EP1756232A1

EP1756232A1 - Concentrated dye solution

Info

Publication number: EP1756232A1
Application number: EP05739802A
Authority: EP
Inventors: Martin Oberholzer
Original assignee: Clariant International Ltd
Current assignee: Clariant Finance BVI Ltd
Priority date: 2004-05-26
Filing date: 2005-05-17
Publication date: 2007-02-28
Also published as: CN1961045A; NO20065378L; TW200613464A; US20070251030A1; BRPI0511598A; KR20070024538A; WO2005116143A1; JP2008500421A

Abstract

Concentrated aqueous dye solutions comprising one or more cationizable dyes, an organic acid and water and their use for dyeing and/or printing organic substrates and for producing inkjet printing inks (Formula I), where each A is independently -NH- or -O-, B is a polyvalent group or atom, n’ and n’’ are natural numbers and the surn total of n’ and n’’ is ≥2, m is a group having the formula (c1) or (c2).

Description

Concentrated dye solution

The present invention relates to a concentrated storage-stable aqueous dye solution and more particularly to a concentrated storage-stable aqueous dye solution without any solubilizer content. The invention further relates to the use of the present invention's concentrated dye solution, if appropriate after dilution with water, especially for dyeing and printing paper, including card and board.

Industrial dyeing and printing is typically carried out in an aqueous medium. Pulverulent dyes must accordingly first be dissolved in mostly warm or hot water to be usable for printing and dyeing.

Metering systems developed for this purpose utilize weighing or volumetric methods to control the metered addition of dyes and they require stable dye solutions instead of powders and granules.

Such dye solutions have the advantage that they are easily meterable, do not dust and do not require costly dissolving operations.

The solutions should possess optimum stability, so that they do not precipitate during transportation or storage. Typically, they should be stable for a prolonged period between nought and five degrees Celsius, but also at around 50°C. Similarly, frozen solutions shall be stable after pouring and should not present any stability problems during pumping. Precipitates can cause disruptions in pumping or metering systems and lead to unacceptable machine shutdowns and costly cleaning and maintenance.

One problem of known aqueous dye solutions is the large amounts of added solubilizers, which lead to a high carbon content in the dyehouse or paper mill effluence. This leads to effluence of high total organic carbon (TOC) and chemical oxygen demand (COD), and hence causes high water-treating costs. It is accordingly an object of the present invention to provide a concentrated aqueous dye solution for which the dye does not have to be isolated and dried (high energy costs!) and which includes few or no solubilizers. It has now been found that a concentrated aqueous dye solution without addition of solubilizers is stable when the dye is not isolated but ultrafiltered to concentrate it and free it of reaction-based solubilizers (such as l-methyl-2-pyrrolidone or dimethylacetamide).

The concentrated aqueous dye solutions of the present invention comprise one or more cationizable dyes, an organic acid and water.

The present invention's concentrated aqueous dye solutions in a further preferred embodiment comprise dyes of the formula (I)

where each A is independently -NH- or -O-, B is a polyvalent group or atom, n' and n" are natural numbers and the sum total of n' and n" is > 2, m is a natural number > 0,

CC is a group having the formula (c ) or (c₂)

where each R₁₀ is independently H; C_1-4alkyl; C5_-6cycloalkyl; phenyl, benzyl or phenylethyl, each R₁₀' is independently H; -OH or C_1-4alkyl each Tx is independently H; -CN; -COOR₁₅; CONR₁₆R₁₇; SO₂NR₁₆R₁₇;

G is H; -R_! iNHR^ or -R_t iNR₁₃R₁₄ where Rπ is C_1-6alkylene or C_2-6alkenylene, R₁₂ and R₁₃ are independently H; unsubstituted C_1-6alkyl; C_2-6alkyl substituted by OH, CN or halogen; phenyl-C_1-3alkyl where the phenyl radical is optionally singly, doubly or triply substituted by substituents selected from the group consisting of chlorine, C_1-4alkyl or C_\. ₄alkoxy; unsubstituted C_5-6cycloalkyl or C_5-6cycloalkyl singly, doubly or triply substituted by C_1-4alkyl groups, R₁₄ has meaning as for R₁₂ or R₁₃ or a hydrogen atom, R₁₅ is C_1-6alkyl radical or phenyl-C_1-3 alkyl radical, R₁₆ and R₁ are independently H or a C_1-4alkyl radical, R₁₈ is in each occurrence independently H; a C_1-4alkyl radical; -NR₁₆R₁₇-(CH₂)_2-4-NR₁₆R₁₇ or -CONR₁₆R₁₇, R₁₉ is a C^alkyl radical or a hydroxy-C_1-4alkyl radical, R₂₀ is -S- or -O-, R₂₁ is a hydrogen atom or a C_1-4alkyl radical, and An^" is a non-coloured anion, with the conditions that

(i) the sum total of n', n" and m is less than the number of valences of B, (ii) when the sum total of n' and n" = 2, then m is > 1,

(iii) when the sum total of n¹ and n" = 3 and A=NH, then m is > 1 an organic acid and water. The present invention's storage-stable high-concentration solutions of dyes of the formula (I) may also comprise a plurality of different dyes whose formulae come within the formula (I).

In preferred dyes of the formula (I), T_t is a substituent of the formula

In further preferred dyes, the CC group is a substituent of the formula

Preferably B is a group B' C[(CH₂)o^]ι-4 or B is one of the groups -[-(CH₂) -O-(CH₂)_M]₄C or [-(CH2)_1-3-O-(CH₂)_1-3-O-(CH₂)_1-3]₄C or [-(CH₂)_1-2-O-(CH₂)_1-2-O-(CH₂)_1-2-O-(CH₂)_1-2]₄C or

[(-CH₂)ι- ]2N(CH₂)ι-₄N[(-CH₂)ι^]2. It is particularly preferable for B to be a carbon atom.

Particularly preferred compounds of the formula of the formula (I) have the formula (la)

, where CC is a substituent of the formula (cι) or (0₂) and n" is 1, 2, 3 or 4, with the conditions that when n" = 1, then B" is C(CH OH)₃, when n" = 2, then B" is C(CH₂OH)₂, when n" = 3, then B" is C(CH₂OH), when n" = 4, then B" is C; [-(CH₂)_1-4-O-(CH₂)_1-4]₄C_; [-(CH₂)_1-3-O-(CH₂)₁-₃-O-(CH₂)j_-3]₄C; [-(CH₂)_1-2-O-(CH₂)_1-2-O-(CH₂)_1-2-O-(CH₂)_1-2]₄C or [(-CH₂)_1-4]₂N(CH₂)_1-4N[(-CH₂)_1-4]₂.

Compounds of the formula of the formula (la) are very special wherein CC is a substituent of the formula (ci) or (c₂) and n" is 1, 2, 3 or 4, with the conditions that when n" = 1, then B" is C(CH₂OH)₃ when n" = 2, then B" is C(CH₂OH)₂, when n" = 3, then B" is C(CH₂OH), when n" = 4, then B" is C.

The present invention's storage-stable high-concentration solutions of dyes of the formula (I) have a formula (I) dye content of up to 40% by weight of dye reckoned on the total weight of the solution. Preferred dye solutions have a dye content in the range from 5% to 40% by weight of dye or a dye content in the range from 10% to 35% by weight of dye and most preferably a dye content in the range from 15% to 25% by weight of dye.

The level of organic acids in the present invention's storage-stable high-concentration solutions of dyes of the formula (I) is between 0.5% by weight and 25% by weight reckoned on the total weight of the solution. Preferred dye solutions comprise from 1% to 15% by weight of added organic acids or from 2% to 10% by weight of added organic acids and most preferably from 3% to 7% by weight of added organic acids.

Preferred organic acids are acids of the formula A(-COOH)_n where A is C_1-12-alkanyl or C_1-12-alkenyl which may each be interrupted by nitrogen atoms and or oxygen atoms and which may each be additionally substituted by hydroxyl or NR'R" (where R' and R" are independently C_1-6-alkanyl or C_1-6-alkenyl or C_1-6-hydroxyalkanyl or Ci-₆-hydroxyalkenyl, or unsubstituted phenyl or hydroxyl- or sulphur- or C_1-18-alkanyl- or C_1-18-alkenyl-substituted phenyl) and with n as a natural number of 1, 2 or 3. n is preferably = 1 or 2 and more preferably = 1.

Particular preference is given to formic acid, acetic acid, malonic acid, propionic acid, lactic acid, tartaric acid, benzoic acid, succinic acid. Acetic acid is the most preferred organic acid. These acids will be present in a partially deprotonated (dissociated) state, as would be expected from their pK value and from the pH value of the dye solution.

Examples of preferred non-coloured anions are chlorides, bromides, sulphates, bisulphates, methosulphates, aminosulphonates, perchlorates, benzenesulphonates, oxalates, malonates, maleates, acetates, propionates, lactates, succinates, tartrates, malates, methanesulphonates and benzoates. But also complex anions such as for example zinc chloride double salts and anions of boric acid, citric acid, glycolic acid, diglycolic acid and adipic acid or addition products of orthoboric acid with polyalcohols having at least one cis diol group. These anions may of course also be exchanged, for example by means of ion exchangers or customary precipitation reactions. The ions can also be exchanged by diafiltration or ultrafiltration. The halides chloride and bromide are particularly preferred anions and chloride is most preferred.

In principle, the salts of the added organic acids can likewise perform the anion function. In a particularly preferred embodiment, the anions are chlorides and the added organic acid is acetic acid.

Preferred dye solutions according to the present invention consist of up to 40% by weight of dye, from 0.5% to 25% by weight of the organic acid and, made up to 100% by weight, of water, but especially of 10% to 35% by weight of dye, from 1% to 15% by weight of the organic acid and, made up to 100% by weight, of water, with especially preferred dye solutions consisting of 15% to 25% by weight of dye, from 2% to 10% by weight of the organic acid and, made up to 100% by weight, of water.

Particularly preferred dye solutions according to the present invention consist of up to 40% by weight of dye as chloride, from 0.5% to 25% by weight of the organic acid and, made up to 100% by weight, of water, but especially of 10% to 35% by weight of dye as chloride, from 1% to 15% by weight of the organic acid and, made up to 100% by weight, of water, with especially preferred dye solutions consisting of 15% to 25% by weight of dye as chloride, from 2% to 10% by weight of the organic acid and, made up to 100% by weight, of water.

Very particularly preferred dye solutions according to the present invention consist of up to 40% by weight of dye as chloride, from 0.5% to 25% by weight of acetic acid and, made up to 100% by weight, of water, but especially of 10% to 35% by weight of dye as chloride, from 1 % to 15% by weight of acetic acid and, made up to 100% by weight, of water, with especially preferred dye solutions consisting of 15% to 25% by weight of dye as chloride, from 2% to 10% by weight of acetic acid and, made up to 100% by weight, of water.

The invention also provides a process for producing the invention's dye solutions which is characterized in that an aqueous solution or suspension of at least one crude cationic dye is pressed through a semipermeable membrane by applying a pressure to remove salts and synthesis by-products having molecular weights below 500 and some water.

In a preferred embodiment, the permeate is continuously or intermittently replaced or supplemented by water or buffer solution so that the volume of the batch changes only minimally, if at all. In other words, the dye concentration remains constant or substantially constant. The dye concentration of the permeate does not change by more than 20% in a preferred embodiment, by not more than 10 % in particularly preferred processes and by not more than 5% in very particularly preferred processes.

Following this diafiltration or ultrafiltration, the dye solution is brought to the desired concentration by concentrating.

The membranes used in the process of the present invention are TFM™ membranes, for example the G10, G20, G50 or DL5 membranes from GE Osmonics Desal (GE Osmonics Inc., 5951 Clearwater Drive, Minnetonka, Minnesota 55343, United States), of which the DL5 membrane is particularly preferred. In a further, preferred version, the counterions of the cationic dye are exchanged, or further anions added, prior to diafiltration. The newly added anions mean that the original anions are easily removable through ultrafiltration or diafiltration. The counterions of the cationic functions are exchanged by halides in a particularly preferred embodiment and by chloride in a very particularly preferred embodiment.

The present invention further provides for the production of stable liquid formulations of anionic dyes by ultrafiltration of the aqueous solution or suspension of the crude dye.

Ultrafiltration or diafiltration of the reaction solution, which is obtained as per the examples of WO 02/062902, although the dyestuff is not isolated, can be used to render the reaction solution free of further, undesirable additions. Free of undesirable additions is to be understood as meaning in particular that, post ultrafiltration or diafiltration, the solutions comprise less than one% by weight and preferably less than 0.5% by weight of further materials. Undesirable further materials are in particular inert salts and electrolytes which, having been used to neutralize and/or salt the dye out, come from the synthesis stage and are carried along in the synthesis solution or suspension, such as alkali metal or alkaline earth metal salts, for example ammonium, magnesium chloride, magnesium sulphate, magnesium bisulphate, sodium chloride, sodium sulphate, sodium bisulphate, potassium chloride, potassium sulphate or potassium bisulphate, especially sodium chloride.

This is followed by the addition of the required amount of organic acid. In principle, the organic acid can also be added before or during the ultrafiltration or diafiltration.

As well as the water-soluble, organic acids identified, the dye solutions of the present invention may comprise biocides.

Any biocide is suitable. But preference is given to biocides having FDA approval. Any biocide capable of controlling the growth of Gram-positive or Gram-negative bacteria, yeasts or fungi can be used in the solutions of the present invention. Suitable biocides are for example 3-thiazolone derivatives, which are for example alkylated and/or chlorinated or used as mixtures. Typically, biocides are added in an amount of up to 0.15% by weight per ready-produced composition.

The concentrated solutions can also be diluted again with water before they are used for dyeing. The concentrated solutions can also be shaded with further dyes before use. But the concentrated solutions can also be used for shading other dyes.

Dyes especially useful for shading or for being shaded include all dyes which the Colour Index identifies as C.I. Basic Red or C.I. Basic Brown or C.I. Basic Blue or C.I. Basic Violet, and especially one or more of the following dyes can be used for shading: C.I. Basic Brown 23 or C.I. Basic Red 12 or C.I. Basic Blue 1 or C.I. Basic Red 14 or C.I. Basic Violet 10 or C.I. Basic Blue 26.

Dyes of the formula (II) and/or of the formula (III) are similarly useful for shading or for being shaded.

The concentrated solutions can also be used for shading brown dyes of the formula (II), or the concentrated solutions can be shaded with dyes of the formula (II).

The dyes of the formula (II) have the following structure:

where _\ and B₂ are independently -OH and NH₂ and D₃ = H or a residue of the formula

and

R₆,R₇,R₈orR₉ are independently H or -SO₃H and M_a or M independently have the meanings of Mi to Mio, with Mi being H, M₂ being -(CH₂)₃N(CH₃)2, M₃ being -(CH₂)2N(CH₂CH₃)₂,

M₄ being

CH,CH₉— N N-CH₃ ^{2 2} \ / M₅ being

M₆ being

M being

Ms being M₉ being Mio being -(CH₂)₂NH₂ and R_a or R_b independently have the meanings of R_\ to R₅.

R_\ being H, + r- N, /> A R₂ being J

R₃ being R₄ being CN. >

< NH R₅ being 2

The dyes of the formula (II) are known per se and can be prepared as described in DE3715066.

The concentrated solutions can also be used for shading brown dyes of the formula (III), or the concentrated solutions can be shaded with dyes of the formula (III).

The dyes of the formula (III) have the following structure: where R\ R² or R³ are independently H, CH₃, C₂H₅, n-C₃H , i-C₃H , n-C₄H₉, i-C₄H₉, sec-C₄H₉,

Rⁿ is -C2H4-, -C3H6-, -CH(CH₃)CH₂- or -C₄H₆- Y is hydrogen or nitro, q is 1 or 2.

The dyes of the formula (III) are known and can be prepared as described in EP 162409 or EP1352928.

Shading can be effected in the ratios of 2% to 98% by weight (based on the dye) of a dye of the formula (I) and 98% to 2% by weight (based on the dye) of a shading dye, i.e. for example in the ratios 2.0 / 98.0; 2.5 / 97.5; 12.5 / 87.5; 22.5 / 77.5; 32.5 / 67.5; 42.5 / 57.5; 50.0 / 50.0; 57.5 / 42.5; 67.5 / 32.5; 77.5 / 22.5; 80.0 / 20.0; 87.5 / 12.5; 90.0 / 10.0; 95.0 / 5.0; 97.5 / 2.5; or 98.0 / 2.0.

The concentrated dye solutions of the present invention are used in particular, if appropriate after dilution with water, for dyeing and printing paper, including board and card, these materials being dyeable for example in the pulp, by coat or by dipping. In addition, such a liquid formulation can also be used for a continuous or batch dyeing process for textile materials, especially cellulose. The concentrated dye solutions of the present invention can be used as a base for producing inkjet inks or other inks and combinations for the contactless printing of substrates such as paper or textiles. The formulations of the present invention can also be used without further modification for the contactless printing of substrates such as paper or textiles. The present invention further provides for the use of the present invention's dye preparations of anionic dyes for producing wood stains for staining solid wood or wood chippings or chipboards or wood fibre boards. Staining wood in form of beams, boards or finished objects like furniture, parts of buildings is a preferred use of the wood stains according to the invention. The application of the liquid formulations according to the invention may be carried out over the whole or part of the wood's surface (to compensate for color defects in the wood or veneer). The liquid formulations according to the invention may be used in water stains (main solvent water), solvent stains (ca. 30 - 95 % organic solvent), or chemical stains (which are generally water thinnable).

The examples which follow illustrate the invention. Parts in the examples as well as in the application as a whole are by weight and %ages always weight %ages unless otherwise stated. Preparation Example 1 425 parts of isatoic anhydride are added gradually at 50°C to a mixture of 118 parts of pentaerythritol and 8.7 parts of sodium carbonate in 434 parts of N,N- dimethylacetamide. The suspension is stirred for 2 hours and diluted with 4340 parts of water. This is followed by filtration, washing with water and drying at 60°C under reduced pressure to obtain a white powder which is a mixture consisting of 4 components having the formulae (la, lb, lc, Id):

Component lb

Component lc

Component Id

Preparation Example 2 434 parts of the amino components of Example 1 are added to a mixture of 1736 parts of ice, 781 parts of 30% HC1, 694 parts of acetic acid and 260 parts of N,N- dimethylacetamide and are diazotized with 182 parts of 4 N sodium nitrite solution. The temperature is maintained at 0 - 5°C by addition of 870 parts of ice. To the diazo solution obtained are added 3281 parts of an approximately 20% aqueous solution of 6- hydroxy-4-methyl-3-ρyridonyl-3'-methylpyridinium chloride. The pH is adjusted to 3 at a temperature of 10 - 20°C by addition of 130 parts of 30% sodium hydroxide solution. After subsequent stirring for 1 hour, 50 parts of Hyflo-Supercel filter earth are added before filtration through a porcelain suction filter with absorbent pad. The clear dye solution obtained (9700 g; 8900 ml) is diafiltered in a laboratory ultrafiltration system having a DL5 membrane at 40 - 45°C and a pressure of 15 bar until the conductivity in the permeate stays constant. In the process, the volume is kept substantially constant. This required about 33 000 parts (ml) of demineralized water. The pH is maintained at 4.0 - 4.5 during the ultrafiltration by addition of acetic acid. The retentate is concentrated at a pressure of 12 - 15 bar to 5180 parts (g) and then admixed with 140 parts of acetic acid to obtain a solution having a total dye content of about 20% by weight, consisting of the components having the formulae (2a, 2b, 2c, 2d):

Component 2a

Component 2b

Component 2c

Component 2d This solution (20.7% dye as chloride, 5.5% of acetic acid, 73.8% of water) dyes paper in a brilliant yellow hue (λ_max. = 423 nm in dimethylformamide/water), the concentrated solution being dilutable if necessary. The dyeings obtained have excellent wet fastnesses (to plain water, alcohol, milk, soapy water, acetic acid, urine, etc.)

Preparation Example Al

A mixture consisting of 7.7 g of 4-aminoacetanilide and 22.9 g of 3-aminoacetanilide is diazotized with sodium nitrite by known methods and to the mixture of the obtained diazonium salts 58.5 g of 6-hydroxy-4-methyl-l-(3^,-dimethylamino)propyl-3-pyridinio- 2-pyridone betaine base are added as coupling component and these are coupled by known methods at a pH of 1.8-2.2.

The acetylamino group is then hydrolyzed with 57.5 g of 30% hydrochloric acid by known methods and thereupon the two aminoazo compounds are diazotized with 13.8 g of sodium nitrite by known methods and the diazonium salts obtained are coupled with 11 g of resorcinol at 0-5°C.

This provides a brown solution comprising 11.2 g of the dye of the formula

25% 75%

which dyes wood-containing paper in brown shades. Preparation Example A2

22.1 parts of (V₂₀ mol) of the compound of formula

are diazotized at 0 - 5°C with 3.45 parts of sodium nitrite (V₂₀ mol) in a hydrochloric aacciidd mmeeddiiuumm aanndd ccoouupplleedd aatt aa ppHH ooff 11 -- 33 oornto 5.4 parts of 1,3-diaminobenzene (V₂₀ mol) to obtain the dye of the formula (A2a)

Coupling 26.1 parts (V₂o mol) of the diazonium salt of the compound of the formula (A2b)

prepared by. known methods by diazotization and coupling of l-amino-3 - acetylaminobenzene-6-sulfonic acid onto pyridone and subsequent saponification onto the dye of the formula (A2a) provides an isomer mixture of the dye of the formula:

(The possible coupling sites are marked by arrows).

This isomer mixture dyes wood-containing paper in brown shades.

Table 1 below indicates the construction of further dyes preparable according to Preparation Example A2. They conform to the formula

where Bi and B₂ are independently -OH and NH₂ and D₃ = H or a residue of the formula

Table for M_a and M_b

Table for R_a and R_b

Table I

2.5

Preparation Example A36

Preparation of the diazo component: to 326 parts of isatoic anhydride in 1000 parts of dioxane are added dropwise 187 parts of dimethylaminoethanol at 60°C. Subsequent stirring for 1 hour is followed by concentrating in a water jet vacuum and distilling in a fine vacuum. 402 parts of 2'-dimethylaminoethyl anthranilate pass over at 160°C / 0.1 Torr.

21 parts of 2'-dimethylaminoethyl anthranilate are dissolved in a mixture of 50 parts of water,

25 parts of glacial acetic acid and 30 parts of concentrated hydrochloric acid and, after cooling to 5°C, admixed with 34.6 parts of a 23% aqueous solution of sodium nitrite added dropwise. After three hours, excess nitrite is destroyed by addition of sulphamic acid. A solution of 11 parts of resorcinol in 30 parts of warm water is then added, the pH is raised with sodium acetate to pH 5 and the batch is stirred at room temperature overnight. After cooling to 0°C, the batch is gradually adjusted to pH 7 with 5N caustic soda. After 4 hours, the dye obtained is through crystallized and can be filtered off with suction and washed with water. Air drying yields 22 g of dye powder. The dye can be dissolved with glacial acetic acid and water to form a stable 20% liquid formulation. The dye dyes paper in a yellow hue. The hue is No. 4 on the Colour Index Hue Indication Chart. The effluent is only minimally coloured. The dyed papers can be bleached by means of hydrosulphite. The dissolved compound conforms to the formula +

CH₃COO

Preparation Example A37

Preparation of the diazo component: to 326 parts of isatoic anhydride in 1000 parts of dioxane are added dropwise 187 parts of dimethylaminoethanol at 60°C. Subsequent stirring for 1 hour was followed by solvent removal in a vacuum and distilling 402 parts of 2'- dimethylaminoethyl anthranilate passed over at 160°C / 0.1 Torr. 275 parts of 2'-dimethylaminoethyl anthranilate were dissolved in a mixture of 190 parts of water and 230 parts of methanesulphonic acid and, after cooling to 5°C, admixed with 150 parts of a 40% aqueous solution of sodium nitrite added dropwise. After three hours, excess nitrite was destroyed by addition of sulphamic acid. A solution of 44 parts of resorcinol in 160 parts of water was then added, and the batch was raised to pH 5 with sodium acetate and subsequently stirred at room temperature for about 12 h to form a homogeneous solution. The dissolved dye conforms to the formula:

2 CH₃SO₃

Preparation Example 3

1.25 kg of the dye solution of Preparation Example 2 are mixed with 7.75 kg of an approximately 10% liquid formulation of the dye of Preparation Example Al at RT (= room temperature). This gives a stable dye solution which dyes paper in a yellowish brown hue (λmax. = 433 nm in water/acetic acid).

Preparation Example 4

4.2 kg of the dye solution of Preparation Example 2 are mixed with 2.5 kg of the dye solution of Preparation Example A36 at RT. The stable dye solution obtained dyes paper in a reddish yellow hue (λ_max. = 450 nm in water/acetic acid).

Drying prescriptions

Dyeing prescription A

70 parts of chemically bleached pinewood sulphite cellulose and 30 parts of chemically bleached birchwood sulphite cellulose are beaten into 2000 parts of water in a hollander. 1.5 parts of the liquid dye preparation of Preparation Example 2 are added to this stock. Paper is made therefrom after a mixing time of 20 minutes. The absorbent paper obtained in this way has a yellow colour.

Dyeing prescription B

1.5 parts of the liquid dye preparation of Preparation Example 2 are added to 100 parts of chemically bleached sulphite cellulose beaten with 2000 parts of water in a hollander. After mixing through for 15 minutes, customary sizing is effected using resin size and aluminium sulphate. Paper made from this material exhibits a yellow hue in each case.

Dyeing Prescription C

An absorbent web of unsized paper is pulled at 40-50°C through an aqueous dye solution consisting of 95 parts of water and 5 parts of the inventive dye solution of Preparation Example 2.

Excess dye solution is squeezed by two rolls. The dried web of paper has a yellow colour in each case.

The dye preparations of Preparation Examples 3, 4 and A1-A37 can be used for dyeing similarly to Prescriptions A to C.

Dyeing Prescription D

5 parts of the dye preparation of Preparation Example 2 are metered into 4000 parts of softened water at room temperature. 100 parts of prewetted woven cotton fabric are introduced into the bath, followed by heating to the boil over 30 minutes. The bath is held at the boil for an hour during which evaporated water is made good from time to time. The dyeing is then removed from the liquor, rinsed with water and dried. The dyeing obtained has a yellow colour.

The dye preparation of Preparation Examples 3, 4 and Al - A37 can be used for dyeing cotton in a similar manner. Dyeing Prescription E

100 parts of freshly tanned and neutralized chrome grain leather are drummed for 30 minutes in a float of 250 parts of water at 55°C and 0.5 part of the dye preparation made according to Preparation Example 2 and are treated for a further 30 minutes in the same bath with 2 parts of anionic fatliquor based on sulphonated fish oil. The leathers are conventionally dried and finished. The leather obtained has a level yellow hue.

Further low-affinity, vegetable-retanned leathers can likewise be dyed according to known methods.

Dyeing can be done in a similar manner with dyes of Preparation Examples 3, 4 and Al - A37.

Use Example F

15 kg of wastepaper (woody), 25 kg of bleached groundwood and 10 kg of unbleached sulphate pulp were beaten in a pulper to form a 3% aqueous pulp suspension. The pulp suspension was diluted to 2% in a dyeing vat. This suspension was then admixed in succession with 5% of kaolin and 1.25 kg of a 5% acetic acid solution of the dye of Preparation Example 2, reckoned on dry total fibre, by stirring. After 20 minutes the pulp in the mixing vat is admixed with 1% (based on absolutely dry fibre) of a resin size dispersion. The homogeneous pulp suspension was adjusted with alum to pH 5 on the paper machine just upstream of the headbox. The paper machine was used to produce 80g/m² of yellow bag paper with a machine finish.

Use Example G

A dry stock containing 60% groundwood and 40% unbleached sulphite pulp is beaten with sufficient water and ground to 40 SR freeness in a hollander for the dry content to be just above 2.5% and then adjusted with water to a dry content of exactly 2.5% for the high-density pulp. 200 parts of this high-density pulp are admixed with 5 parts of a 0.25% aqueous solution of the dye of Preparation Example 2, stirred for about 5 min., admixed with 2% of resin size and 4% of alum, based on dry stock, and again stirred for some minutes until homogeneous. The material is diluted with about 500 parts of water to 700 parts by volume and used in a known manner to prepare sheets of paper by drainage on a sheet-former. These sheets of paper have a deep yellow colour.

Use Example H

An ink composition for inkjet printing consists of

6 parts of the dye of Preparation Example 2,

20 parts of glycerol and

74 parts of water.

This ink composition was then used for printing paper, papery substrates, textile fibre materials and plastic film/sheet by transferring the ink into the ink receptacle of a commercially available inkjet printer and using it to produce a single-coloured test print on the identified sheetlike materials.

Use Example I

A batten of coniferous wood (European spruce) and a batten of leafy wood (beech) were each cut into pieces of about 5 cm and immersed for some minutes in a diluted (10 parts water and 1 part of the dye solution according to example 2) dyestuff solution according to example 2 and after drying for ten hours light brownish batten pieces were obtained.

Claims

1. Concentrated aqueous dye solutions comprising one or more cationizable dyes, an organic acid and water characterized in that the cationizable dye is a dye of the formula (I)

CC is a group having the formula (ci) or (C₂)

where each Rio is independently H; Cι_-4alkyl; C_5-6cycloalkyl; phenyl, benzyl or phenylethyl, each Rio' is independently H; -OH or each Ti is independently H; -CN; -COOR₁₅; CONR₁₆R₁₇; SO₂NR₁₆R₁₇; G is H; -R₁₁NHR12 or -R_πNR₁₃R₁ where Rn is Cι_-6alkylene or C_2-6alkenylene, R₁₂ and Rι₃ are independently H; unsubstituted C^alkyl; C_2-6alkyl substituted by OH, CN or halogen; phenyl-Cι.₃alkyl where the phenyl radical is optionally singly, doubly or triply substituted by substituents selected from the group consisting of chlorine, Cι_-4alkyl or ^alkoxy; unsubstituted C_5-6cycloalkyl or C_5-6cycloalkyl singly, doubly or triply substituted by groups, Rι₄ has meaning as for Rι₂ or Rι₃ or a hydrogen atom, Rι₅ is Cι_-6alkyl radical or phenyl-Cι_-3 alkyl radical, Ri₆ and Rπ are independently H or a Cι_-4alkyl radical, Rι₈ is in each occurrence independently H; a Cι_-4alkyl radical; -NRι₆Rι₇-(CH₂)_2- -NRι₆Rι₇ or -CONRι₆Rι₇, Ri₉ is a Cι_-4alkyl radical or a hydroxy-Cι_-4alkyl radical, R₂₀ is -S- or -O-, R₂₁ is a hydrogen atom or a Cι_-4alkyl radical, and An^" is a non-coloured anion, with the conditions that

(i) the sum total of n', n" and m is less than the number of valences of B, (ii) when the sum total of n' and n" = 2, then m is ≥ 1, (iii) when the sum total of n' and n" = 3 and A=NH, then m is > 1.

2. Concentrated aqueous dye solutions according to Claim 1 comprising a dye of the formula (II) where Bi and B₂ are independently -OH and NH₂ and D₃ = H or a residue of the formula

and R₆, R₇, R₈ or R₉ are independently H or -SO₃H and

M_a or M_b independently have the meanings of Mi to Mio, with Mi being H, M₂ being -(CH₂)₃N(CH₃)₂, M₃ being -(CH₂)₂N(CH₂CH₃)₂,

CHXH„— N NH M₄ being ^{2 2} v_y

M₅ being

M₆ being M being

M₈ being

M₉ being Mio being -(CH₂)₂NH₂ and

R_a or Rb independently have the meanings of Ri to R₅.

Ri being H, + n -N R₂ being YJ A

R₃ being R₄ being CN,

R₅ being . or a dye of the formula (III) where

R¹, R² or R³ are independently H, CH₃, C₂H₅, n-C₃H , i-C₃H , n-C₄H₉, i-C₄H₉, sec-C₄H₉,

Rⁿ is -C2H4-, -C3H6-. -CH(CH3)CH₂- or -C₄H₆- Y is hydrogen or nitro, q is 1 or 2.

3. Concentrated aqueous dye solutions according to claim 1 or 2 characterized in that the organic acid is an organic acid of the formula A(-COOH)_n, where A is Ci-₁₂-alkanyl or C_1-1 - alkenyl which may each be interrupted by nitrogen atoms and or oxygen atoms and which may each be additionally substituted by hydroxyl or NR'R" (where R' and R" are independently Ci-β-alkanyl or C_1-6-alkenyl or C_1-6-hydroxyalkanyl or

C_1-6-hydroxyalkenyl, or unsubstituted phenyl or hydroxyl- or sulphur- or C_1-18-alkanyl- or Ci- ₁₈-alkenyl-substituted phenyl) and with n as a natural number of 1, 2 or 3.

4. Concentrated aqueous dye solutions according to Claim 1 or 2 or 3 characterized in that the dye solutions of the invention comprise up to 40% by weight of dye, from 0.5% to 25% by weight of the organic acid and are made up to 100% by weight with water.

5. Process for producing the invention's dye solutions according to Claim 1 characterized in that an aqueous solution or suspension of at least one crude cationic dye of the formula (I) is pressed through a semipermeable membrane by applying a pressure to remove salts and synthesis by-products having molecular weights below 500 and some water.

6. Process for producing the invention's dye solutions according to Claim 5 characterized in that the permeate is continuously or intermittently replaced or supplemented by water or buffer solution so that the dye concentration of the permeate does not change by more than 20%.

7. Use of concentrated storage-stable aqueous dye solutions according to Claim 1 for dyeing and/or printing cellulosic materials, especially paper and/or board and/or card.

8. Use of concentrated storage-stable aqueous dye solutions according to Claim 1 for producing inks and formulations for contactless printing, especially for inkjet printing.

9. Substrates characterized in that they have been dyed or printed with concentrated storage-stable aqueous dye solutions according to Claim 1.