EP1345869A2 - Machining tool and method of producing the same - Google Patents
Machining tool and method of producing the sameInfo
- Publication number
- EP1345869A2 EP1345869A2 EP01271338A EP01271338A EP1345869A2 EP 1345869 A2 EP1345869 A2 EP 1345869A2 EP 01271338 A EP01271338 A EP 01271338A EP 01271338 A EP01271338 A EP 01271338A EP 1345869 A2 EP1345869 A2 EP 1345869A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- machining tool
- metal
- ceramics
- drill
- composition ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23D—PLANING; SLOTTING; SHEARING; BROACHING; SAWING; FILING; SCRAPING; LIKE OPERATIONS FOR WORKING METAL BY REMOVING MATERIAL, NOT OTHERWISE PROVIDED FOR
- B23D77/00—Reaming tools
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B51/00—Tools for drilling machines
- B23B51/02—Twist drills
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
- C22C1/051—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/16—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on nitrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F2005/001—Cutting tools, earth boring or grinding tool other than table ware
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B2222/00—Materials of tools or workpieces composed of metals, alloys or metal matrices
- B23B2222/28—Details of hard metal, i.e. cemented carbide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B2224/00—Materials of tools or workpieces composed of a compound including a metal
- B23B2224/32—Titanium carbide nitride (TiCN)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B2224/00—Materials of tools or workpieces composed of a compound including a metal
- B23B2224/36—Titanium nitride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B2226/00—Materials of tools or workpieces not comprising a metal
- B23B2226/18—Ceramic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T408/00—Cutting by use of rotating axially moving tool
- Y10T408/78—Tool of specific diverse material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12021—All metal or with adjacent metals having metal particles having composition or density gradient or differential porosity
Definitions
- the present invention relates to a machining tool and a method of producing the same.
- the machining tool is formed of a gradient composite material in which composition ratios of metal and ceramics change inwardly from the surface of the machining tool.
- boring machining is roughly performed for the workpiece using a drill, and then, cutting machining is performed using a reamer.
- Constitutive materials adopted for the drill or the reamer include, for example, SK material, SKD material, or SKH material defined by Japan Industrial Standard (so-called high speed tool steel) containing high carbon steel as a major component, super alloy material such as nickel-based alloy and cobalt-based alloy, and superhard material as composite material of ceramics and metal.
- high speed tool steel containing high carbon steel as a major component
- super alloy material such as nickel-based alloy and cobalt-based alloy
- superhard material as composite material of ceramics and metal.
- the surface of the drill or the reamer is sometimes coated with a coating film of hard ceramics such as TiC or TiN.
- the high speed tool steel and the super alloy material have high strength and high toughness. However, the high speed tool steel and the super alloy do not have sufficient abrasion resistance, compressive strength, and rigidity.
- the superhard material has high abrasion resistance, compressive strength, and rigidity. However, the superhard material does not have sufficient toughness and tends to cause cracks and breakage. That is, the characteristics of the high speed tool steel and the super alloy material are opposite to the characteristics of the superhard material. Therefore, the constitutive material for the drill or the reamer is selected in consideration of the constitutive material of a workpiece and the magnitude of a variety of stresses exerted on the drill or the reamer when the boring machining or the cutting machining is performed. Such stresses include compressive stress exerted when the pressing force is applied to the workpiece, tensile stress acting on the leading part and the cutting part, and tensile stress exerted between the portion to be machined and the portion not to be machined.
- the drill or the reamer has high hardness, high strength, and high toughness.
- High hardness i.e., high abrasion resistance is essential for a long service life.
- High strength helps to prevent deformation of the drill or the reamer, even if the stresses as described above are exerted thereon.
- the drill or the reamer having high toughness scarcely suffers from the occurrence of cracks and breakage.
- conventional drills or reamers do not have all of the characteristics described above.
- the drill or the reamer composed of a superhard material it is possible to improve toughness by increasing the composition ratio of metal.
- the superhard material having high metal composition ratio does not have high hardness and strength. Therefore, the service life of the drill or the reamer may not be long.
- the cracks and breakage tend to occur more frequently.
- the superhard material having high hardness and strength does not have high toughness.
- the superhard material having high toughness does not have high hardness and strength. Therefore, it is difficult to improve all of the characteristics (hardness, strength, and toughness) of the drill or the reamer.
- the present invention has been made in order to solve the problem as described above, and an object of which is to provide a machining tool which has a long service life in which deformation, cracks and breakage scarcely occur, and a method of producing the machining tool.
- a machining tool is composed of a composite material containing ceramics and metal, wherein a composition ratio of the ceramics is increased and a composition ratio of the metal is decreased inwardly from a surface of the machining tool.
- the machining tool constructed as described above has toughness of metal, and hardness and strength of ceramics. Therefore, the cracks and the breakage scarcely occur, abrasion resistance is improved, and the deformation scarcely occurs .
- Suitable ceramics materials used for the machining tool include at least one selected from the group consisting of carbide, nitride, and carbonitride of W, Cr, Mo, Ti, V, Zr, Hf, and lanthanoid.
- Suitable metal materials used for the machining tool include at least one selected from the group consisting of Fe, Ni, Co, and alloy composed of two or more of these metals. Additionally, the metal may further contain at least one of Cr, Mn, V, and Ti.
- the composition ratio of ceramics to the composition ratio of metal is 85:15 to 95:5 by weight. If the metal is less than 5 parts by weight, the cracks and breakage tend to occur, because the toughness is poor. If the metal exceeds 15 parts by weight, hardness and strength, and abrasion resistance are poor. Therefore, the deformation tends to occur when a workpiece is machined. It is preferable that the machining surface of the machining tool has Vickers hardness of not less than 1700 for prolonging the service life of the machining tool and improving the accuracy of machining the workpiece.
- Drills and reamers are preferable examples of the machining tool.
- a method of producing a machining tool in which a composition ratio of ceramics is increased and a composition ratio of metal is decreased inwardly from a surface of the machining tool is provided.
- the method comprises the steps of: forming a compact using mixed powder comprising ceramics powder and metal powder; sintering said compact to prepare a porous member (primary sintering step); impregnating the porous member with a catalyst- containing solution; and resintering said porous member impregnated with the catalyst-containing solution in an atmosphere of nitriding gas to prepare a dense sintered product (secondary sintering step) , wherein the nitriding gas is introduced into a furnace at the beginning of raising temperature of the furnace in the resintering step.
- the metal grains existing in the vicinity of the surface of the porous member start the grain growth earlier than the ceramics grains . Further, the grain growth of the ceramics grains existing in the vicinity of the surface of the porous member is suppressed by the nitriding gas such as nitrogen, because the nitriding gas generally inhibits the grain growth of the ceramic gains .
- the grain growth of the ceramics grains existing centrally in the porous member is not suppressed, because the nitriding gas hardly exists centrally in the porous member. Further, the grain growth of the ceramics grains in the porous member is accelerated by the catalyst.
- the metal grains are concentrated in the vicinity of the surface. In this manner, it is possible to obtain the gradient composite material in which the composition ratio of the metal is decreased and the composition ratio of the ceramics is increased inwardly from the surface.
- the ceramics grains are composed of at least one selected from the group consisting of carbide, nitride, and carbonitride of , Cr, Mo, Ti, V, Zr, Hf, and lanthanoid, and the metal grains are composed of at least one selected from the group consisting of Fe, Ni, Co, and alloy comprising two or more of these metals.
- At least one of Cr, Mn, V, and Ti may be added to the metal grains .
- the composition ratio of ceramics and metal is 85:15 to 95:5 by weight. If the metal is less than 5 parts by weight, the cracks and breakage tend to occur. because toughness is poor. If the metal exceeds 15 parts by weight, hardness and strength, and abrasion resistance are poor. Therefore, the deformation tends to occur when a workpiece is machined.
- Fe, Ni, Co, Mn, Cr, Mo, Ti, or lanthanoid are preferable examples of the catalyst in the catalyst- containing solution.
- the nitriding gas is preferably nitrogen, for example, since it is easy to handle the gas and it is easy to control the reaction velocity.
- FIG. 1 is a view schematically showing, with partial longitudinal section, the overall structure of a machining tool (drill) according to a first embodiment of the present invention
- FIG. 2 is a cross sectional view as viewed along a line II-II indicated by arrows shown in FIG. 1;
- FIG. 3 is a view schematically showing the overall structure of a machining tool (reamer) according to a second embodiment of the present invention
- FIG. 4 is a cross sectional view as viewed along a line IV-IV indicated by arrows shown in FIG. 3;
- FIG. 5 is a flow chart illustrating a method of producing the machining tool according to the embodiments of the present invention
- FIG. 6 is a graph illustrating the relationship between the number of machined holes and the VB abrasion amount, obtained by using the drill according to the first embodiment and commercially available drills .
- FIG. 1 schematically shows, with partial longitudinal section, the overall structure of a drill 10 as a machining tool according to a first embodiment of the present invention.
- the drill 10 is a twist drill having an edge section 12 and a shank section 14.
- the edge section 12 and the shank section 14 are formed integrally into one unit.
- the edge section 12 includes two cutting edges 18 extending from an edge tip 16 in the axial direction (direction of the arrow A) with a predetermined twisting angle.
- FIG. 2 is a cross sectional view as viewed along a line II-II indicated by arrows shown in FIG. 1.
- the drill 10 comprises three sections of different composition ratios. In an inner ceramics-rich section 20, the composition ratio of ceramics is relatively large. In an outer metal-rich section (the surface of the drill 10) 22, the composition ratio of metal is relatively large.
- a gradient section 24 is disposed between the ceramics-rich section 20 and the metal-rich section 22. In the gradient section 24, the composition ratio of metal gradually increases outwardly from the ceramics-rich section 20 to the metal-rich section 22.
- the composition ratio of metal is highest in the metal-rich section 22 constituting the machining surface, and the ratio decreases inwardly.
- the composition ratio of ceramics is lowest in the metal-rich section 22 constituting the machining surface, and the ratio increases inwardly. That is, the drill 10 is composed of the gradient composite material in which the composition ratio of metal decreases and the composition ratio of ceramics increases inwardly from the surface.
- Suitable ceramics materials used for the drill 10 include at least one selected from the group consisting of carbide, nitride, and carbonitride of , Cr, Mo, Ti, V, Zr, Hf, and lanthanoid.
- Suitable metal materials used for the drill 10 include at least one selected from the group consisting of Fe, Ni, Co, and alloy composed of two or more of these metals. Additionally, the metal may further contain at least one of Cr, Mn, V, and Ti. When the ceramics and the metal as described above are used as the constitutive materials, it is possible to form the drill 10 having sufficient strength, hardness, and toughness for performing boring machining.
- the composition ratio of ceramics and metal is 85:15 to 95:5 (weight ratio). If the metal is less than 5 parts by weight, the cracks and breakage tend to occur, because toughness is poor. If the metal exceeds 15 parts by weight, hardness and strength, and abrasion resistance are poor. Therefore, the deformation tends to occur when a workpiece is machined.
- the machining surface of the drill 10 has Nickers hardness (Hv) of not less than 1700. If Hv is less than 1700, the service life of the drill 10 may not be long, because hardness is poor. Further, in this case, the coefficient of friction ( ⁇ ) between the workpiece and the drill 10 is high. As a result, heat and stress generated during boring machining are increased. Therefore, the surface of the workpiece tends to be machined inaccurately. In order to ensure the accuracy of machining the surface of the workpiece and the long service life of the drill 10, it is preferable that Hv is not less than 1750.
- FIG. 3 schematically shows the overall structure of a reamer 30 as a machining tool according to a second embodiment of the present invention.
- the reamer 30 comprises an edge section 32 and a shank section 34.
- the edge section 32 and the shank section 34 are formed integrally into one unit.
- the edge section 32 includes six cutting edges 36 extending in the axial direction (direction of the arrow B) .
- FIG. 4 is a cross sectional view as viewed along a line IV-IV indicated by arrows shown in FIG. 3.
- the reamer 30 comprises three sections (an inner ceramics-rich section 38, a gradient section 42, and an outer metal-rich section 40) of different composition ratios .
- the gradient section 42 the composition ratio of metal gradually increases outwardly from the ceramics-rich section 38 to the metal-rich section 40. That is, the reamer 30 is composed of the gradient composite material in which the composition ratio of metal decreases and the composition ratio of ceramics increases inwardly from the surface as described above in connection with the drill 10.
- the ceramics and metal used for the reamer 30 may be exemplified by the non-oxide ceramics and the metal as described above. Also in this case, when the composition ratio of the ceramics and metal is 85:15 to 95:5, it is possible to form the reamer 30 having sufficient strength, hardness, and toughness for performing cutting machining. As described above in connection with the drill 10, it is preferable that Hv of the machining surface is not less than 1750.
- toughness is high at the surface (in the outer section), and hardness and strength are high in the inner section. That is, all of the hardness, strength, and toughness are sufficient when the workpiece is subjected to boring machining or cutting machining. Therefore, the service life is long, the deformation scarcely occurs, and the cracks and breakage scarcely occur.
- the drill 10 and the reamer 30 can be produced in accordance with a method shown in a flow chart in FIG. 5.
- the production method comprises a sintering step SI of obtaining a compact, a primary sintering step S2 of sintering the compact to prepare a porous member, an impregnating step S3 of impregnating the porous member with a catalyst-containing solution, and a secondary sintering step S4 of resintering the porous member to prepare a dense sintered product.
- ceramics powder of at least one selected from the group consisting of carbide, nitride, and carbonitride of W, Cr, Mo, Ti, V, Zr, Hf, and lanthanoid.
- metal powder of at least one selected from the group consisting of Fe, Ni, Co, and alloy comprising two or more of these metals.
- Cr, Mn, V, and Ti may be added.
- the composition ratio of ceramics powder and metal powder (ceramics powder: metal powder) in the mixed powder is in the range of 85:15 to 95:5.
- a forming load is applied to the mixed powder to prepare the compact having a shape corresponding to the drill 10 or the reamer 30.
- the forming load is determined such that the metal powder does not cause any plastic deformation, in order to obtain the porous member in the primary sintering step as described later on.
- the forming load is about 100 to 300 MPa. In this case, the occurrence of plastic deformation of the metal powder is successfully avoided, and hence open pores of the compact are not closed.
- the primary sintering step S2 the compact is sintered into the porous member such that the pores remain open.
- the sintering temperature and the time in the primary sintering step S2 are determined such that only the metal grains are fused to one another, and the sintering process is finished when necks are formed between the metal grains.
- the ceramics grains are not fused to one another. Accordingly, the volume is not changed significantly in the process in which the compact is converted into the porous member.
- the porous member is impregnated with the catalyst-containing solution. Specifically, the porous member is immersed in the catalyst- containing solution. As a result of the immersion, the catalyst-containing solution permeates into the porous member via the open pores .
- any catalyst which suitably facilitates the growth of the ceramics grains can be used, including, but not limited to, Fe, Ni, Co, Mn, Cr, Mo, Ti, and lanthanoid.
- the catalyst- containing solution include a solution obtained by dissolving a metal salt containing the metal as described above in a solvent, and an organic metal solution.
- the catalyst is dispersed or dissolved in the solvent, and dissociated into single molecules or ions. Therefore, in the impregnating step S3, the catalyst, which is dissociated into single molecules or ions, is uniformly dispersed in the porous member. Accordingly, the grain growth of the ceramics grains in the secondary sintering step S4 is facilitated inwardly from the surface, in the porous member.
- the catalyst-containing solution is left to stand, and dried naturally.
- the porous member may be heated to dry the catalyst-containing solution.
- the porous member is resintered in a nitrogen atmosphere to prepare the dense sintered product.
- the nitriding gas which is used as the atmosphere, is introduced into a furnace at the beginning of raising temperature of the furnace in the secondary sintering step S4. Accordingly, the dense sintered product (gradient composite material), i.e., the drill 10 or the reamer 30 as the product, in which the composition ratio of ceramics and metal is 85:15 to 95:5, is obtained.
- the grain growth of the ceramics grains existing in the vicinity of the surface of the porous member is inhibited by the nitriding gas as the atmosphere.
- the nitriding gas is hardly introduced into the porous member. Therefore, the degree of inhibition of the grain growth of the ceramics grains existing in the porous member by the nitriding gas is small as compared with the surface. Further, the grain growth of the ceramics grains existing in the porous member is facilitated by the catalyst .
- the grain growth of the ceramics grains is suppressed in the vicinity of the surface of the porous member, and the grain growth is facilitated in the porous member.
- the metal grains are rearranged such that the metal grains are concentrated in the vicinity of the surface. That is , in the resulting gradient composite material, the composition ratio of the metal is high in the vicinity of the surface of the porous member, and the composition ratio of the ceramics is high in the porous member.
- the composition ratio of metal is relatively high in the vicinity of the surface of the drill 10 or the reamer 30 obtained as described above, it is possible to grind the surface of the drill 10 or the reamer 30 for improving dimensional accuracy. That is, the thickness of the ceramics-rich section 20, 38 having high hardness and high strength is remarkably increased in the drill 10 or the reamer 30 after the grinding machining. On the other hand, the metal-rich section 22, 40 remains in the vicinity of the surface of the drill 10 or the reamer 30. Therefore, it is possible to obtain the drill 10 or the reamer 30 having sufficient toughness, hardness, and strength.
- the forming step SI and the primary sintering step S2 are performed separately.
- the both steps SI, S2 may be performed simultaneously, for example, by hot isostatic pressing (HIP).
- HIP hot isostatic pressing
- EXAMPLES Mixed powder was prepared by mixing, in a wet manner, 90 parts by weight of tungsten carbide (WC) powder having an average grain size of 1 ⁇ m, 2 parts by weight of tantalum carbide (TaC) having an average grain size of 2 ⁇ m, 1 part by weight of niobium carbide (NbC) having an average grain size of 3.5 ⁇ m, and 7 parts by weight of cobalt (Co) having an average grain size of 1.4 ⁇ m with hexane. Subsequently, the mixed powder was formed to have a shape corresponding to a drill 10 with a pressurizing force of 120 MPa by means of the isostatic pressing method in a mold. An obtained compact was maintained at 900 °C for 30 minutes to prepare a porous member.
- WC tungsten carbide
- TaC tantalum carbide
- NbC niobium carbide
- Co cobalt
- the porous member was immersed in an Ni ion solution having a concentration of 10 % for 3 minutes. Thus, the Ni ion was dispersed in the porous member. Then, the porous member was left for an hour at 90 °C, and dried. Subsequently, the porous member was resintered for 1 hour and 20 minutes at 1400 °C in a nitrogen atmosphere.
- the drill 10 (gradient composite material) having a diameter of 12 mm, an overall length of 100 mm, a length of an edge section 12 of 60 mm was obtained as a dense sintered product.
- the nitrogen was introduced into a furnace at the time of raising temperature of the furnace.
- the obtained drill 10 was cut for observation with an electron microscope. It was found that grains of ceramics grains existing at the surface were round and fine, while ceramics grains existing centrally in the drill 10 were greatly subjected to grain growth.
- Holes each having a depth of 40 mm were successively formed at a boring speed of 500 m/minute for an AC8B material (high silicon aluminum alloy) using the drill 10, a commercially available drill composed of superfine particle sintered product with a grain diameter of ceramics grain as a raw material of about 0.6 to 0.8 ⁇ m, and a drill composed of ultra-superfine particle sintered product with a grain diameter of ceramics grain as a raw material of less than about 0.4 ⁇ m to observe the relationship between the number of machined holes and the VB abrasion amount . A result of the observation is shown in FIG. 6. In FIG.
- the drill 10 is extremely excellent in abrasion resistance, and the drill 10 has a long service life, as compared with the both commercially available products.
- a built-up edge was formed before 10,000 holes were machined. As a result, the dimensional accuracy of the hole was also lowered.
- no formation of built-up edge was found even after 60,000 holes were machined. The holes were successfully formed accurately.
- a reamer 30 (gradient composite material) having a diameter of 15 mm, an overall length of 90 mm, a length of an edge section 32 of 30 mm was obtained.
- a reamer 30 grade composite material
- ceramics grains existing at the surface were fine and round and ceramics grains existing in the reamer 30 were greatly subjected to grain growth.
- a ceramics-rich section 38 was formed over a range of a depth of 5 mm from the surface.
- the holes formed in the AC8B material were subjected to cutting machining using the reamer 30 , a commercially available reamer composed of superfine particle sintered product, and a reamer composed of ultra-superfine particle sintered product to observe the relationship between the number of machined holes and the VB abrasion amount.
- the VB abrasion amount was about more than 0.2 mm when 30,000 holes were machined.
- the VB abrasion amount was less than 0.15 mm even after 60,000 holes were machined.
- a built-up edge was formed before 10,000 holes were machined. In the reamer 30, the formation of built-up edge was not found even after 60,000 holes were machined. The holes were successfully formed accurately.
- the drill 10 and the reamer 30 have the extremely excellent abrasion resistance as compared with the commercially available products, and hence the drill 10 and the reamer 30 have the long service lives.
- the built-up edge was not formed in the drill 10 and the reamer 30 because their machining surfaces are composed of the ceramics-rich sections 20, 38. That is, the composition ratio of the metal is small in the vicinity of the machining surface, and hence mutual reaction with the AC8B material as the workpiece is remarkably suppressed during boring machining or cutting machining.
- the machining tool according to the present invention is composed of the gradient composite material in which the composition ratio of the metal is decreased and the composition ratio of the ceramics is increased inwardly from the surface. Therefore, the machining tool according to the present invention has high hardness and strength as well as high toughness. Accordingly, the machining tool has the long service life, and the deformation scarcely occurs, because the machining tool is excellent in abrasion resistance. Further, the cracks and breakage scarcely occur. Furthermore, it is also possible to improve machining accuracy.
- the porous member impregnated with the catalyst-containing solution is resintered in the nitrogen atmosphere to prepare the cutting machining tool (gradient composite material).
- the grain growth of the ceramics grains existing in the vicinity of the surface of the porous member are suppressed with the nitrogen, while the grain growth of the ceramics grains existing in the porous member are facilitated with the catalyst. Accordingly, the metal grains are concentrated at the surface. Therefore, it is possible to obtain the machining tool in which the composition ratio of the metal is decreased and the composition ratio of the ceramics is increased inwardly from the surface, i.e., the machining tool has high toughness at the surface and high hardness internally.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Drilling Tools (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Powder Metallurgy (AREA)
- Ceramic Products (AREA)
- Processing Of Stones Or Stones Resemblance Materials (AREA)
- Milling, Broaching, Filing, Reaming, And Others (AREA)
Abstract
Description
Claims
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000385268 | 2000-12-19 | ||
JP2000385268 | 2000-12-19 | ||
JP2001236925 | 2001-08-03 | ||
JP2001236925 | 2001-08-03 | ||
PCT/JP2001/010887 WO2002049988A2 (en) | 2000-12-19 | 2001-12-12 | Machining tool and method of producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1345869A2 true EP1345869A2 (en) | 2003-09-24 |
EP1345869B1 EP1345869B1 (en) | 2008-04-30 |
Family
ID=26606094
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01271338A Expired - Lifetime EP1345869B1 (en) | 2000-12-19 | 2001-12-12 | Machining tool and method of producing the same |
Country Status (7)
Country | Link |
---|---|
US (1) | US6918943B2 (en) |
EP (1) | EP1345869B1 (en) |
JP (1) | JP3861056B2 (en) |
CN (1) | CN100500613C (en) |
AU (1) | AU2002222612A1 (en) |
DE (1) | DE60133833T2 (en) |
WO (1) | WO2002049988A2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2954197A1 (en) * | 2009-12-22 | 2011-06-24 | Eads Europ Aeronautic Defence | Drill for use in vibrating drilling system to pierce piece i.e. aeronautical pieces, has tip provided with two cutting edges, where width of core at tip is provided between two and five cm of external diameter of main body |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7169347B2 (en) * | 2000-12-19 | 2007-01-30 | Honda Giken Kogyo Kabushiki Kaisha | Making a molding tool |
SE532721C2 (en) * | 2007-10-01 | 2010-03-23 | Mircona Ab | Product with anti-vibration ceramic coating for chip removal during material processing and method of manufacture |
JP7008556B2 (en) * | 2018-03-26 | 2022-02-10 | 本田技研工業株式会社 | Cutting tool for cutting |
JP7388614B2 (en) * | 2020-03-10 | 2023-11-29 | 住友電工ハードメタル株式会社 | Reamer |
CN111168115A (en) * | 2020-03-17 | 2020-05-19 | 浙江德弘机电科技有限公司 | High-precision aluminum girder drilling process |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63169356A (en) * | 1987-01-05 | 1988-07-13 | Toshiba Tungaloy Co Ltd | Surface-tempered sintered alloy and its production |
DE69025582T3 (en) * | 1989-12-27 | 2001-05-31 | Sumitomo Electric Industries, Ltd. | Coated carbide body and process for its manufacture |
EP0505991B1 (en) * | 1991-03-27 | 1995-11-08 | Hitachi Metals, Ltd. | Titanium carbide-based cermet alloy |
SE9101590D0 (en) * | 1991-05-24 | 1991-05-24 | Sandvik Ab | SINTRAD CARBON Nitride Alloy with Binder Phase Enrichment |
SE9200530D0 (en) * | 1992-02-21 | 1992-02-21 | Sandvik Ab | HARD METAL WITH BINDING PHASE ENRICHED SURFACE |
US5577424A (en) | 1993-02-05 | 1996-11-26 | Sumitomo Electric Industries, Ltd. | Nitrogen-containing sintered hard alloy |
US5494635A (en) * | 1993-05-20 | 1996-02-27 | Valenite Inc. | Stratified enriched zones formed by the gas phase carburization and the slow cooling of cemented carbide substrates, and methods of manufacture |
JP3304726B2 (en) * | 1995-11-28 | 2002-07-22 | 住友金属鉱山株式会社 | Rare earth-iron-nitrogen magnet alloy |
AU8566598A (en) * | 1997-03-25 | 1998-11-11 | Diamond Materials Inc. | Triphasic composite and method for making same |
DE19907749A1 (en) * | 1999-02-23 | 2000-08-24 | Kennametal Inc | Sintered hard metal body useful as cutter insert or throwaway cutter tip has concentration gradient of stress-induced phase transformation-free face-centered cubic cobalt-nickel-iron binder |
-
2001
- 2001-12-12 JP JP2002551491A patent/JP3861056B2/en not_active Expired - Fee Related
- 2001-12-12 DE DE60133833T patent/DE60133833T2/en not_active Expired - Lifetime
- 2001-12-12 EP EP01271338A patent/EP1345869B1/en not_active Expired - Lifetime
- 2001-12-12 AU AU2002222612A patent/AU2002222612A1/en not_active Abandoned
- 2001-12-12 WO PCT/JP2001/010887 patent/WO2002049988A2/en active IP Right Grant
- 2001-12-12 US US10/450,680 patent/US6918943B2/en not_active Expired - Fee Related
- 2001-12-12 CN CNB018218695A patent/CN100500613C/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO0249988A2 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2954197A1 (en) * | 2009-12-22 | 2011-06-24 | Eads Europ Aeronautic Defence | Drill for use in vibrating drilling system to pierce piece i.e. aeronautical pieces, has tip provided with two cutting edges, where width of core at tip is provided between two and five cm of external diameter of main body |
Also Published As
Publication number | Publication date |
---|---|
CN100500613C (en) | 2009-06-17 |
US20040028488A1 (en) | 2004-02-12 |
WO2002049988A3 (en) | 2002-10-10 |
DE60133833T2 (en) | 2009-05-20 |
WO2002049988A2 (en) | 2002-06-27 |
CN1486288A (en) | 2004-03-31 |
AU2002222612A1 (en) | 2002-07-01 |
US6918943B2 (en) | 2005-07-19 |
JP2004517207A (en) | 2004-06-10 |
EP1345869B1 (en) | 2008-04-30 |
JP3861056B2 (en) | 2006-12-20 |
DE60133833D1 (en) | 2008-06-12 |
WO2002049988B1 (en) | 2004-02-19 |
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