EP1546535B1 - Multi-part cooled piston for an internal combustion engine - Google Patents
Multi-part cooled piston for an internal combustion engine Download PDFInfo
- Publication number
- EP1546535B1 EP1546535B1 EP03769200A EP03769200A EP1546535B1 EP 1546535 B1 EP1546535 B1 EP 1546535B1 EP 03769200 A EP03769200 A EP 03769200A EP 03769200 A EP03769200 A EP 03769200A EP 1546535 B1 EP1546535 B1 EP 1546535B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- piston
- pistons
- fact
- holes
- accordance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F3/00—Pistons
- F02F3/16—Pistons having cooling means
- F02F3/20—Pistons having cooling means the means being a fluid flowing through or along piston
- F02F3/22—Pistons having cooling means the means being a fluid flowing through or along piston the fluid being liquid
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F3/00—Pistons
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F3/00—Pistons
- F02F3/0015—Multi-part pistons
- F02F3/003—Multi-part pistons the parts being connected by casting, brazing, welding or clamping
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F3/00—Pistons
- F02F3/0084—Pistons the pistons being constructed from specific materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
- F05C2201/00—Metals
- F05C2201/04—Heavy metals
- F05C2201/0433—Iron group; Ferrous alloys, e.g. steel
- F05C2201/0448—Steel
Definitions
- the invention relates to a multi-part cooled piston for an internal combustion engine according to the preamble of claim 1.
- a multi-part cooled piston for an internal combustion engine is from the JP 61175255 A known.
- This piston shows at the level of the ring portion of the piston a number of ribs, between which a heat-insulating plate for minimizing the heat transfer from the combustion bowl to the ring section is arranged.
- a pendulum piston which consists of a piston body with a piston upper part and formed thereon with pin bosses and a separate shaft part, which is connected by means of piston pin with the piston body.
- the pendulum piston has an annular cooling channel, which is bounded partly by the upper piston part and partly by the shaft part, and also has no technical features that improve the cooling effect of flowing in the cooling channel cooling oil.
- the invention is therefore based on the object to provide a multi-part cooled piston, which is inexpensive to produce with a sufficient dimensional stability and a cooling system with improved cooling effect.
- the cooling channel can be formed closer to the piston crown or combustion bowl and nevertheless has excellent dimensional stability.
- the arrangement of the support ribs a kind of chamber formation in the cooling channel, d. h., A generation of shaker chambers, whereby an extension of the residence time of the cooling oil and thus an improved heat dissipation of the piston areas to be cooled is achieved.
- the multi-part cooled piston 20 consists of a forged piston upper part 1 with a combustion bowl 3, ring wall 4 with ring portion 11 and a (upper, towards the piston head) part of a cooling channel 7 and a piston lower part 2, the (lower, the piston shaft 9 out ) Part of a cooling channel 7, a piston shaft 9 and hub supports 6, as shown Fig. 5 can be seen.
- holes 14 are provided in the cooling channel 7, which are arranged distributed symmetrically on the circumference and in the direction of the piston crown, ie parallel to the piston longitudinal axis K, are introduced.
- the depth h B of the holes is at most half the total height H of the cooling channel 7, so that an unhindered cooling oil circuit is ensured.
- FIGS. 3 and 4 show, between the holes 14 designated as support ribs 8 material areas go radially to the piston longitudinal axis K in sections of an annular rib 5, which forms the annular rib 5 in its entirety.
- the holes 14 and thus the support ribs 8 are, as in Fig. 4 represented, distributed radially symmetrically over the circumference of the cooling channel 7 arranged.
- the distribution can be designed such that in pressure-back pressure direction D, GD of the piston 20, a larger number of holes 14 and thus support ribs 8 is arranged, as transverse to it, ie, a single-ended circumferential distribution in Cooling channel 7 takes place.
- the distribution of the bores 14 and thus of the support ribs 8 in the cooling channel 7 when it is characterized according to the quadrant formed by the piston main axes K H I - IV be such that within a quadrant a symmetric ( Figure 6 ) or unbalanced distribution (not shown) is provided, which in the opposite quadrant, ie I. and III. or II. and IV., finds again.
- the holes 14 can thereby by round holes, as in the FIGS. 4 and 6 shown, or oblong holes (not shown), which are aligned with its long side in the direction of the piston center radially outward to the piston wall.
- the tips of the holes 14 may be round or, as in Fig. 1 shown to be angled.
- the axes of the holes 14 can, as Fig. 1 shows, parallel to the piston longitudinal axis K and / or, that is, in combination, to be arranged at an acute angle thereto, the bores 14 pointing in the direction of the combustion bowl 3.
- annular circumferential support rib 10 is formed, as seen from Fig. 3 can be seen, which corresponds in their geometric dimensions with the annular rib 5.
- the upper piston part 1 and the lower piston part 2 are permanently connected to each other via the supporting and annular ribs 10 and 5 by means of a welding or soldering process, subsequently finishing the piston 20 to a piston which can be used in a motor by means of machining.
- the upper piston part 1 is advantageously made of an oxidation-resistant and / or heat-resistant material and the lower piston part 2 of a precipitation-hardening ferritic-pearlitic steel or tempered steel.
- the outer piston wall regions between two piston parts 1 and 2 form a bearing surface, which is characterized by a few tenths of a millimeter wide gap 13. This can remain open or be sealed by means of a temperature-resistant sealing ring, which is positioned before joining both piston parts 1 and 2 on one of the bearing surfaces, for example, the piston lower part 2.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Pistons, Piston Rings, And Cylinders (AREA)
- Fuel-Injection Apparatus (AREA)
Abstract
Description
Die Erfindung betrifft einen mehrteiligen gekühlten Kolben für einen Verbrennungsmotor nach dem Oberbegriff des Anspruches 1.The invention relates to a multi-part cooled piston for an internal combustion engine according to the preamble of claim 1.
Ein mehrteilig gekühlter Kolben für einen Verbrennungsmotor ist aus der
Aus der
Aus der
Aus der
Die vorgenannten Konstruktionen sind nicht geeignet, den Kolben hinsichtlich seiner Stabilität für hohe Zünddrücke und Temperaturen, wie sie bei modernen Dieselmotoren auftreten, zu verbessern.The above constructions are not suitable to improve the piston in terms of its stability for high ignition pressures and temperatures, such as occur in modern diesel engines.
Der Erfindung liegt daher die Aufgabe zugrunde, einen mehrteiligen gekühlten Kolben anzugeben, der mit einer ausreichenden Formstabilität und einem Kühlsystem mit verbesserter Kühlwirkung kostengünstig herstellbar ist.The invention is therefore based on the object to provide a multi-part cooled piston, which is inexpensive to produce with a sufficient dimensional stability and a cooling system with improved cooling effect.
Gelöst wird die Aufgabe mit den im Kennzeichen des Hauptanspruches stehenden Merkmalen.The problem is solved with the features in the characterizing part of the main claim.
Bei einem derart hergestellten Kolben kann der Kühlkanal näher in Richtung Kolbenboden bzw. Verbrennungsmulde ausgeformt werden und weist trotzdem eine ausgezeichnete Formstabilität auf. Außerdem erfolgt durch die Anordnung der Stützrippen eine Art Kammerbildung im Kühlkanal, d. h., eine Erzeugung von Shaker-Räumen, wodurch eine Verlängerung der Verweildauer des Kühlöls und damit eine verbesserte Wärmeableitung der zu kühlenden Kolbenbereiche erreicht wird.In the case of a piston produced in this way, the cooling channel can be formed closer to the piston crown or combustion bowl and nevertheless has excellent dimensional stability. In addition, the arrangement of the support ribs a kind of chamber formation in the cooling channel, d. h., A generation of shaker chambers, whereby an extension of the residence time of the cooling oil and thus an improved heat dissipation of the piston areas to be cooled is achieved.
Vorteilhafte Weiterbildungen sind Gegenstand der Unteransprüche.Advantageous developments are the subject of the dependent claims.
Die Erfindung wird im Folgenden anhand eines Ausführungsbeispiels näher erläutert. Es zeigt:
- Fig. 1
- einen erfindungsgemäßen Kolben im Querschnitt, geschnitten in Bolzenrichtung;
- Fig. 2
- einen erfindungsgemäßen Kolben in Unteransicht, geschnitten entlang der Linie II gemäß
Fig. 1 ; - Fig. 3
- einen erfindungsgemäßen Kolben im Querschnitt, geschnitten quer zur Kolbenbolzenrichtung;
- Fig. 4
- einen erfindungsgemäßen Kolben, geschnitten entlang der Linie IV-IV aus
Fig.1 ; - Fig. 5
- einen erfindungsgemäßen Kolben in perspektivischer Ansicht;
- Fig. 6
- einen erfindungsgemäßen Kolben, geschnitten entlang der Linie IV-IV aus
Fig.1 , in einem weiteren Ausführungsbeispiel.
- Fig. 1
- a piston according to the invention in cross section, cut in the direction of the bolt;
- Fig. 2
- a piston according to the invention in a bottom view, taken along the line II according to
Fig. 1 ; - Fig. 3
- a piston according to the invention in cross section, cut transversely to the piston pin direction;
- Fig. 4
- a piston according to the invention, taken along the line IV-IV
Fig.1 ; - Fig. 5
- a piston according to the invention in a perspective view;
- Fig. 6
- a piston according to the invention, taken along the line IV-IV
Fig.1 in another embodiment.
Der erfindungsgemäße mehrteilig gekühlte Kolben 20 besteht aus einem geschmiedeten Kolbenoberteil 1 mit einer Verbrennungsmulde 3, Ringwand 4 mit Ringpartie 11 und einem (oberen, zum Kolbenboden hin) Teil eines Kühlkanals 7 sowie aus einem Kolbenunterteil 2, das einen (unteren, zum Kolbenschaft 9 hin) Teil eines Kühlkanals7, einen Kolbenschaft 9 sowie Nabenabstützungen 6, wie aus
Wie die
Die Achsen der Bohrungen 14 können, wie
Aus den Nabenabstützungen 6 heraus ist eine ringförmig umlaufende Tragrippe 10 ausgebildet, wie aus
Im verbundenen Zustand von Kolbenober- und -unterteil 1 und 2 bilden die äußeren Kolbenwandbereiche zwischen beiden Kolbenteilen 1 und 2 eine Auflagefläche aus, die durch einen wenige zehntel Millimeter breiten Spalt 13 gekennzeichnet ist. Dieser kann offen bleiben oder mittels eines temperaturbeständigen Dichtungsringes, der vor dem Fügen beider Kolbenteile 1 und 2 auf einer der Auflageflächen, beispielsweise der des Kolbenunterteils 2, positioniert wird, abgedichtet sein.In the connected state of Kolbenober- and -
- Mehrteilig gekühlter KolbenMulti-piece cooled piston
- 2020
- KolbenoberteilPiston crown
- 11
- KolbenunterteilPiston part
- 22
- Verbrennungsmuldecombustion bowl
- 33
- Ringwandring wall
- 44
- Ringrippeannular rib
- 55
- Nabenabstützungboss support
- 66
- Kühlkanalcooling channel
- 77
- Stützrippensupport ribs
- 88th
- Kolbenschaftpiston shaft
- 99
- Tragrippesupporting rib
- 1010
- Ringpartiering belt
- 1111
- Nabenhub
- 1212
- Spaltgap
- 1313
- Bohrungdrilling
- 1414
- Dichtungpoetry
- 1515
- Kolbenlängsachsepiston longitudinal axis
- KK
- KolbenhauptachsePiston main axis
- KH K H
- KühlkanalhöheCooling duct height
- HH
- Tiefe der BohrungDepth of the hole
- hB h B
- Druck-Gegendruckrichtung des KolbensPressure counterpressure direction of the piston
- D, GDD, GD
Claims (9)
- Multiple cooled pistons (20) for a combustion motor with a steel forged upper piston part (1) which encompasses a combustion bowl (3) in the piston crown and an annular wall (4) with ring belt (11) and with a lower piston part (2) which encompasses a piston skirt (9), hub (12) for the housing of the gudgeon pins connecting the pistons (20) with the connecting rods as well as the hub supports (6) connected with the piston skirt (9), whereby a cooling channel (7) is formed by the upper piston part (1) and the lower piston part (2) and whose cross-section is delimited by these, whereby the upper piston part (1) has a circumferential annular rib (5) delimited by the inner wall of the cooling channel and the lower piston part (2) has an annular-shaped circumferential supporting rib (10) connected to the hub supports (6) and whereby the upper piston part (1) and the lower piston part (2) are joined integrally by the annular ribs (5) and the supporting ribs (10),
characterised by the fact that- the cooling channel (7) formed in the piston upper part (1) has holes (14) distributed throughout it to the piston crown, whereby the existing piston material forms supporting ribs (8) between the holes (14) which form sections of the circumferential annular rib (5) radially to the piston longitudinal axis (K) and- that the annular wall (4) delimiting the cooling channel (7) forms a gap (13) with the piston lower part (2) along its wall cross-section. - Pistons (20) in accordance with claim 1, characterised by the fact that the holes (14) being distributed radially symmetrical and/or asymmetrical along the course of the cooling channel (7).
- Pistons (20) in accordance with claims 1 and 2, characterised by the fact that the holes (14) have a depth (hB) which amounts at most to half of the total height (H) of the cooling channel (7).
- Pistons (20) in accordance with claims 1 through 3, characterised by the fact that at least a portion of the axes of the holes (14) run parallel to the piston longitudinal axis (K).
- Pistons (20) in accordance with claim 4, characterised by the fact that the axes of the holes (14) run at an acute angle to the piston longitudinal axis (K).
- Pistons (20) in accordance with claim 5, characterised by the fact that the holes (14) have a cylindrical or oblong shape.
- Pistons (20) in accordance with claim 1, characterised by the fact that a sealing element (15) is located in the gap (13).
- Pistons (20) in accordance with claim 1, characterised by the fact that the integral connection of the piston upper part and the piston lower part (1, 2) is a welded or soldered joint.
- Pistons (20) in accordance with claim 1, characterised by the fact that the piston upper part (1) is made from an oxidation resistant and/or temperature resistant material and the piston lower part (2) is made from precipitation hardening ferritic-perlitic steel or tempered steel.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10244512 | 2002-09-25 | ||
DE10244512A DE10244512A1 (en) | 2002-09-25 | 2002-09-25 | Multi-part cooled piston for an internal combustion engine |
PCT/DE2003/003114 WO2004029442A1 (en) | 2002-09-25 | 2003-09-19 | Multi-part cooled piston for an internal combustion engine |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1546535A1 EP1546535A1 (en) | 2005-06-29 |
EP1546535B1 true EP1546535B1 (en) | 2011-08-31 |
Family
ID=31502554
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03769200A Expired - Fee Related EP1546535B1 (en) | 2002-09-25 | 2003-09-19 | Multi-part cooled piston for an internal combustion engine |
Country Status (9)
Country | Link |
---|---|
US (1) | US6698391B1 (en) |
EP (1) | EP1546535B1 (en) |
JP (1) | JP2006500505A (en) |
KR (1) | KR20050057574A (en) |
CN (1) | CN100353046C (en) |
BR (1) | BR0314963B1 (en) |
DE (1) | DE10244512A1 (en) |
HK (1) | HK1078917A1 (en) |
WO (1) | WO2004029442A1 (en) |
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DE10301367A1 (en) * | 2003-01-16 | 2004-07-29 | Mahle Gmbh | Method for making shaker bores in the cooling channel of a one-piece piston |
KR20050039320A (en) * | 2003-10-24 | 2005-04-29 | 현대자동차주식회사 | Piston for internal combustion engine |
WO2005121608A1 (en) * | 2004-06-08 | 2005-12-22 | Savice Limited | A piston, a ring and a piston assembly for a two cycle engine |
US7406941B2 (en) | 2004-07-21 | 2008-08-05 | Federal - Mogul World Wide, Inc. | One piece cast steel monobloc piston |
DE102004061778A1 (en) * | 2004-09-29 | 2006-04-06 | Ks Kolbenschmidt Gmbh | Simple friction weld |
US20080271597A1 (en) * | 2006-03-31 | 2008-11-06 | Soul David F | Methods and apparatus for operating an internal combustion engine |
DE102007027162A1 (en) | 2007-06-13 | 2008-12-18 | Mahle International Gmbh | Two-piece piston for an internal combustion engine |
DE102007044106A1 (en) * | 2007-09-15 | 2009-03-19 | Mahle International Gmbh | Two-piece piston for an internal combustion engine |
DE102007050213A1 (en) * | 2007-10-20 | 2009-04-23 | Mahle International Gmbh | Piston for an internal combustion engine |
US7918155B2 (en) * | 2007-12-12 | 2011-04-05 | Mahle International Gmbh | Piston with a cooling gallery |
DE102007061601A1 (en) * | 2007-12-20 | 2009-06-25 | Mahle International Gmbh | Piston for an internal combustion engine and method for its production |
DE102008011922A1 (en) | 2008-02-29 | 2009-09-03 | Ks Kolbenschmidt Gmbh | Piston for internal combustion engines, produced by means of a multi-orbital friction welding process |
DE102008034430B4 (en) * | 2008-07-24 | 2015-02-19 | Ks Kolbenschmidt Gmbh | Friction welded steel piston with optimized cooling channel |
DE102008045456A1 (en) * | 2008-09-02 | 2010-03-04 | Mahle International Gmbh | Piston for an internal combustion engine |
JP5008627B2 (en) * | 2008-09-17 | 2012-08-22 | 本田技研工業株式会社 | Piston and manufacturing method thereof |
CN101644327B (en) * | 2009-06-10 | 2013-01-16 | 北京中清能发动机技术有限公司 | Piston and internal combustion engine of circular slider-crank mechanism |
DE102009025691A1 (en) | 2009-06-20 | 2010-01-28 | Daimler Ag | Piston for internal combustion engine, particularly reciprocating internal combustion engine, has upper piston area, which has ring carrier with ring groove and piston bowl |
US20110030214A1 (en) * | 2009-08-05 | 2011-02-10 | Wolfgang Rein | Piston assembly multiple step forming process |
DE102010015568A1 (en) | 2010-04-19 | 2011-10-20 | Ks Kolbenschmidt Gmbh | Piston upper part of a built or welded piston with extended cooling chambers |
DE102011113800A1 (en) * | 2011-09-20 | 2013-03-21 | Mahle International Gmbh | Piston for an internal combustion engine and method for its production |
WO2013045289A1 (en) | 2011-09-28 | 2013-04-04 | Ks Kolbenschmidt Gmbh | Two-part steel piston for internal combustion engines |
MX2015003487A (en) * | 2012-09-27 | 2015-09-25 | Ks Kolbenschmidt Gmbh | Piston of two-piece construction for an internal combustion engine. |
CN105143732A (en) * | 2013-01-29 | 2015-12-09 | 马勒国际有限公司 | Steel piston with fourth land guidance and improved friction characteristics |
JP6401188B2 (en) | 2013-02-18 | 2018-10-03 | フェデラル−モーグル・リミテッド・ライアビリティ・カンパニーFederal−Mogul Llc | Complex shaped piston oil gallery with piston crown made by cast metal or powder metal process |
US9334958B2 (en) * | 2013-02-18 | 2016-05-10 | Federal-Mogul Corporation | Complex-shaped forged piston oil galleries |
US10787991B2 (en) | 2013-02-18 | 2020-09-29 | Tenneco Inc. | Complex-shaped forged piston oil galleries |
WO2016001379A1 (en) * | 2014-07-02 | 2016-01-07 | Ks Kolbenschmidt Gmbh | Gap geometry in a cohesively joined cooling-channel piston |
US10184422B2 (en) * | 2014-12-30 | 2019-01-22 | Tenneco Inc. | Reduced compression height dual gallery piston, piston assembly therewith and methods of construction thereof |
KR20170107473A (en) * | 2015-01-30 | 2017-09-25 | 페더럴-모걸 엘엘씨 | Piston with sealed cooling passage and method of making the piston |
DE102015006642A1 (en) * | 2015-05-22 | 2016-11-24 | Caterpillar Motoren Gmbh & Co. Kg | PISTON-SUPPORTING ASSEMBLY |
MX2018013353A (en) | 2016-05-04 | 2019-02-20 | Ks Kolbenschmidt Gmbh | Piston. |
JP7137786B2 (en) * | 2018-09-25 | 2022-09-15 | スズキ株式会社 | internal combustion engine piston |
CN109268495B (en) * | 2018-11-19 | 2020-07-10 | 滨州渤海活塞有限公司 | Combination of steel piston and piston pin and processing technology thereof |
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-
2002
- 2002-09-25 DE DE10244512A patent/DE10244512A1/en not_active Withdrawn
- 2002-10-11 US US10/270,255 patent/US6698391B1/en not_active Expired - Lifetime
-
2003
- 2003-09-19 JP JP2004538728A patent/JP2006500505A/en active Pending
- 2003-09-19 EP EP03769200A patent/EP1546535B1/en not_active Expired - Fee Related
- 2003-09-19 BR BRPI0314963-3A patent/BR0314963B1/en not_active IP Right Cessation
- 2003-09-19 KR KR1020057005107A patent/KR20050057574A/en not_active Application Discontinuation
- 2003-09-19 WO PCT/DE2003/003114 patent/WO2004029442A1/en active Application Filing
- 2003-09-19 CN CNB038228432A patent/CN100353046C/en not_active Expired - Fee Related
-
2005
- 2005-11-25 HK HK05110760A patent/HK1078917A1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
HK1078917A1 (en) | 2006-03-24 |
CN1685143A (en) | 2005-10-19 |
EP1546535A1 (en) | 2005-06-29 |
US6698391B1 (en) | 2004-03-02 |
BR0314963A (en) | 2005-08-02 |
KR20050057574A (en) | 2005-06-16 |
WO2004029442A1 (en) | 2004-04-08 |
DE10244512A1 (en) | 2004-04-15 |
BR0314963B1 (en) | 2012-08-21 |
CN100353046C (en) | 2007-12-05 |
JP2006500505A (en) | 2006-01-05 |
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