EP1901394A1 - Magnetic antenna - Google Patents

Magnetic antenna Download PDF

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Publication number
EP1901394A1
EP1901394A1 EP06767954A EP06767954A EP1901394A1 EP 1901394 A1 EP1901394 A1 EP 1901394A1 EP 06767954 A EP06767954 A EP 06767954A EP 06767954 A EP06767954 A EP 06767954A EP 1901394 A1 EP1901394 A1 EP 1901394A1
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EP
European Patent Office
Prior art keywords
magnetic
layer
coils
coil
electrode
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP06767954A
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German (de)
French (fr)
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EP1901394B1 (en
EP1901394A4 (en
Inventor
Tetsuya Otake Plant TODA KOGYO CORP. KIMURA
Yoshiro Tokyo Head Office TODA KOGYO CORP. SATO
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Toda Kogyo Corp
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Toda Kogyo Corp
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Priority claimed from JP2005199451A external-priority patent/JP4821965B2/en
Priority claimed from JP2005206254A external-priority patent/JP2007028114A/en
Application filed by Toda Kogyo Corp filed Critical Toda Kogyo Corp
Publication of EP1901394A1 publication Critical patent/EP1901394A1/en
Publication of EP1901394A4 publication Critical patent/EP1901394A4/en
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Publication of EP1901394B1 publication Critical patent/EP1901394B1/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/36Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith
    • H01Q1/362Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith for broadside radiating helical antennas
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/12Supports; Mounting means
    • H01Q1/22Supports; Mounting means by structural association with other equipment or articles
    • H01Q1/2283Supports; Mounting means by structural association with other equipment or articles mounted in or on the surface of a semiconductor substrate as a chip-type antenna or integrated with other components into an IC package
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/12Supports; Mounting means
    • H01Q1/22Supports; Mounting means by structural association with other equipment or articles
    • H01Q1/24Supports; Mounting means by structural association with other equipment or articles with receiving set
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q7/00Loop antennas with a substantially uniform current distribution around the loop and having a directional radiation pattern in a plane perpendicular to the plane of the loop
    • H01Q7/06Loop antennas with a substantially uniform current distribution around the loop and having a directional radiation pattern in a plane perpendicular to the plane of the loop with core of ferromagnetic material
    • H01Q7/08Ferrite rod or like elongated core

Definitions

  • the present invention relates to a magnetic antenna, and more particularly, to a magnetic antenna for communication using a magnetic field component, which is capable of transmitting and receiving a signal with high sensitivity even when attached to a metal object.
  • the magnetic antenna of the present invention is particularly suited for use in an RFID tag and an RFID tag reader/writer.
  • An antenna for transmitting and receiving an electromagnetic wave using a magnetic material (hereinafter referred to merely as “magnetic antenna"), in which a magnetic field component coming from the outside is allowed to pass through the magnetic material, around which a coil of a conductive wire is wound, to convert the magnetic field component into a voltage (or current) induced by the coil, has been widely used in small-sized radios and TVs.
  • a magnetic antenna is also used in a non-contact object identification device called RFID tag which has recently come into use.
  • a loop antenna free of a magnetic material and including a loop coil having a coil surface parallel to an object to be identified is used in RFID tags.
  • an electric field antenna (dipole antenna or dielectric antenna) for detecting an electric field component instead of a magnetic field component is widely used in such devices including RFID tags.
  • a non-contact sensor coil has been proposed in which a metal surface to which a magnetic antenna is attached is positively used to arrange coils in order to cancel a magnetic field parallel to the metal surface and to generate a magnetic field in a direction perpendicular to the metal surface ( Japanese Patent Application Laid-open (KOKAI) No. 2003-318634 ).
  • the above magnetic antenna for use in an RFID tag has the problem that when the wound coil is brought into contact with a metallic object, the contact surfaces between the wound wire and the metal plate become unstable to cause variations in characteristics of the antenna. Also, since an antenna of the above type has open opposite ends, magnetic fields are generated at both ends of the coil and the separate two poles must be used for transmission and reception, respectively, in spite of the fact that a magnetic antenna for an RFID tag reader/writer having a pole with which both transmission and reception can be achieved is required. Although a magnetic antenna which can overcome the problem has been developed, the magnetic antenna has variations in characteristics when its coil of a wound enamel wire or the like is brought into contact with a metallic object as described above.
  • an antenna applied thereto which has a coil of a wound wire is not suitable for mass-production.
  • conventional magnetic antennas undergo changes in characteristics when brought close to a metallic object and their resonant frequencies are changed. To achieve resonance with a target frequency, the magnetic antennas need to be attached to a metal plate to adjust their frequencies individually.
  • the present invention has been made in view of the above problems, and it is, therefore, an object of the present invention to provide a magnetic antenna, suitable for use in an RFID tag and an RFID tag reader/writer, which does not vary in characteristics even when its coil is brought into contact with a metallic object and which is suitable for mass-production. Another object is to provide a magnetic antenna whose resonant frequency is not changed even when it is brought close to a metallic object. A further object of the present invention is to provide a magnetic antenna, suitable for use in an RFID tag reader/writer, which includes a coil having a pole with which both transmission and reception can be achieved precisely.
  • the present invention has solved the above problems by adopting a structure having a coil including a magnetic layer and an electrode material formed in a spiral configuration around the magnetic layer; and a conductive layer formed on the coil via an insulating layer.
  • a magnetic antenna for transmitting and receiving a magnetic field component comprising: a coil comprising a magnetic layer and an electrode material formed in a spiral configuration around the magnetic layer; an insulating layer provided on one or both outer surfaces of the coil; and a conductive layer provided on an outer surface of at least one of the insulating layers.
  • a magnetic antenna for transmitting and receiving a magnetic field component which is produced by a method comprising: providing a single- or multi-layered magnetic layer comprising a molded sheet or sheets of a mixture of a magnetic powder and a binder resin; forming an electrode material in a spiral configuration around the magnetic layer as an electric circuit to obtain a coil; forming an insulating layer on each of both outer surfaces of the coil; forming a conductive layer on an outer surface of at least one of the insulating layers to obtain a laminate; cutting the laminate into a predetermined size; and calcining the cut laminate into a unitary body.
  • a magnetic antenna for transmitting and receiving a magnetic field component which is produced by a method comprising: providing a single- or multi-layered magnetic layer comprising a square or rectangular molded sheet or sheets of a mixture of a magnetic powder and a binder resin; forming through-holes in the magnetic layer; filling the through-holes with an electrode material; forming an electrode layer of an electrode material on each of outer surfaces of the magnetic layer perpendicular to the through-holes such that the electrode layers are connected to the through-holes to form coils and that opposite ends of the magnetic layer conform to open ends of a magnetic circuit; forming an insulating layer on each of both outer surfaces of the coils having the electrode layers; forming a conductive layer on an outer surface of at least one of the insulating layers to obtain a laminate; cutting the laminate along lines passing the through-holes and along lines corresponding to the open ends of the coils; and calcining the cut laminate into a unitary body.
  • a magnetic antenna for transmitting and receiving a magnetic field component comprising: a plurality of coils each comprising a magnetic layer having a square or rectangular planar shape and arranged radially at generally angularly equal intervals as viewed in a plan view with their one ends connected in series or parallel to one another at the center of the radial pattern by the magnetic layers thereof such that the coils have the same polarity, the plurality of coils extending radially outward and opening in a magnetic circuit at the other ends; an insulating layer provided on one or both outer surfaces of the coils; and a conductive layer provided on an outer surface of at least one of the insulating layers.
  • a magnetic antenna for transmitting and receiving a magnetic field component, comprising: a plurality of coils each comprising a magnetic layer having a square or rectangular planar shape, arranged radially at generally angularly equal intervals as viewed in a plan view, and extending radially inward and opening in a magnetic circuit at their one ends, the plurality of coils having the other ends directed radially outward and connected in series or parallel to one another by an annular magnetic layer such that the coils have the same polarity; an insulating layer provided on one or both outer surfaces of the coils; and a conductive layer provided on an outer surface of at least one of the insulating layers.
  • a magnetic antenna produced using an LTCC technology for transmitting and receiving a magnetic field component comprising: a plurality of coils each comprising a magnetic layer having a square or rectangular planar shape, arranged radially at generally angularly equal intervals as viewed in a plan view with their one ends connected in series or parallel to one another at the center of the radial pattern by the magnetic layers thereof such that the coils have the same polarity, the plurality of coils extending radially outward and opening in a magnetic circuit at the other ends, and obtainable by a method comprising: providing a single- or multi-layered magnetic layer comprising a square or rectangular molded sheet or sheets of a mixture of a magnetic powder and a binder resin; forming through-holes in the magnetic layer; filling the through-holes with an electrode material; forming an electrode layer of an electrode material on each of surfaces of the magnetic layer perpendicular to the through-holes; punching the magnetic layer and the electrode layers
  • a magnetic antenna for transmitting and receiving a magnetic field component comprising: a plurality of coils each comprising a magnetic layer having a square or rectangular planar shape, arranged radially at generally angularly equal intervals as viewed in a plan view, and extending radially inward and opening in a magnetic circuit at their one ends, the plurality of coils having the other ends directed radially outward and connected to one another by an annular magnetic layer such that the coils have the same polarity; and obtainable by a method comprising:
  • a magnetic antenna of the present invention since a conductive layer is provided by an LTCC technology, the laminated layers can be closely bonded to each other and the coil and the conductive layer can be stably joined together. In addition, it is not required to adjust a frequency of the magnetic antenna under environmental conditions upon use, and the frequency can be adjusted independently. Moreover, since the conductive layer is provided, the antenna does not undergo a change in characteristics even when brought close to a metallic object. Further, since a plurality of elements can be stably produced from one sheet, a large number of elements can be produced with little variation and at low production costs.
  • the magnetic antenna according to the first to third aspects of the present invention undergoes as small a change in resonant frequency as 1 MHz or less when attached to a metal surface, it can be used in a wide frequency from 125 KHz to 2.45 GHz.
  • a communication distance of 3 cm or greater can be achieved even when the tag is adhered to a metal surface.
  • the antenna has a symmetrical green sheet laminated structure with respect to the coil at the center, a warpage of 0.5 mm or less per 1 cm length along the long side thereof after firing can be achieved. Therefore, the antenna is suitable for practical use.
  • the magnetic antenna according to the fourth to seventh aspects of the present invention has a magnetic layer on the outside of the conductive layer, the change in characteristics at a time when adhered to a metallic object can be further decreased.
  • the magnetic antenna of the present invention can be used in an RFID tag as well as an RFID tag reader/writer, and can be used in a wide frequency range from 125 kHz to 2.45 GHz when the magnetic layer for the coil is properly selected.
  • Embodiments of a magnetic antenna suitable for use in an RFID tag according to first to third aspects of the present invention will be first described with reference to Fig. 1 to Fig. 7 .
  • the magnetic antenna of the present invention generally has a coil 14 as shown in Fig. 1 and insulating layers 16 sandwiching the coil 14 from both upper and lower surfaces thereof as shown in Fig. 2 .
  • a magnetic layer 15 having a square or rectangular planar shape as shown in Fig. 1 is used to form coils 14.
  • the magnetic layer 15 has a single- or multi-layer structure, and each layer comprises a molded sheet of a mixture of a magnetic powder and a binder. Through-holes 11 are formed in the magnetic layer 15 and filled with an electrode material.
  • Electrode layers 12 of an electrode material are formed on the surfaces of the magnetic layer 15 perpendicular to the through-holes 11 such that the electrode layers 12 are connected to the through-holes 11 to form coils and that opposite ends of the magnetic layer conform to open ends of a magnetic circuit.
  • the coils 14 having the magnetic layer and the electrode layers 12 printed thereon are sandwiched between insulating layers 16 as shown in Fig. 2 , and a conductive layer 17 is formed on an upper surface of at least one of the insulating layers 16.
  • the resulting laminate including the coils 14, insulating layers 16 and at least one conductive layer 17 is cut along lines passing the through-holes 11 and along coil open ends 13, and each cut laminate is calcined into a unitary body.
  • an LTCC Low Temperature Co-fired Ceramics
  • a coil lead terminal 19 and an IC chip connecting terminal 18 may be formed on the magnetic antenna of the present invention as shown in Fig. 3 .
  • Through-holes 11 are formed through one or both of the insulating layers 16 provided over the coils 14 having the electrode layers 12 printed thereon, and filled with an electrode material so that the electrode material filled in the through-holes 11 connected to opposite ends of the coil 14.
  • a coil lead terminal 19 and an IC chip connecting terminal 18 are printed on the insulating layer 16 or layers with an electrode material.
  • the resulting laminate including the coils 14, insulating layers 16 and at least one conductive layer 17 is calcined into a unitary body.
  • the magnetic antenna of the present invention may have an additional magnetic layer 15 provided on the lower surface of the insulating layer 16 having a conductive layer 17 thereon as shown in Fig. 4 .
  • the magnetic antenna of the present invention undergoes only slight changes in characteristics and in resonant frequency even when brought close to a metallic object.
  • the magnetic antenna of the present invention may have an additional magnetic layer 15 provided on the lower surface of the insulating layer 16 having a conductive layer 17 thereon and an additional insulating layer 16 provided on the lower surface of the additional magnetic layer as shown Fig. 5 . In this case, the stresses between the layers can be balanced in the magnetic antenna of the present invention, and warpage of the magnetic antenna can be reduced.
  • the magnetic antenna of the present invention may have a capacitor electrode 1C as shown in Fig. 6 .
  • a capacitor electrode 1C is provided on one or both of the insulating layers between which the coil is sandwiched.
  • An additional insulating layer 16 having an electrode printed on an outer surface thereof is provided on an outer surface of the insulating layers having the capacitor electrode 1C so that a capacitor can be formed between the electrodes.
  • the coil 14 is connected in parallel or series to the IC chip connecting terminal 18 and the coil lead terminal 19.
  • a parallel electrode or interdigital electrode may be printed on the upper surface of the insulating layer to form a capacitor, and the coil 14 may be connected in parallel or series to the coil lead terminal.
  • the capacitor may have a parallel plate structure with an insulating layer 16 sandwiched between electrodes or a planar structure with an interdigital or parallel electrode.
  • one of the capacitor electrodes may serve as an IC chip connecting terminal 18 as shown in Fig. 6 .
  • the magnetic antenna of the present invention has a magnetic layer 15 comprising an Ni-Zn based ferrite magnetic material and is produced by calcination.
  • the ferrite powder preferably has a composition of 45 to 49.5 mol% of Fe 2 O 3 , 9.0 to 45.0 mol% of NiO, 0.5 to 35.0 mol% of ZnO and 4.5 to 15.0 mol% of CuO.
  • the composition is suitably selected such that the resulting magnetic layer will have a high magnetic permeability and a low magnetic loss in the frequency band in which it is intended to operate. When the magnetic permeability is too low, the number of turns of the coil will be so large that the antenna will be difficult to produce by an LTCC technology.
  • the composition of the ferrite is preferably selected such that the magnetic layer will have a magnetic permeability of 70 to 120 at 13.56 MHz when the antenna is applied to an RFID tag, and have a magnetic permeability of 10 to 30 at 100 MHz when the antenna is used to receive commercial FM broadcasts.
  • the ferrite is calcined at a temperature of 800 to 1000°C and preferably 850 to 920°C.
  • a Zn based ferrite is used for the insulating layers 16. It is preferred to select a Zn based ferrite powder having such a composition that a sintered body formed therefrom has a volume resistivity of 10 8 cm or higher. That is, the Zn based ferrite preferably has a composition of 45 to 49.5 mol% of Fe 2 O 3 , 17.0 to 22.0 mol% of ZnO, and 4.5 to 15.0 mol% of CuO.
  • a glass based ceramic may be also used for the insulating layers 16. As the glass based ceramic, a borosilicate glass, a zinc glass, a lead glass or the like can be used.
  • the magnetic antenna of the present invention may have a terminal to which an IC chip is connectable on the upper surface of one of the insulating layers 16 as shown in Fig. 3 and which may be connected in parallel or series to the IC chip connecting terminal 18 and be calcined into a unitary body. Also, a terminal to which a variable capacitor is connectable may be formed on the upper surface of the insulating layer and connected in parallel or series to the coil lead terminal.
  • an Ag paste is suitable.
  • Other metal based conductive pastes such as an Ag based alloy paste can be also used.
  • the magnetic antenna of the present invention is an antenna for transmitting and receiving a magnetic field component and has a plurality of coils each formed of a magnetic layer 21 having a square or rectangular planar shape as shown in Fig. 9 .
  • the coils are arranged radially at generally angularly equal intervals as viewed in a plan view.
  • One ends of the coils are connected to one another at the center of the radial pattern by the magnetic layers thereof, and the coils extend radially outward and terminate (open in a magnetic circuit) at the other ends.
  • the one ends of the coils are connected in series (see Fig. 11 and Fig. 12 ) or parallel (see Fig. 13 ) to each other such that the coils have the same polarity.
  • An insulating layer 23 is provided on one or both outer surfaces of the coils as viewed in a plan view, and a conductive layer 24 is provided on the outside of at least one of the insulating layers 23.
  • the magnetic antenna of the present invention is a magnetic antenna for transmitting and receiving a magnetic field component and has a configuration as shown in Fig. 10 . That is, the magnetic antenna has a plurality of coils each formed of a magnetic layer 21 having a square of rectangular planar shape. The coils are arranged radially at generally angularly equal intervals as viewed in a plan view, and extend radially inward and terminate at their one ends. The other ends of the coils are directed radially outward and connected in series or parallel to one another by an annular magnetic layer such that the coils have the same polarity.
  • An insulating layer 23 is provided on one or both of the outer surfaces of the coils as viewed in a plan view, and a conductive layer 24 is provided on the outside of at least one of the insulating layers 23.
  • the above magnetic antenna is produced utilizing the LTCC technology.
  • the magnetic layer 21 forming the coils has a single- or multi-layer structure, and each layer comprises a molded sheet of a mixture of a calcined magnetic powder and a binder. Through-holes are formed in the magnetic layer 21 and filled with an electrode material. Electrode layers of an electrode material are formed on both surfaces of the magnetic layer 21 perpendicular to the through-holes. The magnetic layer 21 including the electrode layers is punched along lines including lines passing the centers of the through-holes to form a coil structure. That is, coil electrodes 26 are formed by the cross-sections of the electrode material filled in the through-holes.
  • the magnetic layer 21 is punched to form coil assemblies each having three coils arranged radially with their magnetic layers connected at the center of the radial pattern.
  • the shaped magnetic layer 21 (coils) is sandwiched between insulating layers 23.
  • the insulating layer 23 provided on the upper surface of the magnetic layer having an electrode layer printed thereon has been previously punched into a shape adapted to cover the electrode layer 24.
  • a conductive layer 24 comprising the same material as the electrode material is provided on the lower surface of the insulating layer 23 on the lower surface of the magnetic layer 21. Then, the resulting laminate is cut into individual pieces of coil assemblies, and each piece of coil assembly is calcined into a unitary body.
  • the magnetic antenna produced as described above has a plurality of coils arranged radially and each having a magnetic layer 21 with a square or rectangular planar shape. One ends of the coils are connected by the magnetic layer 21, and the coils extend radially and terminate at the other ends.
  • the coils are connected in series or parallel to one another such that all the coils have the same polarity. Since the coils facing one another have the same polarity, components of a magnetic field 27 parallel to a metal surface are cancelled (see Fig. 11 ), and only components perpendicular to the metal surface can be obtained (see Fig. 9 and Fig. 10 ).
  • the insulating layers 23 on both sides of the coils having electrode layers 24 printed thereon or the insulating layer 23 opposite the one on which the conductive layer 24 has been formed may have through-holes filled with an electrode material, and a coil lead terminals 29 of an electrode material printed thereon and connected to the beginnings and ends of the coils.
  • an additional magnetic layer 25 may be provided on the outside the conductive layer 24.
  • the magnetic antenna of the present invention may have another insulating layer on the outside of the magnetic layer on the outside of the conductive layer 24. In this case, the stress between the layers in the laminate structure including the coils can be balanced, and warpage of the magnetic antenna can be reduced.
  • the magnetic antenna of the present invention may have another insulating layer having square or circular electrodes printed on both sides thereof on said additional insulating layer provided on an upper surface of insulating layers 23 covering said coil to form a capacitor 28.
  • the capacitor 28 is connected in parallel (see Fig. 11 and Fig. 13 ) or series (see Fig. 12 ) to the coil lead terminal electrodes 29 to form a circuit as shown in Fig. 11 to Fig. 13 .
  • the magnetic antenna of the present invention may have a parallel electrode or an interdigital electrode printed on an upper surface of the insulating layer 23 on the upper surfaces of the coils to form a capacitor 28.
  • the capacitor 28 is connected in parallel (see Fig. 11 and Fig. 13 ) or series (see Fig. 12 ) to the coil lead terminals 29 to form a circuit as shown in Fig. 11 to Fig. 13 .
  • a specific print pattern is shown in Fig. 6 .
  • the capacitor 28 may have a parallel plate structure having electrodes provided on both sides of an insulating layer 23 or a planar structure having an interdigital or a parallel electrode. When the capacitor 28 has a parallel plate structure, one of the capacitor electrode may serve as an IC chip connecting terminal.
  • the magnetic antenna of the present invention uses an Ni-Zn based ferrite magnetic material for the magnetic layer 21 as the magnetic antenna according to the first to third aspects mentioned above, and is produced by calcination.
  • the composition of the ferrite powder and the ferrite calcination temperature are the same as those in the case of the magnetic antenna described above.
  • the composition of the insulating layers 23 is also the same as in the case of the magnetic antenna described above.
  • a glass based ceramic may be used for the insulating layers 23 as in the case of the magnetic antenna described above.
  • the magnetic antenna of the present invention may have a terminal to which an IC chip is connectable on the surface of insulating layer 23 and which is connected in parallel or series to the coil lead terminals 29 as in the case of the magnetic antenna described above.
  • an Ag paste is suitable for the electrode material as in the case of the magnetic antenna described above.
  • Other metal conductive pastes such as Ag based alloy paste can be also used.
  • a magnetic antenna of the present invention was produced using an LTCC technology.
  • a magnetic layer 15 was prepared. 100 Parts by weight of a calcined Ni-Zn-Cu ferrite powder which had been found to have a magnetic permeability of 100 at 13.56 MHz upon calcination at 900°C (Fe 2 O 3 : 48.5 mol%, NiO: 25 mol%, ZnO: 16 mol%, CuO: 10.5 mol%), 8 parts by weight of a butyral resin, 5 parts by weight of a plasticizer, and 80 parts by weight of a solvent were mixed in a ball mill to prepare a slurry. The slurry was applied on PET films with a size of 150 mm x 150 mm by a doctor blade to such a thickness that the resulting layer thickness after calcination would be 0.1 mm.
  • Insulating layers 16 were prepared as follows. 100 Parts by weight of a calcined Zn-Cu ferrite powder (Fe 2 O 3 : 48.5 mol%, ZnO: 41 mol%, CuO: 10.5 mol%), 8 parts by weight of a butyral resin, 5 parts by weight of a plasticizer, and 80 parts by weight of a solvent were mixed in a ball mill to prepare a slurry. The slurry was applied on PET films to obtain sheets with the same size and thickness as the sheets for the magnetic layer.
  • a calcined Zn-Cu ferrite powder Fe 2 O 3 : 48.5 mol%, ZnO: 41 mol%, CuO: 10.5 mol%
  • 8 parts by weight of a butyral resin 5 parts by weight of a plasticizer
  • 80 parts by weight of a solvent were mixed in a ball mill to prepare a slurry.
  • the slurry was applied on PET films to obtain sheets with the same size and thickness as the sheets for the magnetic layer.
  • the above green sheets were bonded together by applying a pressure.
  • the resulting laminate was cut along lines passing the through-holes 11 and along coil open ends 13, and calcined at 900°C for two hours into a unitary body, thereby obtaining a magnetic antenna with a size of 18 mm (length) x 4 mm (width) having a 32-turn coil (sample 1) (The coil is shown as having only seven turns and a magnetic layer as being formed of only three layers in Fig. 1 and Fig. 2 for simplification, which applies also other drawings).
  • An IC for an RFID tag was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel to the IC. Then, the resonant frequency was adjusted to 13.1 MHz, thereby obtaining an RFID tag.
  • the RFID tag was attached to a metal plate, and its communication distance, the distance over which it was able to communicate with a reader/writer having an output of 10 mW, was measured. Also, the warpage of the magnetic antenna was measured. The measuring methods are described below.
  • the resonant frequency was measured by the following method.
  • a one-turn coil was connected to an impedance analyzer (manufactured by Hewlett Packard Company, product name; 4291A), which was in turn coupled to the RFID tag.
  • the peak frequency of the measured impedance was defined as the resonant frequency.
  • the adjustment of the resonant frequency was made by selecting the position of the coil electrodes exposed at ends of the magnetic antenna to adjust the inductance.
  • the resonant frequency can be adjusted by changing the capacity of a capacitor connected in parallel to the IC.
  • the communication distance was measured by the following method.
  • the antenna of a reader/writer having an output of 10 mW manufactured by FEC Inc., product name; URWI-201
  • the antenna of a reader/writer having an output of 10 mW was fixed horizontally, and the RFID tag attached to a metal plate was placed horizontally above the antenna. Then, the RFID tag was moved within a range in which it was able to communicate at 13.56 MHz and the maximum vertical distance between the antenna and the RFID tag was defined as the communication distance.
  • a dial gage (Mitutoyo Dial Gage ID-C112) having a flat probe was attached to a stand (Mitutoyo Stand BSG-20), and the zero point of the dial gage was adjusted on the surface plate.
  • the magnetic antenna was placed between the surface plate and the flat probe, and the height of the highest point was measured with the dial gage.
  • the thickness of the magnetic antenna measured with a caliper (Mitutoyo caliper CD-C) was subtracted from the height to obtain the warpage.
  • the resonant frequency, communication distance, and warpage were measured by the above methods.
  • the magnetic antenna had a warpage of 0.6 mm, which is in a permissible range for practical use.
  • the RFID tag using the magnetic antenna showed as small a difference as +1 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was 3 cm.
  • a green sheet for an insulating layer 16 was stacked on one surfaces of the coils 14. At this time, a conductive layer 17 was printed on the insulating layer 16 with an Ag paste. Another insulating layer 16 was stacked on the other surfaces of the coils 14, and through-holes 11 were formed through the other insulating layer 16 in connection with both ends of the coils 14 and filled with an Ag paste. Coil lead terminals 19 and IC chip connecting terminals 18 to which an IC was connectable were printed on the outer surface of the other insulating layer perpendicular to the through-holes 11 with an Ag paste.
  • the green sheets were bonded together by applying a pressure.
  • the resulting laminate was cut along lines passing the through-holes 11 and along coil open ends 13, and calcined at 900°C for two hours into a unitary body, thereby obtaining a magnetic antenna with a size of 18 mm (length) x 4 mm (width) having a 32-turn coil (sample 2).
  • An IC for an RFID tag was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel to the IC just as in Example 1. Then, the resonant frequency was adjusted to 13.1 MHz, thereby obtaining an RFID tag.
  • the RFID tag was attached to a metal plate, and its communication distance, the distance over which it was able to communicate with a reader/writer having an output of 10 mW and its resonant frequency, were measured.
  • the warpage of the magnetic antenna was also measured.
  • the magnetic antenna had a warpage of 1.0 mm, which is in a permissible range for practical use.
  • the RFID tag using the magnetic antenna had a resonant frequency of 14.1 MHz and showed as small a difference as +1 MHz in the resonant frequency before and after being attached to a metal plate.
  • the communication distance after the RFID tag was attached to a metal surface was 3.1 cm.
  • the same green sheets for the magnetic layer 15 and the same green sheets for the insulating layers 16 as in Example 1 were used. As shown in Fig. 4 , five green sheets for the magnetic layer 15 were stacked on top of one another, and through-holes 11 were formed therethrough and filled with an Ag paste. Then, an Ag paste was printed on the surfaces of the laminate perpendicular to the through-holes 11 to form coils 14.
  • a green sheet for an insulating layer 16 was stacked on the lower surfaces of the coils 14. At this time, a conductive layer 17 was printed on the insulating layer 16 with an Ag paste.
  • a green sheet for a magnetic layer 15 was stacked on the lower surface of the insulating layer 16.
  • a green sheet for another insulating layer 16 was stacked on the upper surfaces of the coils 14, and through-holes 11 were formed in the upper surface of the other insulating layer 16 in connection with both ends of the coils 14 and filled with Ag paste.
  • Coil lead terminals 19 and IC chip connecting terminals 18 to which an IC was connectable were printed on the outer surface of the other insulating layer perpendicular to the through-holes 11 with an Ag paste.
  • the green sheets were bonded together by applying a pressure.
  • the resulting laminate was cut along lines passing the through-holes 11 and along coil open ends 13, and calcined in the same manner as in Example 1, thereby obtaining a magnetic antenna with a size of 18 mm (length) x 4 mm (width) having a 32-turn coil (sample 3).
  • An IC for an RFID tag was connected to the IC chip connecting terminal 18 of the magnetic antenna as in Example 1, and a capacitor was connected in parallel to the IC. Then, the resonant frequency was adjusted to 13.1 MHz, thereby obtaining an RFID tag.
  • the RFID tag was attached to a metal plate, and its communication distance, the distance over which it was able to communicate with a reader/writer having an output of 10 mW, and its resonant frequency were measured.
  • the warpage of the magnetic antenna was also measured.
  • the magnetic antenna had a warpage of 0.8 mm, which is in a permissible range for practical use.
  • the RFID tag using the magnetic antenna showed a difference of +0.5 MHz in the resonant frequency before and after being attached to a metal plate, which was smaller than those in the above Examples.
  • the communication distance after the RFID tag was attached to a metal surface was 3.3 cm.
  • the same green sheets for the magnetic layer 15 and the same green sheets for the insulating layers 16 as in Example 1 were used. As shown in Fig. 5 , five green sheets for the magnetic layer 15 were stacked on top of one another, and through-holes 11 were formed therethrough and filled with an Ag paste. Then, an Ag paste was printed on the surfaces of the laminate perpendicular to the through-holes 11 to form coils 14.
  • Two green sheets for insulating layers 16 were stacked on the lower surfaces of the coils 14. At this time, a conductive layer 17 was printed on the lower insulating layer 16 with an Ag paste.
  • a green sheet for a magnetic layer 15 was stacked on the lower surface of the lower insulating layer 16, and a green sheet for another insulating layer 16 was stacked on the lower surface thereof.
  • Through-holes 11 were formed through the insulating layer 16 on the upper surfaces of the coils 14 in connection with one ends of the coils 14 and filled with an Ag paste.
  • Coil lead terminals 19 and a half in number of IC chip connecting terminals 18 to which an IC was connectable were printed on the outer surface of the insulating layer perpendicular to the through-holes 11 with an Ag paste.
  • Through-holes 11 were formed through the insulating layer 16 on the upper surfaces of the coils 14 in connection with one ends and several intermediate points of the coils 14 and filled with an Ag paste.
  • Coil lead terminals 19 and the other half of IC chip connecting terminals 18 to which an IC was connectable were printed with an Ag paste on an outer surface of the insulating layer perpendicular to the through-holes 11. Ends of the coil lead terminals 19 were extended in such a manner that they were opposed to each other.
  • the green sheets were bonded together by applying a pressure.
  • the resulting laminate was cut along lines passing the through-holes 11 and along coil open ends 13, and calcined at 900°C for two hours into a unitary body, thereby obtaining a magnetic antenna with a size of 18 mm (length) x 4 mm (width) having a 32-turn coil (sample 4).
  • An IC for an RFID tag was connected to the IC chip connecting terminal 18 of the magnetic antenna as in Example 1. Then, the end faces of the coil lead terminals 19 opposed to each other were short-circuited with a conductive coating or the like, and the inductance was adjusted to adjust the resonant frequency to 13.1 MHz, thereby obtaining an RFID tag.
  • the RFID tag was attached to a metal plate, and its communication distance, the distance over which it was able to communicate with a reader/writer having an output of 10 mW, and its resonant frequency were measured.
  • the warpage of the magnetic antenna was also measured.
  • the magnetic antenna had a warpage of 1.0 mm, which was extremely small.
  • the RFID tag using the magnetic antenna showed as small a difference as +0.5 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was 3.4 cm.
  • the same green sheets for the magnetic layer 15 and the same green sheets for the insulating layers 16 as in Example 1 were used. As shown in Fig. 6 , five green sheets for the magnetic layer 15 were stacked together on each other, and through-holes 11 were formed therethrough and filled with an Ag paste. Then, an Ag paste was printed on the surfaces of the laminate perpendicular to the through-holes 11 to form coils 14.
  • Two green sheets for insulating layers 16 were stacked on the lower surfaces of the coils 14. At this time, a conductive layer 17 was printed on the lower insulating layer 16 with an Ag paste.
  • a green sheet for a magnetic layer 15 was stacked on the lower surface of the lower insulating layer 16.
  • a green sheet for a magnetic layer 15 and a green sheet for an insulating layer 16 were stacked on the upper surfaces of the coils 14.
  • Through-holes 11 were formed through the green sheet for an insulating layer 16 on the upper surfaces of the coils 14 in connection with both ends of the coil 14 and filled with an Ag paste.
  • Capacitor electrodes 1C were printed on an outer surface of the insulating layer perpendicular to the through-holes 11 with an Ag paste.
  • IC chip connecting terminals 18 were printed on the green sheet for another insulating layer 16 on the upper surface of the insulating layer to form capacitors between the IC chip connecting terminals 18 and the capacitor electrodes 1C.
  • the green sheets were bonded together by applying a pressure.
  • the resulting laminate was cut along lines passing the through-holes 11 and along coil open ends 13, and calcined at 900°C for two hours into a unitary body, thereby obtaining a magnetic antenna with a size of 18 mm (length) ⁇ 4 mm (width) having a 32-turn coil (sample 5).
  • An IC for an RFID tag was connected to the IC chip connecting terminal 18 of the magnetic antenna, and the capacitance was adjusted by cutting off a part of the IC chip connecting terminal 18 to adjust the resonant frequency to 13.1 MHz, thereby obtaining an RFID tag.
  • the RFID tag was attached to a metal plate, and its communication distance, the distance over which it was able to communicate with a reader/writer having an output of 10 mW, and its resonant frequency were measured.
  • the warpage of the magnetic antenna was also measured.
  • the magnetic antenna had a warpage of 0.1 mm, which was extremely small.
  • the RFID tag using the magnetic antenna showed as small a difference as +0.5 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was 3.3 cm.
  • Green sheets for a magnetic layer 15 were prepared. 100 Parts by weight of a calcined Ni-Zn-Cu ferrite powder which had been found to have a magnetic permeability of 20 at 100 MHz upon calcination at 900°C (Fe 2 O 3 : 48.5 mol%, NiO: 39 mol%, ZnO: 2 mol%, CuO: 10.5 mol%), 7 parts by weight of a butyral resin, 3 parts by weight of a plasticizer, 100 parts by weight of a solvent were mixed in a ball mill to prepare a slurry. The slurry was applied on PET films with a doctor blade.
  • Green sheets for an insulating layer 16 were prepared. 100 Parts by weight of a calcined Zn-Cu ferrite powder (Fe 2 O 3 : 48.5 mol%, ZnO: 40 mol%, CuO: 11.5 mol%), 7 parts by weight of a butyral resin, 3 parts by weight of a plasticizer, 100 parts by weight of a solvent were mixed in a ball mill to prepare a slurry, and the slurry was applied on PET films with a doctor blade.
  • a calcined Zn-Cu ferrite powder Fe 2 O 3 : 48.5 mol%, ZnO: 40 mol%, CuO: 11.5 mol%
  • a butyral resin 3 parts by weight of a plasticizer
  • 100 parts by weight of a solvent 100 parts by weight of a solvent were mixed in a ball mill to prepare a slurry, and the slurry was applied on PET films with a doctor blade.
  • Fig. 7 five green sheets for the magnetic layer 15 were stacked together on each other, and through-holes 11 were formed therethrough and filled with an Ag paste.
  • An Ag paste was printed on the surfaces of the laminate perpendicular to the through-holes 11 to form coils 14.
  • the green sheets for the insulating layers 16 were stacked on the upper and lower surfaces of the coils 14, and another insulating layer 16 having a conductive layer 17 of an Ag paste printed thereon was stacked on the insulating layer 16 on the lower surfaces of the coils 14.
  • the green sheets were bonded together by applying a pressure.
  • the resulting laminate was cut along lines passing the through-holes 11 and along coil open ends 13, and calcined at 900°C for two hours into a unitary body, thereby obtaining a magnetic antenna with a size of 18 mm (length) x 4 mm (width) having a 50-turn coil (sample 6).
  • An FM radio 1R was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel to the coil 14.
  • the resonant frequency was adjusted to 82 MHz, thereby obtaining an FM broadcast receiving antenna. This is intended for use as an antenna on a metallic case of a cellular phone or the like.
  • the magnetic antenna was attached to a metal plate and used to receive an FM broadcast (82 MHz), good reception was achieved.
  • the warpage of the magnetic antenna was measured, the warpage was as small as 0.6 mm.
  • a magnetic antenna (sample 7), which was the same as the magnetic antenna of Example 1 except for not having a conductive layer 17 as shown in Fig. 8 , was produced.
  • An IC for an RFID tag was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel to the IC as in Example 1.
  • the resonant frequency was adjusted to 13.1 MHz, thereby obtaining an RFID tag.
  • the RFID tag was attached to a metal plate, and the communication distance, resonant frequency, and warpage of the magnetic antenna were measured in the same manner as in Example 1.
  • the magnetic antenna had a warpage of 1.0 mm.
  • the RFID tag using the magnetic antenna showed as large a difference as +1.5 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was only 1.4 cm.
  • a commercially available IC card type tag manufactured by Texas Instruments, product name; Tag-it TMHF
  • Tag-it TMHF Tag-it TMHF
  • the communication distance after being attached to a metal plate was 0.1 cm, and no resonant frequency was observed after being attached to a metal plate.
  • a magnetic antenna of the present invention was produced using an LTCC technology.
  • a magnetic layer 21 was prepared.
  • a calcined ferrite powder, a butyral resin, a plasticizer, and a solvent were mixed in a ball mill to prepare a slurry and the slurry was shaped into sheets in the same manner as in Example 1.
  • insulating layers 23 were prepared in the same manner as in Example 1. That is, a calcined Zn-Cu ferrite powder, a butyral resin, a plasticizer, a solvent were mixed in a ball mill to prepare a slurry and the slurry was shaped into sheets in the same manner as in Example 1.
  • Fig. 9 shows a schematic view of the obtained magnetic antenna. In the drawing, the number of turns of the coils is shown in a simplified manner.
  • An RFID tag reader/writer was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel to the reader/writer.
  • the resonant frequency was adjusted to 13.56 MHz.
  • the magnetic antenna was attached to a metal plate, and its communication distance, the distance over which it was able to communicate with an RFID tag, was measured. The methods for measuring and adjusting the resonant frequency, and the method for measuring the communication distance are described below.
  • the resonant frequency was measured by the following method.
  • a one-turn coil is connected to an impedance analyzer (manufactured by Hewlett Packard Company, product name; 4291A), which was in turn coupled to the RFID tag reader/writer.
  • the peak frequency of the measured impedance was defined as the resonant frequency.
  • the adjustment of the resonant frequency was made by changing the capacity of a capacitor connected in parallel or series thereto.
  • the communication distance was measured by the following method.
  • the standard antenna of a reader/writer having an output of 100 mW manufactured by Takaya Corporation, product name; D002A
  • the magnetic antenna of the present invention was connected thereto and fixed horizontally.
  • An RFID tag (IC card type tag, manufactured by Texas Instruments, product name; Tag-it(TM)HF) was placed horizontally above the magnetic antenna. Then, the RFID tag was moved within a range in which it was able to communicate at 13.56 MHz and the maximum vertical distance between the antenna and the RFID tag was defined as the communication distance.
  • the reader/writer using the magnetic antenna showed as small a difference as +1 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was 3 cm.
  • the five green sheets were punched along lines passing the centers of the through-holes to form coil assemblies each having three coils arranged radially with their magnetic layers connected to an annular portion surrounding them. Then, the five green sheets were stacked in such a manner that the two green sheets having a coil electrode printed thereon were placed on both sides of the other three green sheets to form a three-pole coil.
  • a green sheet as an insulating layer 23 having a conductive layer 24 of an Ag paste printed thereon and having a circular shape was stacked on the lower surface of the coil to cover the entire lower surface thereof in such a manner that the conductive layer 24 was located outside, and a green sheet as another magnetic layer 25 was stacked on the lower surface of the conductive layer 24.
  • Fig. 10 shows a schematic view of the obtained magnetic antenna. In the drawing, the number of turns of the coils is shown in a simplified manner.
  • An RFID tag reader/writer was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel or series to the reader/writer.
  • the resonant frequency was adjusted to 13.56 MHz.
  • the change in the resonant frequency and its communication distance, the distance over which it was able to communicate with an RFID tag when attached to a metal plate, were measured in the same manner as in Example 7.
  • the reader/writer using the magnetic antenna showed as small a difference as +0.5 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was 3.4 cm.
  • a magnetic antenna (sample 10), which was the same as the magnetic antenna of Example 7 except for not having the conductive layer 24 shown in Fig. 9 , was produced.
  • An RFID tag reader/writer was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel or series to the reader/writer.
  • the resonant frequency was adjusted to 13.56 MHz.
  • the change in the resonant frequency and the communication distance of the magnetic antenna, the distance over which it was able to communicate with an RFID tag when attached to a metal plate, were measured in the same manner as in Example 7.
  • the reader/writer using the magnetic antenna showed a difference of +2.3 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was 1.6 cm.
  • a commercially available antenna for a reader/writer having a coil formed on surfaces of a resin film in a spiral pattern was attached to a metal plate and its communication distance, the distance over which it was able to communicate with an RFID tag, was measured.
  • the antenna has a size of 30 mm x 55 mm, and the coil has three turns.
  • the communication distance after being attached to a metal plate was 0.5 cm.

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Abstract

There is provided a magnetic antenna, suitable for use in an RFID tag and an RFID tag reader/writer, which operates stable even if brought close to a metallic object and suitable for mass-production. The magnetic antenna has a coil comprising a magnetic layer and a conductive layer provided on the magnetic layer via an insulating layer. Alternatively, the magnetic antenna has a plurality of coils each comprising a magnetic layer having a square or rectangular shape and arranged radially. One ends of the coils are connected in series or parallel to one another by the magnetic layers thereof such that the coils have the same polarity. An insulating layer is provided on one or both outer surface of the coils, and a conductive layer is provided on an outer surface of at least one of the insulating layers. The magnetic antenna is produced using an LTCC technology.

Description

    TECHNICAL FIELD
  • The present invention relates to a magnetic antenna, and more particularly, to a magnetic antenna for communication using a magnetic field component, which is capable of transmitting and receiving a signal with high sensitivity even when attached to a metal object. The magnetic antenna of the present invention is particularly suited for use in an RFID tag and an RFID tag reader/writer.
  • BACKGROUND ART
  • An antenna for transmitting and receiving an electromagnetic wave using a magnetic material (hereinafter referred to merely as "magnetic antenna"), in which a magnetic field component coming from the outside is allowed to pass through the magnetic material, around which a coil of a conductive wire is wound, to convert the magnetic field component into a voltage (or current) induced by the coil, has been widely used in small-sized radios and TVs. Such a magnetic antenna is also used in a non-contact object identification device called RFID tag which has recently come into use.
  • To transmit and receive an electromagnetic wave with a higher frequency, a loop antenna free of a magnetic material and including a loop coil having a coil surface parallel to an object to be identified is used in RFID tags. When the frequency is much higher (UHF band or microwave band), an electric field antenna (dipole antenna or dielectric antenna) for detecting an electric field component instead of a magnetic field component is widely used in such devices including RFID tags.
  • However, such loop antenna and electric field antenna have the following problem. When such an antenna is brought close to a metallic object, an image (mirror effect) is generated on the metallic object. Since the magnetic field of the image has a phase opposite to that of the antenna or since the electric field drops to zero on the metal surface, the sensitivity of the antenna is lost. To overcome the problem, there has been developed a magnetic antenna including a coil having a coil surface with a square or rectangular shape as viewed in a plan view and to be directly attached to a metallic object to be identified such that a cross-section of the coil is perpendicular to a metal surface of the object ( Japanese Patent Application Laid-open (KOKAI) No. 2003-317052 ). Also, a non-contact sensor coil has been proposed in which a metal surface to which a magnetic antenna is attached is positively used to arrange coils in order to cancel a magnetic field parallel to the metal surface and to generate a magnetic field in a direction perpendicular to the metal surface ( Japanese Patent Application Laid-open (KOKAI) No. 2003-318634 ).
  • DISCLOSURE OF THE INVENTION Problem to be Solved by the Invention
  • The above magnetic antenna for use in an RFID tag, however, has the problem that when the wound coil is brought into contact with a metallic object, the contact surfaces between the wound wire and the metal plate become unstable to cause variations in characteristics of the antenna. Also, since an antenna of the above type has open opposite ends, magnetic fields are generated at both ends of the coil and the separate two poles must be used for transmission and reception, respectively, in spite of the fact that a magnetic antenna for an RFID tag reader/writer having a pole with which both transmission and reception can be achieved is required. Although a magnetic antenna which can overcome the problem has been developed, the magnetic antenna has variations in characteristics when its coil of a wound enamel wire or the like is brought into contact with a metallic object as described above.
  • In any of an RFID tag and a reader/writer, an antenna applied thereto which has a coil of a wound wire is not suitable for mass-production. In addition, conventional magnetic antennas undergo changes in characteristics when brought close to a metallic object and their resonant frequencies are changed. To achieve resonance with a target frequency, the magnetic antennas need to be attached to a metal plate to adjust their frequencies individually.
  • The present invention has been made in view of the above problems, and it is, therefore, an object of the present invention to provide a magnetic antenna, suitable for use in an RFID tag and an RFID tag reader/writer, which does not vary in characteristics even when its coil is brought into contact with a metallic object and which is suitable for mass-production. Another object is to provide a magnetic antenna whose resonant frequency is not changed even when it is brought close to a metallic object. A further object of the present invention is to provide a magnetic antenna, suitable for use in an RFID tag reader/writer, which includes a coil having a pole with which both transmission and reception can be achieved precisely.
  • Means for Solving the Problem
  • The present invention has solved the above problems by adopting a structure having a coil including a magnetic layer and an electrode material formed in a spiral configuration around the magnetic layer; and a conductive layer formed on the coil via an insulating layer.
  • The present invention suitable for use in an RFID tag includes the following first to third aspects. In the first aspect of the present invention, there is provided a magnetic antenna for transmitting and receiving a magnetic field component, comprising: a coil comprising a magnetic layer and an electrode material formed in a spiral configuration around the magnetic layer; an insulating layer provided on one or both outer surfaces of the coil; and a conductive layer provided on an outer surface of at least one of the insulating layers.
  • In the second aspect of the present invention, there is provided a magnetic antenna for transmitting and receiving a magnetic field component, which is produced by a method comprising: providing a single- or multi-layered magnetic layer comprising a molded sheet or sheets of a mixture of a magnetic powder and a binder resin; forming an electrode material in a spiral configuration around the magnetic layer as an electric circuit to obtain a coil; forming an insulating layer on each of both outer surfaces of the coil; forming a conductive layer on an outer surface of at least one of the insulating layers to obtain a laminate; cutting the laminate into a predetermined size; and calcining the cut laminate into a unitary body.
  • In the third aspect of the present invention, there is provided a magnetic antenna for transmitting and receiving a magnetic field component, which is produced by a method comprising: providing a single- or multi-layered magnetic layer comprising a square or rectangular molded sheet or sheets of a mixture of a magnetic powder and a binder resin; forming through-holes in the magnetic layer; filling the through-holes with an electrode material; forming an electrode layer of an electrode material on each of outer surfaces of the magnetic layer perpendicular to the through-holes such that the electrode layers are connected to the through-holes to form coils and that opposite ends of the magnetic layer conform to open ends of a magnetic circuit; forming an insulating layer on each of both outer surfaces of the coils having the electrode layers; forming a conductive layer on an outer surface of at least one of the insulating layers to obtain a laminate; cutting the laminate along lines passing the through-holes and along lines corresponding to the open ends of the coils; and calcining the cut laminate into a unitary body.
  • The present invention suitable for use in an RFID tag reader/writer includes the following fourth to seventh aspects. In the fourth aspect of the present invention, there is provided a magnetic antenna for transmitting and receiving a magnetic field component, comprising: a plurality of coils each comprising a magnetic layer having a square or rectangular planar shape and arranged radially at generally angularly equal intervals as viewed in a plan view with their one ends connected in series or parallel to one another at the center of the radial pattern by the magnetic layers thereof such that the coils have the same polarity, the plurality of coils extending radially outward and opening in a magnetic circuit at the other ends; an insulating layer provided on one or both outer surfaces of the coils; and a conductive layer provided on an outer surface of at least one of the insulating layers.
  • In the fifth aspect of the present invention, there is provided a magnetic antenna for transmitting and receiving a magnetic field component, comprising: a plurality of coils each comprising a magnetic layer having a square or rectangular planar shape, arranged radially at generally angularly equal intervals as viewed in a plan view, and extending radially inward and opening in a magnetic circuit at their one ends, the plurality of coils having the other ends directed radially outward and connected in series or parallel to one another by an annular magnetic layer such that the coils have the same polarity; an insulating layer provided on one or both outer surfaces of the coils; and a conductive layer provided on an outer surface of at least one of the insulating layers.
  • In the sixth aspect of the present invention, there is provided a magnetic antenna produced using an LTCC technology for transmitting and receiving a magnetic field component, comprising: a plurality of coils each comprising a magnetic layer having a square or rectangular planar shape, arranged radially at generally angularly equal intervals as viewed in a plan view with their one ends connected in series or parallel to one another at the center of the radial pattern by the magnetic layers thereof such that the coils have the same polarity, the plurality of coils extending radially outward and opening in a magnetic circuit at the other ends, and obtainable by a method comprising: providing a single- or multi-layered magnetic layer comprising a square or rectangular molded sheet or sheets of a mixture of a magnetic powder and a binder resin; forming through-holes in the magnetic layer; filling the through-holes with an electrode material; forming an electrode layer of an electrode material on each of surfaces of the magnetic layer perpendicular to the through-holes; punching the magnetic layer and the electrode layers along lines passing the centers of the through-holes to form coil assemblies each having three coils arranged radially with their one ends connected to one another; providing an insulating layer punched into a shape adapted to cover the electrode layer on the upper surface of the magnetic layer on an upper surface of the magnetic layer including the coils and forming another insulating layer on a lower surface of the magnetic layer; forming a conductive layer of the same material as the electrode material on a lower surface of the other insulating layer on the lower surface of the magnetic layer to obtain a laminate; and cutting the laminate into individual pieces of coil assemblies and calcining each piece of coil assembly into a unitary body or calcining the laminate into a unitary body and cutting the calcined laminate into individual pieces of coil assemblies.
  • In the seventh aspect of the present invention, there is provided a magnetic antenna for transmitting and receiving a magnetic field component comprising: a plurality of coils each comprising a magnetic layer having a square or rectangular planar shape, arranged radially at generally angularly equal intervals as viewed in a plan view, and extending radially inward and opening in a magnetic circuit at their one ends, the plurality of coils having the other ends directed radially outward and connected to one another by an annular magnetic layer such that the coils have the same polarity; and obtainable by a method comprising:
    • providing a single- or multi-layered magnetic layer comprising a square or rectangular molded sheet or sheets of a mixture of a magnetic powder and a binder resin; forming through-holes in the magnetic layer; filling the through-holes with an electrode material; forming an electrode layer of an electrode material on each of surfaces of the magnetic layer perpendicular to the through-holes; punching the magnetic layer and the electrode layers along lines passing the centers of the through-holes to form coil assemblies; providing an insulating layer punched into a shape adapted to cover the electrode layer on the upper surface of the magnetic layer on an upper surface of the magnetic layer including the coils and forming an another insulating layer on a lower surface of the magnetic layer; forming a conductive layer of the same material as the electrode material on a lower surface of the other insulating layer on the lower surface of the magnetic layer to obtain a laminate; and cutting the laminate into individual pieces of coil assemblies and calcining each piece of coil assemblies into a unitary body.
    EFFECT OF THE INVENTION
  • According to a magnetic antenna of the present invention, since a conductive layer is provided by an LTCC technology, the laminated layers can be closely bonded to each other and the coil and the conductive layer can be stably joined together. In addition, it is not required to adjust a frequency of the magnetic antenna under environmental conditions upon use, and the frequency can be adjusted independently. Moreover, since the conductive layer is provided, the antenna does not undergo a change in characteristics even when brought close to a metallic object. Further, since a plurality of elements can be stably produced from one sheet, a large number of elements can be produced with little variation and at low production costs.
  • In particular, since the magnetic antenna according to the first to third aspects of the present invention undergoes as small a change in resonant frequency as 1 MHz or less when attached to a metal surface, it can be used in a wide frequency from 125 KHz to 2.45 GHz. For example, when the magnetic antenna is used in a 13.56 MHz RFID tag, a communication distance of 3 cm or greater can be achieved even when the tag is adhered to a metal surface. Also, when the antenna has a symmetrical green sheet laminated structure with respect to the coil at the center, a warpage of 0.5 mm or less per 1 cm length along the long side thereof after firing can be achieved. Therefore, the antenna is suitable for practical use.
  • In addition, since the magnetic antenna according to the fourth to seventh aspects of the present invention has a magnetic layer on the outside of the conductive layer, the change in characteristics at a time when adhered to a metallic object can be further decreased. The magnetic antenna of the present invention can be used in an RFID tag as well as an RFID tag reader/writer, and can be used in a wide frequency range from 125 kHz to 2.45 GHz when the magnetic layer for the coil is properly selected.
  • BRIEF DESCRIPTION OF THE DRAWINGS
    • Fig. 1 is a perspective view illustrating the layer structure of a coil of a magnetic antenna according to first to third aspects of the present invention.
    • Fig. 2 is a perspective view illustrating a magnetic antenna of Example 1 according to the first to third aspects of the present invention.
    • Fig. 3 is a perspective view illustrating a magnetic antenna of Example 2 according to the first to third aspects of the present invention.
    • Fig. 4 is a perspective view illustrating a magnetic antenna of Example 3 according to the first to third aspects of the present invention.
    • Fig. 5 is a perspective view illustrating a magnetic antenna of Example 4 according to the first to third aspects of the present invention.
    • Fig. 6 is a perspective view illustrating a magnetic antenna of Example 5 according to the first to third aspects of the present invention.
    • Fig. 7 is a perspective view illustrating a magnetic antenna of Example 6 according to the first to third aspects of the present invention.
    • Fig. 8 is a perspective view of a laminated magnetic antenna having no conductive layer as Comparative Example 1.
    • Fig. 9 is a perspective view illustrating a magnetic antenna of Example 7 according to fourth to seventh aspects of the present invention.
    • Fig. 10 is a perspective view illustrating a magnetic antenna of Example 8 according to the fourth to seventh aspects of the present invention.
    • Fig. 11 is a circuit diagram schematically illustrating an example in which three coils are connected in series and a capacitor is connected in parallel between both ends thereof in the magnetic antenna shown in Fig. 9 or Fig. 10.
    • Fig. 12 is a circuit diagram schematically illustrating an example in which three coils are connected in series and a capacitor is connected in series to one end thereof in the magnetic antenna shown in Fig. 9 or Fig. 10.
    • Fig. 13 is a circuit diagram schematically illustrating an example in which three coils are connected in parallel and a capacitor is connected in parallel between both ends of each coil in the magnetic antenna shown in Fig. 9 or Fig. 10.
    Explanation of Reference Numerals
  • 11:
    through-hole
    12:
    electrode layer
    13:
    coil open end
    14:
    coil
    15:
    magnetic layer
    16:
    insulating layer
    17:
    conductive layer
    18:
    IC chip connecting terminal
    19:
    coil lead terminal
    1R:
    FM radio
    1C:
    capacitor electrode
    21:
    magnetic layer of coil portion
    22:
    coil electrode
    23:
    insulating layer
    24:
    conductive layer
    25:
    magnetic layer
    26:
    coil electrode formed of cross-section of through-hole
    27:
    direction of magnetic field lines
    28:
    capacitor
    29:
    coil lead terminal
    PREFERRED EMBODIMENTS FOR CARRYING OUT THE INVENTION
  • Embodiments of a magnetic antenna suitable for use in an RFID tag according to first to third aspects of the present invention will be first described with reference to Fig. 1 to Fig. 7.
  • The magnetic antenna of the present invention generally has a coil 14 as shown in Fig. 1 and insulating layers 16 sandwiching the coil 14 from both upper and lower surfaces thereof as shown in Fig. 2. In the magnetic antennas of the present invention, a magnetic layer 15 having a square or rectangular planar shape as shown in Fig. 1 is used to form coils 14. The magnetic layer 15 has a single- or multi-layer structure, and each layer comprises a molded sheet of a mixture of a magnetic powder and a binder. Through-holes 11 are formed in the magnetic layer 15 and filled with an electrode material. Electrode layers 12 of an electrode material are formed on the surfaces of the magnetic layer 15 perpendicular to the through-holes 11 such that the electrode layers 12 are connected to the through-holes 11 to form coils and that opposite ends of the magnetic layer conform to open ends of a magnetic circuit.
  • Then, the coils 14 having the magnetic layer and the electrode layers 12 printed thereon are sandwiched between insulating layers 16 as shown in Fig. 2, and a conductive layer 17 is formed on an upper surface of at least one of the insulating layers 16. The resulting laminate including the coils 14, insulating layers 16 and at least one conductive layer 17 is cut along lines passing the through-holes 11 and along coil open ends 13, and each cut laminate is calcined into a unitary body. In the present invention, an LTCC (Low Temperature Co-fired Ceramics) technology is used as described above to improve the mass productivity.
  • A coil lead terminal 19 and an IC chip connecting terminal 18 may be formed on the magnetic antenna of the present invention as shown in Fig. 3. Through-holes 11 are formed through one or both of the insulating layers 16 provided over the coils 14 having the electrode layers 12 printed thereon, and filled with an electrode material so that the electrode material filled in the through-holes 11 connected to opposite ends of the coil 14. A coil lead terminal 19 and an IC chip connecting terminal 18 are printed on the insulating layer 16 or layers with an electrode material. The resulting laminate including the coils 14, insulating layers 16 and at least one conductive layer 17 is calcined into a unitary body.
  • The magnetic antenna of the present invention may have an additional magnetic layer 15 provided on the lower surface of the insulating layer 16 having a conductive layer 17 thereon as shown in Fig. 4. In this case, the magnetic antenna of the present invention undergoes only slight changes in characteristics and in resonant frequency even when brought close to a metallic object. The magnetic antenna of the present invention may have an additional magnetic layer 15 provided on the lower surface of the insulating layer 16 having a conductive layer 17 thereon and an additional insulating layer 16 provided on the lower surface of the additional magnetic layer as shown Fig. 5. In this case, the stresses between the layers can be balanced in the magnetic antenna of the present invention, and warpage of the magnetic antenna can be reduced.
  • The magnetic antenna of the present invention may have a capacitor electrode 1C as shown in Fig. 6. A capacitor electrode 1C is provided on one or both of the insulating layers between which the coil is sandwiched. An additional insulating layer 16 having an electrode printed on an outer surface thereof is provided on an outer surface of the insulating layers having the capacitor electrode 1C so that a capacitor can be formed between the electrodes. The coil 14 is connected in parallel or series to the IC chip connecting terminal 18 and the coil lead terminal 19.
  • In the magnetic antenna of the present invention, a parallel electrode or interdigital electrode may be printed on the upper surface of the insulating layer to form a capacitor, and the coil 14 may be connected in parallel or series to the coil lead terminal. The capacitor may have a parallel plate structure with an insulating layer 16 sandwiched between electrodes or a planar structure with an interdigital or parallel electrode. When the capacitor has a parallel plate structure, one of the capacitor electrodes may serve as an IC chip connecting terminal 18 as shown in Fig. 6.
  • The magnetic antenna of the present invention has a magnetic layer 15 comprising an Ni-Zn based ferrite magnetic material and is produced by calcination. The ferrite powder preferably has a composition of 45 to 49.5 mol% of Fe2O3, 9.0 to 45.0 mol% of NiO, 0.5 to 35.0 mol% of ZnO and 4.5 to 15.0 mol% of CuO. The composition is suitably selected such that the resulting magnetic layer will have a high magnetic permeability and a low magnetic loss in the frequency band in which it is intended to operate. When the magnetic permeability is too low, the number of turns of the coil will be so large that the antenna will be difficult to produce by an LTCC technology. When the magnetic permeability is too high, the loss will be so large that the magnetic layer will be unsuitable for an antenna. For example, the composition of the ferrite is preferably selected such that the magnetic layer will have a magnetic permeability of 70 to 120 at 13.56 MHz when the antenna is applied to an RFID tag, and have a magnetic permeability of 10 to 30 at 100 MHz when the antenna is used to receive commercial FM broadcasts. The ferrite is calcined at a temperature of 800 to 1000°C and preferably 850 to 920°C.
  • A Zn based ferrite is used for the insulating layers 16. It is preferred to select a Zn based ferrite powder having such a composition that a sintered body formed therefrom has a volume resistivity of 108
    Figure imgb0001
    cm or higher. That is, the Zn based ferrite preferably has a composition of 45 to 49.5 mol% of Fe2O3, 17.0 to 22.0 mol% of ZnO, and 4.5 to 15.0 mol% of CuO. A glass based ceramic may be also used for the insulating layers 16. As the glass based ceramic, a borosilicate glass, a zinc glass, a lead glass or the like can be used.
  • The magnetic antenna of the present invention may have a terminal to which an IC chip is connectable on the upper surface of one of the insulating layers 16 as shown in Fig. 3 and which may be connected in parallel or series to the IC chip connecting terminal 18 and be calcined into a unitary body. Also, a terminal to which a variable capacitor is connectable may be formed on the upper surface of the insulating layer and connected in parallel or series to the coil lead terminal. As the electrode material in the present invention, an Ag paste is suitable. Other metal based conductive pastes such as an Ag based alloy paste can be also used.
  • Next, embodiments of a magnetic antenna suitable for use in an RFID tag reader/writer according to fourth to seventh aspects of the present invention will be described with reference to Fig. 9 to Fig. 13.
  • The magnetic antenna of the present invention is an antenna for transmitting and receiving a magnetic field component and has a plurality of coils each formed of a magnetic layer 21 having a square or rectangular planar shape as shown in Fig. 9. The coils are arranged radially at generally angularly equal intervals as viewed in a plan view. One ends of the coils are connected to one another at the center of the radial pattern by the magnetic layers thereof, and the coils extend radially outward and terminate (open in a magnetic circuit) at the other ends. The one ends of the coils are connected in series (see Fig. 11 and Fig. 12) or parallel (see Fig. 13) to each other such that the coils have the same polarity. An insulating layer 23 is provided on one or both outer surfaces of the coils as viewed in a plan view, and a conductive layer 24 is provided on the outside of at least one of the insulating layers 23.
  • Alternatively, the magnetic antenna of the present invention is a magnetic antenna for transmitting and receiving a magnetic field component and has a configuration as shown in Fig. 10. That is, the magnetic antenna has a plurality of coils each formed of a magnetic layer 21 having a square of rectangular planar shape. The coils are arranged radially at generally angularly equal intervals as viewed in a plan view, and extend radially inward and terminate at their one ends. The other ends of the coils are directed radially outward and connected in series or parallel to one another by an annular magnetic layer such that the coils have the same polarity. An insulating layer 23 is provided on one or both of the outer surfaces of the coils as viewed in a plan view, and a conductive layer 24 is provided on the outside of at least one of the insulating layers 23.
  • The above magnetic antenna is produced utilizing the LTCC technology. The magnetic layer 21 forming the coils has a single- or multi-layer structure, and each layer comprises a molded sheet of a mixture of a calcined magnetic powder and a binder. Through-holes are formed in the magnetic layer 21 and filled with an electrode material. Electrode layers of an electrode material are formed on both surfaces of the magnetic layer 21 perpendicular to the through-holes. The magnetic layer 21 including the electrode layers is punched along lines including lines passing the centers of the through-holes to form a coil structure. That is, coil electrodes 26 are formed by the cross-sections of the electrode material filled in the through-holes. At this time, the magnetic layer 21 is punched to form coil assemblies each having three coils arranged radially with their magnetic layers connected at the center of the radial pattern. The shaped magnetic layer 21 (coils) is sandwiched between insulating layers 23. The insulating layer 23 provided on the upper surface of the magnetic layer having an electrode layer printed thereon has been previously punched into a shape adapted to cover the electrode layer 24. A conductive layer 24 comprising the same material as the electrode material is provided on the lower surface of the insulating layer 23 on the lower surface of the magnetic layer 21. Then, the resulting laminate is cut into individual pieces of coil assemblies, and each piece of coil assembly is calcined into a unitary body.
  • The magnetic antenna produced as described above has a plurality of coils arranged radially and each having a magnetic layer 21 with a square or rectangular planar shape. One ends of the coils are connected by the magnetic layer 21, and the coils extend radially and terminate at the other ends. The coils are connected in series or parallel to one another such that all the coils have the same polarity. Since the coils facing one another have the same polarity, components of a magnetic field 27 parallel to a metal surface are cancelled (see Fig. 11), and only components perpendicular to the metal surface can be obtained (see Fig. 9 and Fig. 10).
  • In the magnetic antenna of the present invention, the insulating layers 23 on both sides of the coils having electrode layers 24 printed thereon or the insulating layer 23 opposite the one on which the conductive layer 24 has been formed may have through-holes filled with an electrode material, and a coil lead terminals 29 of an electrode material printed thereon and connected to the beginnings and ends of the coils. In addition, an additional magnetic layer 25 may be provided on the outside the conductive layer 24. When a magnetic layer 25 is provided on the outside of the conductive layer 24, the change in resonant frequency can be decreased when the magnetic antenna is attached to a metal surface as compared to a magnetic antenna without the magnetic layer 25. Moreover, the magnetic antenna of the present invention may have another insulating layer on the outside of the magnetic layer on the outside of the conductive layer 24. In this case, the stress between the layers in the laminate structure including the coils can be balanced, and warpage of the magnetic antenna can be reduced.
  • The magnetic antenna of the present invention may have another insulating layer having square or circular electrodes printed on both sides thereof on said additional insulating layer provided on an upper surface of insulating layers 23 covering said coil to form a capacitor 28. The capacitor 28 is connected in parallel (see Fig. 11 and Fig. 13) or series (see Fig. 12) to the coil lead terminal electrodes 29 to form a circuit as shown in Fig. 11 to Fig. 13.
  • The magnetic antenna of the present invention may have a parallel electrode or an interdigital electrode printed on an upper surface of the insulating layer 23 on the upper surfaces of the coils to form a capacitor 28. The capacitor 28 is connected in parallel (see Fig. 11 and Fig. 13) or series (see Fig. 12) to the coil lead terminals 29 to form a circuit as shown in Fig. 11 to Fig. 13. A specific print pattern is shown in Fig. 6. The capacitor 28 may have a parallel plate structure having electrodes provided on both sides of an insulating layer 23 or a planar structure having an interdigital or a parallel electrode. When the capacitor 28 has a parallel plate structure, one of the capacitor electrode may serve as an IC chip connecting terminal.
  • The magnetic antenna of the present invention uses an Ni-Zn based ferrite magnetic material for the magnetic layer 21 as the magnetic antenna according to the first to third aspects mentioned above, and is produced by calcination. The composition of the ferrite powder and the ferrite calcination temperature are the same as those in the case of the magnetic antenna described above. The composition of the insulating layers 23 is also the same as in the case of the magnetic antenna described above. A glass based ceramic may be used for the insulating layers 23 as in the case of the magnetic antenna described above.
  • The magnetic antenna of the present invention may have a terminal to which an IC chip is connectable on the surface of insulating layer 23 and which is connected in parallel or series to the coil lead terminals 29 as in the case of the magnetic antenna described above. In addition, an Ag paste is suitable for the electrode material as in the case of the magnetic antenna described above. Other metal conductive pastes such as Ag based alloy paste can be also used.
  • EXAMPLES
  • The following examples are examples in which the present invention is applied to a widely used 13.56 MHz IC card type tag system. First, examples of the magnetic antenna according to the first to third aspects of the present invention (Examples 1 to 6) and comparative examples corresponding thereto (Comparative Examples 1 and 2) will be described.
  • Example 1:
  • A magnetic antenna of the present invention was produced using an LTCC technology. First, a magnetic layer 15 was prepared. 100 Parts by weight of a calcined Ni-Zn-Cu ferrite powder which had been found to have a magnetic permeability of 100 at 13.56 MHz upon calcination at 900°C (Fe2O3: 48.5 mol%, NiO: 25 mol%, ZnO: 16 mol%, CuO: 10.5 mol%), 8 parts by weight of a butyral resin, 5 parts by weight of a plasticizer, and 80 parts by weight of a solvent were mixed in a ball mill to prepare a slurry. The slurry was applied on PET films with a size of 150 mm x 150 mm by a doctor blade to such a thickness that the resulting layer thickness after calcination would be 0.1 mm.
  • Insulating layers 16 were prepared as follows. 100 Parts by weight of a calcined Zn-Cu ferrite powder (Fe2O3: 48.5 mol%, ZnO: 41 mol%, CuO: 10.5 mol%), 8 parts by weight of a butyral resin, 5 parts by weight of a plasticizer, and 80 parts by weight of a solvent were mixed in a ball mill to prepare a slurry. The slurry was applied on PET films to obtain sheets with the same size and thickness as the sheets for the magnetic layer.
  • Five green sheets for the magnetic layer 15 were stacked on top of one another as shown in Fig. 1, and through-holes 11 were formed therethrough and filled with an Ag paste. Then, an Ag paste was printed on the surfaces of the laminate perpendicular to the through-holes 11 to form coils 14. The green sheets for the insulating layers 16 were stacked on the upper and lower surfaces of the coils 14 as shown in Fig. 2. A green sheet for another insulating layer 16 having a conductive layer 17 of an Ag paste printed on a surface thereof was stacked on the laminate.
  • The above green sheets were bonded together by applying a pressure. The resulting laminate was cut along lines passing the through-holes 11 and along coil open ends 13, and calcined at 900°C for two hours into a unitary body, thereby obtaining a magnetic antenna with a size of 18 mm (length) x 4 mm (width) having a 32-turn coil (sample 1) (The coil is shown as having only seven turns and a magnetic layer as being formed of only three layers in Fig. 1 and Fig. 2 for simplification, which applies also other drawings).
  • An IC for an RFID tag was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel to the IC. Then, the resonant frequency was adjusted to 13.1 MHz, thereby obtaining an RFID tag. The RFID tag was attached to a metal plate, and its communication distance, the distance over which it was able to communicate with a reader/writer having an output of 10 mW, was measured. Also, the warpage of the magnetic antenna was measured. The measuring methods are described below.
  • (Methods for measuring and adjusting resonant frequency)
  • The resonant frequency was measured by the following method. A one-turn coil was connected to an impedance analyzer (manufactured by Hewlett Packard Company, product name; 4291A), which was in turn coupled to the RFID tag. The peak frequency of the measured impedance was defined as the resonant frequency. The adjustment of the resonant frequency was made by selecting the position of the coil electrodes exposed at ends of the magnetic antenna to adjust the inductance. The resonant frequency can be adjusted by changing the capacity of a capacitor connected in parallel to the IC.
  • (Methods for measuring communication distance)
  • The communication distance was measured by the following method. The antenna of a reader/writer having an output of 10 mW (manufactured by FEC Inc., product name; URWI-201) was fixed horizontally, and the RFID tag attached to a metal plate was placed horizontally above the antenna. Then, the RFID tag was moved within a range in which it was able to communicate at 13.56 MHz and the maximum vertical distance between the antenna and the RFID tag was defined as the communication distance.
  • (Methods for measuring warpage)
  • A dial gage (Mitutoyo Dial Gage ID-C112) having a flat probe was attached to a stand (Mitutoyo Stand BSG-20), and the zero point of the dial gage was adjusted on the surface plate. The magnetic antenna was placed between the surface plate and the flat probe, and the height of the highest point was measured with the dial gage. The thickness of the magnetic antenna measured with a caliper (Mitutoyo caliper CD-C) was subtracted from the height to obtain the warpage.
  • The resonant frequency, communication distance, and warpage were measured by the above methods. The magnetic antenna had a warpage of 0.6 mm, which is in a permissible range for practical use. The RFID tag using the magnetic antenna showed as small a difference as +1 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was 3 cm.
  • Example 2:
  • The same green sheets for the magnetic layer 15 as in Example 1, and green sheets comprising a glass ceramic, instead of a Zn-Cu ferrite, for the insulating layers 16 were used. As shown in Fig. 3, five green sheets for the magnetic layer 15 were stacked on top of one another, and through-holes 11 were formed therethrough and filled with an Ag paste. Then, an Ag paste was printed on the surfaces of the laminate perpendicular to the through-holes 11 to form coils 14.
  • A green sheet for an insulating layer 16 was stacked on one surfaces of the coils 14. At this time, a conductive layer 17 was printed on the insulating layer 16 with an Ag paste. Another insulating layer 16 was stacked on the other surfaces of the coils 14, and through-holes 11 were formed through the other insulating layer 16 in connection with both ends of the coils 14 and filled with an Ag paste. Coil lead terminals 19 and IC chip connecting terminals 18 to which an IC was connectable were printed on the outer surface of the other insulating layer perpendicular to the through-holes 11 with an Ag paste.
  • The green sheets were bonded together by applying a pressure. The resulting laminate was cut along lines passing the through-holes 11 and along coil open ends 13, and calcined at 900°C for two hours into a unitary body, thereby obtaining a magnetic antenna with a size of 18 mm (length) x 4 mm (width) having a 32-turn coil (sample 2).
  • An IC for an RFID tag was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel to the IC just as in Example 1. Then, the resonant frequency was adjusted to 13.1 MHz, thereby obtaining an RFID tag. The RFID tag was attached to a metal plate, and its communication distance, the distance over which it was able to communicate with a reader/writer having an output of 10 mW and its resonant frequency, were measured. The warpage of the magnetic antenna was also measured. The magnetic antenna had a warpage of 1.0 mm, which is in a permissible range for practical use. The RFID tag using the magnetic antenna had a resonant frequency of 14.1 MHz and showed as small a difference as +1 MHz in the resonant frequency before and after being attached to a metal plate. The communication distance after the RFID tag was attached to a metal surface was 3.1 cm.
  • Example 3:
  • The same green sheets for the magnetic layer 15 and the same green sheets for the insulating layers 16 as in Example 1 were used. As shown in Fig. 4, five green sheets for the magnetic layer 15 were stacked on top of one another, and through-holes 11 were formed therethrough and filled with an Ag paste. Then, an Ag paste was printed on the surfaces of the laminate perpendicular to the through-holes 11 to form coils 14.
  • A green sheet for an insulating layer 16 was stacked on the lower surfaces of the coils 14. At this time, a conductive layer 17 was printed on the insulating layer 16 with an Ag paste. A green sheet for a magnetic layer 15 was stacked on the lower surface of the insulating layer 16. A green sheet for another insulating layer 16 was stacked on the upper surfaces of the coils 14, and through-holes 11 were formed in the upper surface of the other insulating layer 16 in connection with both ends of the coils 14 and filled with Ag paste. Coil lead terminals 19 and IC chip connecting terminals 18 to which an IC was connectable were printed on the outer surface of the other insulating layer perpendicular to the through-holes 11 with an Ag paste.
  • The green sheets were bonded together by applying a pressure. The resulting laminate was cut along lines passing the through-holes 11 and along coil open ends 13, and calcined in the same manner as in Example 1, thereby obtaining a magnetic antenna with a size of 18 mm (length) x 4 mm (width) having a 32-turn coil (sample 3).
  • An IC for an RFID tag was connected to the IC chip connecting terminal 18 of the magnetic antenna as in Example 1, and a capacitor was connected in parallel to the IC. Then, the resonant frequency was adjusted to 13.1 MHz, thereby obtaining an RFID tag. The RFID tag was attached to a metal plate, and its communication distance, the distance over which it was able to communicate with a reader/writer having an output of 10 mW, and its resonant frequency were measured. The warpage of the magnetic antenna was also measured. The magnetic antenna had a warpage of 0.8 mm, which is in a permissible range for practical use. The RFID tag using the magnetic antenna showed a difference of +0.5 MHz in the resonant frequency before and after being attached to a metal plate, which was smaller than those in the above Examples. The communication distance after the RFID tag was attached to a metal surface was 3.3 cm.
  • Example 4:
  • The same green sheets for the magnetic layer 15 and the same green sheets for the insulating layers 16 as in Example 1 were used. As shown in Fig. 5, five green sheets for the magnetic layer 15 were stacked on top of one another, and through-holes 11 were formed therethrough and filled with an Ag paste. Then, an Ag paste was printed on the surfaces of the laminate perpendicular to the through-holes 11 to form coils 14.
  • Two green sheets for insulating layers 16 were stacked on the lower surfaces of the coils 14. At this time, a conductive layer 17 was printed on the lower insulating layer 16 with an Ag paste. A green sheet for a magnetic layer 15 was stacked on the lower surface of the lower insulating layer 16, and a green sheet for another insulating layer 16 was stacked on the lower surface thereof. Through-holes 11 were formed through the insulating layer 16 on the upper surfaces of the coils 14 in connection with one ends of the coils 14 and filled with an Ag paste. Coil lead terminals 19 and a half in number of IC chip connecting terminals 18 to which an IC was connectable were printed on the outer surface of the insulating layer perpendicular to the through-holes 11 with an Ag paste. Through-holes 11 were formed through the insulating layer 16 on the upper surfaces of the coils 14 in connection with one ends and several intermediate points of the coils 14 and filled with an Ag paste. Coil lead terminals 19 and the other half of IC chip connecting terminals 18 to which an IC was connectable were printed with an Ag paste on an outer surface of the insulating layer perpendicular to the through-holes 11. Ends of the coil lead terminals 19 were extended in such a manner that they were opposed to each other.
  • The green sheets were bonded together by applying a pressure. The resulting laminate was cut along lines passing the through-holes 11 and along coil open ends 13, and calcined at 900°C for two hours into a unitary body, thereby obtaining a magnetic antenna with a size of 18 mm (length) x 4 mm (width) having a 32-turn coil (sample 4).
  • An IC for an RFID tag was connected to the IC chip connecting terminal 18 of the magnetic antenna as in Example 1. Then, the end faces of the coil lead terminals 19 opposed to each other were short-circuited with a conductive coating or the like, and the inductance was adjusted to adjust the resonant frequency to 13.1 MHz, thereby obtaining an RFID tag. The RFID tag was attached to a metal plate, and its communication distance, the distance over which it was able to communicate with a reader/writer having an output of 10 mW, and its resonant frequency were measured. The warpage of the magnetic antenna was also measured. The magnetic antenna had a warpage of 1.0 mm, which was extremely small. The RFID tag using the magnetic antenna showed as small a difference as +0.5 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was 3.4 cm.
  • Example 5:
  • The same green sheets for the magnetic layer 15 and the same green sheets for the insulating layers 16 as in Example 1 were used. As shown in Fig. 6, five green sheets for the magnetic layer 15 were stacked together on each other, and through-holes 11 were formed therethrough and filled with an Ag paste. Then, an Ag paste was printed on the surfaces of the laminate perpendicular to the through-holes 11 to form coils 14.
  • Two green sheets for insulating layers 16 were stacked on the lower surfaces of the coils 14. At this time, a conductive layer 17 was printed on the lower insulating layer 16 with an Ag paste. A green sheet for a magnetic layer 15 was stacked on the lower surface of the lower insulating layer 16. A green sheet for a magnetic layer 15 and a green sheet for an insulating layer 16 were stacked on the upper surfaces of the coils 14. Through-holes 11 were formed through the green sheet for an insulating layer 16 on the upper surfaces of the coils 14 in connection with both ends of the coil 14 and filled with an Ag paste. Capacitor electrodes 1C were printed on an outer surface of the insulating layer perpendicular to the through-holes 11 with an Ag paste. IC chip connecting terminals 18 were printed on the green sheet for another insulating layer 16 on the upper surface of the insulating layer to form capacitors between the IC chip connecting terminals 18 and the capacitor electrodes 1C.
  • The green sheets were bonded together by applying a pressure. The resulting laminate was cut along lines passing the through-holes 11 and along coil open ends 13, and calcined at 900°C for two hours into a unitary body, thereby obtaining a magnetic antenna with a size of 18 mm (length) × 4 mm (width) having a 32-turn coil (sample 5).
  • An IC for an RFID tag was connected to the IC chip connecting terminal 18 of the magnetic antenna, and the capacitance was adjusted by cutting off a part of the IC chip connecting terminal 18 to adjust the resonant frequency to 13.1 MHz, thereby obtaining an RFID tag. The RFID tag was attached to a metal plate, and its communication distance, the distance over which it was able to communicate with a reader/writer having an output of 10 mW, and its resonant frequency were measured. The warpage of the magnetic antenna was also measured. The magnetic antenna had a warpage of 0.1 mm, which was extremely small. The RFID tag using the magnetic antenna showed as small a difference as +0.5 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was 3.3 cm.
  • Example 6:
  • Green sheets for a magnetic layer 15 were prepared. 100 Parts by weight of a calcined Ni-Zn-Cu ferrite powder which had been found to have a magnetic permeability of 20 at 100 MHz upon calcination at 900°C (Fe2O3: 48.5 mol%, NiO: 39 mol%, ZnO: 2 mol%, CuO: 10.5 mol%), 7 parts by weight of a butyral resin, 3 parts by weight of a plasticizer, 100 parts by weight of a solvent were mixed in a ball mill to prepare a slurry. The slurry was applied on PET films with a doctor blade.
  • Green sheets for an insulating layer 16 were prepared. 100 Parts by weight of a calcined Zn-Cu ferrite powder (Fe2O3: 48.5 mol%, ZnO: 40 mol%, CuO: 11.5 mol%), 7 parts by weight of a butyral resin, 3 parts by weight of a plasticizer, 100 parts by weight of a solvent were mixed in a ball mill to prepare a slurry, and the slurry was applied on PET films with a doctor blade.
  • As shown in Fig. 7, five green sheets for the magnetic layer 15 were stacked together on each other, and through-holes 11 were formed therethrough and filled with an Ag paste. An Ag paste was printed on the surfaces of the laminate perpendicular to the through-holes 11 to form coils 14. The green sheets for the insulating layers 16 were stacked on the upper and lower surfaces of the coils 14, and another insulating layer 16 having a conductive layer 17 of an Ag paste printed thereon was stacked on the insulating layer 16 on the lower surfaces of the coils 14.
  • The green sheets were bonded together by applying a pressure. The resulting laminate was cut along lines passing the through-holes 11 and along coil open ends 13, and calcined at 900°C for two hours into a unitary body, thereby obtaining a magnetic antenna with a size of 18 mm (length) x 4 mm (width) having a 50-turn coil (sample 6).
  • An FM radio 1R was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel to the coil 14. The resonant frequency was adjusted to 82 MHz, thereby obtaining an FM broadcast receiving antenna. This is intended for use as an antenna on a metallic case of a cellular phone or the like. When the magnetic antenna was attached to a metal plate and used to receive an FM broadcast (82 MHz), good reception was achieved. When the warpage of the magnetic antenna was measured, the warpage was as small as 0.6 mm.
  • Comparative Example 1:
  • A magnetic antenna (sample 7), which was the same as the magnetic antenna of Example 1 except for not having a conductive layer 17 as shown in Fig. 8, was produced. An IC for an RFID tag was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel to the IC as in Example 1. The resonant frequency was adjusted to 13.1 MHz, thereby obtaining an RFID tag. The RFID tag was attached to a metal plate, and the communication distance, resonant frequency, and warpage of the magnetic antenna were measured in the same manner as in Example 1. The magnetic antenna had a warpage of 1.0 mm. The RFID tag using the magnetic antenna showed as large a difference as +1.5 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was only 1.4 cm.
  • Comparative Example 2:
  • For the purpose of comparison, a commercially available IC card type tag (manufactured by Texas Instruments, product name; Tag-it TMHF) having an antenna coil formed on surfaces of a resin film in a spiral pattern and an IC connected to both ends of the antenna coil was attached to a metal plate and its communication distance was measured in the same manner as in Example 1. The communication distance after being attached to a metal plate was 0.1 cm, and no resonant frequency was observed after being attached to a metal plate.
  • The results of measurement in the above Examples and Comparative Examples are summarized and shown in Table 1 below.
    Figure imgb0002
    Figure imgb0003
  • Examples of the magnetic antenna according to fourth to seventh aspects of the present invention (Examples 7 and 8) and comparative examples corresponding thereto (Comparative Examples 3 and 4) will be next described.
  • Example 7:
  • A magnetic antenna of the present invention was produced using an LTCC technology. First, a magnetic layer 21 was prepared. A calcined ferrite powder, a butyral resin, a plasticizer, and a solvent were mixed in a ball mill to prepare a slurry and the slurry was shaped into sheets in the same manner as in Example 1. Also, insulating layers 23 were prepared in the same manner as in Example 1. That is, a calcined Zn-Cu ferrite powder, a butyral resin, a plasticizer, a solvent were mixed in a ball mill to prepare a slurry and the slurry was shaped into sheets in the same manner as in Example 1.
  • Five green sheets for the magnetic layer 21 were stacked together on each other, and through-holes were formed therethrough and filled with an Ag paste. An Ag paste was printed on surfaces of two of the green sheets perpendicular to the through-holes to form coil electrodes 22. Then, the five green sheets were punched along lines passing the centers of the through-holes to form coil assemblies each having three coils arranged radially with their magnetic layers connected at the center of the radial pattern. Then, the five green sheets were stacked in such a manner that the two green sheets having a coil electrode printed thereon were placed on both sides of the other three green sheets to form three-pole coils. A green sheet as an insulating layer 23 punched in the same pattern as the magnetic layer and having a conductive layer 24 of an Ag paste printed thereon was stacked on the lower surfaces of the coil assemblies in such a manner that the conductive layer 24 was located outside.
  • The above green sheets were bonded together by applying a pressure. The resulting laminate was cut into individual pieces of coil assemblies, and each piece of coil assembly was calcined at 900°C for two hours into a unitary body, thereby obtaining a magnetic antenna having coils each having a length of 20 mm and 10 turns (sample 8). Fig. 9 shows a schematic view of the obtained magnetic antenna. In the drawing, the number of turns of the coils is shown in a simplified manner.
  • An RFID tag reader/writer was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel to the reader/writer. The resonant frequency was adjusted to 13.56 MHz. The magnetic antenna was attached to a metal plate, and its communication distance, the distance over which it was able to communicate with an RFID tag, was measured. The methods for measuring and adjusting the resonant frequency, and the method for measuring the communication distance are described below.
  • (Methods for measuring and adjusting resonant frequency)
  • The resonant frequency was measured by the following method. A one-turn coil is connected to an impedance analyzer (manufactured by Hewlett Packard Company, product name; 4291A), which was in turn coupled to the RFID tag reader/writer. The peak frequency of the measured impedance was defined as the resonant frequency. The adjustment of the resonant frequency was made by changing the capacity of a capacitor connected in parallel or series thereto.
  • (Method for measuring communication distance)
  • The communication distance was measured by the following method. The standard antenna of a reader/writer having an output of 100 mW (manufactured by Takaya Corporation, product name; D002A) was removed, and the magnetic antenna of the present invention was connected thereto and fixed horizontally. An RFID tag (IC card type tag, manufactured by Texas Instruments, product name; Tag-it(TM)HF) was placed horizontally above the magnetic antenna. Then, the RFID tag was moved within a range in which it was able to communicate at 13.56 MHz and the maximum vertical distance between the antenna and the RFID tag was defined as the communication distance.
  • As a result of measuring the resonant frequency and communication distance by the above methods, the reader/writer using the magnetic antenna showed as small a difference as +1 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was 3 cm.
  • Example 8:
  • The same green sheets for a magnetic layer 21 as in Example 7, and green sheets comprising a glass ceramic, instead of a Zn-Cu ferrite, for the insulating layers 23 were used. Five green sheets for the magnetic layer 21 were stacked on top of one another, and through-holes were formed therethrough and filled with an Ag paste. An Ag paste was printed on surfaces of two of the green sheets perpendicular to the through-holes to form coil electrodes 22.
  • Then, the five green sheets were punched along lines passing the centers of the through-holes to form coil assemblies each having three coils arranged radially with their magnetic layers connected to an annular portion surrounding them. Then, the five green sheets were stacked in such a manner that the two green sheets having a coil electrode printed thereon were placed on both sides of the other three green sheets to form a three-pole coil. A green sheet as an insulating layer 23 having a conductive layer 24 of an Ag paste printed thereon and having a circular shape was stacked on the lower surface of the coil to cover the entire lower surface thereof in such a manner that the conductive layer 24 was located outside, and a green sheet as another magnetic layer 25 was stacked on the lower surface of the conductive layer 24.
  • The above green sheets were bonded together by applying a pressure. The resulting laminate was cut into individual pieces of coil assemblies, and each piece of coil assembly was calcined at 900°C for two hours into a unitary body, thereby obtaining a magnetic antenna having a diameter of 10 mm and having seven turn coils (sample 9). Fig. 10 shows a schematic view of the obtained magnetic antenna. In the drawing, the number of turns of the coils is shown in a simplified manner.
  • An RFID tag reader/writer was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel or series to the reader/writer. The resonant frequency was adjusted to 13.56 MHz. The change in the resonant frequency and its communication distance, the distance over which it was able to communicate with an RFID tag when attached to a metal plate, were measured in the same manner as in Example 7. The reader/writer using the magnetic antenna showed as small a difference as +0.5 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was 3.4 cm.
  • Comparative Example 3:
  • A magnetic antenna (sample 10), which was the same as the magnetic antenna of Example 7 except for not having the conductive layer 24 shown in Fig. 9, was produced. An RFID tag reader/writer was connected to both ends of the coil of the magnetic antenna, and a capacitor was connected in parallel or series to the reader/writer. The resonant frequency was adjusted to 13.56 MHz. The change in the resonant frequency and the communication distance of the magnetic antenna, the distance over which it was able to communicate with an RFID tag when attached to a metal plate, were measured in the same manner as in Example 7. The reader/writer using the magnetic antenna showed a difference of +2.3 MHz in the resonant frequency before and after being attached to a metal plate, and the communication distance after being attached to a metal surface was 1.6 cm.
  • Comparative Example 4:
  • For the purpose of comparison, a commercially available antenna for a reader/writer having a coil formed on surfaces of a resin film in a spiral pattern was attached to a metal plate and its communication distance, the distance over which it was able to communicate with an RFID tag, was measured. The antenna has a size of 30 mm x 55 mm, and the coil has three turns. The communication distance after being attached to a metal plate was 0.5 cm.

Claims (28)

  1. A magnetic antenna for transmitting and receiving a magnetic field component, comprising:
    a coil comprising a magnetic layer and an electrode material formed in a spiral configuration around said magnetic layer;
    an insulating layer provided on one or both outer surfaces of said coil; and
    a conductive layer provided on an outer surface of at least one of said insulating layers.
  2. A magnetic antenna for transmitting and receiving a magnetic field component, which is produced by a method comprising:
    providing a single- or multi-layered magnetic layer comprising a molded sheet or sheets of a mixture of a magnetic powder and a binder resin;
    forming an electrode material in a spiral configuration around said magnetic layer as an electric circuit to obtain a coil;
    forming an insulating layer on each of both outer surfaces of said coil;
    forming a conductive layer on an outer surface of at least one of said insulating layers to obtain a laminate;
    cutting the laminate into a predetermined size; and
    calcining the cut laminate into a unitary body.
  3. A magnetic antenna for transmitting and receiving a magnetic field component, which is produced by a method comprising:
    providing a single- or multi-layered magnetic layer comprising a square or rectangular molded sheet or sheets of a mixture of a magnetic powder and a binder resin;
    forming through-holes in said magnetic layer;
    filling said through-holes with an electrode material;
    forming an electrode layer of an electrode material on each of outer surfaces of said magnetic layer perpendicular to said through-holes such that said electrode layers are connected to said through-holes to form coils and that opposite ends of said magnetic layer conform to open ends of a magnetic circuit;
    forming an insulating layer on each of both outer surfaces of said coils having the electrode layers;
    forming a conductive layer on an outer surface of at least one of said insulating layers to obtain a laminate;
    cutting the laminate along lines passing said through-holes and along lines corresponding to said open ends of said coils; and
    calcining the cut laminate into a unitary body.
  4. A magnetic antenna according to claim 3, wherein said method further comprises forming holes through one or both of said insulating layers provided over the coils having the electrode layers printed thereon, filling said holes with an electrode material so that the filled electrode material in said holes is connected to opposite ends of said coil; and printing a coil lead terminal and an IC chip connecting terminal on said insulating layer or layers.
  5. A magnetic antenna according to claim 3 or 4, further comprising an additional insulating layer or an additional magnetic layer provided on an outer surface of said conductive layer provided on said insulating layers.
  6. A magnetic antenna according to any one of claims 3 to 6, further comprising an additional insulating layer provided on an outer surface of said conductive layer provided on said insulating layers, and an additional magnetic layer provided on an outer surface of said additional insulating layer.
  7. A magnetic antenna according to any one of claims 3 to 5, further comprising an additional magnetic layer provided on an outer surface of said conductive layer provided on said insulating layers, and an additional insulating layer provided on an outer surface of said additional magnetic layer.
  8. A magnetic antenna according to any one of claims 3 to 6, further comprising an additional insulating layer provided on an outer surface of said conductive layer provided on said insulating layers, an additional magnetic layer provided on an outer surface of said additional insulating layer, and a yet additional insulating layer provided on an outer surface of said additional magnetic layer.
  9. A magnetic antenna according to any one of claims 3 to 8, further comprising a capacitor electrode provided on one or both of said insulating layers between which said coil is sandwiched; an additional insulating layer provided on the outside of said capacitor electrode and having an electrode printed on an outer surface thereof so that a capacitor is formed between said capacitor electrode and said electrode, wherein said capacitor is connected in parallel or series to said IC chip connecting terminal.
  10. A magnetic antenna according to any one of claims 3 to 9, further comprising a parallel electrode or interdigital electrode printed on a surface of one of said insulating layers to form a capacitor, wherein said capacitor is connected in parallel or series to said coil lead terminal.
  11. A magnetic antenna according to any one of claims 3 to 10, wherein said magnetic layer comprises an Ni-Zn based ferrite.
  12. A magnetic antenna according to any one of claims 3 to 11, wherein said insulating layers comprise a Zn based ferrite.
  13. A magnetic antenna according to any one of claims 3 to 12, wherein said insulating layers comprise a glass based ceramic.
  14. A magnetic antenna according to any one of claims 3 to 13, further comprising a terminal to which said IC chip is connectable on an upper surface of one of said insulating layers, wherein said terminal is connected in parallel or series to said coil lead terminal.
  15. A magnetic antenna according to any one of claims 3 to 14, further comprising a terminal to which a variable capacitor is connectable, wherein said terminal is connected in parallel or series to said coil lead terminal.
  16. A magnetic antenna for transmitting and receiving a magnetic field component, comprising:
    a plurality of coils each comprising a magnetic layer having a square or rectangular planar shape and arranged radially at generally angularly equal intervals as viewed in a plan view with their one ends connected in series or parallel to one another at the center of the radial pattern by the magnetic layers thereof such that said coils have the same polarity, said plurality of coils extending radially outward and opening in a magnetic circuit at the other ends;
    an insulating layer provided on one or both outer surfaces of said coils; and
    a conductive layer provided on an outer surface of at least one of said insulating layers.
  17. A magnetic antenna for transmitting and receiving a magnetic field component, comprising:
    a plurality of coils each comprising a magnetic layer having a square or rectangular planar shape, arranged radially at generally angularly equal intervals as viewed in a plan view, and extending radially inward and opening in a magnetic circuit at their one ends, said plurality of coils having the other ends directed radially outward and connected in series or parallel to one another by an annular magnetic layer such that said coils have the same polarity;
    an insulating layer provided on one or both outer surfaces of said coils; and
    a conductive layer provided on an outer surface of at least one of said insulating layers.
  18. A magnetic antenna produced using an LTCC technology for transmitting and receiving a magnetic field component, comprising:
    a plurality of coils each comprising a magnetic layer having a square or rectangular planar shape, arranged radially at generally angularly equal intervals as viewed in a plan view with their one ends connected in series or parallel to one another at the center of the radial pattern by the magnetic layers thereof such that said coils have the same polarity, said plurality of coils extending radially outward and opening in a magnetic circuit at the other ends, and
    which is produced by a method comprising:
    providing a single- or multi-layered magnetic layer comprising a square or rectangular molded sheet or sheets of a mixture of a magnetic powder and a binder resin;
    forming through-holes in said magnetic layer;
    filling said through-holes with an electrode material;
    forming an electrode layer of an electrode material on each of surfaces of said magnetic layer perpendicular to said through-holes;
    punching said magnetic layer and said electrode layers along lines passing the centers of said through-holes to form coil assemblies each having three coils arranged radially with their one ends connected to one another;
    providing an insulating layer punched into a shape adapted to cover said electrode layer on the upper surface of said magnetic layer on an upper surface of said magnetic layer including said coils and forming another insulating layer on a lower surface of said magnetic layer;
    forming a conductive layer of the same material as the electrode material on a lower surface of said other insulating layer on the lower surface of said magnetic layer to obtain a laminate; and
    cutting said laminate into individual pieces of coil assemblies and calcining each piece of coil assembly into a unitary body or calcining the laminate into a unitary body and cutting said calcined laminate into individual pieces of coil assemblies.
  19. A magnetic antenna for transmitting and receiving a magnetic field component comprising:
    a plurality of coils each comprising a magnetic layer having a square or rectangular planar shape, arranged radially at generally angularly equal intervals as viewed in a plan view, and extending radially inward and opening in a magnetic circuit at their one ends, said plurality of coils having the other ends directed radially outward and connected to one another by an annular magnetic layer such that said coils have the same polarity; and
    which is produced by a method comprising:
    providing a single- or multi-layered magnetic layer comprising a square or rectangular molded sheet or sheets of a mixture of a magnetic powder and a binder resin;
    forming through-holes in said magnetic layer;
    filling said through-holes with an electrode material;
    forming an electrode layer of an electrode material on each of surfaces of said magnetic layer perpendicular to said through-holes;
    punching said magnetic layer and said electrode layers along lines passing the centers of said through-holes to form coil assemblies;
    providing an insulating layer punched into a shape adapted to cover said electrode layer on the upper surface of said magnetic layer on an upper surface of said magnetic layer including said coils and forming an another insulating layer on a lower surface of said magnetic layer;
    forming a conductive layer of the same material as the electrode material on a lower surface of said other insulating layer on the lower surface of said magnetic layer to obtain a laminate; and
    cutting said laminate into individual pieces of coil assemblies and calcining each piece of coil assemblies into a unitary body.
  20. A magnetic antenna according to any one of claims 16 to 19, wherein said method further comprises forming through-holes in said insulating layer opposite the one on which said conductive layer has been formed, filling said through-holes with an electrode material so that the filled electrode material in said through-holes is connected to opposite ends of said coils, and printing coil lead terminals of an electrode material on said insulating layer.
  21. A magnetic antenna according to any one of claims 16 to 20, further comprising an additional magnetic layer provided on an outer surface of said conductive layer.
  22. A magnetic antenna according to claims 21, further comprising an additional insulating layer provided on an outer surface of said additional magnetic layer.
  23. A magnetic antenna according to any one of claims 16 to 22, further comprising an additional insulating layer having square or circular electrodes printed on both sides thereof on said additional insulating layer and provided on an upper surface of insulating layers covering said coil to form a capacitor, wherein said electrodes of said capacitor are connected in parallel or series to said coil lead terminal electrodes.
  24. A magnetic antenna according to any one of claims 16 to 23, further comprising a parallel electrode or an interdigital electrode printed on an upper surface of said insulating layer on the upper surface of said coil assembly to form a capacitor, and said capacitor is connected in parallel or series to said coil lead terminals.
  25. A magnetic antenna according to any one of claims 16 to 24, wherein said magnetic layer comprises an Ni-Zn based ferrite.
  26. A magnetic antenna according to any one of claims 16 to 25, wherein said insulating layers comprises a Zn based ferrite.
  27. A magnetic antenna according to any one of claims 16 to 25, wherein said insulating layers comprises a glass based ceramic.
  28. A magnetic antenna according to any one of claims 16 to 27, further comprising a terminal on an upper surface thereof to which an IC chip is connectable, wherein said terminal is connected in parallel or series to said coil lead terminals.
EP06767954.8A 2005-07-07 2006-07-06 Magnetic antenna Active EP1901394B1 (en)

Applications Claiming Priority (3)

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JP2005199451A JP4821965B2 (en) 2005-07-07 2005-07-07 Magnetic antenna
JP2005206254A JP2007028114A (en) 2005-07-14 2005-07-14 Magnetic material antenna
PCT/JP2006/313495 WO2007007639A1 (en) 2005-07-07 2006-07-06 Magnetic antenna

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1944827A3 (en) * 2007-01-10 2008-07-23 Toda Kogyo Corporation Board mounted with a magnetic antenna
CN102651083A (en) * 2011-02-25 2012-08-29 中国钢铁股份有限公司 Radio frequency identification (RFID) label holder
JP2013247436A (en) * 2012-05-24 2013-12-09 Murata Mfg Co Ltd Coil antenna and communication terminal device
EP2811656A4 (en) * 2012-02-01 2015-10-07 Murata Manufacturing Co Antenna device and wireless communication device
US20150323695A1 (en) * 2014-05-12 2015-11-12 Ampass-Explorer Corp. Transmitting and receiving antenna for a search antenna polarization instrument
EP2278661A4 (en) * 2008-04-25 2017-08-30 Toda Kogyo Corporation Magnetic antenna, substrate with the magnetic antenna mounted thereon, and rf tag

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101187172B1 (en) * 2007-03-07 2012-09-28 도다 고교 가부시끼가이샤 Ferrite Molded Sheet, Sintered Ferrite Substrate and Antenna Module
CN101034766B (en) * 2007-04-10 2012-12-12 嘉兴佳利电子股份有限公司 Multi-layer porcelain antenna
JP5639330B2 (en) * 2008-04-18 2014-12-10 株式会社スマート Multi-pole magnetic field sensor for metal surface, sensor system, and method for manufacturing multi-pole magnetic field sensor for metal surface
WO2010113751A1 (en) 2009-03-31 2010-10-07 戸田工業株式会社 Composite rf tag and tool provided with the composite rf tag
JP5320278B2 (en) * 2009-12-22 2013-10-23 川崎重工業株式会社 Aircraft radome
JP5305113B2 (en) 2010-05-11 2013-10-02 サムソン エレクトロ−メカニックス カンパニーリミテッド. Electronic device case in which antenna pattern for low frequency is embedded, manufacturing mold and manufacturing method thereof
CN102299408A (en) * 2010-06-22 2011-12-28 佳邦科技股份有限公司 Soft board antenna structure
JP5967028B2 (en) * 2012-08-09 2016-08-10 株式会社村田製作所 ANTENNA DEVICE, WIRELESS COMMUNICATION DEVICE, AND ANTENNA DEVICE MANUFACTURING METHOD
CN103699917B (en) * 2013-12-27 2017-07-04 威海北洋电气集团股份有限公司 RFID is without coupling compact shelving
CN103682641A (en) * 2013-12-30 2014-03-26 深圳市麦捷微电子科技股份有限公司 Small-sized ferrite chip antenna
CN103825099A (en) * 2014-02-28 2014-05-28 电子科技大学 Short-distance wireless communication tag antenna
CN105633583A (en) * 2014-10-28 2016-06-01 林小群 Near-field communication module and manufacture method thereof
WO2016163437A1 (en) * 2015-04-08 2016-10-13 株式会社村田製作所 Antenna device, card-type information medium, electronic apparatus, and antenna device production method
JP6249135B2 (en) * 2015-04-09 2017-12-20 株式会社村田製作所 Inductor element
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CN105281013B (en) * 2015-11-13 2018-06-01 联想(北京)有限公司 A kind of antenna and electronic equipment
KR20180047889A (en) * 2016-11-01 2018-05-10 삼성전기주식회사 Antenna device
KR102001432B1 (en) * 2016-11-25 2019-08-06 주식회사 아모센스 Antenna core for Non-contact electronic payment and Non-contact electronic payment module comprising the same
KR101973122B1 (en) * 2017-10-27 2019-08-16 이용하 Wireless communication antenna and manufacturing method thereof
CN108608554B (en) * 2018-05-11 2021-04-20 广东风华高新科技股份有限公司 Preparation method of ceramic antenna
CN111313150A (en) * 2018-12-11 2020-06-19 航天信息股份有限公司 RFID antenna
KR102309322B1 (en) 2020-10-13 2021-10-06 이성복 Crushing apparatus of magnetic thin-crystal by ultrasonic waves

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1202383A2 (en) * 2000-10-31 2002-05-02 Mitsubishi Materials Corporation Antenna, receiving/transmitting apparatus therewith and method of manufacturing the antenna
JP2002183689A (en) * 2000-12-11 2002-06-28 Dainippon Printing Co Ltd Noncontact data carrier device and method of manufacture
JP2004200829A (en) * 2002-12-17 2004-07-15 Furukawa Electric Co Ltd:The Rf id tag

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3147756B2 (en) * 1995-12-08 2001-03-19 株式会社村田製作所 Chip antenna
JPH11205025A (en) 1998-01-14 1999-07-30 Murata Mfg Co Ltd Chip antenna
US6940468B2 (en) * 2001-02-15 2005-09-06 Integral Technologies, Inc. Transformers or inductors (“transductors”) and antennas manufactured from conductive loaded resin-based materials
JPWO2002089157A1 (en) * 2001-04-27 2004-08-19 味の素株式会社 Multilayer coil and method of manufacturing the same
JP2003046321A (en) 2001-08-01 2003-02-14 Mitsubishi Materials Corp Magnetic core member and rfid use tag using the same
JP2003059722A (en) * 2001-08-10 2003-02-28 Murata Mfg Co Ltd Laminated inductor and its manufacturing method
JP2003152416A (en) * 2001-08-30 2003-05-23 Kyocera Corp Chip antenna manufacturing method
JP3982268B2 (en) 2002-01-17 2007-09-26 ソニー株式会社 Antenna circuit device and manufacturing method thereof
JP2005184094A (en) * 2003-12-16 2005-07-07 Olympus Corp Antenna and manufacturing method of antenna
JP4214913B2 (en) * 2003-12-26 2009-01-28 戸田工業株式会社 Magnetic field antenna, wireless system and communication system using the same
JP4218519B2 (en) * 2003-12-26 2009-02-04 戸田工業株式会社 Magnetic field antenna, wireless system and communication system using the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1202383A2 (en) * 2000-10-31 2002-05-02 Mitsubishi Materials Corporation Antenna, receiving/transmitting apparatus therewith and method of manufacturing the antenna
JP2002183689A (en) * 2000-12-11 2002-06-28 Dainippon Printing Co Ltd Noncontact data carrier device and method of manufacture
JP2004200829A (en) * 2002-12-17 2004-07-15 Furukawa Electric Co Ltd:The Rf id tag

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2007007639A1 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1944827A3 (en) * 2007-01-10 2008-07-23 Toda Kogyo Corporation Board mounted with a magnetic antenna
EP2278661A4 (en) * 2008-04-25 2017-08-30 Toda Kogyo Corporation Magnetic antenna, substrate with the magnetic antenna mounted thereon, and rf tag
CN102651083A (en) * 2011-02-25 2012-08-29 中国钢铁股份有限公司 Radio frequency identification (RFID) label holder
CN102651083B (en) * 2011-02-25 2015-11-25 中国钢铁股份有限公司 Radio RF identification label holder
EP2811656A4 (en) * 2012-02-01 2015-10-07 Murata Manufacturing Co Antenna device and wireless communication device
JP2013247436A (en) * 2012-05-24 2013-12-09 Murata Mfg Co Ltd Coil antenna and communication terminal device
US20150323695A1 (en) * 2014-05-12 2015-11-12 Ampass-Explorer Corp. Transmitting and receiving antenna for a search antenna polarization instrument

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KR20080023694A (en) 2008-03-14
CN103094667A (en) 2013-05-08
EP1901394A4 (en) 2012-09-26
KR101274354B1 (en) 2013-06-13
WO2007007639A1 (en) 2007-01-18
CN103094667B (en) 2016-06-15

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