EP1326495A1 - Active ingredient combinations with insecticidal, fungicidal and acaricidal properties - Google Patents

Active ingredient combinations with insecticidal, fungicidal and acaricidal properties

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Publication number
EP1326495A1
EP1326495A1 EP01982360A EP01982360A EP1326495A1 EP 1326495 A1 EP1326495 A1 EP 1326495A1 EP 01982360 A EP01982360 A EP 01982360A EP 01982360 A EP01982360 A EP 01982360A EP 1326495 A1 EP1326495 A1 EP 1326495A1
Authority
EP
European Patent Office
Prior art keywords
alkyl
optionally substituted
methyl
spp
alkoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01982360A
Other languages
German (de)
French (fr)
Inventor
Reiner Fischer
Ulrike Wachendorff-Neumann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer CropScience AG
Original Assignee
Bayer CropScience AG
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Filing date
Publication date
Application filed by Bayer CropScience AG filed Critical Bayer CropScience AG
Publication of EP1326495A1 publication Critical patent/EP1326495A1/en
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring

Definitions

  • the present invention relates to new combinations of active ingredients which consist of known cyclic ketoenols on the one hand and other known fungicidal active ingredients on the other hand and which are very suitable for controlling phytopathogenic fungi, spider mites and insects.
  • X represents halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano
  • W, Y and Z independently of one another represent hydrogen, halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano,
  • A represents hydrogen, in each case optionally substituted by halogen, alkyl, alkoxyalkyl, saturated, optionally substituted cycloalkyl, in which at least one ring atom is optionally replaced by a heteroatom,
  • B represents hydrogen or alkyl
  • a and B together with the carbon atom to which they are attached represent a saturated or unsaturated, optionally containing at least one heteroatom unsubstituted or substituted cycle,
  • D represents hydrogen or an optionally substituted radical from the series
  • E represents a metal ion or an ammonium ion
  • L represents oxygen or sulfur
  • M oxygen or sulfur
  • R ⁇ represents alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl, optionally substituted by halogen, or cycloalkyl, phenyl or benzyl, optionally substituted
  • R 3 represents alkyl which is optionally substituted by halogen or phenyl which is optionally substituted
  • R4 and R independently of one another each represent optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio or represent optionally substituted phenyl, benzyl, phenoxy or phenylthio and
  • R6 and R independently of one another for hydrogen, in each case optionally substituted by halogen, alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, for optionally substituted phenyl, for optionally substituted benzyl or together with the N atom to which they are attached, for one optionally by Oxygen or sulfur interrupted optionally substituted ring and
  • BAS 500F known from BCPC-Conf.-Pests Diss (2000) (Vol.) 2, 541-548 and or
  • the insecticidal, fungicidal and acaricidal activity of the active compound combination according to the invention is considerably higher than the sum of the effects of the individual active compounds. There is an unforeseeable real synergistic effect and not just an addition.
  • the active substance combinations according to the invention contain, in addition to at least one active substance of the formula (I), at least one active substance of the compounds 1 to 55.
  • W preferably represents hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, chlorine, bromine or fluorine,
  • X preferably represents C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkyl,
  • Y and Z independently of one another preferably represent hydrogen, C1-C4-alkyl, halogen, C 1 -C4-alkoxy or C -C4-haloalkyl,
  • A preferably represents hydrogen or in each case optionally substituted by halogen C C ⁇ -alkyl or C3-Cg-cycloalkyl,
  • B preferably represents hydrogen, methyl or ethyl
  • A, B and the carbon atom to which they are attached preferably represent saturated C3-C6 cycloalkyl in which optionally one ring member is replaced by oxygen or sulfur and which is optionally substituted one or two times by C 1 -C 4 alkyl, Trifluoromethyl or C 1 -C 4 alkoxy is substituted, D preferably represents hydrogen, in each case optionally substituted by fluorine or chlorine, -C 6 -alkyl, C 3 -C 4 -alkenyl or C 3 -C 6 -cycloalkyl,
  • a and D together preferably represent C 3 -C 4 -alkanediyl which is optionally substituted by methyl, in which a methylene group is optionally replaced by sulfur,
  • G preferably represents hydrogen (a) or one of the groups
  • E represents a metal ion or an ammonium ion
  • L represents oxygen or sulfur
  • M oxygen or sulfur
  • R 1 preferably represents in each case optionally substituted by halogen -CC-alyl, C 2 -C 10 -alkenyl, C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl, C 1 -C 4 -alkylthio-
  • phenyl optionally substituted by fluorine, chlorine, bromine, cyano, nitro, C 1 -C 4 -alkyl, CrCzt-alkoxy, trifluoromethyl or trifluoromethoxy
  • pyridyl or thienyl optionally substituted by chlorine or methyl
  • R 2 preferably represents d-do-alkyl, C 2 -do-alkenyl, C 1 -C 4 -alkoxy-C 2 -C 4 -alkyl, each optionally substituted by fluorine or chlorine,
  • C 5 -C 6 cycloalkyl optionally substituted by methyl or methoxy or
  • R 3 preferably represents optionally substituted by fluorine QC 4 - alkyl or optionally substituted by fluorine, chlorine, bromine, Ci-C 4 alkyl, C 1 -C 4 -alkoxy -AI-, trifluoromethyl, trifluoromethoxy, cyano or nitro,
  • R 4 preferably represents in each case optionally fluorine or chlorine substitution jewes by C ⁇ -C 4 alkyl, C 1 -C 4 alkoxy, C 1 -C alkylamino, C 1 -C 4 -alkylthio or represents in each case optionally fluorine- , Chlorine, bromine, nitro, cyano, dC 4 -
  • R 5 preferably represents dC 4 alkoxy or dC 4 thioalkyl
  • R 6 preferably represents dC 6 alkyl, C 3 -C 6 cycloalkyl, dC 6 alkoxy, C 3 -G 6 alkenyl, dC 4 alkoxy -CC 4 -alkyl,
  • R 7 preferably represents dC 6 -alkyl, C 3 -C 6 -alkenyl or dC 4 -alkoxy-dC 4 -alkyl, R 6 and R 7 together preferably represent a C 3 -C 6 -alkylene radical which is optionally substituted by methyl or ethyl and in which a carbon atom is optionally replaced by oxygen or sulfur,
  • W particularly preferably represents hydrogen, methyl, ethyl, chlorine, bromine or methoxy
  • X particularly preferably represents chlorine, bromine, methyl, ethyl, propyl, i-propyl, methoxy, ethoxy or trifluoromethyl,
  • Y and Z are particularly preferably independently of one another hydrogen, fluorine, chlorine, bromine, methyl, ethyl, propyl, i-propyl, trifluoromethyl or methoxy,
  • B particularly preferably represents hydrogen, methyl or ethyl
  • A, B and the carbon atom to which they are attached are particularly preferably saturated C 6 -cycloalkyl, in which a ring member is optionally replaced by oxygen and which is optionally simply substituted by methyl, ethyl, methoxy, ethoxy, propoxy or butoxy,
  • D particularly preferably represents hydrogen, represents methyl, ethyl, propyl, i-propyl, butyl, i-butyl, allyl, cyclopropyl, cyclopentyl or cyclohexyl,
  • a and D together particularly preferably represent C 3 -C 4 -alkanediyl which is optionally substituted by methyl,
  • G particularly preferably represents hydrogen (a) or one of the groups
  • M oxygen or sulfur
  • R 1 particularly preferably represents d-Cs-alkyl, C 2 -C 4 -alkenyl, methoxymethyl, ethoxymethyl, ethylthiomethyl, cyclopropyl, cyclopentyl or cyclohexyl,
  • phenyl optionally substituted by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, methoxy, trifluoromethyl or trifluoromethoxy,
  • R 2 particularly preferably represents CrC 8 alkyl, C 2 -C 4 alkenyl, methoxyethyl, ethoxyethyl or phenyl or benzyl,
  • R 6 and R 7 independently of one another particularly preferably represent methyl, ethyl or together a Cs-alkylene radical in which the C 3 -methylene group is replaced by oxygen.
  • W very particularly preferably represents hydrogen or methyl
  • X very particularly preferably represents chlorine, bromine or methyl
  • Y and Z very particularly preferably independently of one another represent hydrogen, chlorine, bromine or methyl
  • A, B and the carbon atom to which they are attached very particularly preferably represent saturated C 6 -cycloalkyl, in which one ring member is optionally replaced by oxygen and which is optionally simply substituted by methyl, methoxy, ethoxy, propoxy or butoxy,
  • D very particularly preferably represents hydrogen
  • G very particularly preferably represents hydrogen (a) or one of the groups
  • M oxygen or sulfur
  • R 1 very particularly preferably represents C 1 -C 8 -alkyl, C 2 -C 4 -alkenyl, methoxymethyl, ethoxymethyl, ethylmethylthio, cyclopropyl, cyclopentyl, cyclohexyl or
  • phenyl optionally substituted by fluorine, chlorine, bromine, methyl, methoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro,
  • R 2 very particularly preferably represents C 1 -C 6 -alkyl, C 2 -C 4 -alkenyl, methoxyethyl, ethoxyethyl, phenyl or benzyl, R 6 and R 7 independently of one another very particularly preferably represent methyl, ethyl or together a Cs-alkylene radical in which the C 3 -methylene group is replaced by oxygen.
  • the active substance combinations can also contain other fungicidal, acaricidal or insecticidal active components.
  • the combinations according to the invention contain active compounds of the formula (I) and the mixing partner in the preferred and particularly preferred mixing ratios given in the table below:
  • the mixing ratios are based on weight ratios.
  • the ratio is to be understood as an active ingredient of the formula ( ⁇ ): mixing partner
  • the active compound combinations according to the invention have a strong microbicidal action and can be used to control unwanted microorganisms, such as fungi and bacteria, in crop protection and in material protection.
  • Fungicides can be used in crop protection to combat Plasmodiophoromyces, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.
  • Bactericides can be used in crop protection to control Pseudomonadaceae
  • Xanthomonas species such as, for example, Xanthomonas campestris pv. Oryzae;
  • Pseudomonas species such as, for example, Pseudomonas syringae pv. Lachrymans;
  • Erwinia species such as, for example, Erwinia amylovora
  • Pythium species such as, for example, Pythium ultimum
  • Phytophthora species such as, for example, Phytophthora infestans
  • Pseudoperonospora species such as, for example, Pseudoperonospora humuli or
  • Plasmopara species such as, for example, Plasmopara viticola
  • Bremia species such as, for example, Bremia lactucae
  • Peronospora species such as, for example, Peronospora pisi or P. brassicae;
  • Erysiphe species such as, for example, Erysiphe graminis
  • Sphaerotheca species such as, for example, Sphaerotheca Sportsiginea;
  • Podosphaera species such as, for example, Podosphaera leucotricha
  • Venturia species such as, for example, Venturia inaequalis
  • Pyrenophora species such as, for example, Pyrenophora teres or P. graminea
  • Drechslera (Conidial form: Drechslera, Syn: Helminthosporium);
  • Cochliobolus species such as, for example, Cochliobolus sativus
  • Drechslera (Conidial form: Drechslera, Syn: Helminthosporium); Uromyces species, such as, for example, Uromyces appendiculatus;
  • Puccinia species such as, for example, Puccinia recondita; Sclerotinia species, such as, for example, Sclerotinia sclerotiorum; Tilletia species, such as, for example, Tilletia caries; Ustilago species, such as, for example, Ustilago nuda or Ustilago avenae; Pellicularia species, such as, for example, Pellicularia sasakii; Pyricularia species, such as, for example, Pyricularia oryzae;
  • Fusarium species such as, for example, Fusarium culmorum
  • Botrytis species such as, for example, Botrytis cinerea
  • Septoria species such as, for example, Septoria nodorum
  • Leptosphaeria species such as, for example, Leptosphaeria nodorum
  • Cercospora species such as, for example, Cercospora canescens
  • Alternaria species such as, for example, Alternaria brassicae
  • Pseudocercosporella species such as, for example, Pseudocercosporella he ⁇ otrichoides.
  • the active compound combinations according to the invention are also suitable for increasing the crop yield. They are also less toxic and have good plant tolerance.
  • the active compound combinations according to the invention can be used to protect technical materials against attack and destruction by undesired microorganisms.
  • technical materials are to be understood as non-living materials that have been prepared for use in technology.
  • technical materials that are to be protected against microbial change or destruction by active substance combinations according to the invention can be adhesives, glues, paper and cardboard, textiles, leather, wood, paints and plastic articles, cooling lubricants and other materials. which can be attacked or decomposed by microorganisms.
  • parts of production plants for example cooling water circuits, are also mentioned which can be impaired by the multiplication of microorganisms.
  • technical materials are preferably adhesives, glues, papers and cartons, leather,
  • Wood, paints, cooling lubricants and heat transfer liquids called, particularly preferably wood.
  • Bacteria, fungi, yeasts, algae and, for example, are microorganisms which can break down or change the technical materials
  • the active compound combinations according to the invention preferably act against fungi, in particular mold, wood-discoloring and wood-destroying fungi (Basidiomycetes) and against mucus organisms and algae.
  • microorganisms of the following genera may be mentioned:
  • Alternaria such as Alternaria tenuis
  • Aspergillus such as Aspergillus niger
  • Chaetomium like Chaetomium globosum
  • Coniophora such as Coniophora puetana
  • Lentinus such as Lentinus tigrinus
  • Penicillium such as Penicillium glaucum
  • Polyporus such as Polyporus versicolor
  • Aureobasidium such as Aureobasidium pullulans
  • Sclerophoma such as Sclerophoma pityophila
  • Trichoderma such as Trichoderma viride
  • Escherichia such as Escherichia coli
  • Pseudomonas such as Pseudomonas aeruginosa
  • Staphylococcus such as Staphylococcus aureus.
  • the active substance combinations can be converted into the customary formulations.
  • customary formulations such as solutions, emulsions, suspensions, powders, foams, pastes, granules, aerosols, very fine encapsulations in polymeric substances and in coating compositions for seeds, as well as ULV cold and warm mist formulations.
  • formulations are made in a known manner, e.g. by mixing the active ingredients with extenders, that is to say liquid solvents, pressurized liquefied gases and / or solid carriers, if appropriate using surface-active agents, that is to say emulsifiers and / or dispersants and / or foam-generating agents. If water is used as an extender, e.g. organic solvents can also be used as auxiliary solvents.
  • extenders that is to say liquid solvents, pressurized liquefied gases and / or solid carriers, if appropriate using surface-active agents, that is to say emulsifiers and / or dispersants and / or foam-generating agents.
  • surface-active agents that is to say emulsifiers and / or dispersants and / or foam-generating agents.
  • water e.g. organic solvents can also be used as auxiliary solvents.
  • aromatics such as xylene, toluene or alkyl naphthalene
  • chlorinated aromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chlorethylenes or methylene chloride
  • aliphatic hydrocarbons such as cyclohexane or paraffins, e.g. Petroleum fractions, alcohols, such as butanol or glycol, and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
  • highly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • Liquefied gaseous extenders or carriers mean liquids which are gaseous at normal temperature and under normal pressure, e.g. Aerosol propellants such as halogenated hydrocarbons as well as butane, propane, nitrogen and carbon dioxide.
  • Possible solid carriers are: e.g. natural rock meals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock meals, such as highly disperse silica, aluminum oxide and silicates. The following are suitable as solid carriers for granules: e.g. broken and fractionated natural rocks such as calcite, marble,
  • emulsifiers and / or foam-generating agents are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolyzates.
  • Possible dispersants are: eg lignin sulfite waste liquor and methyl cellulose.
  • Adhesives such as carboxymethyl cellulose, natural and synthetic polymers in the form of powders, granules or latices, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and also natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids can be used in the formulations.
  • Other additives can be mineral and vegetable oils.
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.
  • the formulations generally contain between 0.1 and 95 percent by weight
  • Active ingredient preferably between 0.5 and 90%.
  • the active substance combinations can be used as such, in the form of their formulations or the use forms prepared therefrom, such as ready-to-use solutions, suspensions, wettable powders, pastes, soluble powders, dusts and granules. They are used in the usual way, e.g. by pouring, spraying, atomizing, scattering, dusting, foaming, brushing, etc. It is also possible to apply the active ingredients using the ultra-low-volume process or to inject the active ingredient preparation or the active ingredient itself into the soil. The seeds of the plants can also be treated.
  • the application rates can be varied within a relatively wide range, depending on the type of application.
  • the active compound application rates are generally between 0.1 and 10,000 g / ha, preferably between 10 and 1,000 g / ha.
  • the active compound application rates are generally between 0.001 and 50 g per kg of seed, preferably between 0.01 and 10 g per kg of seed.
  • the active compound application rates are generally between 0.1 and 10,000 g / ha, preferably between 1 and 5,000 g / ha.
  • the agents used to protect industrial materials generally contain the active ingredients in an amount of 1 to 95% by weight, preferably 10 to 75% by weight.
  • the application concentrations of the active compound combinations according to the invention depend on the type and the occurrence of the microorganisms to be controlled and on the composition of the material to be protected.
  • the optimal amount can be determined by test series.
  • the application concentrations are in the range from 0.001 to 5% by weight, preferably from 0.05 to 1.0% by weight, based on the material to be protected.
  • the active compound combinations according to the invention are suitable for controlling animal pests, preferably arthropods and nematodes, in particular insects and arachnids, which occur in agriculture, animal health, in forests, in the protection of stored goods and materials and in the hygiene sector. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • animal pests preferably arthropods and nematodes, in particular insects and arachnids, which occur in agriculture, animal health, in forests, in the protection of stored goods and materials and in the hygiene sector. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • the pests mentioned above include:
  • Isopoda e.g. Oniscus asellus, Armadillidium vulgare, Porcellio scaber.
  • Thysanura for example Lepisma saccharina.
  • Collembola for example Onychiurus armatus.
  • Orthoptera for example Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
  • the Blattaria for example Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica.
  • Dermaptera for example, Forficula auricularia.
  • Phthiraptera e.g. Pediculus humanus co ⁇ oris, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp ..
  • Thysanoptera e.g. Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
  • Heteroptera e.g. Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.
  • Homoptera e.g. Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fäbae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis,
  • Anthrenus spp. Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimalltra solitus Lissorhoptrus oryzophilus. From the order of the Hymenoptera, for example Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
  • Dacus oleae Tipula paludosa, Hylemyia spp., Liriomyza spp .. From the order of the Siphonaptera e.g. Xenopsylla cheopis, Ceratophyllus spp .. From the Arachnida class e.g.
  • Hyalomma spp. Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp ..
  • Plant-parasitic nematodes include e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaph.
  • the active substance combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, Pastes, soluble powders, granules, suspension emulsion concentrates, active ingredient-impregnated natural and synthetic substances as well as fine encapsulation in polymeric substances.
  • formulations are made in a known manner, e.g. by mixing the active ingredients with extenders, that is to say liquid solvents and / or solid carriers, optionally using surface-active agents, that is to say emulsifiers and / or dispersants and / or foam-generating agents.
  • extenders that is to say liquid solvents and / or solid carriers
  • surface-active agents that is to say emulsifiers and / or dispersants and / or foam-generating agents.
  • water is used as an extender, e.g. also organic
  • Solvents are used as auxiliary solvents.
  • the following are essentially suitable as liquid solvents: aromatics, such as xylene, toluene, or alkyl naphthalene, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chlorethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable
  • ketones such as acetone, methyl ethyl ketone, methylhysobutyl ketone or cyclohexanone
  • strongly polar solvents such as dimethylformamide and dimethyl sulfoxide
  • solid carriers for example ammonium salts and natural rock powders, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders, such as highly disperse silica, aluminum oxide and silicates, as solid carriers for granules are possible: eg broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; Possible emulsifying and / or foam-generating agents are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl
  • Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids can be used in the formulations.
  • Other additives can be mineral and vegetable oils.
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.
  • the formulations generally contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%.
  • the active compound combinations according to the invention can be used in commercially available formulations and in the use forms prepared from these formulations in a mixture with other active compounds, such as insecticides, attractants, sterilizers,
  • Insecticides include, for example, phosphoric acid esters, carbamates, carboxylic acid esters, chlorinated hydrocarbons, phenylureas, substances produced by microorganisms, etc.
  • the active compound combinations according to the invention can also be present in their commercially available formulations and in the use forms prepared from these formulations in a mixture with synergists.
  • Synergists are compounds that increase the effectiveness of the active ingredients without the added synergist itself having to be active.
  • the active substance content of the use forms prepared from the commercially available formulations can vary within wide ranges.
  • Application forms can be from 0.0000001 to 95% by weight of active compound, preferably between 0.0001 and 1% by weight.
  • the application takes place in a customary manner adapted to the application forms.
  • the active substance combinations When used against hygiene pests and pests of stored products, the active substance combinations are notable for an excellent residual action on wood and clay and for good stability to alkali on limed substrates.
  • the active compound combinations according to the invention act not only against plant, hygiene and stored-product pests, but also in the veterinary sector against animal parasites (ectoparasites) such as tick ticks, leather ticks, space mites, running mites, flies (stinging and licking), parasitic fly larvae, lice, Hair lice, featherlings and fleas.
  • animal parasites ectoparasites
  • tick ticks leather ticks
  • space mites space mites
  • running mites running mites
  • flies stinging and licking
  • parasitic fly larvae lice, Hair lice, featherlings and fleas.
  • Anoplurida e.g. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp ..
  • Nematocerina and Brachycerina for example Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp.
  • Atylotus spp. Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp ..
  • Siphonaptrida e.g. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp ..
  • Heteropterida e.g. Cimex spp., Triatoma spp., Rhodnius spp.
  • Acarapis spp. Cheyletiella spp., Ornitrocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypppectoles spp ., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp ..
  • the active compound combinations according to the invention are also suitable for combating arthropods which are used in agricultural animals, such as Cattle, sheep, goats, horses, pigs, donkeys, camels, buffalo, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as e.g. Dogs, cats, house birds, aquarium fish and so-called experimental animals, such as Hamsters, guinea pigs, rats and
  • the active compound combinations according to the invention are used in the veterinary sector in a known manner by enteral administration in the form of, for example, tablets, capsules, drinkers, drenches, granules, pastes, boluses, the feed-through method, suppositories, by parenteral administration, such as for example play through injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.),
  • Implants by nasal application, by dermal application in the form of, for example, diving or bathing (dipping), spraying (spray), pouring on (pour-on and spot-on), washing, powdering and with the help of shaped articles containing active ingredients, such as collars , Ear tags, tail tags, limb bands, holsters, marking devices, etc.
  • active ingredients such as collars , Ear tags, tail tags, limb bands, holsters, marking devices, etc.
  • the active substance combinations can be formulated (for example powders, emulsions, flowable agents) which contain the active substances in an amount of 1 to 80% by weight, directly or after 100 to 10,000 -Apply thinner or use it as a chemical bath.
  • insects may be mentioned by way of example and without limitation - beetles such as Hylotrupes bajulus, Chlorophoras pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium ca ⁇ ini, Lyctus africanus, Lyctus brunicanus, Lyctus brunicanus Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus.
  • Kalotermes flavicollis Cryptotermes brevis, Heterotermes indicola, Reticuhtermes flavipes, Reticuhtermes santonensis, Reticuhtermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus.
  • Bristle tails such as Lepisma saccharina.
  • non-living materials such as preferably plastics, adhesives, glues, papers and cartons, leather, wood, wood processing products and paints.
  • the material to be protected against insect infestation is very particularly preferably wood and wood processing products.
  • the active ingredient combinations can be used as such, in the form of concentrates or generally customary formulations such as powders, granules, solutions, suspensions, emulsions or pastes.
  • the formulations mentioned can be prepared in a manner known per se, for example by mixing the active ingredients with at least one solvent or diluent, emulsifier, dispersant and / or binder or fixative, water repellants, optionally siccatives and UV stabilizers and, if appropriate Dyes and pigments as well as other processing aids.
  • the insecticidal compositions or concentrates used to protect wood and wood-based materials contain the active compound according to the invention in a concentration of 0.0001 to 95% by weight, in particular 0.001 to 60% by weight.
  • the amount of the agents or concentrates used depends on the type and occurrence of the insects and on the medium. The optimal amount can be determined in each case by test series. In general, however, it is sufficient to use 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of the active compound, based on the material to be protected.
  • Water and optionally an emulsifier and / or wetting agent optionally an emulsifier and / or wetting agent.
  • the organic chemical solvents used are preferably oily or oily solvents with an evaporation number above 35 and a flash point above 30 ° C., preferably above 45 ° C.
  • Corresponding mineral oils or their aromatic fractions or mineral oil-containing solvent mixtures, preferably white spirit, petroleum and / or alkylbenzene, are used as such low-volatility, water-insoluble, oily and oily solvents.
  • Mineral oils with a boiling range of 170 to 220 ° C, white spirit with a boiling range of 170 to 220 ° C, spindle oil with a boiling range of 250 to 350 ° C, petroleum or aromatics with a boiling range of 160 to 280 ° C, Te ⁇ entinöl and Like. Used.
  • organic non-volatile oily or oily solvents with an evaporation number above 35 and a flash point above 30 ° C, preferably above 45 ° C can be partially replaced by slightly or medium-volatile organic chemical solvents, with the proviso that the solvent mixture also has an evaporation number 35 and has a flash point above 30 ° C, preferably above 45 ° C, and that the mixture is soluble or emulsifiable in this solvent mixture.
  • part of the organic chemical solvent or solvent mixture is replaced by an aliphatic polar organic chemical solvent or solvent mixture.
  • Aliphatic organic chemical solvents containing hydroxyl and / or ester and / or ether groups, such as, for example, glycol ethers, esters or the like, are preferably used.
  • organic chemicals which are known per se and which are water-thinnable and / or soluble or dispersible or emulsifiable in the organic chemical solvents used and / or binding drying oils, in particular binders consisting of or comprising an acrylate resin, a vinyl resin, for example polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin such as indene-coumarone resin, silicone resin, drying vegetable and / or drying oils and / or physically drying binders on the Base of a natural and / or synthetic resin used.
  • binders consisting of or comprising an acrylate resin, a vinyl resin, for example polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin such as indene-coumarone resin, silicone resin, drying
  • the synthetic resin used as a binder can be used in the form of an emulsion, dispersion or solution. Bitumen or bituminous substances up to 10% by weight can also be used as binders. In addition, known dyes, pigments, water-repellants, odor correctors and inhibitors or anticorrosive agents and the like can be used.
  • At least one alkyd resin or modified alkyd resin and / or a drying vegetable oil is preferably contained in the agent or in the concentrate as the organic chemical binder.
  • Alkyd resins having an oil content of more than 45% by weight, preferably 50 to, are preferred according to the invention
  • binder mentioned can be replaced by a fixative (mixture) or a plasticizer (mixture).
  • fixative mixture
  • plasticizer mixture
  • additives are intended to volatilize the active ingredients and crystallize or precipitate! prevent. They preferably replace 0.01 to 30% of the binder (based on 100% of the binder used).
  • the plasticizers come from the chemical classes of phthalic acid esters such as dibutyl, dioctyl or benzyl butyl phthalate, phosphoric acid esters such as tributyl phosphate, adipic acid esters such as di- (2-ethylhexyl) adipate, stearates such as butyl stearate or amyl stearate, oleates such as butyl oleate, higher glycerol glycerol or glycerol ether - Kolether, glycerol ester and p-toluenesulfonic acid ester.
  • phthalic acid esters such as dibutyl, dioctyl or benzyl butyl phthalate
  • phosphoric acid esters such as tributyl phosphate
  • adipic acid esters such as di- (2-ethylhexyl) adipate
  • Fixing agents are chemically based on polyvinyl alkyl ethers such as e.g. Polyvinyl methyl ether or ketones such as benzophenone, ethylene benzophenone.
  • Water is also particularly suitable as a solvent or diluent, if appropriate in a mixture with one or more of the above-mentioned organic chemical solvents or diluents, emulsifiers and dispersants.
  • a particularly effective wood protection is achieved by industrial impregnation processes, e.g. vacuum, double vacuum or pressure processes.
  • the active compound combinations according to the invention can be used to protect objects, in particular ship hulls, sieves, nets, structures, quay systems and signaling systems which come into contact with sea or brackish water.
  • Scalpellum species or by species from the group Balanomo ⁇ ha (barnacles), such as Baianus or pollicipes species, increases the frictional resistance of ships and, as a result, leads to a significant increase in operating costs due to increased energy consumption and, moreover, frequent dry dock stays.
  • heavy metals such as e.g. in bis (trialkyltin) sulfides, tri-ra- butyltin laurate, trif-butyltin chloride, copper (I) oxide, triethyltin chloride, tri - / - butyl (2-phenyl-4-chloropheneoxy) tin, tributyltin oxide, molybdenum disulfide , Antimony oxide, polymeric butyl titanate, phenyl (bispyridine) bismuth chloride, tri-n-butyltin fluoride, manganese ethylene bisthiocarbamate, zinc dimethyldithiocarbamate, zinc ethylene bisthiocarbamate,
  • the ready-to-use antifouling paints can also be used if necessary
  • active ingredients preferably algicides, fungicides, herbicides, molluscicides or other antifouling active ingredients.
  • Suitable combination partners for the antifouling agents according to the invention are preferably:
  • the antifouling agents used contain the active substance combinations according to the invention in a concentration of 0.001 to 50% by weight, in particular 0.01 to 20% by weight.
  • the antifouling agents according to the invention furthermore contain the usual constituents, e.g. in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.
  • antifouling paints contain in particular binders.
  • Examples of recognized binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in a solvent system, especially in an aqueous system, vinyl chloride / vinyl acetate copolymer systems in the form of aqueous dispersions or in the form of organic solvent systems, butadiene / styrene / acrylonitrile Rubbers, drying oils, such as linseed oil, resin esters or modified hard resins in combination with tar or bitumen, asphalt and epoxy compounds, small amounts of chlorinated rubber, chlorinated polypropylene and vinyl resins.
  • Paints may also contain inorganic pigments, organic pigments or dyes, which are preferably insoluble in sea water. Paints may also contain materials such as rosin to enable controlled release of the active ingredients.
  • the paints may also contain plasticizers, modifiers that affect rheological properties, and other conventional ingredients.
  • the compounds according to the invention or the abovementioned mixtures can also be incorporated into self-polishing antifouling systems.
  • the active ingredient combinations are also suitable for controlling animal pests, in particular insects, arachnids and mites, which occur in closed rooms, such as, for example, apartments, factory halls, offices, vehicle cabins and others. They can be used to control these pests in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include: From the order of the Sco ⁇ ionidea, for example Buthus occitanus.
  • Acarina e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula arfreddugesi, Neutrombicula autumnalis,
  • Dermatophagoides pteronissimus Dermatophagoides forinae.
  • Araneae e.g. Aviculariidae
  • Araneidae From the order of the Opiliones e.g. Pseudosco ⁇ iones chelifer, Pseudosco ⁇ iones cheiridium, Opiliones phalangium.
  • Isopoda e.g. Oniscus asellus, Porcellio scaber.
  • Diplopoda e.g. Blaniulus guttulatus, Polydesmus spp ..
  • Lepismodes inquilinus From the order of the Blattaria e.g. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa. From the order of the Saltatoria e.g. Acheta domesticus. From the order of the Dermaptera e.g. Forficula auricularia.
  • From the order of the Diptera for example Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis,
  • Lepidoptera e.g. Achroia grisella, Galleria mellonella, Plodia inte ⁇ unctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
  • Ctenocephalides canis From the order of the Siphonaptera e.g. Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis. From the order of the Hymenoptera e.g. Camponotus herculeanus, Lasius Füliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
  • Rhodinus prolixus Triatoma infestans.
  • Plants are understood to mean all plants and plant populations, such as desired and undesirable wild plants or cultivated plants (including naturally occurring cultivated plants).
  • Cultivated plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the Plant varieties that can or cannot be protected by plant breeders' rights.
  • Plant parts are to be understood to mean all above-ground and underground parts and organs of plants, such as shoots, leaves, flowers and roots, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes .
  • the plant parts also include crops and vegetative and generative propagation material, for example cuttings, tubers, rhiozomes, offshoots and seeds.
  • Storage room according to the usual treatment methods, e.g. by dipping, spraying, vaporizing, atomizing, scattering, spreading and, in the case of propagation material, in particular seeds, furthermore by single- or multi-layer coating.
  • plants and their parts can be treated according to the invention.
  • plant species and plant cultivars and their parts occurring wildly or obtained by conventional organic breeding methods, such as crossbreeding or protoplast fusion are treated.
  • transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (genetic modified organisms) and their parts are treated.
  • the term "parts” or “parts of plants” or “plant parts” was explained above.
  • Plants of the plant varieties which are in each case commercially available or in use are particularly preferably treated according to the invention.
  • the treatment according to the invention can also cause superadditive (“synergistic") effects.
  • superadditive for example, reduced application rates and / or extensions of the spectrum and / or an enhancement of the effect of the substances and agents which can be used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to water or soil salt content, increased flowering performance, easier harvesting, acceleration of ripening, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or workability of the harvested products possible, which go beyond the effects that are actually to be expected.
  • the preferred transgenic (genetically engineered) plants or plant cultivars to be treated according to the invention include all plants which, by virtue of the genetic engineering modification, have received genetic material which gives these plants particularly advantageous, valuable properties (“traits”). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering performance, easier harvesting, accelerated ripening, higher harvest yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products.
  • transgenic plants are the important cultivated plants, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybeans, potatoes and cotton and rapeseed are highlighted.
  • the traits are particularly emphasized as the increased defense of the plants against insects by toxins which arise in the plants, in particular those which are caused by the genetic material from Bacillus thuringiensis (for example by the genes Cry ⁇ A (a), CryIA (b), Cry ⁇ A (c), CryllA, CrylllA, C ⁇ ymB2, Cry9c, Cry2Ab, Cry3Bb and CrylF and their combinations) are produced in the plants (hereinafter "Bt plants”).
  • trait As properties (“traits”) continue to be special emphasized the increased tolerance of the plants to certain herbicidal active ingredients, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene).
  • the genes imparting the desired properties (“traits”) can also occur in combinations with one another in the transgenic plants. Examples of “Bt plants” are maize varieties,
  • Cotton varieties, soy varieties and potato varieties named under the trade names YIELD GARD® (e.g. corn, cotton, soy), KnockOut® (e.g. corn), StarLink® (e.g. corn), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf ® (potato) are sold.
  • Examples of herbicide-tolerant plants are corn varieties, cotton varieties and soy varieties which are marketed under the trade names Roundup Ready® (tolerance against glyphosate, e.g. maize, cotton, soy), Liberty Link® (tolerance against phosphinotricin, e.g.
  • Herbicide-resistant plants are also those under the name
  • the plants listed can be treated particularly advantageously according to the invention with the active compound mixtures according to the invention.
  • the preferred ranges given for the mixtures above also apply to the treatment of these plants. Plant treatment with the mixtures specifically listed in the present text should be particularly emphasized.
  • Insecticides, fungicides and acaricides always have a synergistic effect when the effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
  • the expected effect for a given combination of two active substances can be calculated as follows (cf. Colby, SR, "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 15, pages 20-22, 1967):
  • E means the expected efficiency, expressed in% of the untreated control, when using the active compound A and B in a concentration of m and n ppm,
  • the effect of the combination is super-additive, i.e. it is a synergistic
  • Test insect Diabrotica balteata - larvae in the soil
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the stated amount of solvent, the stated amount of emulsifier is added and the concentrate is diluted with water to the desired concentration.
  • the active ingredient preparation is poured onto the floor.
  • the concentration of the active ingredient in the preparation is practically irrelevant, the only decisive factor is the amount of active ingredient per unit volume of soil, which is given in ppm (mg / 1).
  • the bottom is filled in 0.25 l pots and left at 20 ° C.
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • Soybean shoots (Glycine max) of the Roundup Ready variety (trademark of Monsanto Comp. USA) are treated by dipping into the preparation of active compound of the desired concentration and populated with the tobacco bud caterpillar Heliothis virescens while the leaves are still moist.
  • the killing of the insects is determined.

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  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
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Abstract

The novel active ingredient combinations consisting of identified cyclic ketoenoles and active ingredients (1) to (55) listed in the description exhibit excellent insecticidal, fungicidal and acaricidal properties.

Description

Wirkstoffkombinationen mit insektiziden, fungiziden und akarizidcn EigenschaftenActive ingredient combinations with insecticidal, fungicidal and acaricidal properties
Die vorliegende Erfindung betrifft neue Wirkstoffkombinationen, die aus bekannten cyclischen Ketoenole einerseits und weiteren bekannten fungiziden Wirkstoffen andererseits bestehen und sehr gut zur Bekämpfung von phytopathogenen Pilzen, Spinnenmilben und Insekten geeignet sind.The present invention relates to new combinations of active ingredients which consist of known cyclic ketoenols on the one hand and other known fungicidal active ingredients on the other hand and which are very suitable for controlling phytopathogenic fungi, spider mites and insects.
Es ist bereits bekannt, dass bestimmte cyclische Ketoenole herbizide, insektizide und akarizide Eigenschaften besitzen. Die Wirksamkeit dieser Stoffe ist gut, lässt aber bei niedrigen Aufwandmengen in manchen Fällen zu wünschen übrig.It is already known that certain cyclic ketoenols have herbicidal, insecticidal and acaricidal properties. The effectiveness of these substances is good, but leaves something to be desired in some cases at low application rates.
Bekannt mit herbizider, insektizider oder akarizider Wirkung sind unsubstituierte, bi- cyclische 3-Aryl-pyrrolidin-2,4-dion-Derivate (EP-A-355 599 und EP-A-415 211) sowie substituierte monocyclische 3-Aryl-pyrrolidin-2,4-dion-Derivate (EP-A- 377 893 und EP-A-442 077).Unsubstituted, bicyclic 3-aryl-pyrrolidine-2,4-dione derivatives (EP-A-355 599 and EP-A-415 211) and substituted monocyclic 3-aryl-pyrrolidine are known with herbicidal, insecticidal or acaricidal activity -2,4-dione derivatives (EP-A-377 893 and EP-A-442 077).
Weiterhin bekannt sind polycyclische 3-Arylpyrrolidin-2,4-dion-Derivate (EP-A- 442 073) sowie lH-Arylpyrrolidin-dion-Derivate (EP-A-456 063, EP-A-521 334,Polycyclic 3-arylpyrrolidine-2,4-dione derivatives (EP-A-442 073) and 1H-arylpyrrolidine-dione derivatives (EP-A-456 063, EP-A-521 334,
EP-A-596 298, EP-A-613 884, EP-A-613 885, WO 94/01 997, WO 95/26 954, WO 95/20 572, EP-A-0 668 267, WO 96/25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 97/ 43 275, WO 98/05 638, WO 98/06 721, WO 98/25 928, WO 99/16 748, WO 99/24 437, WO 99/43 649, WO 99/48 869 und WO 99/55 673).EP-A-596 298, EP-A-613 884, EP-A-613 885, WO 94/01 997, WO 95/26 954, WO 95/20 572, EP-A-0 668 267, WO 96 / 25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 97/ 43 275, WO 98/05 638, WO 98/06 721, WO 98/25 928 , WO 99/16 748, WO 99/24 437, WO 99/43 649, WO 99/48 869 and WO 99/55 673).
Ferner ist schon bekannt, dass zahlreiche Azol-Derivate, aromatische Carbonsäure- Derivate, Moφholin-Nerbindungen und andere Heterocyclen zur Bekämpfung von Pilzen eingesetzt werden können (vgl. K.H. Büchel "Pflanzenschutz und Schädlings- bekämpfung" Seiten 87, 136, 141 und 146 bis 153, Georg Thieme Verlag, Stuttgart 1977). Die Wirkung der betreffenden Stoffe ist aber bei niedrigen Aufwandmengen nicht immer befriedigend.Furthermore, it is already known that numerous azole derivatives, aromatic carboxylic acid derivatives, Moφholin-Nerbindungen and other heterocycles can be used to combat fungi (see KH Büchel "Plant Protection and Pest Control" pages 87, 136, 141 and 146 bis 153, Georg Thieme Verlag, Stuttgart 1977). The effect of the substances in question is not always satisfactory at low application rates.
Es wurde nun gefunden, dass Verbindungen der Formel (I)It has now been found that compounds of the formula (I)
in welcher in which
X für Halogen, Alkyl, Alkoxy, Halogenalkyl, Halogenalkoxy oder Cyano steht,X represents halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano,
W, Y und Z unabhängig voneinander für Wasserstoff, Halogen, Alkyl, Alkoxy, Halogenalkyl, Halogenalkoxy oder Cyano stehen,W, Y and Z independently of one another represent hydrogen, halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano,
A für Wasserstoff, jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Alkoxyalkyl, gesättigtes, gegebenenfalls substituiertes Cycloalkyl steht, in welchem gegebenenfalls mindestens ein Ringatom durch ein Heteroatom ersetzt ist,A represents hydrogen, in each case optionally substituted by halogen, alkyl, alkoxyalkyl, saturated, optionally substituted cycloalkyl, in which at least one ring atom is optionally replaced by a heteroatom,
B für Wasserstoff oder Alkyl steht,B represents hydrogen or alkyl,
A und B gemeinsam mit dem Kohlenstoffatom an das sie gebunden sind, für einen gesättigten oder ungesättigten, gegebenenfalls mindestens ein Heteroatom enthaltenden unsubstituierten oder substituierten Cyclus stehen,A and B together with the carbon atom to which they are attached represent a saturated or unsaturated, optionally containing at least one heteroatom unsubstituted or substituted cycle,
D für Wasserstoff oder einen gegebenenfalls substituierten Rest aus der ReiheD represents hydrogen or an optionally substituted radical from the series
Alkyl, Alkenyl, Alkoxyalkyl, gesättigtes Cycloalkyl steht, in welchem gegebenenfalls eines oder mehrere Ringglieder durch Heteroatome ersetzt sind, A und D gemeinsam mit den Atomen an die sie gebunden sind für einen gesättigten oder ungesättigten und gegebenenfalls mindestens ein Heteroatom enthaltenden, im A,D-Teil unsubstituierten oder substituierten Cyclus stehen,Alkyl, alkenyl, alkoxyalkyl, saturated cycloalkyl, in which one or more ring members are optionally replaced by heteroatoms, A and D together with the atoms to which they are attached represent a saturated or unsaturated and optionally at least one heteroatom-containing cycle which is unsubstituted or substituted in the A, D part,
G für Wasserstoff (a) oder für eine der GruppenG for hydrogen (a) or for one of the groups
steht, stands,
worinwherein
E für ein Metallion oder ein Ammoniumion steht,E represents a metal ion or an ammonium ion,
L für Sauerstoff oder Schwefel steht,L represents oxygen or sulfur,
M für Sauerstoff oder Schwefel steht,M represents oxygen or sulfur,
R* für jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Alkenyl, Alkoxyalkyl, Alkylthioalkyl, Polyalkoxyalkyl oder gegebenen- falls durch Halogen, Alkyl oder Alkoxy substituiertes Cycloalkyl, das durch mindestens ein Heteroatom unterbrochen sein kann, jeweils gegebenenfalls substituiertes Phenyl, Phenylalkyl, Hetaryl, Phenoxyal- kyl oder Hetaryloxyalkyl steht,R * for each optionally substituted by halogen substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or optionally substituted by halogen, alkyl or alkoxy cycloalkyl, which can be interrupted by at least one heteroatom, each optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyal- kyl or hetaryloxyalkyl,
R^ für jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Alkenyl, Alkoxyalkyl, Polyalkoxyalkyl oder für jeweils gegebenenfalls substituiertes Cycloalkyl, Phenyl oder Benzyl steht, R3 für gegebenenfalls durch Halogen substituiertes Alkyl oder gegebenenfalls substituiertes Phenyl steht,R ^ represents alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl, optionally substituted by halogen, or cycloalkyl, phenyl or benzyl, optionally substituted, R 3 represents alkyl which is optionally substituted by halogen or phenyl which is optionally substituted,
R4 und R unabhängig voneinander für jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Alkoxy, Alkylamino, Dialkylamino, Alkylthio, Alkenylthio, Cycloalkylthio oder für jeweils gegebenenfalls substituiertes Phenyl, Benzyl, Phenoxy oder Phenylthio stehen undR4 and R independently of one another each represent optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio or represent optionally substituted phenyl, benzyl, phenoxy or phenylthio and
R6 und R unabhängig voneinander für Wasserstoff, jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Cycloalkyl, Alkenyl, Alkoxy, Alkoxyalkyl, für gegebenenfalls substituiertes Phenyl, für gegebenenfalls substituiertes Benzyl oder gemeinsam mit dem N-Atom, an das sie gebunden sind, für einen gegebenenfalls durch Sauerstoff oder Schwefel unterbrochenen gegebenenfalls substituierten Ring stehen undR6 and R independently of one another for hydrogen, in each case optionally substituted by halogen, alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, for optionally substituted phenyl, for optionally substituted benzyl or together with the N atom to which they are attached, for one optionally by Oxygen or sulfur interrupted optionally substituted ring and
(A) Azolen,(A) azoles,
bevorzugtprefers
(Fluquinconazol) bekannt aus EP-A-183 458(Fluquinconazole) known from EP-A-183 458
und/oder and or
(Tebuconazol) bekannt aus EP-A-040 345(Tebuconazole) known from EP-A-040 345
und/oderand or
(Bitertanol) bekannt aus DE-A-2 324010(Bitertanol) known from DE-A-2 324010
und/oderand or
(Triadimenol) bekannt aus DE-A-2 324010(Triadimenol) known from DE-A-2 324010
und/oder and or
(Triadimefon) bekannt aus DE-A-2 201 063(Triadimefon) known from DE-A-2 201 063
und/oderand or
(Difenoconazol) bekannt aus EP-A-112 284(Difenoconazole) known from EP-A-112 284
und/oderand or
(Flusilazol) bekannt aus EP-A-068 813(Flusilazole) known from EP-A-068 813
und/oder and or
(Prochloraz) bekannt aus DE-A-2429 523(Prochloraz) known from DE-A-2429 523
und/oderand or
(Penconazol) bekannt aus DE-A-2735872(Penconazole) known from DE-A-2735872
und/oderand or
2-(l-Chlor-cyclopropyl)-l-(2-chlorphenyl)-3-(5-mercapto-l,2,4-tri- azol- 1 -yl)-propan-2-ol bekannt aus EP-A-793 6572- (l-chloro-cyclopropyl) -l- (2-chlorophenyl) -3- (5-mercapto-l, 2,4-tri-azol-1-yl) -propan-2-ol known from EP-A -793 657
und/oder (B) Methoxyacrylaten (Strobinen)and or (B) methoxyacrylates (strobines)
bevorzugtprefers
(Kresoxim-methyl) bekannt aus EP-A-253 213(Kresoxim-methyl) known from EP-A-253 213
und/oderand or
(Azoxystrobin) bekannt aus EP-A-382 375(Azoxystrobin) known from EP-A-382 375
und/oderand or
(Trifloxystrobin) bekannt aus EP-A-460575 und/oder(Trifloxystrobin) known from EP-A-460575 and or
(Picoxystrobin) bekannt aus EP-A-278 595(Picoxystrobin) known from EP-A-278 595
und/oderand or
3-{l-[4-(2-Chlorphenoxy)-5-fluorpyrimid-6-yloxy-phenyl]-l-methoximino- methyl} -5,6-dihydro- 1 ,4,2-dioxazin3- {l- [4- (2-Chlorophenoxy) -5-fluoropyrimid-6-yloxyphenyl] -1-methoximino-methyl} -5,6-dihydro-1,4,2-dioxazine
bekannt aus EP-A-882 043known from EP-A-882 043
und/oderand or
BAS 500F bekannt aus BCPC-Conf.-Pests Diss (2000) (Vol.) 2, 541-548 und/oderBAS 500F known from BCPC-Conf.-Pests Diss (2000) (Vol.) 2, 541-548 and or
(C) Dithiocarbamaten,(C) dithiocarbamates,
bevorzugt U \preferably U \
(16) Mn(16) Mn
\ /\ /
H : H :
(Maneb) bekannt aus US 2,504,404(Maneb) known from US 2,504,404
und/oderand or
(Propineb) bekannt aus BE-A-611 960(Propineb) known from BE-A-611 960
und/oderand or
(18) [-SCS HCH2CH2 HCSSMn-]x(Zn) 'y(18) [-SCS HCH 2 CH 2 HCSSMn-] x (Zn) 'y
(Mancozeb) bekannt aus DE-A-1 234704(Mancozeb) known from DE-A-1 234704
und/oderand or
(D) Halogenalkylsulfenamiden und -imiden, bevorzugt(D) haloalkylsulfenamides and imides, prefers
(Captan) bekannt aus US 2,553,770(Captan) known from US 2,553,770
und/oderand or
Folpet (Phaltan) bekannt aus US 2,533,770Folpet (Phaltan) is known from US 2,533,770
und/oderand or
(Dichlofluanid) bekannt aus DE-A-1 193 498 (Dichlofluanid) known from DE-A-1 193 498
und/oder and or
(Tolylfluanid) bekannt aus DE-A-1 193 498(Tolylfluanid) known from DE-A-1 193 498
und/oderand or
(E) N-Phenylaminoheterocyclen,(E) N-phenylamino heterocycles,
(Famoxadon) bekannt aus EP-A-393 911(Famoxadone) known from EP-A-393 911
und/oderand or
(Fenamidon) bekannt aus EP-A-629616 und/oder(Fenamidon) known from EP-A-629616 and or
(F) Phenethylamiden,(F) phenethylamides,
bevorzugtprefers
(Carpropamid) bekannt aus EP-A-341 475(Carpropamide) known from EP-A-341 475
und/oderand or
(Iprovalicarb) bekannt aus DE-A-4 026 966(Iprovalicarb) known from DE-A-4 026 966
und/oder N-3,5-dichlθφhenylheterocyclen,and or N-3,5-dichlθφhenylheterocyclen,
bevorzugtprefers
(Procymidon) bekannt aus DE-A-2 012 656(Procymidone) known from DE-A-2 012 656
und/oderand or
Vinclozolin (Ronilan) bekannt aus DE-A-2207576Vinclozolin (Ronilan) known from DE-A-2207576
und/oderand or
Iprodion (Rovral) bekannt aus DE-A-2 149 923Iprodion (Rovral) known from DE-A-2 149 923
und/oder (H) Pyrimidinen,and or (H) pyrimidines,
(Cyprodinil) bekannt aus EP-A-310 550(Cyprodinil) known from EP-A-310 550
und/oderand or
(Pyrimethanil) bekannt aus DD-A-151 404(Pyrimethanil) known from DD-A-151 404
und/oderand or
(Mepanipyrim) bekannt aus EP-A-270 111 und/oder(Mepanipyrim) known from EP-A-270 111 and or
(I) Sulfonamiden,(I) sulfonamides,
bevorzugtprefers
(Cyamidazosulfamid) bekannt aus EP-A-298 196(Cyamidazosulfamide) known from EP-A-298 196
und/oderand or
(l-(3,5-Dimethylisoxazol-4-sulfonyl)-2-chlor-6,6-difluor-[l,3]-di- oxolo-[4,5]-benzimidazol) bekannt aus EP-A-844998(1- (3,5-Dimethylisoxazole-4-sulfonyl) -2-chloro-6,6-difluoro- [1,3] dioxolo- [4,5] benzimidazole) known from EP-A-844998
und/oderand or
(J) weiteren Verbindungen, wie (J) other connections, such as
(Spiroxamin) bekannt aus DE-A-3 735 555(Spiroxamine) known from DE-A-3 735 555
und/oderand or
(Chlorothalonil) bekannt aus US 3,290,353(Chlorothalonil) known from US 3,290,353
und/oderand or
(Iminoctadin-triacetat) bekannt aus EP-A-155 509(Iminoctadine triacetate) known from EP-A-155 509
und/oder and or
(Fludioxonil) bekannt aus EP-A-206 999(Fludioxonil) known from EP-A-206 999
und oderand or
Acibenzolar-S-methyl (Bion) bekannt aus EP-A-313 512Acibenzolar-S-methyl (Bion) known from EP-A-313 512
und/oderand or
(Dimethomoφh) bekannt aus EP-A-219 756(Dimethomoφh) known from EP-A-219 756
und/oder and or
(Cymoxanil) bekannt aus DE-A-2 312 956(Cymoxanil) known from DE-A-2 312 956
und/oderand or
(Fosetyl-Al) bekannt aus DE-A-2 456 627(Fosetyl-Al) known from DE-A-2 456 627
und/oderand or
(Pencycuron) bekannt aus DE-A-2 732257(Pencycuron) known from DE-A-2 732257
und/oderand or
(Fenhexamid) bekannt aus EP-A-339418 und/oder(Fenhexamide) known from EP-A-339418 and or
(Zoxamid) bekannt aus EP-A-604 019(Zoxamide) known from EP-A-604 019
und/oderand or
(Carbendazim) bekannt aus US 3,010,968(Carbendazim) known from US 3,010,968
(Rabeid) bekannt aus JP 5 755 844(Rabeid) known from JP 5 755 844
und/oder and or
(Coratop) bekannt aus US 3,917,838(Coratop) known from US 3,917,838
und/oderand or
Chinomethionat (Morestan) bekannt aus DE-A-1 100 372Quinomethionate (Morestan) known from DE-A-1 100 372
und/oderand or
(Fluazinam) bekannt aus EP-A-031 257(Fluazinam) known from EP-A-031 257
und/oderand or
(Metalaxyl-M) bekannt aus WO 96/01559(Metalaxyl-M) known from WO 96/01559
und/oder and or
(Metalaxyl) bekannt aus DE-A-2 515 091(Metalaxyl) known from DE-A-2 515 091
und/oderand or
(53) Schwefel(53) sulfur
und/oderand or
(54) Kupfer(54) copper
und/oderand or
SYP-L 190 bekannt aus BCPC-Conf.-Pests Dis. (2000); Vol. 2), 549-556SYP-L 190 known from BCPC-Conf.-Pests Dis. (2000); Vol. 2), 549-556
sehr gute fungizide, insektizide und akarizide Eigenschaften besitzen. Überraschenderweise ist die Insektizide, fungizide und akarizide Wirkung der erfindungsgemäßen Wirkstoffkombination wesentlich höher als die Summe der Wirkungen der einzelnen Wirkstoffe. Es liegt ein nicht vorhersehbarer echter synergistischer Effekt vor und nicht nur eine Wirkungsergänzung.have very good fungicidal, insecticidal and acaricidal properties. Surprisingly, the insecticidal, fungicidal and acaricidal activity of the active compound combination according to the invention is considerably higher than the sum of the effects of the individual active compounds. There is an unforeseeable real synergistic effect and not just an addition.
Die erfindungsgemäßen Wirkstoffkombinationen enthalten neben mindestens einem Wirkstoff der Formel (I) mindestens einen Wirkstoff der Verbindungen 1 bis 55.The active substance combinations according to the invention contain, in addition to at least one active substance of the formula (I), at least one active substance of the compounds 1 to 55.
Bevorzugt sind Wirkstoffkombinationen enthaltend Verbindungen der Formel (I), in welcher die Reste die folgende Bedeutung haben:Active substance combinations containing compounds of the formula (I) in which the radicals have the following meaning are preferred:
W steht bevorzugt für Wasserstoff, Cj-C^Alkyl, Cι-C4-Alkoxy, Chlor, Brom oder Fluor,W preferably represents hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, chlorine, bromine or fluorine,
X steht bevorzugt für Cι-C4-Alkyl, Cj-C4-Alkoxy, Cj-C4-Halogenalkyl,X preferably represents C 1 -C 4 alkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkyl,
Fluor, Chlor oder Brom,Fluorine, chlorine or bromine,
Y und Z stehen unabhängig voneinander bevorzugt für Wasserstoff, C1-C4- Alkyl, Halogen, C 1 -C4- Alkoxy oder C -C4-Halogenalkyl,Y and Z independently of one another preferably represent hydrogen, C1-C4-alkyl, halogen, C 1 -C4-alkoxy or C -C4-haloalkyl,
A steht bevorzugt für Wasserstoff oder jeweils gegebenenfalls durch Halogen substituiertes C Cβ- Alkyl oder C3-Cg-Cycloalkyl,A preferably represents hydrogen or in each case optionally substituted by halogen C Cβ-alkyl or C3-Cg-cycloalkyl,
B steht bevorzugt für Wasserstoff, Methyl oder Ethyl,B preferably represents hydrogen, methyl or ethyl,
A, B und das Kohlenstoffatom an das sie gebunden sind, stehen bevorzugt für gesättigtes C3-C6-Cycloalkyl, worin gegebenenfalls ein Ringglied durch Sauerstoff oder Schwefel ersetzt ist und welches gegebenenfalls einfach oder zwei- fach durch C1-C4-Alkyl, Trifluormethyl oder C1-C4- Alkoxy substituiert ist, D steht bevorzugt für Wasserstoff, jeweils gegebenenfalls durch Fluor oder Chlor substituiertes -C6- Alkyl, C3-C4-Alkenyl oder C3-C6-Cycloalkyl,A, B and the carbon atom to which they are attached preferably represent saturated C3-C6 cycloalkyl in which optionally one ring member is replaced by oxygen or sulfur and which is optionally substituted one or two times by C 1 -C 4 alkyl, Trifluoromethyl or C 1 -C 4 alkoxy is substituted, D preferably represents hydrogen, in each case optionally substituted by fluorine or chlorine, -C 6 -alkyl, C 3 -C 4 -alkenyl or C 3 -C 6 -cycloalkyl,
A und D stehen gemeinsam bevorzugt für gegebenenfalls durch Methyl substituiertes C3-C4-Alkandiyl, worin gegebenenfalls eine Methylengruppe durch Schwefel ersetzt ist,A and D together preferably represent C 3 -C 4 -alkanediyl which is optionally substituted by methyl, in which a methylene group is optionally replaced by sulfur,
G steht bevorzugt für Wasserstoff (a) oder für eine der GruppenG preferably represents hydrogen (a) or one of the groups
in welchen in which
E für ein Metallion oder ein Ammoniumion steht,E represents a metal ion or an ammonium ion,
L für Sauerstoff oder Schwefel steht undL represents oxygen or sulfur and
M für Sauerstoff oder Schwefel steht,M represents oxygen or sulfur,
R1 steht bevorzugt für jeweils gegebenenfalls durch Halogen substituiertes Cι-Cιo-Al yl, C2-C10-Alkenyl, C1-C4-Alkoxy-C1-C4-alkyl, C1-C4-Alkylthio-R 1 preferably represents in each case optionally substituted by halogen -CC-alyl, C 2 -C 10 -alkenyl, C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl, C 1 -C 4 -alkylthio-
CrC4-alkyl oder gegebenenfalls durch Fluor, Chlor, C1-C4-Alkyl oder CrC2- Alkoxy substituiertes C3-C6-Cycloalkyl,-C 4 -alkyl or optionally substituted by fluorine, chlorine, C 1 -C 4 alkyl or -C 2 - alkoxy-substituted C 3 -C 6 cycloalkyl,
für gegebenenfalls durch Fluor, Chlor, Brom, Cyano, Nitro, Cι-C4-Alkyl, CrCzt-Alkoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl, für jeweils gegebenenfalls durch Chlor oder Methyl substituiertes Pyridyl oder Thienyl,for phenyl optionally substituted by fluorine, chlorine, bromine, cyano, nitro, C 1 -C 4 -alkyl, CrCzt-alkoxy, trifluoromethyl or trifluoromethoxy, for pyridyl or thienyl optionally substituted by chlorine or methyl,
R2 steht bevorzugt für jeweils gegebenenfalls durch Fluor oder Chlor substitu- iertes d-do-Alkyl, C2-do-Alkenyl, C1-C4-Alkoxy-C2-C4-alkyl,R 2 preferably represents d-do-alkyl, C 2 -do-alkenyl, C 1 -C 4 -alkoxy-C 2 -C 4 -alkyl, each optionally substituted by fluorine or chlorine,
für gegebenenfalls durch Methyl oder Methoxy substituiertes C5-C6-Cyclo- alkyl oderfor C 5 -C 6 cycloalkyl optionally substituted by methyl or methoxy or
für jeweils gegebenenfalls durch Fluor, Chlor, Brom, Cyano, Nitro, d-C4-for each optionally by fluorine, chlorine, bromine, cyano, nitro, dC 4 -
Alkyl, CrC4-Alkoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl oder Benzyl,Alkyl, CrC 4 alkoxy, trifluoromethyl or trifluoromethoxy substituted phenyl or benzyl,
R3 steht bevorzugt für gegebenenfalls durch Fluor substituiertes Q-C4- Alkyl oder für gegebenenfalls durch Fluor, Chlor, Brom, Ci-C4-Alkyl, C1-C4-AI- koxy, Trifluormethyl, Trifluormethoxy, Cyano oder Nitro substituiertes Phenyl,R 3 preferably represents optionally substituted by fluorine QC 4 - alkyl or optionally substituted by fluorine, chlorine, bromine, Ci-C 4 alkyl, C 1 -C 4 -alkoxy -AI-, trifluoromethyl, trifluoromethoxy, cyano or nitro,
R4 steht bevorzugt für jeweils gegebenenfalls durch Fluor oder Chlor substitu- iertes Cϊ-C4-Alkyl, C1-C4-Alkoxy, C1-C -Alkylamino, C1-C4-Alkylthio oder für jeweils gegebenenfalls durch Fluor, Chlor, Brom, Nitro, Cyano, d-C4-R 4 preferably represents in each case optionally fluorine or chlorine substitution iertes by C ϊ -C 4 alkyl, C 1 -C 4 alkoxy, C 1 -C alkylamino, C 1 -C 4 -alkylthio or represents in each case optionally fluorine- , Chlorine, bromine, nitro, cyano, dC 4 -
Alkoxy, Trifluormethoxy, Cι-C4-Alkylthio, C1-C4-Halogenalkylthio, d-C4-Alkoxy, trifluoromethoxy, Cι-C 4 alkylthio, C 1 -C 4 haloalkylthio, dC 4 -
Alkyl oder Trifluormethyl substituiertes Phenyl, Phenoxy oder Phenylthio,Alkyl or trifluoromethyl substituted phenyl, phenoxy or phenylthio,
R5 steht bevorzugt für d-C4-Alkoxy oder d-C4-Thioalkyl,R 5 preferably represents dC 4 alkoxy or dC 4 thioalkyl,
R6 steht bevorzugt für d-C6-Alkyl, C3-C6-Cycloalkyl, d-C6-Alkoxy, C3-G6- Alkenyl, d-C4-Alkoxy-Cι-C4-alkyl,R 6 preferably represents dC 6 alkyl, C 3 -C 6 cycloalkyl, dC 6 alkoxy, C 3 -G 6 alkenyl, dC 4 alkoxy -CC 4 -alkyl,
R7 steht bevorzugt für d-C6-Alkyl, C3-C6-Alkenyl oder d-C4-Alkoxy-d-C4- alkyl, R6 und R7 stehen zusammen bevorzugt für einen gegebenenfalls durch Methyl oder Ethyl substituierten C3-C6-Alkylenrest, in welchem gegebenenfalls ein Kohlenstoffatom durch Sauerstoff oder Schwefel ersetzt ist,R 7 preferably represents dC 6 -alkyl, C 3 -C 6 -alkenyl or dC 4 -alkoxy-dC 4 -alkyl, R 6 and R 7 together preferably represent a C 3 -C 6 -alkylene radical which is optionally substituted by methyl or ethyl and in which a carbon atom is optionally replaced by oxygen or sulfur,
W steht besonders bevorzugt für Wasserstoff, Methyl, Ethyl, Chlor, Brom oder Methoxy,W particularly preferably represents hydrogen, methyl, ethyl, chlorine, bromine or methoxy,
X steht besonders bevorzugt für Chlor, Brom, Methyl, Ethyl, Propyl, i-Propyl, Methoxy, Ethoxy oder Trifluormethyl,X particularly preferably represents chlorine, bromine, methyl, ethyl, propyl, i-propyl, methoxy, ethoxy or trifluoromethyl,
Y und Z stehen besonders bevorzugt unabhängig voneinander für Wasserstoff, Fluor, Chlor, Brom, Methyl, Ethyl, Propyl, i-Propyl, Trifluormethyl oder Methoxy,Y and Z are particularly preferably independently of one another hydrogen, fluorine, chlorine, bromine, methyl, ethyl, propyl, i-propyl, trifluoromethyl or methoxy,
A steht besonders bevorzugt für Methyl, Ethyl, Propyl, i-Propyl, Butyl, i-Butyl, sec.-Butyl, tert.-Butyl, Cyclopropyl, Cyclopentyl oder Cyclohexyl,A particularly preferably represents methyl, ethyl, propyl, i-propyl, butyl, i-butyl, sec-butyl, tert-butyl, cyclopropyl, cyclopentyl or cyclohexyl,
B steht besonders bevorzugt für Wasserstoff, Methyl oder Ethyl,B particularly preferably represents hydrogen, methyl or ethyl,
A, B und das Kohlenstoffatom an das sie gebunden sind, stehen besonders bevorzugt für gesättigtes C6-Cycloalkyl, worin gegebenenfalls ein Ringglied durch Sauerstoff ersetzt ist und welches gegebenenfalls einfach durch Methyl, Ethyl, Methoxy, Ethoxy, Propoxy oder Butoxy substituiert ist,A, B and the carbon atom to which they are attached are particularly preferably saturated C 6 -cycloalkyl, in which a ring member is optionally replaced by oxygen and which is optionally simply substituted by methyl, ethyl, methoxy, ethoxy, propoxy or butoxy,
D steht besonders bevorzugt für Wasserstoff, für Methyl, Ethyl, Propyl, i-Propyl, Butyl, i-Butyl, Allyl, Cyclopropyl, Cyclopentyl oder Cyclohexyl,D particularly preferably represents hydrogen, represents methyl, ethyl, propyl, i-propyl, butyl, i-butyl, allyl, cyclopropyl, cyclopentyl or cyclohexyl,
A und D stehen gemeinsam besonders bevorzugt für gegebenenfalls durch Methyl substituiertes C3-C4-Alkandiyl,A and D together particularly preferably represent C 3 -C 4 -alkanediyl which is optionally substituted by methyl,
G steht besonders bevorzugt für Wasserstoff (a) oder für eine der Gruppen G particularly preferably represents hydrogen (a) or one of the groups
in welchenin which
M für Sauerstoff oder Schwefel steht,M represents oxygen or sulfur,
R1 steht besonders bevorzugt für d-Cs-Alkyl, C2-C4-Alkenyl, Methoxymethyl, Ethoxymethyl, Ethylthiomethyl, Cyclopropyl, Cyclopentyl oder Cyclohexyl,R 1 particularly preferably represents d-Cs-alkyl, C 2 -C 4 -alkenyl, methoxymethyl, ethoxymethyl, ethylthiomethyl, cyclopropyl, cyclopentyl or cyclohexyl,
für gegebenenfalls durch Fluor, Chlor, Brom, Cyano, Nitro, Methyl, Ethyl, Methoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl,for phenyl optionally substituted by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, methoxy, trifluoromethyl or trifluoromethoxy,
für jeweils gegebenenfalls durch Chlor oder Methyl substituiertes Pyridyl oder Thienyl,for pyridyl or thienyl optionally substituted by chlorine or methyl,
R2 steht besonders bevorzugt für CrC8-Alkyl, C2-C4-Alkenyl, Methoxyethyl, Ethoxyethyl oder für Phenyl oder Benzyl,R 2 particularly preferably represents CrC 8 alkyl, C 2 -C 4 alkenyl, methoxyethyl, ethoxyethyl or phenyl or benzyl,
R6 und R7 stehen unabhängig voneinander besonders bevorzugt für Methyl, Ethyl oder zusammen für einen Cs-Alkylenrest, in welchem die C3-Methylengruppe durch Sauerstoff ersetzt ist.R 6 and R 7 independently of one another particularly preferably represent methyl, ethyl or together a Cs-alkylene radical in which the C 3 -methylene group is replaced by oxygen.
W steht ganz besonders bevorzugt für Wasserstoff oder Methyl,W very particularly preferably represents hydrogen or methyl,
X steht ganz besonders bevorzugt für Chlor, Brom oder Methyl,X very particularly preferably represents chlorine, bromine or methyl,
Y und Z stehen ganz besonders bevorzugt unabhängig voneinander für Wasserstoff, Chlor, Brom oder Methyl, A, B und das Kohlenstoffatom an das sie gebunden sind, stehen ganz besonders bevorzugt für gesättigtes C6-Cycloalkyl, in welchem gegebenenfalls ein Ringglied durch Sauerstoff ersetzt ist und welches gegebenenfalls einfach durch Methyl, Methoxy, Ethoxy, Propoxy oder Butoxy substituiert ist,Y and Z very particularly preferably independently of one another represent hydrogen, chlorine, bromine or methyl, A, B and the carbon atom to which they are attached very particularly preferably represent saturated C 6 -cycloalkyl, in which one ring member is optionally replaced by oxygen and which is optionally simply substituted by methyl, methoxy, ethoxy, propoxy or butoxy,
D steht ganz besonders bevorzugt für Wasserstoff,D very particularly preferably represents hydrogen,
G steht ganz besonders bevorzugt für Wasserstoff (a) oder für eine der GruppenG very particularly preferably represents hydrogen (a) or one of the groups
in welchenin which
M für Sauerstoff oder Schwefel steht,M represents oxygen or sulfur,
R1 steht ganz besonders bevorzugt für Cj-C8-Alkyl, C2-C4-Alkenyl, Methoxy- methyl, Ethoxymethyl, Ethylmethylthio, Cyclopropyl, Cyclopentyl, Cyclohexyl oderR 1 very particularly preferably represents C 1 -C 8 -alkyl, C 2 -C 4 -alkenyl, methoxymethyl, ethoxymethyl, ethylmethylthio, cyclopropyl, cyclopentyl, cyclohexyl or
für gegebenenfalls durch Fluor, Chlor, Brom, Methyl, Methoxy, Trifluormethyl, Trifluormethoxy, Cyano oder Nitro substituiertes Phenyl,for phenyl optionally substituted by fluorine, chlorine, bromine, methyl, methoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro,
für jeweils gegebenenfalls durch Chlor oder Methyl substituiertes Pyridyl oder Thienyl,for pyridyl or thienyl optionally substituted by chlorine or methyl,
R2 steht ganz besonders bevorzugt für Ci-Cg-Alkyl, C2-C4-Alkenyl, Methoxy- ethyl, Ethoxyethyl, Phenyl oder Benzyl, R6 und R7 stehen unabhängig voneinander ganz besonders bevorzugt für Methyl, Ethyl oder zusammen für einen Cs-Alkylenrest, in welchen die C3-Methylen- gruppe durch Sauerstoff ersetzt ist.R 2 very particularly preferably represents C 1 -C 6 -alkyl, C 2 -C 4 -alkenyl, methoxyethyl, ethoxyethyl, phenyl or benzyl, R 6 and R 7 independently of one another very particularly preferably represent methyl, ethyl or together a Cs-alkylene radical in which the C 3 -methylene group is replaced by oxygen.
Insbesondere bevorzugt sind Wirkstoffkombinationen enthaltend Verbindungen der Formel (I)Active substance combinations containing compounds of the formula (I) are particularly preferred
und mindestens einen Wirkstoff der Verbindungen 1 bis 55.and at least one active ingredient of compounds 1 to 55.
Die Wirkstoffkombinationen können darüber hinaus auch weitere fungizid, akarizid oder insektizid wirksame Zumischkomponenten enthalten.The active substance combinations can also contain other fungicidal, acaricidal or insecticidal active components.
Wenn die Wirkstoffe in den erfindungsgemäßen Wirkstoffkombinationen in bestimmten Gewichtsverhältnissen vorhanden sind, zeigt sich der synergistische Effekt besonders deutlich. Jedoch können die Gewichtsverhältnisse der Wirkstoffe in den Wirkstoffkombinationen in einem relativ großen Bereich variiert werden. Im allgemeinen enthalten die erfindungsgemäßen Kombinationen Wirkstoffe der Formel (I) und den Mischpartner in den in der nachfolgenden Tabelle angegeben bevorzugten und besonders bevorzugten Mischungsverhältnissen:If the active compounds are present in the active compound combinations according to the invention in certain weight ratios, the synergistic effect is particularly evident. However, the weight ratios of the active ingredients in the active ingredient combinations can be varied within a relatively wide range. In general, the combinations according to the invention contain active compounds of the formula (I) and the mixing partner in the preferred and particularly preferred mixing ratios given in the table below:
die Mischungsverhältnisse basieren auf Gewichtsverhältnissen. Das Verhältnis ist zu verstehen als Wirkstoff der Formel (ι):Mischpartnerthe mixing ratios are based on weight ratios. The ratio is to be understood as an active ingredient of the formula (ι): mixing partner
Die erfindungsgemäßen Wirkstoffkombinationen weisen eine starke mikrobizide Wirkung auf und können zur Bekämpfung von unerwünschten Mikroorganismen, wie Fungi und Bakterien, im Pflanzenschutz und im Materialschutz eingesetzt werden. Fungizide lassen sich im Pflanzenschutz zur Bekämpfung von Plasmodiophoro- mycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes und Deuteromycetes einsetzen.The active compound combinations according to the invention have a strong microbicidal action and can be used to control unwanted microorganisms, such as fungi and bacteria, in crop protection and in material protection. Fungicides can be used in crop protection to combat Plasmodiophoromyces, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.
Bakterizide lassen sich im Pflanzenschutz zur Bekämpf ng von Pseudomonadaceae,Bactericides can be used in crop protection to control Pseudomonadaceae,
Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae und Streptomycetaceae einsetzen.Use Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.
Beispielhaft aber nicht begrenzend seien einige Erreger von pilzlichen und bakteriel- len Erkrankungen, die unter die oben aufgezählten Oberbegriffe fallen, genannt:Some pathogens of fungal and bacterial diseases that fall under the generic names listed above may be mentioned as examples, but not by way of limitation:
Xanthomonas- Arten, wie beispielsweise Xanthomonas campestris pv. oryzae;Xanthomonas species, such as, for example, Xanthomonas campestris pv. Oryzae;
Pseudomonas- Arten, wie beispielsweise Pseudomonas syringae pv. lachrymans;Pseudomonas species, such as, for example, Pseudomonas syringae pv. Lachrymans;
Erwinia- Arten, wie beispielsweise Erwinia amylovora; Pythium- Arten, wie beispielsweise Pythium ultimum;Erwinia species, such as, for example, Erwinia amylovora; Pythium species, such as, for example, Pythium ultimum;
Phytophthora- Arten, wie beispielsweise Phytophthora infestans;Phytophthora species, such as, for example, Phytophthora infestans;
Pseudoperonospora- Arten, wie beispielsweise Pseudoperonospora humuli oderPseudoperonospora species, such as, for example, Pseudoperonospora humuli or
Pseudoperonospora cubensis;Pseudoperonospora cubensis;
Plasmopara- Arten, wie beispielsweise Plasmopara viticola; Bremia- Arten, wie beispielsweise Bremia lactucae;Plasmopara species, such as, for example, Plasmopara viticola; Bremia species, such as, for example, Bremia lactucae;
Peronospora-Arten, wie beispielsweise Peronospora pisi oder P. brassicae;Peronospora species, such as, for example, Peronospora pisi or P. brassicae;
Erysiphe- Arten, wie beispielsweise Erysiphe graminis;Erysiphe species, such as, for example, Erysiphe graminis;
Sphaerotheca- Arten, wie beispielsweise Sphaerotheca füliginea;Sphaerotheca species, such as, for example, Sphaerotheca Fülliginea;
Podosphaera- Arten, wie beispielsweise Podosphaera leucotricha; Venturia- Arten, wie beispielsweise Venturia inaequalis;Podosphaera species, such as, for example, Podosphaera leucotricha; Venturia species, such as, for example, Venturia inaequalis;
Pyrenophora- Arten, wie beispielsweise Pyrenophora teres oder P. gramineaPyrenophora species, such as, for example, Pyrenophora teres or P. graminea
(Konidienform: Drechslera, Syn: Helminthosporium);(Conidial form: Drechslera, Syn: Helminthosporium);
Cochliobolus-Arten, wie beispielsweise Cochliobolus sativusCochliobolus species, such as, for example, Cochliobolus sativus
(Konidienform: Drechslera, Syn: Helminthosporium); Uromyces-Arten, wie beispielsweise Uromyces appendiculatus;(Conidial form: Drechslera, Syn: Helminthosporium); Uromyces species, such as, for example, Uromyces appendiculatus;
Puccinia-Arten, wie beispielsweise Puccinia recondita; Sclerotinia- Arten, wie beispielsweise Sclerotinia sclerotiorum; Tilletia-Arten, wie beispielsweise Tilletia caries; Ustilago-Arten, wie beispielsweise Ustilago nuda oder Ustilago avenae; Pellicularia- Arten, wie beispielsweise Pellicularia sasakii; Pyricularia- Arten, wie beispielsweise Pyricularia oryzae;Puccinia species, such as, for example, Puccinia recondita; Sclerotinia species, such as, for example, Sclerotinia sclerotiorum; Tilletia species, such as, for example, Tilletia caries; Ustilago species, such as, for example, Ustilago nuda or Ustilago avenae; Pellicularia species, such as, for example, Pellicularia sasakii; Pyricularia species, such as, for example, Pyricularia oryzae;
Fusarium- Arten, wie beispielsweise Fusarium culmorum; Botrytis-Arten, wie beispielsweise Botrytis cinerea; Septoria- Arten, wie beispielsweise Septoria nodorum; Leptosphaeria- Arten, wie beispielsweise Leptosphaeria nodorum; Cercospora- Arten, wie beispielsweise Cercospora canescens;Fusarium species, such as, for example, Fusarium culmorum; Botrytis species, such as, for example, Botrytis cinerea; Septoria species, such as, for example, Septoria nodorum; Leptosphaeria species, such as, for example, Leptosphaeria nodorum; Cercospora species, such as, for example, Cercospora canescens;
Alternaria- Arten, wie beispielsweise Alternaria brassicae; Pseudocercosporella-Arten, wie beispielsweise Pseudocercosporella heφotrichoides.Alternaria species, such as, for example, Alternaria brassicae; Pseudocercosporella species, such as, for example, Pseudocercosporella heφotrichoides.
Die gute Pflanzenverträglichkeit der Wirkstoffkombinationen in den zur Bekämp- fung von Pflanzenkrankheiten notwendigen Konzentrationen erlaubt eine Behandlung von oberirdischen Pflanzenteilen, von Pflanz- und Saatgut, und des Bodens.The fact that the active ingredient combinations are well tolerated by plants at the concentrations required to combat plant diseases enables treatment of above-ground parts of plants, of propagation stock and seeds, and of the soil.
Die erfindungsgemäßen Wirkstoffkombinationen eignen sich auch zur Steigerung des Ernteertrages. Sie sind außerdem mindertoxisch und weisen eine gute Pflanzen- Verträglichkeit auf.The active compound combinations according to the invention are also suitable for increasing the crop yield. They are also less toxic and have good plant tolerance.
Im Materialschutz lassen sich die erfindungsgemäßen Wirkstoffkombinationen zum Schutz von technischen Materialien gegen Befall und Zerstörung durch unerwünschte Mikroorganismen einsetzen.In material protection, the active compound combinations according to the invention can be used to protect technical materials against attack and destruction by undesired microorganisms.
Unter technischen Materialien sind im vorliegenden Zusammenhang nichtlebende Materialien zu verstehen, die für die Verwendung in der Technik zubereitet worden sind. Beispielsweise können technische Materialien, die durch erfindungsgemäße Wirkstoffkombinationen vor mikrobieller Veränderung oder Zerstörung geschützt werden sollen, Klebstoffe, Leime, Papier und Karton, Textilien, Leder, Holz, Anstrichmittel und Kunststoffartikel, Kühlschmierstoffe und andere Materialien sein, die von Mikroorganismen befallen oder zersetzt werden können. Im Rahmen der zu schützenden Materialien seien auch Teile von Produktionsanlagen, beispielsweise Kühlwasserkreisläufe, genannt, die durch Vermehrung von Mikroorganismen beeinträchtigt werden können. Im Rahmen der vorliegenden Erfindung seien als tech- nische Materialien vorzugsweise Klebstoffe, Leime, Papiere und Kartone, Leder,In the present context, technical materials are to be understood as non-living materials that have been prepared for use in technology. For example, technical materials that are to be protected against microbial change or destruction by active substance combinations according to the invention can be adhesives, glues, paper and cardboard, textiles, leather, wood, paints and plastic articles, cooling lubricants and other materials. which can be attacked or decomposed by microorganisms. In the context of the materials to be protected, parts of production plants, for example cooling water circuits, are also mentioned which can be impaired by the multiplication of microorganisms. In the context of the present invention, technical materials are preferably adhesives, glues, papers and cartons, leather,
Holz, Anstrichmittel, Kühlschmiermittel und Wärmeübertragungsflüssigkeiten genannt, besonders bevorzugt Holz.Wood, paints, cooling lubricants and heat transfer liquids called, particularly preferably wood.
Als Mikroorganismen, die einen Abbau oder eine Veränderung der technischen Ma- terialien bewirken können, seien beispielsweise Bakterien, Pilze, Hefen, Algen undBacteria, fungi, yeasts, algae and, for example, are microorganisms which can break down or change the technical materials
Schleimorganismen genannt. Vorzugsweise wirken die erfindungsgemäßen Wirk- stoffkombinationen gegen Pilze, insbesondere Schimmelpilze, holzverfärbende und holzzerstörende Pilze (Basidiomyceten) sowie gegen Schleimorganismen und Algen.Called slime organisms. The active compound combinations according to the invention preferably act against fungi, in particular mold, wood-discoloring and wood-destroying fungi (Basidiomycetes) and against mucus organisms and algae.
Es seien beispielsweise Mikroorganismen der folgenden Gattungen genannt:For example, microorganisms of the following genera may be mentioned:
Alternaria, wie Alternaria tenuis,Alternaria, such as Alternaria tenuis,
Aspergillus, wie Aspergillus niger,Aspergillus, such as Aspergillus niger,
Chaetomium, wie Chaetomium globosum,Chaetomium, like Chaetomium globosum,
Coniophora, wie Coniophora puetana, Lentinus, wie Lentinus tigrinus,Coniophora, such as Coniophora puetana, Lentinus, such as Lentinus tigrinus,
Penicillium, wie Penicillium glaucum,Penicillium, such as Penicillium glaucum,
Polyporus, wie Polyporus versicolor,Polyporus, such as Polyporus versicolor,
Aureobasidium, wie Aureobasidium pullulans,Aureobasidium, such as Aureobasidium pullulans,
Sclerophoma, wie Sclerophoma pityophila, Trichoderma, wie Trichoderma viride,Sclerophoma, such as Sclerophoma pityophila, Trichoderma, such as Trichoderma viride,
Escherichia, wie Escherichia coli,Escherichia, such as Escherichia coli,
Pseudomonas, wie Pseudomonas aeruginosa,Pseudomonas, such as Pseudomonas aeruginosa,
Staphylococcus, wie Staphylococcus aureus.Staphylococcus, such as Staphylococcus aureus.
Die Wirkstoffkombinationen können in Abhängigkeit von ihren jeweiligen physikalischen und/oder chemischen Eigenschaften in die üblichen Formulierungen über- führt werden, wie Lösungen, Emulsionen, Suspensionen, Pulver, Schäume, Pasten, Granulate, Aerosole, Feinstverkapselungen in polymeren Stoffen und in Hüllmassen für Saatgut, sowie ULV-Kalt- und Warmnebel-Formulierungen.Depending on their respective physical and / or chemical properties, the active substance combinations can be converted into the customary formulations. such as solutions, emulsions, suspensions, powders, foams, pastes, granules, aerosols, very fine encapsulations in polymeric substances and in coating compositions for seeds, as well as ULV cold and warm mist formulations.
Diese Formulierungen werden in bekannter Weise hergestellt, z.B. durch Vermischen der Wirkstoffe mit Streckmitteln, also flüssigen Lösungsmitteln, unter Druck stehenden verflüssigten Gasen und/oder festen Trägerstoffen, gegebenenfalls unter Verwendung von oberflächenaktiven Mitteln, also Emulgiermitteln und/oder Dispergiermitteln und/oder schaumerzeugenden Mitteln. Im Falle der Benutzung von Wasser als Streckmittel können z.B. auch organische Lösungsmittel als Hilfslösungsmittel verwendet werden. Als flüssige Lösungsmittel kommen im wesentlichen in Frage: Aromaten, wie Xylol, Toluol oder Alkylnaphthalme, chlorierte Aromaten oder chlorierte aliphatische Kohlenwasserstoffe, wie Chlorbenzole, Chlorethylene oder Methylenchlorid, aliphatische Kohlenwasserstoffe, wie Cyclohexan oder Paraffine, z.B. Erdöl- fraktionen, Alkohole, wie Butanol oder Glycol sowie deren Ether und Ester, Ketone, wie Aceton, Methylethylketon, Methylisobutylketon oder Cyclohexanon, stark polare Lösungsmittel, wie Dimethylformamid und Dimethylsulfoxid, sowie Wasser. Mit verflüssigten gasförmigen Streckmitteln oder Trägerstoffen sind solche Flüssigkeiten gemeint, welche bei normaler Temperatur und unter Normaldruck gasformig sind, z.B. Aerosol-Treibgase, wie Halogenkohlenwasserstoffe sowie Butan, Propan, Stickstoff und Kohlendioxid. Als feste Trägerstoffe kommen in Frage: z.B. natürliche Gesteinsmehle, wie Kaoline, Tonerden, Talkum, Kreide, Quarz, Attapulgit, Montmo- rillonit oder Diatomeenerde und synthetische Gesteinsmehle, wie hochdisperse Kieselsäure, Aluminiumoxid und Silikate. Als feste Trägerstoffe für Granulate kommen in Frage: z.B. gebrochene und fraktionierte natürliche Gesteine wie Calcit, Marmor,These formulations are made in a known manner, e.g. by mixing the active ingredients with extenders, that is to say liquid solvents, pressurized liquefied gases and / or solid carriers, if appropriate using surface-active agents, that is to say emulsifiers and / or dispersants and / or foam-generating agents. If water is used as an extender, e.g. organic solvents can also be used as auxiliary solvents. The following are essentially suitable as liquid solvents: aromatics such as xylene, toluene or alkyl naphthalene, chlorinated aromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chlorethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, e.g. Petroleum fractions, alcohols, such as butanol or glycol, and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, highly polar solvents, such as dimethylformamide and dimethyl sulfoxide, and water. Liquefied gaseous extenders or carriers mean liquids which are gaseous at normal temperature and under normal pressure, e.g. Aerosol propellants such as halogenated hydrocarbons as well as butane, propane, nitrogen and carbon dioxide. Possible solid carriers are: e.g. natural rock meals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock meals, such as highly disperse silica, aluminum oxide and silicates. The following are suitable as solid carriers for granules: e.g. broken and fractionated natural rocks such as calcite, marble,
Bims, Sepiolith, Dolomit sowie synthetische Granulate aus anorganischen und organischen Mehlen sowie Granulate aus organischem Material wie Sägemehl, Kokosnußschalen, Maiskolben und Tabakstengel. Als Emulgier und/oder schaumerzeugende Mittel kommen in Frage: z.B. nichtionogene und anionische Emulgatoren, wie Polyoxyethylen-Fettsäureester, Polyoxyethylen-Fettalkoholether, z.B. Alkylarylpoly- glycolether, Alkylsulfonate, Alkylsulfate, Arylsulfonate sowie Eiweißhydrolysate. Als Dispergiermittel kommen in Frage: z.B. Lignin-Sulfitablaugen und Methylcel- lulose.Pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stalks. Suitable emulsifiers and / or foam-generating agents are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolyzates. Possible dispersants are: eg lignin sulfite waste liquor and methyl cellulose.
Es können in den Formulierungen Haftmittel wie Carboxymethylcellulose, natürliche und synthetische pulverige, körnige oder latexförmige Polymere verwendet werden, wie Gummi arabicum, Polyvinylalkohol, Polyvinylacetat, sowie natürliche Phospholi- pide, wie Kephaline und Lecithine, und synthetische Phospholipide. Weitere Additive können mineralische und vegetabile Öle sein.Adhesives such as carboxymethyl cellulose, natural and synthetic polymers in the form of powders, granules or latices, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and also natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids can be used in the formulations. Other additives can be mineral and vegetable oils.
Es können Farbstoffe wie anorganische Pigmente, z.B. Eisenoxid, Titanoxid, Ferro- cyanblau und organische Farbstoffe, wie Alizarin-, Azo- und Metallphthalocyanin- farbstoffe und Spurennährstoffe, wie Salze von Eisen, Mangan, Bor, Kupfer, Kobalt, Molybdän und Zink verwendet werden.Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.
Die Formulierungen enthalten im allgemeinen zwischen 0,1 und 95 GewichtsprozentThe formulations generally contain between 0.1 and 95 percent by weight
Wirkstoff, vorzugsweise zwischen 0,5 und 90 %.Active ingredient, preferably between 0.5 and 90%.
Die Wirkstoffkombinationen können als solche, in Form ihrer Formulierungen oder den daraus bereiteten Anwendungsformen, wie gebrauchsfertige Lösungen, Suspen- sionen, Spritzpulver, Pasten, lösliche Pulver, Stäubemittel und Granulate angewendet werden. Die Anwendung geschieht in üblicher Weise, z.B. durch Gießen, Verspritzen, Versprühen, Verstreuen, Verstäuben, Verschäumen, Bestreichen usw. Es ist ferner möglich, die Wirkstoffe nach dem Ultra-Low- Volume-Verfahren auszubringen oder die Wirkstoffzubereitung oder den Wirkstoff selbst in den Boden zu injizieren. Es kann auch das Saatgut der Pflanzen behandelt werden.The active substance combinations can be used as such, in the form of their formulations or the use forms prepared therefrom, such as ready-to-use solutions, suspensions, wettable powders, pastes, soluble powders, dusts and granules. They are used in the usual way, e.g. by pouring, spraying, atomizing, scattering, dusting, foaming, brushing, etc. It is also possible to apply the active ingredients using the ultra-low-volume process or to inject the active ingredient preparation or the active ingredient itself into the soil. The seeds of the plants can also be treated.
Beim Einsatz der erfindungsgemäßen Wirkstoffkombinationen als Fungizide können die Aufwandmengen je nach Applikationsart innerhalb eines größeren Bereiches variiert werden. Bei der Behandlung von Pflanzenteilen liegen die Aufwandmengen an Wirkstoff im allgemeinen zwischen 0,1 und 10.000 g/ha, vorzugsweise zwischen 10 und 1.000 g/ha. Bei der Saatgutbehandlung liegen die Aufwandmengen an Wirkstoff im allgemeinen zwischen 0,001 und 50 g pro Kilogramm Saatgut, vorzugsweise zwischen 0,01 und 10 g pro Kilogramm Saatgut. Bei der Behandlung des Bodens liegen die Aufwandmengen an Wirkstoff im allgemeinen zwischen 0,1 und 10.000 g/ha, vorzugsweise zwischen 1 und 5.000 g/ha.When the active compound combinations according to the invention are used as fungicides, the application rates can be varied within a relatively wide range, depending on the type of application. In the treatment of parts of plants, the active compound application rates are generally between 0.1 and 10,000 g / ha, preferably between 10 and 1,000 g / ha. In the case of seed treatment, the active compound application rates are generally between 0.001 and 50 g per kg of seed, preferably between 0.01 and 10 g per kg of seed. In the treatment of the soil, the active compound application rates are generally between 0.1 and 10,000 g / ha, preferably between 1 and 5,000 g / ha.
Die zum Schutz technischer Materialien verwendeten Mittel enthalten die Wirkstoffe im allgemeinen in einer Menge von 1 bis 95 Gewichts-%, bevorzugt von 10 bis 75 Gewichts-%.The agents used to protect industrial materials generally contain the active ingredients in an amount of 1 to 95% by weight, preferably 10 to 75% by weight.
Die Anwendungskonzentrationen der erfindungsgemäßen Wirkstoffkombinationen richten sich nach der Art und dem Vorkommen der zu bekämpfenden Mikroorganismen sowie nach der Zusammensetzung des zu schützenden Materials. Die optimale Einsatzmenge kann durch Testreihen ermittelt werden. Im allgemeinen liegen die Anwendungskonzentrationen im Bereich von 0,001 bis 5 Gewichts-%», vorzugsweise von 0,05 bis 1,0 Gewichts-% bezogen auf das zu schützende Material.The application concentrations of the active compound combinations according to the invention depend on the type and the occurrence of the microorganisms to be controlled and on the composition of the material to be protected. The optimal amount can be determined by test series. In general, the application concentrations are in the range from 0.001 to 5% by weight, preferably from 0.05 to 1.0% by weight, based on the material to be protected.
Die erfindungsgemäßen Wirkstoffkombinationen eignen sich zur Bekämpfung von tierischen Schädlingen, vorzugsweise Arthropoden und Nematoden, insbesondere Insekten und Spinnentieren, die in der Landwirtschaft, der Tiergesundheit, in Fors- ten, im Vorrats- und Materialschutz sowie auf dem Hygienesektor vorkommen. Sie sind gegen normal sensible und resistente Arten sowie gegen alle oder einzelne Entwicklungsstadien wirksam. Zu den oben erwähnten Schädlingen gehören:The active compound combinations according to the invention are suitable for controlling animal pests, preferably arthropods and nematodes, in particular insects and arachnids, which occur in agriculture, animal health, in forests, in the protection of stored goods and materials and in the hygiene sector. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The pests mentioned above include:
Aus der Ordnung der Isopoda z.B. Oniscus asellus, Armadillidium vulgäre, Porcellio scaber.From the order of the Isopoda e.g. Oniscus asellus, Armadillidium vulgare, Porcellio scaber.
Aus der Ordnung der Diplopoda z.B. Blaniulus guttulatus.From the order of the Diplopoda e.g. Blaniulus guttulatus.
Aus der Ordnung der Chilopoda z.B. Geophilus caφophagus, Scutigera spp..From the order of the Chilopoda e.g. Geophilus caφophagus, Scutigera spp ..
Aus der Ordnung der Symphyla z.B. Scutigerella immaculata.From the order of the Symphyla e.g. Scutigerella immaculata.
Aus der Ordnung der Thysanura z.B. Lepisma saccharina. Aus der Ordnung der Collembola z.B. Onychiurus armatus. Aus der Ordnung der Orthoptera z.B. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria. Aus der Ordnung der Blattaria z.B. Blatta orientalis, Periplaneta americana, Leu- cophaea maderae, Blattella germanica. Aus der Ordnung der Dermaptera z.B. Forficula auricularia.From the order of the Thysanura, for example Lepisma saccharina. From the order of the Collembola, for example Onychiurus armatus. From the order of the Orthoptera, for example Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria. From the order of the Blattaria, for example Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica. From the order of the Dermaptera, for example, Forficula auricularia.
Aus der Ordnung der Isoptera z.B. Reticulitermes spp..From the order of the Isoptera e.g. Reticulitermes spp ..
Aus der Ordnung der Phthiraptera z.B. Pediculus humanus coφoris, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.. Aus der Ordnung der Thysanoptera z.B. Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.From the order of the Phthiraptera e.g. Pediculus humanus coφoris, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp .. From the order of the Thysanoptera e.g. Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
Aus der Ordnung der Heteroptera z.B. Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp. Aus der Ordnung der Homoptera z.B. Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fäbae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis,From the order of the Heteroptera e.g. Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp. From the order of the Homoptera e.g. Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fäbae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis,
Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp. Aus der Ordnung der Lepidoptera z.B. Pectinophora gossypiella, Bupalus piniarius,Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatatausidumonidium, aphidata lidium aphidata, aphidata, aphidata, pseudophilia stratata, pseudophyllum aphid stratiformes, pelphid stratiformes, pelphid stratiformes, pelphid stratiformes, pelphid stratiformes, pelphid stratiformes, pelphid stratiformes, pelphid stratiformes, sap ., Psylla spp. From the order of the Lepidoptera e.g. Pectinophora gossypiella, Bupalus piniarius,
Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Caφocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae. Aus der Ordnung der Coleoptera z.B. Anobium punctatum, R izopertha dominica,Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxiaothpppp., Brassica. Panolis flammea, Spodoptera spp., Trichoplusia ni, Caφocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hofmannophila pseudospretaanaiauaiaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaanaellaana pellella, cocoecuaiaellaella, cacoecia pella , Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae. From the order of the Coleoptera e.g. Anobium punctatum, R izopertha dominica,
Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus. Aus der Ordnung der Hymenoptera z.B. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatordimidhmpphppm, spp. , Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimalltra solitus Lissorhoptrus oryzophilus. From the order of the Hymenoptera, for example Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
Aus der Ordnung der Diptera z.B. Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata,From the order of the Diptera e.g. Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata,
Dacus oleae, Tipula paludosa, Hylemyia spp., Liriomyza spp.. Aus der Ordnung der Siphonaptera z.B. Xenopsylla cheopis, Ceratophyllus spp.. Aus der Klasse der Arachnida z.B. Scoφio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp.,Dacus oleae, Tipula paludosa, Hylemyia spp., Liriomyza spp .. From the order of the Siphonaptera e.g. Xenopsylla cheopis, Ceratophyllus spp .. From the Arachnida class e.g. Scoφio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp.,
Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp..Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp ..
Zu den pflanzenparasitären Nematoden gehören z.B. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp..Plant-parasitic nematodes include e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaph.
Die Wirkstoffkombinationen können in die üblichen Formulierungen überführt werden, wie Lösungen, Emulsionen, Spritzpulver, Suspensionen, Pulver, Stäubemittel, Pasten, lösliche Pulver, Granulate, Suspensions-Emulsions-Konzentrate, Wirkstoffimprägnierte Natur- und synthetische Stoffe sowie Feinstverkapselungen in poly- meren Stoffen.The active substance combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, Pastes, soluble powders, granules, suspension emulsion concentrates, active ingredient-impregnated natural and synthetic substances as well as fine encapsulation in polymeric substances.
Diese Formulierungen werden in bekannter Weise hergestellt, z.B. durch Vermischen der Wirkstoffe mit Streckmitteln, also flüssigen Lösungsmitteln und/oder festen Trägerstoffen, gegebenenfalls unter Verwendung von oberflächenaktiven Mitteln, also Emulgiermitteln und/oder Dispergiermitteln und/oder schaumerzeugenden Mitteln.These formulations are made in a known manner, e.g. by mixing the active ingredients with extenders, that is to say liquid solvents and / or solid carriers, optionally using surface-active agents, that is to say emulsifiers and / or dispersants and / or foam-generating agents.
Im Falle der Benutzung von Wasser als Streckmittel können z.B. auch organischeIf water is used as an extender, e.g. also organic
Lösungsmittel als Hilfslösungsmittel verwendet werden. Als flüssige Lösungsmittel kommen im wesentlichen in Frage: Aromaten, wie Xylol, Toluol, oder Alkylnaphthalme, chlorierte Aromaten und chlorierte aliphatische Kohlenwasserstoffe, wie Chlorbenzole, Chlorethylene oder Methylenchlorid, aliphatische Kohlenwasserstoffe, wie Cyclohexan oder Paraffine, z.B. Erdölfraktionen, mineralische und pflanzlicheSolvents are used as auxiliary solvents. The following are essentially suitable as liquid solvents: aromatics, such as xylene, toluene, or alkyl naphthalene, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chlorethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable
Öle, Alkohole, wie Butanol oder Glykol sowie deren Ether und Ester, Ketone wie Aceton, Methylethylketon, Methyhsobutylketon oder Cyclohexanon, stark polare Lösungsmittel, wie Dimethylformamid und Dimethylsulfoxid, sowie Wasser.Oils, alcohols, such as butanol or glycol, and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methylhysobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulfoxide, and water.
Als feste Trägerstoffe kommen in Frage: z.B. Ammoniumsalze und natürliche Gesteinsmehle, wie Kaoline, Tonerden, Talkum, Kreide, Quarz, Attapulgit, Montmorillonit oder Diatomeenerde und synthetische Gesteinsmehle, wie hochdisperse Kieselsäure, Aluminiumoxid und Silikate, als feste Trägerstoffe für Granulate kommen in Frage: z.B. gebrochene und fraktio- nierte natürliche Gesteine wie Calcit, Marmor, Bims, Sepiolith, Dolomit sowie synthetische Granulate aus anorganischen und organischen Mehlen sowie Granulate aus organischem Material wie Sägemehl, Kokosnußschalen, Maiskolben und Tabakstengeln; als Emulgier- und/oder schaumerzeugende Mittel kommen in Frage: z.B. nich- tionogene und anionische Emulgatoren, wie Polyoxyethylen-Fettsäure-Ester, Poly- oxyethylen-Fettalkohol-Ether, z.B. Alkylaryl-polyglykolether, Alkylsulfonate, Alkyl- sulfate, Arylsulfonate sowie Einweißhydrolysate; als Dispergiermittel kommen in Frage: z.B. Lignin-Sulfitablaugen und Methylcellulose.The following are suitable as solid carriers: for example ammonium salts and natural rock powders, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders, such as highly disperse silica, aluminum oxide and silicates, as solid carriers for granules are possible: eg broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; Possible emulsifying and / or foam-generating agents are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolyzates; Possible dispersing agents are, for example, lignin sulfite waste liquor and methyl cellulose.
Es können in den Formulierungen Haftmittel wie Carboxymethylcellulose, natürliche und synthetische pulvrige, körnige oder latexförmige Polymere verwendet werden, wie Gummiarabicum, Polyvinylalkohol, Polyvinylacetat, sowie natürliche Phospho- lipide, wie Kephaline und Lecithine und synthetische Phospholipide. Weitere Additive können mineralische und vegetabile Öle sein.Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids can be used in the formulations. Other additives can be mineral and vegetable oils.
Es können Farbstoffe wie anorganische Pigmente, z.B. Eisenoxid, Titanoxid, Ferro- cyanblau und organische Farbstoffe, wie Alizarin-, Azo- und Metallphthalocyanin- farbstoffe und Spurennährstoffe wie Salze von Eisen, Mangan, Bor, Kupfer, Kobalt, Molybdän und Zink verwendet werden.Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.
Die Formulierungen enthalten im allgemeinen zwischen 0,1 und 95 Gew.-% Wirkstoff, vorzugsweise zwischen 0,5 und 90 %>.The formulations generally contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%.
Die erfindungsgemäßen Wirkstoffkombinationen können in handelsüblichen Formulierungen sowie in den aus diesen Formulierungen bereiteten Anwendungsformen in Mischung mit anderen Wirkstoffen, wie Insektiziden, Lockstoffen, Sterilantien,The active compound combinations according to the invention can be used in commercially available formulations and in the use forms prepared from these formulations in a mixture with other active compounds, such as insecticides, attractants, sterilizers,
Bakteriziden, Akariziden, Nematiziden, Fungiziden, wachstumsregulierenden Stoffen oder Herbiziden vorliegen. Zu den Insektiziden zählen beispielsweise Phosphorsäureester, Carbamate, Carbonsäureester, chlorierte Kohlenwasserstoffe, Phenyl- harnstoffe, durch Mikroorganismen hergestellte Stoffe u.a.Bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides are present. Insecticides include, for example, phosphoric acid esters, carbamates, carboxylic acid esters, chlorinated hydrocarbons, phenylureas, substances produced by microorganisms, etc.
Auch eine Mischung mit anderen bekannten Wirkstoffen, wie Herbiziden oder mit Düngemitteln und Wachstumsregulatoren ist möglich.A mixture with other known active ingredients, such as herbicides or with fertilizers and growth regulators, is also possible.
Die erfindungsgemäßen Wirkstoffkombinationen können ferner beim Einsatz als Insektizide in ihren handelsüblichen Formulierungen sowie in den aus diesen Formulierungen bereiteten Anwendungsformen in Mischung mit Synergisten vorliegen. Synergisten sind Verbindungen, durch die die Wirkung der Wirkstoffe gesteigert wird, ohne dass der zugesetzte Synergist selbst aktiv wirksam sein muß.When used as insecticides, the active compound combinations according to the invention can also be present in their commercially available formulations and in the use forms prepared from these formulations in a mixture with synergists. Synergists are compounds that increase the effectiveness of the active ingredients without the added synergist itself having to be active.
Der Wirkstoffgehalt der aus den handelsüblichen Formulierungen bereiteten Anwen- dungsformen kann in weiten Bereichen variieren. Die Wirkstoffkonzentration derThe active substance content of the use forms prepared from the commercially available formulations can vary within wide ranges. The drug concentration of the
Anwendungsformen kann von 0,0000001 bis zu 95 Gew.-% Wirkstoff, vorzugsweise zwischen 0,0001 und 1 Gew.-% liegen.Application forms can be from 0.0000001 to 95% by weight of active compound, preferably between 0.0001 and 1% by weight.
Die Anwendung geschieht in einer den Anwendungsformen angepaßten üblichen Weise. —The application takes place in a customary manner adapted to the application forms. -
Bei der Anwendung gegen Hygiene- und Vorratsschädlinge zeichnen sich die Wirk- stoffkombinationen durch eine hervorragende Residualwirkung auf Holz und Ton sowie durch eine gute Alkalistabilität auf gekalkten Unterlagen aus.When used against hygiene pests and pests of stored products, the active substance combinations are notable for an excellent residual action on wood and clay and for good stability to alkali on limed substrates.
Die erfindungsgemäßen Wirkstoffkombinationen wirken nicht nur gegen Pflanzen-, Hygiene- und Vorratsschädlinge, sondern auch auf dem veterinärmedizinischen Sektor gegen tierische Parasiten (Ektoparasiten) wie Schildzecken, Lederzecken, Räudemilben, Laufmilben, Fliegen (stechend und leckend), parasitierende Fliegen- larven, Läuse, Haarlinge, Federlinge und Flöhe. Zu diesen Parasiten gehören:The active compound combinations according to the invention act not only against plant, hygiene and stored-product pests, but also in the veterinary sector against animal parasites (ectoparasites) such as tick ticks, leather ticks, space mites, running mites, flies (stinging and licking), parasitic fly larvae, lice, Hair lice, featherlings and fleas. These parasites include:
Aus der Ordnung der Anoplurida z.B. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp..From the order of the Anoplurida e.g. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp ..
Aus der Ordnung der Mallophagida und den Unterordnungen Amblycerina sowie Ischnocerina z.B. Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp..From the order of the Mallophagida and the subordinates Amblycerina and Ischnocerina e.g. Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp ..
Aus der Ordnung Diptera und den Unterordnungen Nematocerina sowie Brachycerina z.B. Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp..From the order Diptera and the subordinates Nematocerina and Brachycerina, for example Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp. , Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp ..
Aus der Ordnung der Siphonapterida z.B. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.. Aus der Ordnung der Heteropterida z.B. Cimex spp., Triatoma spp., Rhodnius spp.,From the order of the Siphonapterida e.g. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp .. From the order of the Heteropterida e.g. Cimex spp., Triatoma spp., Rhodnius spp.,
Panstrongylus spp..Panstrongylus spp ..
Aus der Ordnung der Blattarida z.B. Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp.. Aus der Unterklasse der Acaria (Acarida) und den Ordnungen der Meta- sowie Mesostigmata z.B. Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp.,From the order of the Blattarida e.g. Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp .. From the subclass of Acaria (Acarida) and the orders of the Meta and Mesostigmata e.g. Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp.,
Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp.. Aus der Ordnung der Actinedida (Prostigmata) und Acaridida (Astigmata) z.B. Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp..Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp .. From the order of the Actinedida ( Prostigmata) and Acaridida (Astigmata) e.g. Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypppectoles spp ., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp ..
Die erfindungsgemäßen Wirkstoffkombinationen eignen sich auch zur Bekämpfung von Arthropoden, die landwirtschaftliche Nutztiere, wie z.B. Rinder, Schafe, Ziegen, Pferde, Schweine, Esel, Kamele, Büffel, Kaninchen, Hühner, Puten, Enten, Gänse, Bienen, sonstige Haustiere wie z.B. Hunde, Katzen, Stubenvögel, Aquarienfische sowie sogenannte Versuchstiere, wie z.B. Hamster, Meerschweinchen, Ratten undThe active compound combinations according to the invention are also suitable for combating arthropods which are used in agricultural animals, such as Cattle, sheep, goats, horses, pigs, donkeys, camels, buffalo, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as e.g. Dogs, cats, house birds, aquarium fish and so-called experimental animals, such as Hamsters, guinea pigs, rats and
Mäuse befallen. Durch die Bekämpfung dieser Arthropoden sollen Todesfälle und Leistungsminderungen (bei Fleisch, Milch, Wolle, Häuten, Eiern, Honig usw.) vermindert werden, so dass durch den Einsatz der erfindungsgemäßen Wirkstoffkombinationen eine wirtschaftlichere und einfachere Tierhaltung möglich ist. Die Anwendung der erfindungsgemäßen Wirkstoffkombinationen geschieht im Veterinärsektor in bekannter Weise durch enterale Verabreichung in Form von beispielsweise Tabletten, Kapseln, Tränken, Drenchen, Granulaten, Pasten, Boli, des feed- through- Verfahrens, von Zäpfchen, durch parenterale Verabreichung, wie zum Bei- spiel durch Injektionen (intramuskulär, subcutan, intravenös, intraperitonal u.a.),Infest mice. By fighting these arthropods, deaths and reduced performance (in meat, milk, wool, skins, eggs, honey, etc.) are to be reduced, so that the use of the active compound combinations according to the invention enables more economical and simple animal husbandry. The active compound combinations according to the invention are used in the veterinary sector in a known manner by enteral administration in the form of, for example, tablets, capsules, drinkers, drenches, granules, pastes, boluses, the feed-through method, suppositories, by parenteral administration, such as for example play through injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.),
Implantate, durch nasale Applikation, durch dermale Anwendung in Form beispielsweise des Tauchens oder Badens (Dippen), Sprühens (Spray), Aufgießens (Pour-on und Spot-on), des Waschens, des Einpuderns sowie mit Hilfe von wirkstoffhaltigen Formköφern, wie Halsbändern, Ohrmarken, Schwanzmarken, Gliedmaßenbändern, Halftern, Markierungsvorrichtungen usw.Implants, by nasal application, by dermal application in the form of, for example, diving or bathing (dipping), spraying (spray), pouring on (pour-on and spot-on), washing, powdering and with the help of shaped articles containing active ingredients, such as collars , Ear tags, tail tags, limb bands, holsters, marking devices, etc.
Bei der Anwendung für Vieh, Geflügel, Haustiere etc. kann man die Wirkstoffkombinationen als Formulierungen (beispielsweise Pulver, Emulsionen, fließfähige Mittel), die die Wirkstoffe in einer Menge von 1 bis 80 Gew.-% enthalten, direkt oder nach 100 bis 10 000-facher Verdünnung anwenden oder sie als chemisches Bad verwenden.When used for cattle, poultry, pets, etc., the active substance combinations can be formulated (for example powders, emulsions, flowable agents) which contain the active substances in an amount of 1 to 80% by weight, directly or after 100 to 10,000 -Apply thinner or use it as a chemical bath.
Außerdem wurde gefunden, dass die erfindungsgemäßen Wirkstoffkombinationen eine hohe insektizide Wirkung gegen Insekten zeigen, die technische Materialien zer- stören.It was also found that the active compound combinations according to the invention have a high insecticidal action against insects which destroy industrial materials.
Beispielhaft und vorzugsweise - ohne jedoch zu limitieren - seien die folgenden Insekten genannt: Käfer wie Hylotrupes bajulus, Chlorophoras pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium caφini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus.The following insects may be mentioned by way of example and without limitation - beetles such as Hylotrupes bajulus, Chlorophoras pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium caφini, Lyctus africanus, Lyctus brunicanus, Lyctus brunicanus Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus.
Hautflügler wie Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur. Termiten wieSkin wings like Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur. Termites like
Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticuhtermes flavipes, Reticuhtermes santonensis, Reticuhtermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus.Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticuhtermes flavipes, Reticuhtermes santonensis, Reticuhtermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus.
Borstenschwänze wie Lepisma saccharina.Bristle tails such as Lepisma saccharina.
Unter technischen Materialien sind im vorliegenden Zusammenhang nicht-lebende Materialien zu verstehen, wie vorzugsweise Kunststoffe, Klebstoffe, Leime, Papiere und Kartone, Leder, Holz, Holzverarbeitungsprodukte und Anstrichmittel.In the present context, technical materials are to be understood as non-living materials, such as preferably plastics, adhesives, glues, papers and cartons, leather, wood, wood processing products and paints.
Ganz besonders bevorzugt handelt es sich bei dem vor Insektenbefall zu schützenden Material um Holz und Holzverarbeitungsprodukte.The material to be protected against insect infestation is very particularly preferably wood and wood processing products.
Unter Holz und Holzverarbeitungsprodukten, welche durch das erfindungsgemäßeAmong wood and wood processing products, which by the invention
Mittel bzw. dieses enthaltende Mischungen geschützt werden kann, ist beispielhaft zu verstehen:Agents or mixtures containing them can be protected is to be understood as an example:
Bauholz, Holzbalken, Eisenbahnschwellen, Brückenteile, Bootsstege, Holzfahrzeuge, Kisten, Paletten, Container, Telefonmasten, Holzverkleidungen, Holzfenster und -türen, Sperrholz, Spanplatten, Tischlerarbeiten oder Holzprodukte, die ganz allgemein beim Hausbau oder in der Bautischlerei Verwendung finden.Lumber, wooden beams, railway sleepers, bridge parts, jetties, wooden vehicles, boxes, pallets, containers, telephone poles, wooden cladding, wooden windows and doors, plywood, chipboard, carpentry or wooden products that are generally used in house construction or joinery.
Die Wirkstoffkombinationen können als solche, in Form von Konzentraten oder allgemein üblichen Formulierungen wie Pulver, Granulate, Lösungen, Suspensionen, Emulsionen oder Pasten angewendet werden.The active ingredient combinations can be used as such, in the form of concentrates or generally customary formulations such as powders, granules, solutions, suspensions, emulsions or pastes.
Die genannten Formulierungen können in an sich bekannter Weise hergestellt werden, z.B. durch Vermischen der Wirkstoffe mit mindestens einem Lösungs- bzw. Verdünnungsmittel, Emulgator, Dispergier- und/oder Binde- oder Fixiermittels, Wasser-Repellent, gegebenenfalls Sikkative und UV-Stabilisatoren und gegebenenfalls Farbstoffen und Pigmenten sowie weiteren Verarbeitungshilfsmitteln. Die zum Schutz von Holz und Holzwerkstoffen verwendeten insektiziden Mittel oder Konzentrate enthalten den erfindungsgemäßen Wirkstoff in einer Konzentration von 0,0001 bis 95 Gew.-%, insbesondere 0,001 bis 60 Gew.-%.The formulations mentioned can be prepared in a manner known per se, for example by mixing the active ingredients with at least one solvent or diluent, emulsifier, dispersant and / or binder or fixative, water repellants, optionally siccatives and UV stabilizers and, if appropriate Dyes and pigments as well as other processing aids. The insecticidal compositions or concentrates used to protect wood and wood-based materials contain the active compound according to the invention in a concentration of 0.0001 to 95% by weight, in particular 0.001 to 60% by weight.
Die Menge der eingesetzten Mittel bzw. Konzentrate ist von der Art und dem Vorkommen der Insekten und von dem Medium abhängig. Die optimale Einsatzmenge kann bei der Anwendung jeweils durch Testreihen ermittelt werden. Im allgemeinen ist es jedoch ausreichend 0,0001 bis 20 Gew.-%, vorzugsweise 0,001 bis 10 Gew.-%, des Wirkstoffs, bezogen auf das zu schützende Material, einzusetzen.The amount of the agents or concentrates used depends on the type and occurrence of the insects and on the medium. The optimal amount can be determined in each case by test series. In general, however, it is sufficient to use 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of the active compound, based on the material to be protected.
Als Lösungs- und/oder Verdünnungsmittel dient ein organisch-chemisches Lösungsmittel oder Lösungsmittelgemisch und/oder ein öliges oder ölartiges schwer flüchtiges organisch-chemisches Lösungsmittel oder Lösungsmittelgemisch und/oder ein polares organisch-chemisches Lösungsmittel oder Lösungsmittelgemisch und/oderAn organic-chemical solvent or solvent mixture and / or an oily or oil-like low-volatility organic-chemical solvent or solvent mixture and / or a polar organic-chemical solvent or solvent mixture and / or serves as the solvent and / or diluent
Wasser und gegebenenfalls einen Emulgator und/oder Netzmittel.Water and optionally an emulsifier and / or wetting agent.
Als organisch-chemische Lösungsmittel werden vorzugsweise ölige oder ölartige Lösungsmittel mit einer Verdunstungszahl über 35 und einem Flammpunkt oberhalb 30°C, vorzugsweise oberhalb 45°C, eingesetzt. Als derartige schwerflüchtige, wasserunlösliche, ölige und ölartige Lösungsmittel werden entsprechende Mineralöle oder deren Aromatenfraktionen oder mineralölhaltige Lösungsmittelgemische, vorzugsweise Testbenzin, Petroleum und/oder Alkylbenzol verwendet.The organic chemical solvents used are preferably oily or oily solvents with an evaporation number above 35 and a flash point above 30 ° C., preferably above 45 ° C. Corresponding mineral oils or their aromatic fractions or mineral oil-containing solvent mixtures, preferably white spirit, petroleum and / or alkylbenzene, are used as such low-volatility, water-insoluble, oily and oily solvents.
Vorteilhaft gelangen Mineralöle mit einem Siedebereich von 170 bis 220°C, Testbenzin mit einem Siedebereich von 170 bis 220°C, Spindelöl mit einem Siedebereich von 250 bis 350°C, Petroleum bzw. Aromaten vom Siedebereich von 160 bis 280°C, Teφentinöl und dgl. zum Einsatz.Mineral oils with a boiling range of 170 to 220 ° C, white spirit with a boiling range of 170 to 220 ° C, spindle oil with a boiling range of 250 to 350 ° C, petroleum or aromatics with a boiling range of 160 to 280 ° C, Teφentinöl and Like. Used.
In einer bevorzugten Ausführungsform werden flüssige aliphatische Kohlenwasserstoffe mit einem Siedebereich von 180 bis 210°C oder hochsiedende Gemische von aromatischen und aliphatischen Kohlenwasserstoffen mit einem Siedebereich von 180 bis 220°C und oder Spindeöl und/oder Monochlornaphthalin, vorzugsweise α- Monochlornaphthalin, verwendet.In a preferred embodiment, liquid aliphatic hydrocarbons with a boiling range of 180 to 210 ° C or high-boiling mixtures of aromatic and aliphatic hydrocarbons with a boiling range of 180 to 220 ° C and or locker oil and / or monochloronaphthalene, preferably α-monochloronaphthalene used.
Die organischen schwerflüchtigen öligen oder ölartigen Lösungsmittel mit einer Verdunstungszahl über 35 und einem Flammpunkt oberhalb 30°C, vorzugsweise oberhalb 45 °C, können teilweise durch leicht oder mittelflüchtige organisch-chemische Lösungsmittel ersetzt werden, mit der Maßgabe, dass das Lösungsmittelgemisch ebenfalls eine Verdunstungszahl über 35 und einen Flammpunkt oberhalb 30°C, vor- zugsweise oberhalb 45°C, aufweist und dass das Gemisch in diesem Lösungsmittelgemisch löslich oder emulgierbar ist.The organic non-volatile oily or oily solvents with an evaporation number above 35 and a flash point above 30 ° C, preferably above 45 ° C, can be partially replaced by slightly or medium-volatile organic chemical solvents, with the proviso that the solvent mixture also has an evaporation number 35 and has a flash point above 30 ° C, preferably above 45 ° C, and that the mixture is soluble or emulsifiable in this solvent mixture.
Nach einer bevorzugten Ausführungsform wird ein Teil des organisch-chemischen Lösungsmittel oder Lösungsmittelgemisches durch ein aliphatisches polares orga- nisch-chemisches Lösungsmittel oder Lösungsmittelgemisch ersetzt. Vorzugsweise gelangen Hydroxyl- und/oder Ester- und/oder Ethergruppen enthaltende aliphatische organisch-chemische Lösungsmittel wie beispielsweise Glycolether, Ester oder dgl. zur Anwendung.According to a preferred embodiment, part of the organic chemical solvent or solvent mixture is replaced by an aliphatic polar organic chemical solvent or solvent mixture. Aliphatic organic chemical solvents containing hydroxyl and / or ester and / or ether groups, such as, for example, glycol ethers, esters or the like, are preferably used.
Als orgamsch-chemische Bindemittel werden im Rahmen der vorliegenden Erfindung die an sich bekannten wasserverdünnbaren und/oder in den eingesetzten organisch-chemischen Lösungsmitteln löslichen oder dispergier- bzw. emulgierbaren Kunstharze und/oder bindende trocknende Öle, insbesondere Bindemittel bestehend aus oder enthaltend ein Acrylatharz, ein Vinylharz, z.B. Polyvinylacetat, Polyester- harz, Polykondensations- oder Polyadditionsharz, Polyurethanharz, Alkydharz bzw. modifiziertes Alkydharz, Phenolharz, Kohlenwasserstoffharz wie Inden-Cumaron- harz, Siliconharz, trocknende pflanzliche und/oder trocknende Öle und/oder physikalisch trocknende Bindemittel auf der Basis eines Natur- und/oder Kunstharzes verwendet. Das als Bindemittel verwendete Kunstharz kann in Form einer Emulsion, Dispersion oder Lösung, eingesetzt werden. Als Bindemittel können auch Bitumen oder bituminöse Substanzen bis zu 10 Gew.-%, verwendet werden. Zusätzlich können an sich bekannte Farbstoffe, Pigmente, wasserabweisende Mittel, Geruchskorrigentien und Inhibitoren bzw. Korrosionsschutzmittel und dgl. eingesetzt werden.In the context of the present invention, organic chemicals which are known per se and which are water-thinnable and / or soluble or dispersible or emulsifiable in the organic chemical solvents used and / or binding drying oils, in particular binders consisting of or comprising an acrylate resin, a vinyl resin, for example polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin such as indene-coumarone resin, silicone resin, drying vegetable and / or drying oils and / or physically drying binders on the Base of a natural and / or synthetic resin used. The synthetic resin used as a binder can be used in the form of an emulsion, dispersion or solution. Bitumen or bituminous substances up to 10% by weight can also be used as binders. In addition, known dyes, pigments, water-repellants, odor correctors and inhibitors or anticorrosive agents and the like can be used.
Bevorzugt ist gemäß der Erfindung als organisch-chemische Bindemittel mindestens ein Alkydharz bzw. modifiziertes Alkydharz und/oder ein trocknendes pflanzliches Öl im Mittel oder im Konzentrat enthalten. Bevorzugt werden gemäß der Erfindung Alkydharze mit einem Ölgehalt von mehr als 45 Gew.-%>, vorzugsweise 50 bisAccording to the invention, at least one alkyd resin or modified alkyd resin and / or a drying vegetable oil is preferably contained in the agent or in the concentrate as the organic chemical binder. Alkyd resins having an oil content of more than 45% by weight, preferably 50 to, are preferred according to the invention
68 Gew.-%, verwendet.68% by weight.
Das erwähnte Bindemittel kann ganz oder teilweise durch ein Fixierungsmit- tel(gemisch) oder ein Weichmacher(gemisch) ersetzt werden. Diese Zusätze sollen einer Verflüchtigung der Wirkstoffe sowie einer Kristallisation bzw. Ausfällen! vorbeugen. Vorzugsweise ersetzen sie 0,01 bis 30 % des Bindemittels (bezogen auf 100 % des eingesetzten Bindemittels).All or part of the binder mentioned can be replaced by a fixative (mixture) or a plasticizer (mixture). These additives are intended to volatilize the active ingredients and crystallize or precipitate! prevent. They preferably replace 0.01 to 30% of the binder (based on 100% of the binder used).
Die Weichmacher stammen aus den chemischen Klassen der Phthalsäureester wie Dibutyl-, Dioctyl- oder Benzylbutylphthalat, Phosphorsäureester wie Tributyl- phosphat, Adipinsäureester wie Di-(2-ethylhexyl)-adipat, Stearate wie Butylstearat oder Amylstearat, Oleate wie Butyloleat, Glycerinether oder höhermolekulare Gly- kolether, Glycerinester sowie p-Toluolsulfonsäureester.The plasticizers come from the chemical classes of phthalic acid esters such as dibutyl, dioctyl or benzyl butyl phthalate, phosphoric acid esters such as tributyl phosphate, adipic acid esters such as di- (2-ethylhexyl) adipate, stearates such as butyl stearate or amyl stearate, oleates such as butyl oleate, higher glycerol glycerol or glycerol ether - Kolether, glycerol ester and p-toluenesulfonic acid ester.
Fixierungsmittel basieren chemisch auf Polyvinylalkylethern wie z.B. Polyvinylme- thylether oder Ketonen wie Benzophenon, Ethylenbenzophenon.Fixing agents are chemically based on polyvinyl alkyl ethers such as e.g. Polyvinyl methyl ether or ketones such as benzophenone, ethylene benzophenone.
Als Lösungs- bzw. Verdünnungsmittel kommt insbesondere auch Wasser in Frage, gegebenenfalls in Mischung mit einem oder mehreren der oben genannten organisch- chemischen Lösungs- bzw. Verdünnungsmittel, Emulgatoren und Dispergatoren. Ein besonders effektiver Holzschutz wird durch großtechnische Imprägnierverfahren, z.B. Vakuum, Doppelvakuum oder Druckverfahren, erzielt.Water is also particularly suitable as a solvent or diluent, if appropriate in a mixture with one or more of the above-mentioned organic chemical solvents or diluents, emulsifiers and dispersants. A particularly effective wood protection is achieved by industrial impregnation processes, e.g. vacuum, double vacuum or pressure processes.
Zugleich können die erfindungsgemäßen Wirkstoffkombinationen zum Schutz vor Bewuchs von Gegenständen, insbesondere von Schiffsköφern, Sieben, Netzen, Bauwerken, Kaianlagen und Signalanlagen, welche mit See- oder Brackwasser in Verbindung kommen, eingesetzt werden.At the same time, the active compound combinations according to the invention can be used to protect objects, in particular ship hulls, sieves, nets, structures, quay systems and signaling systems which come into contact with sea or brackish water.
Bewuchs durch sessile Ohgochaeten, wie KallαOhrenwürrner sowie durch Muscheln und Arten der Gruppe Ledamoφha (Entenmuscheln), wie verschiedene Lepas- undOvergrowth by sessile Ohgochaeten, such as Kallα earworms and by mussels and species of the group Ledamoφha (barnacles), such as various Lepas and
Scalpellum-Arten, oder durch Arten der Gruppe Balanomoφha (Seepocken), wie Baianus- oder Pollicipes-Species, erhöht den Reibungswiderstand von Schiffen und führt in der Folge durch erhöhten Energieverbrauch und darüber hinaus durch häufige Trockendockaufenthalte zu einer deutlichen Steigerung der Betriebskosten.Scalpellum species, or by species from the group Balanomoφha (barnacles), such as Baianus or pollicipes species, increases the frictional resistance of ships and, as a result, leads to a significant increase in operating costs due to increased energy consumption and, moreover, frequent dry dock stays.
Neben dem Bewuchs durch Algen, beispielsweise Ectocaφus sp. und Ceramium sp., kommt insbesondere dem Bewuchs durch sessile Entomostraken-Gruppen, welche unter dem Namen Cirripedia (Rankenflußkrebse) zusammengefaßt werden, besondere Bedeutung zu.In addition to fouling by algae, for example Ectocaφus sp. and Ceramium sp., vegetation by sessile Entomostraken groups, which are grouped under the name Cirripedia (tendril crayfish), is particularly important.
Es wurde nun überraschenderweise gefunden, dass die erfindungsgemäßen Wirkstoffkombinationen eine hervorragende Antifouling (Antibewuchs)-Wirkung aufweisen.It has now surprisingly been found that the active compound combinations according to the invention have an excellent antifouling effect.
Durch Emsatz der erfindungsgemäßen Wirkstoff kombinationen kann auf den Einsatz von Schwermetallen wie z.B. in Bis(trialkylzinn)-sulfiden, Tri-ra-butylzinnlaurat, Tri- ft-butylzinnchlorid, Kupfer(I)-oxid, Triethylzinnchlorid, Tri-/--butyl(2-phenyl-4- chloφhenoxy)-zinn, Tributylzinnoxid, Molybdändisulfid, Antimonoxid, polymerem Butyltitanat, Phenyl-(bispyridin)-wismutchlorid, Tri-n-butylzinnfluorid, Mangan- ethylenbisthiocarbamat, Zinkdimethyldithiocarbamat, Zinkethylenbisthiocarbamat,By using the active ingredient combinations according to the invention, heavy metals such as e.g. in bis (trialkyltin) sulfides, tri-ra- butyltin laurate, trif-butyltin chloride, copper (I) oxide, triethyltin chloride, tri - / - butyl (2-phenyl-4-chloropheneoxy) tin, tributyltin oxide, molybdenum disulfide , Antimony oxide, polymeric butyl titanate, phenyl (bispyridine) bismuth chloride, tri-n-butyltin fluoride, manganese ethylene bisthiocarbamate, zinc dimethyldithiocarbamate, zinc ethylene bisthiocarbamate,
Zink- und Kupfersalze von 2-Pyridinthiol-l-oxid, Bisdimethyldithiocarbamoylzink- ethylenbisthiocarbamat, Zinkoxid, Kupfer(I)-ethylen-bisdithiocarbamat, Kupferthio- cyanat, Kupfernaphthenat und Tributylzinnhalogeniden verzichtet werden oder die Konzentration dieser Verbindungen entscheidend reduziert werden.Zinc and copper salts of 2-pyridinthiol-l-oxide, bisdimethyldithiocarbamoylzinc ethylene bishiocarbamate, zinc oxide, copper (I) ethylene bisdithiocarbamate, copper thiocyanate, copper naphthenate and tributyltin halides or the concentration of these compounds can be significantly reduced.
Die anwendungsfertigen Antifoulingfarben können gegebenenfalls noch andereThe ready-to-use antifouling paints can also be used if necessary
Wirkstoffe, vorzugsweise Algizide, Fungizide, Herbizide, Molluskizide bzw. andere Antifouling- Wirkstoffe enthalten.Contain active ingredients, preferably algicides, fungicides, herbicides, molluscicides or other antifouling active ingredients.
Als Kombinationspartner für die erfindungsgemäßen Antifouling-Mittel eignen sich vorzugsweise:Suitable combination partners for the antifouling agents according to the invention are preferably:
Algizide wieAlgicides like
2-tert.-Butylamino-4-cyclopropylamino-6-methylthio- 1 ,3,5-triazin, Dichlorophen, Diuron, Endothal, Fentinacetat, Isoproturon, Methabenzthiazuron, Oxyfluorfen, Quinoclamine und Terbutryn;2-tert-butylamino-4-cyclopropylamino-6-methylthio-1, 3,5-triazine, dichlorophene, diuron, endothal, fentin acetate, isoproturon, methabenzthiazuron, oxyfluorfen, quinoclamine and terbutryn;
Fungizide wieFungicides like
Benzo[&]thiophencarbonsäurecyclohexylamid-S,S-dioxid, Dichlofluanid, Fluor- folpet, 3-Iod-2-propinyl-butylcarbamat, Tolylfluanid und Azole wie Azaconazole, Cyproconazole, Epoxyconazole, Hexaconazole, Metconazole, Propi- conazole und Tebuconazole;Benzo [&] thiophenecarboxylic acid cyclohexylamide-S, S-dioxide, dichlofluanid, fluorofolpet, 3-iodo-2-propynyl-butylcarbamate, tolylfluanid and azoles such as azaconazoles, cyproconazoles, epoxyconazoles, hexaconazoles, metconazoles and propiconazoles;
Molluskizide wieMolluscicides like
Fentinacetat, Metaldehyd, Methiocarb, Niclosamid, Thiodicarb und Trimethacarb;Fentin acetate, metaldehyde, methiocarb, niclosamide, thiodicarb and trimethacarb;
oder herkömmliche Antifouling- Wirkstoffe wieor conventional antifouling agents such as
4,5-Dichlor-2-octyl-4-isothiazolin-3-on, Diiodmethylparatrylsulfon, 2-(N,N-Di- methylthiocarbamoylthio)-5-nitrothiazyl, Kalium-, Kupfer-, Natrium- und Zinksalze von 2-Pyridinthiol-l-oxid, Pyridin-triphenylboran, Teträbutyldistannoxan, 2,3,5,6- Tetrachlor-4-(methylsulfonyl)-pyridin, 2,4,5, 6-Tetrachloroisophthalonitril, Tetrame- thylthiuramdisulfid und 2,4,6-TricWoφhenyιmaleinimid. Die verwendeten Antifouling-Mittel enthalten die erfindungsgemäßen Wirkstoff- kombinationen in einer Konzentration von 0,001 bis 50 Gew.-%, insbesondere von 0,01 bis 20 Gew.-%.4,5-dichloro-2-octyl-4-isothiazolin-3-one, diiodomethylparatrylsulfone, 2- (N, N-dimethylthiocarbamoylthio) -5-nitrothiazyl, potassium, copper, sodium and zinc salts of 2-pyridinethiol -l-oxide, pyridine-triphenylborane, teträbutyldistannoxane, 2,3,5,6-tetrachloro-4- (methylsulfonyl) -pyridine, 2,4,5, 6-tetrachloroisophthalonitrile, tetramethylthiuram disulfide and 2,4,6-TricWoφhenyιmaleinimid , The antifouling agents used contain the active substance combinations according to the invention in a concentration of 0.001 to 50% by weight, in particular 0.01 to 20% by weight.
Die erfindungsgemäßen Antifouling-Mittel enthalten desweiteren die üblichen Bestandteile wie z.B. in Ungerer, Chem. Ind. 1985, 37, 730-732 und Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973 beschrieben.The antifouling agents according to the invention furthermore contain the usual constituents, e.g. in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.
Antifouling- Anstrichmittel enthalten neben den algiziden, fungiziden, molluskiziden und erfindungsgemäßen insektiziden Wirkstoffen insbesondere Bindemittel.In addition to the algicidal, fungicidal, molluscicidal and insecticidal active compounds according to the invention, antifouling paints contain in particular binders.
Beispiele für anerkannte Bindemittel sind Polyvinylchlorid in einem Lösungsmittelsystem, chlorierter Kautschuk in einem Lösungsmittelsystem, Acrylharze in einem Lösungsmittelsystem insbesondere in einem wäßrigen System, Vinylchlorid/Ninyl- acetat-Copolymersysteme in Form wäßriger Dispersionen oder in Form von organischen Lösungsmittelsystemen, Butadien/Styrol/Acrylnitril-Kautschuke, trocknende Öle, wie Leinsamenöl, Harzester oder modifizierte Hartharze in Kombination mit Teer oder Bitumina, Asphalt sowie Epoxyverbindungen, geringe Mengen Chlorkau- tschuk, chloriertes Polypropylen und Ninylharze.Examples of recognized binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in a solvent system, especially in an aqueous system, vinyl chloride / vinyl acetate copolymer systems in the form of aqueous dispersions or in the form of organic solvent systems, butadiene / styrene / acrylonitrile Rubbers, drying oils, such as linseed oil, resin esters or modified hard resins in combination with tar or bitumen, asphalt and epoxy compounds, small amounts of chlorinated rubber, chlorinated polypropylene and vinyl resins.
Gegebenenfalls enthalten Anstrichmittel auch anorganische Pigmente, organische Pigmente oder Farbstoffe, welche vorzugsweise in Seewasser unlöslich sind. Ferner können Anstrichmittel Materialien, wie Kolophonium enthalten, um eine gesteuerte Freisetzung der Wirkstoffe zu ermöglichen. Die Anstriche können ferner Weichmacher, die rheologischen Eigenschaften beeinflussende Modifizierungsmittel sowie andere herkömmliche Bestandteile enthalten. Auch in Self-Polishing-Antifouling- Systemen können die erfindungsgemäßen Verbindungen oder die oben genannten Mischungen eingearbeitet werden. Die Wirkstoffkombinationen eignen sich auch zur Bekämpfung von tierischen Schädlingen, insbesondere von Insekten, Spinnentieren und Milben, die in geschlossenen Räumen, wie beispielsweise Wohnungen, Fabrikhallen, Büros, Fahrzeugkabinen u.a. vorkommen. Sie können zur Bekämpfung dieser Schädlinge in Haushaltsin- sektizid-Produkten verwendet werden. Sie sind gegen sensible und resistente Arten sowie gegen alle Entwicklungsstadien wirksam. Zu diesen Schädlingen gehören: Aus der Ordnung der Scoφionidea z.B. Buthus occitanus.Paints may also contain inorganic pigments, organic pigments or dyes, which are preferably insoluble in sea water. Paints may also contain materials such as rosin to enable controlled release of the active ingredients. The paints may also contain plasticizers, modifiers that affect rheological properties, and other conventional ingredients. The compounds according to the invention or the abovementioned mixtures can also be incorporated into self-polishing antifouling systems. The active ingredient combinations are also suitable for controlling animal pests, in particular insects, arachnids and mites, which occur in closed rooms, such as, for example, apartments, factory halls, offices, vehicle cabins and others. They can be used to control these pests in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include: From the order of the Scoφionidea, for example Buthus occitanus.
Aus der Ordnung der Acarina z.B. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula arfreddugesi, Neutrombicula autumnalis,From the order of the Acarina e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula arfreddugesi, Neutrombicula autumnalis,
Dermatophagoides pteronissimus, Dermatophagoides forinae. Aus der Ordnung der Araneae z.B. Aviculariidae, Araneidae. Aus der Ordnung der Opiliones z.B. Pseudoscoφiones chelifer, Pseudoscoφiones cheiridium, Opiliones phalangium. Aus der Ordnung der Isopoda z.B. Oniscus asellus, Porcellio scaber.Dermatophagoides pteronissimus, Dermatophagoides forinae. From the order of the Araneae e.g. Aviculariidae, Araneidae. From the order of the Opiliones e.g. Pseudoscoφiones chelifer, Pseudoscoφiones cheiridium, Opiliones phalangium. From the order of the Isopoda e.g. Oniscus asellus, Porcellio scaber.
Aus der Ordnung der Diplopoda z.B. Blaniulus guttulatus, Polydesmus spp..From the order of the Diplopoda e.g. Blaniulus guttulatus, Polydesmus spp ..
Aus der Ordnung der Chilopoda z.B. Geophilus spp..From the order of the Chilopoda e.g. Geophilus spp ..
Aus der Ordnung der Zygentoma z.B. Ctenolepisma spp., Lepisma saccharina,From the order of the Zygentoma e.g. Ctenolepisma spp., Lepisma saccharina,
Lepismodes inquilinus. Aus der Ordnung der Blattaria z.B. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa. Aus der Ordnung der Saltatoria z.B. Acheta domesticus. Aus der Ordnung der Dermaptera z.B. Forficula auricularia.Lepismodes inquilinus. From the order of the Blattaria e.g. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa. From the order of the Saltatoria e.g. Acheta domesticus. From the order of the Dermaptera e.g. Forficula auricularia.
Aus der Ordnung der Isoptera z.B. Kalotermes spp., Reticuhtermes spp.From the order of the Isoptera e.g. Kalotermes spp., Reticuhtermes spp.
Aus der Ordnung der Psocoptera z.B. Lepinatus spp., Liposcelis spp.From the order of the Psocoptera e.g. Lepinatus spp., Liposcelis spp.
Aus der Ordnung der Coleptera z.B. Anthrenus spp., Attagenus spp., Dermestes spp.,From the order of the Coleptera e.g. Anthrenus spp., Attagenus spp., Dermestes spp.,
Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum. Aus der Ordnung der Diptera z.B. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis,Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum. From the order of the Diptera, for example Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis,
Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys calcitrans, Tipula paludosa.Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys calcitrans, Tipula paludosa.
Aus der Ordnung der Lepidoptera z.B. Achroia grisella, Galleria mellonella, Plodia inteφunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.From the order of the Lepidoptera e.g. Achroia grisella, Galleria mellonella, Plodia inteφunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
Aus der Ordnung der Siphonaptera z.B. Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis. Aus der Ordnung der Hymenoptera z.B. Camponotus herculeanus, Lasius füliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.From the order of the Siphonaptera e.g. Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis. From the order of the Hymenoptera e.g. Camponotus herculeanus, Lasius Füliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
Aus der Ordnung der Anoplura z.B. Pediculus humanus capitis, Pediculus humanus coφoris, Phthirus pubis. Aus der Ordnung der Heteroptera z.B. Cimex hemipterus, Cimex lectularius,From the order of the anoplura e.g. Pediculus humanus capitis, Pediculus humanus coφoris, Phthirus pubis. From the order of the Heteroptera e.g. Cimex hemipterus, Cimex lectularius,
Rhodinus prolixus, Triatoma infestans.Rhodinus prolixus, Triatoma infestans.
Die Anwendung erfolgt in Aerosolen, drucklosen Sprühmitteln, z.B. Pump- und Zerstäubersprays, Nebelautomaten, Foggern, Schäumen, Gelen, Verdampfeφrodukten mit Verdampfeφlättchen aus Cellulose oder Kunststoff, Flüssigverdampfern, Gel- und Membranverdampfern, propellergetriebenen Verdampfern, energielosen bzw. passiven Verdampfungssystemen, Mottenpapieren, Mottensäckchen und Mottengelen, als Granulate oder Stäube, in Streuködern oder Köderstationen.They are used in aerosols, non-pressurized sprays, e.g. Pump and atomizer sprays, automatic foggers, foggers, foams, gels, vaporizer products with vaporizer plates made of cellulose or plastic, liquid vaporizers, gel and membrane vaporizers, propeller-driven vaporizers, energy-free or passive evaporation systems, moth papers, moth sachets and moth gels, in granules or dust or bait stations.
Erfindungsgemäß können alle Planzen und Pflanzenteile behandelt werden. UnterAccording to the invention, all plants and parts of plants can be treated. Under
Pflanzen werden hierbei alle Pflanzen und Pflanzenpopulationen verstanden, wie erwünschte und unerwünschte Wildpflanzen oder Kultuφflanzen (einschließlich natürlich vorkommender Kultuφflanzen). Kultuφflanzen können Pflanzen sein, die durch konventionelle Züchtungs- und Optimierungsmethoden oder durch biotechno- logische und gentechnologische Methoden oder Kombinationen dieser Methoden erhalten werden können, einschließlich der transgenen Pflanzen und einschließlich der durch Sortenschutzrechte schützbaren oder nicht schützbaren Pflanzensorten. Unter Pflanzenteilen sollen alle oberirdischen und unterirdischen Teile und Organe der Pflanzen, wie Spross, Blatt, Blüte und Wurzel verstanden werden, wobei beispielhaft, Blätter, Nadeln, Stengel, Stämme, Blüten, Fruchtköφer, Früchte und Samen sowie Wurzeln, Knollen und Rhizome aufgeführt werden. Zu den Pflanzenteilen gehört auch Erntegut sowie vegetatives und generatives Vermehrungsmaterial, beispielsweise Stecklinge, Knollen, Rhiozome, Ableger und Samen.Plants are understood to mean all plants and plant populations, such as desired and undesirable wild plants or cultivated plants (including naturally occurring cultivated plants). Cultivated plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the Plant varieties that can or cannot be protected by plant breeders' rights. Plant parts are to be understood to mean all above-ground and underground parts and organs of plants, such as shoots, leaves, flowers and roots, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes , The plant parts also include crops and vegetative and generative propagation material, for example cuttings, tubers, rhiozomes, offshoots and seeds.
Die erfindungsgemäße Behandlung der Pflanzen und Pflanzenteile mit den Wirk- Stoffen erfolgt direkt oder durch Einwirkung auf deren Umgebung, Lebensraum oderThe treatment of the plants and plant parts according to the invention with the active substances takes place directly or by acting on their environment, habitat or
Lagerraum nach den üblichen Behandlungsmethoden, z.B. durch Tauchen, Sprühen, Verdampfen, Vernebeln, Streuen, Aufstreichen und bei Vermehrungsmaterial, insbesondere bei Samen, weiterhin durch ein- oder mehrschichtiges Umhüllen.Storage room according to the usual treatment methods, e.g. by dipping, spraying, vaporizing, atomizing, scattering, spreading and, in the case of propagation material, in particular seeds, furthermore by single- or multi-layer coating.
Wie bereits oben erwähnt, können erfindungsgemäß alle Pflanzen und deren Teile behandelt werden. In einer bevorzugten Ausführungsform werden wild vorkommende oder durch konventionelle biologische Zuchtmethoden, wie Kreuzung oder Proto- plastenfusion erhaltenen Pflanzenarten und Pflanzensorten sowie deren Teile behandelt. In einer weiteren bevorzugten Ausführungsform werden transgene Pflanzen und Pflanzensorten, die durch gentechnologische Methoden gegebenenfalls in Kombination mit konventionellen Methoden erhalten wurden (Genetic Modified Organisms) und deren Teile behandelt. Der Begriff "Teile" bzw. "Teile von Pflanzen" oder "Pflanzenteile" wurde oben erläutert.As already mentioned above, all plants and their parts can be treated according to the invention. In a preferred embodiment, plant species and plant cultivars and their parts occurring wildly or obtained by conventional organic breeding methods, such as crossbreeding or protoplast fusion, are treated. In a further preferred embodiment, transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (genetic modified organisms) and their parts are treated. The term "parts" or "parts of plants" or "plant parts" was explained above.
Besonders bevorzugt werden erfindungsgemäß Pflanzen der jeweils handelsüblichen oder in Gebrauch befindlichen Pflanzensorten behandelt.Plants of the plant varieties which are in each case commercially available or in use are particularly preferably treated according to the invention.
Je nach Pflanzenarten bzw. Pflanzensorten, deren Standort und Wachstumsbedingungen (Böden, Klima, Vegetationsperiode, Ernährung) können durch die erfin- dungsgemäße Behandlung auch überadditive ("synergistische") Effekte auftreten. So sind beispielsweise erniedrigte Aufwandmengen und/oder Erweiterungen des Wir- kungsspektrums und/oder eine Verstärkung der Wirkung der erfindungsgemäß verwendbaren Stoffe und Mittel, besseres Pflanzenwachstum, erhöhte Toleranz gegenüber hohen oder niedrigen Temperaturen, erhöhte Toleranz gegen Trockenheit oder gegen Wasser- bzw. Bodensalzgehalt, erhöhte Blühleistung, erleichterte Ernte, Be- schleunigung der Reife, höhere Ernteerträge, höhere Qualität und/oder höherer Ernährungswert der Ernteprodukte, höhere Lagerfähigkeit und/oder Bearbeitbarkeit der Ernteprodukte möglich, die über die eigentlich zu erwartenden Effekte hinausgehen.Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, growing season, nutrition), the treatment according to the invention can also cause superadditive ("synergistic") effects. For example, reduced application rates and / or extensions of the spectrum and / or an enhancement of the effect of the substances and agents which can be used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to water or soil salt content, increased flowering performance, easier harvesting, acceleration of ripening, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or workability of the harvested products possible, which go beyond the effects that are actually to be expected.
Zu den bevorzugten erfindungsgemäß zu behandelnden transgenen (gentechnolo- gisch erhaltenen) Pflanzen bzw. Pflanzensorten gehören alle Pflanzen, die durch die gentechnologische Modifikation genetisches Material erhielten, welches diesen Pflanzen besondere vorteilhafte wertvolle Eigenschaften ("Traits") verleiht. Beispiele für solche Eigenschaften sind besseres Pflanzenwachstum, erhöhte Toleranz gegenüber hohen oder niedrigen Temperaturen, erhöhte Toleranz gegen Trockenheit oder gegen Wasser- bzw. Bodensalzgehalt, erhöhte Blühleistung, erleichterte Ernte, Beschleunigung der Reife, höhere Ernteerträge, höhere Qualität und/oder höherer Ernährungswert der Ernteprodukte, höhere Lagerfähigkeit und/oder Bearbeitbarkeit der Ernteprodukte. Weitere und besonders hervorgehobene Beispiele für solche Eigenschaften sind eine erhöhte Abwehr der Pflanzen gegen tierische und mikrobielle Schädlinge, wie gegenüber Insekten, Milben, pflanzenpathogenen Pilzen, Bakterien und/oder Viren sowie eine erhöhte Toleranz der Pflanzen gegen bestimmte herbizide Wirkstoffe. Als Beispiele transgener Pflanzen werden die wichtigen Kultuφflanzen, wie Getreide (Weizen, Reis), Mais, Soja, Kartoffel, Baumwolle, Raps sowie Obstpflanzen (mit den Früchten Äpfel, Birnen, Zitrusfrüchten und Weintrauben) erwähnt, wobei Mais, Soja, Kartoffel, Baumwolle und Raps besonders hervorgehoben werden.The preferred transgenic (genetically engineered) plants or plant cultivars to be treated according to the invention include all plants which, by virtue of the genetic engineering modification, have received genetic material which gives these plants particularly advantageous, valuable properties (“traits”). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering performance, easier harvesting, accelerated ripening, higher harvest yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products. Further and particularly highlighted examples of such properties are an increased defense of the plants against animal and microbial pests, such as against insects, mites, phytopathogenic fungi, bacteria and / or viruses, and an increased tolerance of the plants to certain herbicidal active ingredients. Examples of transgenic plants are the important cultivated plants, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybeans, potatoes and cotton and rapeseed are highlighted.
Als Eigenschaften ("Traits") werden besonders hervorgehoben die erhöhte Abwehr der Pflanzen gegen Insekten durch in den Pflanzen entstehende Toxine, insbesondere solche, die durch das genetische Material aus Bacillus Thuringiensis (z.B. durch die Gene CryΙA(a), CryIA(b), CryΙA(c), CryllA, CrylllA, CιymB2, Cry9c Cry2Ab, Cry3Bb und CrylF sowie deren Kombinationen) in den Pflanzen erzeugt werden (im folgenden "Bt Pflanzen"). Als Eigenschaften ("Traits") werden weiterhin besonders hervorgehoben die erhöhte Toleranz der Pflanzen gegenüber bestimmten herbiziden Wirkstoffen, beispielsweise Imidazolinonen, Sulfonylharnstoffen, Glyphosate oder Phosphinotricin (z.B. "PAT"-Gen). Die jeweils die gewünschten Eigenschaften ("Traits") verleihenden Gene können auch in Kombinationen miteinander in den transgenen Pflanzen vorkommen. Als Beispiele für "Bt Pflanzen" seien Maissorten,The traits are particularly emphasized as the increased defense of the plants against insects by toxins which arise in the plants, in particular those which are caused by the genetic material from Bacillus thuringiensis (for example by the genes CryΙA (a), CryIA (b), CryΙA (c), CryllA, CrylllA, CιymB2, Cry9c, Cry2Ab, Cry3Bb and CrylF and their combinations) are produced in the plants (hereinafter "Bt plants"). As properties ("traits") continue to be special emphasized the increased tolerance of the plants to certain herbicidal active ingredients, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene). The genes imparting the desired properties (“traits”) can also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are maize varieties,
Baumwollsorten, Sojasorten und Kartoffelsorten genannt, die unter den Handelsbezeichnungen YIELD GARD® (z.B. Mais, Baumwolle, Soja), KnockOut® (z.B. Mais), StarLink® (z.B. Mais), Bollgard® (Baumwolle), Nucotn® (Baumwolle) und NewLeaf® (Kartoffel) vertrieben werden. Als Beispiele für Herbizid tolerante Pflan- zen seien Maissorten, Baumwollsorten und Sojasorten genannt, die unter den Handelsbezeichnungen Roundup Ready® (Toleranz gegen Glyphosate z.B. Mais, Baumwolle, Soja), Liberty Link® (Toleranz gegen Phosphinotricin, z.B. Raps), IMI® (Toleranz gegen Imidazolinone) und STS® (Toleranz gegen Sulfonyl- harnstoffe z.B. Mais) vertrieben werden. Als Herbizid resistente (konventionell auf Herbizid-Toleranz gezüchtete) Pflanzen seien auch die unter der BezeichnungCotton varieties, soy varieties and potato varieties named under the trade names YIELD GARD® (e.g. corn, cotton, soy), KnockOut® (e.g. corn), StarLink® (e.g. corn), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf ® (potato) are sold. Examples of herbicide-tolerant plants are corn varieties, cotton varieties and soy varieties which are marketed under the trade names Roundup Ready® (tolerance against glyphosate, e.g. maize, cotton, soy), Liberty Link® (tolerance against phosphinotricin, e.g. rapeseed), IMI® ( Tolerance to imidazolinones) and STS® (tolerance to sulfonylureas such as corn). Herbicide-resistant plants (conventionally bred to herbicide tolerance) are also those under the name
Clearfield® vertriebenen Sorten (z.B. Mais) erwähnt. Selbstverständlich gelten diese Aussagen auch für in der Zukunft entwickelte bzw. zukünftig auf den Markt kommende Pflanzensorten mit diesen oder zukünftig entwickelten genetischen Eigenschaften ("Traits").Clearfield® sold varieties (e.g. maize) mentioned. Of course, these statements also apply to plant varieties developed in the future or coming onto the market in the future with these or future-developed genetic properties ("traits").
Die aufgeführten Pflanzen können besonders vorteilhaft erfindungsgemäß mit den erfindungsgemäßen Wirkstoffmischungen behandelt werden. Die bei den Mischungen oben angegebenen Vorzugsbereiche gelten auch für die Behandlung dieser Pflanzen. Besonders hervorgehoben sei die Pflanzenbehandlung mit den im vorliegenden Text speziell aufgeführten Mischungen.The plants listed can be treated particularly advantageously according to the invention with the active compound mixtures according to the invention. The preferred ranges given for the mixtures above also apply to the treatment of these plants. Plant treatment with the mixtures specifically listed in the present text should be particularly emphasized.
Ein synergistischer Effekt liegt bei Insektiziden, Fungiziden und Akariziden immer dann vor, wenn die Wirkung der Wirkstoffkombinationen größer ist als die Summe der Wirkungen der einzeln applizierten Wirkstoffe. Die zu erwartende Wirkung für eine gegebene Kombination zweier Wirkstoffe kann (vgl. Colby, S.R., "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 15, Seiten 20-22, 1967) wie folgt berechnet werden:Insecticides, fungicides and acaricides always have a synergistic effect when the effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients. The expected effect for a given combination of two active substances can be calculated as follows (cf. Colby, SR, "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 15, pages 20-22, 1967):
WennIf
X den Wirkungsgrad, ausgedrückt in %> der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes A in einer Konzentration von m ppm,X the efficiency, expressed in%> of the untreated control, when using the active ingredient A in a concentration of m ppm,
Y den Wirkungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes B in einer Konzentration von n ppm,Y the efficiency, expressed in% of the untreated control, when using the active ingredient B in a concentration of n ppm,
E den erwarteten Wirkungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes A und B in einer Konzentration von m und n ppm bedeutet,E means the expected efficiency, expressed in% of the untreated control, when using the active compound A and B in a concentration of m and n ppm,
dann ist X - Ythen X - Y
E = X + YE = X + Y
100100
Ist die tatsächliche insektizide fungizide und akarizide Wirkung größer als berechnet, so ist die Kombination in ihrer Wirkung überadditiv, d.h. es liegt ein synergistischerIf the actual insecticidal fungicidal and acaricidal activity is greater than calculated, the effect of the combination is super-additive, i.e. it is a synergistic
Effekt vor. In diesem Fall muss der tatsächlich beobachtete Wirkungsgrad größer sein als der aus der oben angeführten Formel errechnete Wert für den erwarteten Wirkungsgrad (E). Beispiel AEffect before. In this case, the actually observed efficiency must be greater than the value for the expected efficiency (E) calculated from the above formula. Example A
Grenzkonzentrations-Test / Bodeninsekten - Behandlung transgener PflanzenLimit concentration test / soil insects - treatment of transgenic plants
Testinsekt: Diabrotica balteata - Larven im BodenTest insect: Diabrotica balteata - larvae in the soil
Lösungsmittel: 7 Gewichtsteile AcetonSolvent: 7 parts by weight of acetone
Emulgator: 1 Gewichtsteil AlkylarylpolyglykoletherEmulsifier: 1 part by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit der angegebenen Menge Lösungsmittel, gibt die angegebene Menge Emulgator zu und verdünnt das Konzentrat mit Wasser auf die gewünschte Konzentration.To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent, the stated amount of emulsifier is added and the concentrate is diluted with water to the desired concentration.
Die Wirkstoffzubereitung wird auf den Boden gegossen. Dabei spielt die Konzentration des Wirkstoffs in der Zubereitung praktisch keine Rolle, entscheidend ist allein die Wirkstoffgewichtsmenge pro Volumeneinheit Boden, welche in ppm (mg/1) angegeben wird. Man füllt den Boden in 0,25 1 Töpfe und läßt diese bei 20°C stehen.The active ingredient preparation is poured onto the floor. The concentration of the active ingredient in the preparation is practically irrelevant, the only decisive factor is the amount of active ingredient per unit volume of soil, which is given in ppm (mg / 1). The bottom is filled in 0.25 l pots and left at 20 ° C.
Sofort nach dem Ansatz werden je Topf 5 vorgekeimte Maiskörner der Sorte YIELDImmediately after the preparation, 5 pre-germinated maize kernels of the YIELD variety are added to each pot
GUARD (Warenzeichen von Monsanto Comp., USA) gelegt. Nach 2 Tagen werden in den behandelten Boden die entsprechenden Testinsekten gesetzt. Nach weiteren 7 Tagen wird der Wirkungsgrad des Wirkstoffs durch Auszählen der aufgelaufenen Maispflanzen bestimmt (1 Pflanze = 20 % Wirkung). Beispiel BGUARD (trademark of Monsanto Comp., USA). After 2 days, the appropriate test insects are placed in the treated soil. After a further 7 days, the efficiency of the active ingredient is determined by counting the maize plants that have accumulated (1 plant = 20% activity). Example B
Heliothis virescens - Test - Behandlung transgener PflanzenHeliothis virescens - test - treatment of transgenic plants
Lösungsmittel: 7 Gewichtsteile AcetonSolvent: 7 parts by weight of acetone
Emulgator : 1 Gewichtsteil AlkylarylpolyglykoletherEmulsifier: 1 part by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit der angegebenen Menge Lösungsmittel und der angegebe- nen Menge Emulgator und verdünnt das Konzentrat mit Wasser auf die gewünschteTo produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent and the stated amount of emulsifier, and the concentrate is diluted with water to the desired level
Konzentration.Concentration.
Sojatriebe (Glycine max) der Sorte Roundup Ready (Warenzeichen der Monsanto Comp. USA) werden durch Tauchen in die Wirkstoffzubereitung der gewünschten Konzentration behandelt und mit der Tabakknospenraupe Heliothis virescens besetzt, solange die Blätter noch feucht sind.Soybean shoots (Glycine max) of the Roundup Ready variety (trademark of Monsanto Comp. USA) are treated by dipping into the preparation of active compound of the desired concentration and populated with the tobacco bud caterpillar Heliothis virescens while the leaves are still moist.
Nach der gewünschten Zeit wird die Abtötung der Insekten bestimmt. After the desired time, the killing of the insects is determined.

Claims

Patentansprttche Patent claims
1. Mittel, enthaltend Mischungen aus Verbindungen der Formel (I)1. Agents containing mixtures of compounds of the formula (I)
in welcher in which
X für Halogen, Alkyl, Alkoxy, Halogenalkyl, Halogenalkoxy oder Cyano steht,X represents halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano,
W, Y und Z unabhängig voneinander für Wasserstoff, Halogen, Alkyl, Alkoxy, Halogenalkyl, Halogenalkoxy oder Cyano stehen,W, Y and Z independently represent hydrogen, halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano,
A für Wasserstoff, jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Alkoxyalkyl, gesättigtes, gegebenenfalls substituiertes Cycloalkyl steht, in welchem gegebenenfalls mindestens ein Ringatom durch ein Heteroatom ersetzt ist,A represents hydrogen, alkyl optionally substituted by halogen, alkoxyalkyl, saturated, optionally substituted cycloalkyl, in which at least one ring atom is optionally replaced by a heteroatom,
B für Wasserstoff oder Alkyl steht,B represents hydrogen or alkyl,
A und B gemeinsam mit dem Kohlenstoffatom an das sie gebunden sind, für einen gesättigten oder ungesättigten, gegebenenfalls mindestens ein Heteroatom enthaltenden unsubstituierten oder substituierten Cyclus stehen,A and B, together with the carbon atom to which they are bonded, represent a saturated or unsaturated, unsubstituted or substituted cycle optionally containing at least one heteroatom,
D für Wasserstoff oder einen gegebenenfalls substituierten Rest aus der Reihe Alkyl, Alkenyl, Alkoxyalkyl, gesättigtes Cycloalkyl steht, in welchem gegebenenfalls eines oder mehrere Ringglieder durch Hete- roatome ersetzt sind,D represents hydrogen or an optionally substituted radical from the series alkyl, alkenyl, alkoxyalkyl, saturated cycloalkyl, in in which one or more ring members are optionally replaced by heteroatoms,
A und D gemeinsam mit den Atomen an die sie gebunden sind für einen gesättigten oder ungesättigten und gegebenenfalls mindestens ein Heteroatom enthaltenden, im A,D-Teil unsubstituierten oder substituierten Cyclus stehen,A and D together with the atoms to which they are bonded represent a saturated or unsaturated cycle which optionally contains at least one heteroatom and is unsubstituted or substituted in the A, D part,
für Wasserstoff (a) oder für eine der Gruppenfor hydrogen (a) or for one of the groups
(Θ),(Θ),
steht, stands,
woπnwhere
E für ein Metallion oder ein Ammoniumion steht,E stands for a metal ion or an ammonium ion,
L für Sauerstoff oder Schwefel steht,L stands for oxygen or sulfur,
M für Sauerstoff oder Schwefel steht,M stands for oxygen or sulfur,
Rl für jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Alkenyl, Alkoxyalkyl, Alkylthioalkyl, Polyalkoxyalkyl oder gegebenenfalls durch Halogen, Alkyl oder Alkoxy substituier- tes Cycloalkyl, das durch mindestens ein Heteroatom unterbrochen sein kann, jeweils gegebenenfalls substituiertes Phenyl, Phenylalkyl, Hetaryl, Phenoxyalkyl oder Hetaryloxyalkyl steht,Rl for alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl, optionally substituted by halogen or cycloalkyl optionally substituted by halogen, alkyl or alkoxy, which may be interrupted by at least one heteroatom, in each case optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl,
R2 für jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Alkenyl, Alkoxyalkyl, Polyalkoxyalkyl oder für jeweils gegebenenfalls substituiertes Cycloalkyl, Phenyl oder Benzyl steht,R2 represents alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl optionally substituted by halogen or cycloalkyl, phenyl or benzyl optionally substituted,
R3 für gegebenenfalls durch Halogen substituiertes Alkyl oder gegebenenfalls substituiertes Phenyl steht,R 3 represents alkyl optionally substituted by halogen or optionally substituted phenyl,
R4 und R5 unabhängig voneinander für jeweils gegebenenfalls durchR4 and R5 independently of one another for each if necessary
Halogen substituiertes Alkyl, Alkoxy, Alkylamino, Dialkyl- amino, Alkylthio, Alkenylthio, Cycloalkylthio oder für jeweils gegebenenfalls substituiertes Phenyl, Benzyl, Phenoxy oder Phenylthio stehen undHalogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio or represent optionally substituted phenyl, benzyl, phenoxy or phenylthio and
R6 und R^ unabhängig voneinander für Wasserstoff, jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Cycloalkyl, Alkenyl, Alkoxy, Alkoxyalkyl, für gegebenenfalls substituiertes Phenyl, für gegebenenfalls substituiertes Benzyl oder gemeinsam mit dem N-Atom, an das sie gebunden sind, für einen gegebenenfalls durch Sauerstoff oder Schwefel unterbrochenen gegebenenfalls substituierten Ring stehenR6 and R^ independently of one another represent hydrogen, each optionally substituted by halogen, alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, optionally substituted phenyl, optionally substituted benzyl or together with the N atom to which they are bonded, for one optional an optionally substituted ring interrupted by oxygen or sulfur
und mindestens eine der nachfolgenden Verbindungenand at least one of the following compounds
[Fluquinconazol Tebuconazol Bitertanol Triadimenol Triadimefon Difenoconazol[Fluquinconazole Tebuconazole Bitertanol Triadimenol Triadimefon Difenoconazole
FlusilazolFlusilazole
ProchlorazProchloraz
PenconazolPenconazole
2-(l -Chlor-cyclopropyl)- 1 -(2-chlθφhenyl)-3-(5-mercapto-2-(l-chlorocyclopropyl)-1-(2-chlorophenyl)-3-(5-mercapto-
1 ,2,4-triazol- 1 -yl)-propan-2-ol1,2,4-triazol-1-yl)-propan-2-ol
KresoximmethylKresoximmethyl
AzoxystrobinAzoxystrobin
TrifloxystrobinTrifloxystrobin
PicoxystrobinPicoxystrobin
3- { 1 -[4-<2-Chlorphenoxy>-5-fluoφyrimid-6-yloxy)-phenyl]- 1 -(methoximino)-methyl} -5 ,6-dihydro- 1 ,4,2-dioxazin ManebManeb
PropinebPropineb
MancozebMancozeb
CaptanCaptain
Folpet (Phaltan)Folpet (Phaltane)
DichlofluanidDichlofluanide
TolylfluanidTolylfluanide
FamoxadonFamoxadone
FenamidonFenamidone
CaφropamidCarropamide
IprovalicarbIprovalicarb
ProcymidonProcymidone
VinclozolinVinclozolin
IprodionIprodione
CyprodinilCyprodinil
CyamidazosulfamidCyamidazosulfamide
1 -(3 ,5-Dimethylisoxazol-4-sulfonyl)-2-chlor-6,6-difluor-1 -(3,5-Dimethylisoxazole-4-sulfonyl)-2-chloro-6,6-difluoro-
[l,3]-dioxolo-[4,5f)benzimidazol[l,3]-dioxolo-[4,5f)benzimidazole
PyrimethanilPyrimethanil
MepanipyrimMepanipyrim
Spiroxamin ChlorothalonilSpiroxamine Chlorothalonil
Iminoctadien-triacetatIminoctadiene triacetate
FludioxonilFludioxonil
Acibenzolar-S-methyl (Bion)Acibenzolar-S-methyl (Bion)
DimetomoφhDimetomoφh
CymoxanilCymoxanil
Fosetyl-AlFosetyl-Al
PencycuronPencycuron
FenhexamidFenhexamide
ZoxamidZoxamide
CarbendazimCarbendazim
RabeidRabeid
CoratopCoratop
ChinomethionatQuinomethionate
FluazinamFluazinam
Metalaxyl-MMetalaxyl-M
MetalaxylMetalaxyl
Schwefelsulfur
Kupfercopper
SYP-L 190SYP-L 190
BAS 500FBAS 500F
2. Mittel gemäß Ansprach 1 enthaltend Verbindungen der Formel (I) in welcher2. Agents according to claim 1 containing compounds of the formula (I) in which
W für Wasserstoff, C1-C4 -Alkyl, Ci-drAlkoxy, Chlor, Brom oder Fluor steht,W represents hydrogen, C1-C4 alkyl, Ci-drAlkoxy, chlorine, bromine or fluorine,
X für CrC4-Alkyl, CrC4-Alkoxy, CrC4-Halogenalkyl, Fluor, Chlor oder Brom steht, Y und Z unabhängig voneinander für Wasserstoff, C1-C4- Alkyl, Halogen, C1-C4- Alkoxy oder C1-C4-Halogenalkyl stehen,X represents C r C 4 alkyl, C r C 4 alkoxy, C r C 4 haloalkyl, fluorine, chlorine or bromine, Y and Z independently represent hydrogen, C1-C4-alkyl, halogen, C1 - C4-alkoxy or C1- C4-haloalkyl,
A für Wasserstoff oder jeweils gegebenenfalls durch Halogen substitu- iertes d-C6-Alkyl oder C3-Cg-Cycloalkyl steht,A represents hydrogen or dC6 -alkyl or C3-Cg-cycloalkyl optionally substituted by halogen,
B für Wasserstoff, Methyl oder Ethyl steht,B represents hydrogen, methyl or ethyl,
A, B und das Kohlenstoffatom an das sie gebunden sind, für gesättigtes C3-C6-Cyclo alkyl stehen, worin gegebenenfalls ein Ringglied durchA, B and the carbon atom to which they are bonded represent saturated C 3 -C 6 -cycloalkyl, in which a ring member is optionally present
Sauerstoff oder Schwefel ersetzt ist und welches gegebenenfalls einfach oder zweifach durch C1-C4-Alkyl, Trifluormethyl oder d-C4-Al- koxy substituiert ist,oxygen or sulfur is replaced and which is optionally substituted once or twice by C 1 -C 4 alkyl, trifluoromethyl or dC 4 alkoxy,
D für Wasserstoff, jeweils gegebenenfalls durch Fluor oder Chlor substituiertes Ci-Cß- Alkyl, C3-C4-Alkenyl oder C3-C6-Cycloalkyl steht,D represents hydrogen, in each case Ci-C ß -alkyl, C 3 -C 4 -alkenyl or C 3 -C 6 -cycloalkyl optionally substituted by fluorine or chlorine,
A und D gemeinsam für gegebenenfalls durch Methyl substituiertes C3-C - Alkandiyl stehen, worin gegebenenfalls eine Methylengruppe durch Schwefel ersetzt ist,A and D together represent C 3 -C alkanediyl, optionally substituted by methyl, in which a methylene group is optionally replaced by sulfur,
G für Wasserstoff (a) oder für eine der GruppenG for hydrogen (a) or for one of the groups
O R4 OR4
^ (°), - R2 «* /S° -R3 <d>> / RR5° (e)>^ (°), - R2 « * /S ° - R3 < d >> / R R5 ° (e)>
steht, in welchen stands in which
E für ein Metallion oder ein Ammoniumion steht, L für Sauerstoff oder Schwefel steht undE stands for a metal ion or an ammonium ion, L stands for oxygen or sulfur and
M für Sauerstoff oder Schwefel steht,M stands for oxygen or sulfur,
R1 für jeweils gegebenenfalls durch Halogen substituiertes d-do-Alkyl, C2-C10-Alkenyl, C1-C4-Alkoxy-Cι-C4-alkyl, d-C4-Alkylthio-d-C4- alkyl oder gegebenenfalls durch Fluor, Chlor, d-C - Alkyl oder d-C2-Alkoxy substituiertes d-d-Cycloalkyl, R 1 for d-do-alkyl, C 2 -C 10 -alkenyl, C 1 -C 4 -alkoxy-Cι-C 4 -alkyl, dC 4 -alkylthio-dC 4 -alkyl, optionally substituted by halogen, or optionally by fluorine , chlorine, dC - alkyl or dC 2 -alkoxy substituted dd-cycloalkyl,
für gegebenenfalls durch Fluor, Chlor, Brom, Cyano, Nitro, d-C4-Al- kyl, d-C4-Alkoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl,for phenyl optionally substituted by fluorine, chlorine, bromine, cyano, nitro, dC 4 -alkyl, dC 4 -alkoxy, trifluoromethyl or trifluoromethoxy,
für jeweils gegebenenfalls durch Chlor oder Methyl substituiertes Py- ridyl oder Thienyl steht,represents pyridyl or thienyl optionally substituted by chlorine or methyl,
R2 für jeweils gegebenenfalls durch Fluor oder Chlor substituiertes d-do-Alkyl, C2-do-Alkenyl, d-d-Alkoxy-d-Q-alkyl,R 2 for d-do-alkyl, C 2 -do-alkenyl, dd-alkoxy-dQ-alkyl, each optionally substituted by fluorine or chlorine,
für gegebenenfalls durch Methyl oder Methoxy substituiertes -Cö- Cycloalkyl oderfor -C ö -cycloalkyl optionally substituted by methyl or methoxy or
für jeweils gegebenenfalls durch Fluor, Chlor, Brom, Cyano, Nitro, Cι-C4- Alkyl, d-C4-Alkoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl oder Benzyl steht,represents phenyl or benzyl optionally substituted by fluorine, chlorine, bromine, cyano, nitro, Cι-C 4 -alkyl, dC 4 -alkoxy, trifluoromethyl or trifluoromethoxy,
R für gegebenenfalls durch Fluor substituiertes d-C4-Alkyl oder für gegebenenfalls durch Fluor, Chlor, Brom, d-C4-Alkyl, d-C4-Alkoxy, Trifluormethyl, Trifluormethoxy, Cyano oder Nitro substituiertesR for dC 4 -alkyl optionally substituted by fluorine or for optionally substituted by fluorine, chlorine, bromine, dC 4 -alkyl, dC 4 -alkoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro
Phenyl steht, R4 für jeweils gegebenenfalls durch Fluor oder Chlor substituiertes d-C4-Alkyl, d-C4-Alkoxy, C1-C4-Alkylamino, C1-C4-Alkylthio oder für jeweils gegebenenfalls durch Fluor, Chlor, Brom, Nitro, Cyano, d-C4- Alkoxy, Trifluormethoxy, C1-C4-Alkylthio, C1-C4-Halogenal- kylthio, C C4-Alkyl oder Trifluormethyl substituiertes Phenyl, Phenoxy oder Phenylthio steht,phenyl stands, R 4 for dC 4 alkyl, dC 4 alkoxy, C 1 -C 4 alkylamino, C 1 -C 4 alkylthio, each optionally substituted by fluorine or chlorine, or each optionally substituted by fluorine, chlorine, bromine, nitro, cyano, dC 4 -alkoxy, trifluoromethoxy, C 1 -C 4 -alkylthio, C 1 -C 4 -haloalkylthio, CC 4 -alkyl or trifluoromethyl substituted phenyl, phenoxy or phenylthio,
R5 für Cι-C4-Alkoxy oder d-C4-Thioalkyl steht,R 5 is Cι-C 4 alkoxy or dC 4 thioalkyl,
R6 für C C6-Alkyl, C3-C6-Cycloalkyl, d-C6-Alkoxy, C3-C6-Alkenyl, C1-C4-Alkoxy-C1-C4-alkyl steht,R 6 is CC 6 alkyl, C 3 -C 6 cycloalkyl, dC 6 alkoxy, C 3 -C 6 alkenyl, C 1 -C 4 alkoxy-C 1 -C 4 alkyl,
R7 für d-d-Alkyl, C3-C6-Alkenyl oder d-C4-Alkoxy-d-C4-alkyl steht,R 7 is dd-alkyl, C 3 -C 6 -alkenyl or dC 4 -alkoxy-dC 4 -alkyl,
R und R zusammen für einen gegebenenfalls durch Methyl oder Ethyl substituierten Crd-Alkylenrest stehen, in welchem gegebenenfalls ein Kohlenstoffatom durch Sauerstoff oder Schwefel ersetzt ist.R and R together represent a Crd-alkylene radical optionally substituted by methyl or ethyl, in which a carbon atom is optionally replaced by oxygen or sulfur.
Mittel gemäß Ansprach 1 enthaltend Verbindungen der Formel (I) in welcherAgents according to claim 1 containing compounds of the formula (I) in which
W für Wasserstoff, Methyl, Ethyl, Chlor, Brom oder Methoxy steht,W stands for hydrogen, methyl, ethyl, chlorine, bromine or methoxy,
X für Chlor, Brom, Methyl, Ethyl, Propyl, i-Propyl, Methoxy, Ethoxy oder Trifluormethyl steht,X represents chlorine, bromine, methyl, ethyl, propyl, i-propyl, methoxy, ethoxy or trifluoromethyl,
Y und Z unabhängig voneinander für Wasserstoff, Fluor, Chlor, Brom, Methyl, Ethyl, Propyl, i-Propyl, Trifluormethyl oder Methoxy stehen,Y and Z independently represent hydrogen, fluorine, chlorine, bromine, methyl, ethyl, propyl, i-propyl, trifluoromethyl or methoxy,
A für Methyl, Ethyl, Propyl, i-Propyl, Butyl, i-Butyl, sec.-Butyl, tert.-A for methyl, ethyl, propyl, i-propyl, butyl, i-butyl, sec-butyl, tert.-
Butyl, Cyclopropyl, Cyclopentyl oder Cyclohexyl steht, B für Wasserstoff, Methyl oder Ethyl steht,butyl, cyclopropyl, cyclopentyl or cyclohexyl, B represents hydrogen, methyl or ethyl,
A, B und das Kohlenstoffatom an das sie gebunden sind, für gesättigtes C6- Cycloalkyl stehen, worin gegebenenfalls ein Ringglied durch Sauerstoff ersetzt ist und welches gegebenenfalls einfach durch Methyl, Ethyl, Methoxy, Ethoxy, Propoxy oder Butoxy substituiert ist,A, B and the carbon atom to which they are bonded represent saturated C 6 -cycloalkyl, in which one ring member is optionally replaced by oxygen and which is optionally simply substituted by methyl, ethyl, methoxy, ethoxy, propoxy or butoxy,
D für Wasserstoff, für Methyl, Ethyl, Propyl, i-Propyl, Butyl, i-Butyl, Allyl, Cyclopropyl, Cyclopentyl oder Cyclohexyl steht,D represents hydrogen, methyl, ethyl, propyl, i-propyl, butyl, i-butyl, allyl, cyclopropyl, cyclopentyl or cyclohexyl,
A und D gemeinsam für gegebenenfalls durch Methyl substituiertes C3-C4- Alkandiyl stehen,A and D together represent C 3 -C 4 alkanediyl optionally substituted by methyl,
G für Wasserstoff (a) oder für eine der GruppenG for hydrogen (a) or for one of the groups
<β> < β >
steht,stands,
in welchenin which
M für Sauerstoff oder Schwefel steht,M stands for oxygen or sulfur,
R1 für d-C8-Alkyl, C2-C4-Alkenyl, Methoxymethyl, Ethoxymethyl,R 1 for dC 8 -alkyl, C 2 -C 4 -alkenyl, methoxymethyl, ethoxymethyl,
Ethylthiomethyl, Cyclopropyl, Cyclopentyl oder Cyclohexyl,Ethylthiomethyl, cyclopropyl, cyclopentyl or cyclohexyl,
für gegebenenfalls durch Fluor, Chlor, Brom, Cyano, Nitro, Methyl, Ethyl, Methoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl, für jeweils gegebenenfalls durch Chlor oder Methyl substituiertes Py- ridyl oder Thienyl steht,for phenyl optionally substituted by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, methoxy, trifluoromethyl or trifluoromethoxy, represents pyridyl or thienyl optionally substituted by chlorine or methyl,
R2 für d-Cs-Alkyl, C2-C4-Alkenyl, Methoxyethyl, Ethoxyethyl oder fürR 2 for d-Cs-alkyl, C 2 -C 4 -alkenyl, methoxyethyl, ethoxyethyl or for
Phenyl oder Benzyl steht,is phenyl or benzyl,
R und R unabhängig voneinander für Methyl, Ethyl oder zusammen für einen C5-Alkylenrest stehen, in welchem die C3-Methylengruppe durch Sauerstoff ersetzt ist.R and R independently represent methyl, ethyl or together represent a C 5 -alkylene radical in which the C 3 -methylene group is replaced by oxygen.
4. Mittel gemäß Ansprach 1 enthaltend Verbindungen der Formel (I) in welcher4. Agents according to claim 1 containing compounds of the formula (I) in which
W für Wasserstoff oder Methyl steht,W stands for hydrogen or methyl,
X für Chlor, Brom oder Methyl steht,X represents chlorine, bromine or methyl,
Y und Z unabhängig voneinander für Wasserstoff, Chlor, Brom oder Methyl stehen,Y and Z independently represent hydrogen, chlorine, bromine or methyl,
A, B und das Kohlenstoffatom an das sie gebunden sind, für gesättigtes C6- Cycloalkyl stehen, in welchem gegebenenfalls ein Ringglied durch Sauerstoff ersetzt ist und welches gegebenenfalls einfach durch Methyl, Methoxy, Ethoxy, Propoxy oder Butoxy substituiert ist,A, B and the carbon atom to which they are bonded represent saturated C 6 -cycloalkyl, in which one ring member is optionally replaced by oxygen and which is optionally simply substituted by methyl, methoxy, ethoxy, propoxy or butoxy,
D für Wasserstoff steht,D stands for hydrogen,
G für Wasserstoff (a) oder für eine der GruppenG for hydrogen (a) or for one of the groups
steht, stands,
in welchenin which
M für Sauerstoff oder Schwefel steht,M stands for oxygen or sulfur,
R1 für CrCs-Alkyl, C2-C4-Alkenyl, Methoxymethyl, Ethoxymethyl, Ethylmethylthio, Cyclopropyl, Cyclopentyl, Cyclohexyl oderR 1 for CrCs-alkyl, C 2 -C 4 -alkenyl, methoxymethyl, ethoxymethyl, ethylmethylthio, cyclopropyl, cyclopentyl, cyclohexyl or
für gegebenenfalls durch Fluor, Chlor, Brom, Methyl, Methoxy, Trifluormethyl, Trifluormethoxy, Cyano oder Nitro substituiertes Phenyl,for phenyl optionally substituted by fluorine, chlorine, bromine, methyl, methoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro,
für jeweils gegebenenfalls durch Chlor oder Methyl substituiertes Py- ridyl oder Thienyl steht,represents pyridyl or thienyl optionally substituted by chlorine or methyl,
R2 für C]-C8- Alkyl, C2-C4-Alkenyl, Methoxyethyl, Ethoxyethyl, Phenyl oder Benzyl steht,R 2 represents C]-C 8 -alkyl, C 2 -C 4 -alkenyl, methoxyethyl, ethoxyethyl, phenyl or benzyl,
R und R unabhängig voneinander für Methyl, Ethyl oder zusammen für einen C5-Alkylenrest stehen, in welchen die C3-Methylengrappe durch Sauerstoff ersetzt ist.R and R independently represent methyl, ethyl or together represent a C 5 -alkylene radical in which the C 3 -methylene group is replaced by oxygen.
5. Mittel gemäß Ansprach 1 enthaltend Verbindungen der Formel (I)5. Agents according to claim 1 containing compounds of the formula (I)
in welcher W, X, Y, Z, R und G die in der Tabelle angegebenen Bedeutungen haben.in which W, X, Y, Z, R and G have the meanings given in the table.
Verwendung von Mischungen, wie in Anspruch 1 definiert, zur Bekämpfung von Pilzen, Spinnenmilben und Insekten.Use of mixtures as defined in claim 1 for controlling fungi, spider mites and insects.
Verfahren zur Bekämpfung von Pilzen, Spinnmilben und Insekten, dadurch gekennzeichnet, dass man Mischungen, wie in Anspruch 1 definiert, auf Pilzen, Spinnmilben, Insekten und/oder deren Lebensraum einwirken lässt.Method for combating fungi, spider mites and insects, characterized in that mixtures as defined in claim 1 are allowed to act on fungi, spider mites, insects and/or their habitat.
Verfahren zur Herstellung fungizider, insektizider und akarizider Mittel, dadurch gekennzeichnet, dass man Mischungen, wie in Ansprach 1 definiert, mit Streckmitteln und/oder oberflächenaktiven Stoffen vermischt. Process for the production of fungicidal, insecticidal and acaricidal agents, characterized in that mixtures, as defined in address 1, are mixed with extenders and/or surface-active substances.
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