EP1479752A3 - Low emission diesel lubricant with improved corrosion protection - Google Patents

Low emission diesel lubricant with improved corrosion protection Download PDF

Info

Publication number
EP1479752A3
EP1479752A3 EP04252592A EP04252592A EP1479752A3 EP 1479752 A3 EP1479752 A3 EP 1479752A3 EP 04252592 A EP04252592 A EP 04252592A EP 04252592 A EP04252592 A EP 04252592A EP 1479752 A3 EP1479752 A3 EP 1479752A3
Authority
EP
European Patent Office
Prior art keywords
low emission
hydrocarbyl
emission diesel
lubricant
provides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP04252592A
Other languages
German (de)
French (fr)
Other versions
EP1479752A2 (en
EP1479752B1 (en
Inventor
Willem Van Dam
Gene Spala
Peter Kleijwegt
Jeroen Van Leeuwen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron Oronite Technology BV
Chevron Oronite Co LLC
Original Assignee
Chevron Oronite Technology BV
Chevron Oronite Co LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Oronite Technology BV, Chevron Oronite Co LLC filed Critical Chevron Oronite Technology BV
Publication of EP1479752A2 publication Critical patent/EP1479752A2/en
Publication of EP1479752A3 publication Critical patent/EP1479752A3/en
Application granted granted Critical
Publication of EP1479752B1 publication Critical patent/EP1479752B1/en
Anticipated expiration legal-status Critical
Active legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M163/00Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/142Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings polycarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/144Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28Amides; Imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40Low content or no content compositions
    • C10N2030/42Phosphor free or low phosphor content compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40Low content or no content compositions
    • C10N2030/43Sulfur free or low sulfur content compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40Low content or no content compositions
    • C10N2030/45Ash-less or low ash content
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/50Emission or smoke controlling properties
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • C10N2040/252Diesel engines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2060/00Chemical after-treatment of the constituents of the lubricating composition
    • C10N2060/14Chemical after-treatment of the constituents of the lubricating composition by boron or a compound containing boron

Abstract

The present invention provides engine lubricants for low emission diesel engines featuring low levels of ash, sulfur and phosphorus. Specifically, this invention provides a low emission diesel lubricant comprising from about 0 wt. % to about 1.2 wt. % ash; from about 0.1 wt. % to about 0.5 wt. % sulfur; and from about 0.02 wt. % to about 0.1 wt. % phosphorus. Said lubricant may also comprise a novel unsulfurized, carboxylate-containing additive for lubricating oils, comprising a mixture of alkaline earth metal salts (hydrocarbyl phenate/hydrocarbyl salicylate) and a reduced amount of unreacted hydrocarbyl phenols, in which said hydrocarbyl salicylate is primarily single-aromatic-ring hydrocarbyl salicylate. The invention also provides a method for producing said additive and said low emission diesel lubrificant (LEDL).
EP04252592A 2003-05-22 2004-05-04 Low emission diesel lubricant with improved corrosion protection Active EP1479752B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US444333 1995-05-18
US10/444,333 US20040235682A1 (en) 2003-05-22 2003-05-22 Low emission diesel lubricant with improved corrosion protection

Publications (3)

Publication Number Publication Date
EP1479752A2 EP1479752A2 (en) 2004-11-24
EP1479752A3 true EP1479752A3 (en) 2009-10-28
EP1479752B1 EP1479752B1 (en) 2011-07-27

Family

ID=33098025

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04252592A Active EP1479752B1 (en) 2003-05-22 2004-05-04 Low emission diesel lubricant with improved corrosion protection

Country Status (5)

Country Link
US (1) US20040235682A1 (en)
EP (1) EP1479752B1 (en)
JP (1) JP4921697B2 (en)
CA (1) CA2467843C (en)
SG (1) SG116548A1 (en)

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* Cited by examiner, † Cited by third party
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JP4578115B2 (en) * 2004-02-04 2010-11-10 Jx日鉱日石エネルギー株式会社 Lubricating oil composition
JP4515797B2 (en) * 2004-03-19 2010-08-04 新日本石油株式会社 Lubricating oil composition for diesel engines
US20060223724A1 (en) * 2005-03-29 2006-10-05 Gatto Vincent J Lubricating oil composition with reduced phosphorus levels
US7956022B2 (en) * 2005-07-29 2011-06-07 Chevron Oronite Company Llc Low sulfur metal detergent-dispersants
US7951760B2 (en) * 2005-07-29 2011-05-31 Chevron Oronite S.A. Overbased alkali metal alkylhydroxybenzoates having low crude sediment
US8030258B2 (en) * 2005-07-29 2011-10-04 Chevron Oronite Company Llc Overbased alkaline earth metal alkylhydroxybenzoates having low crude sediment
JP5438251B2 (en) * 2005-08-29 2014-03-12 シェブロン・オロナイト・カンパニー・エルエルシー Lubricating oil composition for internal combustion engines
ATE552328T1 (en) * 2005-11-03 2012-04-15 Infineum Int Ltd LINEAR DIBLOCK COPOLYMERS AS ANTI-WEAR ADDITIVES FOR LUBRICANTS IN COMBUSTION ENGINE CRANKCASES
US20070105731A1 (en) * 2005-11-04 2007-05-10 Chin Chu Lubricating oil compositions
US7981846B2 (en) * 2005-11-30 2011-07-19 Chevron Oronite Company Llc Lubricating oil composition with improved emission compatibility
US20080146473A1 (en) * 2006-12-19 2008-06-19 Chevron Oronite Company Llc Lubricating oil with enhanced piston cleanliness control
US8747650B2 (en) * 2006-12-21 2014-06-10 Chevron Oronite Technology B.V. Engine lubricant with enhanced thermal stability
US7838474B2 (en) * 2007-10-31 2010-11-23 Chevron Oronite Company Llc Lubricating oil compositions comprising a biodiesel fuel and a detergent
JP5823392B2 (en) * 2009-08-06 2015-11-25 ザ ルブリゾル コーポレイションThe Lubrizol Corporation Lubricating composition containing asphaltene dispersant
CN102782102B (en) * 2009-12-14 2014-09-24 卢布里佐尔公司 Lubricating composition containing an antiwear agent
ES2673725T3 (en) * 2012-03-01 2018-06-25 Infineum International Limited Lubrication method of a marine engine
US9359573B2 (en) * 2012-08-06 2016-06-07 Exxonmobil Research And Engineering Company Migration of air release in lubricant base stocks
JP5831440B2 (en) 2012-12-17 2015-12-09 株式会社ダイヤメット Raw material powder for powder metallurgy
US10370320B2 (en) * 2017-12-30 2019-08-06 Rohm And Haas Electronic Materials Llc Purification methods

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US6162770A (en) * 1998-01-30 2000-12-19 Chevron Chemical Company Llc Unsulfurized alkali metal-free, additive for lubricating oils
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CA2385969A1 (en) * 2001-05-11 2002-11-11 Infineum International Limited Lubricating oil composition

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EP0370555A2 (en) * 1988-11-23 1990-05-30 Shell Internationale Researchmaatschappij B.V. A process for the separation of a phenol
EP0675191A2 (en) * 1994-03-30 1995-10-04 Cosmo Research Institute Petroleum additive and process for producing alkaline earth metal salt of an aromatic hydroxy-carboxylic acid
US6162770A (en) * 1998-01-30 2000-12-19 Chevron Chemical Company Llc Unsulfurized alkali metal-free, additive for lubricating oils
EP1167497A2 (en) * 2000-06-02 2002-01-02 Chevron Oronite Japan Limited Diesel motor lubricating oil composition
CA2385969A1 (en) * 2001-05-11 2002-11-11 Infineum International Limited Lubricating oil composition

Also Published As

Publication number Publication date
US20040235682A1 (en) 2004-11-25
CA2467843C (en) 2013-08-06
JP4921697B2 (en) 2012-04-25
SG116548A1 (en) 2005-11-28
JP2004346326A (en) 2004-12-09
EP1479752A2 (en) 2004-11-24
CA2467843A1 (en) 2004-11-22
EP1479752B1 (en) 2011-07-27

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