EP1550734A1 - Stainless steel powder for high temperature applications - Google Patents

Stainless steel powder for high temperature applications Download PDF

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Publication number
EP1550734A1
EP1550734A1 EP04027718A EP04027718A EP1550734A1 EP 1550734 A1 EP1550734 A1 EP 1550734A1 EP 04027718 A EP04027718 A EP 04027718A EP 04027718 A EP04027718 A EP 04027718A EP 1550734 A1 EP1550734 A1 EP 1550734A1
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Prior art keywords
weight percent
compact
powder
weight
nickel
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EP04027718A
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German (de)
French (fr)
Inventor
Ryan Sun
Kai Xu
Dan Matthews
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BorgWarner Inc
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BorgWarner Inc
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/23—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces involving a self-propagating high-temperature synthesis or reaction sintering step
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C33/00—Making ferrous alloys
    • C22C33/02—Making ferrous alloys by powder metallurgy
    • C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
    • C22C33/0278—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
    • C22C33/0285—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with Cr, Co, or Ni having a minimum content higher than 5%
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12—Both compacting and sintering
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/02—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of piston rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/10—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of articles with cavities or holes, not otherwise provided for in the preceding subgroups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10—Processes characterised by the sequence of their steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy

Definitions

  • the invention pertains to the field of metal powder. More particularly, the invention pertains to a metal powder for high temperature applications.
  • US 3,620,690 discloses a powder of 16 to 26 weight percent chromium, 6 to 22 weight percent nickel, 0.03-0.25 weight percent carbon, 1.75 to 4.0 weight percent of molybdenum, and small amounts of titanium, tantalum, and niobium.
  • the powder is then compacted under a pressure of 2 to 100 tsi and then sintered at 2192 to 2552°F for 10 to 90 minutes.
  • the sintering takes place in a reducing atmosphere (i.e. hydrogen and anhydrous or cracked ammonia), a vacuum, or an inert gas such as argon.
  • a reducing atmosphere i.e. hydrogen and anhydrous or cracked ammonia
  • a vacuum i.e. hydrogen and anhydrous or cracked ammonia
  • an inert gas such as argon
  • US 3,953,201 discloses a powder of 10.5 to 19 weight percent chromium, up to 0.0.3 weight percent carbon, up to 0.2 weight percent manganese, up to 0.2 weight percent silicon, up to 0.3 weight percent nickel, up to 0.1 weight percent aluminum, up to 0.2 weight percent copper, and at least one element from the group of titanium, and molybdenum where titanium is 4 (%C+%N) and molybdenum is 0.5-2.5 weight percent.
  • the powder was heated at various temperatures using various methods of heating to improve corrosion resistance and increase ductility.
  • US 4,220,689 discloses a powder of 13 to 19 weight percent chromium, 13 to 19 weight percent nickel, 0.5 to 4.0 weight percent manganese, 3.5 to 7.0 weight percent silicon, up to 0.15 weight percent carbon, less than 0.04 weight percent nickel, 0.05 weight percent phosphorus, and 0.05 weight percent sulfur.
  • the balance between the elements silicon, chromium, nickel manganese, and nitrogen is essential for the desired properties of stress corrosion resistance, high temperature oxidation resistance, high work hardening rate, and galling resistance.
  • US 5,302,214 discloses up to 0.03 weight percent carbon, 0.1-0.8 weight percent silicon, 0.6 to 2.0 weight percent manganese, 0-0.006 weight percent sulfur, up to 4.0 weight percent nickel, 17 to 25 weight percent chromium, 0.2 to 0.8 weight percent niobium, 1 to 4.5 weight percent molybdenum, 0.1 to 2.5 weight percent copper, up to 0.03 weight percent nitrogen, and other elements. Furthermore, the ratio between the weight percent of manganese and sulfur is no less than 200, and niobium is defined by Nb% -8 (C%+N%) is not less than 0.2, and (Ni%+Cu%) is not more than 4.
  • the powder has an improved low temperature toughness and a high resistance to weld cracking at high temperatures.
  • US 5,110,544 discloses a powder of not more than 0.010 weight percent carbon, not more than 0.2 weight percent silicon, 0.05 to 1.5 weight percent manganese, 12-20 weight percent chromium, 0.2 to 3.0 weight percent molybdenum, 0.005-0.1 weight percent aluminum, not more than 0.015 weight percent nitrogen, not more than 0.025 weight percent phosphorus, not more than 0.010 weight percent sulfur, either or both of 10*(C %+N %)-0.5% Ti and 5 *(C %+N %) 0.5% Nb.
  • the powder displays anticorrosion properties.
  • US 6,342,087 discloses a process for producing low oxygen, essentially carbon free stainless steel powder which is produced by preparing molten steel in which contains 10 to 30 weight percent chromium, 0 to 5 weight percent molybdenum, 0 to 15 weight percent nickel, 0 to 1.5 weight percent silicon, 0 to 1.5 weight percent manganese, 0 to 2 weight percent niobium, 0 to 2 weight percent titanium, and 0 to 2 weight percent vanadium.
  • the powder is heated to a temperature of at least 1120°C in a reducing atmosphere.
  • US 6,365,095 discloses a powder including 10 to 30 weight percent of chromium, 0 to 5 weight percent of molybdenum, 0 to 15 weight percent of nickel, 0 to 0.5 weight percent of silicon, 0 to 1.5 weight percent of manganese, 0 to 2 weight percent of niobium, 0 to 2 weight percent of titanium, 0 to 2 weight percent of vanadium, 0 to 5 weight percent of Fe.sub.3 P, 0 to 0.4 weight percent graphite and at most 0.3 weight percent of inevitable impurities and most preferably 10 to 20 weight percent of chromium, 0 to 3 weight percent of molybdenum, 0.1 to 0.3 weight percent of silicon, 0.1 to 0.4 weight percent of manganese, 0 to 0.5 weight percent of niobium, 0 to 0.5 weight percent of titanium, 0 to 0.5 weight percent of vanadium, 0 to 0.2 weight percent of graphite and essentially no nickel or alternatively 7 to 10 weight percent of nickel, the balance being iron and un
  • the powder is then combined with a lubricant and optionally a binding agent and heated to a temperature of 80 to 150°C., preferably 100 to 120°C.
  • the heated mixture is then compacted in a tool heated to 80 to 130°C, preferably 100 to 120°C.
  • the compact is sintered at temperatures between 1100 to 1300°C in a standard non-oxidative atmosphere for periods between 15 and 90, preferably between 20 and 60 minutes.
  • a method of producing parts from powdered metal comprising the steps of providing a metallurgic powder comprising iron, 0-0.6 weight percent carbon, 0.5-5.0 weight percent silicon, 0.5-6.0 weight percent nickel, 0.5-1.5 weight percent molybdenum, 0-0.7 weight percent manganese, and 12-20 weight percent chromium, the weight percentages calculated based on the total weight of the powder. Secondly, the powders are compressed at a pressure of 35 to 65 tsi to provide a green compact. Then, the compact is heated in an atmosphere to a temperature of 2100°F to 2400°F for 20 to 90 minutes, such that the resulting microstructure of the compact is either single phase ferritic or dual phase ferritic and austenitic.
  • FIG. 1 is a block diagram that shows the method of producing metal parts.
  • a mixture of metallurgical powder consisting of iron, 0-0.6 weight percent carbon, 12-20 weight percent chromium, 0.5-6.0 weight percent nickel, 0.5-1.5 weight percent molybdenum, 0-0.7 weight percent manganese, and 0.5-5.0 weight percent silicon is combined, see Table 1.
  • Fe C Si Ni Mo Mn Cr New Powder Balance 0-0.6 0.5-5.0 0.5-6.0 0.5-1.5 0-0.7 12-20
  • the mixture of powders is compacted with a compaction pressure in the range of 35 to 65 tsi, resulting in a compact with a green density of 6.0 to7.0g/cc.
  • the green compact is then sintered in a H 2 , N 2 /H 2 , or a vacuum atmosphere at a temperature in the range of 2100°F to 2400°F for 20 to 90 minutes.
  • the resulting microstructure is either dual phase Ferritic and Austinic or single phase Ferritic.
  • the duplex microstructure gives the compact a higher corrosion resistance due to the lower impurity concentration level on grain boundaries.
  • the compact also has high hot tensile strength due to the smaller grain size and the increased difficulty of dislocation motion through grain boundaries. For example, the tensile strength of the compact at 1200°F is up to 28 ksi and the tensile strength of the same compact at room temperature is up to 115 ksi.
  • the application required a finished material that would be formed into vane rings and used in a variable turbine geometry (VTG) turbocharger.
  • VGT variable turbine geometry
  • Numerous design considerations were taken into account for the formation of the vane rings.
  • the vane rings had to perform at elevated temperatures in the range of 1000°F to 1600°F and include hardness/wear resistance, ultimate tensile strength, and a decreased amount of elongation at the elevated temperatures. Since the vane rings are attached to a housing and act as bearing surfaces for the movement of the vanes and the vane levers in the turbocharger, the vane rings have to allow for free movement of the vanes while still controlling the position of the vanes accurately over the life of the turbocharger.
  • the stainless steel powder composition to make the vane rings consisted of iron, 14 weight percent chromium, 4 weight percent nickel, 3 weight percent silicon, and 0.5 weight percent molybdenum. The mixture was then pressed at a compaction pressure of 50 tsi and then sintered in a hydrogen atmosphere at 2350°F for 40 minutes.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Powder Metallurgy (AREA)
  • Supercharger (AREA)

Abstract

A method of producing parts from powdered metal comprising the steps of providing a metallurgic powder comprising iron, 0-0.6 weight percent carbon, 0.5-5.0 weight percent silicon, 0.5-6.0 weight percent nickel, 0.5-1.5 weight percent molybdenum, 0-0.7 weight percent manganese, and 12-20 weight percent chromium, the weight percentages calculated based on the total weight of the powder. Secondly, the powders are compressed at a pressure of 35 to 65 tsi to provide a green compact. Then, the compact is heated in an atmosphere to a temperature of 2100°F to 2400°F for 20 to 90 minutes, such that the resulting microstructure of the compact is either single phase ferritic or dual phase ferritic and austenitic.

Description

    FIELD OF THE INVENTION
  • The invention pertains to the field of metal powder. More particularly, the invention pertains to a metal powder for high temperature applications.
    • DESCRIPTION OF RELATED ART
  • In the automobile industry there is a constant need for metal manufactured parts that can withstand and have a long wear life in high temperatures, resistant to corrosion and have a high tensile strength. One example of a composition used to achieve the above properties is US 3,620,690 which discloses a powder of 16 to 26 weight percent chromium, 6 to 22 weight percent nickel, 0.03-0.25 weight percent carbon, 1.75 to 4.0 weight percent of molybdenum, and small amounts of titanium, tantalum, and niobium. The powder is then compacted under a pressure of 2 to 100 tsi and then sintered at 2192 to 2552°F for 10 to 90 minutes. The sintering takes place in a reducing atmosphere (i.e. hydrogen and anhydrous or cracked ammonia), a vacuum, or an inert gas such as argon. Lastly, the compact undergoes rapid cooling.
  • Another example is US 3,953,201 which discloses a powder of 10.5 to 19 weight percent chromium, up to 0.0.3 weight percent carbon, up to 0.2 weight percent manganese, up to 0.2 weight percent silicon, up to 0.3 weight percent nickel, up to 0.1 weight percent aluminum, up to 0.2 weight percent copper, and at least one element from the group of titanium, and molybdenum where titanium is 4 (%C+%N) and molybdenum is 0.5-2.5 weight percent. The powder was heated at various temperatures using various methods of heating to improve corrosion resistance and increase ductility.
  • US 4,220,689 discloses a powder of 13 to 19 weight percent chromium, 13 to 19 weight percent nickel, 0.5 to 4.0 weight percent manganese, 3.5 to 7.0 weight percent silicon, up to 0.15 weight percent carbon, less than 0.04 weight percent nickel, 0.05 weight percent phosphorus, and 0.05 weight percent sulfur. The balance between the elements silicon, chromium, nickel manganese, and nitrogen is essential for the desired properties of stress corrosion resistance, high temperature oxidation resistance, high work hardening rate, and galling resistance.
  • US 5,302,214 discloses up to 0.03 weight percent carbon, 0.1-0.8 weight percent silicon, 0.6 to 2.0 weight percent manganese, 0-0.006 weight percent sulfur, up to 4.0 weight percent nickel, 17 to 25 weight percent chromium, 0.2 to 0.8 weight percent niobium, 1 to 4.5 weight percent molybdenum, 0.1 to 2.5 weight percent copper, up to 0.03 weight percent nitrogen, and other elements. Furthermore, the ratio between the weight percent of manganese and sulfur is no less than 200, and niobium is defined by Nb% -8 (C%+N%) is not less than 0.2, and (Ni%+Cu%) is not more than 4. The powder has an improved low temperature toughness and a high resistance to weld cracking at high temperatures.
  • US 5,110,544 discloses a powder of not more than 0.010 weight percent carbon, not more than 0.2 weight percent silicon, 0.05 to 1.5 weight percent manganese, 12-20 weight percent chromium, 0.2 to 3.0 weight percent molybdenum, 0.005-0.1 weight percent aluminum, not more than 0.015 weight percent nitrogen, not more than 0.025 weight percent phosphorus, not more than 0.010 weight percent sulfur, either or both of 10*(C %+N %)-0.5% Ti and 5 *(C %+N %) 0.5% Nb. The powder displays anticorrosion properties.
  • US 6,342,087 discloses a process for producing low oxygen, essentially carbon free stainless steel powder which is produced by preparing molten steel in which contains 10 to 30 weight percent chromium, 0 to 5 weight percent molybdenum, 0 to 15 weight percent nickel, 0 to 1.5 weight percent silicon, 0 to 1.5 weight percent manganese, 0 to 2 weight percent niobium, 0 to 2 weight percent titanium, and 0 to 2 weight percent vanadium. The powder is heated to a temperature of at least 1120°C in a reducing atmosphere.
  • US 6,365,095 discloses a powder including 10 to 30 weight percent of chromium, 0 to 5 weight percent of molybdenum, 0 to 15 weight percent of nickel, 0 to 0.5 weight percent of silicon, 0 to 1.5 weight percent of manganese, 0 to 2 weight percent of niobium, 0 to 2 weight percent of titanium, 0 to 2 weight percent of vanadium, 0 to 5 weight percent of Fe.sub.3 P, 0 to 0.4 weight percent graphite and at most 0.3 weight percent of inevitable impurities and most preferably 10 to 20 weight percent of chromium, 0 to 3 weight percent of molybdenum, 0.1 to 0.3 weight percent of silicon, 0.1 to 0.4 weight percent of manganese, 0 to 0.5 weight percent of niobium, 0 to 0.5 weight percent of titanium, 0 to 0.5 weight percent of vanadium, 0 to 0.2 weight percent of graphite and essentially no nickel or alternatively 7 to 10 weight percent of nickel, the balance being iron and unavoidable impurities. The powder is then combined with a lubricant and optionally a binding agent and heated to a temperature of 80 to 150°C., preferably 100 to 120°C. The heated mixture is then compacted in a tool heated to 80 to 130°C, preferably 100 to 120°C. The compact is sintered at temperatures between 1100 to 1300°C in a standard non-oxidative atmosphere for periods between 15 and 90, preferably between 20 and 60 minutes.
    • SUMMARY OF THE INVENTION
  • A method of producing parts from powdered metal comprising the steps of providing a metallurgic powder comprising iron, 0-0.6 weight percent carbon, 0.5-5.0 weight percent silicon, 0.5-6.0 weight percent nickel, 0.5-1.5 weight percent molybdenum, 0-0.7 weight percent manganese, and 12-20 weight percent chromium, the weight percentages calculated based on the total weight of the powder. Secondly, the powders are compressed at a pressure of 35 to 65 tsi to provide a green compact. Then, the compact is heated in an atmosphere to a temperature of 2100°F to 2400°F for 20 to 90 minutes, such that the resulting microstructure of the compact is either single phase ferritic or dual phase ferritic and austenitic.
    • BRIEF DESCRIPTION OF THE DRAWING
  • Fig. 1 shows a block diagram showing the steps of the present invention to produce metal parts from powder that has high temperature applications.
    • DETAILED DESCRIPTION OF THE INVENTION
  • The present invention provides a method for producing metal parts that have high temperature and corrosive applications. Figure 1 is a block diagram that shows the method of producing metal parts. In the first step a mixture of metallurgical powder consisting of iron, 0-0.6 weight percent carbon, 12-20 weight percent chromium, 0.5-6.0 weight percent nickel, 0.5-1.5 weight percent molybdenum, 0-0.7 weight percent manganese, and 0.5-5.0 weight percent silicon is combined, see Table 1.
    Fe C Si Ni Mo Mn Cr
    New Powder Balance 0-0.6 0.5-5.0 0.5-6.0 0.5-1.5 0-0.7 12-20
  • In the second step the mixture of powders is compacted with a compaction pressure in the range of 35 to 65 tsi, resulting in a compact with a green density of 6.0 to7.0g/cc. The green compact is then sintered in a H2, N2/H2, or a vacuum atmosphere at a temperature in the range of 2100°F to 2400°F for 20 to 90 minutes.
  • Lastly, a secondary heating or other operation may be applied to the compact depending upon the required mechanical properties. The resulting microstructure is either dual phase Ferritic and Austinic or single phase Ferritic. The duplex microstructure gives the compact a higher corrosion resistance due to the lower impurity concentration level on grain boundaries. The compact also has high hot tensile strength due to the smaller grain size and the increased difficulty of dislocation motion through grain boundaries. For example, the tensile strength of the compact at 1200°F is up to 28 ksi and the tensile strength of the same compact at room temperature is up to 115 ksi.
    • Example 1
  • The application required a finished material that would be formed into vane rings and used in a variable turbine geometry (VTG) turbocharger. Numerous design considerations were taken into account for the formation of the vane rings. The vane rings had to perform at elevated temperatures in the range of 1000°F to 1600°F and include hardness/wear resistance, ultimate tensile strength, and a decreased amount of elongation at the elevated temperatures. Since the vane rings are attached to a housing and act as bearing surfaces for the movement of the vanes and the vane levers in the turbocharger, the vane rings have to allow for free movement of the vanes while still controlling the position of the vanes accurately over the life of the turbocharger. Lastly, the design of the vane rings had to be different from the vane and vane levers to prevent welding. The stainless steel powder composition to make the vane rings consisted of iron, 14 weight percent chromium, 4 weight percent nickel, 3 weight percent silicon, and 0.5 weight percent molybdenum. The mixture was then pressed at a compaction pressure of 50 tsi and then sintered in a hydrogen atmosphere at 2350°F for 40 minutes.
  • Accordingly, it is to be understood that the embodiments of the invention herein described are merely illustrative of the application of the principles of the invention. Reference herein to details of the illustrated embodiments is not intended to limit the scope of the claims, which themselves recite those features regarded as essential to the invention.

Claims (4)

  1. A method of producing parts from powdered metal comprising the steps of:
    a) providing a metallurgic powder comprising iron, 0-0.6 weight percent carbon, 0.5-5.0 weight percent silicon, 0.5-6.0 weight percent nickel, 0.5-1.5 weight percent molybdenum, 0-0.7 weight percent manganese, and 12-20 weight percent chromium, the weight percentages calculated based on the total weight of the powder;
    b) compressing the metallurgic powder at a pressure of 35 to 65 tsi to provide a green compact; and
    c) heating the compact in an atmosphere to a temperature of 2100°F to 2400°F for 20 to 90 minutes, such that microstructure of the compact has a duplex phase or a single phase, the duplex phase having both ferritic and austenitic phases and the single phase having only a ferritic phase.
  2. The method of claim 1, wherein the parts are rings used in a variable turning geometry turbocharger.
  3. The method of claim 1, wherein the step of compressing the metallurgic powder produces a compact with a density of 6.0g/cc to 7.0 g/cc.
  4. The method of claim 1, wherein the atmosphere in which the compact is heated is selected from the group consisting of:
    a) H2;
    b) N2/H2; and
    c) vacuum.
EP04027718A 2003-12-11 2004-11-23 Stainless steel powder for high temperature applications Withdrawn EP1550734A1 (en)

Applications Claiming Priority (2)

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US10/733,193 US20050129563A1 (en) 2003-12-11 2003-12-11 Stainless steel powder for high temperature applications
US733193 2003-12-11

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CN (1) CN1626298A (en)

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DE102010035293A1 (en) * 2010-08-25 2012-03-01 Bosch Mahle Turbo Systems Gmbh & Co. Kg Sintered molded part comprises carbon, chromium, nickel, molybdenum, manganese, silicon, at least one of cobalt, titanium, niobium, vanadium or tungsten, sulfur, and iron including production related impurities

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US10975718B2 (en) 2013-02-12 2021-04-13 Garrett Transportation I Inc Stainless steel alloys, turbocharger turbine housings formed from the stainless steel alloys, and methods for manufacturing the same
CN105537579A (en) * 2015-12-24 2016-05-04 宁波天阁汽车零部件有限公司 Turbocharger high-temperature-resistant turbine shell body and preparation method thereof
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US10953465B2 (en) 2016-11-01 2021-03-23 The Nanosteel Company, Inc. 3D printable hard ferrous metallic alloys for powder bed fusion
DK3333275T3 (en) * 2016-12-07 2021-02-08 Hoeganaes Ab Publ STAINLESS STEEL POWDER FOR THE MANUFACTURE OF STAINLESS DUPLEX SINTER STEEL
US10844465B2 (en) * 2017-08-09 2020-11-24 Garrett Transportation I Inc. Stainless steel alloys and turbocharger kinematic components formed from stainless steel alloys
CN108546889B (en) * 2018-05-11 2020-09-08 飞亚达（集团）股份有限公司 Stainless steel material and preparation method thereof
KR102202390B1 (en) * 2018-12-13 2021-01-13 한국표준과학연구원 Hydrogen embrittlement resistive stainless steel agglomerated parts and powder reformed by gas treatment
KR20210107289A (en) 2020-02-24 2021-09-01 현대자동차주식회사 Stainless steel powder, powder composition for powder metallurgy containing the same and method of manufacturing the same

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