EP1240374A2 - Dispersible nonwoven materials - Google Patents
Dispersible nonwoven materialsInfo
- Publication number
- EP1240374A2 EP1240374A2 EP00992741A EP00992741A EP1240374A2 EP 1240374 A2 EP1240374 A2 EP 1240374A2 EP 00992741 A EP00992741 A EP 00992741A EP 00992741 A EP00992741 A EP 00992741A EP 1240374 A2 EP1240374 A2 EP 1240374A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- fabric
- fibrous component
- fibrous
- fibers
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000463 material Substances 0.000 title description 10
- 239000004744 fabric Substances 0.000 claims abstract description 139
- 239000000835 fiber Substances 0.000 claims abstract description 136
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 46
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 46
- 238000000034 method Methods 0.000 claims abstract description 23
- 239000007864 aqueous solution Substances 0.000 claims description 28
- 239000000853 adhesive Substances 0.000 claims description 16
- 230000001070 adhesive effect Effects 0.000 claims description 16
- 239000004831 Hot glue Substances 0.000 claims description 9
- 239000006194 liquid suspension Substances 0.000 claims description 4
- 239000002657 fibrous material Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 68
- 239000002351 wastewater Substances 0.000 abstract description 2
- 239000000975 dye Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 6
- 239000012530 fluid Substances 0.000 description 4
- 239000010781 infectious medical waste Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000004065 wastewater treatment Methods 0.000 description 4
- 239000002699 waste material Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 240000009002 Picea mariana Species 0.000 description 2
- 235000017997 Picea mariana var. mariana Nutrition 0.000 description 2
- 235000018000 Picea mariana var. semiprostrata Nutrition 0.000 description 2
- 235000008565 Pinus banksiana Nutrition 0.000 description 2
- 241000218680 Pinus banksiana Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 208000015181 infectious disease Diseases 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000011122 softwood Substances 0.000 description 2
- 239000002910 solid waste Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 240000005020 Acaciella glauca Species 0.000 description 1
- 101000745895 Emericella nidulans (strain FGSC A4 / ATCC 38163 / CBS 112.46 / NRRL 194 / M139) Oligoxyloglucan-reducing end-specific xyloglucanase Proteins 0.000 description 1
- 101000745894 Neosartorya fischeri (strain ATCC 1020 / DSM 3700 / CBS 544.65 / FGSC A1164 / JCM 1740 / NRRL 181 / WB 181) Probable oligoxyloglucan-reducing end-specific xyloglucanase Proteins 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- -1 for example Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002906 medical waste Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 235000003499 redwood Nutrition 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/425—Cellulose series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4282—Addition polymers
- D04H1/4309—Polyvinyl alcohol
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/593—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives to layered webs
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/60—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in dry state, e.g. thermo-activatable agents in solid or molten state, and heat being applied subsequently
Definitions
- the present invention generally relates to a fabric for various uses, such as a garment, that can be disposed of using a liquid or aqueous solution. More particularly, the present invention is directed to a fabric having a hot water soluble component and a non-soluble component that is dispersible.
- one garment made by Isolyser Company, Inc.
- this garment which is described in more detail in U.S. Patent 5,268,222 to Honevcutt, contains a reusable component that is substantially insoluble in aqueous solutions such that it can be repeatedly relaundered and disinfected while a second component within the garment dissolves when contacted with hot water and washes down the drain.
- These fabrics can have increased strength over completely soluble fabrics.
- a fabric having a reusable component is not always desired.
- a fabric is required that can be completely disposed of using waste water disposal techniques, but that also has strength characteristics of a fabric containing a reusable component.
- a fabric of the present invention includes non-soluble, but generally dispersible pulp fibers and polyvinyl alcohol fibers that are soluble in hot water such that the resulting fabric can be disposed of using waste water treatment techniques, i.e. disposal of fabrics with hot water. It should be noted that any given range presented herein is intended to include any and all lesser included ranges.
- a range of from 45-90 would also include 50-90; 45-80; 46-89 and the like.
- the range of 95% to 99.999% also includes, for example, the ranges of 96% to 99.1 %, 96.3% to 99.7%, and 99.91 to 99.999%.
- any material known in the art to dissolve in aqueous solutions at high temperatures can generally be used as a hot water soluble component of the present invention.
- fibers that dissolve in aqueous solutions at temperatures above about 37°C can generally be used as the hot water soluble component of the present invention.
- fibers that dissolve in water at temperatures between about 80°C and about 95°C are employed.
- polyvinyl alcohol fibers that dissolve at the above temperature ranges are utilized as a hot water soluble component of the present invention.
- a fabric of the present invention also includes a dispersible non-soluble component.
- a dispersible component of the present invention can be made from any material that is capable of dispersing in an aqueous solution.
- the dispersible component is made from pulp fibers either alone or in combination with other fibers. It has been discovered that the addition of a dispersible component, such as pulp fibers can provide strength and dimensional stability to the fabric and can also allow the fabric to be completely disposed of by waste water treatment techniques
- a dispersible component of the present invention typically comprises less than about 55% by weight of the total content of the fabric. In one embodiment, the dispersible component comprises less than about 40%, and in particular, less than about 20% of the total content of the fabric.
- any material that does not affect the solubility and/or dispersability of the fabric components can be added.
- dyes can be applied to the fabric to impart color.
- surface chemicals can be applied to impart water or alcohol repellancy to the fabric surface.
- the dispersible component can also be entangled with the hot water soluble component to further increase the strength of a fabric formed therefrom.
- Any known method of entangling fibers such as air entangling or hydraulic (hydro) entangling, can be used. Hydraulic entangling may be accomplished utilizing conventional hydraulic entangling equipment such as may be found in, for example, in U.S.
- the hydraulic entangling of the present invention may be carried out with any appropriate working fluid such as, for example, water.
- the working fluid flows through a manifold which evenly distributes the fluid to a series of individual holes or orifices. These holes or orifices may be from about 0.003 to about 0.015 inch in diameter.
- the invention may be practiced utilizing a manifold produced by Honeycomb Systems Incorporated of Biddeford, Maine, containing a strip having 0.007 inch diameter orifices, 30 holes per inch, and 1 row of holes.
- Many other manifold configurations and combinations may be used.
- a single manifold may be used or several manifolds may be arranged in succession.
- the dispersible component e.g. pulp fibers
- the hot water soluble component e.g. polyvinyl alcohol fibers
- each component can be mixed with cold water to form a liquid suspension of fibrous material which is thereafter formed into a web and hydraulically entangled.
- any other method of forming and/or entangling a fabric that is known in the art can be used to produce a fabric of the present invention.
- the hot water soluble and dispersible components can also be formed into a multi-ply structure.
- a multi- component structure of the present invention can have two or more layers.
- the hot water soluble component can be adhered to the dispersible component with a dispersible adhesive.
- the adhesive is a hot melt adhesive that disperses in a pH greater than about 8.
- the adhesive disperses in a pH greater than about 9.
- Such a pH sensitive adhesive can enhance the ability of a fabric to be disposed of in alkaline-aqueous solutions sometimes used in medical applications.
- Fabrics having a multi-component structure can also be entangled as described above. Specifically, one or more components, or the entire fabric, can be hydroentangled to enhance strength characteristics of the fabric.
- one of the layers of the multi-component structure is made from pulp fibers that have been hydroentangled.
- the multi- component structure includes a web of polyvinyl alcohol fibers adhered to a web of pulp fibers. The entire multi-component structure, in this embodiment, can be entangled such that the pulp fibers sufficiently entangle with the polyvinyl alcohol fibers to increase the strength of the fabric.
- the present invention is directed to a fabric for various uses, such as a garment, that is dispersible when contacted with an aqueous solution.
- an aqueous solution can include any liquid or solution, such as water or solutions thereof.
- a fabric of the present invention contains at least one component that is soluble in hot water and at least one component that is dispersible, but not completely soluble. It has been discovered that a fabric of the present invention can partially dissolve in hot water to aid in waste management. Moreover, it has also been discovered that a fabric of the present invention can retain enhanced strength characteristics and dimensional integrity during everyday use.
- polyvinyl alcohol fibers and pulp fibers are incorporated into a fabric such that the polyvinyl alcohol fibers can dissolve when the fabric is contacted with hot water, whereas the pulp fibers only disperse into individual fibers.
- a fabric of the present invention includes at least one hot water soluble component.
- hot water generally refers to liquids having a temperature sufficient to dissolve a component
- cold water generally refers to liquids having any other temperature.
- the hot water soluble fibers of the present invention are normally dissolvable at temperatures above about 37°C. In one embodiment, the fibers dissolve in water at temperatures above about 80°C, and in particular, between about
- the hot water soluble component is made from polyvinyl alcohol fibers.
- polyvinyl alcohol fibers are those that dissolve in water at a temperature between about 80°C to about 95°C.
- polyvinyl alcohol fibers are provided that dissolve in water at 92°C.
- polyvinyl alcohol fibers are provided that dissolve in water at 80°C.
- Commercially available polyvinyl alcohol fibers that are suitable for use in the present invention are VPB 201 or 304 staple fibers made by Kuraray Company, Ltd. (Japan).
- Other examples of suitable polyvinyl alcohol fibers are disclosed in U.S. Patent No. 5,268,222 to Honevcutt, which is herein incorporated by reference.
- a fabric of the present invention also includes at least one component that is dispersible. It has been discovered that a fabric of the present invention can have increased dimensional stability and strength by utilizing dispersible fibers in conjunction with hot water soluble fibers, as described above. Moreover, although a fabric of the present invention is not completely hydrolytically degradable, it can nevertheless be substantially disposed of when the hot water soluble fibers dissolve in a hot liquid. Any material that is dispersible in water can generally be used as a dispersible component of the present invention. In particular, components that are dispersible and do not significantly affect the solubility of other components within the fabric can be utilized in accordance with the present invention.
- the hot water dispersible component is made from pulp fibers either alone or in combination with other fibers.
- the pulp fibers can be softwood fibers having an average fiber length of greater than 1 mm and particularly from about 2 to 5 mm based on a length-weighted average.
- Such fibers can include Northern softwood kraft fibers, redwood fibers, pine fibers, spruce fibers, or a combination thereof. Secondary fibers obtained from recycled materials may also be used.
- a dispersible component of the present invention is made from about 50%-70% black spruce fibers and about 25%-50% jack pine fibers.
- anionic or cationic dyes can be used to impart a particular color to the resulting fabric.
- An example of an anionic dye suitable for use in the present invention is Pergasol Blue 2R made by Ciba Specialty
- a dye can generally be applied to a fabric of the present invention by any manner known in the art, such as by saturating the fabric in the dye or utilizing a weir device installed onto a hydroentangling line.
- surface chemicals can also be added to the fabric to provide water or alcohol repellancy.
- the fabric is made from polyvinyl alcohol and pulp fibers. It should be understood, however, that various other components and/or materials may be used in accordance with the present invention and that the following description is for exemplary purposes only. In particular, it should be understood that the following concentration ranges and parameters can widely vary depending upon the particular application.
- a fabric of the present invention typically contains a hot water soluble component.
- the hot water soluble component is made from polyvinyl alcohol fibers.
- the hot water soluble component can be formed into a web using any technique known in the art for making nonwoven webs. Such nonwoven techniques useful for making polymer sheets include spun bonding, melt blowing, wet laying, hydroentangling with cold water, and/or thermally bonding.
- the hot water soluble component is carded into a carded web as is well-known in the art.
- a web of polyvinyl alcohol fibers is formed by carding the fibers into a carded web.
- the fibers can also be cross-layed (cross-lapped) in the machine direction and/or cross machine direction and thereafter thermally bonded to achieve further strength.
- the web of polyvinyl alcohol fibers has a basis weight above about 40 grams per square meter.
- one embodiment of a fabric of the present invention also includes a generally non-soluble, dispersible component that includes pulp fibers either alone or in combination with other fibers.
- the strength of the fabric can often increase proportionately.
- the pulp fibers typically comprise up to about 55% of the fabric by weight.
- the pulp fibers comprise up to about 40% by weight of the fabric, and even more preferably, up to about 20%.
- the pulp fibers comprise 37% by weight of the fabric.
- the pulp fibers comprise 17% by weight of the fabric.
- dispersible fibers When adding dispersible fibers, it is typically desired to entangle the fibers with the hot water soluble fibers to form a stronger web.
- any method known in the art such as air entangling or hydraulic entangling, can be used in the present invention to entangle different fibers together.
- dispersible fibers are entangled into a web of hot water soluble fibers.
- dispersible fibers are combined with hot water soluble fibers in a liquid suspension to form a web that is thereafter entangled.
- a sheet of dispersible fibers is adhered to a sheet of hot water soluble fibers by an adhesive to form a multi-component structure that is thereafter entangled.
- other methods of entangling dispersible fibers with hot water soluble fibers are equally suitable and can be used in the present invention.
- pulp fibers are hydraulically entangled into a carded web of polyvinyl alcohol fibers to form a fabric having increased strength.
- Hydroentangled webs which are also known as spunlace webs, refer to webs that have been subjected to columnar jets of a fluid that cause the fibers in the web to entangle.
- hydroentangling can increase the strength of the web by entangling the shorter fibers around the longer fibers.
- the strength of the fabric can be increased by hydraulically entangling the dispersible fibers into a web of hot water soluble fibers.
- Another embodiment of a fabric made according to the present invention can include the use of hot water soluble fibers, dispersible fibers, and an adhesive that is dispersible in an aqueous environment.
- Suitable hot melt adhesives for example, are described in U.S. Patent
- Strelow No. 5,527,845 to Strelow et al.. which is incorporated herein by reference.
- One such adhesive disclosed in Strelow includes about 10% to about 80%, by weight, of an alkali soluble polymer; about 0 to about 30%, by weight, of a poly (vinyl methyl ether); about 30% to about 70%, by weight, of a tackifying resin; and about 5% to about
- suitable plasticizer 30%, by weight, of a suitable plasticizer.
- suitable adhesives include HX 9236-01 or HX 9237-01 hot melt adhesives, which are obtainable from ATO Findley, Inc..
- the hot melt adhesive is also capable of dispersing in an alkaline aqueous solution.
- a pH sensitive adhesive can result in a fabric that is compatible with dispersion techniques and conditions used by hospitals. For instance, hospitals typically prefer to dispose of fabrics using an aqueous-alkali bath containing detergent and bleach (or other suitable caustics). Many of these baths have a pH of about 8 or greater.
- a fabric of the present invention can include an adhesive that disperses in an aqueous environment having a pH greater than about 8, and in other embodiments, greater than about 9. It should be understood, however, that adhesives which disperse at pH levels less than about 8 can also be utilized in the present invention, particularly when used in applications that employ an aqueous solution having a pH less than about 8 to dispose of a fabric.
- a multi-component fabric of the present invention can be formed as follows. It should be understood, however, that a multi-component fabric of the present invention is not limited to the particular embodiment described below.
- hot water soluble polyvinyl alcohol fibers can be formed into a web of carded staple fibers and thermally point bonded into a fabric. Thereafter, a hot melt adhesive, such as meltblown fibers of HX 9236-01 or HX 9237-01 hot melt adhesives, can be attached to the web of polyvinyl alcohol fibers.
- Various plies can then be applied to the carded web of polyvinyl alcohol fibers by the adhesive.
- a dispersible low strength tissue can be attached to the hot water soluble carded web of polyvinyl alcohol fibers by the hot melt adhesive.
- a low strength tissue can be made from pulp fibers.
- One commercially available example of such a water dispersible low strength tissue is Owensboro bath tissue base, type
- a second carded web or film of hot water soluble polyvinyl alcohol fibers can be attached onto the first carded web of polyvinyl alcohol fibers by the hot melt adhesive.
- either one or more layers of the structure can be entangled.
- the resulting multi- component structure can be hydraulically entangled as described above to provide further strength to the fabric.
- pulp fibers are adhered to polyvinyl alcohol fibers as described above, the resulting multi-component structure can also be hydraulically entangled to form a stronger fabric.
- EXAMPLE The ability of a fabric of the present invention to provide increased strength was demonstrated.
- Two types of polyvinyl alcohol fibers were used as the hot water soluble component for the samples, i.e. one being soluble in water at 80°C (VPB 201), the other being soluble in water at 92°C (VPB 304).
- Samples A & B contained VPB 201 fibers bonded at temperatures of 386°F and 390°F, respectively.
- Samples C, D, and E contained VPB 304 fibers bonded at temperatures of 390°F, 440°F, and 440°F, respectively.
- the bonding of the polyvinyl alcohol fibers above was achieved using thermal point bonding without the addition of any additives.
- Various characteristics of Samples A - E are shown below.
- pulp fibers were wet formed onto a forming wire and then transferred onto the various samples.
- a pulp stock (12 lbs of 50%-70% black spruce fibers and 25%-50% jack pine fibers, per 3000 gallons of water) was used as the dispersible component for each sample.
- the conditions and equipment utilized were similar to that of U.S. Patent No. 5,587,225 to Griesbach et al.. which is incorporated herein by reference.
- pilot line equipment which includes 103 A-M PET hydroentangling wire, 6/40/1 strips in each manifold, and three manifolds, was used for the appropriate hydroentangling.
- the tensile strength was determined using modified ASTM methods E4-83a and E74-93. In particular, this test used a 3" x 6" specimen with the long direction corresponding to the orthogonal direction, having the least amount of fibers orientation (cross direction or CD) after fabrication. The entire width of the specimen is held between 1" x 3" jaws spaced 3 inches apart. As the specimen was extended at 300 mm/min, the resisting force was measured with respect to the amount of extension. The tensile strength was the maximum load before the specimen ruptures. For each sample and set of conditions, multiple specimens were tested to determine tensile strength. The average of these tensile strength values was calculated for each set of conditions and reported in
- Tables 2-6 The data for each of Tables 2-6 are arranged in ascending order based on the ratio of normalized strength values as compared to the normalized strength of the sample with 100% polyvinyl alcohol fibers as indicated in Table 1.
- the normalized strength values generally measure strength increases or decreases based on hydroentangling and pulp content conditions, taking into account that the fabric will inevitably have some increase in strength due to increases in other parameters such as basis weight. The results are shown below in Tables 2-6. TABLE 2: Impact of Pulp and Hydroentangling on Strength of
- Tables 2-6 clearly demonstrate that hydroentangling and pulp content can increase the strength of a fabric.
- a fabric containing only underbonded polyvinyl alcohol fibers generally increased in strength after hydroentangling.
- pulp was added to the fabric and hydroentangling was utilized, the normalized strength values increased dramatically.
- Tables 4-6 also demonstrated the ability of pulp content and hydroentangling to increase strength.
- the normalized strengths for the hydroentangled fabrics increased in almost every instance.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Paper (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A fabric having a hot water soluble component and a generally non-soluble, dispersible component is provided. The fabric can be disposed of using conventional waste water management techniques. The hot water soluble component can include polyvinyl alcohol fibers that dissolve at temperatures greater than 37 °C. The generally non-soluble, dispersible component can include pulp fibers. The generally non-soluble, dispersible component can be entangled with the hot water soluble component using various methods, such as hydraulic entangling.
Description
DISPERSIBLE NONWOVEN MATERIALS Field of the Invention
The present invention generally relates to a fabric for various uses, such as a garment, that can be disposed of using a liquid or aqueous solution. More particularly, the present invention is directed to a fabric having a hot water soluble component and a non-soluble component that is dispersible.
Background of the Invention Hospital patient care can generate considerable quantities of infectious medical waste in primary and acute care facilities. One of the substantial components of such medical waste is disposable fabrics or garments. Typically, hospitals employ disposable garments and other fabrics to prevent the spread of infection to hospital workers and/or patients through the reuse of a fabric.
While such fabrics effectively inhibit infection, they must be disposed of in some manner. One way that these fabrics can be disposed is by using conventional solid waste management techniques. For instance, it is estimated that disposable medical fabrics comprise approximately one-half of infectious waste (0.5 million tons) generated by operating rooms each year. While this type of infectious waste may only contribute a small percentage of the total solid waste generated by hospitals yearly, the cost to dispose of such waste (as well as other infectious waste types) can be significantly greater than the costs of disposing of general waste.
As a result, disposable fabrics and garments have been developed that can be disposed of in alternative ways. In particular, fabrics were developed that would completely dissolve in hot water. For example, one such fabric, which is described in U.S. Patent No. 5,207,837 to Honevcutt, discloses a fabric made from polyvinyl alcohol fibers that is completely soluble in water at certain temperatures. This fabric can also be hydroentangled and/or
thermally bonded. However, one of the problems of such completely soluble fabrics is that they lack sufficient strength and dimensional stability.
In addition to fabrics that are completely soluble in hot water, other fabrics have been developed that are only partially soluble in hot water. For example, one garment (OREX®), made by Isolyser Company, Inc., can be partially dissolved in hot water. In particular, this garment, which is described in more detail in U.S. Patent 5,268,222 to Honevcutt, contains a reusable component that is substantially insoluble in aqueous solutions such that it can be repeatedly relaundered and disinfected while a second component within the garment dissolves when contacted with hot water and washes down the drain. These fabrics can have increased strength over completely soluble fabrics. However, despite the benefits of such fabrics, a fabric having a reusable component is not always desired. In many instances, for example, a fabric is required that can be completely disposed of using waste water disposal techniques, but that also has strength characteristics of a fabric containing a reusable component. As such, a need currently exists for a strong fabric that can be partially dissolved in hot water and that does not have a reusable component such that the entire fabric can be disposed of with waste water treatment methods.
Summary of the Invention The present invention recognizes and addresses the foregoing disadvantages and drawbacks of prior art constructions. Objects and additional advantages of the invention will be set forth in part in the following description, or may be obvious from the description, or may be learned through practice of the invention. These and other objects of the present invention are achieved by providing a fabric containing a hot water soluble component and a dispersible component. In one embodiment, a fabric of the present
invention includes non-soluble, but generally dispersible pulp fibers and polyvinyl alcohol fibers that are soluble in hot water such that the resulting fabric can be disposed of using waste water treatment techniques, i.e. disposal of fabrics with hot water. It should be noted that any given range presented herein is intended to include any and all lesser included ranges. For example, a range of from 45-90 would also include 50-90; 45-80; 46-89 and the like. Thus, the range of 95% to 99.999% also includes, for example, the ranges of 96% to 99.1 %, 96.3% to 99.7%, and 99.91 to 99.999%. In accordance with the present invention, any material known in the art to dissolve in aqueous solutions at high temperatures can generally be used as a hot water soluble component of the present invention. In particular, fibers that dissolve in aqueous solutions at temperatures above about 37°C can generally be used as the hot water soluble component of the present invention. In one embodiment, fibers that dissolve in water at temperatures between about 80°C and about 95°C are employed. For example, in one embodiment of the present invention, polyvinyl alcohol fibers that dissolve at the above temperature ranges are utilized as a hot water soluble component of the present invention.
In addition to a hot water soluble component, a fabric of the present invention also includes a dispersible non-soluble component. In general, a dispersible component of the present invention can be made from any material that is capable of dispersing in an aqueous solution. For example, in one embodiment, the dispersible component is made from pulp fibers either alone or in combination with other fibers. It has been discovered that the addition of a dispersible component, such as pulp fibers can provide strength and dimensional stability to the fabric and can also allow the fabric to be completely disposed of by waste water treatment techniques
In some applications, it is desired that the residue of the dispersible component remaining after the fabric is contacted with hot
water be minimized to ease in later waste water treatment. As such, a dispersible component of the present invention, such as pulp fibers, typically comprises less than about 55% by weight of the total content of the fabric. In one embodiment, the dispersible component comprises less than about 40%, and in particular, less than about 20% of the total content of the fabric.
Besides the above-mentioned components, other materials and/or chemicals can be generally added to a fabric of the present invention. In particular, any material that does not affect the solubility and/or dispersability of the fabric components can be added. For example, dyes can be applied to the fabric to impart color. Moreover, surface chemicals can be applied to impart water or alcohol repellancy to the fabric surface.
In accordance with the present invention, the dispersible component can also be entangled with the hot water soluble component to further increase the strength of a fabric formed therefrom. Any known method of entangling fibers, such as air entangling or hydraulic (hydro) entangling, can be used. Hydraulic entangling may be accomplished utilizing conventional hydraulic entangling equipment such as may be found in, for example, in U.S.
Pat. Nos. 3,485,706 to Evans or 5,389,202 to Everhart et al.. the disclosures of which are hereby incorporated by reference. The hydraulic entangling of the present invention may be carried out with any appropriate working fluid such as, for example, water. The working fluid flows through a manifold which evenly distributes the fluid to a series of individual holes or orifices. These holes or orifices may be from about 0.003 to about 0.015 inch in diameter. For example, the invention may be practiced utilizing a manifold produced by Honeycomb Systems Incorporated of Biddeford, Maine, containing a strip having 0.007 inch diameter orifices, 30 holes per inch, and 1 row of holes. Many other manifold configurations and combinations may be used. For example, a single manifold may be used or several
manifolds may be arranged in succession.
As such, in one embodiment of the present invention, the dispersible component, e.g. pulp fibers, is hydraulically entangled into a web of the hot water soluble component, e.g. polyvinyl alcohol fibers, to form a fabric of the present invention. In another embodiment, each component can be mixed with cold water to form a liquid suspension of fibrous material which is thereafter formed into a web and hydraulically entangled. Even if not specifically mentioned herein, any other method of forming and/or entangling a fabric that is known in the art can be used to produce a fabric of the present invention.
Generally, the hot water soluble and dispersible components can also be formed into a multi-ply structure. In particular, a multi- component structure of the present invention can have two or more layers. For example, in one embodiment, the hot water soluble component can be adhered to the dispersible component with a dispersible adhesive. In one embodiment, the adhesive is a hot melt adhesive that disperses in a pH greater than about 8. In another embodiment, the adhesive disperses in a pH greater than about 9. Such a pH sensitive adhesive can enhance the ability of a fabric to be disposed of in alkaline-aqueous solutions sometimes used in medical applications.
Fabrics having a multi-component structure can also be entangled as described above. Specifically, one or more components, or the entire fabric, can be hydroentangled to enhance strength characteristics of the fabric. For example, in one embodiment, one of the layers of the multi-component structure is made from pulp fibers that have been hydroentangled. In another embodiment, the multi- component structure includes a web of polyvinyl alcohol fibers adhered to a web of pulp fibers. The entire multi-component structure, in this embodiment, can be entangled such that the pulp fibers sufficiently entangle with the polyvinyl alcohol fibers to increase the strength of the fabric.
Other objects, features and aspects of the present invention are discussed in greater detail below.
Detailed Description Reference now will be made in detail to various embodiments of the invention, one or more examples of which are set forth below.
Each example is provided by way of explanation of the invention, not limitation of the invention. In fact, it will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the scope or spirit of the invention. For instance, features illustrated or described as part of one embodiment, can be used on another embodiment to yield a still further embodiment. Thus, it is intended that the present invention cover such modifications and variations as come within the scope of the appended claims and their equivalents. Other objects, features and aspects of the present invention are disclosed in or are obvious from the following detailed description. It is to be understood by one of ordinary skill in the art that the present discussion is of exemplary embodiments only, and is not intended as limiting the broader aspects of the present invention. In general, the present invention is directed to a fabric for various uses, such as a garment, that is dispersible when contacted with an aqueous solution. It should be understood that an aqueous solution can include any liquid or solution, such as water or solutions thereof. In particular, a fabric of the present invention contains at least one component that is soluble in hot water and at least one component that is dispersible, but not completely soluble. It has been discovered that a fabric of the present invention can partially dissolve in hot water to aid in waste management. Moreover, it has also been discovered that a fabric of the present invention can retain enhanced strength characteristics and dimensional integrity during everyday use.
For example in one embodiment, polyvinyl alcohol fibers and pulp fibers are incorporated into a fabric such that the polyvinyl alcohol
fibers can dissolve when the fabric is contacted with hot water, whereas the pulp fibers only disperse into individual fibers.
As stated, a fabric of the present invention includes at least one hot water soluble component. As used herein, "hot water" generally refers to liquids having a temperature sufficient to dissolve a component, whereas "cold water" generally refers to liquids having any other temperature. In particular, the hot water soluble fibers of the present invention are normally dissolvable at temperatures above about 37°C. In one embodiment, the fibers dissolve in water at temperatures above about 80°C, and in particular, between about
80°C to about 95°C.
Any fibers that can be dissolved in water or an aqueous solution having a certain temperature, such as above about 37°C, can generally be used in the present invention as the hot water soluble component. In one embodiment, the hot water soluble component is made from polyvinyl alcohol fibers. As stated above, one embodiment of polyvinyl alcohol fibers are those that dissolve in water at a temperature between about 80°C to about 95°C. In one embodiment, for example, polyvinyl alcohol fibers are provided that dissolve in water at 92°C. In another embodiment, polyvinyl alcohol fibers are provided that dissolve in water at 80°C. Commercially available polyvinyl alcohol fibers that are suitable for use in the present invention are VPB 201 or 304 staple fibers made by Kuraray Company, Ltd. (Japan). Other examples of suitable polyvinyl alcohol fibers are disclosed in U.S. Patent No. 5,268,222 to Honevcutt, which is herein incorporated by reference.
In accordance with the present invention, a fabric of the present invention also includes at least one component that is dispersible. It has been discovered that a fabric of the present invention can have increased dimensional stability and strength by utilizing dispersible fibers in conjunction with hot water soluble fibers, as described above. Moreover, although a fabric of the present invention is not completely
hydrolytically degradable, it can nevertheless be substantially disposed of when the hot water soluble fibers dissolve in a hot liquid. Any material that is dispersible in water can generally be used as a dispersible component of the present invention. In particular, components that are dispersible and do not significantly affect the solubility of other components within the fabric can be utilized in accordance with the present invention. In one embodiment, the hot water dispersible component is made from pulp fibers either alone or in combination with other fibers. For instance, the pulp fibers can be softwood fibers having an average fiber length of greater than 1 mm and particularly from about 2 to 5 mm based on a length-weighted average. Such fibers can include Northern softwood kraft fibers, redwood fibers, pine fibers, spruce fibers, or a combination thereof. Secondary fibers obtained from recycled materials may also be used. In a preferred embodiment, a dispersible component of the present invention is made from about 50%-70% black spruce fibers and about 25%-50% jack pine fibers.
In addition to the above components, other chemicals and/or additives can also be employed in forming a fabric of the present invention. In general, any chemical that does not significantly affect the solubility and/or dispersability of fibers within a fabric of the present invention can be added. For instance, in one embodiment, anionic or cationic dyes can be used to impart a particular color to the resulting fabric. An example of an anionic dye suitable for use in the present invention is Pergasol Blue 2R made by Ciba Specialty
Chemicals. Moreover, an example of a suitable cationic dye is Cartsol Blue GDF. A dye can generally be applied to a fabric of the present invention by any manner known in the art, such as by saturating the fabric in the dye or utilizing a weir device installed onto a hydroentangling line. In addition to dyes, surface chemicals can also be added to the fabric to provide water or alcohol repellancy.
Various embodiments of a fabric made according to the present
invention will now be described. In one embodiment, the fabric is made from polyvinyl alcohol and pulp fibers. It should be understood, however, that various other components and/or materials may be used in accordance with the present invention and that the following description is for exemplary purposes only. In particular, it should be understood that the following concentration ranges and parameters can widely vary depending upon the particular application.
In this regard, a fabric of the present invention typically contains a hot water soluble component. In one embodiment, the hot water soluble component is made from polyvinyl alcohol fibers. Moreover, in some embodiments, the hot water soluble component can be formed into a web using any technique known in the art for making nonwoven webs. Such nonwoven techniques useful for making polymer sheets include spun bonding, melt blowing, wet laying, hydroentangling with cold water, and/or thermally bonding.
In addition, in one embodiment, the hot water soluble component is carded into a carded web as is well-known in the art. For example, in a preferred embodiment, a web of polyvinyl alcohol fibers is formed by carding the fibers into a carded web. Although not required, the fibers can also be cross-layed (cross-lapped) in the machine direction and/or cross machine direction and thereafter thermally bonded to achieve further strength. In one embodiment, the web of polyvinyl alcohol fibers has a basis weight above about 40 grams per square meter. As discussed above, one embodiment of a fabric of the present invention also includes a generally non-soluble, dispersible component that includes pulp fibers either alone or in combination with other fibers. In general, by increasing the amount of pulp fibers added, the strength of the fabric can often increase proportionately. For example, the pulp fibers typically comprise up to about 55% of the fabric by weight. In one embodiment, the pulp fibers comprise up to about 40% by weight of the fabric, and even more preferably, up to about 20%.
For instance, in one embodiment, the pulp fibers comprise 37% by weight of the fabric. In another embodiment, the pulp fibers comprise 17% by weight of the fabric. Although it is normally desired to utilize such low levels of pulp fibers, it should also be understood that the acceptable range of pulp fiber concentrations can vary drastically depending on the particular application as well as on the amount and type of other materials present. Thus, pulp fiber concentrations greater those recited above may be equally suitable in some embodiments. When adding dispersible fibers, it is typically desired to entangle the fibers with the hot water soluble fibers to form a stronger web. In particular, any method known in the art, such as air entangling or hydraulic entangling, can be used in the present invention to entangle different fibers together. For example, in one embodiment, dispersible fibers are entangled into a web of hot water soluble fibers.
In another embodiment, dispersible fibers are combined with hot water soluble fibers in a liquid suspension to form a web that is thereafter entangled. In still another embodiment, a sheet of dispersible fibers is adhered to a sheet of hot water soluble fibers by an adhesive to form a multi-component structure that is thereafter entangled. In addition to the above mentioned embodiments, other methods of entangling dispersible fibers with hot water soluble fibers are equally suitable and can be used in the present invention.
In one embodiment, pulp fibers are hydraulically entangled into a carded web of polyvinyl alcohol fibers to form a fabric having increased strength. Hydroentangled webs, which are also known as spunlace webs, refer to webs that have been subjected to columnar jets of a fluid that cause the fibers in the web to entangle. Particularly when fibers of different lengths are present, hydroentangling can increase the strength of the web by entangling the shorter fibers around the longer fibers. Thus, according to the present invention, the strength of the fabric can be increased by hydraulically entangling the
dispersible fibers into a web of hot water soluble fibers.
Another embodiment of a fabric made according to the present invention can include the use of hot water soluble fibers, dispersible fibers, and an adhesive that is dispersible in an aqueous environment. Suitable hot melt adhesives, for example, are described in U.S. Patent
No. 5,527,845 to Strelow et al.. which is incorporated herein by reference. One such adhesive disclosed in Strelow includes about 10% to about 80%, by weight, of an alkali soluble polymer; about 0 to about 30%, by weight, of a poly (vinyl methyl ether); about 30% to about 70%, by weight, of a tackifying resin; and about 5% to about
30%, by weight, of a suitable plasticizer. Examples of suitable adhesives include HX 9236-01 or HX 9237-01 hot melt adhesives, which are obtainable from ATO Findley, Inc..
In one embodiment, the hot melt adhesive is also capable of dispersing in an alkaline aqueous solution. The use of such a pH sensitive adhesive can result in a fabric that is compatible with dispersion techniques and conditions used by hospitals. For instance, hospitals typically prefer to dispose of fabrics using an aqueous-alkali bath containing detergent and bleach (or other suitable caustics). Many of these baths have a pH of about 8 or greater. Thus, in some embodiments, a fabric of the present invention can include an adhesive that disperses in an aqueous environment having a pH greater than about 8, and in other embodiments, greater than about 9. It should be understood, however, that adhesives which disperse at pH levels less than about 8 can also be utilized in the present invention, particularly when used in applications that employ an aqueous solution having a pH less than about 8 to dispose of a fabric.
One example of a multi-component fabric of the present invention can be formed as follows. It should be understood, however, that a multi-component fabric of the present invention is not limited to the particular embodiment described below. In this regard, hot water soluble polyvinyl alcohol fibers can be formed into a web of carded
staple fibers and thermally point bonded into a fabric. Thereafter, a hot melt adhesive, such as meltblown fibers of HX 9236-01 or HX 9237-01 hot melt adhesives, can be attached to the web of polyvinyl alcohol fibers. Various plies can then be applied to the carded web of polyvinyl alcohol fibers by the adhesive. For example, in one embodiment, a dispersible low strength tissue can be attached to the hot water soluble carded web of polyvinyl alcohol fibers by the hot melt adhesive. Typically, a low strength tissue can be made from pulp fibers. One commercially available example of such a water dispersible low strength tissue is Owensboro bath tissue base, type
72000 made by Kimberly-Clark Corporation of Neenah, Wisconsin. Moreover, in another embodiment, a second carded web or film of hot water soluble polyvinyl alcohol fibers can be attached onto the first carded web of polyvinyl alcohol fibers by the hot melt adhesive. In general, when forming a multi-component structure according to the present invention, either one or more layers of the structure can be entangled. For example, when dispersible fibers are adhered to hot water soluble fibers as described above, the resulting multi- component structure can be hydraulically entangled as described above to provide further strength to the fabric. In one embodiment, when pulp fibers are adhered to polyvinyl alcohol fibers as described above, the resulting multi-component structure can also be hydraulically entangled to form a stronger fabric.
The present invention may be better understood with reference to the following examples.
EXAMPLE The ability of a fabric of the present invention to provide increased strength was demonstrated. Two types of polyvinyl alcohol fibers were used as the hot water soluble component for the samples, i.e. one being soluble in water at 80°C (VPB 201), the other being soluble in water at 92°C (VPB 304).
As shown below in Table 1 , the five samples are represented
by the letters "A", "B", "C", "D", and "E". Samples A & B contained VPB 201 fibers bonded at temperatures of 386°F and 390°F, respectively. Samples C, D, and E contained VPB 304 fibers bonded at temperatures of 390°F, 440°F, and 440°F, respectively. The bonding of the polyvinyl alcohol fibers above was achieved using thermal point bonding without the addition of any additives. Various characteristics of Samples A - E are shown below.
Table 1 : Characteristics of Samples A - E
From the above samples, varying degrees of hydroentanglement and/or pulp content were tested. In particular, pulp fibers were wet formed onto a forming wire and then transferred onto the various samples. A pulp stock (12 lbs of 50%-70% black spruce fibers and 25%-50% jack pine fibers, per 3000 gallons of water) was used as the dispersible component for each sample. The conditions and equipment utilized were similar to that of U.S. Patent
No. 5,587,225 to Griesbach et al.. which is incorporated herein by reference. Specifically, pilot line equipment, which includes 103 A-M PET hydroentangling wire, 6/40/1 strips in each manifold, and three manifolds, was used for the appropriate hydroentangling. The strengths of the above sample fabrics at varying degrees of hydroentanglement and/or pulp content were then determined. Pulp content was varied for the samples by adjusting the degree of hydroentangling and the speed of the wire supporting the fibers under the hydroentangling manifolds. Moreover, various hydroentangling energies were utilized to determine the effect hydroentangling on fabric strength. Specifically, the energies (i.e. Energy/Mass) used are described in U.S. Patent No. 5,023,130 to Simpson et al.. which is incorporated herein by reference.
For each set of conditions, the tensile strength was determined using modified ASTM methods E4-83a and E74-93. In particular, this test used a 3" x 6" specimen with the long direction corresponding to the orthogonal direction, having the least amount of fibers orientation (cross direction or CD) after fabrication. The entire width of the specimen is held between 1" x 3" jaws spaced 3 inches apart. As the specimen was extended at 300 mm/min, the resisting force was measured with respect to the amount of extension. The tensile strength was the maximum load before the specimen ruptures. For each sample and set of conditions, multiple specimens were tested to determine tensile strength. The average of these tensile strength values was calculated for each set of conditions and reported in
Tables 2-6, along with the standard deviation for each average value.
The data for each of Tables 2-6 are arranged in ascending order based on the ratio of normalized strength values as compared to the normalized strength of the sample with 100% polyvinyl alcohol fibers as indicated in Table 1. The normalized strength values generally measure strength increases or decreases based on hydroentangling and pulp content conditions, taking into account that
the fabric will inevitably have some increase in strength due to increases in other parameters such as basis weight. The results are shown below in Tables 2-6. TABLE 2: Impact of Pulp and Hydroentangling on Strength of
Sample A
TABLE 3: Impact of Pulp and Hydroentangling on Strength of
Sample B
TABLE 4: Impact of Pulp and Hydroentangling on Strength of
Sample C
TABLE 5: Impact of Pulp and Hydroentangling on Strength of
Sample D
TABLE 6: impact of Pulp and Hydroentangling on Strength of
Sample E
The results shown in Tables 2-6 clearly demonstrate that hydroentangling and pulp content can increase the strength of a fabric. Referring to Tables 2 or 3, for example, a fabric containing only underbonded polyvinyl alcohol fibers generally increased in strength after hydroentangling. However, as pulp was added to the fabric and hydroentangling was utilized, the normalized strength values increased dramatically.
Similarly, Tables 4-6 also demonstrated the ability of pulp content and hydroentangling to increase strength. Fabrics containing only optimally bonded polyvinyl fibers, as shown in Table 4, 5, or 6, demonstrated a general decrease in strength after hydroentangling. In contrast, with the addition of pulp to the optimally bonded fibers, the normalized strengths for the hydroentangled fabrics increased in
almost every instance.
Although various embodiments of the invention have been described using specific terms, devices, and methods, such description is for illustrative purposes only. The words used are words of description rather than limitation. It is to be understood that changes and variations may be made by those of ordinary skill in the art without departing from the spirit or the scope of the present invention, which is set forth in the following claims. In addition, it should be understood that aspects of the various embodiments may be interchanged both in whole or in part. Therefore, the spirit and scope of the appended claims should not be limited to the description of the preferred versions contained therein.
Claims
1. A fabric comprising: a first fibrous component, said first fibrous component containing polyvinyl alcohol fibers that are soluble in an aqueous solution at temperatures sufficient to substantially dissolve said polyvinyl alcohol fibers; and a second fibrous component, said second fibrous component being generally non-soluble and dispersible in said aqueous solution, said second fibrous component being entangled with said first fibrous component.
2. A fabric as defined in claim 1 , wherein said second fibrous component comprises pulp fibers.
3. A fabric as defined in claim 1 , wherein said second fibrous component comprises less than about 55% by weight of said fabric.
4. A fabric as defined in claim 3, wherein said second fibrous component comprises less than about 40% by weight of said fabric.
5. A fabric as defined in claim 4, wherein said second fibrous component comprises less than about are 20% by weight of said fabric.
6. A fabric as defined in claim 1 , wherein said second fibrous component is hydraulically entangled with said polyvinyl alcohol fibers.
7. A fabric as defined in claim 1 , wherein said polyvinyl alcohol fibers dissolve in said aqueous solution at temperatures above about 37°C.
8. A fabric as defined in claim 1 , wherein said polyvinyl alcohol fibers dissolve in said aqueous solution at temperatures between about 80°C and about 95°C.
9. A fabric as defined in claim 1 , further comprising a dye for imparting color to said fabric.
10. A fabric as defined in claim 1 , wherein said first fibrous component is formed into a first fibrous web.
11. A fabric as defined in claim 10, wherein said second fibrous component is hydraulically entangled into said first fibrous web to form said fabric.
12. A fabric as defined in claim 10, wherein said second fibrous component is formed into a second fibrous web, said first fibrous web and said second fibrous web being formed into said fabric.
13. A fabric as defined in claim 12, further comprising an adhesive between said first fibrous web and said second fibrous web, said adhesive being dispersible in said aqueous solution when said aqueous solution has a pH greater than about 8.
14. A fabric as defined in claim 13, wherein said adhesive is a hot melt adhesive.
15. A fabric as defined in claim 12, wherein said second fibrous web comprises pulp fibers.
16. A fabric as defined in claim 12, wherein said second fibrous web comprises a tissue having a low wet-strength.
17. A fabric as defined in claim 10, wherein said first fibrous web has a basis weight above about 40 grams per square meter.
18. A fabric comprising: a first fibrous component, said first fibrous component containing polyvinyl alcohol fibers that are soluble in an aqueous solution at temperatures sufficient to substantially dissolve said polyvinyl alcohol fibers; and a second fibrous component, said second fibrous component containing pulp fibers that are generally non-soluble and dispersible in said aqueous solution, said second fibrous component being hydraulically entangled with said first fibrous component, said second fibrous component comprising less than about 55% by weight of said fabric.
19. A fabric as defined in claim 18, wherein said second fibrous component comprises less than about 40% by weight of said fabric.
20. A fabric as defined in claim 19, wherein said second fibrous component comprises less than about are 20% by weight of said fabric.
21. A fabric as defined in claim 18, wherein said polyvinyl alcohol fibers dissolve in said aqueous solution at temperatures above about 37°C.
22. A fabric as defined in claim 18, wherein said polyvinyl alcohol fibers dissolve in said aqueous solution at temperatures between about 80°C and about 95°C.
23. A fabric comprising: a first fibrous component, said first fibrous component containing polyvinyl alcohol fibers that are soluble in an aqueous solution at temperatures sufficient to substantially dissolve said polyvinyl alcohol fibers; and a second fibrous component, said second fibrous component containing pulp fibers that are generally non-soluble and dispersible in said aqueous solution, said second fibrous component comprising less than about 55% by weight of said fabric, said second fibrous component being hydraulically entangled with said first fibrous component to an extent such that said fabric has a normalized strength of at least about 100%.
24. A fabric as defined in claim 23, wherein said second fibrous component is hydraulically entangled with said first fibrous component to an extent such that said fabric has a normalized strength of at least 200%.
25. A fabric as defined in claim 23, wherein said second fibrous component is hydraulically entangled with said first fibrous component to an extent such that said fabric has a normalized strength greater than about 1000%.
26. A fabric as defined in claim 23, wherein said second fibrous component comprises less than about 40% by weight of said fabric.
27. A fabric as defined in claim 23, wherein said second fibrous component comprises less than about are 20% by weight of said fabric.
28. A method of forming a fabric comprising the steps of: providing a first fibrous component, said first fibrous component containing polyvinyl alcohol fibers that are soluble in an aqueous solution at temperatures sufficient to substantially dissolve said polyvinyl alcohol fibers in said aqueous solution; providing a second fibrous component, said second fibrous component containing pulp fibers that are generally non-soluble and dispersible in said aqueous solution; and entangling said second fibrous component with said first fibrous component.
29. A method as defined in claim 28, further comprising the step of: forming a first fibrous web from said first fibrous component, wherein said second fibrous component is entangled into said first fibrous web.
30. A method as defined in claim 29, wherein said second fibrous component is hydraulically entangled into said first fibrous web.
31. A method as defined in claim 28, further comprising the steps of: forming a liquid suspension from said first fibrous component and said second fibrous component; and forming a web of fibrous material from said liquid suspension prior to said entangling of said second fibrous component with said first fibrous component.
32. A method as defined in claim 31 , wherein said web of fibrous material is hydraulically entangled.
33. A method as defined in claim 28, further comprising the steps of: forming a first web from said first fibrous component; forming a second web from said second fibrous component; disposing a dispersible adhesive between said first web and said second web prior to said entangling of said second fibrous component and said first fibrous component.
34. A method as defined in claim 28, wherein said polyvinyl alcohol fibers are soluble in said aqueous solution at temperatures above about 37°C.
35. A method as defined in claim 28, wherein said polyvinyl alcohol fibers are soluble in said aqueous solution at temperatures between about 80°C and about 95°C.
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| US428811 | 1999-10-28 | ||
| PCT/US2000/041456 WO2001031103A2 (en) | 1999-10-28 | 2000-10-23 | Dispersible nonwoven materials |
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| EP1240374A2 true EP1240374A2 (en) | 2002-09-18 |
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| US7378360B2 (en) | 2003-12-17 | 2008-05-27 | Kimberly-Clark Worldwide, Inc. | Water dispersible, pre-saturated wiping products |
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| CA2070589C (en) * | 1991-12-19 | 2000-11-28 | Kimberly-Clark Corporation | Method of preparing a nonwoven web of poly (vinyl alcohol) fibers |
| US5948710A (en) * | 1995-06-30 | 1999-09-07 | Kimberly-Clark Worldwide, Inc. | Water-dispersible fibrous nonwoven coform composites |
| DE19620503A1 (en) * | 1996-05-22 | 1997-11-27 | Fleissner Maschf Gmbh Co | Process for the production of a fleece by hydromechanical needling and product according to this production process |
| US5986004A (en) * | 1997-03-17 | 1999-11-16 | Kimberly-Clark Worldwide, Inc. | Ion sensitive polymeric materials |
| SG83698A1 (en) * | 1998-01-16 | 2001-10-16 | Uni Charm Corp | Method of manufacturing a water disintegratable non-woven fabric and the water disintegratable non-woven fabric |
-
2000
- 2000-10-23 WO PCT/US2000/041456 patent/WO2001031103A2/en not_active Ceased
- 2000-10-23 EP EP00992741A patent/EP1240374A2/en not_active Withdrawn
- 2000-10-23 CA CA002389223A patent/CA2389223A1/en not_active Abandoned
- 2000-10-23 MX MXPA02004206A patent/MXPA02004206A/en not_active Application Discontinuation
- 2000-10-23 AU AU29170/01A patent/AU2917001A/en not_active Abandoned
- 2000-10-23 JP JP2001533234A patent/JP2003513175A/en active Pending
Non-Patent Citations (1)
| Title |
|---|
| See references of WO0131103A2 * |
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA02004206A (en) | 2002-10-17 |
| WO2001031103A2 (en) | 2001-05-03 |
| CA2389223A1 (en) | 2001-05-03 |
| AU2917001A (en) | 2001-05-08 |
| JP2003513175A (en) | 2003-04-08 |
| WO2001031103A3 (en) | 2002-01-10 |
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