EP1567690A1

EP1567690A1 - Electrocoagulation system

Info

Publication number: EP1567690A1
Application number: EP03773334A
Authority: EP
Inventors: Cameron King
Original assignee: Aquenox Pty Ltd
Current assignee: Aquenox Pty Ltd
Priority date: 2002-11-19
Filing date: 2003-11-19
Publication date: 2005-08-31
Also published as: US20060096853A1; AU2002952743A0; WO2004046051A1; CN1745039A

Abstract

A control assembly for an electrocoagulation cell (1) comprising a plurality of electrodes, a releasable connection means (6) between at least a selection of the electrodes and electrical connection means (9, 10, 9A, 10A) attached to the releasable connection means (6) which in use is connectable to a power supply (12). An electrocoagulation system comprising a plurality of electrodes (2), an electrolytic cell (1) having an internal chamber which contains the plurality of electrodes (2), and a power supply (12) connectable to a power source and also connectable to the electrodes said power supply having control means (14, 24) for providing a selected constant output current or selected constant output voltage whereby the electrolytic cell may process samples of varying characteristics.

Description

ELECTROCOAGULATION SYSTEM

Technical field of the invention

This invention relates to an electrocoagulation system which an electrocoagulation cell includes as well as a control assembly for an electrocoagulation cell.

Background of the invention

Electrolytic cells are commonly used for treating liquids to change the liquid for a predetermined purpose. Electrocoagulation is a particular electrolytic treatment process for separating and removing contaminants or undesirable contents from a liquid.

Typically an electrocoagulation cell contains electrodes and an electrolyte that is to be treated. The treatment process may be performed in a number of ways depending on the nature of the electrolyte.

Numerous prior patents describe electrocoagulation systems of which AU 707432 describes an electrochemical treatment device for softening water. The device is powered by a current generator producing a current which is adjustable and applied to an anode and cathode terminal of an electrolytic tank. The cathode is comprised of a number of plates which are held in place by connection of a plurality of bars. The bars are joined together to an anode terminal. The plates are joined together by a separate bar to a cathode terminal.

Another prior system is described in AU 738707 where a portable electrocoagulation apparatus includes an electrolytic cell having a plurality of vertically extending reaction blades. A selection of the blades have tabs which are electrically connected to power terminals for receiving power. The blades are held in place by a plurality of non-conductive rods. A control unit controls the system operation and applied power. A further system is described in US 4790923, where an electrolytic cell produces a halogen biocide and oxygen in a liquid containing a halogen salt. A plurality of bipolar electrode plates is mounted in the cell with only a select number of electrodes being connectable to a power supply.

Yet another system is described in WO 94/00860 where an electrolytic filter has electrically configurable connections to active electrodes in an electrolytic cell. A sensor senses a resistivity variation in the electrolytic solution and a control circuit varies the current flow by adjusting the separation between electrodes using relay contact switches for electrically connecting or disconnecting each active electrode.

A major drawback of the above systems is they are designed for a specific electrolyte or liquid which is to be treated. The electrodes used, their quantity and desired power requirements are specific to the liquid being treated.

A further drawback of conventional electrocoagulation systems is the high cost associated with designing a system for each specific application. Substantial testing and modification is required where the liquid stream changes in its concentration of contaminants.

Object of the invention

It is an object of the invention to provide an improved electrocoagulation system.

It is a further object of the invention to provide an improved control assembly for an electrocoagulation cell that facilitates treatment of various liquids or species.

Summary of the invention

In one form, although it need not be the only or indeed the broadest form, the invention resides in a control assembly for an electrocoagulation cell comprising:

(i) a plurality of electrodes; (ii) releasable connection means between at least a selection of the electrodes; and

(iii) electrical connection means attached to the releasable connection means which in use is connectable to a power supply. The releasable connection means may facilitate the number of electrodes releasably connected to be varied according to specific requirements for treating a particular electrolyte.

The releasable connection means may include a busbar received in a slot, notch or aperture in each of said selection of the plurality of electrodes. The electrodes may be connected in a series arrangement.

The electrocoagulation cell can treat the electrolyte at a rate of 1 Litre per minute or 5 Litres per minute or 10 Litres per minute or 100 Litres per minute or 500 Litres per minute (LPM).

In another aspect of the invention there is provided an electrocoagulation system comprising: (i) a plurality of electrodes; (ii) an electrolytic cell having an internal chamber which contains the plurality of electrodes; and (iii) a power supply connectable to a power source and also connectable to the electrodes said power supply having control means for providing a selected constant output current or selected constant output voltage whereby the electrolytic cell may process samples of varying characteristics. In a first embodiment the control means may comprise a variac which may be connected to the electrocoagulation cell by a rectifier to provide the selected DC current or voltage of constant value. The variac may also be connected to another transformer if required. In this embodiment the power supply to the cell may also include a reverse polarity timer and a forward polarity timer. In a second embodiment there may be provided:

(i) an adjustable switch connectable to a power source; (ii) a voltage regulator connected to the switch;

(iii) a transformer having a primary coil connected to the voltage regulator; (iv) a rectifier connected to a secondary coil of the transformer and;

(v) said control means being connected between the switch and the voltage regulator to control a DC output applied to the electrolytic cell to have said selected constant current or said selected constant voltage. In the second embodiment the control means may comprise a voltage or current potentiometer or more preferably a digital potentiometer which allows for either of voltage or current to be maintained at a constant value.

The electrocoagulation system may also include a programmable logic control (PLC) for checking parameters associated with the flow of an electrolyte to and through the cell.

There also may be provided flow control means for delivering the electrolyte to the electrocoagulation cell.

In a preferred form of the invention, the flow control means includes a digital controller, variable AC motor drive, feed pump with pump motor and a flow transmitter.

The power supply may be connected to a three phase AC power source.

Preferably, the constant output current and the constant output voltage is a direct current (DC).

Preferably, if a constant output current is selected, then the DC current is maintained constant with respect to a reference set by the control means and the DC voltage may vary.

Preferably, if a constant output voltage is selected, then the DC voltage is maintained constant with respect to a reference set by the control means and the DC current may vary. The constant output current or voltage may be set at a level according to the type of electrolyte which is to be treated.

Brief description of the drawings FIG 1 is an illustrative embodiment of an electrocoagulation cell to which a power supply of the present invention is applied;

FIG 2 is a process flow diagram of the electrocoagulation system in accordance with the present invention;

FIGS 3a-3d are schematic illustrations showing a varied number of electrodes and electrode configurations that can be connected to a power supply, in accordance with the invention;

FIG 4 is a block diagram of a power supply in accordance with one embodiment of the present invention;

FIG 5 is a schematic diagram of a power supply in accordance with a second embodiment of the invention;

FIG 6 is a basic circuit diagram of the power supply shown in FIG 4; FIG 7 is a basic circuit diagram of a reversing relay control circuit associated with the power supply of FIG 4;

FIG 8 is a basic circuit diagram of control circuits associated with the power supply of FIG 4;

FIG 9 is a schematic diagram of a system start control of an electrocoagulation system using a power supply of the present invention; and FIG 10 is a treatment rate control schematic of an electrocoagulation system using a power supply of the present invention.

Detailed description of the preferred embodiment

In a preferred form, the invention will be described with reference to an electrocoagulation cell and system of the type described in the co- pending International Patent Application No. PCT/AU01/00054. However, it should be noted that the invention could also be realised with other types of electrocoagulation cells.

Referring now to FIG 1 , there is generally shown an electrocoagulation cell 1 comprising a plurality of electrodes 2, in the form of plates, which form the electrocoagulation cell. Plate extensions 3 and 4 abut the respective edges 2A of the electrodes 2 which form part of a housing 5 of the electrocoagulation cell 1. The extensions 3 and 4 prevent short-circuiting between the electrodes 2 of different potential. DC power to the electrocoagulation cell is applied to the two end electrodes as shown in FIG 1.

The electrocoagulation cell is used in fluid treatment plants for treatment and purification of a conductive solution such as might be produced by a manufacturing, treatment, refining or other process. Typically, a conductive solution is caused to flow between electrodes 2 at different electrical potentials. A current is caused to flow between the electrodes through the solution which results in a chemical reaction within the solution and in many cases, between the solution and the electrode material which comprises the electrode.

The electrodes 2 of the electrocoagulation cell 1 are made from metal alloys or other suitable metals and are shaped to fit into individual grooves (not shown) within the electrode housing 5. The electrodes are designed to provide sufficient reaction surface area to effectively treat an electrolyte solution such as water up to the maximum design rate of cell 1. Electrodes are unipolar (anodic or cathodic) or bipolar (anodic and cathodic). Bipolar electrodes have both surfaces of the electrode plate reacting with the electrolyte solution. One side is anodic, the other cathodic. Unipolar electrodes are either wholly anodic or wholly cathodic. Unipolar electrodes located at the ends of the reaction cell, (see FIG 3c), have only one surface of the electrode reacting with the electrolyte solution. Unipolar electrodes located between bipolar electrodes, (see FIG 3a), have both surfaces of the electrode reacting with the electrolyte solution.

Referring to FIG 2, in operation, once the material to be treated is determined and the nature of the electrocoagulation cell 1 is determined, that is, the type, number and the configuration of the electrodes, the operating parameters of the electrocoagulation system is checked by a Programmable Logic Controller (PLC). The required flow rate of electrolyte or liquid, such as 5 or 100 Litres per minute or any flow rate there between is determined. All switches and valves are checked so that they are opened or closed as required and there is no fault conditions detected in the system. When the operating parameters of the electrocoagulation system are satisfied, a power supply is adjusted in its voltage or current and applied to the system, according to the specific power requirements for a particular liquid or species to be treated in the electrocoagulation cell. The power is disengaged whenever any of the operating parameters are outside their operational range or when a user manually stops the electrocoagulation system by activating a stop switch.

Referring now to FIGs 3a-3d, there are shown electrode configurations for two different species or liquids to be treated. FIG 3a shows a releasable connection means 6 in the form of a busbar connection, for releasably connecting a selection of a plurality of electrodes 2 in the electrocoagulation cell. In this arrangement, there are twenty-five electrodes with nine electrodes connected by the busbars, for treating one particular species or liquid. Two busbars are used, one for each polarity. Each selected electrode 2 includes a slot 7 (shown in FIG 3b) for receiving a bar 8 to which is applied a power source via lead connections 9 and 10. Bar 8 is placed in slots 7 of each of the electrodes 2 in a series alignment and the bar is secured to the electrodes by securing means comprising a nut 11a and washer 11b. The connected electrodes are uni-polar and hence are either anionic or cationic depending on the polarity of the power applied through power leads 9 and 10 each of which have connectors 9A and 10A having apertures (not shown) retained by nuts 10B on each side of connectors 9A and 10A. The remaining sixteen unconnected electrodes are bi-polar and they are charged by the energised electrolytic solution.

Referring to FIG 3c, there is shown an electrode arrangement for treating a second species or liquid. In this configuration there are a total of eighteen electrodes of which two are connected by the busbars. Only two electrodes therefore are unipolar, being the end electrodes to which power is applied and the remaining are bipolar as shown in FIG 3d.

In the above arrangement of the busbar, the bar is threaded so that the securing nuts 11a can be threadably secured to the bar thereby bearing tight against the electrodes 2 to secure them to the bar 8. The bar may be made of a brass material which is resistant to rust and has good conductivity properties. However, other suitable material having these properties may used to secure and electrically connect the electrodes, such as steel. The washer 11b assists in the protection of the electrode against wear from the nut 11 a. The washer also increases the surface area of the current applied to the electrodes.

In operation, the bar 8 is placed in the slots 7 of adjacent electrodes 2 and the securing nuts 11a and washer 11b are secured against the electrodes to hold it in place. To replace an electrode, the securing nuts 11a are loosened so that they no longer bear tight against the electrode and the bar is simply lifted so that access can be gained to the electrodes as shown in FIGs 3a and 3b.

The electrocoagulation cell is designed to treat fluid such as water at various flow rates. In one embodiment of the invention, a power supply outputs the desired power requirements for treating the electrolyte solution at various flow rates.

Referring now to FIG 4, there is shown a power supply 12 for the electrocoagulation cell 1 of FIG 1. The power supply 12 can be used for treating an electrolyte solution at a maximum flow rate of five Litres per minute, 5LPM. The power supply 12 receives a single phase AC input 13 of 240v at 10amps (maximum). A variac 14 is adjusted by operation of control dial 14a to increase or decrease the voltage and current. The adjusted voltage and current are applied to a transformer 15 for stepping up or stepping down the voltage as may be required. For example, if the system is configured for a flow rate of five Litres per minute, 5LPM, a maximum output of 110v DC at 10 amps is required. However at 100LPM, a maximum output of 110v DC at 300 amps is required.

A rectifier 16 converts the AC voltage into a DC signal and the adjusted and rectified signal is displayed on a display 17 for viewing by an operator. Depending on the type of treatment required and the types of electrodes used, the output signal may be a DC signal with a negative polarity adjusted by a reverse polarity timer 18 or a positive output signal adjusted by aforward polarity timer 19. The output of the power supply 12 is then applied to the busbar and electrodes of the electrocoagulation cell 1. The variac of the power supply is rated at 15 amps with a maximum of 250v AC. If the power source is required for a 10LM electrocoagulation system, the variac is required to be rated at 28 amps due to the increased flow rate.

If the electrocoagulation system is operating at 10LM, then a maximum output of 110v DC at 28 amps is required to power the system. The power supply for the 10LM system is similar to the 5LM system except that is requires a larger variac rated at 28 amps and powered by 240v single phase AC input at 20 amps (maximum).

The power supply will now be described in more detail with reference to FIGs 5 to 8. Referring to FIG 5 there is shown a power supply for supplying DC power for the electrocoagulation cell 1 for operating at 100LP . It will be appreciated however, that the power supply can also be used with 1, 5, and 10LPM systems using single phase AC input.

The power supply in FIG 5 is fed with a three phase, AC input of 415v through lock 19. However, it will be understood that any suitable source of electrical power may be used. The input power is connected to an adjustable main switch 20, which may be, for example a Terasaki™ circuit breaker XS125CJ633P or a similar circuit breaker. The main switch 20 is connected to a voltage regulator 21 , which is preferably a three-phase SCR digital power controller such as that marketed by Fastron Technologies Pty Ltd. A phase controlled variable output from the voltage regulator 21 is supplied to a primary coil of a main transformer 22, the secondary of which is connected to a rectifier 23, such as a matched hexaphase back to back SCR module.

A voltage and a current potentiometer 24 (shown as one) connect between the main switch 20 and the voltage regulator 21 to control a DC output 25 to be either constant current or constant voltage. A voltage or current regulator 26 receives an output from the rectifier 23 and together with the potentiometer 24, effect the firing control 27 of the voltage regulator 21. In the present embodiment, the power supply has two distinct modes of operation that allow the user to maintain either constant output voltage or constant amperage. These values are set by the voltage or current potentiometer 24. When the current potentiometer is set for constant current, the voltage pot is rotated to "100%" which allows the power supply to float output voltage between 0 and a full rated DC voltage. The constant current pot can then be set to the desired output current depending on the type and consistency of the electrolyte being treated. As the load is increased or decreased, the amperage will remain at the set point while the voltage will vary. If the constant voltage pot is set at less than 100% output, the voltage will then be limited to this set point. In this case, if the set point is less than the required voltage to maintain a set current level, an automatic cross over to constant voltage will occur. Alternatively, to maintain constant voltage, the constant current pot can be rotated clockwise so that it is at 100% thereby allowing the power supply to float the output current between zero and full rated DC amperage.

As noted above, the constant voltage pot is set to the desired output voltage, such as 110v DC and as the load is increased or decreased, the voltage will remain at 110v DC while the DC amperage will vary. If however, the constant current pot is set at less than 100%, the output current will be limited to the set point. Alternatively, if the set current is less than the minimum current required to maintain the set voltage level, an automatic cross over to constant current will occur. A current trip is provided for protection against exceeding a maximum

DC amperage rating of the power supply. If the DC amperage is exceeded, the power supply will continue to run, however, there will not be any output. Similarly, an over temperature relay 36 is provided to sense any overheating in rectifier 23 and if there is overheating, shutting down the power supply at the main switch 20.

The power supply of the present embodiment provides control of either the voltage or the current to produce a constant current or voltage at the desired output level.

Details of the power supply are illustrated in FIGs 6, 7 and 8. FIG 6 shows a schematic circuit diagram of the power supply of FIG 5. The diagram further shows display means 26 and 27 for displaying the amperage and voltage as they are adjusted. A secondary transformer 28 is connected at the primary side, to the output of the adjustable main switch 20 and supplies power at its secondary side, for monitoring and control circuits shown in FIGs 7 and 8.

FIG 7 illustrates a relay circuitry 29 for actuation which reverses the polarity of the rectified DC signal output 25. The circuitry will be readily known to a person skilled in the art and will not be described in further detail. It should be noted that this circuitry may also be used with the power supply for the electrocoagulation system at 1LPM, 5LPM or 10LPM.

Referring now to FIG 8, there is shown a circuit diagram of the control circuit associated with the power supply in accordance with the invention. The control and monitoring circuits include a power on indicator 30, cooling fans 31 , a 12v DC power supply 32, a mains contactor 33, a rectifier running indicator 34, a fault relay 35, an over temperature relay 36 with heat syncs 37 and transformer temperature sensor 38. A controller 39 controls the functions of the regulator 21. Any fault condition arising will give rise to actuation of the voltage regulator fault relay 40. A test lamp relay 41 has a test switch 42, and indicator lamps 43 and 44 provide visual indication for any over temperature and faults in the voltage regulator.

The operation of the process flow and the power supply will be described with reference to FIGs.9 and 10. The power supply of the present invention is connected to an electrocoagulation cell 1 within which liquid is to be treated by electrolysis. In operation of the system, an algorithm in a program logic control (PLC) 47 is executed to ensure a number of conditions are met. First, before DC power is supplied to the electrodes, a mode switch 45 is set to "run" and a start button 46 is actuated. PLC 47 receives status and condition signals from a DC power supply 48, a feed tank low level switch 47, a feed tank mid level switch 50 and a fault indicator 51. The PLC determines whether all the parameters are satisfied and that all the switches are closed and there are no faults conditions detected in the system. Once the initial conditions are satisfied, the PLC 47 sends a signal to actuate a feed valve 52 to open and after a time delay 53, a feed pump 54 is started to commence operation of one or more pumps to thereby circulate liquid through the electrocoagulation system.

A flow transmitter 55 provides a signal to the PLC 47 whether the measured flow rate is greater than a low flow-set point and if so, the PLC signals the DC power supply 48 to start operation to provide a voltage across the electrodes of the electrocoagulation cell 1.

The power supply will cease applying a voltage across the electrodes if the mode switch 45 is set to a function other than a "run", or a stop button is pressed, or a fault condition is detected in 51, or any other sensed parameter such as low flow is sensed in the flow transmitter 55. In these cases, the PLC will signal the power supply to stop operating.

The PLC can also cause the operation of the electrocoagulation to be paused, if for example a liquid level in a feed tank falls below the low level switch. In this case, the switch will open and the system will go into a pause mode where it will wait until there is sufficient fluid in the feed tank before automatically restarting the feed pump and the DC power supply.

In a further embodiment, the flow rate of the liquid entering the electrocoagulation system may be controlled by the power supply of the present invention. Referring to FIG. 10, the digital controller 21 of the power supply may automatically control the flow rate of the electrolyte or water entering the electrocoagulation cell. In operation, a user enters the desired flow rate set point 56 into the digital controller 21. The controller sends control signals to a variable speed AC motor drive 57 in order to achieve the flow rate set point. The variable AC motor drive 57 controls a feed pump motor 58, which varies the speed at which the pump operates. A feed tank 59 supplies the water or electrolyte that is to be pumped into the electrocoagulation cell 1. The flow transmitter 55 measures the flow rate of the water being delivered to the electrocoagulation cell and transmits a signal back to the digital controller 21. The digital controller 21 then makes adjustments to its control signals in order to bring the measured flow rate to the flow rate set point entered by the user at 56. It will be appreciated that the flow rate of the electrolyte or water through an electrocoagulation cell may be of critical importance in the performance of the system.

The power supply may also control other functions associated with operation of the electrocoagulation system. For example, a cell drain control may be incorporated into the system whereby the cell is drained prior to cleaning, shut down or maintenance. Similarly, the system may be actuated to facilitate cleaning the cell using a cleaning solution in which case no voltage will be applied between the electrodes.

The invention has been described with reference to exemplary embodiments. However, it should be noted that other embodiments are envisaged within the spirit and scope of the invention, for example the power supply for the 100LPM system could be used for a flow rate of 500LPM.

Claims

THE CLAIMS DEFINING THE INVENTION ARE AS FOLLOWS:

1. A control assembly for an electrocoagulation cell comprising: (iv) a plurality of electrodes;

(v) releasable connection means between at least a selection of the electrodes; and

(vi) electrical connection means attached to the releasable connection means which in use is connectable to a power supply.

2. A control assembly as claimed in claim 1 wherein the releasable connection means is a rod which extends between a slot, aperture or notch of said at least a selection of the electrodes.

3. A control assembly as claimed in claim 2 or 3 wherein the rod is a threaded rod and is attached to an associated electrode by one or more threaded fasteners.

4. A control assembly as claimed in claim 3 wherein the threaded fastener(s) comprise one or more nuts each having an associated washer.

5. A control assembly as claimed in any one of claims 2 to 4 wherein each electrode has one or more upwardly extending tabs wherein each tab includes said slot, aperture or notch.

6. A control assembly as claimed in any preceding claim wherein the electrical connection means comprises a power lead secured to a conductor having an aperture for engaging with an adjacent end of the attachment rod.

7. A control assembly as claimed in claim 6 wherein each electrical connector is attached to the attachment rod with a fastener on either side of the connector.

8. An electrocoagulation cell which includes the control assembly of any preceding claim.

9. An electrocoagulation system comprising: (iv) a plurality of electrodes;

(v) an electrolytic cell having an internal chamber which contains the plurality of electrodes; and (vi) a power supply connectable to a power source and also connectable to the electrodes said power supply having control means for providing a selected constant output current or selected constant output voltage whereby the electrolytic cell may process samples of varying characteristics.

10. A electrocoagulation system as claimed in claim 9 wherein there is provided said control means comprises a variac connected to the power source through a switch means and also connected to the electrolytic cell by a rectifier to provide a DC voltage to the electrolytic cell.

11. An electrocoagulation system as claimed in claim 10 wherein there is provided a transformer which is interposed between the variac and the rectifier.

12. An electrocoagulation system as claimed in claim 11 wherein the power supply also includes a reverse polarity timer and a forward polarity timer.

13. An electrocoagulation system as claimed in claim 9 which comprises: (vi) an adjustable switch connectable to a power source; (vii) a voltage regulator connected to the switch;

(viii) a transformer having a primary coil connected to the voltage regulator; (ix) a rectifier connected to a secondary coil of the transformer and; (x) said control means being connected between the switch and the voltage regulator to control a DC output applied to the electrolytic cell to have said selected constant current or said selected constant voltage.

14. A power supply as claimed in claim 13 which further includes a polarity switch relay to select an output polarity.

15. A power supply as claimed in claim 13 or 14 which further includes a voltage or current regulator which receives an output from the rectifier ad together with said control means effects a firing control of the voltage regulator.

16. A power supply as claimed in any one of claims 13 to 15 wherein said control means includes a voltage and current potentiometer.

17. A power supply as claimed in any one of claims 13 to 16 which further includes a current trip for protection against exceeding a maximum DC amperage rating of the power supply.

18. A power supply as claimed in any one of claims 13 to 17 which further includes an over temperature relay to sense any overheating in the rectifier.