EP1250494A1 - Method for introducing a moisture-impermeable layer into the ground, as well as a trench obtained by such a method - Google Patents
Method for introducing a moisture-impermeable layer into the ground, as well as a trench obtained by such a methodInfo
- Publication number
- EP1250494A1 EP1250494A1 EP01906414A EP01906414A EP1250494A1 EP 1250494 A1 EP1250494 A1 EP 1250494A1 EP 01906414 A EP01906414 A EP 01906414A EP 01906414 A EP01906414 A EP 01906414A EP 1250494 A1 EP1250494 A1 EP 1250494A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- trench
- clay
- dry solids
- containing mixture
- ground
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 47
- 239000000203 mixture Substances 0.000 claims abstract description 79
- 239000007787 solid Substances 0.000 claims abstract description 62
- 239000004927 clay Substances 0.000 claims abstract description 50
- 229910021647 smectite Inorganic materials 0.000 claims abstract description 12
- 239000011435 rock Substances 0.000 claims abstract description 6
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 8
- 239000012530 fluid Substances 0.000 claims description 8
- 239000004576 sand Substances 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 4
- 125000006850 spacer group Chemical group 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 238000009434 installation Methods 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- -1 silica compound Chemical class 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 229910010293 ceramic material Inorganic materials 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 229910001416 lithium ion Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910001415 sodium ion Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 238000000280 densification Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000004888 barrier function Effects 0.000 description 7
- 229910000278 bentonite Inorganic materials 0.000 description 7
- 239000000440 bentonite Substances 0.000 description 7
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 5
- 238000007789 sealing Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052900 illite Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229940094522 laponite Drugs 0.000 description 1
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 238000007613 slurry method Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000009271 trench method Methods 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D19/00—Keeping dry foundation sites or other areas in the ground
- E02D19/06—Restraining of underground water
- E02D19/12—Restraining of underground water by damming or interrupting the passage of underground water
- E02D19/16—Restraining of underground water by damming or interrupting the passage of underground water by placing or applying sealing substances
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D19/00—Keeping dry foundation sites or other areas in the ground
- E02D19/06—Restraining of underground water
- E02D19/12—Restraining of underground water by damming or interrupting the passage of underground water
- E02D19/18—Restraining of underground water by damming or interrupting the passage of underground water by making use of sealing aprons, e.g. diaphragms made from bituminous or clay material
Definitions
- the present invention relates to a method for introducing a moisture-impermeable layer into the ground, wherein the moisture- impermeable layer is placed into the ground in a trench, as well as a trench obtained by such a method.
- German Offenlegungsschrift no. 37 17 885 discloses a method for producing a sealing course of mineral sealing materials, such as, for example, bentonite, using a trench method, wherein the dry material is introduced into a trench.
- One drawback of said method is the fact that the dry mixture comes into direct contact with possibly contaminated water from the environment upon being introduced into the trench, which interferes with the swelling capacity of the bentonite, which is still dry at that stage, as a result of which the durability thereof is affected in comparison with bentonite that has been hydrated in advance. No further details with regard to the composition are provided.
- US patent no. 3,986,365 relates to a method for forming a moisture-impermeable layer, wherein a composition of sand and bentonite is mixed with a water-soluble polymer.
- the mixture thus obtained is only suitable for horizontal use under water basins, and owing to the properties of bentonite and sand, which are not specified in detail, this mixture is not suitable for use in vertical sealing systems.
- Such methods based on liquid slurries are characterized by a very low density in dry condition and a large specific surface area, however, as a result of which cracks are easily formed due to contraction.
- the slurry only provides limited resistance against penetration of the adjacent soil, so that local failure of the wall may occur. Since the impermeability of the slurries is relatively high in comparison with the density of the materials having a higher dry mass that are used in conventional horizontal seals, a relatively thick wall is necessary in order to provide sufficient certainty.
- the object of the present invention is to provide a method for introducing a moisture-impermeable layer into the ground, wherein the aforesaid problems of the prior art are eliminated to a significant degree.
- Another object of the present invention is to provide a method for introducing a moisture-impermeable layer into the ground, which method comprises a sealing system that corresponds to the horizontal sealing systems or the surface sealing systems that have been usual so far.
- the method as referred to in the introduction is according to the present invention characterized in that the trench is supported by one or more casing members, which trench is subsequently filled with a clay-containing mixture of dry solids, which mixture can form a moisture- resistant gel, comprising powdery or pulverized smectite and/or smectite- containing natural rock and a water-soluble polymer.
- a dry mixture comes into contact with water or with a water-containing fluid, which takes place in the case of rainfall or of water or an aqueous solution seeping through, gelation will take place spontaneously and will continue for some time, resulting in the formation of a moisture-resistant, water-impermeable gel.
- the use of a dry mixture leads to a proper filling degree or densification, resulting in satisfactory crossl inking upon contact with water.
- Such a clay-containing mixture of dry solids is known per se from European patent no. 0 682 684 in the name of the present applicants. From said European patent the special application in accordance with the present invention, viz. the forming of a trench in the ground, which trench is subsequently filled with the clay-containing mixture of dry solids, is not known, however, which application must be considered to be novel and inventive, therefore.
- a clay-containing mixture capable of forming a moisture-resistant gel is known from European patent no. 0 335 653, but the application that is known therefrom is essentially different from the present application.
- the trench in the ground by using one or more casing members, wherein one or more hollow elements are installed in the ground, said elements consisting of at least two plates which are interconnected by means of spacers, which plates may include a disconnectable closure part on their bottom sides.
- a tight seal on the sides of the elements may also function as a spacer, which seal can also serve as a guide for the adjacent elements.
- the hollow element is filled with the clay-containing mixture of dry solids first before being installed in the ground, after which the element thus filled is installed in the ground.
- the hollow element is lined with a material on the inside before the element is filled with the clay-containing mixture of dry solids, which material prevents the clay-containing mixture of dry solids from adhering to the hollow element.
- a material facilitates sliding of the hollow element upon being removed from the trench, and it also functions as a barrier layer between the clay-containing mixture of dry solids and the adjacent soil.
- An example of such a material is geofabric.
- one compartment containing the clay-containing mixture of dry solids and one compartment containing sand Such an embodiment is in particular advantageous if it is not necessary to fill the trench with the same clay-containing mixture of dry solids along its entire length, depth and width, so that generally a cost saving is achieved.
- the trench that has been formed in the ground is lined on both longitudinal sides thereof with one or more casing members consisting of one or more panels, after which the space thus enclosed by the panels is filled with the clay-containing mixture of dry solids.
- the clay-containing mixture of dry solids in the trench is densified by removing the panels from the trench in such a manner that this leads to densification of the clay-containing mixture of dry solids that is present in the trench.
- Such densification is obtained in particular if the panels are vibrated upon being removed from the trench.
- the panels In a special embodiment it is preferable to line the panels with a material on the side facing away from the soil before the panels are filled with the clay-containing mixture of dry solids, which material prevents the clay-containing mixture of dry solids from adhering to the panel.
- a material makes it easier for the panel to slide upon being removed from the trench, and it furthermore functions as a barrier layer between the clay-containing mixture of dry solids and the adjacent soil.
- the densification of the clay-containing mixture in the trench has resulted in a certain drop in the level of said mixture in the trench, it is preferable to fill the space that has thus formed, preferably with the same clay-containing mixture of dry solids. It is not inconceivable, however, to use a filling material other than the present clay-containing mixture of dry solids, for example sand. Thus the trench is filled in stages.
- the present invention it is possible to use a supporting fluid when forming the trench in the ground, in order to prevent the side walls of the trench from caving in. Furthermore it is preferred that the supporting fluid be forced out of the trench upon installation of the hollow elements and/or the mat in the trench.
- the smectite is preferably in an inactive state, that is, the lattice sodium and lithium ions that may be present do not make up more than 30% of the sum of the exchangeable lattice cations.
- the smectite may be one of the following: montmorillonite, beidellite, hectorite, montronite, saponite, illite, allevardite, mixtures thereof, natural rock containing one or more of the above (such as bentonite), or artificial mixtures of smectite-type silicate compounds (for example Laponite (trademark), Laporte Co., Great Britain).
- the moisture content of the present clay-containing mixture of dry solids is preferably ⁇ 20%, whereby the desired moisture content is determined to a significant degree by the manner in which said mixture is processed, as well as by the dimensions of the trench.
- a moisture content of ⁇ 10% will be preferred when a narrow trench is to be filled, in connection with the required flow characteristics of the clay- containing mixture; it will also be possible, however, to fill a hollow element outside the trench with a mixture having a moisture content of maximally 20%.
- the clay-containing mixture of dry solids additionally comprises a powdery solid activating agent in an amount of 0.8 - 6.0 wt. %, based on the weight of the smectite.
- the clay-containing mixture preferably comprises more than 0.5 wt. % of one or more solid inert fillers having an average particle size of more than 0.05 mm, based on the weight of the smectite.
- the clay-containing mixture of dry solids contains in particular 1 - 95 wt. % of a solid inert filler, based on the weight of the overall mixture. It is in particular preferred for the solid inert filler to have a particle size of 0.1 - 8.0 mm.
- Each water-soluble polymer which is capable of reacting with smectite can be used as the polymer component in the present clay- containing mixture of dry solids.
- polymers to be used are polyacryl amide having a degree of hydrolysis of less than 40%, polymethacryl amide, acryl ami de-acrylic acid-copolymers, vinyl alcohol -acrylic acid copolymers, polyethylene oxides and mixtures thereof. It is also possible to use graft polymers, such as acrylamide grafted onto a cellulose backbone.
- the molecular weight of the polymer is generally less than 15,000,000, with the preferred molecular weight ranging between 400,000 and 10,000,000.
- the clay-containing mixture of dry solids may also comprise one or more solid inert fillers, for example sand, silica compounds, pulverized rock or minerals, a pulverized ceramic material or a mixture thereof.
- solid inert fillers for example sand, silica compounds, pulverized rock or minerals, a pulverized ceramic material or a mixture thereof.
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Paleontology (AREA)
- Mining & Mineral Resources (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Civil Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Structural Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Revetment (AREA)
- Bulkheads Adapted To Foundation Construction (AREA)
- Building Environments (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1014185 | 2000-01-26 | ||
| NL1014185A NL1014185C2 (en) | 2000-01-26 | 2000-01-26 | Method for applying a moisture-impermeable layer in the soil, as well as a trench obtained by such a method. |
| PCT/NL2001/000049 WO2001055514A1 (en) | 2000-01-26 | 2001-01-25 | Method for introducing a moisture-impermeable layer into the ground, as well as a trench obtained by such a method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1250494A1 true EP1250494A1 (en) | 2002-10-23 |
| EP1250494B1 EP1250494B1 (en) | 2003-11-19 |
Family
ID=19770667
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP01906414A Expired - Lifetime EP1250494B1 (en) | 2000-01-26 | 2001-01-25 | Method for introducing a moisture-impermeable layer into the ground, as well as a trench obtained by such a method |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20030111425A1 (en) |
| EP (1) | EP1250494B1 (en) |
| JP (1) | JP2003520916A (en) |
| CN (1) | CN1177977C (en) |
| AT (1) | ATE254699T1 (en) |
| AU (1) | AU779942B2 (en) |
| DE (1) | DE60101258T2 (en) |
| NL (1) | NL1014185C2 (en) |
| WO (1) | WO2001055514A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010068087A1 (en) | 2008-12-03 | 2010-06-17 | Trisoplast International B.V. | Method for stimulating biodegradation and the degassing of waste disposal sites |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102023109314A1 (en) | 2023-04-13 | 2024-10-17 | Stephan Schmidt Kg | Clay-containing composition, process for its preparation and its use |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1171208A (en) * | 1957-04-12 | 1959-01-23 | Entpr Roumagnou | Process for preparing, in the ground, a continuous waterproof veil, intended to limit the underlying flow inside the banks |
| US3986365A (en) * | 1975-02-20 | 1976-10-19 | American Colloid Company | Soil sealing method |
| JPS58189417A (en) * | 1982-04-27 | 1983-11-05 | Kajima Corp | Water sealing for joint of sheathing |
| NL8301918A (en) | 1983-05-31 | 1984-12-17 | Nico Gerhard Cortlever | FILM WALL FORMING A WATERPROOF SCREEN IN THE GROUND AND METHOD FOR APPLICATION THEREOF. |
| JPH0615768B2 (en) * | 1985-08-07 | 1994-03-02 | 大成建設株式会社 | Construction method of water blocking wall |
| DE3717885C3 (en) * | 1987-05-27 | 1994-12-15 | Dyckerhoff & Widmann Ag | Method and device for producing a sealing layer from mineral sealing materials |
| US4908129A (en) * | 1987-05-27 | 1990-03-13 | Dyckerhoff & Widmann Aktiengesellschaft | Impervious layer formation process and landfill adsorption system |
| NL8702984A (en) | 1987-12-10 | 1989-07-03 | Verstraeten Funderingstech Bv | METHOD AND APPARATUS FOR MANUFACTURING A CLOSING WALL IN THE BOTTOM |
| DE68908447T2 (en) | 1988-03-28 | 1993-12-23 | Altalanos Iparfejlesztesi Rt B | Process for the production of gels from mineral clays and polymers, which can absorb water reversibly. |
| US5259705A (en) | 1989-08-25 | 1993-11-09 | Breaux Louis B | Guide box assembly system for in-ground barrier installation |
| JP2912500B2 (en) * | 1992-07-03 | 1999-06-28 | ライト工業株式会社 | How to build a continuous underground water barrier |
| WO1994018284A1 (en) | 1993-02-03 | 1994-08-18 | Aannemingsbedrijf Van Den Biggelaar Limburg B.V. | Clay-containing mixture and blend capable of forming a moisture rsistant gel, and use of that mixture and blend |
| DE4418629A1 (en) * | 1994-05-27 | 1995-11-30 | Sued Chemie Ag | Process for the production of sealing walls |
| JPH0849242A (en) * | 1994-08-04 | 1996-02-20 | Shimizu Corp | Underground structure and its construction method |
| EP0900883B1 (en) * | 1997-09-04 | 2002-03-20 | JOSEF MÖBIUS BAUGESELLSCHAFT (GmbH & Co.) | Method for making a column in the ground, which can carry loads from buildings or traffic |
| IT1304093B1 (en) * | 1998-12-10 | 2001-03-07 | Sibelon Srl | DAM IN LOOSE MATERIAL AND WATERPROOFING PROCEDURE |
| US6386796B1 (en) * | 2000-03-06 | 2002-05-14 | John H. Hull | Composite particles and methods for their application and implementation |
-
2000
- 2000-01-26 NL NL1014185A patent/NL1014185C2/en not_active IP Right Cessation
-
2001
- 2001-01-25 DE DE60101258T patent/DE60101258T2/en not_active Expired - Lifetime
- 2001-01-25 WO PCT/NL2001/000049 patent/WO2001055514A1/en not_active Ceased
- 2001-01-25 AT AT01906414T patent/ATE254699T1/en not_active IP Right Cessation
- 2001-01-25 CN CNB018042201A patent/CN1177977C/en not_active Expired - Fee Related
- 2001-01-25 EP EP01906414A patent/EP1250494B1/en not_active Expired - Lifetime
- 2001-01-25 JP JP2001554536A patent/JP2003520916A/en active Pending
- 2001-01-25 AU AU34242/01A patent/AU779942B2/en not_active Ceased
- 2001-01-25 US US10/181,920 patent/US20030111425A1/en not_active Abandoned
Non-Patent Citations (1)
| Title |
|---|
| See references of WO0155514A1 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010068087A1 (en) | 2008-12-03 | 2010-06-17 | Trisoplast International B.V. | Method for stimulating biodegradation and the degassing of waste disposal sites |
Also Published As
| Publication number | Publication date |
|---|---|
| DE60101258D1 (en) | 2003-12-24 |
| CN1423720A (en) | 2003-06-11 |
| AU3424201A (en) | 2001-08-07 |
| ATE254699T1 (en) | 2003-12-15 |
| DE60101258T2 (en) | 2004-08-05 |
| WO2001055514A1 (en) | 2001-08-02 |
| AU779942B2 (en) | 2005-02-17 |
| EP1250494B1 (en) | 2003-11-19 |
| JP2003520916A (en) | 2003-07-08 |
| NL1014185C2 (en) | 2001-07-27 |
| CN1177977C (en) | 2004-12-01 |
| US20030111425A1 (en) | 2003-06-19 |
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