EP1576949A1 - Combination of the lipids shea butter and cocoa butter for the treatment of ashen skin - Google Patents

Combination of the lipids shea butter and cocoa butter for the treatment of ashen skin Download PDF

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Publication number
EP1576949A1
EP1576949A1 EP05101706A EP05101706A EP1576949A1 EP 1576949 A1 EP1576949 A1 EP 1576949A1 EP 05101706 A EP05101706 A EP 05101706A EP 05101706 A EP05101706 A EP 05101706A EP 1576949 A1 EP1576949 A1 EP 1576949A1
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EP
European Patent Office
Prior art keywords
skin
butter
cocoa butter
shea butter
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP05101706A
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German (de)
French (fr)
Inventor
Rainer Kröpke
Jens Schulz
Stephanie Von Der Fecht
Astid Heptner
Stefanie Kaninck
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Beiersdorf AG
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Beiersdorf AG
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Publication of EP1576949A1 publication Critical patent/EP1576949A1/en
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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/007Preparations for dry skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions

Definitions

  • the present invention relates to a combination of shea butter and cocoa butter as well their use.
  • the skin is the largest organ in humans. Among its many features (for example for thermoregulation and sensory organ) is the barrier function that causes the desiccation of the Organism prevents, probably the most important. At the same time, the skin acts as a protective device against the penetration and absorption of substances coming from outside. This is done Barrier function through the epidermis, which as the outermost layer the actual protective cover towards the environment. At about one tenth of the total thickness, it is simultaneously the thinnest layer of the skin.
  • the skin is exposed to stress due to various exogenous and endogenous factors, which affect their external appearance and their physiological function.
  • One consequence of these impairments is, for example, dehydration of the skin.
  • the cause of dry skin is usually a lack of moisturizing factors (engl. Moisturizer) in the epidermis.
  • moisturizing factors engl. Moisturizer
  • An important factor of dry skin is the reduced water binding capacity. This depends on the concentration of natural Moisturizing Factors (NMF) in the skin, besides Urea and amino acids play an essential role in epidermal lipids.
  • NMF Moisturizing Factors
  • a lack of Natural moisturizing factors leads to increased transepidermal water loss (TEWL) and finally to the drying of the skin with their typical symptoms such as roughness, Scaling, tightness, cracking, redness or itching.
  • the lack of natural Moisturizing factors can be caused by endogenous factors such as genetic predisposition, Hormonal disorders, diseases or by exogenous factors such as defatting the Skin during skin cleansing or caused by climatic influences.
  • Dry skin torments an increasing number of patients, especially in winter. In addition to elders People as well as children of lighter skin type are also people with darker skin type disproportionately affected by this condition.
  • cocoa processing refers to yellowish colored cocoa-smelling fat localized in the cacao bean storage cotyledons (50-58%) , Cocoa butter forms six crystal forms with melting points between 17.3 and 36.3 ° C. It consists on average of 25% palmitic acid, 37% stearic acid, 34% oleic acid and 3% linoleic acid.
  • the fatty acid profile is characterized by narrow concentration ranges; only for linoleic acid there are small differences.
  • the vitamin E derivatives usually dominates the ⁇ -tocopherol, but its content is subject to very strong fluctuations.
  • cocoa Due to the climatic requirements of the kakako plant ( Theobroma cacao L., Sterculiaceae) cocoa is grown exclusively in a narrow belt along the equator. Therefore, three main provenances (Central and South America, West Africa, Southeast Asia / Oceania) can be distinguished, which are also reflected in the chemical composition of cocoa butter. For many of the characteristic properties of cocoa butter, a high content of symmetrical, monounsaturated triglycerides is responsible (Römpp Chemie-Lexikon online, Version 2.2).
  • Shea butter (INCI Butyrospermum Parkii (shea butter), CAS 68920-03-6) is made from the seeds (about 45% fat) of the predominantly West African-based, about 20 m high butter tree Vitellaria paradoxa, [syn. Butyrospermum parkii ], Sapotaceae. It is a tough buttery fat that is relatively stable to oxide. is u. used directly for food purposes in producer countries (eg Sudan). Furthermore, shea butter is used in cosmetics. The most important fatty acids in the triglycerides are: oleic acid 49-50%, stearic acid 36-42%, palmitic acid 5-6% u. Linoleic acid 4-5%. The export quantities amount to approx. 50,000 t / a (Römpp Chemie-Lexikon online, Version 2.2).
  • advantageous water-in-oil emulsions (W / O emulsions) and uses are characterized by containing cocoa butter in an amount of from 0.1% to 30% by weight, and preferably in an amount of 0.5 to 10% by weight, based in each case on Total weight of the preparation, included.
  • advantageous water-in-oil emulsions W / O emulsions
  • uses are characterized by containing shea butter in an amount of 0.1 to 30% by weight, and preferably in an amount of 0.5 to 30.0% by weight, based in each case on the total weight of the preparation.
  • advantageous water-in-oil emulsion and uses are also characterized characterized in that the weight ratio of shea butter to cocoa butter in the emulsion from 1: 1 to 1:10.
  • W / O emulsifiers one or more Compounds selected from the group polyglycerol isostearates and ethoxylated W / O emulsifiers the following emulsifiers / emulsifier mixtures are used according to the invention preferred are: triglycerol diisostearate and PEG-40 perisostearate and triglycerol diisostearate and diglycerol polyhydroxystearate.
  • advantageous water-in-oil emulsion and uses are characterized characterized in that the W / O emulsifiers in a total amount of 0.1 to 15% by weight, and preferably in a total amount of 0.75 to 5% by weight, based in each case on the total weight of the preparation in which emulsion is present.
  • the lipid phase of the emulsion of the invention may contain fats, oils, waxes and other fatty substances contain.
  • esters from saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 3 to 30 carbon atoms, from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols having a chain length of 3 to 30 carbon atoms, enhalten.
  • ester oils can then be advantageously selected from the group isopropyl myristate, Isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, Isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyl dodecyl palmitate, oleyl oleate, oleyl erucate, erucyl oleate, Erucylerucate as well as synthetic, semi-synthetic and natural mixtures of such Esters, e.g. Jojoba oil.
  • the oil phase can be advantageously selected from the group of branched and unbranched Hydrocarbons and waxes, silicone oils, dialkyl ethers, group of saturated or unsaturated, branched or unbranched alcohols, and fatty acid triglycerides, namely the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids having a chain length of 8 to 24, in particular 12 - 18 C atoms.
  • the fatty acid triglycerides can be chosen, for example, advantageously from the group of synthetic, semi-synthetic and natural oils, e.g. Olive oil, sunflower oil, Soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, palm kernel oil and the like more.
  • waxes For example, cetyl palmitate to use as the sole lipid component of the oil phase.
  • the oil phase is selected from the group consisting of 2-ethylhexyl isostearate, octyldodecanol, isotridecyl isononanoate, isoeicosane, 2-ethylhexyl cocoate, C 12-15 alkyl benzoate, caprylic capric triglyceride, dicaprylyl ether.
  • Particularly advantageous are mixtures of C 12-15 -alkyl benzoate and 2-ethylhexyl isostearate, mixtures of C 12-15 -alkyl benzoate and isotridecyl isononanoate and mixtures of C 12-15 -alkyl benzoate, 2-ethylhexyl isostearate and isotridecyl isononanoate.
  • hydrocarbons paraffin oil, squalane and squalene are advantageous in terms of to use present invention.
  • the oil phase may further comprise a content of cyclic or linear silicone oils or entirely of such oils, although preferred, except the silicone oil or silicone oils an additional content of other oil phase components to use.
  • cyclomethicone octamethylcyclotetrasiloxane
  • Silicone oil used.
  • silicone oils are advantageous in the context of the present Invention, for example hexamethylcyclotrisiloxane, polydimethylsiloxane, Poly (methylphenylsiloxane).
  • mixtures of cyclomethicone and isotridecyl isononanoate from cyclomethicone and 2-ethylhexyl isostearate.
  • the aqueous phase of the preparations according to the invention optionally contains advantageous Alcohols, diols or polyols of low C number, and their ethers, preferably ethanol, isopropanol, Propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether, Propylene glycol monomethyl, monoethyl or monobutyl ether, diethylene glycol monomethyl or monoethyl ethers and analogous products, furthermore lower C number alcohols, e.g.
  • Ethanol isopropanol, 1,2-propanediol, 2-methyl-1,3-propanediol, glycerol and in particular one or more thickening agents, which or which can be chosen advantageously from the group silicon dioxide, aluminum silicates, polysaccharides or their derivatives, e.g. Hyaluronic acid, xanthan gum, hydroxypropylmethylcellulose.
  • thickening agents which or which can be chosen advantageously from the group silicon dioxide, aluminum silicates, polysaccharides or their derivatives, e.g. Hyaluronic acid, xanthan gum, hydroxypropylmethylcellulose.
  • the cosmetic and dermatological preparations according to the invention can be cosmetic Contain excipients as commonly used in such preparations, e.g. Preservatives, bactericides, perfumes, UV light filters, skin bleaching agents, Foaming inhibitors, dyes, pigments containing a coloring matter
  • Cosmetic Contain excipients e.g. Preservatives, bactericides, perfumes, UV light filters, skin bleaching agents, Foaming inhibitors, dyes, pigments containing a coloring matter
  • Have thickening agents, surface-active substances, emulsifiers, softening, moisturizing and / or moisturizing substances, fats, oils, waxes or others usual constituents of a cosmetic or dermatological formulation such as alcohols, Polyols, polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.
  • active compound combinations used according to the invention can also be used with others Antioxidants and / or radical scavengers are combined.
  • antioxidants are selected from the group consisting of amino acids (eg glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (eg urocanic acid) and their derivatives, peptides such as D, L-carnosine, D-carnosine, L-carnosine and their derivatives (eg anserine), carotenoids, carotenes (eg ⁇ -carotene, ⁇ -carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (eg dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (eg thioredoxin, Glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmito
  • Heptathioninsulfoximin in very low tolerated dosages (eg pmol to ⁇ mol / kg), furthermore (metal) chelators (eg ⁇ -hydroxy fatty acids, palmitic acid, phytic acid, phytin, lactoferrin), ⁇ -hydroxy acids (eg citric acid, lactic acid, malic acid), Humic acid, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (eg ⁇ -linolenic acid, linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, tocopherols and derivatives (eg Vitamin E acetate), vitamin A and derivatives (vitamin A palmitate) and benzylic resin, benzylic acid, rutinic acid and its derivatives, butylhydroxytoluene
  • the amount of the aforementioned antioxidants (one or more compounds) in the preparations is preferably from 0.001 to 30% by weight, particularly preferably from 0.05 to 20% by weight, in particular 1-10% by weight, based on the total weight of the preparation.
  • vitamin E and / or its derivatives are the additional antioxidant (s), is advantageous, their respective concentrations in the range of 0.001 to 10 wt .-%, based on the total weight of the formulation to choose.
  • vitamin A, or vitamin A derivatives, or carotenes or their derivatives are advantageous, their respective concentrations from the Range from 0.001 to 10% by weight, based on the total weight of the formulation.
  • Niacinamide and / or panthenol can also be used according to the invention in the preparations be used.
  • Compositions according to the invention may also contain active substances which increase the blood flow of the Stimulate the skin and / or have a vasodilatory effect, advantageous are caffeine, B vitamins (pyridoxine and nicotinic acid and its derivatives), camphor, capsaicin.
  • active substances which increase the blood flow of the Stimulate the skin and / or have a vasodilatory effect, advantageous are caffeine, B vitamins (pyridoxine and nicotinic acid and its derivatives), camphor, capsaicin.
  • selected formulations of the invention are suitable which z.
  • B. known Anti-wrinkle agents such as flavone glycosides (especially ⁇ -glycosyl rutin), coenzyme Q10, vitamin E and / or derivatives and the like, in particular advantageous for Prophylaxis and treatment of cosmetic or dermatological lesions such as they z. In skin aging (e.g., wrinkles and wrinkles).
  • ⁇ -glycosylrutin is the antioxidant, it is advantageous whose respective concentrations from the range of 0.001-5% by weight, based on the total weight of the formulation, to choose.
  • glucocorticoids e.g., hydrocortisone
  • plant agents such as azulene and bisabolol, glycyrrhizin, hamamelin and plant extracts such as Chamomile, aloe vera, Hamazelis, licorice root.
  • TEWL t rans e pidermal w ater l oss
  • moisturizers for the purposes of the present invention are, for example, glycerol, Lactic acid and / or lactates, in particular sodium lactate, butylene glycol, propylene glycol, Biosaccaride gum-1, glycine soy, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid and urea.
  • polymeric moisturizers from the group of water-soluble ones and / or water-swellable and / or water-gellable polysaccharides to use.
  • Hyaluronic acid for example, is particularly advantageous.
  • moisturizers are particularly preferably used according to the invention: Glycerin, sorbitol, urea and panthenol.
  • moisturizers in a total concentration from 1 to 25% by weight, based on the total weight of the preparation, in the Use emulsion.
  • the cosmetic or dermatological emulsions according to the invention can furthermore advantageous, although not mandatory to contain fillers which z. B. the sensory and further improve cosmetic properties of the formulations and, for example create or strengthen a velvety or silky skin feeling.
  • fillers in For the purposes of the present invention, starch and starch derivatives (such as, for example, tapioca starch, Distarch phosphate, aluminum or sodium starch, octenylsuccinate and the like), Pigments which have neither primary UV filter nor coloring action (such as boron nitride etc.) and / or Aerosile® (CAS No. 7631-86-9).
  • emulsions according to the invention can advantageously be used according to the invention as an ointment, cream or lotion. Also, their use is in the form of a spray, e.g. a pump spray According to the invention advantageous, wherein the preparations advantageously also foamed can be. Not least, they can according to the invention advantageous for impregnation of a substrate (e.g., a nonwoven cloth).
  • a substrate e.g., a nonwoven cloth

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Abstract

Cosmetic or dermatological water-in-oil emulsion comprises a combination of shea butter and cocoa butter.

Description

Die vorliegende Erfindung betrifft eine Kombination aus Sheabutter und Kakaobutter sowie deren Verwendung.The present invention relates to a combination of shea butter and cocoa butter as well their use.

Der Wunsch, schön und attraktiv auszusehen, ist von Natur aus im Menschen verwurzelt. Auch wenn das Schönheitsideal im Laufe der Zeit Wandlungen erfahren hat, so ist das Streben nach einem makellosen Äußeren immer das Ziel der Menschen gewesen. Einen wesentlichen Anteil an einem schönen und attraktiven Äußeren hat dabei der Zustand und das Aussehen der Haut.The desire to look beautiful and attractive is inherently rooted in man. Although the beauty ideal has undergone changes over time, so is the quest after a flawless appearance always been the goal of the people. An essential Share in a beautiful and attractive appearance has the state and that Appearance of the skin.

Die Haut ist das größte Organ des Menschen. Unter ihren vielen Funktionen (beispielsweise zur Wärmeregulation und als Sinnesorgan) ist die Barrierefunktion, die das Austrocknen des Organismus verhindert, die wohl wichtigste. Gleichzeitig wirkt die Haut als Schutzeinrichtung gegen das Eindringen und die Aufnahme von außen kommender Stoffe. Bewirkt wird diese Barrierefunktion durch die Epidermis, welche als äußerste Schicht die eigentliche Schutzhülle gegenüber der Umwelt bildet. Mit etwa einem Zehntel der Gesamtdicke ist sie gleichzeitig die dünnste Schicht der Haut.The skin is the largest organ in humans. Among its many features (for example for thermoregulation and sensory organ) is the barrier function that causes the desiccation of the Organism prevents, probably the most important. At the same time, the skin acts as a protective device against the penetration and absorption of substances coming from outside. This is done Barrier function through the epidermis, which as the outermost layer the actual protective cover towards the environment. At about one tenth of the total thickness, it is simultaneously the thinnest layer of the skin.

Die Haut ist durch unterschiedliche exogene und endogene Faktoren Belastungen ausgesetzt, die ihr äußeres Erscheinungsbild sowie ihre physiologische Funktion beeinträchtigen. Eine Folge dieser Beeinträchtigungen ist beispielsweise eine Austrocknung der Haut. Die Ursache für trockene Haut liegt in der Regel in einem Mangel an Feuchthaltefaktoren (engl. Moisturizer) in der Epidermis begründet. Bei atopisch trockener Haut spielt zusätzlich ein gestörter Fettsäure-Methabolismus eine Rolle. Ein wichtiger Faktor der trockenen Haut ist das verminderte Wasserbindevermögen. Dieses hängt von der Konzentration an natürlichen Feuchthaltefaktoren (engl. Natural Moisturizing Factors, NMF) in der Haut ab, wobei neben Harnstoff und Aminosäuren epidermale Lipide eine wesentliche Rolle spielen. Ein Mangel an natürlichen Feuchthaltefaktoren führt zu einem erhöhten transepidermalen Wasserverlust (TEWL) und schließlich zur Austrocknung der Haut mit ihren typische Symptomen wie Rauhigkeit, Schuppung, Spannungsgefühl, Rissigkeit, Rötung oder Juckreiz. Der Mangel an natürlichen Feuchthaltefaktoren kann durch endogene Faktoren wie genetische Veranlagung, Hormonelle Störungen, Krankheiten oder durch exogene Faktoren wie eine Entfettung der Haut bei der Hautreinigung oder durch klimatische Einflüsse hervorgerufen werden.The skin is exposed to stress due to various exogenous and endogenous factors, which affect their external appearance and their physiological function. One consequence of these impairments is, for example, dehydration of the skin. The The cause of dry skin is usually a lack of moisturizing factors (engl. Moisturizer) in the epidermis. In atopic dry skin additionally plays impaired fatty acid metabolism. An important factor of dry skin is the reduced water binding capacity. This depends on the concentration of natural Moisturizing Factors (NMF) in the skin, besides Urea and amino acids play an essential role in epidermal lipids. A lack of Natural moisturizing factors leads to increased transepidermal water loss (TEWL) and finally to the drying of the skin with their typical symptoms such as roughness, Scaling, tightness, cracking, redness or itching. The lack of natural Moisturizing factors can be caused by endogenous factors such as genetic predisposition, Hormonal disorders, diseases or by exogenous factors such as defatting the Skin during skin cleansing or caused by climatic influences.

Trockene Haut quält besonders im Winter eine steigende Anzahl von Patienten. Neben Älteren Menschen sowie Kindern helleren Hauttyps sind auch Menschen mit dunklerem Hauttyp überproportional häufig von diesem Leiden betroffen.Dry skin torments an increasing number of patients, especially in winter. In addition to elders People as well as children of lighter skin type are also people with darker skin type disproportionately affected by this condition.

Je nach Herkunft und Abstammung lassen sich bei Menschen unterschiedliche Hauttypen beobachten, da sich dieses Organ im Verlaufe der Evolution an die unterschiedlichen Umwelteinflüsse angepasst hat. So kennt man beispielsweise aus dem Bereich des Sonnenschutzes die Einteilung der Haut in die folgenden sechs Pigmentierungstypen mit unterschiedlicher Empfindlichkeit gegenüber UV-Lichtstrahlung: Hauttyp Beschreibung Bezeichnung I Haut auffallend hell, blass und zu Sommersprossen neigend; rötliche Haare; Brustwarzen: sehr hell; Augen: grün, blau Keltischer Typ II Etwas dunkler als Typ I, selten Sommersprossig; Haare blond bis braun; Brustwarzen: hell; Augen: blau, grün, blau Germanischer Typ III Haut hell bis hellbraun, keine Sommersprossen; Haare dunkelblond, braun; Brustwarzen: dunkler Dunkelhäutiger Europäer IV Haut braun, oliv; keine Sommersprossen; Haare: dunkelbraun, schwarz, Brustwarzen: sehr dunkel Mediterraner Typ V Haut mit tiefbrauner Grundfarbe Mittelöstlicher oder südamerikanischer Typ VI Haut mit dunkelbrauner bis schwarzer Farbe Afrikanischer Typ Depending on their origin and descent, different types of skin can be observed in humans, as this organ has adapted to the different environmental influences in the course of evolution. For example, from the field of sun protection, the classification of the skin into the following six pigmentation types with different sensitivity to UV light radiation is known: skin type description description I Skin strikingly pale, pale and prone to freckles; reddish hair; Nipples: very bright; Eyes: green, blue Celtic type II Slightly darker than Type I, rarely freckled; Hair blond to brown; Nipples: bright; Eyes: blue, green, blue Germanic type III Skin light to light brown, no freckles; Hair dark blond, brown; Nipples: darker Dark-skinned European IV Skin brown, olive; no freckles; Hair: dark brown, black, nipples: very dark Mediterranean type V Skin with a deep brown base color Middle Eastern or South American type VI Skin with dark brown to black color African guy

Obwohl an sich naheliegend, blieb es in der kosmetischen und dermatologischen Hautpflege lang Zeit weitgehend unbeachtet, dass die unterschiedlichen Hauttypen auch auf andere Umwelteinflüsse wie Hitze, Kälte, Trockenheit oder hohe Luftfeuchtigkeit unters chiedlich empfindlich reagieren. Erst in jüngerer Zeit wird versucht diesen Phänomenen mit Hilfe von "Ethnic skin care" oder "ethnic cosmetics" Rechnung zu tragen. Dabei rücken zunehmend auch die Probleme von Menschen mit den Hauttypen IV bis VI, insbesondere in gemäßigten und kalten Klimazonen, in den Blickpunkt der Forschung. Doch so reichhaltig das Angebot an Kosmetika für hellhäutige Menschen ist, welche diese beispielsweise vor den negativen Folgen einer UV-Licht-Exposition bewahren, so unzureichend ist bis heute das Angebot für dunkelhäutige Menschen, sich insbesondere ihre Haut vor den Belastungen durch Kälte und trockene Luft zu schützen.Although obvious in itself, it remained in the cosmetic and dermatological skin care long time largely unnoticed that the different skin types also affect others Environmental influences such as heat, cold, dryness or high humidity vary sensitive. Only recently has this phenomenon been tried with the help of "Ethnic skin care" or "ethnic cosmetics". In the process, they are increasingly moving also the problems of people with skin types IV to VI, especially in temperate ones and cold climates, in the focus of research. But so rich the offer On cosmetics for fair-skinned people, for example, this is the negative Preserve consequences of UV light exposure, so insufficient is the offer for Dark-skinned people, especially their skin from the stresses of cold and to protect dry air.

Eine Austrocknung der Haut führt bei stark pigmentierter Haut zu einer optischen Graufärbung derselben. Abgestorbene ausgetrocknete Hautschuppen erzeugen dabei einen Grauschleier, der im Allgemeinen als wenig ästhetisch empfunden wird. In der angelsächsischen Literatur ist dieses Phänomen unter dem Begriff "ashy skin" bekannt. Nach dem Stand der Technik wird diese "aschenfarbene Haut" mit reinen Fettcremes z.B. wie Vaseline behandelt. Derartige Produkte haben jedoch den Nachteil, dass sie auf der Haut ein intensives fettigklebriges Hautgefühl erzeugen, ihr ein glänzend unästhetisches Aussehen verleihen und die Haut meist luftundurchlässig abdecken. Auch ist die Fähigkeit Feuchtigkeit in der Haut zu speichern äußerst begrenzt. Derartige Zubereitungen können getrost als "Steinzeit-Kosmetika" bezeichnet werden.Dehydration of the skin results in highly pigmented skin to an optical gray coloration the same. Dead, dehydrated dander create a gray haze, which is generally considered to be of little aesthetic value. In the Anglo-Saxon Literature, this phenomenon is known by the term "ashy skin". According to the state of Technique will use this "ash skin" with pure fat creams e.g. treated like Vaseline. However, such products have the disadvantage that they have an intense greasy on the skin Create a skin feeling, give it a shiny unaesthetic appearance and the Cover skin mostly impermeable to air. Also, the ability to moisturize the skin too store extremely limited. Such preparations can be confidently called "Stone Age cosmetics" be designated.

Es war daher die Aufgabe der vorliegenden Erfindung Lipidkombinationen und Zubereitungen zu entwickeln, welche die Mängel des Standes der Technik beseitigen und eine wirkungsvolle Prophylaxe, Behandlung und Pflege trockener oder gar trocken rissiger Haut und insbesondere stark pigmentierter trockener oder gar trocken rissiger Haut ermöglichen. Das raue, angespannte Hautgefühl, welches bei trockener Haut auftritt sollte ebenso wirkungsvoll und lang anhaltend beseitigt werden wie die bei trockener Haut auftretenden Flecken, Risse und /oder Rötungen der Haut.It was therefore the object of the present invention lipid combinations and preparations which eliminate the deficiencies of the prior art and an effective one Prophylaxis, treatment and care of dry or even dry-chapped skin and especially strongly pigmented dry or even dry-chapped skin. The rough, tense skin sensation that occurs on dry skin should be just as effective and be removed for a long time, such as stains, cracks, and dry skin and / or redness of the skin.

Überraschend gelöst werden die Aufgaben durch

  • eine kosmetische und/oder dermatologische Wasser-in-Öl-Emulsion enthaltend eine Lipidkombination aus Sheabutter und Kakaobutter.
  • die Verwendung einer Lipidkombination aus Sheabutter und Kakaobutter zur Prophylaxe, Behandlung und Pflege von trockener und/oder rissiger Haut, insbesondere von stark pigmentierter trockener und/oder rissiger Haut.
  • die Verwendung einer W/O-Emulsion enthaltend eine Lipidkombination aus Sheabutter und Kakaobutter, zur Prophylaxe, Behandlung und Pflege von trockener und/oder rissiger Haut, insbesondere von trockener und/oder rissiger stark pigmentierter Haut.
  • die Verwendung einer Lipidkombination aus Sheabutter und Kakaobutter zur Prophylaxe, Behandlung und Pflege des Phänomens der aschenfarbener Haut bei Menschen mit stark pigmentierter Haut.
  • die Verwendung einer W/O-Emulsion enthaltend eine Lipidkombination aus Sheabutter und Kakaobutter, zur Prophylaxe, Behandlung und Pflege des Phänomens der aschenfarbener Haut bei Menschen mit stark pigmentierter Haut.
The tasks are solved by surprise
  • a cosmetic and / or dermatological water-in-oil emulsion comprising a lipid combination of shea butter and cocoa butter.
  • the use of a lipid combination of shea butter and cocoa butter for the prophylaxis, treatment and care of dry and / or chapped skin, in particular of highly pigmented dry and / or chapped skin.
  • the use of a W / O emulsion comprising a lipid combination of shea butter and cocoa butter for the prophylaxis, treatment and care of dry and / or chapped skin, in particular of dry and / or chapped, strongly pigmented skin.
  • The use of a lipid combination of shea butter and cocoa butter for the prophylaxis, treatment and care of the phenomenon of ash-colored skin in people with heavily pigmented skin.
  • the use of a W / O emulsion containing a lipid combination of shea butter and cocoa butter for the prophylaxis, treatment and maintenance of the phenomenon of the ash-colored skin in people with highly pigmented skin.

Dabei werden erfindungsgemäß unter "stark pigmentierter Haut" oder "dunkelhäutig" insbesondere Hauttypen der Kategorie IV-VI verstanden.In this case, according to the invention, "strongly pigmented skin" or "dark-skinned" in particular Skin types of category IV-VI understood.

Als Kakaobutter (Kakaoöl, INCI Theobroma Cacao (Cocoa) Seed, CAS 8002-31-1) wird bei der Kakao-Verarbeitung anfallendes, in den Speicherkeimblättern der Kakaobohne (50-58%) lokalisiertes, gelblich gefärbtes und schwach nach Kakao riechendes Fett bezeichnet. Kakaobutter bildet sechs Kristallformen aus mit Schmelzpunkten zwischen 17,3 und 36,3°C. Sie besteht im Mittel aus 25% Palmitinsäure, 37% Stearinsäure, 34% Ölsäure sowie 3% Linolsäure. Das Fettsäure-Profil ist durch enge Konzentrationsbereiche charakterisiert; nur für Linolsäure ergeben sich geringe Unterschiede. Unter den Vitamin-E-Derivaten dominiert gewöhnlich das γ-Tocopherol, dessen Gehalt allerdings sehr starken Schwankungen unterliegt.Aufgrund der klimatischen Anforderungen der Kakakopflanze (Theobroma cacao L., Sterculiaceae) wird Kakao ausschließlich in einem schmalen Gürtel entlang des Äquators angebaut. Daher lassen sich drei Hauptprovenienzen (Mittel- bzw. Südamerika, Westafrika, Südostasien/Ozeanien) unterscheiden, welche auch in der chemischen Zusammensetzung der Kakaobutter zum Ausdruck kommen. Für viele der charakteristischen Eigenschaften der Kakaobutter ist ein hoher Gehalt an symmetrischen, einfach ungesättigten Triglyceriden verantwortlich (Römpp Chemie-Lexikon online, Version 2.2).As cocoa butter (cocoa oil, INCI Theobroma Cocoa (Cocoa) Seed, CAS 8002-31-1), cocoa processing refers to yellowish colored cocoa-smelling fat localized in the cacao bean storage cotyledons (50-58%) , Cocoa butter forms six crystal forms with melting points between 17.3 and 36.3 ° C. It consists on average of 25% palmitic acid, 37% stearic acid, 34% oleic acid and 3% linoleic acid. The fatty acid profile is characterized by narrow concentration ranges; only for linoleic acid there are small differences. Among the vitamin E derivatives usually dominates the γ-tocopherol, but its content is subject to very strong fluctuations. Due to the climatic requirements of the kakako plant ( Theobroma cacao L., Sterculiaceae) cocoa is grown exclusively in a narrow belt along the equator. Therefore, three main provenances (Central and South America, West Africa, Southeast Asia / Oceania) can be distinguished, which are also reflected in the chemical composition of cocoa butter. For many of the characteristic properties of cocoa butter, a high content of symmetrical, monounsaturated triglycerides is responsible (Römpp Chemie-Lexikon online, Version 2.2).

Sheabutter (INCI Butyrosspermum Parkii (Sheabutter), CAS 68920-03-6) wird aus den Samen (ca. 45% Fett) des vornehmlich in Westafrika beheimateten, ca. 20 m hohen Butterbaumes Vitellaria paradoxa, [syn. Butyrospermum parkii], Sapotaceae, gewonnenen. Es ist ein zäh-butterartiges Fett, das relativ stabil gegen Oxid. ist u. in den Erzeugerländern (z. B. Sudan) direkt zu Nahrungszwecken verwendet wird. Weiterhin findet Sheabutter Einsatz in Kosmetika. Die wichtigsten Fettsäuren in den Triglyceriden sind: Ölsäure 49-50%, Stearinsäure 36-42%, Palmitinsäure 5-6% u. Linolsäure 4-5%. Die Exportmengen betragen ca. 50 000 t/a (Römpp Chemie-Lexikon online, Version 2.2).Shea butter (INCI Butyrospermum Parkii (shea butter), CAS 68920-03-6) is made from the seeds (about 45% fat) of the predominantly West African-based, about 20 m high butter tree Vitellaria paradoxa, [syn. Butyrospermum parkii ], Sapotaceae. It is a tough buttery fat that is relatively stable to oxide. is u. used directly for food purposes in producer countries (eg Sudan). Furthermore, shea butter is used in cosmetics. The most important fatty acids in the triglycerides are: oleic acid 49-50%, stearic acid 36-42%, palmitic acid 5-6% u. Linoleic acid 4-5%. The export quantities amount to approx. 50,000 t / a (Römpp Chemie-Lexikon online, Version 2.2).

Erfindungsgemäß vorteilhafte Wasser-in-Öl-Emulsionen (W/O-Emulsionen) und Verwendungen sind dadurch gekennzeichnet, dass sie Kakaobutter in einer Menge 0,1 von bis 30 Gewichts-%, und bevorzugt in einer Menge von 0,5 bis 10 Gewichts-%, jeweils bezogen auf das Gesamtgewicht der Zubereitung, enthalten.According to the invention advantageous water-in-oil emulsions (W / O emulsions) and uses are characterized by containing cocoa butter in an amount of from 0.1% to 30% by weight, and preferably in an amount of 0.5 to 10% by weight, based in each case on Total weight of the preparation, included.

Erfindungsgemäß vorteilhafte Wasser-in-Öl-Emulsionen (W/O-Emulsionen) und Verwendungen sind dadurch gekennzeichnet, dass sie Sheabutter in einer Menge von 0,1 bis 30 Gewichts-%, und bevorzugt in einer Menge von 0,5 bis 30,0 Gewichts-%, jeweils bezogen auf das Gesamtgewicht der Zubereitung, enthalten.According to the invention advantageous water-in-oil emulsions (W / O emulsions) and uses are characterized by containing shea butter in an amount of 0.1 to 30% by weight, and preferably in an amount of 0.5 to 30.0% by weight, based in each case on the total weight of the preparation.

Erfindungsgemäß vorteilhafte Wasser-in-Öl-Emulsion und Verwendungen sind auch dadurch gekennzeichnet, dass das Gewichtsverhältnis von Sheabutter zu Kakaobutter in der Emulsion von 1 : 1 bis 1: 10 beträgt.According to the invention advantageous water-in-oil emulsion and uses are also characterized characterized in that the weight ratio of shea butter to cocoa butter in the emulsion from 1: 1 to 1:10.

Dabei ist es erfindungsgemäß vorteilhaft, wenn als W/O-Emulgatoren eine oder mehrere Verbindungen gewählt aus der Gruppe Polyglycerinisostearate und ethoxylierte W/O-Emulgatoren eingesetzt werden wobei die folgenden Emulgatoren /Emulgatormischungen erfindungsgemäß bevorzugt sind: Triglycerindiisostearat und PEG-40 Perisostearat und Triglycerindiisostearat und Diglycerindipolyhydroxystearat .It is advantageous according to the invention, if as W / O emulsifiers one or more Compounds selected from the group polyglycerol isostearates and ethoxylated W / O emulsifiers the following emulsifiers / emulsifier mixtures are used according to the invention preferred are: triglycerol diisostearate and PEG-40 perisostearate and triglycerol diisostearate and diglycerol polyhydroxystearate.

Bei erfindungsgemäß vorteilhaften Wasser-in-Öl-Emulsion und Verwendungen sind dadurch gekennzeichnet, dass die W/O-Emulgatoren in einer Gesamtmenge von 0,1 bis 15 Gewichts-%, und bevorzugt in einer Gesamtmenge von 0,75 bis 5 Gewichts-%, jeweils bezogen auf das Gesamtgewicht der Zubereitung, in der Emulsion vorhanden sind.In accordance with the invention advantageous water-in-oil emulsion and uses are characterized characterized in that the W / O emulsifiers in a total amount of 0.1 to 15% by weight, and preferably in a total amount of 0.75 to 5% by weight, based in each case on the total weight of the preparation in which emulsion is present.

Die erfindungsgemäße Lipidphase der Emulsion kann Fette, Öle, Wachse und anderen Fettkörper enthalten. The lipid phase of the emulsion of the invention may contain fats, oils, waxes and other fatty substances contain.

Die Lipidphase kann vorteilhaft gewählt werden aus folgender Substanzgruppe:

  • Mineralöle, Mineralwachse
  • Öle, wie Triglyceride der Caprin- oder der Caprylsäure, ferner natürliche Öle wie z.B. Rizinusöl, Macadamia-, Avocado- oder Jojobaöl, Dialkylether wie z.B. Di-n-octylether sowie Dialkylcarbonate wie beispielsweise Di-n-octylcarbonat
  • Fette, Wachse und andere natürliche und synthetische Fettkörper, vorzugsweise Ester von Fettsäuren mit Alkoholen niedriger C-Zahl, z.B. mit Isopropanol, Propylenglykol oder Glycerin, oder Ester von Fettalkoholen mit Alkansäuren niedriger C-Zahl oder mit Fettsäuren;
  • Alkylbenzoate;
  • Silikonöle wie Dimethylpolysiloxane, Diethylpolysiloxane, Diphenylpolysiloxane sowie Mischformen daraus.
The lipid phase can advantageously be selected from the following substance group:
  • Mineral oils, mineral waxes
  • Oils such as triglycerides of capric or caprylic, further natural oils such as castor oil, macadamia, avocado or jojoba oil, dialkyl ethers such as di-n-octyl ether and dialkyl carbonates such as di-n-octyl carbonate
  • Fats, waxes and other natural and synthetic fatty substances, preferably esters of fatty acids with lower C-number alcohols, for example with isopropanol, propylene glycol or glycerol, or esters of fatty alcohols with lower C-number alkanoic acids or with fatty acids;
  • benzoates;
  • Silicone oils such as dimethylpolysiloxanes, diethylpolysiloxanes, diphenylpolysiloxanes and mixed forms thereof.

Sie kann ferner erfindungsgemäß vorteilhaft Verbindungen gewählt aus der Gruppe der Ester aus gesättigten und/oder ungesättigten, verzweigten und/oder unverzweigten Alkancarbonsäuren einer Kettenlänge von 3 bis 30 C-Atomen und gesättigten und/oder ungesättigten, verzweigten und/oder unverzweigten Alkoholen einer Kettenlänge von 3 bis 30 C-Atomen, aus der Gruppe der Ester aus aromatischen Carbonsäuren und gesättigten und/oder ungesättigten, verzweigten und/oder unverzweigten Alkoholen einer Kettenlänge von 3 bis 30 C-Atomen, enhalten. Solche Esteröle können dann vorteilhaft gewählt werden aus der Gruppe Isopropylmyristat, Isopropylpalmitat, lsopropylstearat, Isopropyloleat, n-Butylstearat, n-Hexyllaurat, n-Decyloleat, Isooctylstearat, Isononylstearat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexyllaurat, 2-Hexyldecylstearat, 2-Octyldodecylpalmitat, Oleyloleat, Oleylerucat, Erucyloleat, Erucylerucat so wie synthetische, halbsynthetische und natürliche Gemische solcher Ester, z.B. Jojobaöl.It can also according to the invention advantageously selected compounds from the group of esters from saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 3 to 30 carbon atoms, from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols having a chain length of 3 to 30 carbon atoms, enhalten. Such ester oils can then be advantageously selected from the group isopropyl myristate, Isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, Isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyl dodecyl palmitate, oleyl oleate, oleyl erucate, erucyl oleate, Erucylerucate as well as synthetic, semi-synthetic and natural mixtures of such Esters, e.g. Jojoba oil.

Ferner kann die Ölphase vorteilhaft gewählt werden aus der Gruppe der verzweigten und unverzweigten Kohlenwasserstoffe und -wachse, der Silkonöle, der Dialkylether, der Gruppe der gesättigten oder ungesättigten, verzweigten oder unverzweigten Alkohole, sowie der Fettsäuretriglyceride, namentlich der Triglycerinester gesättigter und/oder ungesättigter, verzweigter und/oder unverzweigter Alkancarbonsäuren einer Kettenlänge von 8 bis 24, insbesondere 12 - 18 C-Atomen. Die Fettsäuretriglyceride können beispielsweise vorteilhaft gewählt werden aus der Gruppe der synthetischen, halbsynthetischen und natürlichen Öle, z.B. Olivenöl, Sonnenblumenöl, Sojaöl, Erdnussöl, Rapsöl, Mandelöl, Palmöl, Kokosöl, Palmkernöl und dergleichen mehr.Furthermore, the oil phase can be advantageously selected from the group of branched and unbranched Hydrocarbons and waxes, silicone oils, dialkyl ethers, group of saturated or unsaturated, branched or unbranched alcohols, and fatty acid triglycerides, namely the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids having a chain length of 8 to 24, in particular 12 - 18 C atoms. The fatty acid triglycerides can be chosen, for example, advantageously from the group of synthetic, semi-synthetic and natural oils, e.g. Olive oil, sunflower oil, Soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, palm kernel oil and the like more.

Auch beliebige Abmischungen solcher Öl- und Wachskomponenten sind vorteilhaft im Sinne der vorliegenden Erfindung einzusetzen. Es kann auch gegebenenfalls vorteilhaft sein, Wachse, beispielsweise Cetylpalmitat, als alleinige Lipidkomponente der Ölphase einzusetzen.Any mixtures of such oil and wax components are advantageous in the sense to use the present invention. It may also be advantageous, waxes, For example, cetyl palmitate to use as the sole lipid component of the oil phase.

Vorteilhaft wird die Ölphase gewählt aus der Gruppe 2-Ethylhexylisostearat, Octyldodecanol, Isotridecylisononanoat, Isoeicosan, 2-Ethylhexylcocoat, C12-15-Alkylbenzoat, Capryl-Caprinsäuretriglycerid, Dicaprylylether.Advantageously, the oil phase is selected from the group consisting of 2-ethylhexyl isostearate, octyldodecanol, isotridecyl isononanoate, isoeicosane, 2-ethylhexyl cocoate, C 12-15 alkyl benzoate, caprylic capric triglyceride, dicaprylyl ether.

Besonders vorteilhaft sind Mischungen aus C12-15-Alkylbenzoat und 2-Ethylhexylisostearat, Mischungen aus C12-15-Alkylbenzoat und Isotridecylisononanoat sowie Mischungen aus C12-15-Alkylbenzoat, 2-Ethylhexylisostearat und Isotridecylisononanoat.Particularly advantageous are mixtures of C 12-15 -alkyl benzoate and 2-ethylhexyl isostearate, mixtures of C 12-15 -alkyl benzoate and isotridecyl isononanoate and mixtures of C 12-15 -alkyl benzoate, 2-ethylhexyl isostearate and isotridecyl isononanoate.

Von den Kohlenwasserstoffen sind Paraffinöl, Squalan und Squalen vorteilhaft im Sinne der vorliegenden Erfindung zu verwenden.Of the hydrocarbons, paraffin oil, squalane and squalene are advantageous in terms of to use present invention.

Vorteilhaft kann die Ölphase ferner einen Gehalt an cyclischen oder linearen Silikonölen aufweisen oder vollständig aus solchen Ölen bestehen, wobei allerdings bevorzugt wird, außer dem Silikonöl oder den Silikonölen einen zusätzlichen Gehalt an anderen Ölphasenkomponenten zu verwenden.Advantageously, the oil phase may further comprise a content of cyclic or linear silicone oils or entirely of such oils, although preferred, except the silicone oil or silicone oils an additional content of other oil phase components to use.

Vorteilhaft wird Cyclomethicon (Octamethylcyclotetrasiloxan) als erfindungsgemäß zu verwendendes Silikonöl eingesetzt. Aber auch andere Silikonöle sind vorteilhaft im Sinne der vorliegenden Erfindung zu verwenden, beispielsweise Hexamethylcyclotrisiloxan, Polydimethylsiloxan, Poly(methylphenylsiloxan).Advantageously, cyclomethicone (octamethylcyclotetrasiloxane) is used as the invention Silicone oil used. But other silicone oils are advantageous in the context of the present Invention, for example hexamethylcyclotrisiloxane, polydimethylsiloxane, Poly (methylphenylsiloxane).

Besonders vorteilhaft sind ferner Mischungen aus Cyclomethicon und Isotridecylisononanoat, aus Cyclomethicon und 2-Ethylhexylisostearat.Also particularly advantageous are mixtures of cyclomethicone and isotridecyl isononanoate, from cyclomethicone and 2-ethylhexyl isostearate.

Die wässrige Phase der erfindungsgemäßen Zubereitungen enthält gegebenenfalls vorteilhaft Alkohole, Diole oder Polyole niedriger C-Zahl, sowie deren Ether, vorzugsweise Ethanol, Isopropanol, Propylenglykol, Glycerin, Ethylenglykol, Ethylenglykolmonoethyl- oder -monobutylether, Propylenglykolmonomethyl, -monoethyl- oder -monobutylether, Diethylenglykolmonomethyl- oder -monoethylether und analoge Produkte, ferner Alkohole niedriger C-Zahl, z.B. Ethanol, Isopropanol, 1,2-Propandiol, 2-Methyl-1,3-propandiol, Glycerin sowie insbesondere ein oder mehrere Verdickungsmittel, welches oder welche vorteilhaft gewählt werden können aus der Gruppe Siliciumdioxid, Aluminiumsilikate, Polysaccharide bzw. deren Derivate, z.B. Hyaluronsäure, Xanthangummi, Hydroxypropylmethylcellulose.The aqueous phase of the preparations according to the invention optionally contains advantageous Alcohols, diols or polyols of low C number, and their ethers, preferably ethanol, isopropanol, Propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether, Propylene glycol monomethyl, monoethyl or monobutyl ether, diethylene glycol monomethyl or monoethyl ethers and analogous products, furthermore lower C number alcohols, e.g. Ethanol, isopropanol, 1,2-propanediol, 2-methyl-1,3-propanediol, glycerol and in particular one or more thickening agents, which or which can be chosen advantageously from the group silicon dioxide, aluminum silicates, polysaccharides or their derivatives, e.g. Hyaluronic acid, xanthan gum, hydroxypropylmethylcellulose.

Die erfindungsgemäßen kosmetischen und dermatologischen Zubereitungen können kosmetische Hilfsstoffe enthalten, wie sie üblicherweise in solchen Zubereitungen verwendet werden, z.B. Konservierungsmittel, Bakterizide, Parfume, UV -Lichtschutzfilter, hautbleichende Mittel, Substanzen zum Verhindern des Schäumens, Farbstoffe, Pigmente, die eine färbende Wirkung haben, Verdickungsmittel, oberflächenaktive Substanzen, Emulgatoren, weichmachende, anfeuchtende und/oder feucht haltende Substanzen, Fette, Öle, Wachse oder andere übliche Bestandteile einer kosmetischen oder dermatologischen Formulierung wie Alkohole, Polyole, Polymere, Schaumstabilisatoren, Elektrolyte, organische Lösemittel oder Silikonderivate.The cosmetic and dermatological preparations according to the invention can be cosmetic Contain excipients as commonly used in such preparations, e.g. Preservatives, bactericides, perfumes, UV light filters, skin bleaching agents, Foaming inhibitors, dyes, pigments containing a coloring matter Have thickening agents, surface-active substances, emulsifiers, softening, moisturizing and / or moisturizing substances, fats, oils, waxes or others usual constituents of a cosmetic or dermatological formulation such as alcohols, Polyols, polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.

Insbesondere können erfindungsgemäß verwendete Wirkstoffkombinationen auch mit anderen Antioxidantien und/oder Radikalfängern kombiniert werden.In particular, active compound combinations used according to the invention can also be used with others Antioxidants and / or radical scavengers are combined.

Vorteilhaft werden solche Antioxidantien gewählt aus der Gruppe bestehend aus Aminosäuren (z.B. Glycin, Histidin, Tyrosin, Tryptophan) und deren Derivate, Imidazole (z.B. Urocaninsäure) und deren Derivate, Peptide wie D,L-Carnosin, D-Carnosin, L-Carnosin und deren Derivate (z.B. Anserin), Carotinoide, Carotine (z.B. α-Carotin, β-Carotin, Lycopin) und deren Derivate, Chlorogensäure und deren Derivate, Liponsäure und deren Derivate (z.B. Dihydroliponsäure), Aurothioglucose, Propylthiouracil und andere Thiole (z.B. Thioredoxin, Glutathion, Cystein, Cystin, Cystamin und deren Glycosyl-, N-Acetyl-, Methyl-, Ethyl-, Propyl-, Amyl-, Butyl- und Lauryl-, Palmitoyl-, Oleyl-, γ-Linoleyl-, Cholesteryl- und Glycerylester) sowie deren Salze, Dilaurylthiodipropionat, Distearylthiodipropionat, Thiodipropionsäure und deren Derivate (Ester, Ether, Peptide, Lipide, Nukleotide, Nukleoside und Salze) sowie Sulfoximinverbindungen (z.B. Buthioninsulfoximine, Homocysteinsulfoximin, Buthioninsulfone, Penta-, Hexa-, Heptathioninsulfoximin) in sehr geringen verträglichen Dosierungen (z.B. pmol bis µmol/kg), ferner (Metall)-Chelatoren (z.B. α-Hydroxyfettsäuren, Palmitinsäure, Phytinsäure, Phytin, Lactoferrin), α-Hydroxysäuren (z.B. Citronensäure, Milchsäure, Apfelsäure), Huminsäure, Gallensäure, Gallenextrakte, Bilirubin, Biliverdin, EDTA, EGTA und deren Derivate, ungesättigte Fettsäuren und deren Derivate (z.B. γ-Linolensäure, Linolsäure, Ölsäure), Folsäure und deren Derivate, Ubichinon und Ubichinol und deren Derivate, Tocopherole und Derivate (z.B. Vitamin-E-acetat), Vitamin A und Derivate (Vitamin-A-palmitat) sowie Koniferylbenzoat des Benzoeharzes, Rutinsäure und deren Derivate, Butylhydroxytoluol, Butylhydroxyanisol, Nordihydroguajakharzsäure, Nordihydroguajaretsäure, Trihydroxybutyrophenon, Harnsäure und deren Derivate, Mannose und deren Derivate, Sesamol, Sesamolin, Zink und dessen Derivate (z.B. ZnO, ZnSO4) Selen und dessen Derivate (z.B. Selenmethionin), Stilbene und deren Derivate (z.B. Stilbenoxid, Trans-Stilbenoxid) und die erfindungsgemäß geeigneten Derivate (Salze, Ester, Ether, Zucker, Nukleotide, Nukleoside, Peptide und Lipide) dieser genannten Wirkstoffe.Advantageously, such antioxidants are selected from the group consisting of amino acids (eg glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (eg urocanic acid) and their derivatives, peptides such as D, L-carnosine, D-carnosine, L-carnosine and their derivatives (eg anserine), carotenoids, carotenes (eg α-carotene, β-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (eg dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (eg thioredoxin, Glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, γ-linoleyl, cholesteryl and glyceryl esters ) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and derivatives thereof (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and sulfoximine compounds (eg buthionine sulfoximines, homocysteinesulfoximine, buthionine sulfones, penta, hexa). , Heptathioninsulfoximin) in very low tolerated dosages (eg pmol to μmol / kg), furthermore (metal) chelators (eg α-hydroxy fatty acids, palmitic acid, phytic acid, phytin, lactoferrin), α-hydroxy acids (eg citric acid, lactic acid, malic acid), Humic acid, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (eg γ-linolenic acid, linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, tocopherols and derivatives (eg Vitamin E acetate), vitamin A and derivatives (vitamin A palmitate) and benzylic resin, benzylic acid, rutinic acid and its derivatives, butylhydroxytoluene, butylated hydroxyanisole, nordihydroguaiacetic acid, nordihydroguiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, sesamol, Sesamolin, zinc and its derivatives (eg ZnO, ZnSO 4 ) selenium and its derivatives (eg selenium methionine), stilbenes and their D derivatives (eg stilbene oxide, trans-stilbene oxide) and the derivatives which are suitable according to the invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) of these active substances mentioned.

Die Menge der vorgenannten Antioxidantien (eine oder mehrere Verbindungen) in den Zubereitungen beträgt vorzugsweise 0,001 bis 30 Gew.-%, besonders bevorzugt 0,05 - 20 Gew.-%, insbesondere 1 - 10 Gew.-%, bezogen auf das Gesamtgewicht der Zubereitung.The amount of the aforementioned antioxidants (one or more compounds) in the preparations is preferably from 0.001 to 30% by weight, particularly preferably from 0.05 to 20% by weight, in particular 1-10% by weight, based on the total weight of the preparation.

Sofern Vitamin E und/oder dessen Derivate das oder die zusätzlichen Antioxidantien darstellen, ist vorteilhaft, deren jeweilige Konzentrationen aus dem Bereich von 0,001 - 10 Gew.-%, bezogen auf das Gesamtgewicht der Formulierung, zu wählen.If vitamin E and / or its derivatives are the additional antioxidant (s), is advantageous, their respective concentrations in the range of 0.001 to 10 wt .-%, based on the total weight of the formulation to choose.

Sofern Vitamin A, bzw. Vitamin-A-Derivate, bzw. Carotine bzw. deren Derivate das oder die zusätzlichen Antioxidantien darstellen, ist vorteilhaft, deren jeweilige Konzentrationen aus dem Bereich von 0,001 - 10 Gew.-%, bezogen auf das Gesamtgewicht der Formulierung, zu wählen.If vitamin A, or vitamin A derivatives, or carotenes or their derivatives, the one or more represent additional antioxidants is advantageous, their respective concentrations from the Range from 0.001 to 10% by weight, based on the total weight of the formulation.

Auch Niacinamid und/oder Panthenol können erfindungsgemäß vorteilhaft in den Zubereitungen eingesetzt werden.Niacinamide and / or panthenol can also be used according to the invention in the preparations be used.

Erfindungsgemäße Zubereitungen können auch Wirkstoffe enthalten, die die Durchblutung der Haut anregen und/oder vasodilatorisch wirken, vorteilhaft sind Coffein, B-Vitamine (Pyridoxin und Nikotinsäure und ihre Derivate), Campher, Capsaicin.Compositions according to the invention may also contain active substances which increase the blood flow of the Stimulate the skin and / or have a vasodilatory effect, advantageous are caffeine, B vitamins (pyridoxine and nicotinic acid and its derivatives), camphor, capsaicin.

Darüber hinaus eignen sich ausgewählte erfindungsgemäße Rezepturen, welche z. B. bekannte Antifaltenwirkstoffe wie Flavonglycoside (insbesondere α-Glycosylrutin), Coenzym Q10, Vitamin E und/oder Derivate und dergleichen enthalten, insbesondere vorteilhaft zur Prophylaxe und Behandlung kosmetischer oder dermatologischer Hautveränderungen, wie sie z. B. bei der Hautalterung (z.B. Falten und Fältchen) auftreten. In addition, selected formulations of the invention are suitable which z. B. known Anti-wrinkle agents such as flavone glycosides (especially α-glycosyl rutin), coenzyme Q10, vitamin E and / or derivatives and the like, in particular advantageous for Prophylaxis and treatment of cosmetic or dermatological lesions such as they z. In skin aging (e.g., wrinkles and wrinkles).

Sofern α-Glycosylrutin das Antioxidants darstellt, ist vorteilhaft, deren jeweilige Konzentrationen aus dem Bereich von 0,001 - 5 Gew.-%, bezogen auf das Gesamtgewicht der Formulierung, zu wählen.If α-glycosylrutin is the antioxidant, it is advantageous whose respective concentrations from the range of 0.001-5% by weight, based on the total weight of the formulation, to choose.

In die erfindungsgemäßen Zubereitungen können aber auch andere pharmazeutisch oder dermatologisch wirkende Substanzen wie beispielsweise die Haut beruhigende und pflegende Substanzen eingearbeitet sein. Hierzu zählen beispielsweise Panthenol, Allantoin, Tannin, Antihistaminika, Antiphlogistika, Glucocorticoide (z.B. Hydrocortison) sowie Pflanzenwirkstoffe wie Azulen und Bisabolol, Glycyrrhizin, Hamamelin und Pflanzenextrakte wie Kamille, aloe vera, Hamazelis, Süßholzwurzel.In the preparations according to the invention, however, other pharmaceutical or Dermatologically active substances such as skin soothing and nourishing Be incorporated substances. These include, for example, panthenol, allantoin, Tannin, antihistamines, antiphlogistics, glucocorticoids (e.g., hydrocortisone), and plant agents such as azulene and bisabolol, glycyrrhizin, hamamelin and plant extracts such as Chamomile, aloe vera, Hamazelis, licorice root.

Als Moisturizer werden Stoffe oder Stoffgemische bezeichnet, welche kosmetischen oder dermatologischen Zubereitungen die Eigenschaft verleihen, nach dem Auftragen bzw. Verteilen auf der Hautoberfläche die Feuchtigkeitsabgabe der Hornschicht (auch transepidermal water loss (TEWL) genannt) zu reduzieren und/oder die Hydratation der Hornschicht positiv zu beeinflussen.Moisturizers substances or mixtures of substances which impart to cosmetic or dermatological preparations the property, after the application or distribution on the skin surface, the release of moisture in the horny layer (also called t rans e pidermal w ater l oss (TEWL)) to reduce and / or to positively influence the hydration of the horny layer.

Vorteilhafte Moisturizer im Sinne der vorliegenden Erfindung sind beispielsweise Glycerin, Milchsäure und/oder Lactate, insbesondere Natriumlactat, Butylenglykol, Propylenglykol, Biosaccaride Gum-1, Glycine Soja, Ethylhexyloxyglycerin, Pyrrolidoncarbonsäure und Harnstoff. Ferner ist es insbesondere von Vorteil, polymere Moisturizer aus der Gruppe der wasserlöslichen und/oder in Wasser quellbaren und/oder mit Hilfe von Wasser gelierbaren Polysaccharide zu verwenden. Insbesondere vorteilhaft sind beispielsweise Hyaluronsäure, Chitosan und/oder ein fucosereiches Polysaccharid, welches in den Chemical Abstracts unter der Registraturnummer 178463-23-5 abgelegt und z. B. unter der Bezeichnung Fucogel®1000 von der Gesellschaft SOLABIA S.A. erhältlich ist. Moisturizer können vorteilhaft auch als Antifaltenwirkstoffe zur Prophylaxe und Behandlung kosmetischer oder dermatologischer Hautveränderungen, wie sie z. B. bei der Hautalterung auftreten, verwendet werden.Advantageous moisturizers for the purposes of the present invention are, for example, glycerol, Lactic acid and / or lactates, in particular sodium lactate, butylene glycol, propylene glycol, Biosaccaride gum-1, glycine soy, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid and urea. Furthermore, it is particularly advantageous to use polymeric moisturizers from the group of water-soluble ones and / or water-swellable and / or water-gellable polysaccharides to use. Hyaluronic acid, for example, is particularly advantageous. Chitosan and / or a fucose-rich polysaccharide, which in the Chemical Abstracts under the registry number 178463-23-5 filed and z. B. under the name Fucogel®1000 from the company SOLABIA S.A. is available. Moisturizers can be beneficial also as anti-wrinkle active ingredients for the prophylaxis and treatment of cosmetic or dermatological Skin changes, such as B. occur during skin aging, can be used.

Erfindungsgemäß besonders bevorzugt werden die folgenden Moisturizer eingesetzt:
Glycerin, Sorbitol, Harnstoff und Panthenol.
The following moisturizers are particularly preferably used according to the invention:
Glycerin, sorbitol, urea and panthenol.

Dabei ist es erfindungsgemäß vorteilhaft ein oder mehrere Moisturizer in einer Gesamtkonzentration von 1 bis 25 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung, in der Emulsion einzusetzen.It is advantageous according to the invention one or more moisturizers in a total concentration from 1 to 25% by weight, based on the total weight of the preparation, in the Use emulsion.

Die erfindungsgemäßen kosmetischen oder dermatologischen Emulsionen können ferner vorteilhaft, wenngleich nicht zwingend, Füllstoffe enthalten, welche z. B. die sensorischen und kosmetischen Eigenschaften der Formulierungen weiter verbessern und beispielsweise ein samtiges oder seidiges Hautgefühl hervorrufen oder verstärken. Vorteilhafte Füllstoffe im Sinne der vorliegenden Erfindung sind Stärke und Stärkederivate (wie z. B. Tapiocastärke, Distärkephosphat, Aluminium- bzw. Natrium-Stärke Octenylsuccinat und dergleichen), Pigmente, die weder hauptsächlich UV-Filter- noch färbende Wirkung haben (wie z. B. Bornitrid etc.) und/oder Aerosile® (CAS-Nr. 7631-86-9).The cosmetic or dermatological emulsions according to the invention can furthermore advantageous, although not mandatory to contain fillers which z. B. the sensory and further improve cosmetic properties of the formulations and, for example create or strengthen a velvety or silky skin feeling. Advantageous fillers in For the purposes of the present invention, starch and starch derivatives (such as, for example, tapioca starch, Distarch phosphate, aluminum or sodium starch, octenylsuccinate and the like), Pigments which have neither primary UV filter nor coloring action (such as boron nitride etc.) and / or Aerosile® (CAS No. 7631-86-9).

Die erfindungsgemäßen Emulsionen können erfindungsgemäß vorteilhaft als Salbe, Creme oder Lotion eingesetzt werden. Auch ist ihr Einsatz in Form eines Sprays, z.B. eines Pumpsprays erfindungsgemäß vorteilhaft, wobei die Zubereitungen vorteilhafterweise auch aufgeschäumt werden können. Nicht zuletzt können sie erfindungsgemäß vorteilhaft zur Tränkung eines Substrates (z.B. ein Tuch aus Vlies) eingesetzt werden.The emulsions according to the invention can advantageously be used according to the invention as an ointment, cream or lotion. Also, their use is in the form of a spray, e.g. a pump spray According to the invention advantageous, wherein the preparations advantageously also foamed can be. Not least, they can according to the invention advantageous for impregnation of a substrate (e.g., a nonwoven cloth).

Die nachfolgenden Beispiele sollen die vorliegende Erfindung verdeutlichen, ohne sie einzuschränken. Alle Mengenangaben, Anteile und Prozentanteile sind, soweit nicht anders angegeben, auf das Gewicht und die Gesamtmenge bzw. auf das Gesamtgewicht der Zubereitungen bezogen. The following examples are intended to illustrate the present invention without limiting it. All quantities, proportions and percentages are, unless stated otherwise, on the weight and the total amount or on the total weight of the preparations based.

BeispieleExamples

W/O-EmulsionenW / O emulsions, 11 22 33 44 55 TriglycerindiisostearatTriglycerindiisostearat 1,01.0 0,50.5 1,41.4 2,02.0 3,03.0 PEG-40 PerisostearatPEG-40 perisostearate 1,01.0 1,51.5 1,751.75 3,03.0 2,02.0 Isopropylpalmitatisopropyl palmitate ------ 3,03.0 3,03.0 5,05.0 ------ Paraffinölparaffin oil 12,512.5 10,010.0 8,58.5 5,05.0 1,51.5 Vaselinevaseline 8,08.0 6,06.0 3,03.0 12,012.0 2,52.5 Silikonöl (Cyclomethicon)Silicone oil (cyclomethicone) 2,02.0 1,01.0 3,03.0 5,05.0 0,250.25 Isohexadekanisohexadecane 0,50.5 0,750.75 3,03.0 2,02.0 0,250.25 Octyldodecanoloctyldodecanol 0,50.5 1,01.0 0,750.75 3,03.0 0,250.25 Aluminiumstearataluminum stearate 0,40.4 0,30.3 0,60.6 1,01.0 0,050.05 Dicaprylylcarbonatdicaprylyl 0,10.1 0,050.05 0,150.15 0,50.5 1,01.0 Vitamin E AcetatVitamin E acetate 0,50.5 0,750.75 0,50.5 2,52.5 0,50.5 Kakaobuttercocoa butter 0,50.5 1,01.0 0,50.5 2,52.5 2525 Sheabuttershea butter 0,50.5 1,01.0 0,50.5 0,250.25 2,52.5 Magnesiumsulfatmagnesium sulfate 0,50.5 0,60.6 0,60.6 0,70.7 1,01.0 Glyceringlycerin 3,03.0 5,05.0 5,05.0 15,015.0 1,51.5 Milchsäurelactic acid 0,20.2 0,10.1 0,70.7 0,30.3 1,01.0 Zitronensäurecitric acid 0,10.1 0,250.25 0,050.05 0,10.1 0,20.2 Natriumlactatsodium lactate 0,20.2 0.0500:05 1,51.5 0.30.3 2,02.0 ParfumPerfume q,s,q, s, q,s,q, s, q,s,q, s, q,s,q, s, q,s,q, s, Capryl-/CaprinsäuretriglyceridCaprylic / capric 2,02.0 2,52.5 ------ 5,05.0 ------ Kaliumsorbatpotassium sorbate 0,040.04 0,150.15 0,050.05 0,030.03 0,40.4 Wollwachslanolin 0,30.3 0,40.4 0,10.1 0,150.15 ------ Talkumtalc ------ ------ 0,10.1 1,01.0 0,10.1 Wasserwater ad 100ad 100 ad 100ad 100 ad 100ad 100 ad 100ad 100 ad 100ad 100 W/O-EmulsionenW / O emulsions, 66 77 88th 99 1010 PEG-30 DipolyhydroxystearatPEG-30 dipolyhydroxystearate ------ 0,50.5 0,250.25 ------ 3,03.0 Lanolin AlcoholLanolin Alcohol 1,01.0 1,51.5 1,751.75 3,03.0 --- Paraffinölparaffin oil 12,512.5 10,010.0 8,08.0 5,05.0 1,51.5 Vaselinevaseline 8,08.0 6,06.0 5,05.0 12,012.0 2,52.5 hydrierte Kokosglyceridehydrogenated coconut glycerides 2,02.0 1,01.0 2,52.5 5,05.0 0,250.25 Hydriertes PolyisobutenHydrogenated polyisobutene 0,50.5 0,750.75 1,01.0 2,02.0 0,250.25 Octyldodecanoloctyldodecanol 0,50.5 1,01.0 0,750.75 3,03.0 0,250.25 Aluminiumstearataluminum stearate 0,40.4 0,30.3 0,60.6 1,01.0 0,050.05 Dicaprylylcarbonatdicaprylyl 0,10.1 0,050.05 0,150.15 0,50.5 1,01.0 hydriertes Rizinusölhydrogenated castor oil 0,50.5 0,750.75 1,01.0 2,52.5 5,05.0 Kakaobuttercocoa butter 0,50.5 1,01.0 5,05.0 2,52.5 2525 Sheabuttershea butter 0,50.5 1,01.0 5,05.0 0,250.25 2,52.5 Microcrystalline CelluloseMicrocrystalline cellulose 0,50.5 1,01.0 0,750.75 0,250.25 0,10.1 Magnesiumsulfatmagnesium sulfate 0,50.5 0,60.6 0,50.5 0,70.7 1,01.0 Glyceringlycerin 3,03.0 5,05.0 10,010.0 15,015.0 1,51.5 Zitronensäurecitric acid 0,20.2 0,10.1 0,20.2 0,30.3 1,01.0 ParfumPerfume q,s,q, s, q,s,q, s, q,s,q, s, q,s,q, s, q,s,q, s, 1,3 Butylenglykol1,3 butylene glycol 2,02.0 ------ 5,05.0 ------ ------ Capryl-/CaprinsäuretriglyceridCaprylic / capric 2,02.0 2,52.5 3,03.0 5,05.0 0,50.5 NatriumdehydracetNatriumdehydracet ------ ------ 0,050.05 ------ ------ Kaliumsorbatpotassium sorbate 0,30.3 0,40.4 0,250.25 0,150.15 ------ Talkumtalc ------ ------ 0,050.05 ------ 0,10.1 Wasserwater ad 100ad 100 ad 100ad 100 ad 100ad 100 ad 100ad 100 ad 100ad 100 W/S-EmulsionW / S-emulsion 1111 1212 1313 1414 1515 Cetyl PEG/PPG-10/1 DimethiconeCetyl PEG / PPG-10/1 dimethicone 1,01.0 ------ --- 3,03.0 5,05.0 Cylomethicon + PEG/PPG-18/18 Dimethicon (90:10)Cylomethicone + PEG / PPG-18/18 dimethicone (90:10) 10,010.0 12,512.5 2525 --- --- Cyclomethiconcyclomethicone 12,512.5 1515 28,028.0 25,025.0 7,57.5 Dimethicondimethicone 5,05.0 13,013.0 5,05.0 12,012.0 5,05.0 hydriertes Polyisobutenhydrogenated polyisobutene 0,50.5 0,750.75 1,01.0 2,02.0 0,250.25 Octyldodecanoloctyldodecanol 0,50.5 1,01.0 0,750.75 3,03.0 0,250.25 Panthenolpanthenol 0,50.5 1,01.0 0,750.75 0,250.25 0,10.1 Natriumchloridsodium chloride 2,02.0 0,60.6 2,52.5 0,70.7 1,01.0 Kakaobuttercocoa butter 0,50.5 1,01.0 5,05.0 2,52.5 2525 Sheabuttershea butter 0,50.5 1,01.0 5,05.0 0,250.25 2,52.5 Glyceringlycerin 3,03.0 5,05.0 10,010.0 15,015.0 1,51.5 Zitronensäurecitric acid 0,20.2 0,10.1 0,20.2 0,30.3 1,01.0 Natriumcitratsodium citrate 1,01.0 0,10.1 0,40.4 0,90.9 2,52.5 ParfumPerfume q,s,q, s, q,s,q, s, q,s,q, s, q,s,q, s, q,s,q, s, Kaliumsorbatpotassium sorbate 0,40.4 0,10.1 0,050.05 0,30.3 0,40.4 Microcrystalline CelluloseMicrocrystalline cellulose 1,01.0 0,10.1 0,50.5 0,250.25 0,10.1 Cetyldimethiconcetyidimethicone 0,50.5 ------ 0,70.7 ------ ------ Benzylalkoholbenzyl alcohol ------ ------ 0,050.05 ------ 0,10.1 modifizierte Stärkemodified starch ------ 2,52.5 ------ 0,150.15 --- Wasserwater ad 100ad 100 ad 100ad 100 ad 100ad 100 ad 100ad 100 ad 100ad 100 W/S-EmulsionenW / S emulsions 1616 1717 1818 1919 2020 Cetyl PEG/PPG-10/1 DimethiconeCetyl PEG / PPG-10/1 dimethicone 1,01.0 ------ --- 3,03.0 5,05.0 Cylomethicon + PEG/PPG-18/18 Dimethicon (90:10)Cylomethicone + PEG / PPG-18/18 dimethicone (90:10) 10,010.0 12,512.5 2525 --- --- Cyclomethiconcyclomethicone 12,512.5 1515 28,028.0 25,025.0 7,57.5 Dimethicondimethicone 5,05.0 13,013.0 5,05.0 12,012.0 5,05.0 hydriertes Polyisobutenhydrogenated polyisobutene 0,50.5 0,750.75 1,01.0 2,02.0 0,250.25 Octyldodecanoloctyldodecanol 0,50.5 1,01.0 0,750.75 3,03.0 0,250.25 Kakaobuttercocoa butter 0,50.5 1,01.0 5,05.0 2,52.5 2525 Sheabuttershea butter 0,50.5 1,01.0 5,05.0 0,250.25 2,52.5 Panthenolpanthenol 0,50.5 1,01.0 0,750.75 0,250.25 0,10.1 Natriumchloridsodium chloride 2,02.0 0,60.6 2,52.5 0,70.7 1,01.0 Glyceringlycerin 3,03.0 5,05.0 10,010.0 15,015.0 1,51.5 Milchsäurelactic acid 0,20.2 0,10.1 0,20.2 ------ ------ Natriumlactatsodium lactate 0,20.2 1,01.0 0.0500:05 ------ ------ ParfumPerfume q,s,q, s, q,s,q, s, q,s,q, s, q,s,q, s, q,s,q, s, Microcrystalline CelluloseMicrocrystalline cellulose 1,01.0 0,10.1 1,51.5 2,52.5 0,10.1 Kaliumsorbatpotassium sorbate 0,30.3 0,40.4 0,250.25 0,150.15 ------ Stearyldimethiconstearyl 0,50.5 ------ 0,70.7 ------ ------ Dehydracetsäuredehydroacetic ------ ------ 0,050.05 ------ 0,10.1 modifizierte Stärkemodified starch ------ 2,52.5 ------ 0,150.15 --- Wasserwater ad 100ad 100 ad 100ad 100 ad 100ad 100 ad 100ad 100 ad 100ad 100 W/O-EmulsionenW / O emulsions, 2121 2222 2323 2424 2525 PEG-22 Dodecyl Glycol CopolymerPEG-22 dodecyl glycol copolymer 5,05.0 1,51.5 0,250.25 ------ 3,03.0 PEG-45 Dodecyl Glycol PolymerPEG-45 dodecyl glycol polymer 1,01.0 1,51.5 1,751.75 3,03.0 --- Paraffinölparaffin oil 12,512.5 10,010.0 8,08.0 5,05.0 7,57.5 lsopropylstearatlsopropylstearat 8,08.0 6,06.0 5,05.0 12,012.0 2,52.5 hydrierte Kokosglyceridehydrogenated coconut glycerides 2,02.0 1,01.0 2,52.5 5,05.0 0,250.25 NachtkerzenölEvening primrose oil 0,50.5 0,750.75 1,01.0 2,02.0 0,250.25 Octyldodecanoloctyldodecanol 0,50.5 1,01.0 0,750.75 3,03.0 0,250.25 Aluminiumstearataluminum stearate 0,40.4 0,30.3 0,60.6 1,01.0 0,050.05 Kakaobuttercocoa butter 0,50.5 1,01.0 5,05.0 2,52.5 2525 Sheabuttershea butter 0,50.5 1,01.0 5,05.0 0,250.25 2,52.5 Dicaprylylcarbonatdicaprylyl 0,10.1 0,050.05 0,150.15 0,50.5 1,01.0 hydriertes Rizinusölhydrogenated castor oil 0,50.5 0,750.75 1,01.0 2,52.5 5,05.0 Microcrystalline CelluloseMicrocrystalline cellulose 0,50.5 1,01.0 0,750.75 0,250.25 0,10.1 Magnesiumsulfatmagnesium sulfate 0,50.5 0,60.6 0,50.5 0,70.7 1,01.0 Glyceringlycerin 3,03.0 5,05.0 10,010.0 15,015.0 1,51.5 Natriumcitratsodium citrate 0,20.2 0,10.1 ------ ------ ------ Zitronensäurecitric acid 0,20.2 0,10.1 ------ ------ ------ ParfumPerfume q,s,q, s, q,s,q, s, q,s,q, s, q,s,q, s, q,s,q, s, 1,3 Butylenglykol1,3 butylene glycol 2,02.0 ------ 5,05.0 ------ ------ Capryl-/CaprinsäuretriglyceridCaprylic / capric 2,02.0 2,52.5 3,03.0 5,05.0 0,50.5 Kaliumsorbatpotassium sorbate 0,40.4 0,150.15 0,050.05 0,30.3 0,40.4 Talkumtalc 0,30.3 0,40.4 0,250.25 0,150.15 ------ Benzylalkoholbenzyl alcohol ------ ------ 0,050.05 ------ 0,10.1 Wasserwater ad 100ad 100 ad 100ad 100 ad 100ad 100 ad 100ad 100 ad 100ad 100 W/O-EmulsionenW / O emulsions, 2626 2727 2828 2929 3030 DiglycerindipolyhydroxystearatDiglycerindipolyhydroxystearat 3,03.0 ------ 0,250.25 ------ 3,03.0 TriglycerindiisostearateTriglycerindiisostearate 1,01.0 3,53.5 1,751.75 2,52.5 --- PEG-40 sorbitanisostearatePEG-40 sorbitan isostearate ------ 2,52.5 0,50.5 3,53.5 3,03.0 Paraffinölparaffin oil 12,512.5 10,010.0 8,08.0 5,05.0 7,57.5 lsopropylstearatlsopropylstearat 8,08.0 6,06.0 5,05.0 12,012.0 2,52.5 Kakaobuttercocoa butter 0,50.5 1,01.0 5,05.0 2,52.5 2525 Sheabuttershea butter 0,50.5 1,01.0 5,05.0 0,250.25 2,52.5 hydrierte Kokosglyceridehydrogenated coconut glycerides 2,02.0 1,01.0 2,52.5 5,05.0 0,250.25 Isopropylpalmitatisopropyl palmitate 0,50.5 1,01.0 0,750.75 3,03.0 0,250.25 Dicaprylylcarbonatdicaprylyl 0,10.1 0,050.05 0,150.15 0,50.5 1,01.0 hydriertes Rizinusölhydrogenated castor oil 0,50.5 0,750.75 1,01.0 2,52.5 5,05.0 Microcrystalline CelluloseMicrocrystalline cellulose 0,50.5 1,01.0 0,750.75 0,250.25 0,10.1 Magnesiumsulfatmagnesium sulfate 0,50.5 0,60.6 0,50.5 0,70.7 1,01.0 Glyceringlycerin 3,03.0 5,05.0 10,010.0 15,015.0 1,51.5 Zitronensäurecitric acid 0,20.2 0,10.1 0,10.1 0,30.3 1,01.0 Natriumcitratsodium citrate 0,20.2 0,30.3 0,20.2 1,51.5 0.80.8 ParfumPerfume q,s,q, s, q,s,q, s, q,s,q, s, q,s,q, s, q,s,q, s, Capryl-/CaprinsäuretriglyceridCaprylic / capric 2,02.0 2,52.5 3,03.0 5,05.0 0,50.5 Kaliumsorbatpotassium sorbate 0,240.24 0,150.15 0,050.05 0,30.3 0,40.4 Talkumtalc ------ ------ 0,50.5 ------ 0,10.1 Wasserwater ad 100ad 100 ad 100ad 100 ad 100ad 100 ad 100ad 100 ad 100ad 100

Claims (10)

Kosmetische und/oder dermatologische Wasser-in-Öl-Emulsion enthaltend eine Lipidkombination aus Sheabutter und Kakaobutter.Cosmetic and / or dermatological water-in-oil emulsion containing a Lipid combination of shea butter and cocoa butter. Verwendung einer Lipidkombination aus Sheabutter und Kakaobutter zur Prophylaxe, Behandlung und Pflege von trockener und/oder rissiger Haut, insbesondere von stark pigmentierter trockener und/oder rissiger Haut.Use of a lipid combination of shea butter and cocoa butter for prophylaxis, Treatment and care of dry and / or chapped skin, in particular of strong pigmented dry and / or chapped skin. Verwendung einer W/O-Emulsion enthaltend eine Lipidkombination aus Sheabutter und Kakaobutter, zur Prophylaxe, Behandlung und Pflege von trockener und/oder rissiger Haut, insbesondere von trockener und/oder rissiger stark pigmentierter Haut.Use of a W / O emulsion containing a lipid combination of shea butter and cocoa butter, for the prophylaxis, treatment and care of dry and / or cracked Skin, in particular dry and / or chapped, strongly pigmented skin. Verwendung einer Lipidkombination aus Sheabutter und Kakaobutter zur Prophylaxe, Behandlung und Pflege des Phänomens der aschenfarbenen Haut bei Menschen mit stark pigmentierter Haut.Use of a lipid combination of shea butter and cocoa butter for prophylaxis, Treatment and care of the phenomenon of ash-colored skin in humans with heavily pigmented skin. Verwendung einer W/O-Emulsion enthaltend eine Lipidkombination aus Sheabutter und Kakaobutter zur Prophylaxe, Behandlung und Pflege des Phänomens der aschenfarbenen Haut bei Menschen mit stark pigmentierter Haut.Use of a W / O emulsion containing a lipid combination of shea butter and cocoa butter for the prophylaxis, treatment and care of the phenomenon of ash-colored skin in people with heavily pigmented skin. Wasser-in-Öl-Emulsion nach Anspruch 1 oder Verwendung nach einem der Ansprüche 2 bis 5, dadurch gekennzeichnet, dass sie Sheabutter in einer Menge von 0,1 bis 30 Gewichts-%, bezogen auf das Gesamtgewicht der Emulsion, enthält.A water-in-oil emulsion according to claim 1 or a use according to any one of claims 2 to 5, characterized in that it contains shea butter in an amount of from 0.1 to 30% by weight, based on the total weight of the emulsion. Wasser-in-Öl-Emulsion oder Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass sie Kakaobutter in einer Menge von 0,1 bis 30 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung, enthält.Water-in-oil emulsion or use according to one of the preceding claims, characterized in that it contains cocoa butter in an amount of 0.1 to 30% by weight, based on the total weight of the preparation. Wasser-in-Öl-Emulsion oder Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass das Gewichtsverhältnis von Sheabutter zu Kakaobutter in der Emulsion von 1 : 1 bis 1 : 10 beträgt.A water-in-oil emulsion or use according to any one of the preceding claims, characterized in that the weight ratio of shea butter to cocoa butter in the emulsion is from 1: 1 to 1:10. Wasser-in-Öl-Emulsion oder Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass als W/O-Emulgatoren eine oder mehrere Verbindungen gewählt aus der Gruppe Polyglycerinisostearate und ethoxylierte W/O-Emulgatoren eingesetzt werden.Water-in-oil emulsion or use according to one of the preceding claims, characterized in that as W / O emulsifiers one or more compounds selected from the group Polyglycerinisostearate and ethoxylated W / O emulsifiers are used. Wasser-in-Öl-Emulsion oder Verwendung nach Anspruch 9, dadurch gekennzeichnet, dass die W/O-Emulgatoren in einer Gesamtmenge von 0,1 bis 15 Gewichts-%, bezogen auf das Gesamtgewicht der Zubereitung, in der Emulsion vorhanden sind.A water-in-oil emulsion or use according to claim 9, characterized in that the W / O emulsifiers in a total amount of 0.1 to 15% by weight, based on the total weight of the preparation, are present in the emulsion.
EP05101706A 2004-03-18 2005-03-04 Combination of the lipids shea butter and cocoa butter for the treatment of ashen skin Withdrawn EP1576949A1 (en)

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