EP1533596A2 - Surveillance du débit avec un appareil de contrôle du débit - Google Patents

Surveillance du débit avec un appareil de contrôle du débit Download PDF

Info

Publication number
EP1533596A2
EP1533596A2 EP04022991A EP04022991A EP1533596A2 EP 1533596 A2 EP1533596 A2 EP 1533596A2 EP 04022991 A EP04022991 A EP 04022991A EP 04022991 A EP04022991 A EP 04022991A EP 1533596 A2 EP1533596 A2 EP 1533596A2
Authority
EP
European Patent Office
Prior art keywords
fluid
flow control
valve
algorithm
flow rate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP04022991A
Other languages
German (de)
English (en)
Other versions
EP1533596B1 (fr
EP1533596A3 (fr
Inventor
Stuart Bruce Williams
Jean-Philippe Trembley
Jeremy Paul Miller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Products and Chemicals Inc
Original Assignee
Air Products and Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Publication of EP1533596A2 publication Critical patent/EP1533596A2/fr
Publication of EP1533596A3 publication Critical patent/EP1533596A3/fr
Application granted granted Critical
Publication of EP1533596B1 publication Critical patent/EP1533596B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
    • G01F1/00—Measuring the volume flow or mass flow of fluid or fluent solid material wherein the fluid passes through a meter in a continuous flow
    • G01F1/74—Devices for measuring flow of a fluid or flow of a fluent solid material in suspension in another fluid
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D29/00—Arrangement or mounting of control or safety devices
    • F25D29/001—Arrangement or mounting of control or safety devices for cryogenic fluid systems

Definitions

  • the flow rate of a fluid into a process is important for many applications, because it provides useful information to both the user of the fluid in an application and the supplier of the fluid.
  • knowing the flow rate into an application will allow the user to know the amount and costs in real time for the use of the fluid.
  • the user would also benefit from knowing the flow rate which would give extra information on performance of the equipment, particularly during commissioning (start-up) of the equipment.
  • the flow rate of the cryogenic fluid indicates the refrigeration power and allows the performance of the application to be optimized to provide best efficiency. With flow rate data it will be possible to immediately demonstrate improvements made to equipment and measure savings.
  • the fluid flow meters that are currently available are not generally used for cryogenic fluid applications.
  • Flow meters useful for cryogenic fluids are expensive and sophisticated pieces of equipment, and their accuracy depends on the consistency of the gas and liquid fractions of the fluid.
  • Many flow meters are accurate for subcooled and low gas fraction two phase flows (less than 0.5% gas by weight), but are poor for higher gas fraction two phase fluids, and gas only fluids; however, in cryogenic applications, the gas and liquid fractions in the fluid may vary greatly. Due to the flow meters' high sensitivity, they are also susceptible to rough handling. Also the potential for moisture ingress is a major cause for unreliability with conventional low temperature flow metering equipment.
  • cryogenic flow gives rise to three distinct flow regimes: sub cooled liquid, two phase gas and liquid, and super heated gas.
  • Flow meters are normally designed to work in one of these regions. To maintain good accuracy the flow meters are complex, sensitive and expensive, but their accuracy can be poor and highly variable when the gas and liquid fractions of the cryogenic fluid vary beyond the gas and liquid fractions that the meters are designed for.
  • Current flow meters include those that measure the flow directly using the velocity and density of the fluid, and those that measure the flow indirectly using properties such as pressure drop and fluid modeling equations.
  • the flow meters that measure the flow directly are complex meters. They are accurate for their design conditions. Examples of these meters are disclosed in US patents 4835456, 3635084, 4272982.
  • Flow is measured using a moving part (e.g. a turbine) to find the fluid velocity directly. They are susceptible to the stability of the gas and liquid fractions of the cryogenic fluid and can have poor accuracy for high gas fraction cryogenic fluids.
  • Non-cryogenic indirect measurement flow meters include Pitot tubes, and the Venturi's and orifice plate meters. They rely on finding the pressure drop and using it in flow modeling equations, for example Bernoulli's equation. For two phase flow more complex flow modeling is required and is very dependent on the gas and liquid fractions of the cryogenic fluid. An example can be found in US patent 4168624.
  • flow meters measure flow using electronic means (e.g. capacitance) to find the fluid velocity, such as those flow meters disclosed in US patents 4,509,366, and 5,861,755. They are susceptible to the stability of the gas and liquid fractions of the cryogenic fluid and can have poor accuracy for high gas fraction cryogenic fluids.
  • electronic means e.g. capacitance
  • a third group of flow meters arises where the fluid is split into its gas and liquid phase, each phase has its flow rate measured using one of the techniques above and the total flow is found by summing the two. Examples of these flow meters are found in US patents 4881412 and 5679905. They are complex and expensive as they require two or more flow meters to measure the total flow.
  • This invention provides a method of determining the flow rate of a fluid, having a liquid fraction and a gas fraction, comprising the steps of: measuring the pressure and temperature of said fluid at a flow control device through which said fluid passes; inputting said measured pressure and C v into an algorithm; and performing a single or multi-step iteration to determine a fluid mass flow rate of the fluid through said flow control device using said algorithm that relates the mass flow rate of said fluid to said C v , and mass densities of said liquid fraction and said gas fraction of said fluid which are a function of said measured pressure, and temperature.
  • This invention further provides a system comprising a source of fluid having a liquid fraction and a gas fraction, one or more flow control devices, one or more apparatuses, means for measuring temperature and pressure at said one or more flow control devices, a pipe comprising one or more pipe portions in fluid communication with said source and at least one of said one or more apparatuses, an algorithm, means for inputting said measured pressures and C v for each of said one or more flow control devices into said algorithm; and means for performing a single or multi-step iteration to determine a mass flow rate of the fluid to said one or more apparatuses using said algorithm that relates the mass flow rate of said fluid to said one or more apparatuses to said C v for each of said one or more flow control devices and mass densities of said gas fraction and said liquid fraction of said fluid which are a function of said measured pressures and temperatures.
  • the system and method of this invention can be used for continuous, or semi-continuous, or on-demand (i.e. when needed or desired) measurement and calculations of the mass flow rates and/or of the mass fractions of a fluid, e.g. a cryogenic fluid which comprises liquid and gas fractions.
  • a fluid e.g. a cryogenic fluid which comprises liquid and gas fractions.
  • This invention is applicable to any fluid comprising liquid and gas fractions, including cryogenic fluid.
  • the temperature(s) may be inputted into the algorithm during the inputting step and/or used to determine properties of the gas and liquid fractions and the values of properties may be inputted into the algorithm.
  • This invention further provides a method of determining the use of a cryogenic liquid and gas mixture on a continuous or semi-continuous basis comprising the steps of: measuring the pressure and temperature of said liquid and gas mixture at a valve through which said cryogenic liquid and gas mixture passes (P valve and T valve ); measuring the percent opening for said valve; inputting the P valve , T valve , C v , and percent opening of the valve into an algorithm, and performing a single or multi-step iteration to determine the fluid mass flow rate of the cryogenic liquid and gas mixture using said algorithm that relates the mass flow rate to C v , vapor pressure and mass densities of the gas and liquid mixture which are a function of the pressure and temperature of the liquid and gas mixture.
  • This new invention answers the need for determining, mass flow of a fluid to an apparatus with limited additional cost, because flow measurement is possible using a control valve or other flow control device.
  • the invention provides a reliable, robust, inexpensive and effective method of measuring flow for cryogenic fluids having any gas and liquid fractions. It will allow a method and system of flow measurement to be added and installed to most applications at minimal extra cost.
  • the simplicity of the invention means that the measurement calculations may be performed in the valve controller, PLC, computer, server, supervisory control data and acquisition (SCADA) industrial controller, or the like.
  • SCADA supervisory control data and acquisition
  • This invention can be used to provide reliable information on flow to both the end user and the supplier of a two phase fluid, for example a cryogenic fluid. It will allow the user to monitor production efficiency and make the necessary adjustments to improve it. It is particularly useful for systems that comprise multiple apparatus that use cryogenic fluid from a single fluid supply and/or storage source.
  • This invention will be described with reference to one embodiment using a cryogenic fluid; however, it can be used and adapted to any system in which measurement of the mass flow rate of a fluid comprising liquid and gas fractions is desired.
  • FIG 1 shows one embodiment of the system of this invention.
  • FIGS 2-4 show one embodiment of the method of this invention.
  • FIG. 5 shows an alternative embodiment of the system of this invention.
  • One embodiment of the method and system of this invention is designed to operate for any standard cryogenic system that uses a source of cryogenic fluid, one or more apparatuses that use the cryogenic fluid from the source, one or more flow control devices positioned near the one or more apparatuses, and a pipe comprising one or more pipe portions in fluid communication with the source for the cryogenic fluid, the one or more flow control devices and the one or more apparatuses.
  • the one or more flow control devices may be valves (e.g. variable position, on/off, or solenoid valves), each having a known flow coefficient, or are valves or other flow control devices for which flow coefficient(s) can be determined.
  • a flow coefficient, C v is a dimensionless number that is related to the amount of fluid or gas that can pass through a valve under certain conditions of temperature and pressure when open, and for variable position valves when open a known amount.
  • the valve flow coefficient, C v may be defined as the amount of water at 60°F, in gallons per minute, that will pass through a fully open valve with a 1 psi pressure drop.
  • C v can be determined for other flow control devices other than valves. The invention will be described with reference to embodiments in which the flow control device(s) is(are) valve(s); however, it is understood that one or more flow control devices can be substituted for the one or more valves described herein.
  • One embodiment of the method and system of this invention uses an algorithm to calculate the mass flow rate of a cryogenic fluid from a cryogenic fluid source to one or more apparatuses.
  • the flow is calculated using an equation or equations that define the C v /Flow characteristics for sub cooled, two phase, and superheated fluids. These types of equations will be referred to as C v Equations.
  • C v Equations An example of such an equation can be found in "Masoneilan's Control Valve Sizing and Selection Handbook" and is as follows:
  • the C v term used in the equation is the product of the C v for the valve and the percentage opening of the valve measured by an instrument mounted on the valve or a signal from the valve controller.
  • C v can mean either the flow coefficient of the flow coefficient multiplied by the percent opening of the flow control device.
  • w is weight (mass) flow rate of two-phase mixture in units of kg/hour.
  • F L , F P , x, and x T are physical properties of the control valve and may be found from a valve data manual, such as supplied by valve manufacturer.
  • P c , P v , F K , ⁇ l , and ⁇ g are physical properties of the fluid determined by tabulated data that can be found in a Chemical Engineering Handbook, such as Perry's for example.
  • F F 0.96- 0.28 Pv Pc (Equation 1B)
  • ⁇ P l is limited to F L 2 ( P 1 - F F P v )
  • ⁇ P g is limited to F k ⁇ T P 1 where P 1 is the upstream pressure measured just prior to the valve.
  • Equations 1C and 1D can be used to determine the maximum values for ⁇ P l and ⁇ P g if only P 1 (also referred to as P fcd and P valve ) is measured, and that the measurement of P 2 is optional, and not necessary to perform the method and system of the invention.
  • C v is normally associated with a valve and its characteristics
  • the C v Equations above could also be used to determine 2 phase fluid flow through other flow control devices, such as orifices, holes, open ended pipes, nozzles or in fact any type of flow / flow control restriction device.
  • the term "flow control device" will be used to generally refer to any of those devices including valves.
  • F P may be assumed to be equal to 1
  • F P may be found from manufacturers' data.
  • To calculate the mass flow rate using one of the C v Equations typically requires knowledge of the C v of the flow control device (e.g. valve), pressure upstream (just before the flow control device or valve), vapor pressure and also the mass fraction of gas and liquid in the fluid, and optionally the change in pressure across the flow control device (e.g. valve).
  • the flow control device e.g. valve
  • pressure upstream just before the flow control device or valve
  • vapor pressure also the mass fraction of gas and liquid in the fluid
  • optionally the change in pressure across the flow control device e.g. valve
  • the change in pressure at the valve, ⁇ P and the fluid temperature at the valve, T valve can be determined by placing a measuring sensor (or multiple sensors that can be averaged, if desired) for temperature at the valve, and pressure sensors before or after the valve to measure P 1 and P 2 .
  • the change in pressure across the valve is then calculated as P 1 minus P 2 ; however, ⁇ P l and ⁇ P g are limited to maximum values for choked flow and are given in the equations above (Equations 1 C and 1 D).
  • the vapor pressure (P v ) of the fluid may be calculated. Comparing the vapor pressure with the actual pressure P 1 will determine the condition of the fluid as sub cooled, mixed liquid/gas, or superheated gas.
  • the quality of the fluid could be measured directly at each flow control device using a quality measurement instrument using such techniques as capacitance, dielectric, ultrasound or the like, but presently these instruments are expensive and unreliable. So if such an instrument is not used at each flow control device, at least one additional relationship between the variables needs to be defined to help solve the C v Equation.
  • One such relationship that can be used in the algorithm of this invention is that the mass fraction of the fluid at the valve is related to the mass fraction of the fluid from the source and the heat inleak into the pipe (heat that is input into the pipe that causes a phase change to a portion or all of the fluid), and the flash loss in the pipe (gas generated due to pressure drop in the pipe) between the source and the valve.
  • the heat inleak is related to the length of the pipe, and type of insulation of the pipe.
  • the flash loss is related to the enthalpy change of the fluid within the pipe from the cryogenic source to the valve.
  • the heat inleak is also a function of the unknown mass flow rate, and the gas and liquid fractions of the fluid, which are unknown.
  • the algorithm of this invention can perform an iterative calculation to determine (or closely approximate) the mass flow rate using the C v Equation and the relationship between the heat inleak and enthalpy change to the fluid in the pipe from the source to the valve.
  • the iterative calculation begins with assuming that the fluid at each of the valves located relatively closely to the one or more apparatuses that use the cryogenic fluid is 100% liquid.
  • the fluid could be assumed to be a certain fraction of gas or liquid or all gas depending upon the system and the fluid.
  • the system 500 shown in Figure 1 consists of a cryogenic fluid source 100, apparatuses 160, 161 a control valve 150 located near apparatus 160, a second control valve 151 located near apparatus 161 and pipe 170. Both apparatuses 160, 161 are in fluid communication with source 100, via pipe 170.
  • Pipe 170 consists of pipe portions 170a, 170b, 170c, 170d and 170e. From source 100, pipe portion 170a branches at point 171 into pipe portions 170b and 170c. Pipe portion 170b is connected to control valve 150, which communicates with apparatus 160 via pipe portion 170d.
  • the source 100 is connected to apparatus 161 via pipe portion 170a that branches at point 171 into 170c, connects with control valve 151 and is connected to apparatus 161 via pipe portion 170e.
  • the source 100 is shown as a storage tank, but can be any cryogenic fluid source or other fluid source, such as, a portable vessel/container, road tanker, trailer, chemical production facility, or liquid air separation plant or multiples of the above sources.
  • the pipe portions of pipe 170 are usually well insulated with vacuum jacketing super insulation or other insulation, such as, foam, polyurethane, polystyrene, foam-glass or the like. Each pipe portion is considered separately, because the insulation of the pipes and lengths of the pipe portions vary.
  • the apparatuses 160, and 161 can be any device, equipment, or process that uses the fluid, such as a cryogenic fluid, such as a freezer tunnel, batch chiller, cryogenic grinding machine, de-flashing machine, solvent recovery equipment, or heat exchanger.
  • the system 500 further comprises sensors 182 located close to the outlet of the cryogenic fluid from the source 100.
  • the sensors 182 measure at least the temperature and pressure.
  • the temperature may be measured using a platinum resistance device, or thermocouple, however, alternative temperature measuring devices can be used if desired.
  • the pressure may be measured using a pressure probe/transmitter/transducer; however, alternative pressure measuring devices can be used if desired.
  • These temperature and pressure measuring devices are affixed or otherwise connected to the pipe 170 to provide actual fluid information.
  • Sensors 180 are present on the control valve 150.
  • Sensors 180 measure at least temperature T valve and pressure upstream of the control valve 150, and preferably the downstream pressure, meaning the pressure just prior to (P 1 ) and just after (P 2 ) the control valve, respectively. To make these measurements sensors for pressure and temperature should be located a short distance, e.g. less than 100 centimeters away from the control valve. Sensors 180 also include the measurement of the actual valve position that is the percent opening of the valve, or percent opening of the valve multiplied by the C v for the valve. (For other flow control devices, that have a fixed opening, the step of measuring the percent opening will not apply.) The valve position may be measured using a linear position transducer, feedback transducer or similar device; however, alternative position measurement devices can be used if desired or required. Valve position may also be known from the electronic or pneumatic signal to the control valve, or manually determined and inputted into the computer.
  • Sensors 181 are present on the control valve 151. Sensors 181 measure at least the temperature and pressure upstream of the control valve 151, and preferably the downstream pressure, as described above for sensors 180. Sensors 181 also include the measurement of the actual valve position (percent opening of the valve), if applicable as described above for sensors 180.
  • Each group of the sensors 182, 181 and 180 transmits its generated signals to a device 106, shown as part of the system 500, such as, a data logger, data-recording device, programmable logic controller (PLC), valve controller, computer or any type of data storage device, or the like, which may also be capable of running the algorithm or communicating with a computer, that is capable of running the algorithm to calculate the fluid mass flow rate.
  • a device 106 shown as part of the system 500, such as, a data logger, data-recording device, programmable logic controller (PLC), valve controller, computer or any type of data storage device, or the like, which may also be capable of running the algorithm or communicating with a computer
  • the means of transmission, as shown, from the sensors 182, 181, and 180 are wires 190, 191, and 192.
  • the transmission could be via wireless communication device, a network, IR link and/or by a similar communications transfer protocol.
  • the sensors may transmit to the device 106 continuously, semi-continuously, or on-demand, and the device 106 can be programmed to continuously, semi-continuously or on-demand calculate (or have calculated) the mass flow rate through the valves in the system when the cryogenic fluid is being used in the apparatus(es). Continuous measurements and calculations are limited by the time it takes to make the measurements and/or perform the calculations. Semi-continuously can be any amount of time, e.g. every minute or every 5 minutes the measurements are made and/or the calculations are performed.
  • any measurements taken by the sensors may be read in real time or stored in a database file with a time stamp and later inputted from the database file and used for calculating the mass flow of the fluid.
  • the measurement by the sensors and/or the calculation using the algorithm can be controlled manually, or performed only at start-up, or at any other desired interval or times.
  • the calculations may be performed if the temperature and pressures are not within a set range.
  • the calculated mass flow rates can be used to determine the real-time usage of cryogenic fluid by apparatuses 160, 161.
  • sensors could be provided on the equipment to store and transmit this data, or it could be stored in a database that could be accessed by the algorithm.
  • the device 106 is programmed to calculate the mass flow rate through the valves using the temperature and pressure data measured and communicated by the sensors using the iterative method (the algorithm) which was described above, and will be described in greater detail with reference to Figure 2, 3, and 4 as follows.
  • the algorithm was written including the definition of the length or lengths of the pipe between valves and branches in the pipe for the distribution of cryogenic fluid to the apparatuses, the insulation type and heat-leak values for all the pipe lengths (portions), the C v for each valve, and the location of the valves and branches in the pipes.
  • sensors could be provided on the equipment to read, or store and transmit this data, or this data could be stored in a database that could be accessed by the algorithm. Therefore in the method of this invention, unless otherwise specified, the step of inputting information includes: inputting the information from the sensors in the system, inputting the information from another database, and/or accessing information previously defined and stored within the algorithm.
  • step 501 a for each control valve through which fluid is flowing for our example control valves 150 and 151, from sensors 180 and 181 the upstream P 1 , T valve , downstream P 2 , and current valve position (pos) for each valve are read and via sensors 182, the P tank , and T tank are read and all the values are inputted into the algorithm.
  • step 501 b the data collected in step 501 a for each valve is used to calculate the fluid physical properties: density of the liquid, ⁇ l , density of the gas, ⁇ g , the vapor pressure, P v , enthalpy of the liquid, h l , the latent enthalpy h lat , at each of the valves, the enthalpy of the fluid at the source (e.g. at the tank), h tank , the liquid critical pressure P c and the ratio specific heats factor F K based on tabulated or polynomial data for the fluid from an engineering handbook.
  • step 501c further calculations are performed to determine ⁇ P g , ⁇ P l , F F , and Y using Equations 1 A, 1 B, 1 C and 1D.
  • ⁇ P g is the change in pressure of the gas phase across the valve. (For the first iteration this is 0).
  • ⁇ P l is the change in pressure of the liquid phase across the valve, which for the first iteration is P 1 minus P 2 .
  • F L , and x are typically provided by the valve manufacturer for each valve, and are defined in the algorithm for each valve.
  • one or more separate algorithms having for examples, look up tables, or formulas, may be provided to determine values for the variables and then those values may be inputted into the algorithm used to determine the mass flow rate of the fluid.
  • subroutines having for examples, look-up tables or formulas, may be imbedded into the algorithm (used to determine the mass flow rate of the fluid) to determine the values for the variables.
  • step 501 d further calculations are then performed to determine the heat inleak values for the pipe portions.
  • the distribution system is split into pipe portions or nodes.
  • the pipe includes pipe portions 170a and 170b as shown in Figure 1.
  • the pipe includes pipe portions 170a and 170c.
  • the heat loss, HL, for each of the pipes connecting the source to the control valve for the apparatus is calculated by summing the insulation factor multiplied by the length for each portion of the pipe.
  • a check is performed to determine if the fluid at each valve is a sub cooled liquid, a superheated gas or a mixture of liquid and gas. If the fluid is a sub cooled liquid, the C v Equation shown in step 503a is used to calculate the mass flow rate. If the fluid is gas, then the C v Equation shown in step 503b is used to calculate the mass flow rate. If the fluid is only a sub cooled liquid or only a gas, then the calculation is complete after step 503a or 503b.
  • the equations shown in step 509 could be solved simultaneously to calculate the mass of the liquid and gas respectively at each valve and the calculation would be complete. Since the ratio of liquid and gas at the valves is unknown, for the first iteration, the fluid is assumed to be 100% liquid at each of the valves 150 and 151.
  • the liquid mass flow rates, w l150 and w l151 are calculated using the C v Equation shown in step 503c for each of the valves 150 and 151, respectively.
  • step 503d the liquid flow rate in all the pipe portions (nodes) are calculated.
  • the mass flow rate in pipe portion 170a, w l170a equals w l150 + w l151 .
  • step 503f the gas that will result from the heat inleak in each pipe portion or node is calculated using the formula shown in Figure 3.
  • the heat loss for each node was determined in step 501 d.
  • the latent enthalpy was determined in step 503e.
  • step 503g the gas GHL 170a is distributed into subsequent nodes based on the flows calculated in step 503d, and new values for gas due to the heat inleak GHL 170b and GHL 170c are calculated by adding the just-described value to the values calculated for GHL 170b and GHL 170c in step 503f.
  • step 504 the flash loss for each valve is calculated from the latent heat at the source and the valve using the h tank and h lat150 and h lat151 values determined in step 501 b.
  • step 505 using the values for flash loss and gas due to heat inleak calculated in step 503g and 504, and the mass flow rates calculated in step 503c, the gas fractions, f, of the fluid at each of the valves 150 and 151 are calculated.
  • step 506 using the gas fractions that are calculated in step 505 for each of the valves 150 and 151, and the densities of the liquid and gas from step 501 b, a new modified density is then calculated for the fluid at valves 150 and 151.
  • step 507 the first estimation for mass flow rate at each of the valves is recalculated using the initial mass flow rate W i that was calculated in step 503c for each of the valves, the density for the liquid at each valve that was calculated in step 501 b and the modified density calculated at each valve calculated in step 506.
  • step 508 using the flash loss and heat inleak data that was calculated in steps 503g and 504, and the mass flow rates, w, that were calculated in step 507, the gas fraction of the fluid at the valve, f', for each valve is recalculated.
  • step 509 the final mass flow rate at each valve is recalculated using the gas fraction f' calculated in step 508, using the C v Equation with all other input values either as previously determined or calculated within the algorithm.
  • the embodiment shown in Figure 1 with the method steps (algorithm) described in Figures 2, 3, and 4 pertains to a single source of cryogenic fluid and 2 apparatuses that use the fluid from the source.
  • the algorithm can be adapted to any pipe setup and for any number of apparatuses in fluid communication with one or more cryogenic fluid sources by amending the algorithm to include them, which given the teaching herein can be done by a person of ordinary skill.
  • Figure 5 shows a system 600 of the invention. Like equipment in Figure 1 and Figure 5 is labeled the same. Figure 5 differs from Figure 1 in that Figure 5 shows only a single apparatus 160; however, it is understood that the method and system of this invention is most useful for and can be tailored for any number of apparatus receiving cryogenic fluid from a source of cryogenic fluid.
  • the sensors 180 transmits generated signals to a programmable logic controller (PLC) 106.
  • PLC programmable logic controller
  • the PLC 106 serves as an intelligent portal on a network 136 through which the signals from the sensors 180, 182 pass to be stored on a local database 114 or transmitted across various networks 136 or 140 for storage on a remote global database 126 and 140 for viewing by various personnel on personal computers, terminals, and workstations 112, 120, 124, and 130.
  • Each of the devices residing on the network 140 if properly authorized can receive sensor data, and access to the calculated mass flow rates, from the PLC 106 through a secure access server 138.
  • sensor signals or the server 138 can also be accessed by means of portable devices 134, such as cell phones and personal digital assistants.
  • the networks 136 and 140 can be any combination of hard-wired and wireless networks including local area networks, wide area networks, private networks, public networks intranets, extranets, and the internet. Access across the networks can be though a dial-up network telephone line a wireless link, a hard wired connection, or any combination thereof. Remote access to the system is available by any number of known communication protocols including wireless.
  • the system of this invention can comprise any combination of the devices shown in Figure 5 and anticipates the capacity to provide for a means for a person accessing the network to change the flow rates or other characteristics of the equipment in response to the information from the sensors.
  • the PLC 106 or computers may be programmed to calculate the mass flow rate through the valve using the temperature and pressure data measured and communicated by the sensors; however it is presently preferred that the PLC transmit the data measured by the sensors to an offsite server that will be programmed to calculate the mass flow rate through the valve to the apparatus.
  • the sensors may transmit to the PLC continuously, semi-continuously, or when requested or otherwise programmed and the PLC or offsite server can be programmed to continuously, semi-continuously, or otherwise as requested, calculate the mass flow rate through the valve.
  • the calculated mass flow rates can be used to determine the usage of cryogenic fluid by the apparatus. This information can be used to determine the proper allocation of costs for what the apparatus is being used for. For example, if the apparatus is a food freezer, the amount of cryogenic fluid used to freeze the food can be calculated as the food passes through the freezer and the costs for freezing the food can be properly allocated to the particular food after freezing it. This is particularly beneficial when multiple freezing apparatuses freeze multiple products yet use cryogenic fluid from a single source of cryogenic fluid.
  • this invention allows the cost of freezing each individual product to be known.
  • the usage of the cryogenic fluid by a particular piece of apparatus would have to be approximated. It is additionally beneficial to measure the mass flow rate of the cryogenic fluid used by each apparatus, because then the optimization of the process becomes easier.
  • the algorithm could be part of a larger algorithm or program that could calculate the running costs of the use of the cryogenic fluid, and allocate those costs to the use of the fluid by weight of food product frozen or if the cryogenic fluid is used in a freezing apparatus or by weight of material ground if the cryogenic fluid is used in a cryogenic grinding apparatus, for examples to help the user offer more accurate pricing based on actual use of the cryogenic fluid to its customers. Additionally, the algorithm could be used to notify the user and supplier when to schedule the next delivery of cryogenic fluid or when to service an air separation unit or apparatus that used the cryogenic fluid.
  • the invention has been described with particular reference to embodiments in which the flow rate of a cryogenic fluid are determined; however, the method and system of this invention are adaptable to determine the mass flow rate of other fluids having a liquid and a gas fraction.
  • the method and system of this invention are adaptable to determine the mass flow rate of other fluids having a liquid and a gas fraction.
  • the 2 phase fluid may be cooled (instead of heated as described above) causing a phase change from gas to liquid in the pipe lengths due to heat inleak.

Landscapes

  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • General Physics & Mathematics (AREA)
  • Pipeline Systems (AREA)
  • Measuring Volume Flow (AREA)
  • Flow Control (AREA)
EP04022991.6A 2003-09-29 2004-09-27 Surveillance du débit avec un appareil de contrôle du débit Active EP1533596B1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US507184 1995-07-26
US50718403P 2003-09-29 2003-09-29
US10/939,809 US7054764B2 (en) 2003-09-29 2004-09-13 Flow monitoring using flow control device
US939809 2004-09-13

Publications (3)

Publication Number Publication Date
EP1533596A2 true EP1533596A2 (fr) 2005-05-25
EP1533596A3 EP1533596A3 (fr) 2007-02-28
EP1533596B1 EP1533596B1 (fr) 2017-11-22

Family

ID=34437273

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04022991.6A Active EP1533596B1 (fr) 2003-09-29 2004-09-27 Surveillance du débit avec un appareil de contrôle du débit

Country Status (3)

Country Link
US (1) US7054764B2 (fr)
EP (1) EP1533596B1 (fr)
JP (1) JP2005134375A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103206995A (zh) * 2013-04-11 2013-07-17 西安拓普电气有限责任公司 适用于厂房条件的气体流量测量装置及测试方法

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7255013B2 (en) * 2005-11-02 2007-08-14 General Electric Company Method and apparatus for measuring cryogenic flow
US8027793B2 (en) * 2006-07-10 2011-09-27 Daniel Measurement And Control, Inc. Method and system of validating data regarding measured hydrocarbon flow
DE102006033611B4 (de) * 2006-07-18 2010-04-08 Hydrometer Gmbh Gasphasenkorrektur für Ultraschalldurchflussmesser
ES2467099T3 (es) * 2006-08-28 2014-06-11 Air Products And Chemicals, Inc. Aparato y método para controlar el caudal de un líquido criogénico
CA2697889C (fr) * 2007-08-28 2012-10-02 Air Products And Chemicals, Inc. Procede et appareil de decharge d'un spray cryogenique non lineaire sur la largeur d'une cage de laminoir
BRPI0815929A2 (pt) * 2007-08-28 2017-05-16 Air Prod & Chem equipamento, método para prevenir a formação de congelamento em um dispositivo criogênicos, e método de operar um dispositivo criogênico
MY155518A (en) * 2007-08-28 2015-10-30 Air Prod & Chem Apparatus and method for controlling the temperature of a cryogen
BRPI0815928A2 (pt) * 2007-08-28 2017-05-16 Air Prod & Chem equipamento para uso com um sistema que possui um componente de resfriamento criogênico, método utilizado com um sistema que possui um componente de resfriamento criogênico
US8474273B2 (en) 2009-10-29 2013-07-02 Air Products And Chemicals, Inc. Apparatus and method for providing a temperature-controlled gas
EP2562541A1 (fr) * 2011-08-23 2013-02-27 Siemens Aktiengesellschaft Détermination hautement précise de la masse d'un composant dans un fluide à plusieurs composants
AU2012329604B2 (en) 2011-10-28 2016-02-04 Delaval Holding Ab Multiphase flow measurement
EP2667164A1 (fr) 2012-05-24 2013-11-27 Air Products And Chemicals, Inc. Procédé et dispositif pour mesurer les propriétés physiques d'un fluide cryogénique
ES2556783T3 (es) 2012-05-24 2016-01-20 Air Products And Chemicals, Inc. Método y aparato para medir las propiedades físicas de fluidos bifásicos
CN103267872A (zh) * 2013-05-16 2013-08-28 桂林电子科技大学 一种测量物质在不同温度释放气体流速和流量的装置
US9689823B2 (en) * 2015-03-10 2017-06-27 Rosemount Inc. Steam quality meter and measurement method
US10101194B2 (en) 2015-12-31 2018-10-16 General Electric Company System and method for identifying and recovering from a temporary sensor failure
US9989301B2 (en) 2016-03-21 2018-06-05 Progress Rail Locomotive Inc. System and method for controlling flow of fluid
US10401207B2 (en) 2016-09-14 2019-09-03 GE Oil & Gas UK, Ltd. Method for assessing and managing sensor uncertainties in a virtual flow meter
US11940318B2 (en) 2016-09-27 2024-03-26 Baker Hughes Energy Technology UK Limited Method for detection and isolation of faulty sensors
CN107388032A (zh) * 2017-07-04 2017-11-24 大连理工大学 一种液氮射流状态稳定流量的调控方法
JP6926986B2 (ja) * 2017-11-24 2021-08-25 株式会社デンソーウェーブ 流速推定装置及び流速推定方法
WO2022026261A1 (fr) * 2020-07-27 2022-02-03 Chart Inc. Ensemble débitmètre
CN116758493B (zh) * 2023-08-22 2023-11-21 中国水利水电第七工程局有限公司 基于图像处理的隧道施工监测方法、装置及可读存储介质

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4881412A (en) * 1985-08-14 1989-11-21 Ronald Northedge Flow meters
WO2002044664A1 (fr) * 2000-11-29 2002-06-06 Expro North Sea Limited Débitmètre multiphase utilisant des différentiels de pression multiples
WO2002046705A2 (fr) * 2000-12-04 2002-06-13 Weatherford/Lamb, Inc. Procede et appareil permettant de determiner des debits de constituants, pour un ecoulement multiphase

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3635084A (en) * 1969-08-28 1972-01-18 Simmonds Precision Products Mass fuel flow measurement system
FR2386021A1 (fr) * 1977-03-31 1978-10-27 Flopetrol Ste Auxil Product Pe Procede et dispositif de determination du debit volumetrique de chaque phase d'un melange diphasique
US4272982A (en) * 1979-10-17 1981-06-16 Texaco Inc. Fluid flow meter for mixed liquid and gas
JPS58190719A (ja) * 1982-04-30 1983-11-07 Nippon Steel Corp 気液・固液・固気等二相流流量計
US4776210A (en) * 1987-06-03 1988-10-11 Atlantic Richfield Company Multiphase fluid flow measurement systems and methods
US4835456A (en) * 1988-02-01 1989-05-30 Quantum Dynamics Company, Inc. Cryogenic density and mass-flow measurement system
GB2286463A (en) * 1994-02-14 1995-08-16 Boc Group Plc Fluid flow measurement
US5400657A (en) * 1994-02-18 1995-03-28 Atlantic Richfield Company Multiphase fluid flow measurement
US5861755A (en) * 1995-11-06 1999-01-19 The United States Of America As Represented By The Adminstrator Of National Aeronautics And Space Administration Two-phase quality/flow meter
US5991696A (en) * 1997-07-11 1999-11-23 American Air Liquide Inc. Method for intelligent data acquisition in a measurement system
US6422092B1 (en) * 1998-09-10 2002-07-23 The Texas A&M University System Multiple-phase flow meter
US6646564B1 (en) 2001-03-07 2003-11-11 L'air Liquide Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude System and method for remote management of equipment operating parameters

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4881412A (en) * 1985-08-14 1989-11-21 Ronald Northedge Flow meters
WO2002044664A1 (fr) * 2000-11-29 2002-06-06 Expro North Sea Limited Débitmètre multiphase utilisant des différentiels de pression multiples
WO2002046705A2 (fr) * 2000-12-04 2002-06-13 Weatherford/Lamb, Inc. Procede et appareil permettant de determiner des debits de constituants, pour un ecoulement multiphase

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103206995A (zh) * 2013-04-11 2013-07-17 西安拓普电气有限责任公司 适用于厂房条件的气体流量测量装置及测试方法
CN103206995B (zh) * 2013-04-11 2015-08-19 西安拓普电气有限责任公司 适用于厂房条件的气体流量测量装置及测试方法

Also Published As

Publication number Publication date
EP1533596B1 (fr) 2017-11-22
US20050103093A1 (en) 2005-05-19
US7054764B2 (en) 2006-05-30
EP1533596A3 (fr) 2007-02-28
JP2005134375A (ja) 2005-05-26

Similar Documents

Publication Publication Date Title
EP1533596B1 (fr) Surveillance du débit avec un appareil de contrôle du débit
CN109344436A (zh) 一种大型复杂天然气管网系统在线仿真方法
CN100552588C (zh) 调节器流量测量装置
CN111486930B (zh) 一种天然气能量计量赋值核查方法及系统
CN104266702B (zh) 多相湿气流流量与相含率在线测量方法及装置
CN101014917A (zh) 用于流量测量和确认质量流量控制器有效性的方法和系统
EP1913449A2 (fr) Dispositif et architecture de gestion de biens sur le terrain
US20220001578A1 (en) Methods and compositions for delivery of carbon dioxide
CN101855495B (zh) 用于控制致冷剂温度的设备和方法
CN101449224B (zh) 用于输气管线的压力设定法
RU2344288C2 (ru) Способ определения продуктивности группы скважин
Stoots et al. Thermal Energy Delivery System Design Basis Report
CN106840733A (zh) 一种空调机组性能在线检测方法及其检测设备
KR102418408B1 (ko) 열수요 시계열 데이터에 기반한 지역난방열공급망의 실시간 해석 방법 및 장치
GB2509108A (en) Method and apparatus for flow measurement
CN111426113B (zh) 一种冷能供应系统的冷源液化天然气的流量控制方法
Velichko et al. The development of solar-powered gas metering units equipped with radio or 3g based telemetry systems
Jin et al. Characteristics of R-123 two-phase flow through micro-scale short tube orifice for design of a small cooling system
Stone et al. Water flow rates from a site-specific irrigation system
KR100497909B1 (ko) 유무선인터넷을 이용한 냉각수계 자동 모니터링 시스템
KR101391618B1 (ko) 압축성 유체 분배 시스템의 누설 감지를 위한 시스템, 제어장치 및 방법
Shtern et al. Intelligent system and electron components for controlling individual heat consumption
EP4261511A1 (fr) Procédé de monitorage de réseau et réseau de chauffage
CN112257014B (zh) 一种低压饱和蒸汽管道压力的计算方法及系统
CN215447100U (zh) 一种低温水箱

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL HR LT LV MK

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL HR LT LV MK

17P Request for examination filed

Effective date: 20070312

AKX Designation fees paid

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

17Q First examination report despatched

Effective date: 20110610

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

REG Reference to a national code

Ref country code: DE

Ref legal event code: R079

Ref document number: 602004052076

Country of ref document: DE

Free format text: PREVIOUS MAIN CLASS: G01F0001740000

Ipc: F25D0029000000

RIC1 Information provided on ipc code assigned before grant

Ipc: F25D 29/00 20060101AFI20170622BHEP

Ipc: G01F 1/74 20060101ALI20170622BHEP

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20170728

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 948805

Country of ref document: AT

Kind code of ref document: T

Effective date: 20171215

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602004052076

Country of ref document: DE

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20171122

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 948805

Country of ref document: AT

Kind code of ref document: T

Effective date: 20171122

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180222

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180223

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602004052076

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20180823

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602004052076

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20180930

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180927

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190402

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180927

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180930

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180930

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180930

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171122

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20040927

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230504

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20230803

Year of fee payment: 20