EP1423077B1 - Belted absorbent article and a method of producing a laminate for use as belt material - Google Patents

Belted absorbent article and a method of producing a laminate for use as belt material Download PDF

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Publication number
EP1423077B1
EP1423077B1 EP02759039A EP02759039A EP1423077B1 EP 1423077 B1 EP1423077 B1 EP 1423077B1 EP 02759039 A EP02759039 A EP 02759039A EP 02759039 A EP02759039 A EP 02759039A EP 1423077 B1 EP1423077 B1 EP 1423077B1
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EP
European Patent Office
Prior art keywords
outer layer
bonding
absorbent article
laminate
belt members
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP02759039A
Other languages
German (de)
French (fr)
Other versions
EP1423077A1 (en
Inventor
Christian Almberg
Liljana Kusibojoska
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Essity Hygiene and Health AB
Original Assignee
SCA Hygiene Products AB
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Filing date
Publication date
Application filed by SCA Hygiene Products AB filed Critical SCA Hygiene Products AB
Publication of EP1423077A1 publication Critical patent/EP1423077A1/en
Application granted granted Critical
Publication of EP1423077B1 publication Critical patent/EP1423077B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/144Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers using layers with different mechanical or chemical conditions or properties, e.g. layers with different thermal shrinkage, layers under tension during bonding
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/45Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
    • A61F13/49Absorbent articles specially adapted to be worn around the waist, e.g. diapers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/56Supporting or fastening means
    • A61F13/64Straps, belts, ties or endless bands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/28Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B32B37/065Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method resulting in the laminate being partially bonded
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/14Velocity, e.g. feed speeds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/16Tension
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00Treatment by energy or chemical effects
    • B32B2310/028Treatment by energy or chemical effects using vibration, e.g. sonic or ultrasonic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00Treatment by energy or chemical effects
    • B32B2310/08Treatment by energy or chemical effects by wave energy or particle radiation
    • B32B2310/0806Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation
    • B32B2310/0843Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation using laser
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2555/00Personal care
    • B32B2555/02Diapers or napkins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/0076Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised in that the layers are not bonded on the totality of their surfaces
    • B32B37/0084Point bonding

Definitions

  • the present invention refers to an absorbent article such as a diaper and an incontinence guard comprising a liquid permeable topsheet, a liquid impermeable backsheet and an absorbent body enclosed therebetween, said article having a front portion, a rear portion and a crotch portion therebetween, and further is provided with a pair of belt members attached to the rear portion , alternatively to the front portion, of the article and which are intended to be fastened together around the waist of the wearer and where said front portion, alternatively said rear portion, is provided with fastening means intended to be fastened to the belt members, in such a way that the article will assume a pantlike shape, where the belt members form a part of the waist portions of the pant.
  • the invention further refers to a method of producing a flexible laminate for use as belt members on an absorbent article such as a diaper and an incontinence guard
  • Diapers and incontinence guards for incontinent adults usually have a garment portion holding an absorbent body in place against the user's body and attachment means which hold the garment portion in place also when the user is moving.
  • a common type of attachment means are adhesive tapes or hook and loop fasteners of the touch-and-close type which directly attach the front and rear portions of the absorbent article to each other. It is further known, through e g EP-A-0 287 388 , EP-A-0 409 307 , EP-A-0 605 012 and FR-A-2 586 558 , to attach the front and rear portions of the article by means of a belt.
  • the belt members are usually attached to the rear portion of the diaper and are intended to be fastened together around the waist of the wearer and fastening means provided at the front portion of the diaper are then intended to be fastened to the outside of the belt members.
  • the belt provides improved possibilities to adjust the fit of the diaper.
  • the belt further provides a simplified change of diaper or incontinence guard, especially when the wearer is standing.
  • the outside of the belt should serve as a receiving surface for the fastening means provided on one of the belt members and on the front portion of the diaper or incontinence guard.
  • the outside of the belt should serve as a loop material cooperating with a hook material constituting said fastening means.
  • a nonwoven material is from cost point of view preferred to use as a loop material, but a substantially plane and smooth nonwoven material does not always provide the necessary shear and peel strength required to withstand the forces applied thereto during normal use of the article.
  • a shear force is applied in a plane substantially parallel to the connected surfaces of the hook and loop elements, while a peel force is applied in a direction substantially perpendicular to the connected surfaces of the hook and loop elements.
  • WO 97/19665 discloses a loop fastening material in the form of a creped nonwoven layer attached to a support layer by a bonding pattern provided by heat or ultrasonic. The creping of the material is told to improve the loop function of the material. There is no disclosure of this material being used as a belt material.
  • An object of the present invention is to provide a belt for absorbent articles which is comfortable to wear, is resistant to tearing and which has an improved loop function.
  • the belt members comprise a flexible laminate of at least three layers, a first outer layer, a middle layer and a second outer layer of fibrous material bonded together in a bonding pattern provided by ultrasonic, laser and/or heat, said bonding pattern having a bonding area of no more than 10% , said first outer layer and said middle layer of the laminate having a creped structure of a plurality of raised areas separated by a plurality of non-raised area formed by the bonding sites of said bonding pattern, wherein the creped structure of the first outer layer is more distinct with a greater height of said raised areas as compared to the middle layer.
  • the second outer layer of said laminate is substantially smooth and uncreped.
  • the second outer layer of the laminate is preferably used as the internal side of the belt members intended to be facing the wearer, while the first outer layer of the laminate is used as the external side of the belt members intended to act as receiving surface for said fastening means, and is especially used as a loop material for a complementary hook material of a hook-and-loop type fastening means.
  • the bonding pattern has a bonding area of no more than 8% and preferably no more than 5%
  • the bonding pattern has a tightness of bonding sites of between 1 and 15 bonding sites per cm 2 and preferably between 1 and 10 bonding sites per cm 2 .
  • said middle layer is a relatively tear strong fibrous material comprising continuous filaments, such as a spunbond and/or meltblown material.
  • the invention further refers to a method of producing a flexible laminate for use as belt material on an absorbent article such as a diaper and an incontinence guard, said method comprising the steps of: binding together at least three layers, a first outer layer, a middle layer and a second outer layer of fibrous material in a bonding pattern provided by ultrasonic, laser and/or heat, said bonding pattern having a bonding area of no more than 10% , said layers of the laminate exhibiting different web tensions and/or web speeds during bonding, so that said first outer layer exhibits the lowest web tension and/or lowest web speed, the second outer layer exhibits the highest web tension and/or highest web speed and the middle layer exhibits a web tension and/or web speed that is higher than that of the first outer layer and lower than that of the second outer layer.
  • the second outer layer has a web tension and/or web speed during bonding that is between 15 and 50% and preferably between 18 and 33% higher than that of the first outer layer.
  • the middle layer has a web tension and/or web speed during bonding that is between 5 and 40% and preferably between 9 and 18% higher than that of the first outer layer.
  • Fig. 1 of the drawings shows an embodiment of a diaper or incontinence guard 1 comprising a liquid permeable topsheet 2, a liquid impermeable backsheet 3 and an absorbent body 4 enclosed therebetween.
  • the liquid permeable topsheet 2 can be any material used for this purpose, for example a nonwoven material, such as a spunbond material of continuous filaments, a meltblown material, a thermobonded fibrous web such as a carded fibrous web.
  • the topsheet may also be a layer of so called tow fibers bonded in a bonding pattern or a perforated plastic film.
  • the liquid impermeable backsheet 3 may also be any material used for this purpose, such as a plastic film, a nonwoven material coated with a liquid impervious material, a hydrophobic nonwoven material which resists liquid penetration and/or a laminate of plastic film and nonwoven material. Breathable materials which are permeable to air and water vapour but which resist liquid penetration at least up to a certain pressure may also be used as backsheet materials.
  • the topsheet 2 and the backsheet material 3 have a somewhat greater extension in the plane than the absorbent body 4 and extends outside the edges thereof.
  • the layers 2 and 3 are connected to each other within the projecting portions thereof, e g by gluing or welding by heat or ultrasonic.
  • the absorbent body 4 can be of any kind used for this purpose.
  • Examples of commonly used absorbent materials are cellulosic fluff pulp, tissue layers, highly absorbent polymers (so called superabsorbents), absorbent foam materials, absorbent nonwoven materials or the like. It is common to combine cellulosic fluff pulp with superabsorbents in an absorbent body. It is also common to have absorbent bodies comprising layers of different material with different properties with respect to liquid acquisition capacity, liquid distribution capacity and storage capacity. It is well-known to the person skilled in the art and does therefore not have to be described in detail.
  • the thin absorbent bodies which are common in for example baby diapers and incontinence guards often comprise a compressed mixed or layered structure of cellulosic fluff pulp and superabsorbent.
  • the diaper is intended to enclose the lower part of the wearer's trunk like a pair of absorbent pants. It comprises a front portion 5 intended during use to be worn on the front part of the user's body, a rear portion 6 intended during use to be worn on the rear part of the user's body, and a more narrow crotch portion 7 located between the front and rear portions and which is intended to be worn in the crotch part of the user between the legs.
  • the front portion 5 is provided with a pair of tabs 8 carrying attachment means such as a hook material 9 of a so called hook-and-loop type fastener or other type of attachment means such as adhesive tape.
  • hook material is used to designate the portion of a mechanical fastening means having engaging "hook” element.
  • shape of the engaging elements is not intended to limit the shape of the engaging elements to include only “hooks” but encompasses any shape of engaging elements, unidirectional or bidirectional, known in the art to mechanically engage a complementary loop fastening material.
  • a pair of belt members 10a and b are with one end attached, e g glued or ultrasonically welded to the rear part 6 of the diaper.
  • the belt members 10 a, b are with their opposite ends intended to be fastened together, e g by a tab 11 on one belt member 10a, said tab carrying a hook material 12 of a so called hook-and-loop type fastener.
  • the hook material 12 on the tab 11 is intended to attach to the outside of the opposite belt member 10 b.
  • hook-and-loop type fastener 12 there may be another type of optional attachment means, such as adhesive tape.
  • the tabs 8 carrying a hook material or corresponding attachment means of the front portion 5 are intended to be attached to the outside of the belt members 10 a, b in order to fasten together the diaper to the desired pantlike shape.
  • the belt members 10 a, b are attached to the front portion 5 of the diaper and are then fastened together on the back of the wearer.
  • Tabs 8 carrying fastening means, for example a hook material or an adhesive tape, are in this case provided at the rear portion 6 of the diaper.
  • the outside of the belt members 10 a, b should act as a reception surface cooperating with the fastening means on tabs 8 and 11.
  • the material on the outside of the belt portions should serve as a loop material.
  • the term "loop" in this respect is not limited only to materials in which discrete, separately formed loops of material are adapted to receive and engage the hook elements of a complementary hook material, but the loop material also includes fibrous nonwoven in which the individual fibers function to engage the hook elements without such fibers being formed into discrete loops.
  • the material on the outside of the belt members 10 a, b should serve as attachment surface for adhesive tapes.
  • Certain nonwoven materials will function both as loop material for hook-and-loop fasteners and as attachments surface admitting refastening of an adhesive tape. This is disclosed in WO 01/00129 .
  • the width of the belt members should be between 5 and 20 cm, preferably between 7 and 15 cm.
  • the belt members according to this invention comprise a flexible laminate of at least three fibrous layers 14, 15 and 16, first and second outer layers 14, 15 and a middle layer 16, of fibrous material bonded together in a bonding pattern 13 provided by ultrasonic, laser and/or heat. At least some of the fibers in the layers of fibrous material should therefore be meltable by such bonding techniques.
  • the bonding pattern 13 should have a bonding area of no more than 10% .
  • the fibrous materials are preferably nonwoven materials, such as spunbond, meltblown, carded bonded webs, thermobonded webs etc.
  • the first outer layer 14 and the middle layer 16 of the laminate have a creped structure of a plurality of raised areas 14a, 16a separated by a plurality of non-raised areas 14b, 16b formed by the bonding sites of said bonding pattern 13.
  • the creped structure of the first outer layer 14 is more distinct with a greater height h of said raised areas 14a as compared to the middle layer 16.
  • the second outer layer 15 of said laminate is substantially plane and uncreped and is preferably used as the internal side of the belt members intended to be facing the wearer, and should therefor be smooth and skin-friendly.
  • the first outer layer 14 of the laminate is used as the external side of the belt members intended to act as receiving surface for said fastening means, and is especially used as a loop material for a complementary hook material of a hook-and-loop type fastening means 8 and 9.
  • the creped structure of the layer 14 will provide an increased bulk and a three-dimensional structure suitable for engaging a hook material.
  • the loop function for the creped material is thus improved as compared to a substantially plane and smooth nonwoven material.
  • nonwoven materials suitable for the first outer layer 14 are spunbond, meltblown, carded bonded materials etc.
  • the other outer layer 15, intended to form an inner layer of the belt facing the wearer, should be of a soft and skin friendly fibrous material.
  • suitable materials are spunbond and meltblown materials, carded bonded materials etc.
  • polymer materials used in the different fibrous materials may be any suited for this purpose, for example polypropylene, polyethylene, polyester and /or so called bicomponent fibers.
  • the middle layer 16 is used as a support layer providing strength and stability to the laminate.
  • the middle layer 16 should be of a relatively tear strong fibrous material, such as a spunbond or meltblown material comprising continuous filaments.
  • the laminate should have a tear strength of at least 22 N. This will make the belt members resist tearing as the belt is tightened around the waist of the wearer. Tests have proven that the tearing frequency at normal use for belts having a tear strength of 21 N and lower was unaccetably high. Preferably the tear strength should be at least 24 N, more preferably at least 25 N and most preferably at least 27N. For those belt having a tear strength of 29 N or higher there were no tearing at all.
  • the tear strength is measured by EDANA test method TEAR 70.3-96 with the modification that a conditioning time of 4h, a temperature of 23°C and a relative humidity of 50% R.H. is used.
  • a bonding area of more than 10% will result in an increased amount of tearing indications or notches and an increased risk for tearing of the belt members.
  • the bonding area should be no more than 8% and more preferably no more than 5%.
  • the bonding pattern comprises a plurality of bonding sites in the form of points, lines, spots or the like arranged in a pattern.
  • the bonding area of a bonding pattern is defined as the amount of the pattern that consists of the bonding sites.
  • the bonding tightness is the number of bonding sites per area unit. It is preferred that the bonding pattern 13 has a bonding tightness of between 1 and 15 bonding sites per cm 2 . Preferably it has a bonding tightness of between 1 and 10 bonding sites per cm 2 . With a high bonding tightness more tearing indications or notches are formed, which will deteriorate the tearing strength.
  • Relatively large bonding sites for example in the form of lines, provides a relatively large bonding area with a smaller number of bonding sites, as compared to a bonding pattern of small bonding sites, for example in the form of points, arranged with a higher bonding tightness. Thus both bonding area and bonding tightness are important.
  • One non-limiting example of a laminate according to the invention is a three-layered laminate:
  • the spunbond layer is used as the middle layer, the carded material having the highest basis weight is creped and intended to be used as outside of the belt and is adapted to act as loop material for a hook-and-loop type fastener and the carded material having the lowest basis weight is used as inner skin-facing side of the belt.
  • the middle spunbond layer is also creped, but with a less distinct creped structure as compared to the carded material intended to be used as outside of the belt.
  • the laminate is bonded by ultrasonic bonding with a bonding area of about 3% and a bonding tightness of about 7 bonding sites per cm 2 .
  • the tear strength is 55N.
  • the method for manufacturing the laminate material according to the invention comprises binding together at least three layers 14, 15 and 16 of fibrous material in a bonding pattern 13 provided by ultrasonic, laser and/or heat in a bonding station 17 schematically illustrated in Fig. 3 .
  • the bonding station 17 in one embodiment of the invention comprises an ultrasonic horn 18 arranged opposite a patterning roll 19.
  • the layers are fed with different web tensions and/or web speeds into the bonding station 17, at which the layer 14 exhibiting the lowest web tension and/or web speed is slowed down and becomes corrugated or creped at the feed end of the bonding station.
  • the layer 15 exhibiting the highest web tension and/or web speed will remain substantially smooth, while the middle layer 16 exhibiting a web tension and/or web speed that is higher than that of the layer 14 but lower than that of the layer 16, will also become corrugated or creped but to a less extent than the layer 14.
  • the laminate is fed from the bonding station with a web tension/web speed that is substantially equal to that of the lowest web tension/web speed, namely that of the layer 14.
  • the second outer layer 15 has a web tension and/or web speed entering the bonding station that is between 15 and 50% and preferably between 18 and 33% higher than that of the first outer layer 14.
  • the middle layer 16 has a web tension and/or web speed entering the bonding station that is between 5 and 40% and preferably between 9 and 18% higher than that of the first outer layer.

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biomedical Technology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Vascular Medicine (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Mechanical Engineering (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)

Abstract

Absorbent article such as a diaper and an incontinence guard provided with a pair of belt members (10a, b) intented to be fastened together around the waist of the wearer by fastening means (11, 12) and where said front portion (5), is provided with fastening means (8, 9) intended to be fastened to the belt members (10a, b), in such a way that the article will assume a pantlike shape, where the belt members (10a, b) form a part of the waist portions of the pant. The belt members (10a, b) comprise a flexible laminate of at least three layers, a first outer layer (14), a middle layer (16) and a second outer layer (15) of fibrous material bonded together in a bonding pattern (13) provided by ultrasonic, laser and/or heat, said bonding pattern (13) having a bonding area of no more than 10 %. The first outer layer (14) and said middle layer (16) have a creped structure of a plurality of raised areas (14a; 16a) separated by a plurality of non-raised areas formed by the bonding sites (13) of said bonding pattern, wherein the creped structure of the first outer layer (14) is more distinct with a greater height of said raised areas (14a) as compared to the middle layer (16).

Description

    Technical field
  • The present invention refers to an absorbent article such as a diaper and an incontinence guard comprising a liquid permeable topsheet, a liquid impermeable backsheet and an absorbent body enclosed therebetween, said article having a front portion, a rear portion and a crotch portion therebetween, and further is provided with a pair of belt members attached to the rear portion , alternatively to the front portion, of the article and which are intended to be fastened together around the waist of the wearer and where said front portion, alternatively said rear portion, is provided with fastening means intended to be fastened to the belt members, in such a way that the article will assume a pantlike shape, where the belt members form a part of the waist portions of the pant. The invention further refers to a method of producing a flexible laminate for use as belt members on an absorbent article such as a diaper and an incontinence guard
  • Background of the invention
  • Diapers and incontinence guards for incontinent adults usually have a garment portion holding an absorbent body in place against the user's body and attachment means which hold the garment portion in place also when the user is moving. A common type of attachment means are adhesive tapes or hook and loop fasteners of the touch-and-close type which directly attach the front and rear portions of the absorbent article to each other. It is further known, through e g EP-A-0 287 388 , EP-A-0 409 307 , EP-A-0 605 012 and FR-A-2 586 558 , to attach the front and rear portions of the article by means of a belt. The belt members are usually attached to the rear portion of the diaper and are intended to be fastened together around the waist of the wearer and fastening means provided at the front portion of the diaper are then intended to be fastened to the outside of the belt members. The belt provides improved possibilities to adjust the fit of the diaper. The belt further provides a simplified change of diaper or incontinence guard, especially when the wearer is standing.
  • One problem with these belts is that they may cause skin irritations to the user, due to that the belt is in direct contact with the skin of the wearer and has to be tightened relatively strongly in order to have a satisfactory fit and security against leakage of the diaper or incontinence guard. By the tight contact and friction between the belt and the skin there will be a mechanic wear of the skin which gives rise to irritation and even skin injuries. It is therefor important that the material used to form the inside of the belt is soft and skin-friendly. Belt materials dealing with this problem are disclosed in WO 00/27330 and in WO 01/00129 .
  • As mentioned above the outside of the belt should serve as a receiving surface for the fastening means provided on one of the belt members and on the front portion of the diaper or incontinence guard. For a hook-and-loop type fastening means the outside of the belt should serve as a loop material cooperating with a hook material constituting said fastening means. A nonwoven material is from cost point of view preferred to use as a loop material, but a substantially plane and smooth nonwoven material does not always provide the necessary shear and peel strength required to withstand the forces applied thereto during normal use of the article. A shear force is applied in a plane substantially parallel to the connected surfaces of the hook and loop elements, while a peel force is applied in a direction substantially perpendicular to the connected surfaces of the hook and loop elements.
  • WO 97/19665 discloses a loop fastening material in the form of a creped nonwoven layer attached to a support layer by a bonding pattern provided by heat or ultrasonic. The creping of the material is told to improve the loop function of the material. There is no disclosure of this material being used as a belt material.
  • Object and most important features of the invention
  • An object of the present invention is to provide a belt for absorbent articles which is comfortable to wear, is resistant to tearing and which has an improved loop function. This has according to the invention been provided by the fact that the belt members comprise a flexible laminate of at least three layers, a first outer layer, a middle layer and a second outer layer of fibrous material bonded together in a bonding pattern provided by ultrasonic, laser and/or heat, said bonding pattern having a bonding area of no more than 10% , said first outer layer and said middle layer of the laminate having a creped structure of a plurality of raised areas separated by a plurality of non-raised area formed by the bonding sites of said bonding pattern, wherein the creped structure of the first outer layer is more distinct with a greater height of said raised areas as compared to the middle layer.
  • According to one embodiment the second outer layer of said laminate is substantially smooth and uncreped.
  • The second outer layer of the laminate is preferably used as the internal side of the belt members intended to be facing the wearer, while the first outer layer of the laminate is used as the external side of the belt members intended to act as receiving surface for said fastening means, and is especially used as a loop material for a complementary hook material of a hook-and-loop type fastening means.
  • According to further preferred embodiments the bonding pattern has a bonding area of no more than 8% and preferably no more than 5%
  • In a further aspect of the invention the bonding pattern has a tightness of bonding sites of between 1 and 15 bonding sites per cm2 and preferably between 1 and 10 bonding sites per cm2.
  • According to one embodiment said middle layer is a relatively tear strong fibrous material comprising continuous filaments, such as a spunbond and/or meltblown material.
  • The invention further refers to a method of producing a flexible laminate for use as belt material on an absorbent article such as a diaper and an incontinence guard, said method comprising the steps of: binding together at least three layers, a first outer layer, a middle layer and a second outer layer of fibrous material in a bonding pattern provided by ultrasonic, laser and/or heat, said bonding pattern having a bonding area of no more than 10% , said layers of the laminate exhibiting different web tensions and/or web speeds during bonding, so that said first outer layer exhibits the lowest web tension and/or lowest web speed, the second outer layer exhibits the highest web tension and/or highest web speed and the middle layer exhibits a web tension and/or web speed that is higher than that of the first outer layer and lower than that of the second outer layer.
  • In one embodiment the second outer layer has a web tension and/or web speed during bonding that is between 15 and 50% and preferably between 18 and 33% higher than that of the first outer layer. According to a further embodiment the middle layer has a web tension and/or web speed during bonding that is between 5 and 40% and preferably between 9 and 18% higher than that of the first outer layer.
  • Description of drawings
  • The invention will in the following be closer described witch reference to an embodiment shown in the accompanying drawings.
    • Fig. 1 shows a schematic perspective view of a belt diaper according to the invention.
    • Fig. 2 shows schematically a cross section through a laminate according to the invention.
    • Fig. 3 is a schematic side view of a device for performing the method according to the invention.
    Description of embodiments
  • Fig. 1 of the drawings shows an embodiment of a diaper or incontinence guard 1 comprising a liquid permeable topsheet 2, a liquid impermeable backsheet 3 and an absorbent body 4 enclosed therebetween. The liquid permeable topsheet 2 can be any material used for this purpose, for example a nonwoven material, such as a spunbond material of continuous filaments, a meltblown material, a thermobonded fibrous web such as a carded fibrous web. The topsheet may also be a layer of so called tow fibers bonded in a bonding pattern or a perforated plastic film.
  • The liquid impermeable backsheet 3 may also be any material used for this purpose, such as a plastic film, a nonwoven material coated with a liquid impervious material, a hydrophobic nonwoven material which resists liquid penetration and/or a laminate of plastic film and nonwoven material. Breathable materials which are permeable to air and water vapour but which resist liquid penetration at least up to a certain pressure may also be used as backsheet materials.
  • The topsheet 2 and the backsheet material 3 have a somewhat greater extension in the plane than the absorbent body 4 and extends outside the edges thereof. The layers 2 and 3 are connected to each other within the projecting portions thereof, e g by gluing or welding by heat or ultrasonic.
  • The absorbent body 4 can be of any kind used for this purpose. Examples of commonly used absorbent materials are cellulosic fluff pulp, tissue layers, highly absorbent polymers (so called superabsorbents), absorbent foam materials, absorbent nonwoven materials or the like. It is common to combine cellulosic fluff pulp with superabsorbents in an absorbent body. It is also common to have absorbent bodies comprising layers of different material with different properties with respect to liquid acquisition capacity, liquid distribution capacity and storage capacity. It is well-known to the person skilled in the art and does therefore not have to be described in detail. The thin absorbent bodies which are common in for example baby diapers and incontinence guards often comprise a compressed mixed or layered structure of cellulosic fluff pulp and superabsorbent.
  • The diaper is intended to enclose the lower part of the wearer's trunk like a pair of absorbent pants. It comprises a front portion 5 intended during use to be worn on the front part of the user's body, a rear portion 6 intended during use to be worn on the rear part of the user's body, and a more narrow crotch portion 7 located between the front and rear portions and which is intended to be worn in the crotch part of the user between the legs. The front portion 5 is provided with a pair of tabs 8 carrying attachment means such as a hook material 9 of a so called hook-and-loop type fastener or other type of attachment means such as adhesive tape.
  • The term "hook material" is used to designate the portion of a mechanical fastening means having engaging "hook" element. However it is not intended to limit the shape of the engaging elements to include only "hooks" but encompasses any shape of engaging elements, unidirectional or bidirectional, known in the art to mechanically engage a complementary loop fastening material.
  • A pair of belt members 10a and b are with one end attached, e g glued or ultrasonically welded to the rear part 6 of the diaper. The belt members 10 a, b are with their opposite ends intended to be fastened together, e g by a tab 11 on one belt member 10a, said tab carrying a hook material 12 of a so called hook-and-loop type fastener. The hook material 12 on the tab 11 is intended to attach to the outside of the opposite belt member 10 b. Instead of hook-and-loop type fastener 12 there may be another type of optional attachment means, such as adhesive tape.
  • The tabs 8 carrying a hook material or corresponding attachment means of the front portion 5 are intended to be attached to the outside of the belt members 10 a, b in order to fasten together the diaper to the desired pantlike shape.
  • In an alternative embodiment the belt members 10 a, b are attached to the front portion 5 of the diaper and are then fastened together on the back of the wearer. Tabs 8 carrying fastening means, for example a hook material or an adhesive tape, are in this case provided at the rear portion 6 of the diaper.
  • The outside of the belt members 10 a, b should act as a reception surface cooperating with the fastening means on tabs 8 and 11. For hook-and-loop fasteners the material on the outside of the belt portions should serve as a loop material. The term "loop" in this respect is not limited only to materials in which discrete, separately formed loops of material are adapted to receive and engage the hook elements of a complementary hook material, but the loop material also includes fibrous nonwoven in which the individual fibers function to engage the hook elements without such fibers being formed into discrete loops.
  • For tape fasteners the material on the outside of the belt members 10 a, b should serve as attachment surface for adhesive tapes. Certain nonwoven materials will function both as loop material for hook-and-loop fasteners and as attachments surface admitting refastening of an adhesive tape. This is disclosed in WO 01/00129 .
  • The width of the belt members should be between 5 and 20 cm, preferably between 7 and 15 cm.
  • The belt members according to this invention comprise a flexible laminate of at least three fibrous layers 14, 15 and 16, first and second outer layers 14, 15 and a middle layer 16, of fibrous material bonded together in a bonding pattern 13 provided by ultrasonic, laser and/or heat. At least some of the fibers in the layers of fibrous material should therefore be meltable by such bonding techniques. The bonding pattern 13 should have a bonding area of no more than 10% . The fibrous materials are preferably nonwoven materials, such as spunbond, meltblown, carded bonded webs, thermobonded webs etc.
  • The first outer layer 14 and the middle layer 16 of the laminate have a creped structure of a plurality of raised areas 14a, 16a separated by a plurality of non-raised areas 14b, 16b formed by the bonding sites of said bonding pattern 13. The creped structure of the first outer layer 14 is more distinct with a greater height h of said raised areas 14a as compared to the middle layer 16.
  • The second outer layer 15 of said laminate is substantially plane and uncreped and is preferably used as the internal side of the belt members intended to be facing the wearer, and should therefor be smooth and skin-friendly. The first outer layer 14 of the laminate is used as the external side of the belt members intended to act as receiving surface for said fastening means, and is especially used as a loop material for a complementary hook material of a hook-and-loop type fastening means 8 and 9. The creped structure of the layer 14 will provide an increased bulk and a three-dimensional structure suitable for engaging a hook material. The loop function for the creped material is thus improved as compared to a substantially plane and smooth nonwoven material. Examples of nonwoven materials suitable for the first outer layer 14 are spunbond, meltblown, carded bonded materials etc. The other outer layer 15, intended to form an inner layer of the belt facing the wearer, should be of a soft and skin friendly fibrous material. Examples of suitable materials are spunbond and meltblown materials, carded bonded materials etc. Examples of polymer materials used in the different fibrous materials may be any suited for this purpose, for example polypropylene, polyethylene, polyester and /or so called bicomponent fibers. The middle layer 16 is used as a support layer providing strength and stability to the laminate. The middle layer 16 should be of a relatively tear strong fibrous material, such as a spunbond or meltblown material comprising continuous filaments.
  • The laminate should have a tear strength of at least 22 N. This will make the belt members resist tearing as the belt is tightened around the waist of the wearer. Tests have proven that the tearing frequency at normal use for belts having a tear strength of 21 N and lower was unaccetably high. Preferably the tear strength should be at least 24 N, more preferably at least 25 N and most preferably at least 27N. For those belt having a tear strength of 29 N or higher there were no tearing at all.
  • The tear strength is measured by EDANA test method TEAR 70.3-96 with the modification that a conditioning time of 4h, a temperature of 23°C and a relative humidity of 50% R.H. is used.
  • A bonding area of more than 10% will result in an increased amount of tearing indications or notches and an increased risk for tearing of the belt members.
  • Preferably the bonding area should be no more than 8% and more preferably no more than 5%.
  • The bonding pattern comprises a plurality of bonding sites in the form of points, lines, spots or the like arranged in a pattern. The bonding area of a bonding pattern is defined as the amount of the pattern that consists of the bonding sites.
  • Another important factor for providing high tear strength is the bonding tightness, which is the number of bonding sites per area unit. It is preferred that the bonding pattern 13 has a bonding tightness of between 1 and 15 bonding sites per cm2. Preferably it has a bonding tightness of between 1 and 10 bonding sites per cm2. With a high bonding tightness more tearing indications or notches are formed, which will deteriorate the tearing strength.
  • Relatively large bonding sites, for example in the form of lines, provides a relatively large bonding area with a smaller number of bonding sites, as compared to a bonding pattern of small bonding sites, for example in the form of points, arranged with a higher bonding tightness. Thus both bonding area and bonding tightness are important.
  • One non-limiting example of a laminate according to the invention is a three-layered laminate:
    • Carded thermobonded material, basis weight 30 gsm, PP fibers of 2.2 dtex;
    • Spunbond layer, basis weight 40 gsm, PP fibers of 2.2 dtex;
    • Carded thermobonded material, basis weight 22 gsm, PP fibers of 2.2 dtex.
  • The spunbond layer is used as the middle layer, the carded material having the highest basis weight is creped and intended to be used as outside of the belt and is adapted to act as loop material for a hook-and-loop type fastener and the carded material having the lowest basis weight is used as inner skin-facing side of the belt. The middle spunbond layer is also creped, but with a less distinct creped structure as compared to the carded material intended to be used as outside of the belt.
  • The laminate is bonded by ultrasonic bonding with a bonding area of about 3% and a bonding tightness of about 7 bonding sites per cm2. The tear strength is 55N.
  • The method for manufacturing the laminate material according to the invention comprises binding together at least three layers 14, 15 and 16 of fibrous material in a bonding pattern 13 provided by ultrasonic, laser and/or heat in a bonding station 17 schematically illustrated in Fig. 3. The bonding station 17 in one embodiment of the invention comprises an ultrasonic horn 18 arranged opposite a patterning roll 19. In order to provide the creped structure the layers are fed with different web tensions and/or web speeds into the bonding station 17, at which the layer 14 exhibiting the lowest web tension and/or web speed is slowed down and becomes corrugated or creped at the feed end of the bonding station. The layer 15 exhibiting the highest web tension and/or web speed will remain substantially smooth, while the middle layer 16 exhibiting a web tension and/or web speed that is higher than that of the layer 14 but lower than that of the layer 16, will also become corrugated or creped but to a less extent than the layer 14. After bonding the laminate is fed from the bonding station with a web tension/web speed that is substantially equal to that of the lowest web tension/web speed, namely that of the layer 14.
  • According to one embodiment the second outer layer 15 has a web tension and/or web speed entering the bonding station that is between 15 and 50% and preferably between 18 and 33% higher than that of the first outer layer 14. According to a further embodiment the middle layer 16 has a web tension and/or web speed entering the bonding station that is between 5 and 40% and preferably between 9 and 18% higher than that of the first outer layer.

Claims (13)

  1. Absorbent article such as a diaper and an incontinence guard comprising a liquid permeable topsheet (2), a liquid impermeable backsheet (3) and an absorbent body (4) enclosed therebetween, said article having a front portion (5), a rear portion (6) and a crotch portion (7) therebetween, and further is provided with a pair of belt members (10 a, b) attached to the rear portion (6), alternatively to the front portion, of the article and which are intended to be fastened together around the waist of the wearer by fastening means (11,12) and where said front portion (5), alternatively said rear portion, is provided with fastening means (8,9) intended to be fastened to the belt members (10 a, b), in such a way that the article will assume a pantlike shape, where the belt members (10 a,b) form a part of the waist portions of the pant,
    characterized in
    that the belt members (10 a, b) comprise a flexible laminate of at least three layers, a first outer layer (14), a middle layer (16) and a second outer layer (15) of fibrous material bonded together in a bonding pattern (13) provided by ultrasonic, laser and/or heat, said bonding pattern (13) having a bonding area of no more than 10% , said first outer layer (14) and said middle layer (16) of the laminate having a creped structure of a plurality of raised areas (14a;16a) separated by a plurality of non-raised areas formed by the bonding sites (13) of said bonding pattern, wherein the creped structure of the first outer layer (14) is more distinct with a greater height (h) of said raised areas (14a) as compared to the middle layer (16).
  2. Absorbent article as claimed in claim 1,
    characterized in
    that the second outer layer (15) of said laminate is substantially smooth and uncreped.
  3. Absorbent article as claimed in claim 1or 2,
    characterized in
    that the second outer layer (15) of the laminate is used as the internal side of the belt members (10a, b) intended to be facing the wearer, while the first outer layer (14) of the laminate is used as the external side of the belt members intended to act as receiving surface for said fastening means (8, 9).
  4. Absorbent article as claimed in claim 3,
    characterized in
    that the first outer layer (14) is used as a loop material for a complementary hook material of a hook-and-loop type fastening means (8, 9).
  5. Absorbent article as claimed in any of the preceding claims,
    characterized in
    that said bonding pattern (13) has a bonding area of no more than 8% and preferably no more than 5%.
  6. Absorbent article as claimed in any of the preceding claims,
    characterized in
    that said bonding pattern (13) has a tightness of bonding sites of between 1 and 15 bonding sites per cm2.
  7. Absorbent article as claimed in claim 6,
    characterized in
    that said bonding pattern (13) has a tightness of bonding sites of between 1 and 10 bonding sites per cm2.
  8. Absorbent article as claimed in claim 7,
    characterized in
    that said middle layer (16) is a relatively tear strong fibrous material comprising continuous filaments, such as a spunbond and/or meltblown material.
  9. Method of producing a flexible laminate for use as belt members (10a, b ) on an absorbent article such as a diaper and an incontinence guard of the kind stated in claim 1,
    characterized in
    binding together in a bonding station (17) at least three layers, a first outer layer (14), a middle layer (16) and a second outer layer (15) of fibrous material in a bonding pattern (13) provided by ultrasonic, laser and/or heat, said bonding pattern (13) having a bonding area of no more than 10% , said layers (14,15,16) of the laminate exhibiting different web tensions and/or web speeds when entering the bonding station (17), so that said first outer layer (14) exhibits the lowest web tension and/or lowest web speed, the second outer layer (15) exhibits the highest web tension and/or highest web speed and the middle layer (16) exhibits a web tension and/or web speed that is higher than that of the first outer layer (14) and lower than that of the second outer layer (15).
  10. Method as claimed in claim 9,
    characterized in
    that the second outer layer (15) has a web tension and/or web speed during bonding that is between 15 and 50% higher than that of the first outer layer (14).
  11. Method as claimed in claim 10,
    characterized in
    that the second outer layer (15) has a web tension and/or web speed during bonding that is between 18 and 33% higher than that of the first outer layer (14).
  12. Method as claimed in any of claims 9-11,
    characterized in
    that the middle layer (16) has a web tension and/or web speed during bonding that is between 5 and 40% higher than that of the first outer layer (14).
  13. Method as claimed in claim 12,
    characterized in
    that the middle layer (15) has a web tension and/or web speed during bonding that is between 9 and 18% higher than that of the first outer layer (14).
EP02759039A 2001-08-22 2002-08-21 Belted absorbent article and a method of producing a laminate for use as belt material Expired - Lifetime EP1423077B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SE0102800A SE0102800L (en) 2001-08-22 2001-08-22 Belt-provided absorbent article and method for preparing a laminate for use as a belt material
SE0102800 2001-08-22
PCT/SE2002/001496 WO2003017904A1 (en) 2001-08-22 2002-08-21 Belted absorbent article and a method of producing a laminate for use as belt material

Publications (2)

Publication Number Publication Date
EP1423077A1 EP1423077A1 (en) 2004-06-02
EP1423077B1 true EP1423077B1 (en) 2010-03-31

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JP (1) JP4317448B2 (en)
KR (1) KR100886648B1 (en)
AR (1) AR035142A1 (en)
AT (1) ATE462390T1 (en)
BR (1) BR0212091B1 (en)
CA (1) CA2456300A1 (en)
DE (1) DE60235818D1 (en)
MX (1) MXPA04001326A (en)
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PL (1) PL205775B1 (en)
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Publication number Priority date Publication date Assignee Title
DE10337537A1 (en) 2003-08-06 2005-02-24 Paul Hartmann Ag Throw-away diaper, in particuar, for incontinence sufferers comprises additional fastening elements forming a connection between the waist band and the front or crotch zone of the diaper main section
US7507680B2 (en) * 2003-11-12 2009-03-24 Tredegar Film Products Corporation Composite elastic web
US8187247B2 (en) 2005-12-19 2012-05-29 Sca Hygiene Products Ab Multi-configurable absorbent article
CN101325940A (en) 2005-12-19 2008-12-17 Sca卫生产品股份公司 Absorbent product with multiple constructions
CN101534775B (en) * 2006-11-07 2013-04-17 Sca卫生用品公司 Absorbent article
JP5366958B2 (en) 2007-10-10 2013-12-11 エスセーアー・ハイジーン・プロダクツ・アーベー Absorbent article with belt
EP2197403A4 (en) 2007-10-10 2012-05-09 Sca Hygiene Prod Ab Belted absorbent article
JP5452903B2 (en) 2008-10-15 2014-03-26 ユニ・チャーム株式会社 Composite sheet manufacturing method, absorbent article manufacturing method using composite sheet, and composite sheet manufacturing apparatus
US8870843B2 (en) 2012-08-07 2014-10-28 Sca Hygiene Products Ab Disposable absorbent product with temporary adhesive attachment and related methods

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US5628741A (en) * 1991-02-28 1997-05-13 The Procter & Gamble Company Absorbent article with elastic feature having a prestrained web portion and method for forming same
US5807368A (en) * 1993-06-14 1998-09-15 Minnesota Mining And Manufacturing Company Disposable garment formed from an elastic film laminate
ES2125479T3 (en) * 1993-08-25 1999-03-01 Procter & Gamble ABSORBING ARTICLE WITH A MEMBER MADE ELASTIC COMPOSITE.
JP3564344B2 (en) * 1999-11-25 2004-09-08 ユニ・チャーム株式会社 Elastic stretch laminate sheet and method for producing the same

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BR0212091A (en) 2004-08-03
MXPA04001326A (en) 2004-05-05
MY129381A (en) 2007-03-30
SE0102800D0 (en) 2001-08-22
RU2295323C2 (en) 2007-03-20
AR035142A1 (en) 2004-04-14
ATE462390T1 (en) 2010-04-15
BR0212091B1 (en) 2012-09-04
SE0102800L (en) 2003-02-23
EP1423077A1 (en) 2004-06-02
CA2456300A1 (en) 2003-03-06
PL368058A1 (en) 2005-03-21
RU2004108131A (en) 2005-03-10
PL205775B1 (en) 2010-05-31
KR20040027955A (en) 2004-04-01
DE60235818D1 (en) 2010-05-12
KR100886648B1 (en) 2009-03-04
JP4317448B2 (en) 2009-08-19
JP2005500136A (en) 2005-01-06

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