Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q5/00—Preparations for care of the hair
  • A61Q5/12—Preparations containing hair conditioners
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
  • A61K8/11—Encapsulated compositions
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
  • A61K8/26—Aluminium; Compounds thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
  • A61K8/29—Titanium; Compounds thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
  • A61K8/41—Amines
  • A61K8/416—Quaternary ammonium compounds
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
  • A61K8/89—Polysiloxanes
  • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
  • A61K8/89—Polysiloxanes
  • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
  • A61K8/892—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
  • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
  • A61K8/89—Polysiloxanes
  • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
  • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/41—Particular ingredients further characterized by their size
  • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
  • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
  • A61K2800/42—Colour properties
  • A61K2800/43—Pigments; Dyes
  • A61K2800/436—Interference pigments, e.g. Iridescent, Pearlescent

Definitions

• the present invention relates to a conditioning and shine enhancing aqueous composition for keratin fibres especially human hair.
• Hair conditioning compositions have widely been used for improving primarily combability of hair and, furthermore, enhancing smoothness, elasticity and shine.
• Many type of conditioners have been found on the market varying from emulsions, which are generally rinsed of from hair after application and certain period of processing time, to low viscosity lotions used without rinsing off after application.
• Hair shine improvement has been one of the main areas of development. Hair shine is very much related to the surface structure of hair and varies very much with the degree of damage either by environmental effects or chemical treatment of hair such as permanent shaping or oxidative colouring. Although consumers with healthy, non-damaged hair are generally satisfied with hair shine, shine of damaged hair is usually found to be unsatisfactory. There have been studies aiming improving shine of especially damaged hair.
• composition comprising at least one silicone compound and a colour effect pigment of synthetic mica coated with metal oxide or oxides improves shine and conditions hair excellently in terms of combability, elasticity, smoothness and softness.
• the subject of the present invention is an aqueous composition
• aqueous composition comprising at least one silicone compound at a concentration of 0.01 to 10% by weight, and at least one colour effect pigment consisting of synthetic mica coated with metal oxide or oxides and having a volume particle size distribution in the range of 1 to 750 ⁇ m at a concentration of 0.01 to 10% by weight, calculated to total composition.
• Suitable metal oxide or oxides for coating synthetic mica are titanium dioxide, chromium oxide, ferric oxide or mixtures thereof.
• the preferred is synthetic mica coated with titanium dioxide.
• Such materials are commercially available from Sun Chemical Corporation and known with their INCI names Synthetic Fluorphologopite.
• the volume particle size distribution of synthetic mica coated with a metal oxide or oxides is in the range of 1 to 750 ⁇ m, preferably 1 to 250 ⁇ m, more preferably 1 to 100 ⁇ m and most preferably 20 to 95 ⁇ m.
• the particle sizes referred are relating to the volume particle size distribution meaning that particles found in the coated synthetic mica having volume particle size in the given ranges.
• Concentration of synthetic mica coated with at least metal oxide or oxides is from 0.001 to 10%, preferably 0.05 to 7.5%, more preferably 0.1 to 5% and most preferably 0.25 to 2.5% by weight calculated to total composition.
• compositions of the present invention comprise at least one silicone compound at a concentration of 0.01 to 10%, preferably 0:05 to 7.5%, more preferably 0.1 to 5% by weight calculated to total composition.
• Suitable silicone compounds are those water soluble or insoluble organosiloxane polymers having a linear or cyclic or branched or cross-linked structure, volatile or nonvolatile with variable molecular weight which are commercially largely available for conditioning keratin fibres especially human hair.
• Suitable polysiloxanes may be volatile or non volatile, substituted with linear or branched, saturated or unsaturated alkyl or alkoxy chain, or with an amine group or with an aromatic group such as phenyl.
• silicones are aminated silicones with at least one primary, secondary tertiary, or quaternary amine group.
• suitable silicones are aminated silicones with at least one primary, secondary tertiary, or quaternary amine group.
• Example to such compounds are amodimethicone commercially available from Dow Corning under the trade name DC 949 or polysilicone-9 commercially available from Kao Corporation, trimethylsilylamodimethicone commercially available under trade name Q2-8220 from Dow Corning.
• the cationic polymers also include the quaternized products of graft polymers from organopolysiloxanes and polyethyl oxazolines described in EP-A 524 612 and EP-A 640 643 .
• Suitable non-limiting examples of polyoxyalkylenated silicones are those available from Goldschmidt under the trade name Abil, from Rhodia Chemie under the trade name Mirasil, from Dow Corning under trade names such as DC Fluid 190, DC 3225 C, Q2-5220, from Shin Etsu under trade name KF 351, from Wacker under trade name Belsil.
• the composition can be in form of two phases which should be shaken to homogeneity prior to application.
• compositions of the present invention can be in the form of a thin liquid, emulsion, thickened liquid and gel.
• the compositions are in the form of a thin liquid, it may be that metal oxide or oxides coated synthetic particles are precipitated so that should be used after uniformly distributing the particles in the composition by agitation for example by shaking prior to application.
• metal oxide or oxides coated synthetic mica particles prior to application onto keratin fibres with a composition comprising at least one silicone compound.
• Emulsion, thickened liquid and gel compositions are preferred within the meaning of the present invention.
• another subject of the present invention is process for treating keratin fibres especially human hair wherein synthetic mica coated with metal oxide or oxides is added into the composition comprising at least one silicone compound prior to application onto hair,
• compositions comprise additionally a thickening agent.
• compositions comprise additionally a gelling agent and the gelling agent is a polymer forming a shear thinning gel
• the thickening agents include any polymer either natural or synthetic thickening aqueous composition. Examples are cellulose and its derivatives such as hydroxyethylcellulose, guar and its derivatives such as hydroxypropyl guar. In the selection of the thickening gels compatibility with cationic surfactant should be carefully examined.
• the gelling agents include polymers either synthetic or natural forming shear thinning compositions.
• examples to the natural polymers are xanthan gum and its derivatives.
• Synthetic shear thinning polymers may be those of acrylate polymers wherein compatibility with cationic surfactant should carefully be examined prior to use.
• Concentration of the thickening and/or gelling agents should be in the range of 0.05 to 5%, preferably 0.1 to 2.5% by weight calculated to total content. It should also be noted that gelling and thickening polymers can be used together.
• Emulsions according to the present invention preferably comprise at least one fatty alcohol with linear of branched alkyl chain. Suitable ones are fatty alcohols having 12 to 22 C atoms in its alkyl chain. Examples are myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol and their mixtures. Preferred are cetyl, stearyl and behenyl alcohol and their mixtures i.e. cetearyl alcohol. Fatty alcohols may be included into the compositions of the present invention at a concentration of 0.1 to 20%, preferably 0.5 to 15% and more preferably 1 to 10% by weight calculated to total composition.
• At least one cationic surfactant is selected from the compounds with the general formula where R 1 s a saturated or unsaturated, branched or non-branched alkyl chain with 8-22 C atoms or R 5 CO NH (CH 2 ) n where R 5 is saturated or unsaturated, branched or non-branched alkyl chain with 7-21 C atoms and n has typical value of 0 -4 or R 5 CO O (CH 2 ) n where R 6 is saturated or unsaturated, branched or non-branched alkyl chain with 7-21 C atoms and n has typical value of 0 - 4, and and R 2 , R 3 and R 4 are independent from each other H or lower alkyl chain with 1 to 4 carbon atoms or ethoxy or propoxy group with number of ethoxy or propoxy groups varying in the range of 0 to 4, and X is chloride, bromide or methosulfate.
• nonionic surfactant components are, for example, long-chain fatty acid mono- and dialkanolamides, such as coco fatty acid monoethanolamide and myristic fatty acid monoethanolamide.
• sorbitan esters such as polyethylene glycol sorbitan stearic acid ester, fatty acid polyglycol esters or poly-condensates of ethyleneoxide and propyleneoxide, as they are on the market, for example, under the trade name "Pluronics R ".
• nonionic surfactants as emulsifiers useful in the compositions according to invention are C 10 -C 22 -fatty alcohol ethoxylates.
• C 10 -C 22 -fatty alcohol ethers the alkyl polyglycol ethers known by the generic terms "Laureth”, “Myristeth”, “Oleth”, “Ceteth”, “Deceth”, “Steareth” and “Ceteareth” according to the CTFA nomenclature, including addition of the number of ethylene oxide molecules, e.g., "Laureth-16":
• non-ionic surfactants mentioned above fatty alcohol ethoxylates are the most preferred ones.
• non-ionic surfactants can also be used as a mixture of one category such as several ethoxylated fatty alcohols or several categories such as mixture of alkyl polyglucoside and ethoxylated fatty alcohol.
• compositions according to the invention can also contain amphoteric or zwitterionic surfactants.
• amphoteric or zwitterionic surfactants Useful as such are in particular the various known betaines such as alkyl betaines, fatty acid amidoalkyl betaines and sulfobetaines, for example, lauryl hydroxysulfobetaine; long-chain alkyl amino acids, such as cocoaminoacetate, cocoaminopropionate and sodium cacoamphopropionate and -acetate.
• emulsifiers suitable within the meaning of the present invention are anionic surfactants of the sulfate, sulfonate, carboxylate and alkyl phosphate type, for example, the known C 10 -C 18 -alkyl sulfates, and in particular the respective ether sulfates, for example, C 12 -C 14 -alkyl ether sulfate, lauryl ether sulfate, especially with 1 to 4 ethylene oxide groups in the molecule, monoglyceride (ether) sulfates, fatty acid amide sulfates obtained by ethoxylation and subsequent sulfatation of fatty acid alkanolamides, and the alkali salts thereof, as well as the salts of long-chain mono- and dialkyl phosphates constituting mild, skin-compatible detergents.
• anionic surfactants of the sulfate, sulfonate, carboxylate and alkyl phosphate type for example, the
• Additional anionic surfactants useful are ⁇ -olefin sulfonates or the salts thereof, and in particular alkali salts of sulfosuccinic acid semiesters, for example, the disodium salt of monooctyl sulfosuccinate and alkali salts of long-chain monoalkyl ethoxysulfosuccinates.
• Suitable surfactants of the carboxylate type are alkyl polyether carboxylic acids and the salts thereof of the formula R 9 -(C 2 H 4 O) n -O-CH 2 COOX, wherein Rg is a C 8 -C 20 -alkyl group, preferably a C 12 -C 14 -alkyl group, n is a number from 1 to 20, preferably 2 to 17, and X is H or preferably a cation of the group sodium, potassium, magnesium and ammonium, which can optionally be hydroxyalkyl-substituted.
• Lipophilic oily compounds such as fatty acid esters are as well suitable for the composition of the present invention. Those are such as isopropyl myristate, palmitate, stearate and isostearate, oleyl oleate, lsocetyl stearate, hexyl laurate, dibutyl adipate, dioctyl adipate, myristyl myristate, oleyl erucate, cetyl palmitate, etc.
• Composition of the present invention comprises cationic polymers as conditioning agents.
• cationic polymers know as Polymer JR type from Amerchol such as Polyquatemium 10 or cationic guar gum known with trade name Jaguar from Rhône-Poulenc and chemically for example Guar hydroxypropyl trimonium chloride.
• chitosan and chitin can also be included in the compositions as cationic natural polymers,
• compositions according to the present invention can also comprise further agents, such as protein hydrolyzates and polypeptides, e.g. keratin hydrolyzates, collagen hydrolyzates of the type "Nutrilan” or elastin hydrolyzates, as well as, in particular vegetable, optionally cationized protein hydrolyzates, for example "Gluadin”.
• protein hydrolyzates and polypeptides e.g. keratin hydrolyzates, collagen hydrolyzates of the type "Nutrilan” or elastin hydrolyzates, as well as, in particular vegetable, optionally cationized protein hydrolyzates, for example "Gluadin”.
• alcoholic or hydro-alcoholic plant extracts known per se are in particular extracts from leaves, fruits, blossoms, roots, rinds or stems of aloe, pineapple, artichoke, arnica, avocado, valerian, bamboo, green tea, blue lotus flower, henbane, birch, stinging nettle, echinacea, ivy, wild angelica, gentian, ferns, pine needles, silver weed, ginseng, broom, oat, rose hip, hamamelis, hay flowers, elderberry, hop, coltsfoot, currants, chamomile, carrots, chestnuts, clover, burr root, cocoanut, cornflower, lime blossom, lily of the valley, marine algae, balm, mistletoe, passion flower, ratanhia, marigold, rosemary, horse chestnut, pink hawthorn, sage, horsetail, yarrow, primrose, nettle, thyme, walnut, wine leaves,
• Suitable trade products are, for example, the various "Extrapone” products and “Herbasol R”. Extracts and the preparation thereof are also described in “ Hagers Handbuch der pharmazeuticiantechnik", 4th Ed .
• compositions may contain organic solvents such as ethanol, propanol, isopropanol, benzyl alcohol, benzyloxyethanol, alkylene carbonates such as ethylene carbonate and propylene carbonate, phenoxyethanol, butanol, isobutanol, cyclohexane, cyclohexanol, hexyleneglycol, ethylenecarbonate, ethyleneglycol monoethylether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, 1-phenylethylalcohol, 2-phenylethylalcohol, o-methoxyphenol.
• Concentration of organic solvents in the composition should not exceed 10% by weight. It should be noted that penetration enhancers are useful for both cleansing and after shampoo conditioning preparations. It is obvious that the concentration in the cleansing compositions is usually lower than in the conditioning preparations.
• compositions of the present invention can comprise UV filters either for stabilization of the product colour or for protection of hair from environmental influences such as loss of elasticity, loss of hair colour (bleaching effect of sun light).
• the UV-absorbing substance is preferably selected from the following compounds: 4-Aminabenzoic acid and the esters and salts thereof, 2-phenyl benzimidazole-5-sulfonic acid and the alkali and amine salts thereof, 4-dimethyl aminobenzoic acid and the esters and salts thereof, cinnamic acid and the esters and salts thereof, 4-methoxycinnamio acid and the esters and salts thereof, salicylic acid and the esters and salts thereof, 2.4-dihydroxybenzophenone, 2.2'.4.4'-tetrahydroxy- benzophenone, 2-hydroxy-4-methoxybenzophenone and its 5-sulfonic acid or the sodium salt thereof, 2.2'-dihydroxy-4.4'-dimethoxybenzophenone, 2-hydroxy-5-chlorobenz
• compositions of the present invention can comprise hair-restructuring agents.
• the hair restructuring agents preferred are especially the ones disclosed in the German patent DE 197 51 550 C2 . Namely they are ceramide type of compounds, fatty acids and phytosterol or their mixtures,
• Preferred ceramide compound is cetyl-PG-hydroxyethylpalmitamide
• Sterols are as well preferred hair restructuring agents as disclosed in the above mentioned german patent.
• Especially preferred ones are of plant origin for example ergosterol, sitosterol, stigmasterol, fucosterol, brassicasterol, fungisterol, campesterol, zymosterol, ascosterol, cerevisterol, episterol, faecosterol, spinasterol.
• those phytosterols the ones found in "Avocadin" which is the unsaponified fraction of the avocado oil is more preferred.
• the pH of the compositions according to the invention is in the range of 2 to 7, preferably 3 to 6, more preferably 3 to 5.
• following ingredients can be used: Organic acids such as citric acid, lactic acid, tartaric acid, malic acid, maleic acid. fumaric acid, levulinic acid, butyric acid and hydroxy butyric acids, valeric acid, oxalic acid, succinic acid, mandelic acid, glycolic acid, glucuronic acid, propionic acid, salicylic acid or acetic acid or inorganic acids such as hydrochloric acid, phosphoric acid, sulphuric acid, nitric acid.
• Concentration of the organic and/or inorganic acids or their mixtures should be chosen in a way that composition reaches the desired pH value as given above.
• concentration for acids can be 0.01 - 3% by weight, preferably 0,05 - 2% by weight, more preferably 0.05 -1,5% by weight calculated to the total composition.
• the pH of the composition can also be adjusted to the required pH by using alkaline solution such as sodium hydroxide, ammonium hydroxide, potassium hydroxide or their salts with those acids mentioned above in the case that at the selected acid concentration pH of the composition is lower than that of the aimed value.
• compositions of the present invention are used as a rinse off conditioners and usually used after cleansing hair.
• usage without previous cleansing should not be excluded.
• process for conditioning keratin fibres especially human hair, especially enhancing shine consists of washing hair, preferably with a cleansing composition and then applying a composition comprising at least one cationic surfactant at a concentration of 0:01 to 10% by weight, and at least one colour effect pigment consisting of synthetic mica coated with metal oxide or oxides and having a particle size distribution of 1 to 750 ⁇ m at a concentration of 0.01 to 10% by weight, calculated to total composition, onto hair and after processing for 30 sec to 30 min, preferably 1 min to 15 min and more preferably 3 minute to 10 min at ambient temperature or at a temperature not exceeding 40°C, rinsed off,
• Synthetic fluorphologopite* 1.0 Citric acid/Sodium hydroxide q.s. to pH 4.0 Fragrance 0.2 Water to 100 *: Synthetic fluorphologopite used is commercially available from Sun Chemical Corporation under the trade name SunShine Glitter White with a volume particle size distribution in the range of 20 to 95 ⁇ m.
• the above composition was prepared by dispersing dimethicone and synthetic fluorphologopite in water and finally pH was adjusted to 4.
• Synthetic fluorphologopite used is commercially available from Sun Chemical Corporation under the trade name SunShine Glitter White with a volume particle size distribution in the range of 20 to 95 ⁇ m,
• composition was prepared first by dissolving behentrimonium chlode in water with heat and subsequent dispersion of dimethiconol, synthetic fluorphologopite and fragrance therein after cooling. Finally pH was adjusted to 4.0,
• Synthetic fluorphologopite* 1.0 Citric acid/Sodium hydroxide q.s. to pH 4.0 Fragrance 0.4 Water to 100 *: Synthetic fluorphologopite used is commercially available from Sun Chemical Corporation under the trade name SunShine Ultra Glitter White with a volume particle size distribution in the range of 95 to 730 ⁇ m.
• Synthetic fluorphologopite used is commercially available from Sun Chemical Corporation under the trade name SunShine Super Glitter White with a volume particle size distribution in the range of 40 to 250 ⁇ m.
• Synthetic fluorphologopite used is commercially available from Sun Chemical Corporation under the trade name SunShine Glitter White with a volume particle size distribution in the range of 20 to 95 ⁇ m.
• Synthetic fluorphologopite* 1.0 Polyquaternium-10 0.7 Dimethicone 3.0 Citric acid/Sodium hydroxide q.s. to pH 3.5 Fragrance 0.4 Solubilizer as in Example 1 0.4 Water to 100 *; Synthetic fluorphologopfte used is commercially available from Sun Chemical Corporation under the trade name SunShine Glitter White with a volume particle size distribution in the range of 20 to 95 ⁇ m,
• Synthetic fluorpholpgopite* 1.0 Polyquaternium 37 1,5 Dimethiconol 2.0 Citric acid/Sodium hydroxide q.s. to pH 4.5 Fragrance 0.4 Water to 100 *: Synthetic fluorphologopite used is commercially available from Sun Chemical Corporation under the trade name SunShine Glitter White with a volume particle size distribution in the range of 20 to 95 ⁇ m.
• Synthetic fluorphologopite* 1.0 Dimethicone 0.5 Hydroxypropyl guar 0.8 Citric acid/Sodium hydroxide q.s. to pH 4.5 Fragrance 0.4 Solubilizer as in Example 1 0.4 Water to 100 *: Synthetic fluorphologopite used is commercially available from Sun Chemical Corporation under the trade name SunShine Glitter White with a volume particle size distribution in the range of 20 to 95 ⁇ m.

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• 2006
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