EP1601824A1 - The method of making modified cellulose fibers - Google Patents
The method of making modified cellulose fibersInfo
- Publication number
- EP1601824A1 EP1601824A1 EP03816268A EP03816268A EP1601824A1 EP 1601824 A1 EP1601824 A1 EP 1601824A1 EP 03816268 A EP03816268 A EP 03816268A EP 03816268 A EP03816268 A EP 03816268A EP 1601824 A1 EP1601824 A1 EP 1601824A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cellulose
- weight
- spinning
- fibers
- spinning solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920003043 Cellulose fiber Polymers 0.000 title claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 6
- 238000009987 spinning Methods 0.000 claims abstract description 74
- 229920002678 cellulose Polymers 0.000 claims abstract description 45
- 239000001913 cellulose Substances 0.000 claims abstract description 45
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 claims abstract description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000975 dye Substances 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 6
- 239000003899 bactericide agent Chemical group 0.000 claims abstract description 5
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
- 239000000919 ceramic Substances 0.000 claims abstract description 5
- 238000001914 filtration Methods 0.000 claims abstract description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 5
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 239000002696 acid base indicator Chemical group 0.000 claims abstract description 4
- 230000003750 conditioning effect Effects 0.000 claims abstract description 4
- 238000001035 drying Methods 0.000 claims abstract description 4
- 238000001704 evaporation Methods 0.000 claims abstract description 4
- 239000004332 silver Substances 0.000 claims abstract description 4
- 229910052709 silver Inorganic materials 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims abstract description 4
- 239000004094 surface-active agent Substances 0.000 claims abstract description 4
- 239000000243 solution Substances 0.000 claims description 56
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 235000012239 silicon dioxide Nutrition 0.000 claims description 8
- PRZSXZWFJHEZBJ-UHFFFAOYSA-N thymol blue Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C PRZSXZWFJHEZBJ-UHFFFAOYSA-N 0.000 claims description 7
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 claims description 6
- 239000002071 nanotube Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 description 62
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 230000000844 anti-bacterial effect Effects 0.000 description 9
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 6
- 239000003242 anti bacterial agent Substances 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 230000003385 bacteriostatic effect Effects 0.000 description 4
- 229910052681 coesite Inorganic materials 0.000 description 4
- 229910052906 cristobalite Inorganic materials 0.000 description 4
- 229910052682 stishovite Inorganic materials 0.000 description 4
- 229910052905 tridymite Inorganic materials 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000002041 carbon nanotube Substances 0.000 description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 description 3
- 229910052593 corundum Inorganic materials 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- SEQDDYPDSLOBDC-UHFFFAOYSA-N Temazepam Chemical compound N=1C(O)C(=O)N(C)C2=CC=C(Cl)C=C2C=1C1=CC=CC=C1 SEQDDYPDSLOBDC-UHFFFAOYSA-N 0.000 description 1
- MQIGIUNAEDOSKG-UHFFFAOYSA-K [Zn+2].[Ag+].[O-]P([O-])([O-])=O Chemical compound [Zn+2].[Ag+].[O-]P([O-])([O-])=O MQIGIUNAEDOSKG-UHFFFAOYSA-K 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- ZBJVLWIYKOAYQH-UHFFFAOYSA-N naphthalen-2-yl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=C(C=CC=C2)C2=C1 ZBJVLWIYKOAYQH-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- -1 propyl Chemical group 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
Definitions
- the subject of this invention is the method of making modified cellulose fibers from cellulose solution in N-methylmorpholine-N-oxide .
- the common method to make cellulose fibers from cellulose solution in N- methylmorpholine-N-oxide involves mixing cellulose with aqueous N-methylmorpholine-N- oxide, evaporating excess water from the cellulose solution, filtration of the spinning solution which is forced through the holes in the spinning nozzle into the airspace, subsequently followed by water spinning bath, drying and conditioning.
- some modifying substances such as titan dioxide, organic or inorganic dyes in the shape of molecules above 1 nm in diameter are added into the spinning solution.
- the method of making modified cellulose fibers from cellulose solutions in N- methylmorpholine-N-oxide involving mixing the cellulose with aqueous NMMO solution, evaporating of the originated cellulose solution until 12-20 weight % cellulose content and less than 13.3 weight % water are left herein, filtration of the spinning solution, forcing through the nozzles into the airspace, from which it is led into the aqueous spinning bath, finally rinsing, drying and conditioning by means of adding modifying substances, according to the principles of this invention, is described by the fact that modifying substances such as ceramic oxides, metal oxides or their mixtures, if necessary containing additional surfactants, carbon, if necessary modified with silver, bactericidal agents, acid-base indicators, thermochromic dyes with nano- or supramolecular break-up are added to the cellulose, to the solvent-or ⁇ to " the ⁇ spinning"solution in ⁇ proportiOn ⁇ not bigger than-10 weight- % in ratio-to ⁇ the cellulose solvent.
- Ceramic oxides advantageously silicon dioxide, metal oxides or their mixtures are used in the shape of powder or its suspended matter in water or aqueous solution in NMMO. Carbon is used in the shape of nanotubes. Phenolphthalein or thymol blue are advantageously used as acid base indicators.
- cellulose fibers of specific properties are made relatively simply and easily.
- the method improves some of the physico-mechanical properties of the fibers at the same time.
- the spinning solution made by this method contained 15% cellulose by weight, having been thoroughly filtered by acid resisting screen unit it was forced into the spinning head of worm spinning frame, where it was forced through the 0,16 mm holes in the spinning nozzle at temperature 100°C, placed 20 mm above the spinning bath, into the aqueous spinning bath of 80°C comprising 4% NMMO by weight.
- the formed fibers were rinsed in the rinsing bath of 80° C, taken up on the reel with the speed of 80 m/min, subsequently dried and conditioned.
- the received fibers were circular in section, white and lustreless, tensile strength being 32 cN/tex, elongation 12 % and fibrillization 2-3, whereas the fibrillization of unmodified fibers is 6.
- the received spinning solution was filtered as in Example I, subsequently at temperature 110°C forced through the holes in the spinning nozzle, placed 20 mm above the spinning bath, into the spinning bath as in Example I.
- the next step was as in Example I.
- the speed of fiber forming was 120 m/ min.
- the received fibers were circular in section, tensile strength being 36 cN/tex, elongation 13 % and fibrillization 3-4.
- Example III Example III.
- the spinning solution was prepared as in Example I, but at the same time, while dissolving the cellulose, aqueous supension of silicon dioxide SiO 2 with nanomolecular break up (the molecules diameter being 78 nm), was added to the crusher in such quantity that SiO 2 content was equal to 5 weight % in ratio to the cellulose by weight.
- the surfactant under the trade name Berol V-4026 was introduced along with the silicon suspension in the amount 1 weight % in ratio to the cellulose- weight.
- the received spinning solution was filtered as in example I, subsequently at temperature 110° C forced through the holes in the spinning nozzle, placed 45 mm above the spinning bath, into the spinning bath as in Example I.
- the next step was as in Example I.
- the speed of fiber forming was 160 m/ min.
- the received fibers were described as having tensile strength 38 cN/tex, elongation 12 % and fibrillization 3-4.
- Example IV The received fibers were described as having tensile strength 38 cN/tex, elongation 12 % and fibrillization 3-4.
- the received spinning solution was filtered as in example I, subsequently at temperature 110° C forced through the holes in the spinning nozzle, placed 150 mm above the spinning bath, into the spinning bath at temperature 30°C containing 6% NMMO.
- the next step was as in Example I.
- the speed of fiber forming was 150 m/ min.
- the received fibers were described as having tensile strength 36 cN/tex, elongation 10 % and fibrillization 3-4. Moreover they were described as having 50% greater ability to disperse UV radiation as compared to fibers received by all known methods.
- Aqueous supension of zinc oxide ZnO with nanomolecular break up, the molecules diameter being 30 nm, was introduced into the cellulose solution in NMMO, prepared as in Example I, in such an amount that the ZnO content was 1 weight % in ratio to the cellulose weight, and the whole lot was mixed.
- the received spinning solution was filtered as in Example I, subsequently at temperature 110° C forced through the holes in the spinning nozzle, placed 60 mm above the spinning bath, into the spinning bath of 20° C, containing 4,5 % NMMO.
- the next step was as in Example I.
- the speed of fiber forming was 180 m/min.
- the received fibers were described as having tensile strength 33 cN/tex, elongation 10%, fibrillization 3 and 37% greater ability to disperse UV radiation as compared to standard cellulose fibers.
- the spinning solution was prepared as in Example I, but at the same time, in the place of aqueous supension of silicon dioxide, aqueous solution of aluminium trioxide Al 2 O 3 with nanomolecular break up, the molecules diameter being 37 nm, was added in such quantity that Al 2 O 3 content was equal to 1,5 weight % in ratio to the cellulose by weight.
- the received spinning solution was filtered as in example I, subsequently at temperature 110°C forced through the holes in the spinning nozzle, placed 40 mm above the spinning bath, into the spinning bath of 20°C, containing 4% NMMO.
- the next step was as in Example I.
- the speed of fiber forming was 80 m/min.
- the received fibers circular in section, were described by the tensile strength 39 cN/tex, elongation 14 % and fibrillization 3.
- Example VII The received fibers, circular in section, were described by the tensile strength 39 cN/tex, elongation 14 % and fibrillization 3.
- the received spinning solution was filtered as in example I, subsequently at temperature 110°C forced through the holes in the spinning nozzle, placed 20 mm above the spinning bath, into the spinning bath of 20° C, containing 4% NMMO.
- the next step was as in Example I.
- the speed of fiber forming was 140 m/min.
- the received fibers were described as having tensile strength 42 cN/tex, elongation 10%, fibrillization 3 and ability to disperse UV radiation 40% greater as compared to standard cellulose fibers.
- Antibacterial activity of produced fibers towards Escherichia coli was estimated based on the Japanese standard JIS LI 902; 1998. It was stated that the fibers originating from the spinning solution already containing 0.5 weight % of antibacterial agent showed high both bactericidal and bacteriostatic activity. It was stated, moreover, that adding even 5 weight % of a bactericide agent into the spinning solution does not cause any significant changes in physico- mechanical parameters as compared to cellulose fibers produced without Irgasan.
- Example VIII The process of fiber making was repeated as in Example VIII, but instead of Irgasan silver iodide AgJ in the shape of nanomolecular powder, the grain diameter being up to 98 nm, was added to the spinning solution in the amount 0,2-5 weight % in ratio to the cellulose weight.
- Antibacterial activity of produced fibers was estimated as in Example VIII. It was stated that the fibers received from the spinning solution already containing 0.5 weight % of antibacterial agent showed high both bactericidal and bacteriostatic activity. It was stated, moreover, that adding 5 weight % of AgJ to the spinning solution causes only slight reduction of fiber elongation at breaking, and of water retention, as compared to other fibers produced without AgJ.
- Example X Antibacterial activity of produced fibers was estimated as in Example VIII. It was stated that the fibers received from the spinning solution already containing 0.5 weight % of antibacterial agent showed high both bactericidal and bacteriostatic activity. It was stated, moreover, that adding 5 weight % of AgJ to the spinning solution causes only slight reduction of fiber elongation at breaking, and of water retention, as compared to other fibers produced without AgJ.
- Example X Example X.
- Example VIII The process of fiber making was repeated as in Example VIII, but, instead of Irgasan, Al 2 O 3 , doped with silver ion, under the trade name Biostat, in the shape of nanomolecular powder, the grain diameter being 57 nm, was added to the spinning solution in the amount 0,2-5 weight % in ratio to the cellulose weight.
- Antibacterial activity of produced fibers was estimated as in Example VIII. It was stated that the fibers originating from the spinning solution already containing 0.5 weight % of antibacterial agent showed high both bactericidal and bacteriostatic activity. It was stated, moreover, that adding 5 weight % of Biostat causes only slight change in physicomechanical parameters of fibers as compared to other fibers produced without Biostat.
- Example XI Example XI.
- Example VIII The process of fiber making was repeated as in Example VIII, but, instead of Irgasan, silver- zinc phosphate under the trade name Novaron, in the shape of supramolecular powder, the grain diameter being 132 nm, was added to the spinning solution in the amount 0,2-5 weight % in ratio to the cellulose weight.
- Irgasan silver- zinc phosphate under the trade name Novaron, in the shape of supramolecular powder, the grain diameter being 132 nm, was added to the spinning solution in the amount 0,2-5 weight % in ratio to the cellulose weight.
- Antibacterial activity of produced fibers was estimated as in Example VIII. It was stated that the fibers originating from the spinning solution already containing 0.5 weight % of antibacterial agent showed high bactericidal and bacteriostatic activity. The addition of even 5 weight % of Novaron caused insignificant physico-mechanical changes of the fibers as compared to other fibers produced without Novaron. Bactericidal properties of fibers made in Examples Vffl-XI were shown in tab.l, and physico-mechanical properties of these fibers, according to the amount of antibacterial agent added, in tab. 2. Table 1.
- Carbon nanotubes in the shape of powder was introduced into the cellulose solution in ' NMMO, prepared as in Example I, in the amount 3 weight % in ratio to the cellulose by weight, and the whole lot was exposed to mixing.
- the received spinning solution was filtered, subsequently forced through the 18-hole spinning nozzle with the speed of 87m/min into the spinning bath at temperature 20°C
- the distance between the spinneret and the aqueous bath was 100 mm.
- the produced fibers were rinsed under stress in water bath at temperature 80° C, subsequently they were dried and conditioned. Subsequently mechanical and electrical properties of the fibers were measured.
- the received fibers were described as having tensile strength 36 cN/tex and elongation 10%.
- the fibers conducted the current, their resistance was 10 ⁇ *cm whereas the resistance of fibers not containing carbon nanotubes was 10 10 ⁇ 'cm
- the spinning solution was prepared as in Example XII, and at the same time carbon nanotubes, modified by metallic silver, in the shape of powder, were introduced into the cellulose solution in NMMO in the amount 3 weight % in ratio to the cellulose by weight,
- Nanotubes were modified in such way that they were impregnated by aqueous solution of silver salt, subsequently the silver salts were reduced. Fibers were formed from the filtered spinning solution following Example XII.
- the spinning solution was prepared as in Example I, but, at the same time, instead of silicon dioxide, thymol blue in the shape of a paste with supramolecular break-up, nibbed in the aqueous N-methylmorpholine-N-oxide solution, was introduced. The amount of introduced thymol blue was 0,5 weight % in ratio to the cellulose by weight.
- Fibers were formed from the filtered spinning solution following example XII. Tensile strength of the received fibers was 35 cN/tex , elongation was 10 %. It was stated, moreover, that the produced fibers changed their colour according to the pH of environment. An so, if dipped in an aqueous solution with the pH of 12, they turned blue, whereas dipped in an aqueous solution at the pH of 3, they turned yellow, what proved that the received fibers are the pH sensors.
- Example XV Example XV.
- the spinning solution was prepared as in Example XIV, with such difference, that instead of thymol blue, phenolphthalein in the shape of nanomolecular powder, the molecules diameter being 96 nm, was introduced in the amount 0,3 weight % in ratio to the cellulose by weight. Fibers were formed from the filtered spinning solution following example XII.
- Tensile strength of the received fibers was 32cN/tex , elongation was 10%.
- the produced fibers were white, and turned red, if dipped in an aqueous solution at the pH of 10, whereas if dipped in an aqueous solution at the pH of 8 they turned blue, what proved that the received fibers are the pH sensors.
- thermochromic dye BT-31 in the shape of supramolecular powder, the molecules diameter being 173 rim, was introduced in the .amount 3 weight % in ratio to the cellulose by weight. Fibers were formed from the filtered spinning solution following example XII.
- the produced fibers were pale blue, and turned white at the temperature 31° C. It proved that the received fibers are temperature sensors, Tensile strength of the received fibers was 35cN/tex , elongation was 12 %.
- thermochromic dye Bt-43 in the shape of nanomolecular powder, the molecules diameter being 85 nm, was introduced in the amount 2 weight % in ratio to the cellulose by weight. Fibers were formed from the filtered spinning solution following example XII.
- the produced fibers were pale blue, and turned white at the temperature 43° C. In the temperature rising above 43° C they become colorless, and if the temperature was lowered below 43° C they became pale blue again. It proved that the received fibers had stable thermochromic properties. Tensile strength -of -the received fibers was 35cN/tex , elongation was 12 %.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL359080A PL201205B1 (en) | 2003-03-10 | 2003-03-10 | Method for manufacture of modified cellulose fibres |
PL35908003 | 2003-03-10 | ||
PCT/PL2003/000060 WO2004081267A1 (en) | 2003-03-10 | 2003-06-25 | The method of making modified cellulose fibers |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1601824A1 true EP1601824A1 (en) | 2005-12-07 |
EP1601824B1 EP1601824B1 (en) | 2007-01-17 |
Family
ID=32986092
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03816268A Revoked EP1601824B1 (en) | 2003-03-10 | 2003-06-25 | The method of making modified cellulose fibers |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1601824B1 (en) |
AT (1) | ATE351933T1 (en) |
DE (1) | DE60311324T2 (en) |
PL (1) | PL201205B1 (en) |
WO (1) | WO2004081267A1 (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0417477D0 (en) * | 2004-08-05 | 2004-09-08 | Tencel Ltd | Anti-microbial fibres |
KR100575377B1 (en) * | 2004-12-24 | 2006-05-02 | 주식회사 효성 | The method for producing cellulose fibers containing nano-particles |
AT502743B1 (en) | 2005-08-26 | 2008-06-15 | Chemiefaser Lenzing Ag | CELLULOSIC FORM BODY, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF |
DE102006014171A1 (en) * | 2006-03-24 | 2007-09-27 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Panel radiator for use in the field of heating voltage, has electrically conductive cellulose non-woven material that forms electrical resistance required for heating, and two electrical strips, which electrically contacts the material |
DE102006033591B4 (en) * | 2006-07-18 | 2008-10-16 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Process for stabilizing the spinning solution in the production of cellulosic composite moldings |
DE102006046358B3 (en) * | 2006-09-28 | 2007-11-29 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Producing formed cellulose with inclusions of non-polar organic compounds, e.g. fibres for textiles, involves coating emulsified compounds in cellulose solution with waterproofed nano-particles before spinning |
EP2126146B1 (en) | 2007-02-13 | 2015-07-15 | Institute of Natural Fibres and Medicinal Plants | Method of manufacturing silver nanoparticles, cellulosic fibers and nanofibers containing silver nanoparticles and uses thereof in bactericidal yarns and tissues |
DE102007011848A1 (en) * | 2007-03-12 | 2008-09-25 | Wiberg Gmbh | Method for preventing the growth of microorganisms on the outside of a food casing |
DE102007019768A1 (en) * | 2007-04-25 | 2008-11-13 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | A process for producing a high whiteness bioactive cellulosic fiber |
EP2162575B1 (en) * | 2007-07-03 | 2013-03-13 | Aditya Birla Science & Technology CO. LTD. | A lyocell fiber with modified property and a process for making therefor |
DE102007054702B4 (en) | 2007-11-14 | 2018-10-18 | Smartpolymer Gmbh | Process for the preparation of cellulosic shaped bodies, cellulosic shaped bodies and their use |
AT508497A1 (en) * | 2009-06-15 | 2011-01-15 | Chemiefaser Lenzing Ag | PROTECTION TISSUE AGAINST ULTRAVIOLETTE RADIATION BASED ON ARTIFICIAL CELLULOSE FIBERS |
JP5544510B2 (en) * | 2010-03-30 | 2014-07-09 | 国立大学法人信州大学 | Composite fiber and method for producing composite fiber |
CN104233492B (en) * | 2014-10-15 | 2016-01-06 | 钱景 | A kind of nanometer silver antimicrobial salix monogolica regenerated celulose fibre and preparation method thereof |
CN104264259A (en) * | 2014-10-15 | 2015-01-07 | 钱景 | Graphene and salix psammophila regenerated cellulose blended fiber and preparation method thereof |
AT516414B1 (en) | 2014-10-28 | 2017-07-15 | Chemiefaser Lenzing Ag | Liquid-soaked non-woven fabric containing zinc oxide-containing cellulose fibers |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06220712A (en) * | 1993-01-22 | 1994-08-09 | Asahi Chem Ind Co Ltd | Synthetic resin fiber |
KR19980701923A (en) * | 1995-03-04 | 1998-06-25 | 샬크비즈크 피이터 코르넬리스,페트 귄터 | Compositions Containing Solid Fine Particles |
JP3051709B2 (en) * | 1997-09-30 | 2000-06-12 | 憲司 中村 | Antimicrobial cellulose fiber and method for producing the same |
AT407997B (en) * | 1999-08-10 | 2001-07-25 | Chemiefaser Lenzing Ag | COLORED CELLULOSIC SHAPED BODIES |
JP3852681B2 (en) * | 2001-10-12 | 2006-12-06 | 東洋紡績株式会社 | Polybenzazole fiber |
-
2003
- 2003-03-10 PL PL359080A patent/PL201205B1/en not_active IP Right Cessation
- 2003-06-25 AT AT03816268T patent/ATE351933T1/en not_active IP Right Cessation
- 2003-06-25 DE DE60311324T patent/DE60311324T2/en not_active Expired - Fee Related
- 2003-06-25 WO PCT/PL2003/000060 patent/WO2004081267A1/en active IP Right Grant
- 2003-06-25 EP EP03816268A patent/EP1601824B1/en not_active Revoked
Non-Patent Citations (1)
Title |
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See references of WO2004081267A1 * |
Also Published As
Publication number | Publication date |
---|---|
ATE351933T1 (en) | 2007-02-15 |
EP1601824B1 (en) | 2007-01-17 |
DE60311324D1 (en) | 2007-03-08 |
PL201205B1 (en) | 2009-03-31 |
PL359080A1 (en) | 2004-09-20 |
DE60311324T2 (en) | 2007-11-15 |
WO2004081267A1 (en) | 2004-09-23 |
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