EP1765080A2 - Soy seed dressing - Google Patents

Soy seed dressing

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Publication number
EP1765080A2
EP1765080A2 EP05756392A EP05756392A EP1765080A2 EP 1765080 A2 EP1765080 A2 EP 1765080A2 EP 05756392 A EP05756392 A EP 05756392A EP 05756392 A EP05756392 A EP 05756392A EP 1765080 A2 EP1765080 A2 EP 1765080A2
Authority
EP
European Patent Office
Prior art keywords
dmi
prothioconazole
seed
group
fungicides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05756392A
Other languages
German (de)
French (fr)
Inventor
Konrad Kemper
Isolde HÄUSER-HAHN
Paul Reinecke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer CropScience AG
Original Assignee
Bayer CropScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34925399&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1765080(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Bayer CropScience AG filed Critical Bayer CropScience AG
Priority to EP08157864A priority Critical patent/EP1969936A3/en
Priority to EP05756392A priority patent/EP1765080A2/en
Priority to EP08157865A priority patent/EP1969937A3/en
Priority to EP10177897A priority patent/EP2266403A3/en
Priority to EP08157863A priority patent/EP1985179A2/en
Publication of EP1765080A2 publication Critical patent/EP1765080A2/en
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur

Definitions

  • the invention relates to the use of fungicides which act as sterol biosynthesis inhibitors, as seed dressings, a process for controlling phytopathogenic fungi by treating seeds with these fungicides, and seeds which have been treated with such fungicides.
  • Inhibitors of sterol biosynthesis in fungi which block the demethylation at position 14 in ergosteroid biosynthesis have become of great practical importance as fungicides (see, for example, CDS Tomlin (ed.), The Pesticide Manual, 13th edition, The British Crop Protection Council, Farnham 2003).
  • Some of these fungicides are already known as seed dressings, including from soybeans (see e.g. WO-A 03/09 90 10, Fitopatologia Brasileira (1998) 23 (2) 127-131). The effects of such a seed treatment against soybean rust have also been described in isolated cases (Fitopatologia Brasileira (1984) 9 (1), 13 and 119).
  • fungicides from the DMI group as dressing agents for soybean seed have a particularly good action against soybean rust (Phakopsora, in particular Phakopsora pachyrhizi and Phakopsora meibomiae).
  • the invention therefore relates to the use of one or more DMI fungicides from the group:
  • Triazoles al Azaconazole, a.2. Bitertanol, a.3. Bromuconazole, a.4. Cyproconazole, a.5. Difenoconazole, a.6. Diniconazole, a.7. Epoxiconazole, a.8. Fenbuconazole, a.9. Fluquinconazole, a.10. Flusilazole, al l. Flutriafol, a.12. Hexaconazole, a.13. Imibenconazole, a.14. Ipconazole, a.15. Metconazole, a.16. Myclobutanil, a.17.
  • Paclobutrazole a.18. Penconazole, a.19. Propiconazole, a.20. Prothioconazole, a.21. Simeconazole, a.22. Tebuconazole, a.23. Tetraconazole, a.24. Triadimenol, a.25. triticonazole;
  • Imidazoles d.i. Imazalil, d.2. Oxpoconazole fumarate, d.3. Peforazoate, d.4. Prochloraz, d.5. Triflumizole,
  • the invention further relates to a method for protecting soybean plants against soybean rust, wherein the seed of the plants is treated with one or more DMI fungicides from group ad.
  • DMI fungicides Some of the DMI fungicides mentioned have not yet been used for dressing soybean seeds.
  • the invention therefore also relates to the use of one or more DMI fungicides from the groups ad for the seed dressing of soybeans, a process for protecting soy plants against phytopathogenic fungi, the seeds of the plants being treated with one or more DMI fungicides from the groups ad , and soybean seed, treated and / or coated with one or more DMI fungicides from the groups ad.
  • the invention also relates in particular to the use of one or more DMI fungicides from the group:
  • Triazoles a.20. prothioconazole
  • the invention furthermore relates in particular to a method for protecting soybean plants against phytopathogenic fungi, wherein the plants are seeded with one or more DMI fungicides from the group
  • Triazoles a.20. prothioconazole
  • the invention also relates to soybean seed, treated and / or coated with one or more DMI funigicides from the group
  • Triazoles a.20. prothioconazole
  • c) pyridines cl. Pyrifenox.
  • the stain according to the invention is particularly effective against soybean rust, although this particularly aggressive plant disease is not due to the soil but to the wind.
  • the stain according to the invention also enables an economically and ecologically advantageous control of fungal diseases in soybeans and also leads to an improvement in plant health and vitality.
  • Group A-e DMI fungicides are known and commercially available. Details of the individual substances and their relation can be found in "The Pesticide Manual", 13th edition.
  • the DMI fungicides from group a and prochloraz from group e are preferred.
  • Fluquinconazole, flutriafol, ipconazole, prothioconazole, tebuconazole, triticonazole, metconazole, cyproconazole, bitertanol, triadimefon and triadimenol are particularly preferred.
  • Fluquinconazole, flutriafol, ipconazole, prothioconazole and triticonazole are particularly preferred.
  • the mixtures of the compounds fluquinconazole and prothioconazole are particularly preferred.
  • the weight ratio of the respective DMI fungicides is generally 1: 0.01-100, preferably 1: 0.2-20, particularly preferably 1: 0.1-10.
  • the DMI fungicides used according to the invention can be used as such or in their formulations also in a mixture with other known fungicides, bactericides, acaricides, nematicides or insecticides, in order, for example, to broaden the spectrum of activity or to prevent the development of resistance. In many cases, synergistic effects are obtained, i.e. the effectiveness of the mixture is greater than the effectiveness of the individual components.
  • chlozolinate cis-l- (4-chlorophenyl) -2- (lH-l, 2,4-triazol-l-yl) cycloheptanol; Clozylacon; cyazofamid; cyflufenamid; cymoxanil; cyprodinil; cyprofuram; Dagger G; debacarb;
  • dichlofluanid dichlone; dichlorophen; diclocymet; Diclomezine; dicloran; diethofencarb;
  • etridiazole famoxadone; fenamidone; Fenapanil; fenfuram; fenhexamid; Fenitropan; fenoxanil; fenpiclonil; fenpropidin; fenpropimorph; ferbam; fluazinam; Flubenzimine; fludioxonil;
  • flumetover flumorph; fluoromides; fluoxastrobin; flurprimidol; flusulfamide; flutolanil; folpet;
  • Fosetyl-Al Fosetyl-sodium; fuberidazole; furalaxyl; furametpyr; Furcarbanil; Furmecyclox;
  • guazatine Hexachlorobenzene; hymexazol; Iminoctadine triacetate; Iminoctadine tris (albesilate);
  • metalaxyl Metalaxyl-M; methasulfocarb; Methfuroxam; Methyl l- (2,3-dihydro-2,2-dimethyl-lH-inden-1-yl) -1 H-imidazole-5-carboxylates; Methyl 1--2 [[[cyclopropyl [(4-methoxyphenyl) imino] methyl] thio] methyl] -.
  • proquinazid pyraclostrobin; Pyrazohos; pyrimethanil; pyroquilon; Pyroxyfur; Pyrrolnitrine;
  • Copper salts and preparations such as Bordeaux mixture; Copper hydroxide; Copper naphthenate; Copper oxychloride; Copper sulfate; Cufraneb; copper; mancopper; Oxine-copper:
  • Carbamates for example Alanycarb, Aldicarb, Aldoxycarb, Allyxycarb, Aminocarb, Bendiocarb, Benfuracarb, Bufencarb, Butacarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Cloethocarb, Dimetilan, Ethiofenocoth, Fenobocarbi, Fenobucarb, Furobucarb, Form , Metam-sodium, Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Promecarb, Propoxur, Thiodicarb, Thiofanox, Trimethacarb, XMC, Xylylcarb, Triazamate
  • organophosphates for example acephate, azamethiphos, azinphos (-methyl, -ethyl), bromophos-ethyl, bromfenvinfos (-methyl), butathiofos, cadusafos, carbophenothion, chlorethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos (-methyl / -ethyl) , Cyanofenphos, Cyanophos, Chlorfenvinphos, Demeton-S-methyl, Demeton-S-methylsulphon, Dialifos, Diazinon, Dichlofenthion, Dichlorvos / DDVP, Dicrotophos, Dimethoate, Dimethylvinphos, Dioxabenzofos, Disulfoton, EPN, Ethion Fimophos, Fenion Ephamophos, Ethion Fimoprophos , Fenitrothion,
  • pyrethroids for example acrinathrin, allethrin (d-cis-trans, d-trans), beta-cyfluthrin, bifenthrin, bioallethrin, bioallethrin-S-cyclopentyl-isomer, bioethanomethrin, biopinethrin, bioresmethrin, chlovaporthrin, cis-chlorothrinethrin Resmethrin, Cis-Permethrin, Clocythrin, Cycloprothrin, Cyfluthrin, Cyhalothrin, Cypermethrin (alpha, beta, theta, zeta), Cyphenothrin, Deltamethrin, Empenthrin (lR-isomer), Esfenvalerate, Etofenin, Fenphrine, Fenflhrin, Fenflhrin, Fenflhrin, Fenfl
  • Chloronicotinyls for example acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, nitiazines, thiacloprid, thiamethoxam
  • Acetylcholine receptor modulators are Acetylcholine receptor modulators
  • GABA-controlled chloride channel antagonists 5.1 organochlorines, for example camphechlor, chlordane, endosulfan, gamma-HCH, HCH, heptachlor, lindane, methoxychlor
  • Fiprole for example acetoprole, ethiprole, fipronil, pyrafluprole, pyriprole, vaniliprole
  • Mectins for example avermectin, emamectin, emamectin-benzoate, ivermectin, milbemycin
  • Juvenile hormone mimetics for example diofenolan, epofenonane, fenoxycarb, hydroprene, kinoprene, methoprene, pyriproxifene, triprene
  • Diacy lhy drazine for example chromafenozide, halofenozide, methoxyfenozide, tebufenozide
  • Benzoylureas for example bistrifluron, chlofluazuron, diflubenzuron, fluazuron, flucycloxuron, fluefenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, penfluron, teflubenzuron, triflumuron
  • organotin compounds for example azocyclotin, cyhexatin, fenbutatin oxide
  • METI's for example fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, tolfenpyrad
  • Tetronic acids for example spirodiclofen, spiromesifen tetramic acids, for example spirotetramate (CAS Reg.-No .: 203313-25-1) and 3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-l-azaspiro [ 4.5] dec-3-en-4-yl ethyl carbonate (alias: Carbonic acid, 3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-l-azaspiro [4.5] dec-3-en-4 yl ethyl ester, CAS Reg.No .: 382608-10-8) carboxamides, for example flonicamide Octopaminergic agonists, for example Amitraz
  • Nereistoxin analogs for example Thiocyclam hydrogen oxalate, Thiosultap-sodium
  • Biologics, hormones or pheromones Azadirachtin, Bacillus spec, Beauveria spec, Codlemone, Metarrhiziu spec, Paecilomyces spec, Thuringiensin, Verticillium spec.
  • fumigants for example aluminum phosphide, methyl bromide, sulfuryl fluoride
  • a mixture with other known active compounds, such as herbicides, or with fertilizers and growth regulators, safeners or semiochemicals is also possible.
  • the DMI fungicides are converted into the customary mordant formulations, such as solutions, emulsions, suspensions, powders, foams, slurries or other coating compositions for seeds, and also ULV formulations.
  • Dry pickling (preferably with the addition of adhesion promoters, such as paraffin oil or talc and possibly dyes),
  • Slurry pickling (preferably with the addition of wetting agents, dispersing agents, emulsifiers, adhesives, inert fillers and dyes),
  • Aqueous liquid stains preferably with the addition of emulsifiers, dispersants, thickeners, antifreeze agents, polymers, adhesives and dyes
  • solvent-containing liquid stains with the addition of solvents and dyes
  • emulsion stains with the addition of emulsifiers, solvents and dyes.
  • formulations are prepared in a known manner by mixing the active ingredients or combinations of active ingredients with customary additives, such as, for example, conventional extenders and solvents or diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and also Water.
  • customary additives such as, for example, conventional extenders and solvents or diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and also Water.
  • Suitable dyes which can be contained in the mordant formulations which can be used according to the invention are all dyes customary for such purposes. Both pigments that are sparingly soluble in water and dyes that are soluble in water can be used. Examples which may be mentioned are the dyes known under the designations rhodamine B, C.L Pigment Red 112 and C.L Solvent Red 1.
  • the wetting agents which can be contained in the mordant formulations which can be used according to the invention are all those which are customary for the formulation of agrochemical active compounds, wetting promoting substances in question.
  • Alkyl naphthalene sulfonates such as diisopropyl or diisobutyl naphthalene sulfonates, can preferably be used.
  • Suitable dispersants and / or emulsifiers which may be present in the mordant formulations which can be used according to the invention are all nonionic, anionic and cationic dispersants customary for the formulation of agrochemical active ingredients.
  • Nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants can preferably be used.
  • Suitable nonionic dispersants include, in particular, ethylene oxide / propylene oxide block polymers, alkylphenol polyglycol ethers and tristryrylphenol polyglycol ethers and their phosphated or sulfated derivatives.
  • Suitable anionic dispersants are, in particular, lignin sulfonates, polyacrylic acid salts and aryl sulfonate-formaldehyde condensates.
  • the mordant formulations which can be used according to the invention can contain as defoamers all of the foam-inhibiting substances which are customary for the formulation of agrochemical active compounds. Silicone defoamers and magnesium stearate can preferably be used.
  • All substances which can be used for such purposes in agrochemical compositions can be present as preservatives in the mordant formulations which can be used according to the invention.
  • Examples include dichlorophene and benzyl alcohol hemiform.
  • Secondary thickeners which can be contained in the mordant formulations which can be used according to the invention are all substances which can be used in agrochemical compositions for such purposes. Cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and highly disperse silica are preferred.
  • organic solvents which can be used in agrochemical compositions are suitable as solvents which can be combined with the DMI fungicides.
  • Ketones such as methyl isobutytketone and cyclohexanone, furthermore amides, such as dimethylformamide, and further cyclic compounds, such as N-methyl-pyrrolidone, N-octyl-pyrrolidone, N-dodecyl-pyrrolidone, N-octyl-caprolactam, N- Dodecyl-caprolactam and ⁇ -butyrolactone, in addition strongly polar solvents, such as dimethyl sulfoxide, also aromatic hydrocarbons, such as xylene, also esters, such as propylene glycol monomethyl ether acetate, adipic acid dibutyl ester, acetic acid hexyl ester, acetic acid heptyl ester, citric acid tri- n-butyl ester, die
  • Suitable adhesives which can be contained in the mordant formulations which can be used according to the invention are all binders which are customary in mordants.
  • Polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and tylose are preferred.
  • Substances of the formula are preferably used as gibberellins which can be contained in the mordant formulations which can be used according to the invention
  • R represents a hydrogen atom or a hydroxy group
  • the gibberellins of the formula (I) are known (cf. R. Wegler “Chemistry of Plant Protection Products and Pest Control", Volume 2, Springer Verlag, Berlin-Heidelberg-New York, 1970, pages 401-412).
  • the mordant formulations which can be used according to the invention are used either directly or after prior dilution with water for the treatment of soybean seed.
  • the seed dressing formulations which can be used according to the invention or their diluted preparations can also be used for dressing seeds of transgenic soy plants. In cooperation with the substances formed by expression, additional synergistic effects can also occur.
  • the application rate of the mordant formulations which can be used according to the invention can be varied within a relatively wide range. It depends on the respective content of the active ingredients in the formulations and on the seeds.
  • the application rates of DMI fungicides or their combination are generally between 0.001 and 50 g per kilogram of seed, preferably between 0.01 and 15 g per kilogram of seed.
  • the seed dressing according to the invention can be in addition to the control of Phakopsora, in particular Phakopsora pachyrhizi and Phakopsora meibomiae, for example for controlling Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.
  • Xanthomonas species such as, for example, Xanthomonas campestris pv. Oryzae;
  • Pseudomonas species such as, for example, Pseudomonas syringae pv. Lachrymans;
  • Erwinia species such as, for example, Erwinia amylovora;
  • Phytophthora species such as, for example, Phytophthora sojae
  • Pseudoperonospora species such as, for example, Pseudoperonospora humuli or
  • Peronospora species such as, for example, Peronospora brassicae or Peronospora manshurica;
  • Erysiphe species such as, for example, Erysiphe polygoni;
  • Podosphaera species such as, for example, Podosphaera leucotricha
  • Puccinia species such as, for example, Puccinia recondita
  • Sclerotinia species such as, for example, Sclerotinia sclerotiorum
  • Ustilago species such as, for example, Ustilago nuda or Ustilago avenae;
  • Pellicularia species such as, for example, Pellicularia sasakii;
  • Fusarium species such as, for example, Fusarium culmorum
  • Septoria species such as, for example, Septoria nodorum or Septoria glycines
  • Leptosphaeria species such as, for example, Leptosphaeria nodorum;
  • Cercospora species such as, for example, Cercospora kikuchii;
  • Alternaria species such as, for example, Alternaria brassicae.
  • Phomopsis species such as, for example, Phomopsis longicola
  • Colletotrichum species such as, for example, Celletotrichum truncatum;
  • Rhizoctoinia species such as, for example, Rhicoctoinia solani;
  • Microsphera species such as Microsphera manshurica.
  • the mordants used according to the invention are particularly suitable for controlling the soybean rust.
  • the stains according to the invention also have a very good strengthening effect in plants. They are therefore suitable for mobilizing the plant's own defenses against attack by undesired microorganisms.
  • Plant-strengthening (resistance-inducing) substances are to be understood in the present context as substances which are able to stimulate the defense system of plants in such a way that the treated plants develop extensive resistance to these microorganisms when subsequently inoculated with undesired microorganisms.
  • Undesired microorganisms are to be understood in the present case as phytopathogenic fungi and bacteria.
  • the substances according to the invention can thus be used to protect plants against attack by the pests mentioned within a certain period of time after the treatment.
  • the period within which protection is provided generally ranges from 1 to 70 days, preferably 1 to 35 days after sowing.
  • the seed was shaken with the dressing in a sealed plastic bag for 1 minute.
  • the seeds were sown in the field (4 plots, each 10 m 2 , 40 seeds per m 2 ) and irrigated artificially the day after sowing.
  • the natural infestation of the control averaged 75%.
  • the effectiveness is expressed in percent. 0% means an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
  • the seed was shaken with the dressing in a sealed plastic bag for 1 minute.
  • the seeds were sown in the field (4 plots, each 10 m 2 , 40 seeds per m 2 ) and irrigated artificially the day after sowing.
  • the natural infestation of the control averaged 75%.
  • the effectiveness is expressed in percent. 0% means an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
  • the seed was shaken with the dressing in a sealed plastic bag for 1 minute.
  • the seeds were sown in the field (4 plots, parcel size 10m 2 each, 40 seeds per m 2 ) and irrigated artificially the day after sowing.
  • soybean plants whose seeds were treated with a mixture of the fungicide carbendazim and the insecticide imidacloprid (100 g or 120 g per 100 kg of seed) were treated. Controls were 33% and 68% after 19 and 25 days, respectively.
  • the effectiveness is expressed in percent according to the Abbott formula ([(effect control - effect example according to the invention) / effect control] * 100). 0% means an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infection is observed.

Abstract

Disclosed is the use of one or several DMI fungicides from the group comprising: a) triazoles: a.1. azaconazoles, a.2. bitertanol, a.3. bromuconazoles, a.4. cyproconazoles, a.5. difenoconazoles, a.6. diniconazoles, a.7. epoxiconazoles, a.8. fenbuconazoles, a.9. fluquinconazoles, a.10. flusilazoles, a.11. flutriafol, a.12. hexaconazoles, a.13. imibenconazoles, a.14. ipconazoles, a.15. metconazoles, a.16. myclobutanil, a.17. paclobutrazol, a.18. penconazoles, a.19. propiconazoles, a.20. prothioconazoles, a.21. simeconazoles, a.22. tebuconazoles, a.23. tetraconazoles, a.24. triadimenol, a.25. triticonazoles; b) pyrimidines: b.1. fenarimol, b.2. nuarimol; c) pyridines: c.1. pyrifenox; and d) imidazoles: d.1. imazalil, d.2. oxpoconazole fumarate, d.3. pefurazoate, d.4. prochloraz, d.5. triflumizoles, as a soy seed dressing against soybean rust.

Description

Saatgutbehandlungsmittel für SojaSeed treatment agent for soy
Die Erfindung betrifft die Verwendung von Fungiziden, die als Sterolbiosynthese-Hemmstoffe wirken, als Saatbeizmittel, ein Verfahren zum Bekämpfen phytopathogener Pilze durch Behandlung von Saatgut mit diesen Fungiziden, sowie Saatgut, welches mit solchen Fungiziden behandelt wurde.The invention relates to the use of fungicides which act as sterol biosynthesis inhibitors, as seed dressings, a process for controlling phytopathogenic fungi by treating seeds with these fungicides, and seeds which have been treated with such fungicides.
Hemmstoffe der Sterolbiosynthese in Pilzen, welche die Demethylierung an Position 14 innerhalb der Ergosteroidbiosynthese blockieren (Demethylierungsinhibitoren, DMI), haben als Fungizide große praktische Bedeutung erlangt (siehe z.B. C.D.S. Tomlin (Hrg.), The Pesticide Manual, 13. Auflage, The British Crop Protection Council, Farnham 2003).Inhibitors of sterol biosynthesis in fungi which block the demethylation at position 14 in ergosteroid biosynthesis (demethylation inhibitors, DMI) have become of great practical importance as fungicides (see, for example, CDS Tomlin (ed.), The Pesticide Manual, 13th edition, The British Crop Protection Council, Farnham 2003).
Einzelne dieser Fungizide sind bereits als Beizmittel für Saatgut unter anderem auch von Soja bekannt (siehe z.B. WO-A 03/09 90 10, Fitopatologia Brasileira (1998) 23(2) 127-131). Vereinzelt wurde auch die Wirkung einer solchen Saatgutbeize gegen Sojabohnenrost beschrieben (Fitopatologia Brasileira (1984) 9(1), 13 und 119).Some of these fungicides are already known as seed dressings, including from soybeans (see e.g. WO-A 03/09 90 10, Fitopatologia Brasileira (1998) 23 (2) 127-131). The effects of such a seed treatment against soybean rust have also been described in isolated cases (Fitopatologia Brasileira (1984) 9 (1), 13 and 119).
In der US 2003/0060371 wird die Beize von Sojasaatgut mit unter anderen DMI-Fungiziden vorgeschlagen, um Ertrag und Stärke der Pflanzen zu verbessern. Ein Hinweis auf eine Wirkung gegen Sojabohnenrost ist nicht beschrieben.In US 2003/0060371 the dressing of soybean seed with other DMI fungicides is proposed in order to improve the yield and strength of the plants. There is no description of an effect against soybean rust.
Da sich aber die ökologischen und ökonomischen Anforderungen an moderne Fungizide laufend erhöhen, beispielsweise was Wirkspektrum, Toxizität, Selektivität, Aufwandmenge, Rückstandsbildung und günstige Herstellbarkeit angeht, und außerdem z.B. Probleme mit Resistenzen auf- treten können, besteht die ständige Aufgabe, neue Fungizide zu entwickeln, die zumindest in Teilbereichen Vorteile gegenüber den bekannten aufweisen.However, since the ecological and economic requirements for modern fungicides are constantly increasing, for example in terms of activity spectrum, toxicity, selectivity, application rate, residue formation and inexpensive to produce, and also e.g. Problems with resistance can arise, the constant task is to develop new fungicides which have advantages over the known ones, at least in some areas.
Es wurde nun überraschend gefunden, dass Fungizide aus der Gruppe der DMI als Beizmittel für Sojasaatgut eine besonders gute Wirkung gegen Sojabohnenrost (Phakopsora, insbesondere Phakopsora pachyrhizi und Phakopsora meibomiae) zeigen.It has now surprisingly been found that fungicides from the DMI group as dressing agents for soybean seed have a particularly good action against soybean rust (Phakopsora, in particular Phakopsora pachyrhizi and Phakopsora meibomiae).
Gegenstand der Erfindung ist daher die Verwendung eines oder mehrerer DMI-Fungizide aus der Gruppe:The invention therefore relates to the use of one or more DMI fungicides from the group:
a) Triazole: a.l. Azaconazole, a.2. Bitertanol, a.3. Bromuconazole, a.4. Cyproconazole, a.5. Difeno- conazole, a.6. Diniconazole, a.7. Epoxiconazole, a.8. Fenbuconazole, a.9. Fluquinconazole, a.10. Flusilazole, a.l l. Flutriafol, a.12. Hexaconazole, a.13. Imibenconazole, a.14. Ipconazole, a.15. Metconazole, a.16. Myclobutanil, a.17. Paclobutrazol, a.18. Penconazole, a.19. Propiconazole, a.20. Prothioconazole, a.21. Simeconazole, a.22. Tebuconazole, a.23. Tetraconazole, a.24. Triadimenol, a.25. Triticonazole;a) Triazoles: al Azaconazole, a.2. Bitertanol, a.3. Bromuconazole, a.4. Cyproconazole, a.5. Difenoconazole, a.6. Diniconazole, a.7. Epoxiconazole, a.8. Fenbuconazole, a.9. Fluquinconazole, a.10. Flusilazole, al l. Flutriafol, a.12. Hexaconazole, a.13. Imibenconazole, a.14. Ipconazole, a.15. Metconazole, a.16. Myclobutanil, a.17. Paclobutrazole, a.18. Penconazole, a.19. Propiconazole, a.20. Prothioconazole, a.21. Simeconazole, a.22. Tebuconazole, a.23. Tetraconazole, a.24. Triadimenol, a.25. triticonazole;
b) Pyrimidine: b.1. Fenarimol, b.2. Nuarimol;b) Pyrimidines: b.1. Fenarimol, b.2. nuarimol;
c) Pyridine: c.1. Pyrifenox;c) pyridines: c.1. pyrifenox;
undand
d) Imidazole: d.i. Imazalil, d.2. Oxpoconazole Fumarat, d.3. Peforazoate, d.4. Prochloraz, d.5. Triflumi- zole,d) Imidazoles: d.i. Imazalil, d.2. Oxpoconazole fumarate, d.3. Peforazoate, d.4. Prochloraz, d.5. Triflumizole,
als Saatgutbeize für Soja gegen Sojabohnenrost.as seed dressing for soybeans against soybean rust.
Weiterhin Gegenstand der Erfindung ist ein Verfahren zum Schutz von Sojapflanzen gegen Sojabohnenrost, wobei man Saatgut der Pflanzen mit einem oder mehreren DMI-Fungiziden aus der Gruppe a - d behandelt.The invention further relates to a method for protecting soybean plants against soybean rust, wherein the seed of the plants is treated with one or more DMI fungicides from group ad.
Die genannten DMI-Fungizide sind teilweise noch nicht zur Beize von Sojasaatgut verwendet worden.Some of the DMI fungicides mentioned have not yet been used for dressing soybean seeds.
Gegenstand der Erfindung ist daher auch die Verwendung eines oder mehrer DMI-Fungizide aus den Gruppen a-d zur Sattgutbeize von Soja, ein Verfahren zum Schutz von Sojapflanzen gegen phytopathogene Pilze, wobei man Saatgut der Pflanzen mit einem oder mehreren DMI-Fungiziden aus den Gruppen a-d behandelt, sowie Sojasaatgut, behandelt und/oder beschichtet mit einem oder mehreren DMI-Fungiziden aus den Gruppen a-d.The invention therefore also relates to the use of one or more DMI fungicides from the groups ad for the seed dressing of soybeans, a process for protecting soy plants against phytopathogenic fungi, the seeds of the plants being treated with one or more DMI fungicides from the groups ad , and soybean seed, treated and / or coated with one or more DMI fungicides from the groups ad.
Gegenstand der Erfindung ist insbesondere auch die Verwendung eines oder mehrerer DMI- Fungizide aus der Gruppe:The invention also relates in particular to the use of one or more DMI fungicides from the group:
a) Triazole: a.20. Prothioconazole;a) Triazoles: a.20. prothioconazole;
b) Pyrimidine: b.l. Fenarimol, b.2.Nuarimol; undb) pyrimidines: bl fenarimol, b.2.nuarimol; and
c) Pyridine: c.l . Pyrifenox,c) pyridines: c.l. pyrifenox,
zur Saatgutbeizung von Soja.for seed dressing of soy.
Weiterhin Gegenstand der Erfindung ist insbesondere ein Verfahren zum Schutz von Sojapflanzen gegen phytopathogene Pilze, wobei man Saatgut der Pflanzen mit einem oder mehreren DMI- Fungiziden aus der GruppeThe invention furthermore relates in particular to a method for protecting soybean plants against phytopathogenic fungi, wherein the plants are seeded with one or more DMI fungicides from the group
a) Triazole: a.20. Prothioconazole;a) Triazoles: a.20. prothioconazole;
b) Pyrimidine: b.l. Fenarimol, b.2. Nuarimol;b) Pyrimidines: b.l. Fenarimol, b.2. nuarimol;
undand
c) Pyridine: c.l. Pyrifenox,c) pyridines: c.l. pyrifenox,
behandelt.treated.
Ebenso Gegenstand der Erfindung ist Sojasaatgut, behandelt und/oder beschichtet mit einem oder mehreren DMI-Funigiziden aus der GruppeThe invention also relates to soybean seed, treated and / or coated with one or more DMI funigicides from the group
a) Triazole: a.20. Prothioconazole;a) Triazoles: a.20. prothioconazole;
b) Pyrimidine: b.l . Fenarimol, b.2. Nuarimol;b) Pyrimidines: b.l. Fenarimol, b.2. nuarimol;
undand
c) Pyridine: c.l . Pyrifenox. Überraschenderweise ist die erfindungsgemäße Beize gegen Sojabohnenrost besonders wirksam, obwohl diese besonders agressive Pflanzenkrankheit nicht boden- sondern windbürtig ist.c) pyridines: cl. Pyrifenox. Surprisingly, the stain according to the invention is particularly effective against soybean rust, although this particularly aggressive plant disease is not due to the soil but to the wind.
Die erfindungsgemäße Beize ermöglicht zudem eine ökonomisch und ökologisch vorteilhafte Bekämpfung von Pilzkrankheiten in Soja und führt auch zu einer Verbesserung der Pflanzengesundheit und -Vitalität.The stain according to the invention also enables an economically and ecologically advantageous control of fungal diseases in soybeans and also leads to an improvement in plant health and vitality.
Die DMI-Fungizide der Gruppe a - e sind bekannt und kommerziell erhältlich. Einzelheiten zu den einzelnen Stoffen und deren Bezug finden sich in „The Pesticide Manual", 13. Auflage.Group A-e DMI fungicides are known and commercially available. Details of the individual substances and their relation can be found in "The Pesticide Manual", 13th edition.
Bevorzugt sind die DMI-Fungizide der Gruppe a sowie Prochloraz aus der Gruppe e.The DMI fungicides from group a and prochloraz from group e are preferred.
Besonders bevorzugt sind Fluquinconazole, Flutriafol, Ipconazole, Prothioconazole, Tebuconazole, Triticonazole, Metconazole, Cyproconazole, Bitertanol, Triadimefon und Triadimenol.Fluquinconazole, flutriafol, ipconazole, prothioconazole, tebuconazole, triticonazole, metconazole, cyproconazole, bitertanol, triadimefon and triadimenol are particularly preferred.
Insbesondere bevorzugt sind Fluquinconazole, Flutriafol, Ipconazole, Prothioconazole und Triticonazole.Fluquinconazole, flutriafol, ipconazole, prothioconazole and triticonazole are particularly preferred.
Weiterhin bevorzugt ist es, Mischungen von zwei oder mehreren, insbesondere einer der genannten DMI-Fungizide zu verwenden.It is further preferred to use mixtures of two or more, in particular one, of the DMI fungicides mentioned.
Besonders bevorzugt sind die Mischungen der Verbindungen Fluquinconazole und Prothioconazole.The mixtures of the compounds fluquinconazole and prothioconazole are particularly preferred.
In den genannten Mischungen von zwei Wirkstoffen beträgt das Gewichtsverhältnis der jeweiligen DMI-Fungizide im Allgemeinen 1:0,01-100, vorzugsweise 1:0,2-20, besonders bevorzugt 1 :0,1-10.In the mixtures of two active compounds mentioned, the weight ratio of the respective DMI fungicides is generally 1: 0.01-100, preferably 1: 0.2-20, particularly preferably 1: 0.1-10.
Die erfindungsgemäß verwendeten DMI-Fungizide können als solche oder in ihren Formulie- rungen auch in Mischung mit weiteren bekannten Fungiziden, Bakteriziden, Akariziden, Nematizi- den oder Insektiziden verwendet werden, um so z.B. das Wirkungsspektrum zu verbreitern oder Resistenzentwicklungen vorzubeugen. In vielen Fällen erhält man dabei synergistische Effekte, d.h. die Wirksamkeit der Mischung ist größer als die Wirksamkeit der Einzelkomponenten.The DMI fungicides used according to the invention can be used as such or in their formulations also in a mixture with other known fungicides, bactericides, acaricides, nematicides or insecticides, in order, for example, to broaden the spectrum of activity or to prevent the development of resistance. In many cases, synergistic effects are obtained, i.e. the effectiveness of the mixture is greater than the effectiveness of the individual components.
Als Mischpartner kommen zum Beispiel folgende Verbindungen infrage:The following connections can be considered as mixed partners:
Fungizide:fungicides:
2-Phenylphenol; 8-Hydroxyquinoline sulfate; Acibenzolar-S-methyl; Actinovate; Aldimorph; Amidoflumet; Ampropylfos; Ampropylfos-potassium; Andoprim; Anilazine; Azoxystrobin; Benalaxyl; Benodanil; Benomyl; Benthiavalicarb-isopropyl; Benzamacril; Benzamacril-isobutyl; Bilanafos; Binapacryl; Biphenyl; Blasticidin-S; Boscalid; Bupirimate; Buthiobate; Butylamine;2-phenylphenol; 8-hydroxyquinoline sulfates; Acibenzolar-S-methyl; Actinovate; aldimorph; amidoflumet; Ampropylfos; Ampropylfos-potassium; andoprim; anilazine; azoxystrobin; benalaxyl; Benodanil; benomyl; Benthiavalicarb-isopropyl; Benzamacril; Benzamacril-isobutyl; bilanafos; binapacryl; biphenyl; Blasticidin-S; boscalid; Bupirimate; Buthiobate; butylamine;
Calcium polysulfide; Capsimycin; Captafol; Captan; Carbendazim; Carboxin; Carpropamid;Calcium polysulfide; capsimycin; captafol; captan; carbendazim; carboxin; carpropamid;
Carvone; Chinomethionat; Chlobenthiazone; Chlorfenazole; Chloroneb; Chlorothalonil;carvones; chinomethionat; Chlobenthiazone; Chlorfenazole; chloroneb; chlorothalonil;
Chlozolinate; cis-l-(4-chlorophenyl)-2-(lH-l,2,4-triazol-l-yl)-cycloheptanol; Clozylacon; Cyazofamid; Cyflufenamid; Cymoxanil; Cyprodinil; Cyprofuram; Dagger G; Debacarb;chlozolinate; cis-l- (4-chlorophenyl) -2- (lH-l, 2,4-triazol-l-yl) cycloheptanol; Clozylacon; cyazofamid; cyflufenamid; cymoxanil; cyprodinil; cyprofuram; Dagger G; debacarb;
Dichlofluanid; Dichlone; Dichlorophen; Diclocymet; Diclomezine; Dicloran; Diethofencarb;dichlofluanid; dichlone; dichlorophen; diclocymet; Diclomezine; dicloran; diethofencarb;
Diflumetorim; Dimethirimol; Dimethomorph; Dimoxystrobin; Dinocap; Diphenylamine; Dipyri- thione; Ditalimfos; Dithianon; Dodine; Drazoxolon; Edifenphos; Ethaboxam; Ethirimol;diflumetorim; dimethirimol; dimethomorph; dimoxystrobin; dinocap; diphenylamines; Dipyrithione; Ditalimfos; dithianon; dodine; Drazoxolon; edifenphos; ethaboxam; ethirimol;
Etridiazole; Famoxadone; Fenamidone; Fenapanil; Fenfuram; Fenhexamid; Fenitropan; Fenoxanil; Fenpiclonil; Fenpropidin; Fenpropimorph; Ferbam; Fluazinam; Flubenzimine; Fludioxonil;etridiazole; famoxadone; fenamidone; Fenapanil; fenfuram; fenhexamid; Fenitropan; fenoxanil; fenpiclonil; fenpropidin; fenpropimorph; ferbam; fluazinam; Flubenzimine; fludioxonil;
Flumetover; Flumorph; Fluoromide; Fluoxastrobin; Flurprimidol; Flusulfamide; Flutolanil; Folpet;flumetover; flumorph; fluoromides; fluoxastrobin; flurprimidol; flusulfamide; flutolanil; folpet;
Fosetyl-Al; Fosetyl-sodium; Fuberidazole; Furalaxyl; Furametpyr; Furcarbanil; Furmecyclox;Fosetyl-Al; Fosetyl-sodium; fuberidazole; furalaxyl; furametpyr; Furcarbanil; Furmecyclox;
Guazatine; Hexachlorobenzene; Hymexazol; Iminoctadine triacetate; Iminoctadine tris(albesilate);guazatine; Hexachlorobenzene; hymexazol; Iminoctadine triacetate; Iminoctadine tris (albesilate);
Iodocarb; Iprobenfos; Iprodione; Iprovalicarb; Irumamycin; Isoprothiolane; Isovaledione; Kasugamycin; Kresoxim-methyl; Mancozeb; Maneb; Meferimzone; Mepanipyrim; Mepronil;iodocarb; iprobenfos; iprodione; iprovalicarb; Irumamycin; isoprothiolane; Isovaledione; kasugamycin; Kresoxim-methyl; mancozeb; maneb; Meferimzone; mepanipyrim; mepronil;
Metalaxyl; Metalaxyl-M; Methasulfocarb; Methfuroxam; Methyl-l-(2,3-dihydro-2,2-dimethyl-lH- inden- 1 -yl)- 1 H-imidazole-5 -carboxylate; Methy l-2-[ [ [cyclopropyl [(4-methoxypheny l)imino] - methyl]thio]methyl]-.alpha.-(methoxymethylene)-benzeneacetate; Methy l-2-[2-[3-(4-chloro-phe- nyl)-l-methyl-allylideneaminooxymethyl]-phenyl]-3-methoxy-acrylate; Metiram; Metominostro- bin; Metrafenone; Metsulfovax; Mildiomycin; monopotassium carbonate; Myclozolin; N-(3-Ethyl-metalaxyl; Metalaxyl-M; methasulfocarb; Methfuroxam; Methyl l- (2,3-dihydro-2,2-dimethyl-lH-inden-1-yl) -1 H-imidazole-5-carboxylates; Methyl 1--2 [[[cyclopropyl [(4-methoxyphenyl) imino] methyl] thio] methyl] -. Alpha .- (methoxymethylene) benzene acetates; Methyl 1--2 [2- [3- (4-chlorophenyl) -1-methyl-allylideneaminooxymethyl] phenyl] -3-methoxy-acrylates; metiram; Metominostrobin; metrafenone; Metsulfovax; mildiomycin; monopotassium carbonate; myclozoline; N- (3-ethyl
3,5,5-trimethyl-cyclohexyl)-3-formylamino-2-hydroxy-benzamide; N-(6-methoxy-3-pyridinyl)-cyc- lopropanecarboxamide; N-bufyl-8-(l,l-dimethylethyl)-l-oxaspiro[4.5]decan-3-amine; Natamycin;3,5,5-trimethyl-cyclohexyl) -3-formylamino-2-hydroxy-benzamide; N- (6-methoxy-3-pyridinyl) cyclopropanecarboxamide; N-bufyl-8- (l, l-dimethylethyl) -l-oxa-spiro [4.5] decan-3-amine; natamycin;
Nitrothal-isopropyl; Noviflumuron; Ofurace; Orysastrobin; Oxadixyl; Oxolinic acid; Oxycarboxin;Nitro Thal-isopropyl; Noviflumuron; ofurace; orysastrobin; oxadixyl; Oxolinic acid; oxycarboxin;
Oxyfenthiin; Pencycuron; Penthiopyrad; Phosdiphen; Phthalide; Picobenzamid; Picoxystrobin; Piperalin; Polyoxins; Polyoxorim; Procymidone; Propamocarb; Propanosine-sodium; Propineb;Oxyfenthiin; pencycuron; penthiopyrad; phosdiphen; phthalides; Picobenzamid; picoxystrobin; piperalin; Polyoxins; Polyoxorim; procymidone; propamocarb; Propanosine-sodium; propineb;
Proquinazid; Pyraclostrobin; Pyrazophos; Pyrimethanil; Pyroquilon; Pyroxyfur; Pyrrolnitrine;proquinazid; pyraclostrobin; Pyrazohos; pyrimethanil; pyroquilon; Pyroxyfur; Pyrrolnitrine;
Quinconazole; Quinoxyfen; Quintozene; Silthiofam; Sodium tetrathiocarbonate; Spiroxamine;Quinconazole; quinoxyfen; quintozene; silthiofam; Sodium tetrathiocarbonate; spiroxamine;
Sulfur; Tecloftalam; Tecnazene; Tetcyclacis; Thicyofen; Thifluzamide; Thiophanate-methyl;Sulfur; tecloftalam; Tecnazene; Tetcyclacis; Thicyofen; Thifluzamide; Thiophanate-methyl;
Thiram; Tiadinil; Tioxymid; Tolclofos-methyl; Tolylfluanid; Triazbutil; Triazoxide; Tricyclamide; Tricyclazole; Tridemorph; Trifloxystrobin; Validamycin A; Vinclozolin; Zineb; Ziram; Zoxamide;thiram; tiadinil; Tioxymid; Tolclofos-methyl; tolylfluanid; Triazbutil; triazoxide; Tricyclamide; Tricyclazole; tridemorph; trifloxystrobin; Validamycin A; vinclozolin; Zineb; ziram; zoxamide;
(2S)-N-[2-[4-[[3-(4-chlorophenyl)-2-propynyl]oxy]-3-methoxyphenyl]ethyl]-3-methyl- 2-[(methyl- sulfonyl)amino]-butanamide; l-(l-naphthalenyl)-lH-pyrrole-2,5-dione; 2,3,5, 6-tetrachloro-4-(2S) -N- [2- [4 - [[3- (4-chlorophenyl) -2-propynyl] oxy] -3-methoxyphenyl] ethyl] -3-methyl- 2 - [(methylsulfonyl) amino] -butanamide; l- (l-naphthalenyl) -lH-pyrrole-2,5-dione; 2,3,5,6-tetrachloro-4-
(methylsulfonyl)-pyridine; 2,4-Dihydro-5-methoxy-2-methyl-4-[[[[l-[3-(trifluoromethyl)-phenyl]- ethylidene]-amino]-oxy]-methyl]-phenyl]-3H-l,2,3-triazol-3-one; 2-amino-4-methyl-N-phenyl-5- thiazolecarboxamide; 2-chloro-N-(2,3-dihydro- 1 , 1 ,3-trimethy 1- 1 H-inden-4-yl)-3 -pyridincarbox- amide; 3,4,5-trichloro-2,6-pyridinedicarbonitrile; 3-[(3-Bromo-6-fluoro-2-methyl-lH-indol-l-yl)- sulfony 1] -N,N-dimethy 1- 1 H- 1 ,2,4-triazole- 1 -sulfonamide;(Methylsulfonyl) -pyridine; 2,4-Dihydro-5-methoxy-2-methyl-4 - [[[[l- [3- (trifluoromethyl) phenyl] ethylidene] amino] oxy] methyl] phenyl] -3H-l , 2,3-triazol-3-one; 2-amino-4-methyl-N-phenyl-5-thiazolecarboxamide; 2-chloro-N- (2,3-dihydro-1, 1, 3-trimethyl 1- 1 H-inden-4-yl) -3-pyridinecarbox- amides; 3,4,5-trichloro-2,6-pyridinedicarbonitrile; 3 - [(3-Bromo-6-fluoro-2-methyl-1H-indol-1-yl) -sulfony 1] -N, N-dimethyl 1- 1 H-1, 2,4-triazole-1 -sulfonamides ;
sowie Kupfersalze und -Zubereitungen, wie Bordeaux mixture; Kupfer Hydroxid; Kupfer naphthe- nat; Kupfer Oxychlorid; Kupfer Sulfat; Cufraneb; Kupferoxid; Mancopper; Oxine-copper:as well as copper salts and preparations, such as Bordeaux mixture; Copper hydroxide; Copper naphthenate; Copper oxychloride; Copper sulfate; Cufraneb; copper; mancopper; Oxine-copper:
Bakterizide:bactericides:
Bronopol, Dichlorophen, Nitrapyrin, Nickel-dimethyldithiocarbamat, Kasugamycin, Octhilinon, Furancarbonsäure, Oxytetracyclin, Probenazol, Streptomycin, Tecloftalam, Kupfersulfat und andere Kupfer-Zubereitungen.Bronopol, dichlorophene, nitrapyrin, nickel dimethyldithiocarbamate, kasugamycin, octhilinone, furan carboxylic acid, oxytetracycline, probenazole, streptomycin, tecloftalam, copper sulfate and other copper preparations.
Insektizide / Akarizide / Nematizide:Insecticides / acaricides / nematicides:
Acetylcholinesterase (AChE) InhibitorenAcetylcholinesterase (AChE) inhibitors
1.1 Carbamate, zum Beispiel Alanycarb, Aldicarb, Aldoxycarb, Allyxycarb, Aminocarb, Bendiocarb, Ben- furacarb, Bufencarb, Butacarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Cloethocarb, Dimetilan, Ethiofencarb, Fenobucarb, Fenothiocarb, Formetanate, Furathiocarb, Isoprocarb, Metam-sodium, Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Promecarb, Propoxur, Thiodicarb, Thiofanox, Trimethacarb, XMC, Xylylcarb, Triazamate1.1 Carbamates, for example Alanycarb, Aldicarb, Aldoxycarb, Allyxycarb, Aminocarb, Bendiocarb, Benfuracarb, Bufencarb, Butacarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Cloethocarb, Dimetilan, Ethiofenocoth, Fenobocarbi, Fenobucarb, Furobucarb, Form , Metam-sodium, Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Promecarb, Propoxur, Thiodicarb, Thiofanox, Trimethacarb, XMC, Xylylcarb, Triazamate
1.2 Organophosphate, zum Beispiel Acephate, Azamethiphos, Azinphos (-methyl, -ethyl), Bromophos-ethyl, Bromfenvinfos (-methyl), Butathiofos, Cadusafos, Carbophenothion, Chlorethoxyfos, Chlorfenvinphos, Chlormephos, Chlorpyrifos (-methyl/-ethyl), Coumaphos, Cyanofenphos, Cyanophos, Chlorfenvinphos, Demeton-S-methyl, Demeton-S- methylsulphon, Dialifos, Diazinon, Dichlofenthion, Dichlorvos/DDVP, Dicrotophos, Dimethoate, Dimethylvinphos, Dioxabenzofos, Disulfoton, EPN, Ethion, Ethoprophos, Etrimfos, Famphur, Fenamiphos, Fenitrothion, Fensulfothion, Fenthion, Flupyrazofos, Fonofos, Formothion, Fosmethilan, Fosthiazate, Heptenophos, Iodofenphos, Iprobenfos, Isazofos, Isofenphos, Isopropyl O-salicylate, Isoxathion, Malathion, Mecarbam, Methacrifos, Methamidophos, Methidathion, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion (-methyl/-ethyl), Phenthoate, Phorate, Phosalone, Phosmet, Phosphamidon, Phosphocarb, Phoxim, Pirimiphos (-methyl/-ethyl), Profenofos, Propaphos, Propetamphos, Prothiofos, Prothoate, Pyraclofos, Pyridaphenthion, Pyridathion, Quinalphos, Sebufos, Sulfotep, Sulprofos, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, Triclorfon, Vamidothion1.2 organophosphates, for example acephate, azamethiphos, azinphos (-methyl, -ethyl), bromophos-ethyl, bromfenvinfos (-methyl), butathiofos, cadusafos, carbophenothion, chlorethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos (-methyl / -ethyl) , Cyanofenphos, Cyanophos, Chlorfenvinphos, Demeton-S-methyl, Demeton-S-methylsulphon, Dialifos, Diazinon, Dichlofenthion, Dichlorvos / DDVP, Dicrotophos, Dimethoate, Dimethylvinphos, Dioxabenzofos, Disulfoton, EPN, Ethion Fimophos, Fenion Ephamophos, Ethion Fimoprophos , Fenitrothion, fensulfothion, fenthion, flupyrazofos, fonofos, formothion, fosmethilan, fosthiazate, heptenophos, iodofenphos, iprobefos, isazofos, isofenphos, isopropyl o-salicylate, isoxathion, malathion, mecarbam, methacrifosidos, methacrifosin, methacrifosin, methacrifosin, methacrifosin Omethoate, Oxydemeton-methyl, Parathion (-methyl / -ethyl), Phenthoate, Phorate, Phosalone, Phosmet, Phosphamidon, Phosphocarb, Phoxim, Pirimiphos (-methyl / -ethyl), Profenofos, Propaphos, Propetamphos, Prothiofos, Prothoate, Pyraclofos, Pyridaphenthion, Pyridathion, Quinalphos, Sebufos, Sulfotep, Sulprofos, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, Triclorfon, Vamidothion
Natrium-Kanal-Modulatoren / Spannungsabhängige Natrium-Kanal-BlockerSodium channel modulators / voltage-dependent sodium channel blockers
2.1 Pyrethroide, zum Beispiel Acrinathrin, Allethrin (d-cis-trans, d-trans), Beta-Cyfluthrin, Bifenthrin, Bioallethrin, Bioallethrin-S-cyclopentyl-isomer, Bioethanomethrin, Biopeπnethrin, Bioresmethrin, Chlovaporthrin, Cis-Cypermethrin, Cis-Resmethrin, Cis-Permethrin, Clocythrin, Cycloprothrin, Cyfluthrin, Cyhalothrin, Cypermethrin (alpha-, beta-, theta-, zeta-), Cyphenothrin, Deltamethrin, Empenthrin (lR-isomer), Esfenvalerate, Etofenprox, Fenfluthrin, Fenpropathrin, Fenpyrithrin, Fenvalerate, Flubrocythrinate, Flucythrinate, Flufenprox, Flumethrin, Fluvalinate, Fubfenprox, Gamma-Cyhalothrin, Imiprothrin, Kadethrin, Lambda- Cyhalothrin, Metofluthrin, Permethrin (eis-, trans-), Phenothrin (IR-trans isomer), Prallethrin, Profluthrin, Protrifenbute, Pyresmethrin, Resmethrin, RU 15525, Silafluofen, Tau-Fluvalinate, Tefluthrin, Terallethrin, Tetramethrin (-1R- isomer), Tralomethrin, Transfluthrin, ZXI 8901, Pyrethrins (pyrethrum)2.1 pyrethroids, for example acrinathrin, allethrin (d-cis-trans, d-trans), beta-cyfluthrin, bifenthrin, bioallethrin, bioallethrin-S-cyclopentyl-isomer, bioethanomethrin, biopinethrin, bioresmethrin, chlovaporthrin, cis-chlorothrinethrin Resmethrin, Cis-Permethrin, Clocythrin, Cycloprothrin, Cyfluthrin, Cyhalothrin, Cypermethrin (alpha, beta, theta, zeta), Cyphenothrin, Deltamethrin, Empenthrin (lR-isomer), Esfenvalerate, Etofenin, Fenphrine, Fenflhrin, Fenflhrin, Fenflhrin, Fenflhrin Fenvalerate, Flubrocythrinate, Flucythrinate, Flufenprox, Flumethrin, Fluvalinate, Fubfenprox, Gamma-Cyhalothrin, Imiprothrin, Kadethrin, Lambda-Cyhalothrin, Metofluthrin, Permethrin (IR, Trans-, Isothrin, Protothrin), Phenothrin), Phenothrin) , Pyresmethrin, resmethrin, RU 15525, silafluofen, tau fluvalinate, tefluthrin, terallethrin, tetramethrin (-1R-isomer), tralomethrin, transfluthrin, ZXI 8901, pyrethrins (pyrethrum)
DDTDDT
2.2 Oxadiazine, zum Beispiel Indoxacarb2.2 oxadiazines, for example indoxacarb
Acetylcholin-Rezeptor-Agonisten/-AntagonistenAcetylcholine receptor agonists / antagonists
3.1 Chloronicotinyle, zum Beispiel Acetamiprid, Clothianidin, Dinotefuran, Imidacloprid, Nitenpyram, Ni- thiazine, Thiacloprid, Thiamethoxam3.1 Chloronicotinyls, for example acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, nitiazines, thiacloprid, thiamethoxam
3.2 Nicotine, Bensultap, Cartap3.2 Nicotine, Bensultap, Cartap
Acetylcholin-Rezeptor-ModulatorenAcetylcholine receptor modulators
4.1 Spinosyne, zum Beispiel Spinosad4.1 Spinosyne, for example Spinosad
GABA-gesteuerte Chlorid-Kanal-Antagonisten 5.1 Organochlorine, zum Beispiel Camphechlor, Chlordane, Endosulfan, Gamma-HCH, HCH, Heptachlor, Lindane, MethoxychlorGABA-controlled chloride channel antagonists 5.1 organochlorines, for example camphechlor, chlordane, endosulfan, gamma-HCH, HCH, heptachlor, lindane, methoxychlor
5.2 Fiprole, zum Beispiel Acetoprole, Ethiprole, Fipronil, Pyrafluprole, Pyriprole, Vaniliprole5.2 Fiprole, for example acetoprole, ethiprole, fipronil, pyrafluprole, pyriprole, vaniliprole
Chlorid-Kanal-AktivatorenChloride channel activators
6.1 Mectine, zum Beispiel Avermectin, Emamectin, Emamectin-benzoate, Ivermectin, Milbemycin6.1 Mectins, for example avermectin, emamectin, emamectin-benzoate, ivermectin, milbemycin
Juvenilhormon-Mimetika, zum Beispiel Diofenolan, Epofenonane, Fenoxycarb, Hydroprene, Kinoprene, Methoprene, Pyriproxifen, TripreneJuvenile hormone mimetics, for example diofenolan, epofenonane, fenoxycarb, hydroprene, kinoprene, methoprene, pyriproxifene, triprene
Ecdysonagonisten/disruptorenEcdysone agonists / disruptors
8.1 Diacy lhy drazine, zum Beispiel Chromafenozide, Halofenozide, Methoxyfenozide, Tebufenozide8.1 Diacy lhy drazine, for example chromafenozide, halofenozide, methoxyfenozide, tebufenozide
Inhibitoren der ChitinbiosyntheseInhibitors of chitin biosynthesis
9.1 Benzoylharnstoffe, zum Beispiel Bistrifluron, Chlofluazuron, Diflubenzuron, Fluazuron, Flucycloxuron, Flu- fenoxuron, Hexaflumuron, Lufenuron, Novaluron, Noviflumuron, Penfluron, Teflubenzuron, Triflumuron9.1 Benzoylureas, for example bistrifluron, chlofluazuron, diflubenzuron, fluazuron, flucycloxuron, fluefenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, penfluron, teflubenzuron, triflumuron
9.2 Buprofezin9.2 Buprofezin
9.3 Cyromazine9.3 Cyromazines
Inhibitoren der oxidativen Phosphorylierung, ATP-DisruptorenOxidative phosphorylation inhibitors, ATP disruptors
10.1 Diafenthiuron10.1 Diafenthiuron
10.2 Organozinnverbindungen, zum Beispiel Azocyclotin, Cyhexatin, Fenbutatin-oxide10.2 organotin compounds, for example azocyclotin, cyhexatin, fenbutatin oxide
Entkoppler der oxidativen Phoshorylierung durch Unterbrechung des H-Protongradienten 11.1 Pyrrole, zum Beispiel ChlorfenapyrDecoupler of oxidative phosphorylation by breaking the H proton gradient 11.1 pyrroles, for example chlorfenapyr
11.2 Dinitrophenole, zum Beispiel Binapacyrl, Dinobuton, Dinocap, DNOC11.2 dinitrophenols, for example binapacyrl, dinobutone, dinocap, DNOC
Seite-I-ElektronentransportinhibitorenSide-I electron transport inhibitors
12.1 METI's, zum Beispiel Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad, Tolfenpyrad12.1 METI's, for example fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, tolfenpyrad
12.2 Hydramethylnon12.2 hydramethylnon
12.3 Dicofol12.3 Dicofol
Seite-H-ElektronentransportinhibitorenPage-H electron transport inhibitors
RotenoneRotenone
Seite-πi-ElektronentransportinhibitorenSide-πi electron transport inhibitors
Acequinocyl, FluacrypyrimAcequinocyl, fluacrypyrim
Mikrobielle Disruptoren der InsektendarmmembranMicrobial disruptors of the insect intestinal membrane
Bacillus thuringiensis-StämmeBacillus thuringiensis strains
Inhibitoren der FettsyntheseInhibitors of fat synthesis
Tetronsäuren, zum Beispiel Spirodiclofen, Spiromesifen Tetramsäuren, zum Beispiel Spirotetramat (CAS-Reg.-No.: 203313-25-1) und 3-(2,5-Dimethylphenyl)-8-methoxy-2-oxo-l -azaspiro[4.5]dec-3-en-4-yl ethyl carbonate (alias: Carbonic acid, 3-(2,5-dimethylphenyl)-8-methoxy-2-oxo-l-azaspiro[4.5]dec-3-en-4- yl ethyl ester, CAS-Reg.-No.: 382608-10-8) Carboxamide, zum Beispiel Flonicamid Oktopaminerge Agonisten, zum Beispiel AmitrazTetronic acids, for example spirodiclofen, spiromesifen tetramic acids, for example spirotetramate (CAS Reg.-No .: 203313-25-1) and 3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-l-azaspiro [ 4.5] dec-3-en-4-yl ethyl carbonate (alias: Carbonic acid, 3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-l-azaspiro [4.5] dec-3-en-4 yl ethyl ester, CAS Reg.No .: 382608-10-8) carboxamides, for example flonicamide Octopaminergic agonists, for example Amitraz
Inhibitoren der Magnesium-stirnulierten ATPase,Inhibitors of magnesium-stimulated ATPase,
Propargite Benzoesäuredicarboxamide, zum Beispiel FlubendiamidePropargite benzoic acid dicarboxamides, for example flubendiamide
Nereistoxin-Analoge, zum Beispiel Thiocyclam hydrogen oxalate, Thiosultap-sodiumNereistoxin analogs, for example Thiocyclam hydrogen oxalate, Thiosultap-sodium
Biologika, Hormone oder Pheromone Azadirachtin, Bacillus spec, Beauveria spec, Codlemone, Metarrhiziu spec, Paecilomyces spec, Thuringiensin, Verticillium spec.Biologics, hormones or pheromones Azadirachtin, Bacillus spec, Beauveria spec, Codlemone, Metarrhiziu spec, Paecilomyces spec, Thuringiensin, Verticillium spec.
Wirkstoffe mit unbekannten oder nicht spezifischen WirkmechanismenActive substances with unknown or non-specific mechanisms of action
23.1 Begasungsmittel, zum Beispiel Aluminium phosphide, Methyl bromide, Sulfuryl fluoride23.1 fumigants, for example aluminum phosphide, methyl bromide, sulfuryl fluoride
23.2 Fraßhemmer, zum Beispiel Cryolite, Flonicamid, Pymetrozine23.2 feeding inhibitors, for example cryolite, flonicamide, pymetrozine
23.3 Milbenwachstumsinhibitoren, zum Beispiel Clofentezine, Etoxazole, Hexythiazox23.3 mite growth inhibitors, for example clofentezine, etoxazole, hexythiazox
23.4 Amidoflumet, Benclothiaz, Benzoximate, Bifenazate, Bromopropylate, Buprofezin, Chino- methionat, Chlordimeform, Chlorobenzilate, Chloropicrin, Clothiazoben, Cycloprene, Cyflumetofen, Dicyclanil, Fenoxacrim, Fentrifanil, Flubenzimine, Flufenerim, Flutenzin, Gossyplure, Hydramethylnone, Japonilure, Metoxadiazone, Petroleum, Piperonyl butoxide, Potassium oleate, Pyridalyl, Sulfluramid, Tetradifon, Tetrasul, Tri- arathene,Verbutin23.4 amidoflumet, benclothiaz, benzoximate, bifenazate, bromopropylate, buprofezin, quinoline methionate, Chlordimeform, Chlorobenzilate, Chloropicrin, Clothiazoben, Cycloprene, Cyflumetofen, dicyclanil, Fenoxacrim, Fentrifanil, Flubenzimine, flufenerim, Flutenzin, Gossyplure, Hydra methyl None, Japonilure, Metoxadiazone, petroleum , Piperonyl butoxide, Potassium oleate, Pyridalyl, Sulfluramid, Tetradifon, Tetrasul, Triarathene, Verbutin
Auch eine Mischung mit anderen bekannten Wirkstoffen, wie Herbiziden, oder mit Düngemitteln und Wachstumsregulatoren, Safenern bzw. Semiochemicals ist möglich. Bevorzugt sind Mischungen der genannten Triazole, insbesondere Fluquinconazole, Flutriafol, Ipconazole, Triticonazole und Prothioconazole mit Tolylfluanid oder Strobilurinen, insbesondere Fluoxastrobin, Trifloxystrobin, Azoxylstrobin und Pyraclostrobin.A mixture with other known active compounds, such as herbicides, or with fertilizers and growth regulators, safeners or semiochemicals is also possible. Mixtures of the triazoles mentioned, in particular fluquinconazole, flutriafol, ipconazole, triticonazole and prothioconazole with tolylfluanid or strobilurins, in particular fluoxastrobin, trifloxystrobin, azoxylstrobin and pyraclostrobin, are preferred.
Besonders bevorzugt sind die Mischungen Fluquinconazole/Tolylfluanid, Fluquinconazole/ Fluoxastrobin, Fluquinconazole/Trifloxystrobin, Fluquinconazole/Azoxylstrobin, Fluquinconazole/ Pyraclostrobin, Prothioconazole/Tolylfluanid, Prothioconazole/Fluoxastrobin, Prothioconazole/ Trifloxystrobin, Prothioconazole/Azoxystrobin und Prothioconazole/Pyraclostrobin.Particularly preferred are the mixtures fluquinconazole / tolylfluanid, fluquinconazole / fluoxastrobin, fluquinconazole / trifloxystrobin, fluquinconazole / azoxylstrobin, fluquinconazole / pyraclostrobin, prothioconazole / tolylfluanid, prothioconazole / fluoxastroonoxinrozrozrozrozrozrozrozrozrozystrobinro / proxy.
Bevorzugt sind die o.g. Gewichtsverhältnisse.The above are preferred. Weight ratios.
Die DMI-Fungizide werden erfindungsgemäß in die üblichen Beizmittel-Formulierungen über- führt, wie Lösungen, Emulsionen, Suspensionen, Pulver, Schäume, Slurries oder andere Hüllmassen für Saatgut, sowie ULV-Formulierungen.According to the invention, the DMI fungicides are converted into the customary mordant formulations, such as solutions, emulsions, suspensions, powders, foams, slurries or other coating compositions for seeds, and also ULV formulations.
Trockenbeizen (vorzugsweise unter Zusatz von Haftvermittlern, wie z.B. Paraffinöl oder Talkum und gegebenenfalls Farbstoffen),Dry pickling (preferably with the addition of adhesion promoters, such as paraffin oil or talc and possibly dyes),
Schlämmbeizen (vorzugsweise unter Zusatz von Netzmitteln, Dispergiermitteln, Emulgatoren, Klebern, inerten Füllstoffen und Farbstoffen),Slurry pickling (preferably with the addition of wetting agents, dispersing agents, emulsifiers, adhesives, inert fillers and dyes),
Wässrige Flüssigbeizen (vorzugsweise unter Zusatz von Emulgatoren, Dispergiermitteln, Ver- dickungsmitteln, Frostschutzmitteln, Polymeren, Klebern und Farbstoffen), Lösungsmittelhaltige Flüssigbeizen (unter Zusatz von Lösungsmitteln und Farbstoffen), Emulsionsbeizen (unter Zusatz von Emulgatoren, Lösungsmitteln und Farbstoffen).Aqueous liquid stains (preferably with the addition of emulsifiers, dispersants, thickeners, antifreeze agents, polymers, adhesives and dyes), solvent-containing liquid stains (with the addition of solvents and dyes), emulsion stains (with the addition of emulsifiers, solvents and dyes).
Diese Formulierungen werden in bekannter Weise hergestellt, indem man die Wirkstoffe oder Wirkstoffkombinationen mit üblichen Zusatzstoffen vermischt, wie zum Beispiel übliche Streckmittel sowie Lösungs- oder Verdünnungsmittel, Farbstoffe, Netzmittel, Dispergiermittel, Emulgatoren, Entschäumer, Konservierungsmittel, sekundäre Verdickungsmittel, Kleber, Gibberelline und auch Wasser.These formulations are prepared in a known manner by mixing the active ingredients or combinations of active ingredients with customary additives, such as, for example, conventional extenders and solvents or diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and also Water.
Als Farbstoffe, die in den erfmdungsgemäß verwendbaren Beizmittel-Formulierungen enthalten sein können, kommen alle für derartige Zwecke üblichen Farbstoffe in Betracht. Dabei sind sowohl in Wasser wenig lösliche Pigmente als auch in Wasser lösliche Farbstoffe verwendbar. Als Beispiele genannt seien die unter den Bezeiclrnungen Rhodamin B, C.L Pigment Red 112 und C.L Solvent Red 1 bekannten Farbstoffe.Suitable dyes which can be contained in the mordant formulations which can be used according to the invention are all dyes customary for such purposes. Both pigments that are sparingly soluble in water and dyes that are soluble in water can be used. Examples which may be mentioned are the dyes known under the designations rhodamine B, C.L Pigment Red 112 and C.L Solvent Red 1.
Als Netzmittel, die in den erfindungsgemäß verwendbaren Beizmittel-Formulierungen enthalten sein können, kommen alle zur Formulierung von agrochemischen Wirkstoffen üblichen, die Benetzung fördernden Stoffe in Frage. Vorzugsweise verwendbar sind Alkylnaphthalin-Sulfonate, wie Diisopropyl- oder Diisobutyl-naphthalin-Sulfonate.The wetting agents which can be contained in the mordant formulations which can be used according to the invention are all those which are customary for the formulation of agrochemical active compounds, wetting promoting substances in question. Alkyl naphthalene sulfonates, such as diisopropyl or diisobutyl naphthalene sulfonates, can preferably be used.
Als Dispergiermittel und/oder Emulgatoren, die in den erfindungsgemäß verwendbaren Beizmittel- Formulierungen enthalten sein können, kommen alle zur Formulierung von agrochemischen Wirkstoffen üblichen nichtionischen, anionischen und kationischen Dispergiermittel in Betracht. Vorzugsweise verwendbar sind nichtionische oder anionische Dispergiermittel oder Gemische von nichtionischen oder anionischen Dispergiermitteln. Als geeignete nichtionische Dispergiermittel sind insbesondere Ethylenoxid-Propylenoxid Blockpolymere, Alkylphenolpolyglykolether sowie Tri- stryrylphenolpolyglykolether und deren phosphatierte oder sulfatierte Derivate zu nennen. Geeignete anionische Dispergiermittel sind insbesondere Ligninsulfonate, Polyacrylsäuresalze und Aryl- sulfonat-Formaldehydkondensate.Suitable dispersants and / or emulsifiers which may be present in the mordant formulations which can be used according to the invention are all nonionic, anionic and cationic dispersants customary for the formulation of agrochemical active ingredients. Nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants can preferably be used. Suitable nonionic dispersants include, in particular, ethylene oxide / propylene oxide block polymers, alkylphenol polyglycol ethers and tristryrylphenol polyglycol ethers and their phosphated or sulfated derivatives. Suitable anionic dispersants are, in particular, lignin sulfonates, polyacrylic acid salts and aryl sulfonate-formaldehyde condensates.
Als Entschäumer können in den erfindungsgemäß verwendbaren Beizmittel-Formulierungen alle zur Formulierung von agrochemischen Wirkstoffen üblichen schaumhemmenden Stoffe enthalten sein. Vorzugsweise verwendbar sind Silikonentschäumer und Magnesiumstearat.The mordant formulations which can be used according to the invention can contain as defoamers all of the foam-inhibiting substances which are customary for the formulation of agrochemical active compounds. Silicone defoamers and magnesium stearate can preferably be used.
Als Konservierungsmittel können in den erfindungsgemäß verwendbaren Beizmittel-Formulierungen alle für derartige Zwecke in agrochemischen Mitteln einsetzbaren Stoffe vorhanden sein. Beispielhaft genannt seien Dichlorophen und Benzylalkoholhemiformal.All substances which can be used for such purposes in agrochemical compositions can be present as preservatives in the mordant formulations which can be used according to the invention. Examples include dichlorophene and benzyl alcohol hemiform.
Als sekundäre Verdickungsmittel, die in den erfmdungsgemäß verwendbaren Beizmittel-Formulierungen enthalten sein können, kommen alle für derartige Zwecke in agrochemischen Mitteln einsetzbaren Stoffe in Frage. Vorzugsweise in Betracht kommen Cellulosederivate, Acrylsäure- derivate, Xanthan, modifizierte Tone und hochdisperse Kieselsäure.Secondary thickeners which can be contained in the mordant formulations which can be used according to the invention are all substances which can be used in agrochemical compositions for such purposes. Cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and highly disperse silica are preferred.
Als Lösungsmittel, die mit den DMI-Fungiziden kombiniert werden können, kommen alle in agrochemischen Mitteln einsetzbaren organischen Solventien in Betracht. Vorzugsweise in Frage kommen Ketone, wie Methylisobutytketon und Cyclohexanon, ferner Amide, wie Dimethyl- formamid, weiterhin cyclische Verbindungen, wie N-Methyl-pyrrolidon, N-Octyl-pyrrolidon, N- Dodecyl-pyrrolidon, N-Octyl-caprolactam, N-Dodecyl-caprolactam und γ-Butyrolacton, darüber hinaus stark polare Solventien, wie Dimethylsulfoxid, ferner aromatische Kohlenwasserstoffe, wie Xylol, außerdem Ester, wie Propylenglykol-monomethylether-acetat, Adipinsäure-dibutylester, Essigsäure-hexylester, Essigsäure-heptylester, Zitronensäure-tri-n-butylester, Phthalsäure-diethyl- ester und Phthalsäure-di-n-butylester, und weiterhin Alkohole, wie Ethanol, n- und i-Propanol, n- und i-Butanol, n- und i-Amylalkohol, Benzylalkohol und l-Methoxy-2-propanol. Als polymere Zumischkomponenten kommen übliche biologisch abbaubare, natürliche und synthetische Stoffe in Betracht. Vorzugsweise in Frage kommen Polyester, Polyetherester, Copoly- ester, Polyanhydride, Polyesterurethane, thermoplastische Polysaccharide oder Polysaccharid- Derivate, und auch Polyester, Polyetherester und Polyesteramide, die aliphatische und aromatische Estergruppierungen enthalten.All organic solvents which can be used in agrochemical compositions are suitable as solvents which can be combined with the DMI fungicides. Ketones, such as methyl isobutytketone and cyclohexanone, furthermore amides, such as dimethylformamide, and further cyclic compounds, such as N-methyl-pyrrolidone, N-octyl-pyrrolidone, N-dodecyl-pyrrolidone, N-octyl-caprolactam, N- Dodecyl-caprolactam and γ-butyrolactone, in addition strongly polar solvents, such as dimethyl sulfoxide, also aromatic hydrocarbons, such as xylene, also esters, such as propylene glycol monomethyl ether acetate, adipic acid dibutyl ester, acetic acid hexyl ester, acetic acid heptyl ester, citric acid tri- n-butyl ester, diethyl phthalate and di-n-butyl phthalate, and also alcohols, such as ethanol, n- and i-propanol, n- and i-butanol, n- and i-amyl alcohol, benzyl alcohol and l- methoxy-2-propanol. Customary biodegradable, natural and synthetic substances come into consideration as polymeric admixing components. Polyester, polyether esters, copolyesters, polyanhydrides, polyester urethanes, thermoplastic polysaccharides or polysaccharide derivatives, and also polyesters, polyether esters and polyester amides which contain aliphatic and aromatic ester groups are preferred.
Als Kleber, die in den erfindungsgemäß verwendbaren Beizmittel-Foπnulierungen enthalten sein können, kommen alle üblichen in Beizmitteln einsetzbaren Bindemittel in Frage. Vorzugsweise genannt seien Polyvinylpyrrolidon, Polyvinylacetat, Polyvinylalkohol und Tylose.Suitable adhesives which can be contained in the mordant formulations which can be used according to the invention are all binders which are customary in mordants. Polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and tylose are preferred.
Als Gibberelline, die in den erfindungsgemäß verwendbaren Beizmittel-Formulierungen enthalten sein können, kommen vorzugsweise Stoffe der FormelSubstances of the formula are preferably used as gibberellins which can be contained in the mordant formulations which can be used according to the invention
in welcherin which
R für ein Wasserstoffatom oder eine Hydroxygruppe steht undR represents a hydrogen atom or a hydroxy group and
die gestrichelte Linie andeutet, dass an der Stelle des Ringes entweder eine C-C-Einfachbindung oder eine C=C-Doppelbindung enthalten ist,the dashed line indicates that there is either a C-C single bond or a C = C double bond at the position of the ring,
in Betracht.into consideration.
Als Beispiele für Gibberelline der Formel (I) seien genannt:The following may be mentioned as examples of gibberellins of the formula (I):
(1-1) Gibberellin A3 (1-2) (= Gibberellinsäure) (1-1) Gibberellin A3 (1-2) (= gibberellic acid)
Gibberellin A4 (1-3) Gibberellin A4 (1-3)
undand
Gibberellin Aη (1-4) Gibberellin Aη (1-4)
Besonders bevorzugt ist die Gibberellinsäure der Formel (T2).Gibberellic acid of the formula (T2) is particularly preferred.
Die Gibberelline der Formel (I) sind bekannt (vgl. R. Wegler "Chemie der Pflanzenschutz- und Schädlingsbekämpfungsmittel", Band 2, Springer Verlag, Berlin-Heidelberg-New York, 1970, Seiten 401 - 412).The gibberellins of the formula (I) are known (cf. R. Wegler "Chemistry of Plant Protection Products and Pest Control", Volume 2, Springer Verlag, Berlin-Heidelberg-New York, 1970, pages 401-412).
Die erfindungsgemäß verwendbaren Beizmittel-Formulierungen werden entweder direkt oder nach vorherigem Verdünnen mit Wasser zur Behandlung von Sojasaatgut eingesetzt. Die erfindungsgemäß verwendbaren Beizmittel-Formulierungen oder deren verdünnte Zubereitungen können auch zum Beizen von Saatgut transgener Sojapflanzen eingesetzt werden. Dabei können im Zusammenwirken mit den durch Expression gebildeten Substanzen auch zusätzliche synergistische Effekte auftreten.The mordant formulations which can be used according to the invention are used either directly or after prior dilution with water for the treatment of soybean seed. The seed dressing formulations which can be used according to the invention or their diluted preparations can also be used for dressing seeds of transgenic soy plants. In cooperation with the substances formed by expression, additional synergistic effects can also occur.
Zur Behandlung des Sojasaatguts mit den erfindungsgemäß verwendbaren Beizmittel-Formulierungen oder den daraus durch Zugabe von Wasser hergestellten Zubereitungen kommen alle üblicherweise für die Beizung einsetzbaren Mischgeräte in Betracht. Im einzelnen geht man bei der Beizung so vor, dass man das Saatgut in einen Mischer gibt, die jeweils gewünschte Menge an Beizmittel-Formulierungen entweder als solche oder nach vorherigem Verdünnen mit Wasser hinzufügt und bis zur gleichmäßigen Verteilung der Formulierung auf dem Saatgut mischt. Gegebenenfalls schließt sich ein Trocknungsvorgang an.For the treatment of the soybean seed with the mordant formulations which can be used according to the invention or the preparations prepared therefrom by adding water, all mixing devices which can usually be used for the mordanting are suitable. In detail, one proceeds with the dressing in such a way that the seed is put into a mixer, the desired quantity in each case Add mordant formulations either as such or after prior dilution with water and mix until the formulation is evenly distributed on the seeds. If necessary, a drying process follows.
Die Aufwandmenge an den erfmdungsgemäß verwendbaren Beizmittel-Foπnulierungen kann inner- halb eines größeren Bereiches variiert werden. Sie richtet sich nach dem jeweiligen Gehalt der Wirkstoffe in den Formulierungen und nach dem Saatgut. Die Aufwandmengen an DMI-Fungiziden oder deren Kombination liegen im Allgemeinen zwischen 0,001 und 50 g pro Kilogramm Saatgut, vorzugsweise zwischen 0,01 und 15 g pro Kilogramm Saatgut.The application rate of the mordant formulations which can be used according to the invention can be varied within a relatively wide range. It depends on the respective content of the active ingredients in the formulations and on the seeds. The application rates of DMI fungicides or their combination are generally between 0.001 and 50 g per kilogram of seed, preferably between 0.01 and 15 g per kilogram of seed.
Die erfindungsgemäß verwendeten Saatgutbeizen lassen sich neben der Bekämpfung von Phakopsora, insbesondere Phakopsora pachyrhizi und Phakopsora meibomiae, beispielsweise zur Bekämpfung von Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, Pseudomonadaceae, Rhizobiaceae, Enterobacte- riaceae, Corynebacteriaceae und Streptomycetaceae einsetzen.The seed dressing according to the invention can be in addition to the control of Phakopsora, in particular Phakopsora pachyrhizi and Phakopsora meibomiae, for example for controlling Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.
Beispielhaft aber nicht begrenzend seien einige Erreger von pilzlichen und bakteriellen Erkran- kungen, die unter die oben aufgezählten Oberbegriffe fallen, genannt:Some pathogens of fungal and bacterial diseases that fall under the generic names listed above may be mentioned as examples, but not by way of limitation:
Xanthomonas-Arten, wie beispielsweise Xanthomonas campestris pv. oryzae;Xanthomonas species, such as, for example, Xanthomonas campestris pv. Oryzae;
Pseudomonas-Arten, wie beispielsweise Pseudomonas syringae pv. lachrymans;Pseudomonas species, such as, for example, Pseudomonas syringae pv. Lachrymans;
Erwinia- Arten, wie beispielsweise Erwinia amylovora;Erwinia species, such as, for example, Erwinia amylovora;
Phytophthora-Arten, wie beispielsweise Phytophthora sojae; Pseudoperonospora-Arten, wie beispielsweise Pseudoperonospora humuli oderPhytophthora species, such as, for example, Phytophthora sojae; Pseudoperonospora species, such as, for example, Pseudoperonospora humuli or
Pseudoperonospora cubensis;Pseudoperonospora cubensis;
Peronospora-Arten, wie beispielsweise Peronospora brassicae oder Peronospora manshurica;Peronospora species, such as, for example, Peronospora brassicae or Peronospora manshurica;
Erysiphe-Arten, wie beispielsweise Erysiphe polygoni;Erysiphe species, such as, for example, Erysiphe polygoni;
Podosphaera-Arten, wie beispielsweise Podosphaera leucotricha; Puccinia-Arten, wie beispielsweise Puccinia recondita;Podosphaera species, such as, for example, Podosphaera leucotricha; Puccinia species, such as, for example, Puccinia recondita;
Sclerotinia-Arten, wie beispielsweise Sclerotinia sclerotiorum;Sclerotinia species, such as, for example, Sclerotinia sclerotiorum;
Ustilago-Arten, wie beispielsweise Ustilago nuda oder Ustilago avenae;Ustilago species, such as, for example, Ustilago nuda or Ustilago avenae;
Pellicularia-Arten, wie beispielsweise Pellicularia sasakii;Pellicularia species, such as, for example, Pellicularia sasakii;
Fusarium-Arten, wie beispielsweise Fusarium culmorum; Septoria-Arten, wie beispielsweise Septoria nodorum oder Septoria glycines;Fusarium species, such as, for example, Fusarium culmorum; Septoria species, such as, for example, Septoria nodorum or Septoria glycines;
Leptosphaeria-Arten, wie beispielsweise Leptosphaeria nodorum;Leptosphaeria species, such as, for example, Leptosphaeria nodorum;
Cercospora-Arten, wie beispielsweise Cercospora kikuchii;Cercospora species, such as, for example, Cercospora kikuchii;
Alternaria-Arten, wie beispielsweise Alternaria brassicae. Phomopsis Arten, wie beispielsweise Phomopsis longicola; Colletotrichum Arten, wie beispielsweise Celletotrichum truncatum;Alternaria species, such as, for example, Alternaria brassicae. Phomopsis species, such as, for example, Phomopsis longicola; Colletotrichum species, such as, for example, Celletotrichum truncatum;
Rhizoctoinia Arten, wie beispielsweise Rhicoctoinia solani;Rhizoctoinia species, such as, for example, Rhicoctoinia solani;
und insbesondereand particularly
Microsphera Arten, wie Microsphera manshurica.Microsphera species, such as Microsphera manshurica.
Insbesondere eignen sich die erfindungsgemäß eingesetzten Beizmittel zur Bekämpfung des Soja- bohnenrosts.The mordants used according to the invention are particularly suitable for controlling the soybean rust.
Die erfindungsgemäßen Beizen weisen auch eine sehr gute stärkende Wirkung in Pflanzen auf. Sie eignen sich daher zur Mobilisierung pflanzeneigener Abwehrkräfte gegen Befall durch uner- wünschte Mikroorganismen.The stains according to the invention also have a very good strengthening effect in plants. They are therefore suitable for mobilizing the plant's own defenses against attack by undesired microorganisms.
Unter pflanzenstärkenden (resistenzinduzierenden) Stoffen sind im vorliegenden Zusammenhang solche Substanzen zu verstehen, die in der Lage sind, das Abwehrsystem von Pflanzen so zu stimulieren, dass die behandelten Pflanzen bei nachfolgender Inokulation mit unerwünschten Mikroorganismen weitgehende Resistenz gegen diese Mikroorganismen entfalten.Plant-strengthening (resistance-inducing) substances are to be understood in the present context as substances which are able to stimulate the defense system of plants in such a way that the treated plants develop extensive resistance to these microorganisms when subsequently inoculated with undesired microorganisms.
Unter unerwünschten Mikroorganismen sind im vorliegenden Fall phytopathogene Pilze und Bakterien zu verstehen. Die erfindungsgemäßen Stoffe können also eingesetzt werden, um Pflanzen innerhalb eines gewissen Zeitraumes nach der Behandlung gegen den Befall durch die genannten Schaderreger zu schützen. Der Zeitraum, innerhalb dessen Schutz herbeigeführt wird, erstreckt sich im allgemeinen von 1 bis 70 Tage, vorzugsweise 1 bis 35 Tage nach Aussaat.Undesired microorganisms are to be understood in the present case as phytopathogenic fungi and bacteria. The substances according to the invention can thus be used to protect plants against attack by the pests mentioned within a certain period of time after the treatment. The period within which protection is provided generally ranges from 1 to 70 days, preferably 1 to 35 days after sowing.
Die Erfindung wird durch die Beispiele näher erläutert, ohne sie darauf zu beschränken. The invention is explained in more detail by the examples, without being restricted thereto.
Beispiel 1example 1
Wirkung von Fluquinconazole gegen Phakopsora pachyrhiziEffect of fluquinconazole against Phakopsora pachyrhizi
Beizmittel: Fluquinconazole 25 WPC (wettable powder)Mordant: Fluquinconazole 25 WPC (wettable powder)
Zur Beizung wurde das Saatgut 1 Minute lang mit dem Beizmittel in einem verschlossenen Plastiksack geschüttelt.For the dressing, the seed was shaken with the dressing in a sealed plastic bag for 1 minute.
Das Saatgut wurde im Feld ausgesät (4 Parzellen, Parzellengröße je 10 m2, 40 Samen pro m2) und am Tag nach der Aussaat künstlich beregnet.The seeds were sown in the field (4 plots, each 10 m 2 , 40 seeds per m 2 ) and irrigated artificially the day after sowing.
Der natürliche Befall der Kontrolle betrug durchschnittlich 75 %.The natural infestation of the control averaged 75%.
Die Wirksamkeit wird in Prozent ausgedrückt. Dabei bedeutet 0 % einen Wirkungsgrad, der dem der Kontrolle entspricht, während ein Wirkungsgrad von 100 % bedeutet, dass kein Befall beobachtet wird.The effectiveness is expressed in percent. 0% means an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Beispiel 2Example 2
Wirkung von Prothioconazole gegen Phakopsora pachyrhiziEffect of prothioconazole against Phakopsora pachyrhizi
Beizmittel: ProthioconazoleMordant: prothioconazole
Zur Beizung wurde das Saatgut 1 Minute lang mit dem Beizmittel in einem verschlossenen Plastiksack geschüttelt.For the dressing, the seed was shaken with the dressing in a sealed plastic bag for 1 minute.
Das Saatgut wurde im Feld ausgesät (4 Parzellen, Parzellengröße je 10 m2, 40 Samen pro m2) und am Tag nach der Aussaat künstlich beregnet.The seeds were sown in the field (4 plots, each 10 m 2 , 40 seeds per m 2 ) and irrigated artificially the day after sowing.
Der natürliche Befall der Kontrolle betrug durchschnittlich 75 %.The natural infestation of the control averaged 75%.
Die Wirksamkeit wird in Prozent ausgedrückt. Dabei bedeutet 0 % einen Wirkungsgrad, der dem der Kontrolle entspricht, während ein Wirkungsgrad von 100 % bedeutet, dass kein Befall beobachtet wird.The effectiveness is expressed in percent. 0% means an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infection is observed.
Beispiel 3Example 3
Wirkung von Flutriafol gegen Phakopsora pachyrhiziEffect of flutriafol against Phakopsora pachyrhizi
Beizmittel: Flutriafol / Carbendazim / ImidaclopridMordant: Flutriafol / Carbendazim / Imidacloprid
Zur Beizung wurde das Saatgut 1 Minute lang mit dem Beizmittel in einem verschlossenen Plastiksack geschüttelt.For the dressing, the seed was shaken with the dressing in a sealed plastic bag for 1 minute.
Das Saatgut wurde im Feld ausgesät (4 Parzellen, Parzellengröße je 10m2, 40 Samen pro m2) und am Tag nach der Aussaat künstlich beregnet.The seeds were sown in the field (4 plots, parcel size 10m 2 each, 40 seeds per m 2 ) and irrigated artificially the day after sowing.
Als Kontrolle dienten Sojapflanzen deren Saatgut mit einer Mischung des Fungizids Carbendazim und des Insektizids Imidacloprid (100 g bzw. 120 g pro 100 kg Saatgut) gebeizt wurden. Der Befall der Kontrolle lag nach 19 und 25 Tagen bei 33% bzw. 68%.As a control, soybean plants whose seeds were treated with a mixture of the fungicide carbendazim and the insecticide imidacloprid (100 g or 120 g per 100 kg of seed) were treated. Controls were 33% and 68% after 19 and 25 days, respectively.
Die Wirksamkeit wird in Prozent nach der Formel Abbott ([(Wirkung Kontrolle - Wirkung erfindungsgemäßes Beispiel) / Wirkung Kontrolle] * 100) ausgedrückt. Dabei bedeutet 0 % einen Wirkungsgrad, der dem der Kontrolle entspricht, während ein Wirkungsgrad von 100 % bedeutet, dass kein Befall beobachtet wird.The effectiveness is expressed in percent according to the Abbott formula ([(effect control - effect example according to the invention) / effect control] * 100). 0% means an efficiency that corresponds to that of the control, while an efficiency of 100% means that no infection is observed.

Claims

Patentansprüche claims
1. Verwendung eines oder mehrerer Demethylierungsinhibitor (DMI)-Fungizide aus der Gruppe: a) Triazole: a.l. Azaconazole, a.2. Bitertanol, a.3. Bromuconazole, a.4. Cyproconazole, a.5. Difenoconazole, a.6. Diniconazole, a.7. Epoxiconazole, a.8. Fenbuconazole, a.9. Fluquinconazole, a.10. Flusilazole, a.ll. Flutriafol, a.12. Hexaconazole, a.13. Imibenconazole, a.14. Ipconazole, a.15. Metconazole, a.16. Myclobutanil, a.17. Paclobutrazol, a.18. Penconazole, a.19. Propiconazole, a.20. Prothioconazole, a.21. Simeconazole, a.22. Tebuconazole, a.23. Tetraconazole, a.24. Triadimenol, a.25. Triticonazole; b) Pyrimidine: b.l. Fenarimol, b.2. Nuarimol; c) Pyridine: c.l. Pyrifenox; und d) Imidazole: d.i. Imazalil, d.2. Oxpoconazole Fumarat, d.3. Peforazoate, d.4. Prochloraz, d.5. Triflumizole, als Saatgutbeize für Soja gegen Sojabohnenrost.1. Use of one or more demethylation inhibitor (DMI) fungicides from the group: a) triazoles: a.l. Azaconazole, a.2. Bitertanol, a.3. Bromuconazole, a.4. Cyproconazole, a.5. Difenoconazole, a.6. Diniconazole, a.7. Epoxiconazole, a.8. Fenbuconazole, a.9. Fluquinconazole, a.10. Flusilazole, a.ll. Flutriafol, a.12. Hexaconazole, a.13. Imibenconazole, a.14. Ipconazole, a.15. Metconazole, a.16. Myclobutanil, a.17. Paclobutrazole, a.18. Penconazole, a.19. Propiconazole, a.20. Prothioconazole, a.21. Simeconazole, a.22. Tebuconazole, a.23. Tetraconazole, a.24. Triadimenol, a.25. triticonazole; b) Pyrimidines: b.l. Fenarimol, b.2. nuarimol; c) pyridines: c.l. pyrifenox; and d) imidazoles: d.i. Imazalil, d.2. Oxpoconazole fumarate, d.3. Peforazoate, d.4. Prochloraz, d.5. Triflumizole, as a seed treatment for soybeans against soybean rust.
2. Verwendung nach Anspruch 1 mit einem DMI-Fungizid aus der Gruppe Fluquinconazole, Flutriafol, Ipconazole, Prothioconazole und Triticonazole.2. Use according to claim 1 with a DMI fungicide from the group fluquinconazole, flutriafol, ipconazole, prothioconazole and triticonazole.
3. Verfahren zum Schutz von Sojapflanzen gegen Sojabohnenrost, wobei man Saatgut der Pflanzen mit einem oder mehreren DMI-Fungiziden aus der Gruppe a - e gemäß Anspruch 1 behandelt.3. A method for protecting soybean plants against soybean rust, wherein the seed of the plants is treated with one or more DMI fungicides from group a - e according to claim 1.
4. Verfahren nach Anspruch 3, wobei man ein oder mehrere DMI-Fungizide aus der Gruppe Fluquinconazole, Flutriafol, Ipconazole, Prothioconazole und Triticonazole einsetzt. 4. The method according to claim 3, wherein one or more DMI fungicides from the group fluquinconazole, flutriafol, ipconazole, prothioconazole and triticonazole are used.
5. Verwendung eines oder melirerer DMI-Fungizide aus der Gruppe: a) Triazole: a.20. Prothioconazole; b) Pyrimidine: b.l. Fenarimol, b.2. Nuarimol; und c) Pyridine: c.l. Pyrifenox, als Saatgutbeize für Soja.5. Use of one or more meltered DMI fungicides from the group: a) triazoles: a.20. prothioconazole; b) Pyrimidines: b.l. Fenarimol, b.2. nuarimol; and c) pyridines: c.l. Pyrifenox, as a seed dressing for soy.
6. Verwendung nach Anspruch 5 mit dem DMI-Fungizid Prothioconazole.6. Use according to claim 5 with the DMI fungicide prothioconazole.
7. Verfahren zum Schutz von Sojapflanzen gegen phytopathogene Pilze, wobei man Saatgut der Pflanzen mit einem oder mehreren DMI-Fungiziden aus der Gruppe a - c gemäß Anspruch 5 behandelt.7. A method for protecting soybean plants against phytopathogenic fungi, wherein the seed of the plants is treated with one or more DMI fungicides from group a - c according to claim 5.
8. Verfahren nach Anspruch 7, wobei man als DMI-Fungizid Prothioconazole einsetzt.8. The method according to claim 7, wherein the DMI fungicide used is prothioconazole.
9. Sojasaatgut, behandelt und/oder beschichtet mit einem oder mehreren DMI-Fungiziden aus der Gruppe a - c gemäß Anspruch 5.9. soybean seed, treated and / or coated with one or more DMI fungicides from group a - c according to claim 5.
10. Sojasaatgut gemäß Anspruch 9, behandelt und/oder beschichtet mit Prothioconazole. 10. Soybean seed according to claim 9, treated and / or coated with prothioconazole.
EP05756392A 2004-06-18 2005-06-07 Soy seed dressing Withdrawn EP1765080A2 (en)

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EP08157864A EP1969936A3 (en) 2004-06-18 2005-06-07 Soy seed dressing
EP05756392A EP1765080A2 (en) 2004-06-18 2005-06-07 Soy seed dressing
EP08157865A EP1969937A3 (en) 2004-06-18 2005-06-07 Seed treatment agent for soy
EP10177897A EP2266403A3 (en) 2004-06-18 2005-06-07 Seed treatment agent for soy
EP08157863A EP1985179A2 (en) 2004-06-18 2005-06-07 Seed treatment agent for soya

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EP04014307A EP1606999A1 (en) 2004-06-18 2004-06-18 Seed treatment agent for soy
EP05756392A EP1765080A2 (en) 2004-06-18 2005-06-07 Soy seed dressing
PCT/EP2005/006085 WO2005122772A2 (en) 2004-06-18 2005-06-07 Soy seed dressing

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EP10177897A Withdrawn EP2266403A3 (en) 2004-06-18 2005-06-07 Seed treatment agent for soy
EP05756392A Withdrawn EP1765080A2 (en) 2004-06-18 2005-06-07 Soy seed dressing
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