EP1258620A2 - Method for desulfating an NOx absorber in internal combustion engine - Google Patents

Method for desulfating an NOx absorber in internal combustion engine Download PDF

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Publication number
EP1258620A2
EP1258620A2 EP02007800A EP02007800A EP1258620A2 EP 1258620 A2 EP1258620 A2 EP 1258620A2 EP 02007800 A EP02007800 A EP 02007800A EP 02007800 A EP02007800 A EP 02007800A EP 1258620 A2 EP1258620 A2 EP 1258620A2
Authority
EP
European Patent Office
Prior art keywords
knock
fuel
determined
sensitivity
fuel consumption
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP02007800A
Other languages
German (de)
French (fr)
Other versions
EP1258620A3 (en
EP1258620B1 (en
Inventor
Florian Preuss
Stefan Detterbeck
Hanns-Christian Hasenclever
Matthew Dr. Keenan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayerische Motoren Werke AG
Original Assignee
Bayerische Motoren Werke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayerische Motoren Werke AG filed Critical Bayerische Motoren Werke AG
Publication of EP1258620A2 publication Critical patent/EP1258620A2/en
Publication of EP1258620A3 publication Critical patent/EP1258620A3/en
Application granted granted Critical
Publication of EP1258620B1 publication Critical patent/EP1258620B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0842Nitrogen oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D35/00Controlling engines, dependent on conditions exterior or interior to engines, not otherwise provided for
    • F02D35/02Controlling engines, dependent on conditions exterior or interior to engines, not otherwise provided for on interior conditions
    • F02D35/027Controlling engines, dependent on conditions exterior or interior to engines, not otherwise provided for on interior conditions using knock sensors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D41/00Electrical control of supply of combustible mixture or its constituents
    • F02D41/02Circuit arrangements for generating control signals
    • F02D41/021Introducing corrections for particular conditions exterior to the engine
    • F02D41/0235Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus
    • F02D41/027Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to purge or regenerate the exhaust gas treating apparatus
    • F02D41/0275Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to purge or regenerate the exhaust gas treating apparatus the exhaust gas treating apparatus being a NOx trap or adsorbent
    • F02D41/028Desulfurisation of NOx traps or adsorbent
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/04Sulfur or sulfur oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D2200/00Input parameters for engine control
    • F02D2200/02Input parameters for engine control the parameters being related to the engine
    • F02D2200/06Fuel or fuel supply system parameters
    • F02D2200/0611Fuel type, fuel composition or fuel quality
    • F02D2200/0612Fuel type, fuel composition or fuel quality determined by estimation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D2200/00Input parameters for engine control
    • F02D2200/02Input parameters for engine control the parameters being related to the engine
    • F02D2200/08Exhaust gas treatment apparatus parameters
    • F02D2200/0818SOx storage amount, e.g. for SOx trap or NOx trap

Definitions

  • the invention relates to a method for desulfurizing a NO x storage device in an internal combustion engine according to the preamble of claim 1.
  • NO x accumulator in order to reduce the environmental impact and are then regularly eliminated in a regeneration process in the case of a rich mode of operation of the internal combustion engine.
  • NO x sensor can be used to identify the nitrogen oxide load in the storage and thus to control the regeneration process.
  • suitable models can also be used to infer the sulfur loading of the NO x storage.
  • a sulfur loading model is conventionally used to assess the extent of sulfur storage in the NO x storage, the sulfur loading model usually being designed in such a way that an artificial, sufficiently early desulfation is requested and carried out, even for predominantly short distances and in urban use becomes.
  • the object of the present invention is a method of the aforementioned Provide species with a desulfation that meets the needs.
  • a normal model calculation as is already known from the prior art used.
  • the knock signal or the knock control which is in the engine control in is present in most cases, evaluated and a knock sensitivity of the Fuel determined.
  • the amount of fuel used, determined and evaluated in particular during lean operation. On fuel consumption can be done, for example, by evaluating the injection processes or close the tank level evaluation.
  • Size can be determined, which is included in the model calculation and so affects that with a fuel with a high tendency to knock in shorter intervals desulfation is carried out. For a fuel with one less With a high tendency to knock, the desulfation intervals are selected further apart.
  • a map there is a relation between the knock sensitivity and the sulfur concentration in the fuel, depending on the tendency to knock deduces the sulfur concentration.
  • the present invention thus allows a simple and very inexpensive way perform a needs-based adaptation of the desulfation steps.

Abstract

In a process to remove sulfur from an automotive NOx storage trap operated in lean burn mode, a calculation model determines the sulfur removal steps. The steps are modified using information derived from a knock signal and the fuel anti-knock sensitivity, fuel consumption. The fuel consumption is determined during a lean burn phase of motor operation. The fuel consumption is determined since the previous sulfur removal cycle. A relationship is established between the knock-sensitivity and the fuel sulfur concentration. The relationship between knock-sensitivity and sulfur concentration is held in a memory device. A correctional parameter is determined using the knock-sensitivity and fuel consumption. This parameter is incorporated in the calculation model and is determines the sulfur removal process intervals.

Description

Die Erfindung betrifft ein Verfahren zur Desulfatisierung eines NOx-Speichers bei einem Verbrennungsmotor gemäß dem Oberbegriff des Anspruchs 1.The invention relates to a method for desulfurizing a NO x storage device in an internal combustion engine according to the preamble of claim 1.

Es ist bekannt, Motoren zumindest zum Teil in einem Magermodus zu betreiben, um den Kraftstoffverbrauch zu senken. Bei dieser Betriebsweise werden jedoch Stickstoffoxide frei, die zur Verminderung der Umweltbelastung zunächst in einem sog. NOx-Speicher zwischengespeichert und dann regelmäßig in einem Regenerationsprozeß bei einer fetten Betriebsweise des Verbrennungsmotors beseitigt werden. Üblicherweise kann mit einem sog. NOx-Sensor die Stickoxidbelastung des Speichers erkannt und damit der Regenerationsablauf gesteuert werden.It is known to operate engines at least partially in a lean mode in order to reduce fuel consumption. In this mode of operation, however, nitrogen oxides are released, which are first temporarily stored in a so-called NO x accumulator in order to reduce the environmental impact and are then regularly eliminated in a regeneration process in the case of a rich mode of operation of the internal combustion engine. Typically, the so-called NO x sensor can be used to identify the nitrogen oxide load in the storage and thus to control the regeneration process.

Durch Detektion der Stickoxidbelastung der Abgase nach dem NOx-Speicher kann mittels geeigneter Modelle überdies auf die Schwefelbelastung des NOx-Speichers geschlossen werden.By detecting the nitrogen oxide pollution of the exhaust gases after the NO x storage, suitable models can also be used to infer the sulfur loading of the NO x storage.

Bei Motorsteuersystemen ohne einen NOx-Sensor wird herkömmlicherweise ein Schwefelbeladungsmodell zur Beurteilung des Ausmaßes der Schwefeleinlagerung im NOx-Speicher verwendet, wobei das Schwefelbeladungsmodell üblicherweise so ausgelegt ist, dass auch bei überwiegenden Kurzstrecken und im Stadtbetrieb eine künstliche, ausreichend frühe Desulfatisierung angefordert und durchgeführt wird. In engine control systems without a NO x sensor, a sulfur loading model is conventionally used to assess the extent of sulfur storage in the NO x storage, the sulfur loading model usually being designed in such a way that an artificial, sufficiently early desulfation is requested and carried out, even for predominantly short distances and in urban use becomes.

Diese "künstlich eingeleitete" Desulfatisierung wird also auch dann durchgeführt, wenn der Speicher noch nicht entsprechend stark mit Schwefel beladen ist. Dies führt herkömmlicherweise zu einem höheren Kraftstoffaufwand, da bei den heute üblichen, hochwertigen, schwefelarmen Kraftstoffen zu häufig desulfatisiert wird.This "artificially initiated" desulfation is also carried out if the storage is not yet heavily loaded with sulfur. This traditionally leads to higher fuel consumption, as with today's usual, high-quality, low-sulfur fuels is desulfated too often.

Aufgabe der vorliegenden Erfindung ist es, ein Verfahren der eingangs genannten Art mit einer bedarfsgerechten Desulfatisierung zur Verfügung zu stellen.The object of the present invention is a method of the aforementioned Provide species with a desulfation that meets the needs.

Ansatz bei der vorliegenden Erfindung ist der Gedanke, dass ein Zusammenhang zwischen der Klopfempfindlichkeit und dem Schwefelgehalt eines Kraftstoffs besteht. Zumeist sind nämlich hochschwefelhaltige Kraftstoffe auch wenig klopffest. Die Auswertung der Klopfregelung in Verbindung mit einer Verbrauchsermittelung (z.B. über Einspritzvorgänge oder eine Tankfüllstandsauswertung), findet erfindungsgemäß in die Modellrechnung Eingang, so dass bei einem qualitativ hochwertigen, schwefelarmen Kraftstoff, nicht mit der Häufigkeit, wie bei einem herkömmlichen System, desulfatisiert werden muss. Durch das Erkennen der klopfempfindlichen Kraftstoffe kann somit eine Verbesserung des Modells hinsichtlich des aktuellen Schwefelgehaltes im Tank erreicht werden, was wiederum zu einer exakteren Abschätzung des Verschwefelungsgrades und so zu einer Verringerung des Kraftstoffaufwandes führt. Überdies ist es möglich, einen teueren zusätzlichen NOx-Sensor zu vermeiden. Allgemein ist es also mit der vorliegenden Erfindung ohne weiteres möglich, häufige Desulfatisierungsvorgänge zu vermeiden und trotzdem eine Überladung des NOx-Speichers mit Schwefeloxiden zu verhindern.Approach to the present invention is the idea that there is a connection between the knock sensitivity and the sulfur content of a fuel. Mostly, fuels containing high sulfur are also not very resistant to knock. The evaluation of the knock control in conjunction with a consumption determination (for example via injection processes or a tank fill level evaluation) is incorporated into the model calculation according to the invention, so that in the case of a high-quality, low-sulfur fuel, the frequency does not have to be desulfated, as in a conventional system. By recognizing the knock-sensitive fuels, an improvement of the model with regard to the current sulfur content in the tank can be achieved, which in turn leads to a more precise estimate of the degree of sulfurization and thus to a reduction in fuel consumption. Moreover, it is possible to avoid an expensive additional NO x sensor. In general, it is therefore easily possible with the present invention to avoid frequent desulphation processes and still prevent the NO x accumulator from being overloaded with sulfur oxides.

Bei einer Ausführungsform der vorliegenden Erfindung wird eine normale Modellberechnung, wie sie aus dem Stand der Technik bereits bekannt ist, verwendet. Zudem wird das Klopfsignal oder die Klopfregelung, welche in der Motorsteuerung in den meisten Fällen vorhanden ist, ausgewertet und eine Klopfempfindlichkeit des Kraftstoffes bestimmt. Zudem wird der die Menge des verbrauchten Kraftstoffes, insbesondere während des Magerbetriebs, ermittelt und ausgewertet. Auf den Kraftstoffverbrauch kann man beispielsweise über die Auswertung der Einspritzvorgänge oder die Tankfüllstandsauswertung schließen. Natürlich sind auch andere Möglichkeiten denkbar, wir man auf den Kraftstoffverbrauch allgemein schließen kann. Aus den beiden Größen Klopfempfindlichkeit und Kraftstoffverbrauch kann sodann eine Größe bestimmt werden, die in die Modellrechnung einbezogen wird und sich so auswirkt, dass bei einem Kraftstoff mit hoher Klopfneigung in kürzeren Intervallen eine Desulfatisierung vorgenommen wird. Bei einem Kraftstoff mit einer weniger großen Klopfneigung werden die Desulfatisierungsintervalle weiter auseinander gewählt. In einem Kennfeld ist dabei eine Relation zwischen der Klopfempfindlichkeit und der Schwefelkonzentration im Kraftstoff abgelegt, wobei man je nach Klopfneigung auf die Schwefelkonzentration schließt.In one embodiment of the present invention, a normal model calculation, as is already known from the prior art used. moreover the knock signal or the knock control, which is in the engine control in is present in most cases, evaluated and a knock sensitivity of the Fuel determined. In addition, the amount of fuel used, determined and evaluated in particular during lean operation. On fuel consumption can be done, for example, by evaluating the injection processes or close the tank level evaluation. Of course, there are other options conceivable, we can generally conclude on fuel consumption. Out The two sizes knock sensitivity and fuel consumption can then Size can be determined, which is included in the model calculation and so affects that with a fuel with a high tendency to knock in shorter intervals desulfation is carried out. For a fuel with one less With a high tendency to knock, the desulfation intervals are selected further apart. In a map there is a relation between the knock sensitivity and the sulfur concentration in the fuel, depending on the tendency to knock deduces the sulfur concentration.

Die vorliegende Erfindung erlaubt somit auf einfache und sehr kostengünstige Weise eine bedarfsgerechte Adaption der Desulfatisierungsschritte durchzuführen.The present invention thus allows a simple and very inexpensive way perform a needs-based adaptation of the desulfation steps.

Claims (6)

Verfahren zur Desulfatisierung eines NOx-Speichers bei einem Verbrennungsmotor, der zumindest zum Teil in einem Magermodus betrieben wird, wobei eine Modellrechnung zur Bestimmung eines Desulfatisierungsschrittes durchgeführt wird,
dadurch gekennzeichnet, dass ein Klopfsignal oder eine Klopfregelung ausgewertet und eine Klopfempfindlichkeit des Kraftstoffes bestimmt wird, dass ein Kraftstoffverbrauch bestimmt wird, und dass die Modellberechung in Abhängigkeit von der Klopfempfindlichkeit des Kraftstoffes und der Tankfüllstandsauswertung durchgeführt wird.
Method for desulfating a NO x store in an internal combustion engine, which is operated at least in part in a lean mode, a model calculation for determining a desulfating step being carried out,
characterized, that a knock signal or a knock control is evaluated and a knock sensitivity of the fuel is determined, that fuel consumption is determined, and that the model calculation is carried out depending on the knock sensitivity of the fuel and the tank level evaluation.
Verfahren nach Anspruch 1,
dadurch gekennzeichnet, dass der Kraftstoffverbrauch während des Betriebs im Magermodus bestimmt wird.
Method according to claim 1,
characterized in that the fuel consumption is determined during operation in lean mode.
Verfahren nach Anspruch 1 oder 2,
dadurch gekennzeichnet, dass der Kraftstoffverbrauch seit der letzten Desulfatisierung bestimmt wird.
The method of claim 1 or 2,
characterized in that the fuel consumption has been determined since the last desulfation.
Verfahren nach einem der Ansprüche 1 bis 3,
dadurch gekennzeichnet, dass eine Relation zwischen der Klopfempfindlichkeit und der Schwefelkonzentration im Kraftstoff bestimmt wird.
Method according to one of claims 1 to 3,
characterized in that a relation between the knock sensitivity and the sulfur concentration in the fuel is determined.
Verfahren nach Anspruch 4,
dadurch gekennzeichnet, dass die Relation zwischen Klopfempfindlichkeit und Schwefelkonzentration in einem Kennfeld oder einer Kennlinien abgelegt ist.
Method according to claim 4,
characterized in that the relationship between knock sensitivity and sulfur concentration is stored in a map or a characteristic curve.
Verfahren nach einem der Ansprüche 1 bis 5,
dadurch gekennzeichnet, dass aus der Klopfempfindlichkeit und dem Kraftstoffverbrauch ein Korrekturparameter bestimmt wird, der in die Modellrechnung eingeht und die Zeiträume zur und/oder der Desulfatisierung ändert.
Method according to one of claims 1 to 5,
characterized in that a correction parameter is determined from the knock sensitivity and the fuel consumption, which is included in the model calculation and changes the periods for and / or desulfating.
EP02007800A 2001-05-16 2002-04-06 Method for desulfating an NOx absorber in internal combustion engine Expired - Lifetime EP1258620B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10123682 2001-05-16
DE10123682A DE10123682A1 (en) 2001-05-16 2001-05-16 Process for desulfurizing a NOx storage device in an internal combustion engine

Publications (3)

Publication Number Publication Date
EP1258620A2 true EP1258620A2 (en) 2002-11-20
EP1258620A3 EP1258620A3 (en) 2005-04-13
EP1258620B1 EP1258620B1 (en) 2006-07-12

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EP02007800A Expired - Lifetime EP1258620B1 (en) 2001-05-16 2002-04-06 Method for desulfating an NOx absorber in internal combustion engine

Country Status (3)

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EP (1) EP1258620B1 (en)
AT (1) ATE333040T1 (en)
DE (2) DE10123682A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1515016A2 (en) * 2003-09-12 2005-03-16 Toyota Jidosha Kabushiki Kaisha Apparatus for controlling exhaust purifying catalyst of internal combustion engine

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5657625A (en) * 1994-06-17 1997-08-19 Mitsubishi Jidosha Kogyo Kabushiki Kaisha Apparatus and method for internal combustion engine control
JP2000073925A (en) * 1998-09-03 2000-03-07 Nippon Soken Inc Knock control device
US6116208A (en) * 1998-09-29 2000-09-12 Mazda Motor Corporation Control system for a direct injection-spark ignition engine
DE10018333A1 (en) * 1999-05-19 2000-11-23 Ford Global Tech Inc Procedure for controlling operation of lean-mix IC engine has determination of characteristic values for incremental NOX amount generated during lean-mix operating state and stored in trap

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5657625A (en) * 1994-06-17 1997-08-19 Mitsubishi Jidosha Kogyo Kabushiki Kaisha Apparatus and method for internal combustion engine control
JP2000073925A (en) * 1998-09-03 2000-03-07 Nippon Soken Inc Knock control device
US6116208A (en) * 1998-09-29 2000-09-12 Mazda Motor Corporation Control system for a direct injection-spark ignition engine
DE10018333A1 (en) * 1999-05-19 2000-11-23 Ford Global Tech Inc Procedure for controlling operation of lean-mix IC engine has determination of characteristic values for incremental NOX amount generated during lean-mix operating state and stored in trap

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN Bd. 2000, Nr. 06, 22. September 2000 (2000-09-22) & JP 2000 073925 A (NIPPON SOKEN INC; TOYOTA MOTOR CORP), 7. März 2000 (2000-03-07) *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1515016A2 (en) * 2003-09-12 2005-03-16 Toyota Jidosha Kabushiki Kaisha Apparatus for controlling exhaust purifying catalyst of internal combustion engine
EP1515016A3 (en) * 2003-09-12 2006-03-08 Toyota Jidosha Kabushiki Kaisha Apparatus for controlling exhaust purifying catalyst of internal combustion engine

Also Published As

Publication number Publication date
EP1258620A3 (en) 2005-04-13
DE50207467D1 (en) 2006-08-24
ATE333040T1 (en) 2006-08-15
DE10123682A1 (en) 2002-12-19
EP1258620B1 (en) 2006-07-12

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