EP1301162A1 - Cosmetic composition comprising a starch betainate and a detergent surfactant - Google Patents

Cosmetic composition comprising a starch betainate and a detergent surfactant

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Publication number
EP1301162A1
EP1301162A1 EP01956595A EP01956595A EP1301162A1 EP 1301162 A1 EP1301162 A1 EP 1301162A1 EP 01956595 A EP01956595 A EP 01956595A EP 01956595 A EP01956595 A EP 01956595A EP 1301162 A1 EP1301162 A1 EP 1301162A1
Authority
EP
European Patent Office
Prior art keywords
alkyl
composition according
group
chosen
starch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP01956595A
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German (de)
French (fr)
Inventor
Claude Dubief
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
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Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Publication of EP1301162A1 publication Critical patent/EP1301162A1/en
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof

Definitions

  • the present invention relates to a composition for cosmetic treatment of keratin materials, in particular of the skin and hair, comprising, in a cosmetically acceptable aqueous medium, at least one starch betainate and at least one detergent surfactant, with a process for the cosmetic treatment of keratin materials and a use for washing the skin or the hair.
  • the hair is generally damaged and weakened by the action of external atmospheric agents such as light and the weather, and by mechanical or chemical treatments such as brushing, combing, bleaching, perms and / or dyes. .
  • external atmospheric agents such as light and the weather
  • mechanical or chemical treatments such as brushing, combing, bleaching, perms and / or dyes.
  • the hair is often difficult to disentangle or to comb and the hair, even abundant, hardly retains a hairstyle of good appearance due to the fact that the hair lacks vigor and nervousness.
  • conditioning agents to the hair which facilitate the disentangling and combing of wet hair, ensuring good maintenance of the hairstyle and communicating to them, after drying, the body, the swelling and elasticity.
  • cationic starches can be used which facilitate the disentangling of wet hair, which improve its softness and which, when dried, give them good properties of nervousness, hold, volume without touching or greasy appearance.
  • repeated applications of these conditioning agents cause a rough feel of the hair and sometimes a lack of shine.
  • the Applicant has surprisingly discovered that these unwanted effects can be avoided by using at least one starch betainate combined with at least one detergent surfactant.
  • starch betainates are new polymers described in patent application WO 00/15669 from the company Raisio Chemicals OY and in the article "Preparation of starch betainate: a novel cationic starch derivative". They are only known in the field of papermaking and have never been used in cosmetics.
  • the subject of the present invention is therefore a composition for the cosmetic treatment of keratin materials, and in particular of the skin and hair, comprising in a cosmetically acceptable aqueous medium, at least one starch betainate and at least one detergent surfactant.
  • Another subject of the invention consists in a cosmetic treatment process for keratin materials using the composition according to the invention.
  • composition according to the invention for washing the skin or the hair.
  • Other objects, characteristics, aspects and advantages of the invention will appear even more clearly on reading the description and the various examples which follow.
  • the composition for cosmetic treatment of keratin materials comprises, in a cosmetically acceptable aqueous medium, at least one starch betainate corresponding to the following formula:
  • St represents a polymeric structure of starch, and at least one detergent surfactant, the total amount of detergent surfactant (s) being greater than or equal to 3%. by weight relative to the total weight of the composition.
  • cosmetically acceptable aqueous medium means a medium compatible with all keratin materials such as the skin, hair, nails, eyelashes and eyebrows, lips and any other area of the body and of the face, but also of odor, of pleasant appearance and touch.
  • the starch molecules can come from all vegetable sources of starch such as, in particular corn, potato, oats, rice, tapioca, sorghum, barley or wheat. Potato starch is preferred.
  • starch betainates which can be used according to the present invention, as well as their preparation, are described in particular in the application.
  • WO 00/15669 and in the article "Preparation of starch betainate: a novel cationic starch derivative". They are prepared from natural products, namely a starch as described above and betaine.
  • the starch betainates can be used in a concentration of between 0.01 and 20% by weight, preferably between 0.05 and 10% by weight, better still between 0.1 and 5% by weight relative to the total weight. of composition.
  • the detergent surfactants can be anionic, nonionic, amphoteric surfactants or a mixture of these.
  • anionic surfactants which can be used, alone or in mixtures, in the context of the present invention, there may be mentioned in particular the salts, in particular the alkali metal salts such as the sodium salts, the ammonium salts, the salts of amines, amino alcohol salts or alkaline earth metal salts, for example, magnesium, of the following compounds: alkyl sulfates, alkyl ether sulfates, alkylamidoethersulfates, alkylaryl polyethersulfates, monoglyceride sulfates; alkylsulfonates, alkyl phosphates, alkylamidesulfonates, alkylarylsulfonates, ⁇ -olefin sulfonates, paraffin-tallow onates; alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamidesulfosuccinates; alkyl sulfoacetates;
  • C 6 -C 24 alkyl esters and of polyglycoside-carboxylic acids such as alkyl glucoside-citrates, alkyl polyglycoside-tartrates, and alkyl polyglycoside-sulfosuccinates; alkyl sulfosuccinamates, acyl isethionates and N-acyltaurates, the alkyl or acyl group of all these compounds having from 12 to 20 carbon atoms.
  • anionic surfactants which can still be used, mention may also be made of acyl lactylates, the acyl group of which contains from 8 to 20 carbon atoms.
  • uronic alkyl-D-galactoside acids and their salts as well as polyoxyalkylenated (C 6 -C 24 ) ether carboxylic acids, aryl (C 6 -C 24 ) alkyl acids 6 - C 24 ) polyoxyalkylenated ether-carboxyls, (C 6 - C 24 ) amidoether polyoxyalkylenated carboxylic acids and their salts, in particular those comprising from 2 to 50 ethylene oxide groups, and mixtures thereof.
  • anionic surfactants mentioned above, it is preferred to use, according to the invention, the salts of alkyl sulfates, of alkyl ether sulfates and of alkyl ether carboxylates, and their mixtures.
  • Non-ionic surfactants are also compounds well known per se (see in particular in this regard "Handbook of
  • Surfactants "by MR PORTER, Blackie & Son editions (Glasgow and London), 1991, pp 116-178). Thus, they can in particular be chosen from alcohols, alpha-diols, (C 1 -C 20 ) alkyl phenols or polyethoxylated, polypropoxylated or polyglycerolated fatty acids, having a fatty chain comprising, for example, from 8 to 18 carbon atoms, the number of ethylene oxide or propylene oxide groups possibly ranging from 2 to 50 and the number of glycerol groups possibly ranging from 2 to 30.
  • copolymers of ethylene and propylene oxide may also cite copolymers of ethylene and propylene oxide, condensates of ethylene and propylene oxide on fatty alcohols; polyethoxylated fatty amides preferably having from 2 to 30 moles of ethylene oxide, polyglycerolated fatty amides comprising on average 1 to 5 glycerol groups and.
  • polyethoxylated fatty amines preferably having 2 to 30 moles of ethylene oxide
  • ethoxylated sorbitan fatty acid esters having from 2 to 30 moles of ethylene oxide
  • sucrose fatty acid esters polyethylene glycol fatty acid esters, (C 6 -C 24 ) alkyl polyglycosides, N-alkyl (C 6 -C 24 ) glucamine derivatives, amine oxides such as that the oxides of alkyl (C 10 -
  • Ci 4 amines or oxides of N-acyl (C 1 oC 1 ) aminopropylmorpholine; and their mixtures.
  • alkyl (C 6 -C 2 4) polyglycosides use is preferably made of alkyl (C 6 -C 2 4) polyglycosides.
  • the amphoteric surfactants suitable in the present invention, can in particular be derivatives of secondary or tertiary aliphatic amines, in which the aliphatic group is a straight or branched chain containing from 8 to 22 carbon atoms and containing, at least one water-soluble anionic group such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group; Mention may also be made of (C 3 -C 20 ) alkyl betaines, sulfobetaines, (C 8 -C 20 ) alkyl amidoalkyl (C 6 -C 8 ) -betaines or (C 8 -C 20 ) alkyl amidoalkyl (C 6 -C 8 ) sulfobetaines
  • amine derivatives include the products commer- clauses under the name MIRANOL, as described in patents US 2,528,378 and US 2,781,354 and classified in the CTFA dictionary, 3rd edition, 1982 , under the names Amphocarboxy-glycinate and Amphocarboxypropionate of respective structures (2) and (3): R 2 -CONHCH 2 CH 2 -N + (R 3 ) (R 4 ) (CH 2 COO-) (2) in which:
  • R 2 represents an alkyl group derived from an acid R 2 -COOH present in the hydrolyzed coconut oil, a heptyl, nonyl or undecyl group,
  • R 3 represents a beta-hydroxyethyl group, and R 4 represents a carboxymethyl group
  • B represents -CH 2 CH 2 OX '
  • X ' represents the group -CH 2 CH 2 -COOH or a hydrogen atom
  • Y' represents -COOH or the group -CH 2 -CHOH-SO 3 H
  • R 2 represents an alkyl group of an acid R g -COOH present in coconut oil or in hydrolysed linseed oil, an alkyl group, in particular C 17 and its iso form, an unsaturated C 17 group .
  • cocoamphodiacetate sold under the trade name MIRANOL® C2M concentrated by the company RHODIA.
  • amphoteric surfactants use is preferably made of (C 8 -C 20 ) alkyl betaines, (C 8 -C 20 ) alkyl amidoalkyl (C 6 -C 8 ) betaines, alkylamphodiacetates and their mixtures.
  • the detergent surfactants described above can be used alone or in mixtures and their total amount is greater than or equal to 3% by weight, preferably between 3% and 30% by weight. weight, better still between 3% to 25% by weight and at best between 3% and 20% by weight relative to the total weight of the composition.
  • the cosmetically acceptable aqueous medium may consist solely of water or of a mixture of water and a cosmetically acceptable solvent such as a lower C 4 -C 4 alcohol, such as ethanol, isopropanol. , tert-butanol, n-butanol; alkylene glycols such as propylene glycol, glycol ethers.
  • a cosmetically acceptable solvent such as a lower C 4 -C 4 alcohol, such as ethanol, isopropanol. , tert-butanol, n-butanol
  • alkylene glycols such as propylene glycol, glycol ethers.
  • the cosmetic treatment composition of the invention can also comprise at least one cationic polymer different from the starch betainate above.
  • cationic polymer any polymer containing cationic groups and / or groups ionizable into cationic groups.
  • the cationic polymers which can be used in accordance with the present invention can be chosen from all those already known per se as improving the cosmetic properties of hair treated with detergent compositions, namely in particular those described in patent application EP-A-0 337 354 and in French patent applications FR-A- 2 270 846, 2 383 660, 2 598 611, 2 470 596 and 2 519 863.
  • the preferred cationic polymers are chosen from those which contain units comprising primary, secondary amino groups , tertiary and / or quaternary can either be part of the main polymer chain, or be carried by a lateral substituent directly connected thereto.
  • the cationic polymers used generally have a number average molecular mass of between 500 and 5.10 6 approximately, and preferably between 10 3 and 3.10 6 approximately.
  • cationic polymers mention may more particularly be made of polymers of the polyamine, polyaminoamide and quaternary polyammonium type. These are known products.
  • polymers of the polyamine, polyaminoamide, quaternary polyammonium type which can be used in the composition of the present invention, are those described in French patents Nos . 2 505 348 or 2 542 997.
  • R 3 identical or different, denote a hydrogen atom or a CH 3 group
  • A identical or different, represent an alkyl group, linear or branched, comprising from 1 to 6 carbon atoms, preferably from 2 to 3 carbon atoms, or a hydroxyalkyl group comprising from 1 to 4 carbon atoms;
  • R 4 , R 5 , R 6 identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl group, and preferably an alkyl group having from 1 to 6 carbon atoms;
  • R, and R 2 identical or different, represent a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms, and preferably a methyl or ethyl group;
  • X denotes an anion derived from a mineral or organic acid such as a methosulfate anion or a halide such as chloride or bromide.
  • the copolymers of family (1) can also contain one or more units deriving from comonomers which can be chosen from the family of acrylamides, methacrylamides, diacetone-acrylamides, acrylamides and methacrylamides substituted on the nitrogen atom by lower alkyl groups (Cr -C 4 ), groups derived from acrylic or methacrylic acids or their esters, from vinyllactams such as la.vinylpyrrolidone or vinylcaprolacta . me, vinyl esters.
  • Cationic cellulose derivatives such as cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, and described in particular in US Pat. No. 4,131,576, such as hydroxyalkylcelluloses, such as hydroxymethyl-, hydroxyethyl- or hydroxypropyl-celluloses grafted in particular with a salt of methacryloylethyl-trimethylammonium, of methacrylarnidopropyl-trimethylammonium, of dimethyldiallylammonium.
  • guar gums containing cationic trialkylammonium groups Use is made, for example, of guar gums modified with a salt, for example chloride, of 2,3-epoxypropyltrimethylammonium.
  • a salt for example chloride
  • Such products are marketed in particular under the trade names of JAGUAR ® Cl 3 S, JAGUAR ® C 15, JAGUAR ® C 17 or JAGUAR ® Cl 62 by the company MEYHALL.
  • Water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides can be crosslinked with an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-halide of alkyl or also with an oligomer resulting from the reaction of a bifunctional compound reactive with a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, an alkyl bis-halide, d 'an epilhalohydrin, a diepoxide or a bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 mol per amino group of the polyaminoamide; these polyaminoamide
  • Polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids, followed by alkylation with bifunctional agents Mention may be made, for example, of the adipic acid / diakylaminohydroxyalkyldialky-lene-triamine polymers in which the alkyl group contains from 1 to 4 carbon atoms and preferably denotes a methyl, ethyl, propyl group and the alkylene group comprises from 1 to 4 carbon atoms, and preferably denotes the ethylene group.
  • Such polymers are described in particular in French patent 1,583,363.
  • These derivatives include in particular polymers, adipic acid / dimethyl-diethylenetriamine sold under the name "CARTARETINE ® F, F4 or F8" by Sandoz.
  • the polymers obtained by reaction of a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group, with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 atoms of carbon.
  • the molar ratio between the polyalkylene polylamine and the dicarboxylic acid being between
  • Polymers of this type are sold in particular under the name "Hercosett ® 57” by the company Hercules Inc. or else under the name of "PD 170” or “Delsette ® 101” by the company Hercules in the case of the copolymer of adipic acid / epoxypropyl-diethylene-triamine.
  • R 12 denotes a hydrogen atom or a methyl group
  • R 10 and R u independently of one another, denote an alkyl group having from 1 to 22 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has 1 to 5 carbon atoms, a lower amidoalkyl group (Cj-), or then R 10 and R n can denote, jointly with the nitrogen atom to which they are attached, heterocyclic groups, such as piperidinyl or morpholinyl
  • Y " is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, piiosphate.
  • R 10 and R n independently of one another, preferably denote an alkyl group having from 1 to 4 carbon atoms.
  • R 13 , R 14 , R 15 and R 16 identical or different, represent aliphatic, alicyclic or arylaliphatic groups containing from 1 to 20 carbon atoms or. lower hydroxyalkylaliphatic groups, or alternatively R 13 , R 14 , R 15 and R 16 , together or separately, constitute with the nitrogen atoms to which they are attached heterocycles optionally containing a second heteroatom other than nitrogen, or alternatively R 13 , R 14 , R 15 and R 16 represent a linear or branched CC 6 ⁇ alkyl group, substituted by a nitrile, ester, acyl, amide or -CO-OR ⁇ -D or -CO group -NH-R ⁇ -D where R 17 is an alkylene group and D a quaternary ammonium group; Ai and Bj represent polymethylenic groups containing from 2 to 20 carbon atoms, which may be linear or branched, saturated or unsaturated, and which may contain,
  • X denotes an anion derived from a mineral or organic acid
  • AR 13 and R 15 can form with the two nitrogen atoms to which they are attached a piperazine ring; moreover, if A, denotes a linear alkylene or hydroxyalkylene group or branched, saturated or unsaturated, B, can also denote a group:
  • D denotes: a) a glycol residue of formula -OZO-, where Z denotes a linear or branched hydrocarbon group, or a group corresponding to one of the following formulas:
  • x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization; b) a bis-secondary diamine residue such as a piperazine derivative; c) a bis-primary diamine residue of formula -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon group, or else the divalent group -CH 2 -CH 2 -SS-CH 2 -CH 2 -; d) a ureylene group of formula -NH-CO-NH-.
  • X " is an anion such as chloride or bromide.
  • These polymers have a number average molecular weight generally between 1000 and 100,000.
  • R l 9 R 2 , R 3 and R 4 which are identical or different, denote an alkyl or hydroxyalkyl group having from 1 to 4 carbon atoms approximately, n and p are whole numbers varying from 2 to 20 approximately and, X " is an anion derived from a mineral or organic acid.
  • CFA hexadimethrin chloride
  • R 18 , R 19 , R 20 and R 21 identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, ⁇ -hydroxyethyl, ⁇ -hydroxypropyl or -CH 2 CH 2 (OCH 2 CH 2 ) group p OH, where p is equal to 0 or an integer between 1 and 6, provided that R 18 , R 19 , R 20 and R 21 do not simultaneously represent a hydrogen atom, r and s, identical or are whole numbers between 1 and 6, q is 0 or an integer between 1 and 34, X " denotes an anion such as a halide,
  • A denotes a radical of a dihalide or preferably represents -CH 2 -CH 2 -O-CH 2 -CH 2 -.
  • Patent Application EP-122 324 Such compounds are described in Patent Application EP-122 324. These include among them, for example the products "Mirapol ®
  • Quaternary polymers of vinylpyrrolidone and of vinylimidazole such as, for example, the products sold under the names Luviquat ® FC 905, FC 550 and FC 370 by the company
  • This dispersion is sold under the name Salcare ® SC 92 by Allied Colloids.
  • a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride containing approximately 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are sold under the names Salcare ® SC 95 and Salcare ® SC 96 by Allied Colloids.
  • cationic polymers which can be used in the context of the invention are cationic proteins or cationic protein hydrolysates, polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and epichlorohydrin, quaternary polyureylenes and chitin derivatives.
  • cationic polymers capable of being used in the context of the present invention, it is preferred to use quaternary cellulose ether derivatives such as the products sold under the name "JR 400" by the company UNION CARBIDE CORPORATION, cationic cyclopolymers, in particular homopolymers or copolymers of dimethyldiallyl ammonium chloride, sold under the names MERQUAT 100, MERQUAT ® 550 and MERQUAT ® S by the company CALGON, cationic polysaccharides such as guar gums modified with a salt of 2,3-epoxypropyl-trimethylammonium, quaternary polymers of vinylpyrrolidone and vinylimidazole and their mixtures.
  • quaternary cellulose ether derivatives such as the products sold under the name "JR 400" by the company UNION CARBIDE CORPORATION
  • cationic cyclopolymers in particular homopolymers or copolymers of dimethyldiallyl ammonium chlor
  • compositions according to the invention can also comprise one or more amphoteric polymers.
  • one can particularly include acrylic acid copolymers / chloride dialkyldiallylammonium such as Merquat ® 100 sold by Calgon.
  • the cationic polymer (s) can represent from 0.001% to 10% by weight, preferably from 0.005% to 5% by weight and more particularly from 0.01 to 3% by weight relative to the total weight of the final composition.
  • the pH of the compositions of the invention is between 4 and 8, preferably between 5 and 7.
  • compositions according to the invention may also contain additives such as natural or synthetic polymeric thickeners, anionic, amphoteric, zwitteronic, nonionic or cationic, associative or not, non-polymeric thickeners such as acids or electrolytes, nacrants , opacifiers, organic solvents, perfumes, mineral, vegetable and / or synthetic oils, fatty acid esters, dyes, volatile or non-volatile silicones, organomodified or not, cyclic or acyclic, branched or not, mineral or organic particles, preservatives, pH stabilizers.
  • additives such as natural or synthetic polymeric thickeners, anionic, amphoteric, zwitteronic, nonionic or cationic, associative or not, non-polymeric thickeners such as acids or electrolytes, nacrants , opacifiers, organic solvents, perfumes, mineral, vegetable and / or synthetic oils, fatty acid esters, dyes, volatile or non-vola
  • additives are present in the composition according to the invention in an amount ranging from 0 to 20% by weight relative to the total weight of the composition.
  • compositions can be in the form of fluid or thickened liquids, gels, creams, foams, W / O, O / W emulsions or multiple emulsions.
  • They can be used, for example, as shampoos, rinsed or leave-in care, deep care masks, lotions or creams for treating the scalp and skin, make-up removers.
  • the present invention also relates to a method of cosmetic treatment of keratin materials which consists in applying to the keratin materials an effective amount of a composition as described above, and optionally in rinsing after a possible pause time.
  • a method of cosmetic treatment of keratin materials which consists in applying to the keratin materials an effective amount of a composition as described above, and optionally in rinsing after a possible pause time.
  • a shampoo according to the invention was prepared from the following ingredients:
  • the hair After rinsing, the hair is soft, smooth and easy to disentangle.
  • a shampoo according to the invention was prepared from the following ingredients:
  • a shampoo according to the invention was prepared from the following ingredients:
  • the hair After rinsing, the hair is soft, smooth and easy to disentangle.

Abstract

The invention concerns a cosmetic treatment composition comprising, in a cosmetically acceptable aqueous medium, at least a starch betainate of formula (I), wherein: St represents a polymeric starch structure, and at least a detergent surfactant, the total amount of detergent being higher than 3 wt. % relative to the composition total weight. The invention also concerns a cosmetic treatment method for keratinous matter and use for washing skin and hair.

Description

COMPOSITION COSMETIQUE COMPRENANT UN BETAINATE D ' AMISON ET UN TENSIOACTIF DETERGENT COSMETIC COMPOSITION COMPRISING A HOUSEHOLD BETAINATE AND A DETERGENT SURFACTANT
La présente invention est relative à une composition de traitement cosmétique des matières kératiniques, en particulier de la peau et des cheveux, comprenant dans ..' un milieu aqueux cosmétiquement acceptable, au moins un bétaïnate d' amidon et au moins un tensioactif détergent, à un procédé de traitement cosmétique des matières kératiniques et à une utilisation pour le lavage de la peau ou des cheveux.The present invention relates to a composition for cosmetic treatment of keratin materials, in particular of the skin and hair, comprising, in a cosmetically acceptable aqueous medium, at least one starch betainate and at least one detergent surfactant, with a process for the cosmetic treatment of keratin materials and a use for washing the skin or the hair.
Les cheveux sont généralement abîmés et fragilisés par l' action des agents atmosphériques extérieurs tels que la lumière et les intem- péries, et par des traitements mécaniques ou chimiques tels que le brossage, le peignage, les décolorations, les permanentes et/ou les teintures. Il en résulte que les cheveux sont souvent difficiles à démêler ou à coiffer et les chevelures, même abondantes, conservent difficilement une coiffure de bon aspect en raison du fait que les cheveux manquent de vigueur et de nervosité.The hair is generally damaged and weakened by the action of external atmospheric agents such as light and the weather, and by mechanical or chemical treatments such as brushing, combing, bleaching, perms and / or dyes. . As a result, the hair is often difficult to disentangle or to comb and the hair, even abundant, hardly retains a hairstyle of good appearance due to the fact that the hair lacks vigor and nervousness.
Ainsi, pour remédier à cela, il est maintenant usuel d' appliquer sur les cheveux des agents de conditionnement qui facilitent le démêlage et le peignage des cheveux humides, assurant un bon maintien de la coiffure et leur communiquant, après séchage, du corps, du gonflant et de l'élasticité. Par exemple, on peut utiliser des amidons cationiques qui facilitent le démêlage des cheveux mouillés, qui en améliorent la douceur et qui leur apportent, une fois séchés, de bonnes propriétés de nervosité, de tenue, de volume sans toucher ni aspect gras. Cependant, des applications répétées de ces agents de conditionnement entraînent un toucher rêche des cheveux et parfois un manque de brillance. La demanderesse a découvert de manière surprenante que ces effets non désirés peuvent être évités en utilisant au moins un bétaïnate d'amidon associé à au moins un tensioactif détergent.Thus, to remedy this, it is now customary to apply conditioning agents to the hair which facilitate the disentangling and combing of wet hair, ensuring good maintenance of the hairstyle and communicating to them, after drying, the body, the swelling and elasticity. For example, cationic starches can be used which facilitate the disentangling of wet hair, which improve its softness and which, when dried, give them good properties of nervousness, hold, volume without touching or greasy appearance. However, repeated applications of these conditioning agents cause a rough feel of the hair and sometimes a lack of shine. The Applicant has surprisingly discovered that these unwanted effects can be avoided by using at least one starch betainate combined with at least one detergent surfactant.
Ces bétaïnates d' amidon sont de nouveaux polymères décrits dans la demande de brevet WO 00/15669 de la société Raisio Chemicals OY et dans l' article "Préparation of starch bétaïnate : a novel ca- tionic starch derivative". On ne les connaît que dans le domaine de la fabrication du papier et n' ont jamais été utilisés en cosmétique.These starch betainates are new polymers described in patent application WO 00/15669 from the company Raisio Chemicals OY and in the article "Preparation of starch betainate: a novel cationic starch derivative". They are only known in the field of papermaking and have never been used in cosmetics.
Ces nouveaux bétaïnates d' amidon sont préparés à partir de produits naturels et présentent donc une bonne biodégrabilité. Associés à des tensioactifs, ils permettent d' obtenir un démêlage et une douceur améliorés par rapport aux combinaisons d' amidons cationi- ques et de tensioactifs de l' art antérieur.These new starch betainates are prepared from natural products and therefore have good biodegradability. Associated with surfactants, they make it possible to obtain an disentangling and an improved softness compared to the combinations of cationic starches and surfactants of the prior art.
La présente invention a donc pour objet une composition de traitement cosmétique des matières kératiniques, et en particulier de la peau et des cheveux, comprenant dans un milieu aqueux cosmétiquement acceptable, au moins un bétaïnate d' amidon et au moins un tensioactif détergent.The subject of the present invention is therefore a composition for the cosmetic treatment of keratin materials, and in particular of the skin and hair, comprising in a cosmetically acceptable aqueous medium, at least one starch betainate and at least one detergent surfactant.
Un autre objet de l'invention consiste en un procédé de traitement cosmétique des matières kératiniques mettant en œuvre la composition selon l'invention.Another subject of the invention consists in a cosmetic treatment process for keratin materials using the composition according to the invention.
L'invention a encore pour objet une utilisation de la composition selon l'invention pour le lavage de la peau ou des cheveux. D'autres objets, caractéristiques, aspects et avantages de l'invention apparaîtront encore plus clairement à la lecture de la description et des divers exemples qui suivent.The subject of the invention is also a use of the composition according to the invention for washing the skin or the hair. Other objects, characteristics, aspects and advantages of the invention will appear even more clearly on reading the description and the various examples which follow.
Selon l'invention, la composition de traitement cosmétique des matières kératiniques comprend dans un milieu aqueux cosmétiquement acceptable, au moins un bétaïnate d' amidon répondant à la formule suivante : According to the invention, the composition for cosmetic treatment of keratin materials comprises, in a cosmetically acceptable aqueous medium, at least one starch betainate corresponding to the following formula:
dans laquelle St représente une structure polymère d' amidon, et au moins un tensioactif détergent, la quantité totale de tensioactif(s) détergent(s) étant supérieure ou égale à 3 % . en poids par rapport au poids total de la composition.in which St represents a polymeric structure of starch, and at least one detergent surfactant, the total amount of detergent surfactant (s) being greater than or equal to 3%. by weight relative to the total weight of the composition.
Par milieu aqueux cosmétiquement acceptable, on entend un milieu compatible avec toutes les matières kératiniques telles que la peau, les cheveux, les ongles, les cils et sourcils, les lèvres et toute autre zone du corps et du visage, mais aussi d'odeur, d'aspect et de toucher agréables.The term “cosmetically acceptable aqueous medium” means a medium compatible with all keratin materials such as the skin, hair, nails, eyelashes and eyebrows, lips and any other area of the body and of the face, but also of odor, of pleasant appearance and touch.
Les molécules d'amidon peuvent être issues de toutes les sources végétales d'amidon telles que, notamment le maïs, la pomme de terre, l'avoine., le riz, le tapioca, le sorgho, l'orge ou le blé. L'amidon de pomme de terre est préféré.The starch molecules can come from all vegetable sources of starch such as, in particular corn, potato, oats, rice, tapioca, sorghum, barley or wheat. Potato starch is preferred.
Les bétaïnates d'amidon utilisables selon la présente invention, ainsi que leur préparation, sont notamment décrits dans la demandeThe starch betainates which can be used according to the present invention, as well as their preparation, are described in particular in the application.
WO 00/15669 et dans l'article "Préparation of starch bétaïnate : a novel cationic starch derivative". Ils sont préparés à partir de produits naturels, à savoir un amidon tel que décrit ci-dessus et la bétaïne.WO 00/15669 and in the article "Preparation of starch betainate: a novel cationic starch derivative". They are prepared from natural products, namely a starch as described above and betaine.
Les bétaïnates d'amidon peuvent être utilisés en une concentration comprise entre 0,01 et 20 % en poids, de préférence entre 0,05 et 10 % en poids, mieux encore entre 0, 1 et 5 % en poids par rapport au poids total de la composition. Les tensioactifs détergents peuvent être des tensioactifs anioni- ques, non-ioniques, amphotères ou un mélange de ces derniers.The starch betainates can be used in a concentration of between 0.01 and 20% by weight, preferably between 0.05 and 10% by weight, better still between 0.1 and 5% by weight relative to the total weight. of composition. The detergent surfactants can be anionic, nonionic, amphoteric surfactants or a mixture of these.
A titre de tensioactifs anioniques utilisables, seuls ou en mélanges, dans le cadre de la présente invention, on peut citer notamment les sels, en particulier les sels de métaux alcalins tels que les sels de sodium, les sels d'ammonium, les sels d'aminés, les sels d'aminoalcools ou les sels de métaux alcalino-terreux, par exemple, de magnésium, des composés suivants : les sulfates d'alkyle, les alkyléther-sulfates, les alkylamidoéthersulfates, les alkylaryl- polyéthersulfates, les monoglycéride-sulfates ; les alkylsulfonates, les phosphates d' alkyle, les alkylamidesulfonates, les alkylarylsulfonates, les α-oléfine-sulfonates, les paraffine-suif onates ; les sulfosuccinates d' alkyle, les alkyléthersulfosuccinates, les alkylamidesulfosuccinates ; les sulfoacétates d' alkyle ; les acylsarcosinates ; et les acylglutamates, les groupes alkyle ou acyle de tous ces composas comportant de 6 à 24 atomes de carbone et le groupe aryle désignant de préférence un groupe phényle ou benzyle. On peut également utiliser les esters d'alkyle en C6-C24 et d'acides polyglycoside-carboxyliques tels que les glucoside-citrates d' alkyle, les polyglycoside-tartrates d' alkyle, et les polyglycoside-sulfosuccinates d' alkyle ; les sulfosuccinamates d' alkyle, les iséthionates d' acyle et les N-acyltaurates, le groupe alkyle ou acyle de tous ces composés comportant de 12 à 20 atomes de carbone. Parmi les tensioactifs anioniques encore utilisables, on peut également citer les lactylates d'acyle dont le groupe acyle comporte de 8 à 20 atomes de carbone.As anionic surfactants which can be used, alone or in mixtures, in the context of the present invention, there may be mentioned in particular the salts, in particular the alkali metal salts such as the sodium salts, the ammonium salts, the salts of amines, amino alcohol salts or alkaline earth metal salts, for example, magnesium, of the following compounds: alkyl sulfates, alkyl ether sulfates, alkylamidoethersulfates, alkylaryl polyethersulfates, monoglyceride sulfates; alkylsulfonates, alkyl phosphates, alkylamidesulfonates, alkylarylsulfonates, α-olefin sulfonates, paraffin-tallow onates; alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamidesulfosuccinates; alkyl sulfoacetates; acylsarcosinates; and acylglutamates, alkyl or acyl groups of all these composites containing from 6 to 24 carbon atoms and the aryl group preferably denoting a phenyl or benzyl group. It is also possible to use C 6 -C 24 alkyl esters and of polyglycoside-carboxylic acids such as alkyl glucoside-citrates, alkyl polyglycoside-tartrates, and alkyl polyglycoside-sulfosuccinates; alkyl sulfosuccinamates, acyl isethionates and N-acyltaurates, the alkyl or acyl group of all these compounds having from 12 to 20 carbon atoms. Among the anionic surfactants which can still be used, mention may also be made of acyl lactylates, the acyl group of which contains from 8 to 20 carbon atoms.
En outre, on peut encore citer les acides d'alkyl-D-galactoside uroniques et leurs sels ainsi que les acides alkyl(C6-C24)éther- carboxyliques polyoxyalkylénés, les acides alkyl(C6-C24)aryl(C6- C24)éther-carboxyliques polyoxyalkylénés, les acides alkyl(C6- C24)amidoéther carboxyliques polyoxyalkylénés et leurs sels, en particulier ceux comportant de 2 à 50 groupements oxyde d'éthylène, et leurs mélanges.In addition, mention may also be made of uronic alkyl-D-galactoside acids and their salts as well as polyoxyalkylenated (C 6 -C 24 ) ether carboxylic acids, aryl (C 6 -C 24 ) alkyl acids 6 - C 24 ) polyoxyalkylenated ether-carboxyls, (C 6 - C 24 ) amidoether polyoxyalkylenated carboxylic acids and their salts, in particular those comprising from 2 to 50 ethylene oxide groups, and mixtures thereof.
Parmi les tensioactifs anioniques cités ci-dessus, on préfère utiliser selon l'invention les sels de sulfates d'alkyle, d'alkyléther- sulfates et d'alkyléthercarboxylates, et leurs mélanges.Among the anionic surfactants mentioned above, it is preferred to use, according to the invention, the salts of alkyl sulfates, of alkyl ether sulfates and of alkyl ether carboxylates, and their mixtures.
Les agents tensioactifs non-ioniques sont, eux aussi, des com- posés bien connus en soi (voir notamment à cet égard "Handbook ofNon-ionic surfactants are also compounds well known per se (see in particular in this regard "Handbook of
Surfactants" par M.R. PORTER, éditions Blackie & Son (Glasgow and London), 1991 , pp 116-178). Ainsi, ils peuvent être notamment choisis parmi les alcools, les alpha-diols, les alkyl(C1-C20)phénols ou les acides gras polyéthoxylés, polypropoxylés ou polyglycérolés, ayant une chaîne grasse comportant, par exemple, de 8 à 18 atomes de carbone, le nombre de groupements oxyde d'éthylène ou oxyde de propylène pouvant aller notamment de 2 à 50 et le nombre de groupements glycérol pouvant aller notamment de 2 à 30. On peut également citer les copolymères d'oxyde d'éthylène et de propylène, les condensats d'oxyde d'éthylène et de propylène sur des alcools gras ; les amides gras polyéthoxylés ayant de préférence de 2 à 30 moles d'oxyde d'éthylène, les amides gras polyglycérolés comportant en moyenne 1 à 5 groupements glycérol et. en particulier 1,5 à 4 ; les aminés grasses polyéthoxylées ayant de préférence 2 à 30 moles d'oxyde d'éthylène ; les esters d'acides gras du sorbitane éthoxylés ayant de 2 à 30 moles d'oxyde d'éthylène ; les esters d'acides gras du saccharose, les esters d'acides gras du polyéthylèneglycol, les alkyl(C6-C24)polyglycosides, les dérivés de N-alkyl(C6- Ç24)glucamine, les oxydes d'aminés tels que les oxydes d'alkyl(C10-Surfactants "by MR PORTER, Blackie & Son editions (Glasgow and London), 1991, pp 116-178). Thus, they can in particular be chosen from alcohols, alpha-diols, (C 1 -C 20 ) alkyl phenols or polyethoxylated, polypropoxylated or polyglycerolated fatty acids, having a fatty chain comprising, for example, from 8 to 18 carbon atoms, the number of ethylene oxide or propylene oxide groups possibly ranging from 2 to 50 and the number of glycerol groups possibly ranging from 2 to 30. may also cite copolymers of ethylene and propylene oxide, condensates of ethylene and propylene oxide on fatty alcohols; polyethoxylated fatty amides preferably having from 2 to 30 moles of ethylene oxide, polyglycerolated fatty amides comprising on average 1 to 5 glycerol groups and. in particular 1.5 to 4; polyethoxylated fatty amines preferably having 2 to 30 moles of ethylene oxide; ethoxylated sorbitan fatty acid esters having from 2 to 30 moles of ethylene oxide; sucrose fatty acid esters, polyethylene glycol fatty acid esters, (C 6 -C 24 ) alkyl polyglycosides, N-alkyl (C 6 -C 24 ) glucamine derivatives, amine oxides such as that the oxides of alkyl (C 10 -
Ci4)amines ou les oxydes de N-acyl(C1o-C1 )aminopropylmorpholine ; et leurs mélanges.Ci 4 ) amines or oxides of N-acyl (C 1 oC 1 ) aminopropylmorpholine; and their mixtures.
Parmi les tensioactifs non-ioniques cités ci-dessus, on utilise de préférence les alkyl(C6-C24)polyglycosides. Les agents tensioactifs amphotères, convenant dans la présente invention, peuvent être notamment des dérivés d'aminés aliphatiques secondaires ou tertiaires, dans lesquels le groupe aliphatique est une chaîne linéaire ou ramifiée comportant de 8 à 22- atomes de carbone et contenant, au moins un groupe anionique hydrosolubilisant tel que, par exemple, un groupe carboxylate, sulfonate, sulfate, phosphate ou phosphonate ; on peut citer encore les alkyl(C3-C20)bétaïnes, les sulfobétaïnes, les alkyl(C8-C20)amidoalkyl(C6-Ç8)-bétaïnes ou les alkyl(C8-C20)amidoalkyl(C6-C8)sulfobétaïnes ; et leurs mélanges.Among the nonionic surfactants mentioned above, use is preferably made of alkyl (C 6 -C 2 4) polyglycosides. The amphoteric surfactants, suitable in the present invention, can in particular be derivatives of secondary or tertiary aliphatic amines, in which the aliphatic group is a straight or branched chain containing from 8 to 22 carbon atoms and containing, at least one water-soluble anionic group such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group; Mention may also be made of (C 3 -C 20 ) alkyl betaines, sulfobetaines, (C 8 -C 20 ) alkyl amidoalkyl (C 6 -C 8 ) -betaines or (C 8 -C 20 ) alkyl amidoalkyl (C 6 -C 8 ) sulfobetaines; and their mixtures.
Parmi les dérivés d'aminés, on peut citer les produits commer- clauses sous la dénomination MIRANOL®, tels que décrits dans les brevets US-2 528 378 et US-2 781 354 et classés dans le dictionnaire CTFA, 3ème édition, 1982, sous les dénominations Amphocarboxy- glycinate et Amphocarboxypropionate de structures respectives (2) et (3) : R2-CONHCH2CH2-N+(R3)(R4)(CH2COO-) (2) dans laquelle :Among the amine derivatives include the products commer- clauses under the name MIRANOL, as described in patents US 2,528,378 and US 2,781,354 and classified in the CTFA dictionary, 3rd edition, 1982 , under the names Amphocarboxy-glycinate and Amphocarboxypropionate of respective structures (2) and (3): R 2 -CONHCH 2 CH 2 -N + (R 3 ) (R 4 ) (CH 2 COO-) (2) in which:
R2 représente un groupe alkyle dérivé d'un acide R2-COOH présent dans l'huile de coprah hydrolysée, un groupe heptyle, nonyle ou undécyle,R 2 represents an alkyl group derived from an acid R 2 -COOH present in the hydrolyzed coconut oil, a heptyl, nonyl or undecyl group,
R3 représente un groupe bêta-hydroxyéthyle, et R4 représente un groupe carboxyméthyle ; etR 3 represents a beta-hydroxyethyl group, and R 4 represents a carboxymethyl group; and
R2.-CONHCH2CH2-N(B)(C) (3) dans laquelle :R 2. -CONHCH 2 CH 2 -N (B) (C) (3) in which:
B représente -CH2CH2OX', C représente -(CH2)Z-Y', avec z = 1 ou 2,B represents -CH 2 CH 2 OX ', C represents - (CH 2 ) Z -Y', with z = 1 or 2,
X' représente le groupe -CH2CH2-COOH ou un atome d'hydrogène, Y' représente -COOH ou le groupe -CH2-CHOH-SO3H,X 'represents the group -CH 2 CH 2 -COOH or a hydrogen atom, Y' represents -COOH or the group -CH 2 -CHOH-SO 3 H,
R2. représente un groupe alkyle d'un acide Rg -COOH présent dans l'huile de coprah ou dans l'huile de lin hydrolysée, un groupe alkyle, notamment en C17 et sa forme iso, un groupe en C17 insaturé.R 2 . represents an alkyl group of an acid R g -COOH present in coconut oil or in hydrolysed linseed oil, an alkyl group, in particular C 17 and its iso form, an unsaturated C 17 group .
Ces composés sont classés dans le dictionnaire CTFA, 5ème édition, 1993 , sous les dénominations cocoamphodiacétate de disodium, lauroamphodiacétate de disodium, caprylamphodiacétate de disodium, capryloamphodiacétate de disodium, cocoamphodipropionate de disodium, lauroamphodipropionate de disodium, caprylampho- dipropionate de disodium, capryloamphodipropionate de disodium, acide lauroamphodipropionique, acide cocoamphodipropionique.These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names disodium cocoamphodiacetate, disodium lauroamphodiacetate, disodium caprylamphodiacetate, disodium capryloamphodiacetate, disodium cocoamphodipropionate, disodium lauroamphodipropionate, capryl disodium propopropate , lauroamphodipropionic acid, cocoamphodipropionic acid.
A titre d'exemple, on peut citer le cocoamphodiacétate commercialisé sous la dénomination commerciale MIRANOL® C2M concentré par la société RHODIA.By way of example, mention may be made of cocoamphodiacetate sold under the trade name MIRANOL® C2M concentrated by the company RHODIA.
Parmi les tensioactifs amphotères, on utilise de préférence les alkyl(C8-C20)bétaïnes, les alkyl(C8-C20)amidoalkyl(C6-C8)bétaïnes, les alkylamphodiacétates et leurs mélanges.Among the amphoteric surfactants, use is preferably made of (C 8 -C 20 ) alkyl betaines, (C 8 -C 20 ) alkyl amidoalkyl (C 6 -C 8 ) betaines, alkylamphodiacetates and their mixtures.
Les tensioactifs détergents décrits ci-dessus peuvent être utilisés seuls ou en mélanges et leur quantité totale est supérieure ou égale à 3 % en poids, de préférence comprise entre 3 % et 30 % en poids, mieux encore entre 3 % à 25 % en poids et au mieux entre 3 % et 20 % en poids par rapport au poids total de la composition.The detergent surfactants described above can be used alone or in mixtures and their total amount is greater than or equal to 3% by weight, preferably between 3% and 30% by weight. weight, better still between 3% to 25% by weight and at best between 3% and 20% by weight relative to the total weight of the composition.
Le milieu aqueux cosmétiquement acceptable peut être constitué uniquement par de l'eau ou par un mélange d'eau et d'un solvant cosmétiquement acceptable tel qu'un alcool inférieur en C, -C4, tel que l'éthanol, l'isopropanol, le tertio-butanol, le n-butanol ; les alkylèneglycols comme le propylèneglycol, les éthers de glycol.The cosmetically acceptable aqueous medium may consist solely of water or of a mixture of water and a cosmetically acceptable solvent such as a lower C 4 -C 4 alcohol, such as ethanol, isopropanol. , tert-butanol, n-butanol; alkylene glycols such as propylene glycol, glycol ethers.
La composition de traitement cosmétique de l'invention peut comprendre en outre au moins un polymère cationique différent du bétaïnate d'amidon ci-dessus.The cosmetic treatment composition of the invention can also comprise at least one cationic polymer different from the starch betainate above.
Par polymère cationique, on entend tout polymère contenant des groupes cationiques et/ou des groupes ionisables en groupes cationiques.By cationic polymer is meant any polymer containing cationic groups and / or groups ionizable into cationic groups.
Les polymères cationiques utilisables conformément à la présente invention peuvent être choisis parmi tous ceux déj à connus en soi comme améliorant les propriétés cosmétiques des cheveux traités par des compositions détergentes, à savoir notamment ceux décrits dans la demande de brevet EP-A-0 337 354 et dans les demandes de brevets français FR-A- 2 270 846, 2 383 660, 2 598 611 , 2 470 596 et 2 519 863. Les polymères cationiques préférés sont choisis parmi ceux qui contiennent des motifs comportant des groupements aminés primaires, secondaires, tertiaires et/ou quaternaires pouvant soit faire partie de la chaîne principale polymère, soit être portés par un substituant latéral directement relié à celle-ci. Les polymères cationiques utilisés ont généralement une masse moléculaire moyenne en nombre comprise entre 500 et 5.106 environ, et de préférence comprise entre 103 et 3.106 environ.The cationic polymers which can be used in accordance with the present invention can be chosen from all those already known per se as improving the cosmetic properties of hair treated with detergent compositions, namely in particular those described in patent application EP-A-0 337 354 and in French patent applications FR-A- 2 270 846, 2 383 660, 2 598 611, 2 470 596 and 2 519 863. The preferred cationic polymers are chosen from those which contain units comprising primary, secondary amino groups , tertiary and / or quaternary can either be part of the main polymer chain, or be carried by a lateral substituent directly connected thereto. The cationic polymers used generally have a number average molecular mass of between 500 and 5.10 6 approximately, and preferably between 10 3 and 3.10 6 approximately.
Parmi les polymères cationiques, on peut citer plus particulièrement les polymères du type polyamine, polyaminoamide et polyammonium quaternaire. Ce sont des produits connus.Among the cationic polymers, mention may more particularly be made of polymers of the polyamine, polyaminoamide and quaternary polyammonium type. These are known products.
Les polymères du type polyamine, polyaminoamide, polyammonium quaternaire, que l' on peut utiliser dans la composition de la présente invention, sont ceux décrits dans les brevets français nos 2 505 348 ou 2 542 997. Parmi ces polymères, on peut citer : (1) les homopolymères ou copolymères dérivés d'esters ou d'amides acryliques ou méthacryliques et comportant au moins un des motifs de formules suivantes:The polymers of the polyamine, polyaminoamide, quaternary polyammonium type, which can be used in the composition of the present invention, are those described in French patents Nos . 2 505 348 or 2 542 997. Among these polymers, mention may be made of: (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the units of the following formulas:
dans lesquelles: R3, identiques ou différents, désignent un atome d'hydrogène ou un groupe CH3 ;in which: R 3 , identical or different, denote a hydrogen atom or a CH 3 group;
A, identiques ou différents, représentent un groupe alkyle, linéaire ou ramifié, comportant de 1 à 6 atomes de carbone, de préférence de 2 ou 3 atomes de carbone, ou un groupe hydroxyalkyle comportant de 1 à 4 atomes de carbone ; R4, R5, R6, identiques ou différents, représentent un groupe alkyle ayant de 1 à 18 atomes de carbone ou un groupe benzyle, et de préférence un groupe alkyle ayant de 1 à 6 atomes de carbone;A, identical or different, represent an alkyl group, linear or branched, comprising from 1 to 6 carbon atoms, preferably from 2 to 3 carbon atoms, or a hydroxyalkyl group comprising from 1 to 4 carbon atoms; R 4 , R 5 , R 6 , identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl group, and preferably an alkyl group having from 1 to 6 carbon atoms;
R, et R2, identiques ou différents, représentent un atome d'hydrogène ou un groupe alkyle ayant de 1 à 6 atomes de carbone, et de préférence un groupe méthyle ou éthyle;R, and R 2 , identical or different, represent a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms, and preferably a methyl or ethyl group;
X désigne un anion dérivé d'un acide minéral ou organique tel qu'un anion méthosulfate ou un halogénure comme le chlorure ou le bromure. Les copolymères de la famille (1) peuvent contenir en outre un ou plusieurs motifs dérivant de comonomères pouvant être choisis dans la famille des acrylamides, méthacrylamides, diacétone-acrylamides, acrylamides et méthacrylamides substitués sur l'atome d'azote par des groupes alkyle inférieur (Cr -C4), des groupes dérivés des acides acryliques ou méthacryliques ou de leurs esters, de vinyllactames tels que la.vinylpyrrolidone ou le vinylcaprolacta.me, d'esters vinyliques.X denotes an anion derived from a mineral or organic acid such as a methosulfate anion or a halide such as chloride or bromide. The copolymers of family (1) can also contain one or more units deriving from comonomers which can be chosen from the family of acrylamides, methacrylamides, diacetone-acrylamides, acrylamides and methacrylamides substituted on the nitrogen atom by lower alkyl groups (Cr -C 4 ), groups derived from acrylic or methacrylic acids or their esters, from vinyllactams such as la.vinylpyrrolidone or vinylcaprolacta . me, vinyl esters.
Ainsi, parmi ces copolymères de la famille (1), on peut citer :Thus, among these copolymers of family (1), there may be mentioned:
- les copolymères d'acrylamide et de méthacrylate de diméthyl- aminoéthyle quaternisé au sulfate de diméthyle ou avec un halogénure de diméthyle, tels que celui vendu sous la dénomination HERCOFLOC® par la société HERCULES,- copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulfate or with a dimethyl halide, such as that sold under the name HERCOFLOC ® by the company Hercules;
- les copolymères d'acrylamide et de chlorure de méthacryloyl- oxyéthyltriméthylammonium décrits, par exemple, dans la demande de brevet EP-A-080976 et vendus sous la dénomination BINAQUAT® P 100 par la société CIBA GEIGY,- copolymers of acrylamide and methacryloyl chloride oxyéthyltriméthylammonium described, for example, in EP-A-080976 and sold under the name BINAQUAT ® P 100 by the company Ciba Geigy,
- le copolymère d'acrylamide et de méthosulfate de méthacryloyl- oxyéthyltriméthylammonium vendu sous la dénomination RETEN® par la société HERCULES,- the copolymer of acrylamide and methacryloyl oxyéthyltriméthylammonium methosulfate sold under the name Reten ® by Hercules,
- les copolymères vinylpyrrolidone/acrylate ou méthacrylate de dialkylaminoalkyle quaternisés ou non, tels que les produits vendus sous la dénomination "GAFQUAT® " par la société ISP comme, par exemple, "GAFQUAT® 734" ou "GAFQUAT® 755 " , ou bien les produits dénommés "COPOLYMER 845, 958 et 937". Ces polymères sont décrits en détail dans les brevets français 2 077 143 et 2 393 573, - les terpolymères méthacrylate de diméthylaminoéthyle/ vinyl- caprolactame/vinylpyrrolidone tels que le produit vendu sous la dénomination GAFFIX® VC 713 par la société ISP,- vinylpyrrolidone / acrylate or dialkylaminoalkyl methacrylate copolymers, quaternized or not, such as the products sold under the name "GAFQUAT ® " by the company ISP such as, for example, "GAFQUAT ® 734" or "GAFQUAT ® 755", or else products called "COPOLYMER 845, 958 and 937". These polymers are described in detail in French patents 2,077,143 and 2,393,573, - the dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone such as the product sold under the name GAFFIX ® VC 713 by ISP,
- les copolymères vinylpyrrolidone/méthacrylamidopropyl-di- méthylamine commercialisés notamment sous la dénomination- vinylpyrrolidone / methacrylamidopropyl-dimethylamine copolymers sold in particular under the name
STYLEZE® CC 10 par ISP, etSTYLEZE ® CC 10 by ISP, and
- les copolymères vinylpyrrolidone/méthacrylamide de diméthyl- aminopropyle quaternisé, tels que le produit vendu sous la dénomination "GAFQUAT® HS 100" par la société ISP. (2) Les dérivés d'éthers de cellulose comportant des groupements ammonium quaternaires décrits dans le brevet français 1 492 597, et en particulier les polymères commercialisés sous les dénominations "JR" (JR 400, JR 125, JR 30M) ou "LR" (LR 400, LR 30M) par la Société Union Carbide Corporation. Ces polymères sont également définis dans le dictionnaire CTFA comme des ammoniums quaternaires d'hydroxyéthylcellulose ayant réagi avec un époxyde substitué par un groupement triméthylammonium.- the vinylpyrrolidone / methacrylamide dimethylaminopropyl quaternized copolymers, such as the product sold under the name "GAFQUAT ® HS 100" by the company ISP. (2) Derivatives of cellulose ethers comprising quaternary ammonium groups described in French patent 1 492 597, and in particular the polymers marketed under the names "JR" (JR 400, JR 125, JR 30M) or "LR" (LR 400, LR 30M) by the Union Carbide Corporation. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose having reacted with an epoxide substituted by a trimethylammonium group.
(3) Les dérivés de cellulose cationiques tels que les copolymères de cellulose ou les dérivés de cellulose greffés avec un monomère hydrosoluble d'ammonium quaternaire, et décrits notamment dans le brevet US 4 131 576, tels que les hydroxyalkylcelluloses, comme les hydroxyméthyl-, hydroxyéthyl- ou hydroxypropyl-celluloses greffées notamment avec un sel de méthacryloyléthyl-triméthylammonium, de méthacrylarnidopropyl-triméthylammonium, de diméthyldiallylammo- nium.(3) Cationic cellulose derivatives such as cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, and described in particular in US Pat. No. 4,131,576, such as hydroxyalkylcelluloses, such as hydroxymethyl-, hydroxyethyl- or hydroxypropyl-celluloses grafted in particular with a salt of methacryloylethyl-trimethylammonium, of methacrylarnidopropyl-trimethylammonium, of dimethyldiallylammonium.
Les produits commercialisés répondant à cette définition sont plus particulièrement les produits vendus sous la dénomination "Celquat® L 200" et "Celquat® H 100" par la Société National Starch.The marketed products meeting this definition are more particularly the products sold under the name "Celquat ® L 200" and "Celquat ® H 100" by the National Starch Company.
(4) Les polysaccharides cationiques décrits plus particulièrement dans les brevets US 3 589 578 et 4 031 307 tels que les gommes de guar contenant des groupements cationiques trialkylammonium. On utilise, par exemple, des gommes de guar modifiées par un sel, par exemple le chlorure, de 2,3-époxypropyltriméthylammonium. De tels produits sont commercialisés notamment sous les dénominations commerciales de JAGUAR® Cl 3 S, JAGUAR® C 15, JAGUAR® C 17 ou JAGUAR® Cl 62 par la société MEYHALL.(4) The cationic polysaccharides described more particularly in US patents 3,589,578 and 4,031,307 such as guar gums containing cationic trialkylammonium groups. Use is made, for example, of guar gums modified with a salt, for example chloride, of 2,3-epoxypropyltrimethylammonium. Such products are marketed in particular under the trade names of JAGUAR ® Cl 3 S, JAGUAR ® C 15, JAGUAR ® C 17 or JAGUAR ® Cl 62 by the company MEYHALL.
(5) Les polymères constitués de motifs pipérazinyle et de groupes divalents alkylène ou hydroxyalkylène à chaînes droites ou ramifiées, éventuellement interrompues par des atomes d'oxygène, de soufre, d'azote ou par des cycles aromatiques ou hétérocycliques, ainsi que les produits d'oxydation et/ou de quaternisation de ces polymères. De tels polymères sont notamment décrits dans les brevets français 2 162 025 et 2 280 361.(5) Polymers consisting of piperazinyl units and divalent alkylene or hydroxyalkylene groups with straight or branched chains, optionally interrupted by oxygen, sulfur, nitrogen atoms or by aromatic or heterocyclic rings, as well as the products of oxidation and / or quaternization of these polymers. Such polymers are described in particular in French patents 2 162 025 and 2 280 361.
(6) Les polyaminoamidés solubles dans l'eau, préparés en particulier par polycondensation d'un composé acide avec une polyamine ; ces polyaminoamidés peuvent être réticulés par une épihalohydrine, un diépoxyde, un dianhydride, un dianhydride non saturé, un dérivé bis- insaturé, une bis-halohydrine, un bis-azétidinium, une bis- haloacyldiamine, un bis-halogénure d'alkyle ou encore par un oligomère résultant de la réaction d'un composé bifonctionnel réactif vis-à-vis d'une bis-halohydrine, d'un bis-azétidinium, d'une bis-haloacyldiamine, d'un bis-halogénure d'alkyle, d'une épilhalohydrine, d'un diépoxyde ou d'un dérivé bis-insaturé ; l'agent réticulant étant utilisé dans des proportions allant de 0,025 à 0,35 mole par groupement aminé du polyaminoamide ; ces polyaminoamidés peuvent être alkylés ou s'ils comportent une ou plusieurs fonctions aminés tertiaires, quaternisées. De tels polymères sont notamment décrits dans les brevets français 2 252 840 et 2 368 508.(6) Water-soluble polyaminoamides, prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides can be crosslinked with an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-halide of alkyl or also with an oligomer resulting from the reaction of a bifunctional compound reactive with a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, an alkyl bis-halide, d 'an epilhalohydrin, a diepoxide or a bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 mol per amino group of the polyaminoamide; these polyaminoamides can be alkylated or, if they contain one or more tertiary, quaternized amine functions. Such polymers are described in particular in French patents 2 252 840 and 2 368 508.
(7) Les dérivés de polyaminoamidés résultant de la condensation de polyalkylènes-polyamines avec des acides polycarboxyliques, suivie d'une alkylation par des agents bifonctionnels. On peut citer, par exemple, les polymères acide adipique/diakylaminohydroxyalkyldialky- lène-triamine dans lesquels le groupe alkyle comporte de 1 à 4 atomes de carbone et désigne de préférence un groupe méthyle, éthyle, propyle, et le groupe alkylène comporte de 1 à 4 atomes de carbone, et désigne de préférence le groupe éthylène. De tels polymères sont notamment décrits dans le brevet français 1 583 363. Parmi ces dérivés, on peut citer plus particulièrement les polymères, acide adipique/diméthylaminohydroxypropyl-diéthylène- triamine vendus sous la dénomination "Cartaretine® F, F4 ou F8 " par la société Sandoz. (8) Les polymères obtenus par réaction d'une polyalkylène-polyamine comportant deux groupements aminé primaire et au moins un groupement aminé secondaire, avec un acide dicarboxylique choisi parmi l'acide diglycolique et les acides dicarboxyliques aliphatiques saturés ayant de 3 à 8 atomes de carbone. Le rapport molaire entre la polyalkylène-polylamine et l'acide dicarboxylique étant compris entre(7) Polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids, followed by alkylation with bifunctional agents. Mention may be made, for example, of the adipic acid / diakylaminohydroxyalkyldialky-lene-triamine polymers in which the alkyl group contains from 1 to 4 carbon atoms and preferably denotes a methyl, ethyl, propyl group and the alkylene group comprises from 1 to 4 carbon atoms, and preferably denotes the ethylene group. Such polymers are described in particular in French patent 1,583,363. These derivatives include in particular polymers, adipic acid / dimethyl-diethylenetriamine sold under the name "CARTARETINE ® F, F4 or F8" by Sandoz. (8) The polymers obtained by reaction of a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group, with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 atoms of carbon. The molar ratio between the polyalkylene polylamine and the dicarboxylic acid being between
0,8 : 1 et 1,4 : 1 ; le polyaminoamide en résultant étant amené à réagir avec l'épichlorhydrine dans un rapport molaire d'épichlorhydrine par rapport au groupement aminé secondaire du polyaminoamide compris entre 0,5 : 1 et 1,8 : 1. De tels polymères sont notamment décrits dans les brevets américains 3 227 615 et 2 961 347.0.8: 1 and 1.4: 1; the resulting polyaminoamide being reacted with epichlorohydrin in a molar ratio of epichlorohydrin relative to the secondary amino group of the polyaminoamide of between 0.5: 1 and 1.8: 1. Such polymers are described in particular in the patents 3,227,615 and 2,961,347.
Des polymères de ce type sont en particulier commercialisés sous la dénomination "Hercosett® 57 " par la société Hercules Inc. ou bien sous la dénomination de "PD 170" ou "Delsette® 101 " par la société Hercules dans le cas du copolymère d'acide adipique/époxypropyl- diéthylène-triamine.Polymers of this type are sold in particular under the name "Hercosett ® 57" by the company Hercules Inc. or else under the name of "PD 170" or "Delsette ® 101" by the company Hercules in the case of the copolymer of adipic acid / epoxypropyl-diethylene-triamine.
(9) Les cyclopolymères d'alkyldiallylamine ou de dialkyldiallylammo- nium tels que les homopolymères ou copolymères comportant, comme constituant principal de la chaîne, des motifs répondant aux formules (Va) ou (Vb) :(9) Cyclopolymers of alkyldiallylamine or dialkyldiallylammonium such as homopolymers or copolymers comprising, as main constituent of the chain, units corresponding to formulas (Va) or (Vb):
dans lesquelles k et t sont égaux à 0 ou 1 , la somme k + t étant égale à 1 ; R12 désigne un atome d'hydrogène ou un groupe méthyle ; R10 et Ru , indépendamment l'un de l'autre, désignent un groupement alkyle ayant de 1 à 22 atomes de carbone, un groupement hydroxyalkyle dans lequel le groupement alkyle a de préférence 1 à 5 atomes de carbone, un groupement amidoalkyle inférieur (Cj- ), ou alors R10 et Rn peuvent désigner conjointement avec l'atome d'azote auquel ils sont rattachés, des groupements hétérocycliques, tels que pipéridinyle ou morpho- linyle ; Y" est un anion tel que bromure, chlorure, acétate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, piiosphate. Ces polymères sont notamment décrits dans le brevet français 2 080 759 et dans son certificat d'addition 2 190 406. in which k and t are equal to 0 or 1, the sum k + t being equal to 1; R 12 denotes a hydrogen atom or a methyl group; R 10 and R u , independently of one another, denote an alkyl group having from 1 to 22 carbon atoms, a hydroxyalkyl group in which the alkyl group preferably has 1 to 5 carbon atoms, a lower amidoalkyl group (Cj-), or then R 10 and R n can denote, jointly with the nitrogen atom to which they are attached, heterocyclic groups, such as piperidinyl or morpholinyl; Y " is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, piiosphate. These polymers are described in particular in French patent 2,080,759 and in its certificate of addition 2,190,406.
R10 et Rn, indépendamment l'un de l'autre, désignent de préférence un groupement alkyle ayant de 1 à 4 atomes de carbone.R 10 and R n , independently of one another, preferably denote an alkyl group having from 1 to 4 carbon atoms.
Parmi les polymères définis ci-dessus, on peut citer plus particulièrement l'homopolymère de chlorure de diméthyldiallyl- ammonium vendu sous la dénomination " MERQUAT ® 100" par la société CALGON (et ses homologues de faibles masses moléculaires moyenne en poids) et les copolymères de chlorure de diallyldiméthylammonium et d'acrylamide commercialisés sous la dénomination "MERQUAT® 550". (10) le polymère de diammonium quaternaire contenant des motifs récurrents répondant à la formule (VI) :Among the polymers defined above, mention may be made more particularly of dimethyldiallylammonium chloride homopolymer sold under the name ammonium "Merquat ® 100" by the company Calgon (and homologues of low average molecular weights) and copolymers diallyldimethylammonium chloride and acrylamide marketed under the name "MERQUAT ® 550". (10) the quaternary diammonium polymer containing recurring units corresponding to formula (VI):
dans laquelle : R13, R14, R15 et R16, identiques ou différents, représentent des groupes aliphatiques, alicycliques ou arylaliphatiques contenant de 1 à 20 atomes de carbone ou . des groupes hydroxyalkylaliphatiques inférieurs, ou bien R13, R14, R15 et R16, ensemble ou séparément, constituent avec les atomes d'azote auxquels ils sont rattachés des hétérocycles contenant éventuellement un second hétéroatome autre que l'azote, ou bien R13, R14, R15 et R16 représentent un groupe alkyle en C C6ι linéaire ou ramifié, substitué par un groupement nitrile, ester, acyle, amide ou -CO-O-Rπ-D ou -CO-NH-Rπ-D où R17 est un groupe alkylène et D un groupement ammonium quaternaire ; Ai et Bj représentent des groupements polyméthyléniques contenant de 2 à 20 atomes de carbone, pouvant être linéaires ou ramifiés, saturés ou insaturés, et pouvant contenir, liés à ou intercalés dans la chaîne principale, un ou plusieurs cycles aromatiques, ou un ou plusieurs atomes d'oxygène, de soufre ou des groupements sulfoxyde, sulfone, disulfure, amino, alkylamino, hydroxyle, ammonium quaternaire, uréido, amide ou ester, et in which: R 13 , R 14 , R 15 and R 16 , identical or different, represent aliphatic, alicyclic or arylaliphatic groups containing from 1 to 20 carbon atoms or. lower hydroxyalkylaliphatic groups, or alternatively R 13 , R 14 , R 15 and R 16 , together or separately, constitute with the nitrogen atoms to which they are attached heterocycles optionally containing a second heteroatom other than nitrogen, or alternatively R 13 , R 14 , R 15 and R 16 represent a linear or branched CC 6ι alkyl group, substituted by a nitrile, ester, acyl, amide or -CO-OR π -D or -CO group -NH-R π -D where R 17 is an alkylene group and D a quaternary ammonium group; Ai and Bj represent polymethylenic groups containing from 2 to 20 carbon atoms, which may be linear or branched, saturated or unsaturated, and which may contain, linked to or intercalated in the main chain, one or more aromatic rings, or one or more atoms oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and
X" désigne un anion dérivé d'un acide minéral ou organique; A R13 et R15 peuvent former avec les deux atomes d'azote auxquels ils sont rattachés un cycle pipérazinique ; en outre, si A, désigne un groupe alkylène ou hydroxyalkylène linéaire ou ramifié, saturé ou insaturé, B, peut également désigner un groupement :X " denotes an anion derived from a mineral or organic acid; AR 13 and R 15 can form with the two nitrogen atoms to which they are attached a piperazine ring; moreover, if A, denotes a linear alkylene or hydroxyalkylene group or branched, saturated or unsaturated, B, can also denote a group:
-(CH2)n-CO-D-OC-(CH2)n- dans lequel D désigne : a) un reste de glycol de formule -O-Z-O-, où Z désigne un groupe hydrocarboné linéaire ou ramifié, ou un groupement répondant à l'une des formules suivantes :- (CH 2 ) n -CO-D-OC- (CH 2 ) n - in which D denotes: a) a glycol residue of formula -OZO-, where Z denotes a linear or branched hydrocarbon group, or a group corresponding to one of the following formulas:
-(CH2-CH2-O)x-CH2-CH2- -[CH2-CH(CH3)-O]y-CH2-CH(CH3)- où x et y désignent un nombre entier de 1 à 4, représentant un degré de polymérisation défini et unique ou un nombre quelconque de 1 à 4 représentant un degré de polymérisation moyen ; b) un reste de diamine bis-secondaire tel qu'un dérivé de pipérazine ; c) un reste de diamine bis-primaire de formule -NH-Y-NH-, où Y désigne un groupe hydrocarboné linéaire ou ramifié, ou bien le groupe divalent -CH2-CH2-S-S-CH2-CH2- ; d) un groupement uréylène de formule -NH-CO-NH- .- (CH 2 -CH 2 -O) x -CH 2 -CH 2 - - [CH 2 -CH (CH 3 ) -O] y -CH 2 -CH (CH 3 ) - where x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization; b) a bis-secondary diamine residue such as a piperazine derivative; c) a bis-primary diamine residue of formula -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon group, or else the divalent group -CH 2 -CH 2 -SS-CH 2 -CH 2 -; d) a ureylene group of formula -NH-CO-NH-.
De préférence, X" est un anion tel que le chlorure ou le bromure. Ces polymères ont une masse moléculaire moyenne en nombre généralement comprise entre 1000 et 100000.Preferably, X " is an anion such as chloride or bromide. These polymers have a number average molecular weight generally between 1000 and 100,000.
Des polymères de ce type sont notamment décrits dans les brevets français 2 320 330, 2 270 846, 2 316 271 , 2 336 434 et 2 413 907 et les brevets US 2 273 780, 2 375 853, 2 388 614, 2 454 547,Polymers of this type are described in particular in French patents 2,320,330, 2,270,846, 2,316,271, 2,336,434 and 2,413,907 and US patents 2,273,780, 2,375,853, 2,388,614, 2,454,547 ,
3 206 462, 2 261 002, 2 271 378, 3 874 870, 4 001 432, 3 929 990,3,206,462, 2,261,002, 2,271,378, 3,874,870, 4,001,432, 3,929,990,
3 966 904, 4 005 193, 4 025 617, 4 025 627, 4 025 653, 4 026 945 et3,966,904, 4,005,193, 4,025,617, 4,025,627, 4,025,653, 4,026,945 and
4 027 020.4,027,020.
On peut utiliser plus particulièrement les polymères qui sont constitués de motifs récurrents répondant à la formule :It is possible to use more particularly the polymers which consist of recurring units corresponding to the formula:
dans laquelle Rl 9 R2, R3 et R4 identiques ou différents, désignent un groupe alkyle ou hydroxyalkyle ayant de 1 à 4 atomes de carbone environ, n et p sont des nombres entiers variant de 2 à 20 environ et, X" est un anion dérivé d'un acide minéral ou organique.in which R l 9 R 2 , R 3 and R 4, which are identical or different, denote an alkyl or hydroxyalkyl group having from 1 to 4 carbon atoms approximately, n and p are whole numbers varying from 2 to 20 approximately and, X " is an anion derived from a mineral or organic acid.
Un composé de formule (VII) particulièrement préféré est celui pour lequel Rl s R2, R3 et R4 représentent un groupe méthyle et n=3, p=6 et X=C1, dénommé chlorure d'hexadiméthrine (CTFA). (11) Les polymères de polyammonium quaternaire constitués de motifs de formule (VIII) :A particularly preferred compound of formula (VII) is that for which R 1s R 2 , R 3 and R 4 represent a methyl group and n = 3, p = 6 and X = C1, called hexadimethrin chloride (CTFA). (11) Quaternary polyammonium polymers consisting of units of formula (VIII):
R18 R20 R 18 R 20
-N+-(CH2)-NH-CO-(CH2)q-CO-NH-(CH2)s— N+-A- Ri9 (VIII) χ_ R21 -N + - (CH 2 ) -NH-CO- (CH 2 ) q -CO-NH- (CH 2 ) s - N + -A- R i9 (VIII) χ _ R 21
dans laquelle : R18, R19, R20 et R21, identiques ou différents, représentent un atome d'hydrogène ou un groupe méthyle, éthyle, propyle, β- hydroxyéthyle, β-hydroxypropyle ou -CH2CH2(OCH2CH2)pOH, où p est égal à 0 ou à un nombre entier compris entre 1 et 6, sous réserve que R18, R19, R20 et R21 ne représentent pas simultanément un atome d'hydrogène, r et s, identiques ou différents, sont des nombres entiers compris entre 1 et 6, q est égal à 0 ou à un nombre entier compris entre 1 et 34, X" désigne un anion tel qu'un halogénure,in which : R 18 , R 19 , R 20 and R 21 , identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, β-hydroxyethyl, β-hydroxypropyl or -CH 2 CH 2 (OCH 2 CH 2 ) group p OH, where p is equal to 0 or an integer between 1 and 6, provided that R 18 , R 19 , R 20 and R 21 do not simultaneously represent a hydrogen atom, r and s, identical or are whole numbers between 1 and 6, q is 0 or an integer between 1 and 34, X " denotes an anion such as a halide,
A désigne un radical d'un dihalogénure ou représente de préférence -CH2-CH2-O-CH2-CH2-.A denotes a radical of a dihalide or preferably represents -CH 2 -CH 2 -O-CH 2 -CH 2 -.
De tels composés sont notamment décrits dans la demande de brevet EP-A- 122 324. On peut citer parmi ceux-ci, par exemple, les produits "Mirapol® Such compounds are described in Patent Application EP-122 324. These include among them, for example the products "Mirapol ®
A 15", "Mirapol® AD 1 ", "Mirapol® AZ1 " et "Mirapol® 175" vendus par la société Miranol.At 15 "," Mirapol ® AD 1 "," Mirapol ® AZ1 "and" Mirapol ® 175 "sold by the company Miranol.
(12) Les polymères quaternaires de vinylpyrrolidone et de vinylimidazole tels que, par exemple, les produits commercialisés sous les dénominations Luviquat® FC 905, FC 550 et FC 370 par la société(12) Quaternary polymers of vinylpyrrolidone and of vinylimidazole, such as, for example, the products sold under the names Luviquat ® FC 905, FC 550 and FC 370 by the company
B.A.S.F.B.A.S.F.
(13) Les polyamines comme le Polyquart® H vendu par HENKEL, référencées sous le nom de « POLYETHYLENEGLYCOL (15) TALLOW POLYAMINE » dans le dictionnaire CTFA. (14) Les polymères réticulés de sels de méthacryloyloxyalkyl(C1-C4) trialkyl(C1-C4)ammonium tels que les polymères obtenus par homopolymérisation du méthacrylate de diméthylaminoéthyle quaternisé par le chlorure de méthyle, ou par copolymérisation de l' acrylamide avec le méthacrylate de diméthylaminoéthyle quaternisé par le chlorure de méthyle, l'homopolymérisation ou la copolymérisation étant suivie d'une réticulation par un composé à insaturation oléfinique, en particulier le méthylène-bisacrylamide. On peut plus particulièrement utiliser un copolymère réticulé acrylamide/chlorure de méthacryloyloxy- éthyl-triméthylammonium (20/80 en poids) sous forme de dispersion contenant 50 % en poids dudit copolymère dans de l' huile minérale. Cette dispersion est commercialisée sous le nom de SALCARE® SC 92 par la Société ALLIED COLLOIDS. On peut également utiliser un homopolymère réticulé du chlorure de méthacryloyloxyéthyl- triméthylammonium contenant environ 50 % en poids de l'homopolymère dans de l'huile minérale ou dans un ester liquide. Ces dispersions sont commercialisées sous les noms de SALCARE® SC 95 et SALCARE® SC 96 par la Société ALLIED COLLOIDS.(13) Polyamines such as Polyquart ® H sold by HENKEL, referenced under the name of "POLYETHYLENEGLYCOL (15) TALLOW POLYAMINE" in the CTFA dictionary. (14) Crosslinked polymers of methacryloyloxyalkyl (C 1 -C 4 ) trialkyl (C 1 -C 4 ) ammonium salts such as the polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized by methyl chloride, homopolymerization or copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylene bisacrylamide. One can more particularly use a crosslinked acrylamide / methacryloyloxy-ethyl-trimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion. containing 50% by weight of said copolymer in mineral oil. This dispersion is sold under the name Salcare ® SC 92 by Allied Colloids. It is also possible to use a crosslinked homopolymer of methacryloyloxyethyltrimethylammonium chloride containing approximately 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are sold under the names Salcare ® SC 95 and Salcare ® SC 96 by Allied Colloids.
D'autres polymères cationiques utilisables dans le cadre de l'invention sont des protéines cationiques ou des hydrolysats de protéines cationiques, des polyalkylèneimines, en particulier des polyéthylèneimines, des polymères contenant des motifs vinylpyridine ou vinylpyridinium, des condensais de polyamines et d'épichlorhydrine, des polyuréylènes quaternaires et les dérivés de la chitine. Parmi tous les polymères cationiques susceptibles d' être utilisés dans le cadre de la présente invention, on préfère mettre en oeuvre les dérivés d'éther de cellulose quaternaires tels que les produits vendus sous la dénomination "JR 400" par la Société UNION CARBIDE CORPORATION, les cyclopolymères cationiques, en particulier les homopolymères ou copolymères de chlorure de diméthyldiallyl- ammonium, vendus sous les dénominations MERQUAT 100, MERQUAT® 550 et MERQUAT® S par la société CALGON, les polysaccharides cationiques tels que les gommes de guar modifiées par un sel de 2,3-époxypropyl-triméthylammonium, les polymères quaternaires de vinylpyrrolidone et de vinylimidazole et leurs mélanges.Other cationic polymers which can be used in the context of the invention are cationic proteins or cationic protein hydrolysates, polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and epichlorohydrin, quaternary polyureylenes and chitin derivatives. Among all the cationic polymers capable of being used in the context of the present invention, it is preferred to use quaternary cellulose ether derivatives such as the products sold under the name "JR 400" by the company UNION CARBIDE CORPORATION, cationic cyclopolymers, in particular homopolymers or copolymers of dimethyldiallyl ammonium chloride, sold under the names MERQUAT 100, MERQUAT ® 550 and MERQUAT ® S by the company CALGON, cationic polysaccharides such as guar gums modified with a salt of 2,3-epoxypropyl-trimethylammonium, quaternary polymers of vinylpyrrolidone and vinylimidazole and their mixtures.
Parmi les polymères cationiques mentionnés ci-dessus, convenant dans l'invention, on utilise de préférence les dérivés d' éther de cellulose quaternaires, les cyclopolymères cationiques, les polymères quaternaires de vinylpyrrolidone et de vinylimidazole, et leurs mélanges. Les compositions selon l'invention peuvent également comprendre un ou plusieurs polymères amphotères. Parmi ceux-ci, on peut tout particulièrement citer les copolymères acide acrylique/chlorure de dialkyldiallylammonium tels que le MERQUAT® 100 vendu par la société CALGON. Selon l'invention, le ou les polymères cationiques peuvent représenter de 0,001 % à 10 % en poids, de préférence de 0,005 % à 5% en poids et plus particulièrement de 0,01 à 3% en poids par rapport au poids total de la composition finale. Le pH des compositions de l'invention est compris entre 4 et 8, de préférence entre 5 et 7.Among the cationic polymers mentioned above, which are suitable in the invention, use is preferably made of quaternary cellulose ether derivatives, cationic cyclopolymers, quaternary polymers of vinylpyrrolidone and of vinylimidazole, and mixtures thereof. The compositions according to the invention can also comprise one or more amphoteric polymers. Among these, one can particularly include acrylic acid copolymers / chloride dialkyldiallylammonium such as Merquat ® 100 sold by Calgon. According to the invention, the cationic polymer (s) can represent from 0.001% to 10% by weight, preferably from 0.005% to 5% by weight and more particularly from 0.01 to 3% by weight relative to the total weight of the final composition. The pH of the compositions of the invention is between 4 and 8, preferably between 5 and 7.
Les compositions selon l'invention peuvent également contenir des additifs tels que des épaississants polymériques naturels ou synthétiques, anioniques, amphotères, zwitteroniques, non ioniques ou ca- tioniques, associatifs ou non, des épaississants non polymériques comme des acides ou des électrolytes, des nacrants, des opacifiants, des solvants organiques, des parfums, des huiles minérales, végétales et/ou synthétiques, des esters d'acides gras, des colorants, des silicones volatiles ou non, organomodifiées ou non, cycliques ou acycliques, ramifiées ou non, des particules minérales ou organiques, des conservateurs, des agents de stabilisation du pH.The compositions according to the invention may also contain additives such as natural or synthetic polymeric thickeners, anionic, amphoteric, zwitteronic, nonionic or cationic, associative or not, non-polymeric thickeners such as acids or electrolytes, nacrants , opacifiers, organic solvents, perfumes, mineral, vegetable and / or synthetic oils, fatty acid esters, dyes, volatile or non-volatile silicones, organomodified or not, cyclic or acyclic, branched or not, mineral or organic particles, preservatives, pH stabilizers.
L'homme de métier veillera à choisir les éventuels additifs et leur quantité de manière à ce qu'ils ne nuisent pas aux propriétés des compositions de la présente invention. Ces additifs sont présents dans la composition selon l'invention en une quantité allant de 0 à 20 % en poids par rapport au poids total de la composition.Those skilled in the art will take care to choose any additives and their quantity so that they do not harm the properties of the compositions of the present invention. These additives are present in the composition according to the invention in an amount ranging from 0 to 20% by weight relative to the total weight of the composition.
Les compositions peuvent se présenter sous forme de liquides fluides ou épaissis, de gels, de crèmes, de mousses, d'émulsions E/H, H/E ou d'émulsions multiples.The compositions can be in the form of fluid or thickened liquids, gels, creams, foams, W / O, O / W emulsions or multiple emulsions.
Elles peuvent être utilisées, par exemple, comme shampooings, soins rincés ou non rincés, masques de soin profond, lotions ou crèmes de traitement du cuir chevelu et de la peau, démaquillants.They can be used, for example, as shampoos, rinsed or leave-in care, deep care masks, lotions or creams for treating the scalp and skin, make-up removers.
La présente invention concerne également un procédé de traitement cosmétique des matières kératiniques qui consiste à appliquer sur les matières kératiniques une quantité efficace d'une composition telle que décrite ci-dessus, et à effectuer éventuellement un rinçage après un éventuel temps de pause. Les exemples suivants illustrent la présente invention et ne doivent être considérés en aucune manière comme limitant l'invention.The present invention also relates to a method of cosmetic treatment of keratin materials which consists in applying to the keratin materials an effective amount of a composition as described above, and optionally in rinsing after a possible pause time. The following examples illustrate the present invention and should not be considered in any way as limiting the invention.
Exemple 1Example 1
On a préparé un shampoing selon l'invention à partir des ingrédients suivants :A shampoo according to the invention was prepared from the following ingredients:
- Lauryléthersulfate de sodium (2,2 moles d'oxyde d'éthylène) 17 g - Cocoylbétaïne 2,5 g- Sodium lauryl ether sulfate (2.2 moles of ethylene oxide) 17 g - Cocoylbetaine 2.5 g
- Bétaïnate d'amidon de pomme de terre de degré de substitution 0,8 0,05 g- Potato starch betainate of degree of substitution 0.8 0.05 g
- Eau, parfum, conservateur qsp 100 g pH ajusté à 6 (HCl/NaOH)- Water, perfume, preservative qs 100 g pH adjusted to 6 (HCl / NaOH)
Après rinçage, les cheveux sont doux, lisses et faciles à démêler.After rinsing, the hair is soft, smooth and easy to disentangle.
Exemple 2Example 2
On a préparé un shampoing selon l'invention à partir des ingrédients suivants :A shampoo according to the invention was prepared from the following ingredients:
- Lauryléthersulfate de sodium (2,2 moles d'oxyde d'éthylène) 6 g - N-cocoylamidoéthyl-N-carboxyméthylglycinate de sodium- Sodium laurylethersulfate (2.2 moles of ethylene oxide) 6 g - Sodium N-cocoylamidoethyl-N-carboxymethylglycinate
(Miranol® CLM concentré NP de RHODIA) 3 ,5 g(Miranol ® CLM concentrated NP from RHODIA) 3, 5 g
- Bétaïnate d'amidon de pomme de terre de degré de substitution 0,8 0,8 g- Potato starch betainate of degree of substitution 0.8 0.8 g
- Eau, parfum, conservateur qsp 100 g pH ajusté à 6 (HCl/NaOH)- Water, perfume, preservative qs 100 g pH adjusted to 6 (HCl / NaOH)
Après rinçage, les cheveux sont doux, lisses et faciles à démêler. Exemple 3After rinsing, the hair is soft, smooth and easy to disentangle. Example 3
On a préparé un shampoing selon l'invention à partir des ingrédients suivants :A shampoo according to the invention was prepared from the following ingredients:
- Lauryléthersulfate de sodium (2,2 moles d'oxyde d'éthylène) 17 g- Sodium lauryl ether sulfate (2.2 moles of ethylene oxide) 17 g
- Cocoylbétaïne 2,5 g- Cocoylbetaine 2.5 g
- Cétostéarylsulfate de sodium 0,75 g- Sodium ketostearyl sulfate 0.75 g
- Mélange d'alcool cétylique et de l-(hexadécyloxy)-2-octadécanol 2,5 g- Mixture of cetyl alcohol and 1- (hexadecyloxy) -2-octadecanol 2.5 g
- Monoisopropanolamide d'acide de coprah 0,6 g- Copra acid monoisopropanolamide 0.6 g
- Polydiméthylsiloxane (300 000 mm2/s)- Polydimethylsiloxane (300,000 mm 2 / s)
(DC200 Fluid 300 000 de DOW CORNING) 2,7 g(DC200 Fluid 300,000 from DOW CORNING) 2.7 g
- Bétaïnate d'amidon de pomme de terre de degré de substitution 0,8 1 g- Potato starch betainate of degree of substitution 0.8 1 g
- Eau, parfum, conservateur qsp 100 g- Water, perfume, preservative qs 100 g
Après rinçage, les cheveux sont doux, lisses et faciles à démêler. After rinsing, the hair is soft, smooth and easy to disentangle.

Claims

REVENDICATIONS
1. Composition de traitement cosmétique des matières kératiniques, caractérisée en ce qu'elle comprend, dans un milieu aqueux cosmétiquement acceptable, au moins un bétaïnate d' amidon répondant à la formule suivante :1. Cosmetic treatment composition for keratin materials, characterized in that it comprises, in a cosmetically acceptable aqueous medium, at least one starch betainate corresponding to the following formula:
dans laquelle St représente une structure polymère de l' amidon, et au moins un tensioactif détergent, la quantité totale de tensioactif(s) détergent(s) étant supérieure ou égale à 3 % en poids par rapport au poids total de la composition. in which St represents a polymer structure of starch, and at least one detergent surfactant, the total amount of detergent surfactant (s) being greater than or equal to 3% by weight relative to the total weight of the composition.
2. Composition selon la revendication 1, caractérisée en ce que l' amidon est choisi parmi les amidons de maïs, de pomme de terre, d'avoine, de riz, de tapioca, de sorgho, d'orge ou de blé.2. Composition according to claim 1, characterized in that the starch is chosen from starches of corn, potato, oats, rice, tapioca, sorghum, barley or wheat.
3. Composition selon la revendication 1, caractérisée en ce que les tensioactifs détergents sont choisis parmi les tensioactifs anioniques, non-ioniques, amphotères et leurs mélanges.3. Composition according to claim 1, characterized in that the detergent surfactants are chosen from anionic, nonionic, amphoteric surfactants and their mixtures.
4. Composition selon la revendication 3, caractérisée en ce que les tensioactifs anioniques sont choisis parmi les sels des composés suivants : les sulfates d' alkyle, les alkyléthersulfates, les alkylamidoéthersulfates, les alkylarylpolyéthersulfates, les monoglycéride-sulfates, les alkylsulfonates, les phosphates d' alkyle, les alkylamidesulfonates, les alkylarylsulfonates, les α-oléfine- sulfonates, les paraffine-suif onates ; les sulfosuccinates d' alkyle, les alkyléthersulfosuccinates, les alkylamidesulfosuccinates ; les sulfo- acétates d' alkyle ; les acylsarcosinates ; et les acylglutamates ; les groupes alkyle ou acyle de ces composés comportant de 6 à 24 atomes de carbone et le groupe aryle désignant de préférence un groupe phényle ou benzyle ; les esters d'alkyle en C6-C24 et d'acides polyglycoside-carboxyliques ; les sulfosuccinamates d' alkyle, les iséthionates d' acyle et les N-acyltaurates, le groupe alkyle ou acyle comportant de 12 à 20 atomes de carbone ; les lactylates d'acyle dont le groupe acyle comporte de 8 à 20 atomes de carbone ; les acides d'alkyl-D-galactoside uroniques et leurs sels, les acides alkyl(C6-4. Composition according to claim 3, characterized in that the anionic surfactants are chosen from the salts of the following compounds: alkyl sulfates, alkyl ether sulfates, alkylamidoethersulfates, alkylarylpolyethersulfates, monoglyceride sulfates, alkylsulfonates, phosphates d 'alkyl, alkylamidesulfonates, alkylarylsulfonates, α-olefin sulfonates, paraffin sulfonates; alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamidesulfosuccinates; alkyl sulfo acetates; acylsarcosinates; and acylglutamates; the alkyl or acyl groups of these compounds containing from 6 to 24 carbon atoms and the aryl group preferably denoting a phenyl or benzyl group; C 6 -C 24 alkyl esters and acids polyglycoside-carboxylic; alkyl sulfosuccinamates, acyl isethionates and N-acyltaurates, the alkyl or acyl group having from 12 to 20 carbon atoms; acyl lactylates in which the acyl group contains from 8 to 20 carbon atoms; uronic alkyl-D-galactoside acids and their salts, alkyl acids (C 6 -
C24)éther-carboxyliques polyoxyalkylénés, les acides alkyl(C6-C24)- aryl(C6-C24)éther-carboxyliques polyoxyalkylénés, les acides alkyl(C6- C24)amidoéther carboxyliques polyoxyalkylénés, et leurs sels ; et leurs mélanges. C 24 ) polyoxyalkylenated ether-carboxylic acids (C 6 -C 24 ) alkyl aryl (C 6 -C 24 ) polyoxyalkylenated ether-carboxylic acids, polyoxyalkylenated alkyl (C 6 -C 24 ) amidoether carboxylic acids, and their salts; and their mixtures.
5. Composition selon la revendication 4, caractérisée en ce que les tensioactifs anioniques sont choisis parmi les sels de sulfates d'alkyle, d'alkyléthersulfates et d'alkyléthercarboxylates, et leurs mélanges.5. Composition according to Claim 4, characterized in that the anionic surfactants are chosen from the salts of alkyl sulphates, of alkyl ether sulphates and of alkyl ethercarboxylates, and of their mixtures.
6. Composition selon la revendication 3, caractérisée en ce que les tensioactifs non-ioniques sont choisis parmi les alcools, les alpha-diols, les ou les acides gras en C8-Clg polyéthoxylés, polypropoxylés ou polyglycérolés, le nombre de groupements oxyde d'éthylène ou oxyde de propylène allant de 2 à 50 et le nombre de groupements glycérol allant de 2 à 30, les copolymères d'oxyde d'éthylène et de propylène, les condensats d'oxyde d'éthylène et de propylène sur des alcools gras ; les amides gras polyéthoxylés ayant de 2 à 30 moles d'oxyde d'éthylène, les amides gras polyglycérolés comportant en moyenne 1 à 5 groupements glycérol ; les aminés grasses polyéthoxylées ayant de 2 à 30 moles d'oxyde d'éthylène ; les esters d'acides gras du sorbitane éthoxylés ayant de 2 à6. Composition according to claim 3, characterized in that the nonionic surfactants are chosen from alcohols, alpha-diols, or C 8 -C 1 fatty acids polyethoxylated, polypropoxylated or polyglycerolated, the number of ethylene oxide or propylene oxide groups ranging from 2 to 50 and the number of glycerol groups ranging from 2 to 30, the oxide copolymers ethylene and propylene, condensates of ethylene and propylene oxide on fatty alcohols; polyethoxylated fatty amides having from 2 to 30 moles of ethylene oxide, polyglycerolated fatty amides comprising on average 1 to 5 glycerol groups; polyethoxylated fatty amines having from 2 to 30 moles of ethylene oxide; ethoxylated sorbitan fatty acid esters having from 2 to
30 moles d'oxyde d'éthylène ; les esters d'acides gras du saccharose, les esters d'acides gras du polyéthylèneglycol, les alkyl(C6- C24)polyglycosides, les dérivés de N-alkyl(C6-C24)glucamine, les oxydes d'aminés ; et leurs mélanges. 30 moles of ethylene oxide; the fatty acid esters of sucrose, fatty acid esters of polyethylene glycol, alkyl (C 6 - C 24) polyglycosides, derivatives of N-alkyl (C 6 -C 24) glucamine derivatives, amine oxides; and their mixtures.
7. Composition selon la revendication 3, caractérisée en ce que les tensioactifs amphotères sont choisis parmi des dérivés d'aminés aliphatiques secondaires ou tertiaires, dans lesquels le groupe aliphatique est une chaîne linéaire ou ramifiée comportant de 8 à 22 atomes de carbone et contenant au moins un groupe anionique hydrosolubilisant tel qu'un groupe carboxylate, sulfonate, sulfate, phosphate ou phosphonate ; les alkyl(C8-C20)bétaïnes, les sulfobétaïnes, les alkyl(C8-C20)amidoalkyl(C6-C8)bétaïnes ou les alkyl(C8-C20)amidoalkyl (C6-C8)sulfobétaïnes ; et leurs mélanges. 7. Composition according to claim 3, characterized in that the amphoteric surfactants are chosen from derivatives of secondary or tertiary aliphatic amines, in which the aliphatic group is a linear or branched chain containing from 8 to 22 carbon atoms and containing at minus an anionic group water-solubilizer such as a carboxylate, sulfonate, sulfate, phosphate or phosphonate group; (C 8 -C 20 ) alkyl betaines, sulfobetaines, (C 8 -C 20 ) alkyl amidoalkyl (C 6 -C 8 ) betaines or (C 8 -C 20 ) alkyl amidoalkyl (C 6 -C 8 ) sulfobetaines; and their mixtures.
8. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que la quantité totale de tensioactif(s) détergent(s) est comprise entre 3 % et 30 % en poids.8. Composition according to any one of the preceding claims, characterized in that the total amount of detergent surfactant (s) is between 3% and 30% by weight.
9. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que le bétaïnate d'amidon est présent en une quantité comprise entre 0,01 et 20 % en poids.9. Composition according to any one of the preceding claims, characterized in that the starch betainate is present in an amount between 0.01 and 20% by weight.
10. Composition selon la revendication 9, caractérisée en ce que le bétaïnate d'amidon est présent en une quantité comprise entre 0,05 et 10 % en poids.10. Composition according to claim 9, characterized in that the starch betainate is present in an amount between 0.05 and 10% by weight.
11. Composition selon la revendication 1, caractérisée en ce que le milieu aqueux cosmétiquement acceptable est constitué uniquement par de l'eau ou par un mélange d'eau et d'un solvant cosmétiquement acceptable.11. Composition according to claim 1, characterized in that the cosmetically acceptable aqueous medium consists solely of water or a mixture of water and a cosmetically acceptable solvent.
12. Composition selon la revendication 11 , caractérisée en ce que le solvant cosmétiquement acceptable est choisi parmi les alcools inférieurs en C1-C4, comme l'éthanol, l'isopropanol, le tertio-butanol, le n-butanol ; et les alkylèneglycols comme le propylèneglycol, les éthers de glycol.12. Composition according to claim 11, characterized in that the cosmetically acceptable solvent is chosen from lower C 1 -C 4 alcohols, such as ethanol, isopropanol, tert-butanol, n-butanol; and alkylene glycols such as propylene glycol, glycol ethers.
13. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce qu'elle comprend en outre un autre polymère cationique.13. Composition according to any one of the preceding claims, characterized in that it also comprises another cationic polymer.
14. Composition selon la revendication 13, caractérisée en ce que le polymère cationique est choisi parmi les dérivés d'éther de cellulose quaternaires, les cyclopolymères cationiques, les polymères quaternaires de vinylpyrrolidone et de vinylimidazole, et leurs mélanges.14. Composition according to claim 13, characterized in that the cationic polymer is chosen from quaternary cellulose ether derivatives, cationic cyclopolymers, quaternary polymers of vinylpyrrolidone and of vinylimidazole, and their mixtures.
15. Composition selon selon l'une quelconque des revendications précédentes, caractérisée en ce qu'elle comprend en outre des additifs tels que des épaississants polymériques naturels ou synthétiques, anioniques, amphotères, zwitteroniques, non ioniques ou cationiques, associatifs ou non, des épaississants non polymériques comme des acides ou des électrolytes, des nacrants, des opacifiants, des solvants organiques, des parfums, des huiles minérales, végétales et/ou synthétiques, des esters d'acides gras, des colorants, des silicones volatiles ou non, organomodifiées ou non, cycliques ou acycliques, ramifiées ou non, des particules minérales ou organiques, des conservateurs, des agents de stabilisation du pH.15. Composition according to any one of the preceding claims, characterized in that it further comprises additives such as natural or synthetic polymeric thickeners, anionic, amphoteric, zwitteronic, nonionic or cationic, associative or not, non-polymeric thickeners such as acids or electrolytes, pearlescent agents, opacifiers, organic solvents, perfumes, mineral, vegetable and / or synthetic oils, fatty acid esters, dyes, silicones volatile or not, organomodified or not, cyclic or acyclic, branched or not, mineral or organic particles, preservatives, agents for stabilizing the pH.
16. Procédé de traitement cosmétique des matières kératiniques, caractérisé en ce que l'on applique sur les matières kératiniques une composition selon l'une quelconque des revendications précédentes, et que l'on effectue éventuellement un rinçage après un éventuel temps de pause.16. Cosmetic treatment process for keratin materials, characterized in that a composition according to any one of the preceding claims is applied to the keratin materials, and that a rinsing is optionally carried out after a possible pause time.
17. Utilisation d'une composition de traitement cosmétique selon l'une quelconque des revendications 1 à 15, pour le lavage de la peau ou des cheveux. 17. Use of a cosmetic treatment composition according to any one of claims 1 to 15, for washing the skin or the hair.
EP01956595A 2000-07-21 2001-07-12 Cosmetic composition comprising a starch betainate and a detergent surfactant Withdrawn EP1301162A1 (en)

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FR0009611A FR2811895B1 (en) 2000-07-21 2000-07-21 COSMETIC TREATMENT COMPOSITION COMPRISING AT LEAST ONE SPECIFIC STARCH BETAINATE AND AT LEAST ONE DETERGENT SURFACTANT, METHOD FOR COSMETIC TREATMENT OF KERATINIC MATERIALS AND USE OF THE COMPOSITION
FR0009611 2000-07-21
PCT/FR2001/002266 WO2002007684A1 (en) 2000-07-21 2001-07-12 Cosmetic composition comprising a starch betainate and a detergent surfactant

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DE10201354A1 (en) * 2002-01-16 2003-07-24 Cognis Deutschland Gmbh Novel alk(en)yloligoglycoside betaine quaternary ester useful as an emulsifier, hair conditioner and washing softener
DE602004016908D1 (en) 2003-04-23 2008-11-20 Kao Corp Tensidzuammensetzung
JP4219785B2 (en) * 2003-10-17 2009-02-04 花王株式会社 Surfactant composition
PL1631593T3 (en) * 2003-05-21 2012-03-30 Chemigate Oy A process for the preparation of carnitine esters and their use
US8623341B2 (en) * 2004-07-02 2014-01-07 The Procter & Gamble Company Personal care compositions containing cationically modified starch and an anionic surfactant system
KR100769626B1 (en) 2004-09-17 2007-10-23 파이오니아 가부시키가이샤 Information recording medium, information recording device and method, and information reproducing device and method
CA2630608A1 (en) 2005-12-08 2007-06-14 Ciba Holding Inc. A process for the preparation of hydroxy polymer esters and their use
US20090176675A1 (en) * 2006-01-09 2009-07-09 Marjorie Mossman Peffly Personal Care Compositions Containing Cationically Modified Starch and an Anionic Surfactant System
US20070160555A1 (en) * 2006-01-09 2007-07-12 Staudigel James A Personal care compositions containing cationically modified starch and an anionic surfactant system
US9427391B2 (en) * 2006-01-09 2016-08-30 The Procter & Gamble Company Personal care compositions containing cationic synthetic copolymer and a detersive surfactant
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