EP1322728A4 - USE OF HYDROGEN FOR REGENERATING SORBENTS OF SULFIDE OF METAL OXIDE HYDROGEN - Google Patents

USE OF HYDROGEN FOR REGENERATING SORBENTS OF SULFIDE OF METAL OXIDE HYDROGEN

Info

Publication number
EP1322728A4
EP1322728A4 EP01952851A EP01952851A EP1322728A4 EP 1322728 A4 EP1322728 A4 EP 1322728A4 EP 01952851 A EP01952851 A EP 01952851A EP 01952851 A EP01952851 A EP 01952851A EP 1322728 A4 EP1322728 A4 EP 1322728A4
Authority
EP
European Patent Office
Prior art keywords
hydrogen
metal oxide
hydrogen sulfide
sulfide sorbents
regenerate metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01952851A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1322728A1 (en
Inventor
Jingguang G Chen
Leo Dale Brown
William Chalmers Baird Jr
Gary Brice Mcvicker
Edward Stanley Ellis
Michele Sue Touvelle
Darryl Patrick Klein
David Evan William Vaughan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Publication of EP1322728A1 publication Critical patent/EP1322728A1/en
Publication of EP1322728A4 publication Critical patent/EP1322728A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/56—Use in the form of a bed

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Catalysts (AREA)
EP01952851A 2000-07-21 2001-07-19 USE OF HYDROGEN FOR REGENERATING SORBENTS OF SULFIDE OF METAL OXIDE HYDROGEN Withdrawn EP1322728A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US62086400A 2000-07-21 2000-07-21
US620864 2000-07-21
PCT/US2001/022734 WO2002008361A1 (en) 2000-07-21 2001-07-19 The use of hydrogen to regenerate metal oxide hydrogen sulfide sorbents

Publications (2)

Publication Number Publication Date
EP1322728A1 EP1322728A1 (en) 2003-07-02
EP1322728A4 true EP1322728A4 (en) 2004-10-06

Family

ID=24487726

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01952851A Withdrawn EP1322728A4 (en) 2000-07-21 2001-07-19 USE OF HYDROGEN FOR REGENERATING SORBENTS OF SULFIDE OF METAL OXIDE HYDROGEN

Country Status (6)

Country Link
EP (1) EP1322728A4 (enExample)
JP (1) JP2004504478A (enExample)
AU (1) AU2001273566A1 (enExample)
CA (1) CA2416236A1 (enExample)
NO (1) NO20030283L (enExample)
WO (1) WO2002008361A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2432205C (en) * 2000-12-22 2010-03-16 Europeenne De Retraitement De Catalyseurs Eurecat Regeneration method of heterogeneous catalysts and adsorbents
GB0115850D0 (en) 2001-06-28 2001-08-22 Isis Innovations Ltd Catalyst
US7074324B2 (en) 2002-06-05 2006-07-11 Exxonmobil Research And Engineering Company Process to remove sulfur contaminants from hydrocarbon streams
AU2008267113B2 (en) 2007-06-14 2012-11-22 Exxonmobil Upstream Research Company Process for purification of hydrocarbons

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0244243A1 (en) * 1986-05-01 1987-11-04 Exxon Research And Engineering Company removal of sulfur from process streams
US4729889A (en) * 1985-03-29 1988-03-08 California Institute Of Technology High temperature regenerative H2 S sorbents
US5925239A (en) * 1996-08-23 1999-07-20 Exxon Research And Engineering Co. Desulfurization and aromatic saturation of feedstreams containing refractory organosulfur heterocycles and aromatics
US5928498A (en) * 1996-08-23 1999-07-27 Exxon Research And Engineering Co. Desulfurization and ring opening of petroleum streams
US5935420A (en) * 1996-08-23 1999-08-10 Exxon Research And Engineering Co. Desulfurization process for refractory organosulfur heterocycles
WO2001044407A1 (en) * 1999-12-14 2001-06-21 Philips Petroleum Company Desulfurization process and novel bimetallic sorbent systems for same

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5439583A (en) * 1984-10-31 1995-08-08 Chevron Research And Technology Company Sulfur removal systems for protection of reforming crystals
US5045175A (en) * 1989-12-28 1991-09-03 Uop Separation system for C4 hydrotreater effluent having reduced hydrocarbon loss
GB9421705D0 (en) * 1994-10-27 1994-12-14 Ici Plc Purification process

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4729889A (en) * 1985-03-29 1988-03-08 California Institute Of Technology High temperature regenerative H2 S sorbents
EP0244243A1 (en) * 1986-05-01 1987-11-04 Exxon Research And Engineering Company removal of sulfur from process streams
US5925239A (en) * 1996-08-23 1999-07-20 Exxon Research And Engineering Co. Desulfurization and aromatic saturation of feedstreams containing refractory organosulfur heterocycles and aromatics
US5928498A (en) * 1996-08-23 1999-07-27 Exxon Research And Engineering Co. Desulfurization and ring opening of petroleum streams
US5935420A (en) * 1996-08-23 1999-08-10 Exxon Research And Engineering Co. Desulfurization process for refractory organosulfur heterocycles
WO2001044407A1 (en) * 1999-12-14 2001-06-21 Philips Petroleum Company Desulfurization process and novel bimetallic sorbent systems for same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO0208361A1 *

Also Published As

Publication number Publication date
NO20030283D0 (no) 2003-01-20
EP1322728A1 (en) 2003-07-02
WO2002008361A1 (en) 2002-01-31
AU2001273566A1 (en) 2002-02-05
CA2416236A1 (en) 2002-01-31
NO20030283L (no) 2003-03-18
JP2004504478A (ja) 2004-02-12

Similar Documents

Publication Publication Date Title
GB2359564B (en) Improvements in the electrolytic reduction of metal oxides
GB0012439D0 (en) Improvements to filters
IL153100A0 (en) Particulate metal oxide
EP1223095A4 (en) BODY STRUCTURE
AU8261501A (en) Cathartic composition
NO20030289D0 (no) Regenerering av hydrogensulfidsorbenter
AU2002366160A8 (en) Zinc-alkaline battery containing lambda-mn02
GB0030583D0 (en) Nerve regeneration
NO20030284L (no) Regenerering av jernbaserte hydrogensulfidsorbenter
AU3860101A (en) Utility lighter
GB0012437D0 (en) Improvements to filters
AU141436S (en) Pencil case
EP1322728A4 (en) USE OF HYDROGEN FOR REGENERATING SORBENTS OF SULFIDE OF METAL OXIDE HYDROGEN
AU9110301A (en) Compressed metal oxide composition
GB0022342D0 (en) Reduction of the electrocardiographic QT interval
GB2369073B (en) Gas scrubber with anti-corrosion device
GB0121137D0 (en) Improvements to motorbility vehicles
AU1046702A (en) New use
GB0119539D0 (en) Porous refractory body
GB0004183D0 (en) New use
TW444669U (en) Pen structure
GB0022677D0 (en) Porous refractory body
GB0019665D0 (en) Gasoline desulphurisation
GB0015382D0 (en) Particulate metal oxide
GB0015380D0 (en) Particulate metal oxide

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20030212

AK Designated contracting states

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

AX Request for extension of the european patent

Extension state: AL LT LV MK RO SI

RIN1 Information on inventor provided before grant (corrected)

Inventor name: VAUGHAN, DAVID, EVAN, WILLIAM

Inventor name: KLEIN, DARRYL, PATRICK

Inventor name: TOUVELLE, MICHELE, SUE

Inventor name: ELLIS, EDWARD, STANLEY

Inventor name: MCVICKER, GARY, BRICE

Inventor name: BAIRD, WILLIAM, CHALMERS, JR.

Inventor name: BROWN, LEO, DALE

Inventor name: CHEN, JINGGUANG, G.

A4 Supplementary search report drawn up and despatched

Effective date: 20040823

RIC1 Information provided on ipc code assigned before grant

Ipc: 7C 07C 7/00 B

Ipc: 7C 10G 45/00 B

Ipc: 7B 01J 20/00 B

Ipc: 7C 10G 45/10 B

Ipc: 7C 10G 45/08 B

Ipc: 7C 10G 45/06 B

Ipc: 7C 10G 45/04 B

Ipc: 7B 01J 38/12 B

Ipc: 7B 01J 38/10 B

Ipc: 7B 01J 38/04 B

Ipc: 7B 01J 20/34 B

Ipc: 7C 07C 7/12 A

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20041207