abdeckungen ist der Zusatz eines blau fluoreszierenden Farbstoffs, bevorzugt eines blau fluoreszierenden Perylen-Farbstoffs, insbesondere der Fluoreszenzfarbstoffe Lumogen® F Violett 570 oder Lumogen® F Blue 650 geeignet.For light-scattering covers dyed blue in the base coloring, the addition of a blue-fluorescent dye, preferably a blue-fluorescent perylene dye, in particular the fluorescent dyes Lumogen® F Violet 570 or Lumogen® F Blue 650 is suitable.
Gegenüber der
Die somit erfindungsgemäß zugeordnete lichtstreuende Abdeckung aus Kunststoff weist bei der Wellenlänge des relativen Energiemaximums der Leuchtdiode bevorzugterweise eine Transmission (DIN 5036, s. Teile 1 und 3) von mindestens 20 %, bevorzugt mindestens 35 %, bevorzugt mindestens 38 %, besonders bevorzugt mindestens 41 % und eine Reflexion (DIN 5036, Teile 1 und 3, Reflexion bzw. Remission) von mindestens 28 %, bevorzugt mindestens 40 %, besonders bevorzugt mindestens 50 % auf. Die Reflexion liegt vorteilhafterweise um mindestens 50 %, bevorzugt um mindestens 75 %, besonders bevorzugt mindestens um mindestens 100 % über dem Wert liegt, der mit einer entsprechenden Basiseinfärbung des Standes der Technik ohne fluoreszierenden Farbstoff erreicht werden würde.Opposite the
The plastic light-scattering cover thus assigned according to the invention preferably has a transmission (DIN 5036, see
Vorteilhafterweise liegt die Transmission einer erfindungsgemäßen lichtstreuenden Abdeckung höher als die einer entsprechenden lichtstreuenden Abdeckung des Standes der Technik (siehe Tabellen 4 und 5).
Bei einer erfindungsgemäß gelb eingefärbten lichtstreuenden Abdeckung steigt die Transmission im Vergleich um ca. 1 bis 2 %.
Bei einer erfindungsgemäß rot eingefärbten lichtstreuenden Abdeckung steigt die Transmission im Vergleich um ca. 30 bis 35 %.
Bei einer erfindungsgemäß grün eingefärbten lichtstreuenden Abdeckung steigt die Transmission im Vergleich um ca. 15 bis 25 %.
Bei einer erfindungsgemäß blau eingefärbten lichtstreuenden Abdeckung steigt die Transmission im Vergleich um ca. 7 bis 15 %.Advantageously, the transmission of a light-diffusing cover according to the invention is higher than that of a corresponding light-diffusing cover of the prior art (see Tables 4 and 5).
In a yellow-colored light-diffusing cover according to the invention, the transmission increases by approximately 1 to 2% in comparison.
In a red-colored light-scattering cover according to the invention, the transmission increases by about 30 to 35% in comparison.
In a green-colored light-scattering cover according to the invention, the transmission increases by about 15 to 25% in comparison.
In a light-scattering cover dyed blue according to the invention, the transmission increases by about 7 to 15% in comparison.
Insbesondere kann die Transmission einer, einer gelben LED zugeordneten lichtstreuenden Abdeckung mindestens 50 %, bevorzugt mindestens 60 % betragen. Die entsprechende Reflexion kann bei mindestens 28 %, bevorzugt mindestens 30 %, insbesondere bei mindestens 40 % liegen.In particular, the transmission of a light-diffusing cover associated with a yellow LED can be at least 50%, preferably at least 60%. be. The corresponding reflection can be at least 28%, preferably at least 30%, in particular at least 40%.
Insbesondere kann die Transmission einer, einer roten LED zugeordneten lichtstreuenden Abdeckung mindestens 40 %, bevorzugt mindestens 45 % betragen. Die entsprechende Reflexion kann bei mindestens 28 %, bevorzugt mindestens 45 % liegen.In particular, the transmission of a light-scattering cover assigned to a red LED can amount to at least 40%, preferably at least 45%. The corresponding reflection can be at least 28%, preferably at least 45%.
Insbesondere kann die Transmission einer, einer grünen LED zugeordneten lichtstreuenden Abdeckung mindestens 40 %, bevorzugt mindestens 42 % betragen. Die entsprechende Reflexion kann bei mindestens 28 %, bevorzugt mindestens 30 %, insbesondere bei mindestens 40 % liegen.In particular, the transmission of a light-diffusing cover associated with a green LED can amount to at least 40%, preferably at least 42%. The corresponding reflection can be at least 28%, preferably at least 30%, in particular at least 40%.
Insbesondere kann die Transmission einer, einer blauen LED zugeordneten lichtstreuenden Abdeckung mindestens 40 %, bevorzugt mindestens 42 % betragen. Die entsprechende Reflexion kann bei mindestens 25 %, bevorzugt mindestens 30 % liegen.In particular, the transmission of a light-diffusing cover assigned to a blue LED can amount to at least 40%, preferably at least 42%. The corresponding reflection can be at least 25%, preferably at least 30%.
Für den Fall, dass LEDs unterschiedlicher Farbe gleichzeitig verwendet werden, um Mischfarben zu erreichen, z. B. gelbe und grüne LEDs ergeben einen gelbgrünen Farbeindruck, soll die zugeordnete lichtstreuende Abdeckung aus Kunststoff zumindest bei der Wellenlänge des relativen Energiemaximums einer der verwendeten Leuchtdioden, also z. B. der gelben oder der grünen LED, die oben geforderten Reflexions-Werte und bevorzugterweise auch die oben angegebenen Transmissionswerte aufweisen.In the event that LEDs of different colors are used simultaneously to achieve mixed colors, eg. B. yellow and green LEDs give a yellow-green color impression, should the associated light-diffusing plastic cover at least at the wavelength of the relative energy maximum of one of the LEDs used, ie, for. As the yellow or green LED, the above-required reflection values and preferably also have the above-mentioned transmission values.
Die zugeordnete lichtstreuende Abdeckung besteht aus einem Kunststoff, der ein Kunststoff ist, der im nicht eingefärbten Zustand und ohne Streumittel transparent ist, bzw. bevorzugterweise einen Transmissionsgrad (DIN 5036, s. Teile 1 und 3/ D65) von mindestens 50 %, bevorzugt mindestens 70, besonders bevorzugt von 75 bis 92 % aufweist. Mit Streumittel aber ohne Farbmittel kann der Transmissionsgrad günstigerweise mindestens 40 %, besonders bevorzugt mindestens 50 % betragen.The associated light-diffusing cover consists of a plastic which is a plastic which is transparent in the non-colored state and without scattering agent, or preferably a transmittance (DIN 5036, s.
Geeignete Kunststoffe sind z. B. Polymethylmethacrylat-Kunststoff, schlagzäh modifiziertes Polymethylmethacrylat, Polycarbonat-Kunststoff, Polystyrol-Kunststoff, Styrol-Acryl-Nitril-Kunststoff, Polyethylentherephthalat-Kunststoff, glykolmodifizierten Polyethylentherephthalat-Kunststoff, Polyvinylchlorid-Kunststoff, transparente Polyolefin-Kunststoff, Acrylnitril-Butadien-Stryrol (ABS)-Kunststoff oder Mischungen (Blends) verschiedener thermoplastischer Kunststoffe.Suitable plastics are z. Polymethyl methacrylate plastic, impact modified polymethyl methacrylate, polycarbonate plastic, polystyrene plastic, styrene-acrylonitrile plastic, polyethylene terephthalate plastic, glycol-modified polyethylene terephthalate plastic, polyvinyl chloride plastic, transparent polyolefin plastic, acrylonitrile-butadiene-styrene ( ABS) plastic or blends of various thermoplastics.
Wegen ihrer hohen Witterungsbeständigkeit sind insbesondere für Außenanwendungen Polymethylmethacrylat-Kunststoffe aus gegossenem oder extrudiertem Polymethylmethacrylat, z. B. mit einem Methylmethacrylat-Anteil von 85 bis 100 Gew.-%, bevorzugt. Gegebenenfalls können bis 15 Gew.-% geeignete Comonomere wie z. B. Ester der Methacrylsäure (z. B. Ethylmethacrylat, Butylmethacrylat, Hexylmethacrylat, Cyclohexylmethacrylat), Ester der Acrylsäure (z. B. Methylacrylat, Ethylacrylat, Butylacrylat, Hexylacrylat, Cyclohexylacrylat) oder Styrol und Styrolderivate, wie beispielsweise α-Methylstyrol oder p-Methylstyrol mit polymerisiert werden bzw. im Polymerisat enthalten sein.Because of their high weather resistance, in particular for outdoor applications polymethyl methacrylate plastics from cast or extruded polymethylmethacrylate, z. B. with a methyl methacrylate content of 85 to 100 wt .-%, preferably. Optionally, up to 15 wt .-% of suitable comonomers such as. Esters of methacrylic acid (eg, ethyl methacrylate, butyl methacrylate, hexyl methacrylate, cyclohexyl methacrylate), esters of acrylic acid (eg, methyl acrylate, ethyl acrylate, butyl acrylate, hexyl acrylate, cyclohexyl acrylate), or styrene and styrene derivatives such as α-methylstyrene or p-butyl methacrylate. Methylstyrene be polymerized or contained in the polymer.
Das Lichtstreuvermögen der Abdeckung kann, gemessen nach DIN 5036, bevorzugt einen Wert von mindestens 0,5, besonders bevorzugt von mindestens 0,6, insbesondere mindestens 0,7 aufweisen. Je besser das Lichtstreuvermögen, umso geringere Abstände LEDs von der Abdeckung und damit verbundene Bautiefen der Vorrichtung können realisiert werden.The light scattering capacity of the cover can, measured according to DIN 5036, preferably have a value of at least 0.5, more preferably of at least 0.6, in particular at least 0.7. The better the light scattering capability, the smaller the spacing of the LEDs from the cover and the associated depths of the device can be realized.
Als Lichtstreumittel können z. B. BaSO4, Polystyrol oder Lichtstreuperlen aus einem vernetzten Kunststoff eingesetzt werden.As a light scattering agent z. As BaSO 4 , polystyrene or Lichtstreuperlen be used from a crosslinked plastic.
BaSO4 oder Polystyrol sind bevorzugt und werden bevorzugt in einer Menge von 1,5 bis 2,5 Gew.-% in den Kunststoff eingebracht.BaSO 4 or polystyrene are preferred and are preferably introduced in an amount of 1.5 to 2.5 wt .-% in the plastic.
Lichtstreuperlen aus einem vernetzten Kunststoff werden bevorzugt in einer Menge von 0,1 bis 10 Gew.-% in den Kunststoff eingebracht.Lichtstreuperlen of a crosslinked plastic are preferably introduced in an amount of 0.1 to 10 wt .-% in the plastic.
Die Anforderung nach einer hohen Transmission bei hoher Lichtstreuung ist eine schwierig zu realisierende Anforderung. Ein hohes Streuvermögen wird durch Titandioxid erreicht. Da dieses Farbmittel aber einen großen Teil des Lichtes reflektiert, werden nur geringe Lichtdurchlässigkeiten möglich. Günstiger sind farblose Streupigmente, die im Brechungsindex bis etwa 0,2 vom Brechungsindex des Acrylglases abweichen. Geeignet sind zum Beispiel Calciumcarbonat, Magnesiumcarbonat, Aluminiumtrihydroxid, Magnesiumhydroxid, Bariumsulfat usw.
Ebenso können Polymere, die im geeigneten Brechungsindexbereich liegen, eingesetzt werden. Zum Beispiel kann im Monomeren Methylmethacrylat Polystyrol gelöst werden, das dann während der Polymerisation ausfällt und zu einem Material mit guter Lichtstreuung führt. Es können aber auch vernetzte Polymerteilchen hinzugefügt werden, z.B. Polymerperlen aus vernetztem Polystyrol oder vernetzte Copolymere aus Methylmethacrylat mit Phenyl(meth)acrylat oder Benzyl(meth)acrylat.The requirement for high transmission with high light scattering is a difficult requirement. High scattering power is achieved by titanium dioxide. Since this colorant but reflects a large part of the light, only low light transmittances are possible. More favorable are colorless scattering pigments which deviate in refractive index to about 0.2 from the refractive index of the acrylic glass. For example, calcium carbonate, magnesium carbonate, aluminum trihydroxide, magnesium hydroxide, barium sulfate, etc. are suitable.
Likewise, polymers which lie in the suitable refractive index range can be used. For example, in the monomer methyl methacrylate, polystyrene can be dissolved which then precipitates during polymerization and results in a material with good light scattering. However, it is also possible to add crosslinked polymer particles, for example polymer beads of crosslinked polystyrene or crosslinked copolymers of methyl methacrylate with phenyl (meth) acrylate or benzyl (meth) acrylate.
Streumittel und Farbmittel können dem Kunststoff bei der Herstellung durch Polymerisation im polymerisierbaren Gemisch (Gussherstellung) oder während thermoplastischer Verarbeitung des Polymers im Schmelzezustand, z. B. mittels Extrusion oder Spritzguß, in an sich bekannter Weise zugesetzt bzw. eingearbeitet werden. Neben der Plattenform können auch beliebige Profile, wie Rohre, Stäbe usw. gefertigt werden.Dispersants and colorants can the plastic in the production by polymerization in the polymerizable mixture (casting) or during thermoplastic processing of the polymer in the melt state, for. B. by extrusion or injection, in a conventional manner added or incorporated. In addition to the plate shape, any profiles, such as pipes, rods, etc. can be manufactured.
Auf diese Weise können z. B. Kunststoffplatten, z. B. mit einer Dicke von z. B. 0,5 bis 10, bevorzugt 1 bis 5 mm erhalten werden, die als Abdeckungen für erfindungsgemäße beleuchtbare Vorrichtungen mit rechteckigen Kästen, Rahmen oder Halterung verwendet werden können. Entsprechende Stücke können je nach Bedarf auch durch Schneiden, Fräsen, Sägen oder sonstige Bearbeitung in praktisch beliebige Formen überführt und angepasst werden.In this way, for. B. plastic plates, z. B. with a thickness of z. B. 0.5 to 10, preferably 1 to 5 mm are obtained, which can be used as covers for illuminable devices according to the invention with rectangular boxes, frame or bracket. Corresponding pieces can be converted and adapted as required by cutting, milling, sawing or other processing in virtually any shape and adapted.
Als nicht fluoreszierende Farbmittel für die Basiseinfärbung eignen sich für die Zwecke der Erfindung bevorzugt nicht fluoreszierende organische Farbmittel, da diese sowohl im Auflicht wie im Durchlicht hohe Brillanz und Leuchtkraft besitzen. Um das Acrylglas gegen die Einflüsse von Licht- und Wetter zu schützen, können noch Lichtschutzmittel, UV-Absorber, Antioxidantien usw. hinzugefügt werden.Non-fluorescent colorants for base coloration are preferably non-fluorescent organic colorants for the purposes of the invention, since they have high brilliance and luminosity both in reflected light and in transmitted light. To protect the acrylic against the effects of light and weather, light stabilizers, UV absorbers, antioxidants, etc. can be added.
Als Farbmittel kommen in Kunststoff insbesondere nicht fluoreszierende lösliche Farbstoffe oder nicht fluoreszierende organische Pigmente aber auch weniger bevorzugt unlösliche anorganische Farbpigmente in Frage. Zu nennen sind beispielhaft:
- Für gelbe Einfärbungen: Pyrazolon-Gelb oder Perinon Orange bzw. Mischungen daraus.
- Für rote Einfärbungen: Mischungen aus Pyrazolon-Gelb oder Antrachinonrot oder Naphtol AS oder DPP-Rot bzw. Mischungen daraus.
- Für grüne Einfärbungen: Cu-Phtalocyanin-Grün oder Pyrazolon-Gelb bzw. Mischungen daraus.
- Für blaue Einfärbungen: Anthrachinon-Blau oder Ultramarin-Blau bzw. Mischungen daraus.
- For yellow colorations: pyrazolone yellow or perinone orange or mixtures thereof.
- For red colorations: mixtures of pyrazolone yellow or anthraquinone red or naphtol AS or DPP red or mixtures thereof.
- For green colorations: Cu-phthalocyanine green or pyrazolone yellow or mixtures thereof.
- For blue colorations: anthraquinone blue or ultramarine blue or mixtures thereof.
Die Normfarbtafel nach DIN 5033 ist dem Fachmann bestens bekannt. Die Normfarbtafel nach DIN 5033 gestattet es, die Farben von Lichtquellen und von Körperfarben (z. B. für Aufstriche, Lichtfilter usw.) eindeutig ihrer Farbart nach einzuordnen.The standard color chart according to DIN 5033 is well known to the person skilled in the art. The standard color chart according to DIN 5033 makes it possible to clearly classify the colors of light sources and body colors (eg for spreads, light filters, etc.) according to their color.
Die Einordnung setzt eine Messung der der Normfarbwertanteile x, y voraus; die Koordinaten bestimmen somit den Farbort einer Farbart eindeutig (z. B. rot, grün, gelb oder blau oder Farbmischungen). Entsprechende Farbmessungen können mit handelsüblichen Farbmessgeräten ausgeführt werden. Derartige Farbmessgeräte gestatten in der Regel eine berührungslose Messung von Lichtquellen und Objektfarben. Geeignet ist z. B. das Farbmessgerät Chroma-Meter® CS-1 00 von Minolta oder aber auch entsprechende Geräte anderer Hersteller.The classification presupposes a measurement of the standard color value components x, y; The coordinates thus uniquely determine the color location of a color type (eg red, green, yellow or blue or color mixtures). Corresponding color measurements can be carried out with commercially available colorimeters. Such colorimeters usually allow a non-contact measurement of light sources and object colors. Suitable is z. For example, the colorimeter Chroma-Meter® CS-1 00 from Minolta or similar equipment from other manufacturers.
Die Normfarbtafel stellt eine Schuhsohlen-artige Fläche in einem x-, y-Koorrdinaten-System dar. Jeder Punkt auf dieser Schuhsohlen-artigen Fläche der Farbtafel repräsentiert eindeutig eine Farbart. Farben gleicher Farbart weisen den gleichen Farbort mit identischen x- und y-Koordinaten auf und können sich nur durch ihre Helligkeit unterscheiden.The standard color chart represents a shoe sole-like area in an x, y coordinate system. Each point on this shoe sole-like area of the color chart clearly represents a color type. Colors of the same color type have the same color location with identical x and y coordinates and can only differ in their brightness.
Im mittleren Bereich der Normfarbtafel liegt der so genannte Unbuntpunkt bei den Koordinaten x = 0,33 und y = 0,33. Der Unbuntpunkt stellt je nach Helligkeit Weiß, Grau bis Schwarz dar. Zwischen dem Unbuntpunkt und der Randkurve der Schuhsohlen-artigen Fläche der Normfarbtafel liegen alle anderen (bunten) Farbarten. Die vom Unbuntpunkt ausgehenden Strahlen enthalten jeweils die Farben gleichen Farbtons in zunehmender Sättigung bzw. zunehmende Brillianz, also von blass bis gesättigt bzw. brilliant. Auf dieser Regel ist die Normfarbtafel aufgebaut.In the middle area of the standard color chart, the so-called achromatic point lies at the coordinates x = 0.33 and y = 0.33. The achromatic point represents white, gray to black depending on the brightness. Between the achromatic point and the edge curve of the shoe sole-like surface of the standard color chart are all other (colorful) color grades. The rays emanating from the uncoloured point each contain the same hue colors in increasing saturation or increasing brilliance, ie from pale to saturated or brilliant. The standard color chart is based on this rule.
Die Randkurve der Schuhsohlen-artigen Fläche der Normfarbtafel setzt sich zusammen aus dem Spektralfarbenzug und der so genannten Purpurlinie. Je weiter sich eine Farbart, definiert durch ihre x-, y-Koordinaten, am Rande der Schuhsohlen-artigen Fläche der Normfarbtafel befindet, desto brillianter erscheint sie. Beispielsweise stehen die Koordinaten x = 0,02, y = 0,7 für ein brilliantes Grün; die Koordinaten x = 0,7, y = 0,26 stehen für ein brillantes Rot; die Koordinaten x = 0,18, y = 0,02 stehen für ein brillantes Blau.The boundary curve of the shoe sole-like surface of the standard color chart is composed of the spectral color train and the so-called purple line. The farther a chromaticity, defined by its x, y coordinates, is at the edge of the shoe sole-like surface of the standard color chart, the more brilliant it appears. For example, the coordinates x = 0.02, y = 0.7 represent a brilliant green; the coordinates x = 0.7, y = 0.26 stand for a brilliant red; the coordinates x = 0.18, y = 0.02 stand for a brilliant blue.
Die Erfindung geht von der Überlegung aus, dass je näher der Farbort der Reflexion der eingefärbten Abdeckung am Farbort der LED liegen, die Übereinstimmung des Farbeindrucks bei Auflicht und bei Durchleuchtung umso besser sein sollte. Es hat sich jedoch gezeigt, dass eine Übereinstimmung einer Einfärbung mit einem vorgegebenen LED-Farbort praktisch nur näherungsweise realisierbar ist. Im allgemeinen können Abweichungen, die auf oder nahe der Geraden liegen, die durch den Unbuntpunkt (x/y = 0,33/0,33) und den Farbort der LED verläuft, eher toleriert werden als Abweichungen, die zwar gleich groß sind, aber weiter abseits von der beschriebenen Geraden entfernt liegen.The invention is based on the consideration that the closer the color point of the reflection of the colored cover at the color location of the LED, the match of the color impression in reflected light and fluoroscopy should be even better. However, it has been shown that a match of a coloring with a given LED color point practically only is approximately feasible. In general, deviations that lie on or near the straight line that passes through the achromatic point (x / y = 0.33 / 0.33) and the color locus of the LED, can be tolerated rather than deviations that are equal, but further away from the described straights lie.
Es ist anzustreben, daß die Farborte möglichst am Rande der Farbnormtafel (s. z. B. DIN 5033 oder entsprechende Standard-Literatur) lokalisiert sind, da die farbliche Brillianz hier am höchstens ist. Dies ergibt sich auch dadurch, daß die Farborte der LEDs aufgrund des monochromatischen Lichts ebenfalls am Rand oder nahe am Rand der Normfarbtafel liegen.It is desirable that the color locations are located as far as possible at the edge of the color standard table (see, for example, DIN 5033 or corresponding standard literature), since the color brilliance here is the maximum. This is also due to the fact that the color locations of the LEDs are also due to the monochromatic light at the edge or near the edge of the standard color chart.
In vielen Fällen können entsprechende Einfärbungen nicht mit einem Farbmittel allein erreicht werden. Bei Mischungen ist darauf zu achten, daß die Einzelkomponenten nicht zu weit auf der Farbnormtafel voneinander entfernt liegen, da der Mischfarbton dann eine zu geringe Brillianz aufweisen kann.In many cases, corresponding colorations can not be achieved with a colorant alone. When mixing, make sure that the individual components are not too far away from each other on the color standard board, as the mixed color may then have too low a brilliance.
Bezogen auf die Normfarbtafel (s. z. B. DIN 5033 oder entsprechende Standard-Literatur) und die Farborte der Reflexion der lichtstreuenden Abdeckung und dem Farbort der verwendeten LED bzw. LEDs, verhalten sich die Beträge der Differenz des x-Wertes der lichtstreuenden Abdeckung mit dem x-Wert der LED und der Betrag der Differenz des y-Wertes der lichtstreuenden Abdeckung mit dem y-Wert der LED sich alternativ wie folgt (s. dazu Beispiel 6):
- a) für blaue LED-Beleuchtung: x
kleiner 0,03 /y kleiner 0,05 - b) für grüne LED-Beleuchtung: x
kleiner 0,05 /y kleiner 0,08 - c) für gelbe LED-Beleuchtung: x
kleiner 0,0025/y kleiner 0,02 - d) für rote LED-Beleuchtung: x
kleiner 0,03 / y kleiner 0,003
- a) for blue LED illumination: x less than 0.03 / y less 0.05
- b) for green LED illumination: x less than 0.05 / y smaller than 0.08
- c) for yellow LED illumination: x less than 0.0025 / y less than 0.02
- d) for red LED illumination: x less than 0.03 / y less 0.003
Die Messung des Farborts der Reflexion der lichtstreuenden Abdeckung erfolgt, indem die lichtstreuende Abdeckung vor einem weißen Hintergrund (z. B. ein weiß lackierter Kasten, siehe die Beispiele) mit einer Tageslichtlampe mit 150 W (D65 nach DIN 6173, Güteklasse 1, z.B. von Siemens) in einem Abstand von 60cm von oben beleuchtet wird und die Farbmessung aus 100 cm Abstand ebenfalls von oben ausgeführt wird. Zur Messung von Farborten stehen dem Fachmann handelsübliche Messgeräte zur Verfügung. Die Farbmessung kann z. B. mit dem Farbmessgerät Chroma-Meter CS-100 von Minolta ausgeführt werden. Der Farbort der LED kann z. B. aus ihrem Emissionsspektrum errechnet werden oder ist aus Herstellerangaben bekannt.The color locus of the reflection of the light-scattering cover is measured by placing the light-scattering cover against a white background (eg a box painted white, see the examples) with a 150 W daylight lamp (D65 according to DIN 6173,
Die verwendeten LEDs können z. B. ein gelbes (bzw. gelb-grünes) Licht abstrahlen und einen Farbort im Bereich der Koordinaten x/y = (0,5/0,5) +/- 0,02 aufweisen.The LEDs used can, for. B. radiate a yellow (or yellow-green) light and have a color location in the range of coordinates x / y = (0.5 / 0.5) +/- 0.02.
Der Kunststoff der Abdeckung kann in diesem Fall eine Basiseinfärbung aus einem Gemisch aus 0,075 bis 0,09, bevorzugt 0,081 bis 0,084 Gew.-% Pyrazolon-Gelb und 0,002 bis 0,004, bevorzugt 0,0028 bis 0,0032 Gew.-% Perinon Orange aufweisen. Zusätzlich ist ein Fluoreszenzfarbstoff, bevorzugt ein Fluoreszenzfarbstoff auf Perylenbasis, besonders bevorzugt der Fluoreszenzfarbstoff Lumogen® F Gelb 170 (BASF), vorzugsweise in einer Konzentration von 0,005 bis 0,015 Gew.-%, enthalten sein.The plastic of the cover in this case may be a base color of a mixture of 0.075 to 0.09, preferably 0.081 to 0.084 wt .-% pyrazolone yellow and 0.002 to 0.004, preferably 0.0028 to 0.0032 wt .-% perinone orange exhibit. In addition, a fluorescent dye, preferably a perylene-based fluorescent dye, more preferably the fluorescent dye Lumogen® F Yellow 170 (BASF), preferably in a concentration of 0.005 to 0.015 wt .-%, be contained.
Es ist günstig, diese Einfärbung mit BaSO4 als Streumittel in einer Menge von 1,5 bis 2,5 Gew.-% zu kombinieren.It is convenient to combine this coloring with BaSO 4 as a spreading agent in an amount of 1.5 to 2.5 wt .-%.
Die verwendeten LEDs können z. B. rotes Licht abstrahlen und einen Farbort im Bereich der Koordinaten x/y = (0,67/0,33) +/- 0,02 aufweisen.The LEDs used can, for. B. radiate red light and have a color location in the range of coordinates x / y = (0.67 / 0.33) +/- 0.02.
Der Kunststoff der Abdeckung kann in diesem Fall eine Basiseinfärbung aus 0,2 bis 0,3, bevorzugt 0,22 bis 0,28 Gew.-% Pyrazolon-Gelb aufweisen. Zusätzlich ist ein Fluoreszenzfarbstoff, bevorzugt ein Fluoreszenzfarbstoff auf Perylenbasis, besonders bevorzugt der Fluoreszenzfarbstoff Lumogen® F Rot 305 (BASF), vorzugsweise in einer Konzentration von 0,0025 bis 0,0075 Gew.-%, enthalten sein.The plastic of the cover in this case may have a base coloring of 0.2 to 0.3, preferably 0.22 to 0.28 wt .-% pyrazolone yellow. In addition, a fluorescent dye, preferably a perylene-based fluorescent dye, more preferably the fluorescent dye Lumogen® F Red 305 (BASF), preferably in a concentration of 0.0025 to 0.0075 wt .-%, be included.
Es ist günstig, diese Einfärbung mit Polystyrol als Streumittel in einer Menge von 1,5 bis 2,5 Gew.-% zu kombinieren.It is convenient to combine this coloring with polystyrene as a spreading agent in an amount of 1.5 to 2.5 wt .-%.
Die verwendeten LEDs können z. B. ein grünes Licht abstrahlen und einen Farbort im Bereich der Koordinaten x/y = (0,16/0,73) +/- 0,02 aufweisen.The LEDs used can, for. B. radiate a green light and have a color location in the range of coordinates x / y = (0.16 / 0.73) +/- 0.02.
Der Kunststoff der Abdeckung kann in diesem Fall eine Basiseinfärbung aus 0,03 bis 0,05, bevorzugt 0,035 bis 0,045 Gew.-% Cu-Phtalocyanin-Grün aufweisen. Zusätzlich kann ein Fluoreszenzfarbstoff, bevorzugt ein Fluoreszenzfarbstoff auf Perylenbasis, besonders bevorzugt der Fluoreszenzfarbstoff Fluoreszenzfarbstoff Lumogen® F Gelb 083 (BASF), vorzugsweise in einer Konzentration von 0,01 bis 0,03 Gew.-%, enthalten sein.The plastic of the cover in this case may have a base color of 0.03 to 0.05, preferably 0.035 to 0.045 wt .-% Cu-phthalocyanine green. In addition, a fluorescent dye, preferably a perylene-based fluorescent dye, more preferably the fluorescent dye fluorescent dye Lumogen® F Yellow 083 (BASF), preferably in a concentration of 0.01 to 0.03 wt .-%, may be included.
Es ist günstig diese Einfärbung mit BaSO4 oder Polystyrol als Streumittel in einer Menge von 1,5 bis 2,5 Gew.-% zu kombinieren.It is convenient to combine this coloring with BaSO 4 or polystyrene as a spreading agent in an amount of 1.5 to 2.5 wt .-%.
Die verwendeten LEDs können z. B. ein blaues Licht abstrahlen und einen Farbort im Bereich der Koordinaten x/y = (0,14/0,06) +/- 0,02 aufweisen.The LEDs used can, for. B. radiate a blue light and have a color location in the range of coordinates x / y = (0.14 / 0.06) +/- 0.02.
Der Kunststoff der Abdeckung kann auch mit 0,005 bis 0,015, bevorzugt 0,007 bis 0,012 Gew.-% Anthrachinon-Blau eingefärbt sein. Zusätzlich ist ein Fluoreszenzfarbstoff, bevorzugt ein Fluoreszenzfarbstoff auf Perylenbasis, besonders bevorzugt der Fluoreszenzfarbstoff Fluoreszenzfarbstoff Lumogen® F Violett 570 (BASF), vorzugsweise in einer Konzentration von 0,05 bis 0,15 Gew.-%, enthalten sein.The plastic of the cover may also be colored with 0.005 to 0.015, preferably 0.007 to 0.012 wt .-% anthraquinone blue. In addition, a fluorescent dye, preferably a perylene-based fluorescent dye, more preferably the fluorescent dye fluorescent dye Lumogen® F Violet 570 (BASF), preferably in a concentration of 0.05 to 0.15 wt .-%, be contained.
Es ist günstig, diese Einfärbung mit Polystyrol als Streumittel in einer Menge von 1,5 bis 2,5 Gew.-% zu kombinieren.It is convenient to combine this coloring with polystyrene as a spreading agent in an amount of 1.5 to 2.5 wt .-%.
In einer bevorzugten Ausführungsform enthält der Kunststoff der Abdeckung zusätzlich TiO2 in einer Konzentration von 0,001 bis 0,05 Gew.-%. Dadurch kann nochmals eine Erhöhung des Reflexionswerts um etwa 2 bis 10 % erreicht werden. Bei visueller Betrachtung mit dem bloßen Auge erscheint die Brillianz der Einfärbung nochmals durchaus merklich erhöht.In a preferred embodiment, the plastic of the cover additionally contains TiO 2 in a concentration of 0.001 to 0.05 wt .-%. As a result, an increase of the reflection value by about 2 to 10% can be achieved again. When viewed visually with the naked eye, the brilliance of the coloring appears to be markedly increased again.
In der erfindungsgemäßen Vorrichtung werden die beschriebenen streumittelhaltigen, eingefärbten Kunststoffelemente als Abdeckung als auch farbige LEDs als Lichtquelle verwendet.In the apparatus according to the invention, the described streumittelhaltigen, colored plastic elements are used as a cover and colored LEDs as a light source.
Die Leuchtdichten Y in Cd/m2 im Auflicht gemessen (s. Beispiel 6) liegen bei erfindungsgemäß farblich eingestellten lichtstreuenden Abdeckungen:
- Bei Abdeckungen für blaue LED-Beleuchtung größer/gleich 12,5 Cd/m2,
- bei Abdeckungen für grüne LED-Beleuchtung größer/
gleich 30, bevorzugt größer/gleich 40 besonders bevorzugt größer/gleich 50 Cd/m2, - bei Abdeckungen für gelbe LED-Beleuchtung größer/gleich 100, bevorzugt größer/gleich 110 besonders bevorzugt größer/gleich 120 Cd/m2,
- bei Abdeckungen für rote LED-Beleuchtung größer/gleich 25, bevorzugt größer/
gleich 30 besonders bevorzugt größer/gleich 40 Cd/m2.
- For blue LED lighting covers greater than or equal to 12.5 cd / m 2 ,
- for covers for green LED illumination greater than or equal to 30, preferably greater than / equal to 40, particularly preferably greater than or equal to 50 Cd / m 2 ,
- in the case of covers for yellow LED lighting greater than or equal to 100, preferably greater than / equal to 110, particularly preferably greater than or equal to 120 Cd / m 2 ,
- for covers for red LED lighting greater than or equal to 25, preferably greater than / equal to 30, particularly preferably greater than / equal to 40 Cd / m 2 .
Die Messung der Leuchtdichte Y in Cd/m2 der lichtstreuenden Abdeckung erfolgt, indem die lichtstreuende Abdeckung vor einem weißen Hintergrund (z. B. ein weiß lackierter Kasten, siehe die Beispiele) mit einer Tageslichtlampe mit 150 W (D65 nach DIN 6173, Güteklasse 1, z.B. von Siemens) in einem Abstand von 60cm von oben beleuchtet wird und die Leuchtdichte-Messung aus 100 cm Abstand ebenfalls von oben ausgeführt wird. Zur Messung von Leuchtdichten stehen dem Fachmann handelsübliche Messgeräte zur Verfügung. Die Leuchtdichte-Messung kann z. B. mit dem Farbmessgerät Chroma-Meter CS-100 von Minolta ausgeführt werden, das Farborte und Leuchtdichten misst.The luminance Y is measured in Cd / m 2 of the light-scattering cover by placing the light-scattering cover against a white background (eg a box painted white, see the examples) with a 150 W daylight lamp (D65 according to DIN 6173,
Die Remissionsmessung kann z. B. unter Bestimmung der gemischten Reflexion erfolgen, d.h. die Anteile der gerichteten Reflexion und der gestreuten Reflexion werden erfasst (DIN 5036, Teil 1 Punkt 6).
Die Transmissionsmessung z. B. kann unter Bestimmung der gemischten Transmission erfolgen, d.h. die Anteile der gerichteten Transmission und der gestreuten Transmission werden erfasst (DIN 5036, Teil 1 Punkt 7).
Die dabei gewählte Anordnung der Messgeometrie ist bevorzugt gerichtet /halbräumlich (DIN 5036, Teil 3, Punkt 2 oder 3 und Tab.1)
Der Aufbau der Messanordnung (Zweistrahl-Messgerät mit Ulbrichtscher Kugel) erfolgt bevorzugt nach DIN EN ISO 13468-2 und DIN 5036, Teil 3, Punkt. 4)The remission measurement can z. B. under determination of the mixed reflection, ie, the proportions of the directed reflection and the scattered reflection are detected (DIN 5036,
The transmission measurement z. B. can be done by determining the mixed transmission, ie, the proportions of the directional transmission and the scattered transmission are recorded (DIN 5036,
The chosen arrangement of the measuring geometry is preferably directional / semi-spatial (DIN 5036,
The construction of the measuring arrangement (two-beam measuring instrument with integrating sphere) is preferably carried out according to DIN EN ISO 13468-2 and DIN 5036,
Die Messung des Streuwertes erfolgt bevorzugt unter Bestimmung der Leuchtdichte bei verschiedenen Winkeln (DIN 5036, Teil 1, Punkt 5.1)
Der Messaufbau kann z. B. nach ASTM E 2387-05 erfolgen.The measurement of the scattering value is preferably carried out by determining the luminance at different angles (DIN 5036,
The measurement setup can z. B. according to ASTM E 2387-05.
Bei einer spektralen Messung ist das Messergebnis praktisch unabhängig von der Wahl der Lichtquelle. Diese soll jedoch so beschaffen sein, dass im gewünschten Wellenlängenbereich (i. d. Regel im gesamten sichtbaren Bereich zwischen 380nm und 780nm) Licht ausgesendet wird.In a spectral measurement, the measurement result is practically independent of the choice of the light source. However, this should be such that in the desired wavelength range (usually in the entire visible range between 380nm and 780nm) light is emitted.
Einem Fachmann sind die in der Erfindung genannten Messgrößen, Messmethoden und einschlägigen Normen bestens bekannt. Er kann aufgrund seines Fachwissens geeignete Bedingungen und Anordnungen für alle notwendigen Messungen auswählen. Der Fachmann kann im Einzelfall gegebenenfalls Anpassungen an die Anforderungen der zu messenden Proben vornehmen oder vorgegebene Messbedingungen sinnvoll modifizieren. Es ist grundsätzlich auch möglich, dass im Einzelfall mehrere Messmethoden oder Modifikationen von Messmethoden zur Feststellung der im Rahmen der Erfindung genannten Messgrößen gleichermaßen geeignet sind. Der Fachmann gelangt aufgrund seines Fachwissens und anhand der hier offenbarten Angaben und Hinweise selbstständig zu verlässlichen und reproduzierbaren Messergebnissen im Sinne der vorliegenden Erfindung.A person skilled in the art will be familiar with the measured variables, measuring methods and relevant standards mentioned in the invention. He can select suitable conditions and arrangements for all necessary measurements due to his expertise. In some cases, the person skilled in the art may make adjustments to the requirements of the samples to be measured or usefully modify given measurement conditions. In principle, it is also possible that in individual cases several measuring methods or modifications of measuring methods for determining the measured variables mentioned in the context of the invention are equally suitable. On the basis of his specialist knowledge and based on the information and instructions disclosed here, the person skilled in the art independently obtains reliable and reproducible measurement results in the sense of the present invention.
In 1000 Teilen präpolymerem Metylmethacrylat-Sirup (Viskosität ca. 1000 cP) werden
1 Teil 2,2'-Azobis-(2,4-dimethylvaleronitril) gelöst.
In diesen Ansatz gibt man eine Farbpaste bestehend aus
3 Teilen eines löslichen Polymethylmethacrylatharzes,
20 Teilen Bariumsulfat und den Farbmitteln nach Tabelle 1, die in
30 Teilen Methylmethacrylat mit einem schnelllaufenden Dispergator
(Rotor/Stator-Prinzip) dispergiert wird, hinzu.
Der Ansatz wird intensiv gerührt, in eine mit 3mm dicken Schnur distanzierten Silikatglaskammer gefüllt und im Wasserbad bei 45°C etwa 16 Stunden lang polymerisiert. Die Endpolymerisation erfolgt im Temperschrank bei 115°C für etwa 4 Stunden.In 1000 parts prepolymer Metylmethacrylat syrup (viscosity about 1000 cP) are
1 part of 2,2'-azobis- (2,4-dimethylvaleronitrile) dissolved.
In this approach, one gives a color paste consisting of
3 parts of a soluble polymethylmethacrylate resin,
20 parts of barium sulfate and the colorants according to Table 1 , which in
30 parts of methyl methacrylate with a high-speed dispersant
(Rotor / stator principle) is dispersed, added.
The mixture is stirred vigorously, filled into a silicate glass chamber which is distanced with 3 mm thick cord and polymerized in a water bath at 45 ° C. for about 16 hours. The final polymerization is carried out in a tempering at 115 ° C for about 4 hours.
Herstellung wie in Beispiel 1, aber mit den Farbmitteln gemäß Tabelle 2 Preparation as in Example 1, but with the colorants according to Table 2
Herstellung wie in Beispiel 1, aber mit den Farbmitteln gemäß Tabelle 3
In einem weißlackierten, oben offenen Blechkasten der Maße 90 x 470 mm und 100mm Höhe sind am Innenboden jeweils 32 Leuchtdioden, z.B. von OSRAM (8 Module a'4 LED's) angebracht (Es gibt von vielen Herstellern Standard-LED's, die zueinander einen vergleichbaren Farbton haben). Mit einem Netzteil wird bei einer Betriebsspannung von 10V der zulässige Betriebsstrom von je nach Type zwischen 320 - 400mA eingestellt.
Die oben beschriebenen Muster werden auf diesen Kasten aufgelegt und farblich beurteilt. Die Auflichtprüfung (Tagwirkung) erfolgt durch Beleuchtung mit einer Tageslichtlampe mit 150 W (D65 nach DIN 6173, Güteklasse 1, z.B. von Siemens) in einem Abstand von ca. 60cm von oben. Die LED's sind dabei abgeschaltet. Die Durchlichtprüfung erfolgt in einem abgedunkelten Raum bei eingeschalteten LED's nach obiger Betriebsangabe. Die Farbmessungen werden mit dem Farbmessgerät Chroma-Meter CS-100 von Minolta durchgeführt. Dieses Gerät lässt berührungslose Messungen von Lichtquellen und Objektfarben zu. Der Abstand Probe/Gerät beträgt 1 m. Die Leuchtdichte Y in Cd/m2 wird dabei auch mit diesem Gerät gemessen.In a white-lacquered, open-topped metal box measuring 90 x 470 mm and 100mm in height, 32 light-emitting diodes, eg from OSRAM (8 modules a'4 LEDs), are mounted on the bottom. (There are standard LEDs from many manufacturers which have a comparable color to each other to have). With a power supply, the permissible operating current of between 320 and 400mA is set at an operating voltage of 10V, depending on the type.
The patterns described above are placed on this box and assessed by color. The incident light test (daytime effect) is performed by illumination with a daylight lamp with 150 W (D65 according to DIN 6173,
Die Ergebnisse der Farbmessungen und Leuchtdichten bei LED Hinterleuchtung (Farborte der Transmission) der lichtstreuenden Abdeckungen gemäß den Beispielen 1 und 2 sind in Tabelle 4 dargestellt. Tabelle 5 zeigt zum Vergleich entsprechende Farbmessungen und Leuchtdichten von den Vergleichsversuchen aus Beispiel 3.The results of color measurements and luminances in LED backlighting (color loci of transmission) of the light-diffusing covers according to Examples 1 and 2 are shown in Table 4 . Table 5 shows for comparison corresponding color measurements and luminances of the comparative experiments of Example 3.
Die Ergebnisse (Tab. 4) zeigen, dass mit den nach obiger Vorgehensweise hergestellten farbigen Acrylgläsern, gegenüber den Einfärbungen, die dem Stand der Technik entsprechen (Tab. 5), bei LED-Hinterleuchtung (Nachtwirkung) im Farbort der Transmission nur unwesentlich voneinander abweichen. Die Lichtstreuung ist so gut, dass bei einem Abstand von nur 40mm zur LED, eine gleichmäßige Ausleuchtung erreicht wird.The results (Table 4) show that with the colored acrylic glasses produced according to the above procedure, the colorings corresponding to the prior art (Table 5) differ only insignificantly with LED backlighting (night effect) in the color locus of the transmission , The light diffusion is so good that with a distance of only 40mm to the LED, a uniform illumination is achieved.
Werden die Farbkoordinaten nach Tab.4 in die Normfarbtafel (s. z. B. DIN 5033 oder entsprechende Standard-Literatur) eingetragen, ist ersichtlich, dass die Werte (und damit die Farbtöne) in den von der Erfindung geforderten Grenzen nahe der Linie der farbtongleichen Wellenlänge (Linie zwischen Unbuntpunkt und Farbort der jeweiligen LED-Farbe) liegen. Bei der visuellen Prüfung ist die gute Übereinstimmung des Farbtones bei Auf- und Durchlicht erkennbar.If the color coordinates according to Tab. 4 are entered in the standard color chart (see, for example, DIN 5033 or corresponding standard literature), it can be seen that the values (and therefore the color tones) in the limits required by the invention are close to the line of the color-tone-like wavelength ( Line between achromatic point and color location of the respective LED color) are. In the visual examination, the good match of the color tone in incident and transmitted light can be seen.
Nach
Die Ergebnisse der Farbmessungen und Leuchtdichten bei Auflicht (Farborte der Reflexion bzw. Remission) der lichtstreuenden Abdeckungen gemäß den Beispielen 1 und 2 sind in Tabelle 6 dargestellt. Tabelle 7 zeigt zum Vergleich entsprechende Farbmessungen und Leuchtdichten von den Vergleichsversuchen aus Beispiel 3.The results of the color measurements and luminances in reflected light (color loci of reflection) of the light-diffusing covers according to Examples 1 and 2 are shown in Table 6 . Table 7 shows for comparison corresponding color measurements and luminances of the comparative experiments of Example 3.
Die Ergebnisse der Leuchtdichten Y in Cd/m2 (Tab. 6) zeigen, dass mit den nach obiger Vorgehensweise hergestellten farbigen Acrylgläsern, gegenüber den Einfärbungen, die dem Stand der Technik entsprechen (Tab. 7), deutlich höhere Brillanzen im Auflicht (Tagwirkung) erreicht werden.The results of the luminous densities Y in Cd / m 2 (Table 6) show that with the colored acrylic glasses produced according to the above procedure, compared to the colorations which correspond to the prior art (Table 7), significantly higher brilliance in reflected light (day effect ) can be achieved.
Claims (18)
- Apparatus for illumination with blue, green, yellow or red light-emitting diodes (LEDs), comprising one or more coloured LEDs and a light-scattering cover associated with the LED colour and composed of coloured plastic and having a base colour derived from one or more non-fluorescent dyes, characterized in that
the light-scattering cover comprises, in addition to the base colour, at least one fluorescent dye associated in terms of colour with the base colour, where the dye mixture has been adjusted in such a way that the reflectance of the light-scattering cover is at least 28% at the wavelength of the energy maximum of the LED(s) used, where, based on the standard chromaticity diagram and on the colour loci of the reflected light from the light-scattering cover and on the colour locus of the LED(s) used, the following alternative relationship applies to the absolute value of the difference between the x value of the light-scattering cover and the x value of the LED and the absolute value of the difference between the y value of the light-scattering cover and the y value of the LED:a) for blue LED illumination: absolute value for x smaller than 0.03/absolute value for y smaller than 0.05b) for green LED illumination: absolute value for x smaller than 0.05/absolute value for y smaller than 0.08c) for yellow LED illumination: absolute value for x smaller than 0.0025/absolute value for y smaller than 0.02d) for red LED illumination: absolute value for x smaller than 0.03/absolute value for y smaller than 0.003. - Apparatus according to Claim 1, characterized in that a fluorescent dye is present which emits light in the region of the wavelength of the energy maximum of the coloured LEDs used.
- Apparatus according to Claim 1 or 2, characterized in that a fluorescent dye is present which is a perylene derivative.
- Apparatus according to one or more of Claims 1 to 3, characterized in that the separation between the LEDs and the light-scattering cover is from 3 to 12 cm.
- Apparatus according to one or more of Claims 1 to 4, characterized in that the light-scattering cover is composed of a cast or extruded polymethyl methacrylate plastic.
- Apparatus according to one or more of Claims 1 to 5, characterized in that the light-scattering coefficient, measured to DIN 5036, of the plastic of the cover is at least 0.5.
- Apparatus according to Claim 6, characterized in that the light-scattering agent present comprises BaSO4, polystyrene or light-scattering beads composed of a crosslinked plastic.
- Apparatus according to Claim 7, characterized in that the light-scattering agent used comprises an amount of from 1.5 to 2.5% by weight of BaSO4 or polystyrene.
- Apparatus according to one or more of Claims 1 to 8, characterized in that the location of the LEDs is in a box or frame which is covered by the light-scattering cover.
- Apparatus according to one or more of Claims 1 to 9, characterized in that the colour loci of the transmitted and the reflected light from the coloured cover composed of plastic, based on the standard chromaticity diagram, are in a region whose distance, based on a straight line which runs through the achromatic point (x/y = 0.33/0.33) and through the colour locus of the LED, is not more than 0.2 x/y units from the colour locus of the LED in the direction of the straight line and not more than 0.05 x/y units in the directions perpendicular to the two sides of the straight line.
- Apparatus according to one or more of Claims 1 to 10, characterized in that the LEDs emit yellow light and their colour locus is within the range of coordinates x/y = (0.5/0.5) +/- 0.02.
- Apparatus according to one or more of Claims 1 to 10, characterized in that the LEDs emit red light and their colour locus is within the range of coordinates x/y = (0.67/0.33) +/- 0.02.
- Apparatus according to one or more of Claims 1 to 10, characterized in that the LEDs emit green light and their colour locus is within the range of coordinates x/y = (0.16/0.73) +/- 0.02.
- Apparatus according to one or more of Claims 1 to 10, characterized in that the LEDs emit blue light and their colour locus is within the range of coordinates x/y = (0.14/0.06) +/- 0.02.
- Apparatus according to one or more of Claims 1 to 14, characterized in that the plastic of the cover also comprises TiO2 at a concentration of from 0.001 to 0.05% by weight.
- Apparatus according to one or more of Claims 1 to 15, characterized in that the transmittance of the light-scattering cover is at least 20%.
- Use, as cover for an illuminable apparatus according to one or more of Claims 1 to 16, of a coloured plastics element comprising scattering agent.
- Use, as light source in an illuminable apparatus according to one or more of Claims 1 to 16, of LEDs emitting coloured and, respectively, almost monochromatic light.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005054591A DE102005054591A1 (en) | 2005-11-14 | 2005-11-14 | Device for lighting with blue, green, yellow or red LEDs |
PCT/EP2006/068280 WO2007054532A2 (en) | 2005-11-14 | 2006-11-09 | Device for illuminating using blue, green, yellow, or red light emitting diodes |
Publications (2)
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EP1948727A2 EP1948727A2 (en) | 2008-07-30 |
EP1948727B1 true EP1948727B1 (en) | 2011-03-02 |
Family
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Family Applications (1)
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EP06819357A Not-in-force EP1948727B1 (en) | 2005-11-14 | 2006-11-09 | Device for illuminating using blue, green, yellow, or red light emitting diodes |
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US (1) | US20090146548A1 (en) |
EP (1) | EP1948727B1 (en) |
JP (1) | JP2009516341A (en) |
KR (1) | KR20080074125A (en) |
CN (1) | CN101287785A (en) |
AT (1) | ATE500292T1 (en) |
AU (1) | AU2006311014A1 (en) |
BR (1) | BRPI0618544A2 (en) |
CA (1) | CA2622785A1 (en) |
DE (2) | DE102005054591A1 (en) |
ES (1) | ES2360879T3 (en) |
MX (1) | MX2008004996A (en) |
TW (1) | TW200736545A (en) |
WO (1) | WO2007054532A2 (en) |
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DE102007030263A1 (en) * | 2007-06-28 | 2009-01-08 | Evonik Röhm Gmbh | Illuminable device |
CN101725843B (en) * | 2008-10-20 | 2012-07-04 | 展晶科技(深圳)有限公司 | System and method for configuring LED backlight module with high color saturation |
BR112012022991A8 (en) * | 2010-03-16 | 2018-04-03 | Koninklijke Philips Electronics Nv | LIGHTING APPARATUS, MANUFACTURING METHOD FOR MANUFACTURING A LIGHTING APPLIANCE AND LIGHTING METHOD |
BR112013006778A2 (en) | 2010-09-28 | 2019-09-24 | Koninklijke Philips Eletronics N V | "light emitting disposition" |
TW201221860A (en) * | 2010-10-06 | 2012-06-01 | Koninkl Philips Electronics Nv | Light-emitting arrangement with organic phosphor |
PL2678403T3 (en) * | 2011-02-24 | 2016-08-31 | Basf Se | Novel illumination devices |
EP2686603B1 (en) * | 2011-03-16 | 2016-10-26 | Philips Lighting Holding B.V. | A lighting device, a lamp and a luminaire |
KR101424391B1 (en) * | 2013-04-23 | 2014-07-28 | 금호전기주식회사 | Straight type LED fluorescent lamp |
FR3087776B1 (en) * | 2018-10-26 | 2021-07-30 | Arkema France | POLYMER COMPOSITION COMPRISING PARTICLES AND A COLORANT, ITS PREPARATION PROCESS AND ITS USE |
DE102019004782A1 (en) | 2019-07-09 | 2020-01-16 | Daimler Ag | Layer body assembly |
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DE3323951A1 (en) | 1983-07-02 | 1985-01-03 | Röhm GmbH, 6100 Darmstadt | ACRYLATE RESINS AS BINDERS FOR COLOR CONCENTRATES |
JPS61159440A (en) | 1985-01-07 | 1986-07-19 | Asahi Chem Ind Co Ltd | Light-scattering acrylic resin composition |
US6600175B1 (en) * | 1996-03-26 | 2003-07-29 | Advanced Technology Materials, Inc. | Solid state white light emitter and display using same |
WO1998042799A1 (en) * | 1997-03-21 | 1998-10-01 | Merck Patent Gmbh | Pigment flakes |
DE60137632D1 (en) * | 2000-08-18 | 2009-03-26 | Teijin Chemicals Ltd | CLOTH-SHAPED STRUCTURE WITH ATTRACTIVE APPEARANCE AND ITS APPLICATION |
DE10162360A1 (en) * | 2001-12-18 | 2003-07-03 | Roehm Gmbh | Illuminable device |
JP4161042B2 (en) * | 2002-02-14 | 2008-10-08 | 株式会社アーテックインターナショナル | Light source device for display |
DE10244706A1 (en) * | 2002-09-24 | 2004-03-25 | Röhm GmbH & Co. KG | A shaped body from a plastics matrix of transparent plastics containing a soluble fluorescent dye and a scattering agent useful for automobile bodies, designer furniture, road signs or for illuminated advertising signs |
DE10323789A1 (en) * | 2003-05-23 | 2004-12-09 | Röhm GmbH & Co. KG | Shaped body for light advertising and process for its preparation |
-
2005
- 2005-11-14 DE DE102005054591A patent/DE102005054591A1/en not_active Withdrawn
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2006
- 2006-11-09 JP JP2008540584A patent/JP2009516341A/en active Pending
- 2006-11-09 TW TW095141534A patent/TW200736545A/en unknown
- 2006-11-09 DE DE502006009026T patent/DE502006009026D1/en active Active
- 2006-11-09 CA CA002622785A patent/CA2622785A1/en not_active Abandoned
- 2006-11-09 WO PCT/EP2006/068280 patent/WO2007054532A2/en active Application Filing
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- 2006-11-09 CN CNA2006800379083A patent/CN101287785A/en active Pending
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BRPI0618544A2 (en) | 2011-09-06 |
WO2007054532A2 (en) | 2007-05-18 |
TW200736545A (en) | 2007-10-01 |
CA2622785A1 (en) | 2007-05-18 |
KR20080074125A (en) | 2008-08-12 |
US20090146548A1 (en) | 2009-06-11 |
AU2006311014A1 (en) | 2007-05-18 |
MX2008004996A (en) | 2008-11-13 |
JP2009516341A (en) | 2009-04-16 |
DE502006009026D1 (en) | 2011-04-14 |
WO2007054532A3 (en) | 2007-07-05 |
CN101287785A (en) | 2008-10-15 |
ATE500292T1 (en) | 2011-03-15 |
EP1948727A2 (en) | 2008-07-30 |
ES2360879T3 (en) | 2011-06-09 |
DE102005054591A1 (en) | 2007-05-16 |
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