EP1448932B1 - Vorrichtung für eine brennkammer einer gasturbine - Google Patents

Vorrichtung für eine brennkammer einer gasturbine Download PDF

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Publication number
EP1448932B1
EP1448932B1 EP02775661A EP02775661A EP1448932B1 EP 1448932 B1 EP1448932 B1 EP 1448932B1 EP 02775661 A EP02775661 A EP 02775661A EP 02775661 A EP02775661 A EP 02775661A EP 1448932 B1 EP1448932 B1 EP 1448932B1
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EP
European Patent Office
Prior art keywords
combustion chamber
combination
cover
control element
cover means
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP02775661A
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English (en)
French (fr)
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EP1448932A1 (de
Inventor
Bertil JÖNSSON
Patrik Johansson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GKN Aerospace Sweden AB
Original Assignee
Volvo Aero AB
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Filing date
Publication date
Application filed by Volvo Aero AB filed Critical Volvo Aero AB
Publication of EP1448932A1 publication Critical patent/EP1448932A1/de
Application granted granted Critical
Publication of EP1448932B1 publication Critical patent/EP1448932B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/02Continuous combustion chambers using liquid or gaseous fuel characterised by the air-flow or gas-flow configuration
    • F23R3/26Controlling the air flow
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/28Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply
    • F23R3/286Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply having fuel-air premixing devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/28Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply
    • F23R3/30Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply comprising fuel prevapourising devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/28Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply
    • F23R3/34Feeding into different combustion zones
    • F23R3/343Pilot flames, i.e. fuel nozzles or injectors using only a very small proportion of the total fuel to insure continuous combustion

Definitions

  • the present invention relates to the combination of a combution chamber and a device for the combustion chamber of a gas turbine for controlling the intake of gas into the combustion zone of the combustion chamber, the device comprising a control element which is arranged outside the combustion chamber and which in turn comprises a first means of covering at least a first inlet to the combustion zone, the said means being displaceable in relation to the combustion chamber, and a means of supporting the control element connected to the cover means.
  • gas turbine relates to a unit which comprises at least one turbine and a compressor driven thereby, together with a combustion chamber.
  • Gas turbines are used, for example, as engines for vehicles and aircraft, as prime movers for ships and in electricity-generating power stations.
  • the gas delivered to the combustion chamber by way of the inlet is usually air, but other gases are also conceivable.
  • combustion zone relates to a section in proximity to and at least substantially in front of the fuel distributor(s) in the longitudinal direction of the combustion chamber.
  • the combustion zone is in turn usually divided up into primary zone and dilution zone in the direction away from the fuel distributor.
  • US 4,944,149 describes a device for a combustion chamber for controlling the air intake to the dilution zone of the combustion chamber, with the object of reducing NOx emissions.
  • the device comprises a rotatable ring, which extends around the combustion chamber in the intended dilution zone thereof.
  • the ring has a plurality of through-openings and the combustion chamber wall has correspondingly shaped openings. By bringing the ring openings over the openings in the combustion chamber wall, ducts are formed for the air from the outside to the inside of the combustion chamber.
  • a temperature sensor is provided for controlling the rotation of the ring. Due to the very high temperature around the combustion chamber, the constituent parts of the device are subject to great stress, which means that the device has a relatively short service life.
  • Document US-A-3930369 also relates to a combustion chamber of a gas turbine with a device for controlling the intake of gas to the combustion zone.
  • An object of the invention is to provide a device for controlling the intake of air to a combustion chamber of a gas turbine which creates the prerequisites for greater operating reliability than in the state of the art. It is further intended to provide a device having an increased service life.
  • control element can be accommodated in a relatively cool part of the gas turbine.
  • the structure in which the means of support is accommodated forms part of the combustion chamber cover.
  • the combustion chamber cover has a considerably lower temperature than the wall of the combustion chamber or the flame tube.
  • the temperature of the flame tube wall is usually 5 to 10 times higher than the temperature of the combustion chamber cover.
  • the means of support is accommodated in the said structure at least largely concentrically in relation to the center line of the combustion chamber. This creates the prerequisites for a simple and reliable control of the control element.
  • the means of support is accommodated in the said structure radially outside a pilot distributor to the combustion chamber.
  • the pilot distributor is usually arranged so that it extends forwards from the combustion chamber cover into the combustion chamber, along a center line through the combustion chamber.
  • the pilot distributor is therefore arranged in an opening through the combustion chamber cover in an extension of the combustion chamber center line and the said opening is therefore suitable for receiving the means of support.
  • the first cover means has at least one aperture, which extends at least largely radially through the wall thereof. This creates the prerequisites for a simple and reliable control unit construction.
  • the said aperture in the cover means is preferably designed, together with the said first inlet to the combustion chamber, to form a continuous duct for the gas from a position outside the combustion chamber to the inside of the combustion chamber.
  • the first cover means comprises at least two sets of the said apertures, and a first set of the said sets of apertures is arranged at a distance from the second set of apertures in the longitudinal direction of the combustion chamber.
  • the prerequisites are thereby created for controlling the air intake to two sets of so-called swirls in the combustion chamber, which are arranged at a distance from one another in the longitudinal direction of the combustion chamber.
  • These swirls are a type of vortex generator for the air and are formed by a plurality of inclined vanes.
  • Fig 1 shows a partially cut away side view of a combustion chamber 1.
  • the combustion chamber represents a so-called low-emission combustion chamber.
  • the combustion chamber comprises a pilot distributor 2, which is arranged centrally, and a plurality, for example five main distributors 3 arranged around the pilot distributor 2.
  • the inside of the combustion chamber 1 is defined by a combustion chamber cover 4, a flame tube 5 and a section 6, arranged between the combustion chamber cover 4 and the flame tube 5, for the inlet of air to the inside of the combustion chamber 1.
  • the pilot distributor 2 and the main distributors 3 are arranged in the combustion chamber cover 4 and open out into the inside of the combustion chamber 1.
  • Three so-called swirls 7-9 are arranged in the air inlet section 6. These swirls 7-9 are a type of vortex generator for the inlet air and are formed by a plurality of inclined vanes arranged in an annular shape.
  • the swirls 7-9 are intended to force the inlet air to rotate, which means that when it enters the inside of the combustion chamber it is impelled radially outwards.
  • the hot combustion gases thereby recirculate towards the center and are responsible for a continuous re-ignition of the fuel.
  • the air inlet section 6 more specifically comprises a primary swirl 7, a secondary swirl 8 and a tertiary swirl 9.
  • the primary swirl 7 is arranged centrally for guiding the air to or around the pilot distributor 2.
  • the secondary swirl 8 is arranged around the main distributors 3 for guiding the air to or around the latter.
  • the tertiary swirl 9 is arranged in front of the secondary swirl 8 in the longitudinal direction of the combustion chamber 1.
  • the fuel to be used is in liquid form. Low emissions can be achieved when the fuel is burnt in gaseous form, higher emissions occurring when the fuel is burnt in droplet form.
  • the emissions are made up, for example, of CO, NOx and unburned HC.
  • the main distributors 3 are used in normal operation and are designed for combustion of the fuel in vaporized form.
  • the pilot distributor 2 is designed to heat up the combustion chamber 1 when starting up a cold engine, so that it is then possible to produce a working flame with the main distributors 3.
  • the fuel from the pilot distributor 2, on the other hand, is burned in liquid form, in the form of droplets.
  • the combustion zone of the combustion chamber 1 is usually divided into primary zone 10 and dilution zone 11 in the direction away from the fuel distributors.
  • a control element 12 is arranged outside the combustion chamber 1 and interacting with the inlets to the said swirls 7-9 with the object of controlling the temperature inside the combustion chamber.
  • the control element 12 is more specifically designed to guide the air flow as it is being delivered to the primary zone and/or the dilution zone.
  • the air flows in a space 36, or a duct, which is situated radially outside the combustion chamber 1.
  • the control element 12 the air can be guided to the inlet to the swirls 7-9 and/or to a number of dilution holes 33 downstream.
  • the control element 12 comprises a first means 13 for covering at least a first inlet to the combustion zone, see also figure 3 .
  • the first cover means 13 is in the shape of a ring or sleeve, which extends around the first inlets to the secondary and the tertiary swirls 8,9.
  • the ring 13 is provided with two sets of apertures 14,15.
  • Each of the sets 14,15 comprises a plurality of apertures in the form of through-openings, which are arranged at a distance from one another in the circumferential direction of the ring.
  • a first set of apertures 14 is arranged at a distance from the second set of apertures 15 in the axial direction of the ring.
  • the control element 12 is designed to be set to two limit positions corresponding to the inlet fully closed and inlet fully open, and to be continuously adjustable in positions between the limit positions for partial closure of the inlets.
  • the control element 12 further comprises a means 16, connected to the ring 13, for supporting the control element, see also figure 2 and 3 .
  • the means of support 16 has a circular cross-sectional shape and more specifically the shape of a tube, or a sleeve.
  • the center line of the circular means of support 16 and the center line of the annular, first cover means 13 coincide.
  • the means of support 16 is further offset in an axial direction in relation to the first cover means 13.
  • the circular means of support 16 has a smaller outside diameter than the annular, first cover means 13 and they are connected to one another by a spoke structure 17.
  • the spoke structure 17 extends in a plane at right angles to the center line of the control element 12.
  • the air to the primary swirl 7 is intended to flow in through the openings between the spokes of the spoke structure.
  • the control element 12 further comprises an annular section 18 having a smaller diameter than the ring 13, see also figure 3 .
  • the annular section 18 is arranged radially inside the ring 13.
  • the annular section 18 is provided with a third set of recesses 19 and is intended for controlling the inlets to the primary swirl 7.
  • the means of support 16 is accommodated in the combustion chamber cover 4, which is arranged at the rear of the combustion zone of the combustion chamber 1, see figure 2 .
  • This means that the means of support is accommodated in a relatively cool part of the gas turbine. In a normal operating situation the temperature can reach 150° in the combustion chamber cover and 800° in the combustion chamber wall near the swirls 7-9.
  • the control element 12 is more specifically accommodated radially outside the pilot distributor 2.
  • the means of support 16 for the control element 12 extends around the pilot distributor 2 and is supported against the combustion chamber cover 4 by its radially outer surface 20.
  • the support comprises slide or roller bearings 21. That is to say there is a gap between the means of support 16 and the pilot distributor 2.
  • the combustion chamber cover 4 contains a section 22 of insulating material.
  • the fact that the insulating section 22 is arranged between the bearing 21 and the outlets of the fuel distributors 2, 3 means that the area of the support is relatively cool.
  • the swirls 7-9 are fixed to the combustion chamber cover by a fastener 23 in the form of a bolt, see figure 1 .
  • the fact that the control element 12 and the swirls 7-9 are respectively supported in and connected to the same structure (the combustion chamber cover) means that they can be centered in relation to one another with great accuracy and any thermal expansion problems can be minimized. This improves the facilities for highly accurate control.
  • a control mechanism 24 is shown in figure 4 .
  • the control mechanism 24 comprises a first rotatable arm 25, which extends through the combustion chamber cover 4.
  • a second arm 26 is fixed to the first arm 25 at an inner end thereof and extends at right angles therefrom.
  • the second arm 26 has a pin 27 at its free end.
  • the said pin 27 is arranged in a groove 28, see also figure 3 , in the control element 12 and more specifically in the spoke structure 17.
  • the control mechanism further comprises an adjusting device 29, which is coupled to the first arm 25 on a rear side of the combustion chamber cover 4 relative to the combustion chamber 1.
  • the adjusting device 29 is designed for turning the arm 25, so that the control element 12 is thereby also turned. Alternatively the turning function can also be achieved by means of a linkage system.
  • the adjusting device 29 in this instance comprises an electric motor, but may also consist of a hydraulic or pneumatic adjusting device.
  • Figure 5 shows a second embodiment of the control element 12', which is a variant of the first embodiment.
  • the control element 12' according to the second embodiment differs from the control element 12 according to the first embodiment in that the control element 12' comprises a further, second cover means 30 in the form of a ring or sleeve, see dashed marks.
  • the second cover means 30 is arranged around the flame tube 5 of the combustion chamber 1 at a distance from the first cover means 13 in the longitudinal direction of the combustion chamber 1 and more specifically in the dilution zone 11 of the combustion chamber.
  • the annular cover means 30 has a set of through-openings 32, which are arranged at a distance from one another in the circumferential direction of the ring and are intended to interact with a number of other inlets 33 to the combustion chamber in the form of so-called dilution holes.
  • the ring 30 is connected to the ring 13 by at least one link 31.
  • Each of the rings 13,30 has at least one extended section 34, 35, which extend towards one another. These extended sections 34,35 are connected to one another by the linkage 31.
  • the second embodiment of the control element is particularly advantageous if it is intended to redistribute the air between primary and dilution zone with a slight variation in the overall pressure gradient.
  • the openings in the rings 13,30 are offset in relation to their corresponding inlet in such a way that when control adjustment occurs the swirl inlets to the swirls 7-9 are exposed whilst the dilution holes 33 are covered over, and vice versa.
  • the fact that the ring 30 is connected by the linkage 31 to the ring 13 furthermore means that the lower part of the flame tube 5 is permitted to move somewhat away from the center without the parts impinging on one another.
  • the means of support 16 described and the first cover means 13 comprise a ring or tube of continuous circumference, but the scope of the invention also encompasses those of broken circumference. Nor are any holes necessary in an axial direction for the means of support 16, which can also feasibly be formed by a solid shaft.
  • the control element 12 can also be arranged so that it is displaceable in an axial direction instead of being rotatable about the center line of the combustion chamber.
  • the spoke structure 17 of the control element 12 must only be regarded as one example and may be replaced, for example, by some other type of wall structure or framework having through-holes or openings.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Combustion Methods Of Internal-Combustion Engines (AREA)
  • Sliding Valves (AREA)
  • Portable Nailing Machines And Staplers (AREA)

Claims (20)

  1. Kombination einer Verbrennungskammer (1) in einer Gasturbine und einer Vorrichtung zur Steuerung des Einlasses von Gas zu der Verbrennungszone (10, 11) der Verbrennungskammer, wobei die Vorrichtung ein Steuerelement (12, 12'), das außerhalb der Verbrennungskammer angeordnet ist, wobei das Steuerelement seinerseits eine erste Einrichtung (13) zur Abdeckung wenigstens eines ersten Einlasses zu der Verbrennungszone umfasst, wobei die erste Abdeckungseinrichtung bezüglich der Verbrennungskammer verschiebbar ist, und eine Einrichtung (16) zur Lagerung des Steuerelements umfasst, die mit der ersten Abdeckungseinrichtung verbunden ist,
    dadurch gekennzeichnet, dass
    die Einrichtung zur Lagerung (16) durch Gleit- oder Wälzlager (21) geführt und in einem Aufbau (4) an der Rückseite der Verbrennungskammer (1) aufgenommen ist, wobei die Einrichtung zur Lagerung (16) in dem Aufbau (4) radial außerhalb eines Steuerverteilers (2) zur Verbrennungskammer aufgenommen ist und sich um den Steuerverteiler (2) herum erstreckt und durch ihre radial äußeren Fläche (20) gegen den Aufbau (4) gehalten ist, wobei die Einrichtung zur Lagerung (16) bezogen auf die erste Abdeckeinrichtung (13) in einer Axialrichtung versetzt angeordnet ist.
  2. Kombination nach Anspruch 1, dadurch gekennzeichnet, dass der Aufbau (4), in dem die Einrichtung zur Lagerung (16) aufgenommen ist, wenigstens einen Teil der Verbrennungskammerabdeckung bildet.
  3. Kombination nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass die Einrichtung zur Lagerung (16) in dem Aufbau wenigstens weitgehend konzentrisch zu der Mittellinie der Verbrennungskammer aufgenommen ist.
  4. Kombination nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Einrichtung zur Lagerung (16) eine kreisförmige Querschnittsform aufweist.
  5. Kombination nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die erste Abdeckungseinrichtung (13) wenigstens eine Öffnung (14, 15) aufweist, die sich wenigstens weitgehend in einer Radialrichtung durch deren Wand erstreckt.
  6. Kombination nach Anspruch 5, dadurch gekennzeichnet, dass die Öffnung (14, 15) in der ersten Abdeckungseinrichtung (13) zusammen mit dem ersten Einlass der Verbrennungskammer so ausgelegt ist, dass sie eine Durchgangsleitung für das Gas von einer Position außerhalb der Verbrennungskammer in das Innere der Verbrennungskammer bilden.
  7. Kombination nach Anspruch 6, dadurch gekennzeichnet, dass die erste Abdeckungseinrichtung (13) wenigstens zwei Sätze der Öffnungen umfasst und dass ein erster Satz der Sätze von Öffnungen (14) in Längsrichtung der Verbrennungskammer in einem Abstand von dem zweiten Satz von Öffnungen (15) angeordnet ist.
  8. Kombination nach einem der Ansprüche 5 bis 7, dadurch gekennzeichnet, dass das Steuerelement (12, 12') einen ringförmigen Abdeckabschnitt (18) zur Abdeckung weiterer Einlässe zu der Verbrennungszone der Verbrennungskammer (1) umfasst, dass der Abdeckabschnitt (18) in einem geringeren Abstand von der Mittellinie des Steuerelements angeordnet ist als die erste Abdeckungseinrichtung (13), und dass der Abdeckabschnitt (18) mit wenigstens einer Öffnung (19) versehen ist.
  9. Kombination nach einem der Ansprüche 5 bis 8, dadurch gekennzeichnet, dass die erste Abdeckungseinrichtung (13) die Form eines Rings aufweist, wobei sich die Öffnung (14, 15) durch die Wand des Rings erstreckt.
  10. Kombination nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die erste Abdeckungseinrichtung (13) bezüglich der Verbrennungskammerwand drehbar ist.
  11. Kombination nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Einrichtung zur Lagerung (16) und die erste Abdeckungseinrichtung (13) miteinander befestigt sind.
  12. Kombination nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass das Steuerelement (12, 12') bezüglich des radial äußeren Aufbaus (4) drehbar ist.
  13. Kombination nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die erste Abdeckungseinrichtung (13) in einem größeren radialen Abstand von der Mittelachse durch das Steuerelement (12, 12') angeordnet ist als die Einrichtung zur Lagerung (16).
  14. Kombination nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass der erste Einlass in der Verbrennungskammerwand, der durch das Steuerelement (12) gesteuert werden soll, einen Gaseinlass zu wenigstens einem Wirbel (8, 9) bildet, der in der Verbrennungskammer angeordnet ist.
  15. Kombination nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass das Steuerelement (12') eine zweite Abdeckungseinrichtung (30) umfasst, die so ausgelegt ist, dass sie wenigstens einen zweiten Einlass (33) zu der Verbrennungszone abdeckt, wobei der zweite Einlass in der Längsrichtung der Verbrennungskammer (1) in einem Abstand von dem ersten Einlass angeordnet ist.
  16. Kombination nach Anspruch 15, dadurch gekennzeichnet, dass die zweite Abdeckungseinrichtung (30) wenigstens eine Öffnung (32) aufweist, die sich wenigstens weitgehend in einer Radialrichtung durch deren Wand erstreckt.
  17. Kombination nach Anspruch 16, dadurch gekennzeichnet, dass die Öffnung (32) in der zweiten Abdeckungseinrichtung (30) so ausgelegt ist, dass sie zusammen mit dem zweiten Einlass (33) zu der Verbrennungskammer eine Durchgangsleitung für das Gas von einer Position außerhalb der Verbrennungskammer zum Inneren der Verbrennungskammer bildet.
  18. Kombination nach Anspruch 16 oder 17, dadurch gekennzeichnet, dass die zweite Abdeckungseinrichtung (30) die Form eines Rings aufweist, wobei die Öffnung (32) sich durch die Wand des Rings erstreckt.
  19. Kombination nach einem der Ansprüche 15 bis 18, dadurch gekennzeichnet, dass die zweite Abdeckeinrichtung (30) bezüglich der Verbrennungskammerwand drehbar ist.
  20. Kombination nach Anspruch 19, dadurch gekennzeichnet, dass die zweite Abdeckungseinrichtung (30) mit der ersten Abdeckungseinrichtung (13) durch wenigstens einen Arm (31, 34, 35) verbunden ist.
EP02775661A 2001-11-20 2002-10-10 Vorrichtung für eine brennkammer einer gasturbine Expired - Lifetime EP1448932B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SE0103860 2001-11-20
SE0103860A SE523082C2 (sv) 2001-11-20 2001-11-20 Anordning vid en brännkammare hos en gasturbin för reglering av inflöde av gas till brännkammarens förbränningszon
PCT/SE2002/001854 WO2003044433A1 (en) 2001-11-20 2002-10-10 A device for a combustion chamber of a gas turbine

Publications (2)

Publication Number Publication Date
EP1448932A1 EP1448932A1 (de) 2004-08-25
EP1448932B1 true EP1448932B1 (de) 2011-07-27

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EP02775661A Expired - Lifetime EP1448932B1 (de) 2001-11-20 2002-10-10 Vorrichtung für eine brennkammer einer gasturbine

Country Status (8)

Country Link
US (1) US7096675B2 (de)
EP (1) EP1448932B1 (de)
AT (1) ATE518100T1 (de)
AU (1) AU2002343910A1 (de)
CA (1) CA2467334C (de)
RU (1) RU2301943C2 (de)
SE (1) SE523082C2 (de)
WO (1) WO2003044433A1 (de)

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US20050144929A1 (en) 2005-07-07
US7096675B2 (en) 2006-08-29
CA2467334A1 (en) 2003-05-30
SE0103860D0 (sv) 2001-11-20
AU2002343910A1 (en) 2003-06-10
RU2004118421A (ru) 2005-07-10
SE0103860L (sv) 2003-05-21
WO2003044433A1 (en) 2003-05-30
SE523082C2 (sv) 2004-03-23
ATE518100T1 (de) 2011-08-15
RU2301943C2 (ru) 2007-06-27
CA2467334C (en) 2010-09-28
EP1448932A1 (de) 2004-08-25

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