EP1345971A1 - Method for shortstopping polymerization processes in the manufacture of synthetic rubbers - Google Patents
Method for shortstopping polymerization processes in the manufacture of synthetic rubbersInfo
- Publication number
- EP1345971A1 EP1345971A1 EP01993625A EP01993625A EP1345971A1 EP 1345971 A1 EP1345971 A1 EP 1345971A1 EP 01993625 A EP01993625 A EP 01993625A EP 01993625 A EP01993625 A EP 01993625A EP 1345971 A1 EP1345971 A1 EP 1345971A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- shortstopping
- parts
- ipah
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims description 13
- 238000006116 polymerization reaction Methods 0.000 title abstract description 14
- 238000004519 manufacturing process Methods 0.000 title description 3
- 229920003051 synthetic elastomer Polymers 0.000 title description 3
- 239000005061 synthetic rubber Substances 0.000 title description 3
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 208000020875 Idiopathic pulmonary arterial hypertension Diseases 0.000 claims abstract description 12
- 150000003254 radicals Chemical class 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000010526 radical polymerization reaction Methods 0.000 claims description 2
- 238000007717 redox polymerization reaction Methods 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract description 6
- 239000012458 free base Substances 0.000 abstract description 6
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 239000002244 precipitate Substances 0.000 abstract description 4
- 241001441571 Hiodontidae Species 0.000 abstract description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 description 8
- 239000005060 rubber Substances 0.000 description 7
- 229920000126 latex Polymers 0.000 description 6
- 239000004816 latex Substances 0.000 description 6
- 150000004005 nitrosamines Chemical class 0.000 description 5
- UMFJAHHVKNCGLG-UHFFFAOYSA-N n-Nitrosodimethylamine Chemical compound CN(C)N=O UMFJAHHVKNCGLG-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- MZGNSEAPZQGJRB-UHFFFAOYSA-N dimethyldithiocarbamic acid Chemical compound CN(C)C(S)=S MZGNSEAPZQGJRB-UHFFFAOYSA-N 0.000 description 3
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 2
- 150000002443 hydroxylamines Chemical class 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- GSFSVEDCYBDIGW-UHFFFAOYSA-N 2-(1,3-benzothiazol-2-yl)-6-chlorophenol Chemical compound OC1=C(Cl)C=CC=C1C1=NC2=CC=CC=C2S1 GSFSVEDCYBDIGW-UHFFFAOYSA-N 0.000 description 1
- YGJHZCLPZAZIHH-UHFFFAOYSA-N N-Nitrosodi-n-butylamine Chemical compound CCCCN(N=O)CCCC YGJHZCLPZAZIHH-UHFFFAOYSA-N 0.000 description 1
- YLKFDHTUAUWZPQ-UHFFFAOYSA-N N-Nitrosodi-n-propylamine Chemical compound CCCN(N=O)CCC YLKFDHTUAUWZPQ-UHFFFAOYSA-N 0.000 description 1
- WBNQDOYYEUMPFS-UHFFFAOYSA-N N-nitrosodiethylamine Chemical compound CCN(CC)N=O WBNQDOYYEUMPFS-UHFFFAOYSA-N 0.000 description 1
- -1 N-nitrosodietylamine Chemical compound 0.000 description 1
- UWSDONTXWQOZFN-UHFFFAOYSA-N N-nitrosopiperidine Chemical compound O=NN1CCCCC1 UWSDONTXWQOZFN-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 241000482268 Zea mays subsp. mays Species 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229920003008 liquid latex Polymers 0.000 description 1
- ODHYIQOBTIWVRZ-UHFFFAOYSA-N n-propan-2-ylhydroxylamine Chemical compound CC(C)NO ODHYIQOBTIWVRZ-UHFFFAOYSA-N 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
Definitions
- This invention relates to an improved method for shortstopping polymerization processes for making synthetic rubber, such as butadiene-styrene copolymers.
- Free radical or redox initiated emulsion polymerizations are generally terminated by mixing the latex with shortstopping agents, which are used to prevent a free radical or redox polymerzation reaction from proceeding to completion. The polymerization must be stopped to get a product of the desired characteristics. The properties of the polymers produced vary with the percentage of the monomers conversion.
- SBR styrene-butadiene rubber
- BR butadiene rubber
- NBR acrylonitrile-butadiene rubber
- N- monoalkylhydroxylamines have been suggested as shortstopping agents, particularly isopropylhydroxylamin (IPHA) in US 5.384.372; WO 98/51714). In this case the final rubber was free of nitrosamines and their precursors.
- IPHA isopropylhydroxylamin
- the disadvantage of the described solutions is an not exactly stopping process by drifting the mooneyviscosity and the formation of coagulate and precipitate in the recovery vessels.
- Another problem is the formation of depoty amines using N,N-dialcylated hydroxylamines and/or carbamates.
- the present invention relates to a method for terminating a free radical initiated emulsion polymerization comprising adding to the emulsion a shortstopping agent consisting of a mixture of i-Propylhydroxylamin (IPAH) and Hydroxylamin (HA) (free base).
- a shortstopping agent consisting of a mixture of i-Propylhydroxylamin (IPAH) and Hydroxylamin (HA) (free base).
- HA hydroxylamin (free base)
- IPAH i-propylhydroxylamin
- a mixture of 0,01 to 0,2 parts by weight HA and 0,2 to 0,01 parts by weight IPAH is added.
- the mixture of shortstopping agent is added in an amount from 0.005 to 0.2 parts by weight each 100 parts by weight of initial monomer (phm), preferably 0J to 0.4 parts by weight of initial monomer (phm).
- the shortstopping agent is added is occured with convential techniques used in rubber polymerization processes.
- the original solutions HA 50 percent, IPHA 15 percent
- an aqueous solution of the shortstopping mixture will be added to the polymerization reaction mass when the desired conversion is obtained
- the preferable used polymerization system is a styrene butadiene polymerization.
- the shortstopping agent was then added.
- Example 1 was shortstopped with a dilute aqueous solution of a 90/10 ratio by weight mixture of sodium dimethyldithiocarbamate (DTC) and N,N-diethylhydroxylamine (DEHA).
- DTC sodium dimethyldithiocarbamate
- DEHA N,N-diethylhydroxylamine
- Example 2 3, 4, 5, 6 7, and 8 was shortstopped with a dilute aqueous solution of hydroxylamine (HA) 50 percent and i-propylhydroxylamin (IPAH) 15 percent in water as a
- the mixture of both components was formed as batch or in linedosing, with or without deionized water from the original components.
- the preferential concentration could vary from 1 percent to 25 percent on the active components in water.
- shortstop agent will be made after the desired degree of polymerization directly in the latex.
- * 3) not detected The shortstopp mixture was realized by mixing original solutions of of hydroxylamine (free base)(HA) 50 percent and i-propylhydroxylamin (IPAH) 15 percent in water.
- sample 1 Use of conventional shortstopping agents in sample 1 resulted in relatively high levels of nitrosamines being detected in the rubber. Also was found a high amount of coagulate using dimethyldithiocarbamate (DTC) and N,N-diethylhydroxylamine (DEHA) (examplel).
- DTC dimethyldithiocarbamate
- DEHA N,N-diethylhydroxylamine
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
This invention is related to a new shortstopping combination for use in stopping free radical and redox intiated polymerization is the combination of hydroxylamine (free base) (HA) and i-propylhydroxylamine (IPAH). It is more effective as related N-alcylated-hydroxylamines with regard to mooney stability. The combination is not corrosive to metals used in commercial equipment fr emulsion polymerization and prevents the rust formation and the formation of nitrosamins, coagulate and precipitate.
Description
METHOD FOR SHORTSTOPPING POLYMERIZATION PROCESSES IN THE MANUFACTURE OF SYNTHETIC RUBBERS
This invention relates to an improved method for shortstopping polymerization processes for making synthetic rubber, such as butadiene-styrene copolymers.
Free radical or redox initiated emulsion polymerizations are generally terminated by mixing the latex with shortstopping agents, which are used to prevent a free radical or redox polymerzation reaction from proceeding to completion. The polymerization must be stopped to get a product of the desired characteristics. The properties of the polymers produced vary with the percentage of the monomers conversion.
The main application of free radical or redox polymerization is the emulsion polymerizations used in making elastomers such as styrene-butadiene rubber (SBR), butadiene rubber (BR) and acrylonitrile-butadiene rubber (NBR). Much study has been made toward finding good short-stops and numerous compounds have been found quite useful. However, the compounds used heretofore have certain disadvantages and are not generally satisfactory with all types of polymerization systems. Well known as conventional shortstopping agents are carbamates, hydoquinone, hydracine, polysulfide, nitrocompounds, N- alcylated hydroxylamines and/or other more (US 5.348.372 US 3.296.177;.EP 656 371 ; EP-AO 437 293; DE-A-15 95 177).
N- monoalkylhydroxylamines have been suggested as shortstopping agents, particularly isopropylhydroxylamin (IPHA) in US 5.384.372; WO 98/51714). In this case the final rubber was free of nitrosamines and their precursors. The disadvantage of the described solutions is an not exactly stopping process by drifting the mooneyviscosity and the formation of coagulate and precipitate in the recovery vessels. Another problem is the formation of secundary amines using N,N-dialcylated hydroxylamines and/or carbamates.
The problem has been excellently resolved by using a shortstopping agent as mixture of hydroxylamine (free base) und i-propylhydroylamine. In this way latex free of coagulate and precipitate and rubbers without nitrosamines and their precursors are produced. Never was found a drifting of the mooneyviscosity in latex or rubber.
The present invention relates to a method for terminating a free radical initiated emulsion polymerization comprising adding to the emulsion a shortstopping agent consisting of a mixture of i-Propylhydroxylamin (IPAH) and Hydroxylamin (HA) (free base).
According to the invention there is disclosed a process for preparing a synthetic latex and rubber by free radical and redox initiated emulsion polymerization of a conjugated diene and a monoolefine in an aqueous medium and terminating the polymerization by the addition of a shortstopping agent combination consisting of hydroxylamin (free base) (HA) and i-propylhydroxylamin (IPAH).
The process being characterized in that a mixture consist of hydroxylamin (free base) (HA) and i-propylhydroxylamin (IPAH) is used as shortstopping agent comprising:
a) from 0.001 to 0.499 parts by weight of HA per 100 parts of monomers initially charged,
b) from 0.499 to 0.001 parts by weight of IPHA per 100 parts of monomers initially charged.
Preferably, a mixture of 0,01 to 0,2 parts by weight HA and 0,2 to 0,01 parts by weight IPAH is added.
The mixture of shortstopping agent is added in an amount from 0.005 to 0.2 parts by weight each 100 parts by weight of initial monomer (phm), preferably 0J to 0.4 parts by weight of initial monomer (phm).
The manner by which the shortstopping agent is added is occured with convential techniques used in rubber polymerization processes. Preferably, the original solutions (HA 50 percent, IPHA 15 percent) and or an aqueous solution of the shortstopping mixture will be added to the polymerization reaction mass when the desired conversion is obtained
The preferable used polymerization system is a styrene butadiene polymerization.
The practice of this invention is further illustrated by references to the following examples which are intended to be representative rather than restrictive of the scope of this invention. The term "parts" as employed in the following examples refers to parts by weight of shortstopping agent per 100 parts of monomer charged.
EXAMPLES
For free radical or redox initiated emulsion polymerization we carried out using a could soap styrene butadien polymerization is listed in table 1 :
Table 1
All polymerizations were carried out at 5°C to about 60 percent conversion of monomer to polymer.
The shortstopping agent was then added.
Example 1 was shortstopped with a dilute aqueous solution of a 90/10 ratio by weight mixture of sodium dimethyldithiocarbamate (DTC) and N,N-diethylhydroxylamine (DEHA).
Example 2, 3, 4, 5, 6 7, and 8 was shortstopped with a dilute aqueous solution of hydroxylamine (HA) 50 percent and i-propylhydroxylamin (IPAH) 15 percent in water as a
22 percent solution. The results are given in table 2.
The mixture of both components was formed as batch or in linedosing, with or without deionized water from the original components. The preferential concentration could vary from 1 percent to 25 percent on the active components in water.
The addition of shortstop agent will be made after the desired degree of polymerization directly in the latex.
The presence of nitrosamines was determined by gaschromatographiy using a thermal energy analyzer, called BGA-method.
Table 2
* detection: N-nitrosodimethylamine, N-nitrosodietylamine, N-nitrosodipropylamine, N- nitrosodibutylamine, N-nitrosopiperidine, N-nitosopyrrolidine, N-nitosomorpholine *1)Summary of N-nitrosodimethylamine and N-nitrosodiethylamine in rubber. *2) coagulate/precipitate was detected after monomer recovery *3) not detected The shortstopp mixture was realized by mixing original solutions of of hydroxylamine (free base)(HA) 50 percent and i-propylhydroxylamin (IPAH) 15 percent in water.
Use of conventional shortstopping agents in sample 1 resulted in relatively high levels of nitrosamines being detected in the rubber. Also was found a high amount of coagulate using dimethyldithiocarbamate (DTC) and N,N-diethylhydroxylamine (DEHA) (examplel).
Surprisingly, use of hydroxylamine(HA) and i-propylhydroxylamine(IPAH) resulted in no nitrosamines and coagulate being detected. In the same way resulted a very mooney stable latex without drifting (Examples 2-8). The advantage of the invention is a better shortstopp effect and a better prevention of popcorn formation in the gasphase and also in the liquid-(latex) phase. Besides the quantities of the two components of the mixture forming the shortstopping agent are lower that those required by the use of each single component, thus justifying the existence of a synergetic effect of the two components with respect to the shortstopping reaction.
Claims
1. A method of stopping free radical or redox polymerization comprising a mixture of hydroxylamine (HA) and i-propylhydroxylamine (IPAH) to a polymerizing mixture when a predetermined conversion has been reached.
2. The method of claim 1 wherein the mixture in an amount from 0.005 to 0.2 parts by weight each 100 parts by weight of initial monomer (phm) is added.
3. The method of claim 1 wherein the mixture consist of 0.001 to 0.499 parts by weight hydroxylamine(HA) and 0.499 to 0.001 parts by weight i-propylhydroxylamine (IPAH) by weight of initial monomer (phm), preferably 0.01 to 0.2 parts by weight hydroxylamine(HA) and 0.2 to 0.01 parts by weight i-propylhydroxylamine (IPAH) by weight of initial monomer (phm).
The method of claim 1 wherein the shortstopping agents are used in the original concentrations of the both components, IPAH 15 percent in water and HA 50 percent in water.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24638500P | 2000-11-07 | 2000-11-07 | |
| US246385P | 2000-11-07 | ||
| PCT/US2001/045609 WO2002038617A1 (en) | 2000-11-07 | 2001-10-23 | Method for shortstopping polymerization processes in the manufacture of synthetic rubbers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1345971A1 true EP1345971A1 (en) | 2003-09-24 |
Family
ID=22930439
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP01993625A Withdrawn EP1345971A1 (en) | 2000-11-07 | 2001-10-23 | Method for shortstopping polymerization processes in the manufacture of synthetic rubbers |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP1345971A1 (en) |
| AU (1) | AU2002225840A1 (en) |
| TW (1) | TW588057B (en) |
| WO (1) | WO2002038617A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8481657B2 (en) | 2009-01-14 | 2013-07-09 | Styron Europe Gmbh | Increased monomer conversion in emulsion polymerization |
| EP2841470B1 (en) | 2012-06-14 | 2017-03-15 | ANGUS Chemical Company | Alkyl hyroxylamine compounds and their use for shortstopping free radical polymerizations |
| WO2014052212A1 (en) | 2012-09-28 | 2014-04-03 | Dow Global Technologies Llc | Alkyl hydroxylamine compounds and their use for shortstopping free radical polymerizations |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL131752C (en) * | 1960-09-08 | |||
| US3296177A (en) * | 1964-11-13 | 1967-01-03 | Pennsalt Chemicals Corp | Stopping agents for synthetic rubber polymerization |
| US4912239A (en) * | 1987-11-13 | 1990-03-27 | Dow Corning Corporation | Method for stabilizing unsaturated organosilicone compositions |
| CA2099168A1 (en) * | 1992-10-21 | 1994-04-22 | Betzdearborn Inc. | Compositions and methods for inhibiting styrene polymerization |
| IT1265250B1 (en) * | 1993-12-03 | 1996-10-31 | Enichem Elastomers | PROCEDURE FOR THE TERMINATION OF EMULSION CURING THAT DOES NOT GENERATE NITROSAMINES |
| US5384372A (en) * | 1994-03-30 | 1995-01-24 | The Goodyear Tire & Rubber Company | Shortstopping of free radical polymerizations |
| AU7281998A (en) * | 1997-05-16 | 1998-12-08 | Angus Chemical Company | N-ethylhydroxylamine as a shortstopping agent for free radical polymerization |
| US6495065B1 (en) * | 1999-09-09 | 2002-12-17 | Atofina Chemicals, Inc. | Nitrosamine-inhibiting compositions for shortstopping of free radical emulsion polymerizations |
-
2001
- 2001-10-23 AU AU2002225840A patent/AU2002225840A1/en not_active Abandoned
- 2001-10-23 EP EP01993625A patent/EP1345971A1/en not_active Withdrawn
- 2001-10-23 WO PCT/US2001/045609 patent/WO2002038617A1/en not_active Ceased
- 2001-11-01 TW TW90127176A patent/TW588057B/en not_active IP Right Cessation
Non-Patent Citations (1)
| Title |
|---|
| See references of WO0238617A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2002038617A1 (en) | 2002-05-16 |
| AU2002225840A1 (en) | 2002-05-21 |
| TW588057B (en) | 2004-05-21 |
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