EP1226591A1 - METHOD FOR MANUFACTURING A PERMANENT Fe-Pt MAGNET, AND THE PRODUCT OBTAINED THEREBY - Google Patents
METHOD FOR MANUFACTURING A PERMANENT Fe-Pt MAGNET, AND THE PRODUCT OBTAINED THEREBYInfo
- Publication number
- EP1226591A1 EP1226591A1 EP00971891A EP00971891A EP1226591A1 EP 1226591 A1 EP1226591 A1 EP 1226591A1 EP 00971891 A EP00971891 A EP 00971891A EP 00971891 A EP00971891 A EP 00971891A EP 1226591 A1 EP1226591 A1 EP 1226591A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- approximately
- atom
- temperature
- fusion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 6
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 27
- 239000000956 alloy Substances 0.000 claims abstract description 27
- 238000001953 recrystallisation Methods 0.000 claims abstract description 15
- 230000004927 fusion Effects 0.000 claims abstract description 13
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- 229910052742 iron Inorganic materials 0.000 claims abstract description 5
- 239000000155 melt Substances 0.000 claims abstract description 5
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 5
- 239000012298 atmosphere Substances 0.000 claims abstract description 4
- 230000002401 inhibitory effect Effects 0.000 claims abstract description 4
- OBACEDMBGYVZMP-UHFFFAOYSA-N iron platinum Chemical compound [Fe].[Fe].[Pt] OBACEDMBGYVZMP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 6
- 230000005291 magnetic effect Effects 0.000 claims description 6
- 238000000137 annealing Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 3
- 238000005339 levitation Methods 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 238000003466 welding Methods 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 239000007943 implant Substances 0.000 description 6
- 239000003302 ferromagnetic material Substances 0.000 description 4
- 239000000696 magnetic material Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 3
- 239000010955 niobium Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 229910001260 Pt alloy Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 210000001124 body fluid Anatomy 0.000 description 1
- 239000010839 body fluid Substances 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 210000004746 tooth root Anatomy 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
- A61C13/00—Dental prostheses; Making same
- A61C13/225—Fastening prostheses in the mouth
- A61C13/235—Magnetic fastening
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/032—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
- H01F1/04—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
- H01F1/047—Alloys characterised by their composition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
Definitions
- the invention relates to a method for manufacturing a permanent iron-platinum magnet suitable for fixing a prosthesis in or on a body, wherein an alloy is molten, which comprises at least 30 atom% of platinum, 0-5 atom% of a non-ferro metal, remainder iron, is cooled, after which it is optionally subjected to a recrystallization process .
- Permanent magnets have long been applied for fixing prostheses in or on the body of a user. To this end a ferromagnetic material is anchored in the body and the prosthesis is provided with a magnet exerting a magnetic force on the ferromagnetic material .
- the magnet For a firm attachment of the prosthesis, the magnet needs to be strong, but in addition, the ferromagnetic material in the body must be very readily magnetizable.
- the strongest known permanent magnetic materials are based on compositions of iron or cobalt with rare earth metals. Said magnets are very sus- ceptible to corrosion so that they have to be encapsulated in, for example, stainless steel in order to prevent the release of corrosion products in the body. The possibility exists that during use but also during the fabrication of the prostheses, the stainless steel capsule becomes dam- aged, with the result that within a very short time the magnet system ceases to work.
- DE-A-4027681 discloses a method of fixing a den- tal prosthesis where a magnet is located in the dental prosthesis and interacting with that, a head piece in the dental root.
- the magnet known from this publication comprises 33 to 47 atom% of platinum, rest iron, while the head piece is comprised of soft-magnetic stainless steel.
- the magnet further comprises preferably 0.1 to 10 atom% of an element selected from the group Ti , Mo, Nb, Ta, W, Cr and V. In this construction the implant may exhibit corrosion because the material of the magnet is nobler.
- the soft-magnetic material may then suitably be used as implant, while the prosthesis itself may then suitably the made in one piece from hard-magnetic materials. Soft -magnetic behaviour combined with highly spontaneous magnetisation and low remanence of the implant are important to create good adhesion.
- the method according to the invention is characterized in that the alloy is melted in an oxidation- inhibiting atmosphere, avoiding any contact of the melt with surfaces that have a temperature in the region of or higher than the alloy' s fusion temperature.
- the material obtained according to this method of the invention which material is based on a conventional alloy of iron and platinum, having a platinum content above 30 atom%, is very corrosion-resistant and may be implanted in the body without protective encapsulation.
- the material obtained by the method according to the invention differs from the material known from DE-A-4027681, which may indeed have the same general composition but which suffers from impurities that have a negative effect on the intended application as implant of soft-magnetic material.
- the method according to the invention effectively prevents the diffusion of material between melt and said surfaces, for example, a crucible, so that the melt stays as much as possible free from impurities.
- the inven- tors believe that such impurities, if not avoided, will form so-called pinning centres for magnetic domeins or Bloch walls.
- the melting step preferably involves welding arc fusion in a cold crucible.
- the person skilled in the art is quite familiar with this form of fusion and it requires no further explanation.
- the temperature of the crucible is preferably approximately 100°C below the fusion temperature of the alloy. More preferably the temperature difference is at least approximately 200°C.
- a second preferred embodiment of the method according to the invention is characterized in that the al- loy is molten by means of levitation fusion. Again, the person skilled in the art requires no further explanation. Levitation fusion ensures that there is no contact between the melt and the crucible.
- the method according to the invention differs from the known method as described in the above- mentioned article by atanabe and in DE-A-4026781 , in that the manner of operation is completely clean.
- fusion may be carried out in aluminium crucibles and the product is subsequently poured into quarts ampoules, which results in undesirable contamination of the product obtained by said method.
- an annealing treatment at a temperature in the vicinity of 1300°C.
- the annealing treatment takes approximately one hour.
- This provides a reproducibly homogenous solid solution of the components in the face-centred cubic gamma-iron structure of the alloy.
- the practically contamination- free material obtained by this method is magnetically soft, mechanically strong and very corrosion- resistant, and is especially suitable for use as implant.
- a further elaboration of the method according to the invention is characterized in that a recrystallization treatment is carried out; in order to conveniently control the speed of the recrystallization treatment it is desir- able that the non-ferro metal be selected from the group Nb, Zr, Ga and Ti and that the amount be approximately 1 atom% .
- the recrystallization is performed in a first preferred embodiment by heating for 20 to 80 hours in the range of 575-650°, preferably approximately 625°C. In this way a face-centred tetragonal phase is provided, making the material obtained by the method magnetically hard, mechanically strong and very corrosion resistant. This material is especially suitable to be applied in or as the prosthesis.
- the non-ferro metal advantageously is 0.1 to 0.4 atom% Al, preferably 0.25 atom%, so that after cooling, the recrystallization treatment can be carried out by heating the alloy to approximately 525°C for approximately 20 hours.
- the recrystallization treatment may be further accelerated by placing the alloy during the recrystallization treatment under at least approximately 2 bars of uni- axial pressure, and by heating the alloy at a maximum temperature of approximately 450°C for 2 to 3 hours. This also provides a very energy-efficient recrystallization treatment .
- a casting produced in this manner is very corrosion- resistant, is easy to polish, is mechanically strong, has a Vickers hardness of approximately 400, and, depending on whether or not it has undergone the above-mentioned recrystallization treatment, may have both soft- and hard- magnetic properties.
- the invention is also embodied in a permanent (hard) -magnetic product and a soft-magnetic product obtained by the method according to the invention.
Landscapes
- Health & Medical Sciences (AREA)
- Power Engineering (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Electromagnetism (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Physics & Mathematics (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Materials For Medical Uses (AREA)
- Prostheses (AREA)
Abstract
The invention relates to a method for manufacturing a permanent iron-platinum magnet suitable for fixing a prosthesis in or on a body, wherein an alloy is molten, which comprises at least 30 atom% of platinum, 0-5 atom% of a non-ferro metal, remainder iron, is cooled, after which it is optionally subjected to a recrystallization process. The alloy is melted in an oxidation-inhibiting atmosphere, avoiding any contact of the melt with surfaces that have a temperature in the region of or higher than the alloy's fusion temperature.
Description
Method for manufacturing a permanent Fe-Pt magnet, and the product obtained thereby
The invention relates to a method for manufacturing a permanent iron-platinum magnet suitable for fixing a prosthesis in or on a body, wherein an alloy is molten, which comprises at least 30 atom% of platinum, 0-5 atom% of a non-ferro metal, remainder iron, is cooled, after which it is optionally subjected to a recrystallization process . Permanent magnets have long been applied for fixing prostheses in or on the body of a user. To this end a ferromagnetic material is anchored in the body and the prosthesis is provided with a magnet exerting a magnetic force on the ferromagnetic material . For a firm attachment of the prosthesis, the magnet needs to be strong, but in addition, the ferromagnetic material in the body must be very readily magnetizable. The strongest known permanent magnetic materials are based on compositions of iron or cobalt with rare earth metals. Said magnets are very sus- ceptible to corrosion so that they have to be encapsulated in, for example, stainless steel in order to prevent the release of corrosion products in the body. The possibility exists that during use but also during the fabrication of the prostheses, the stainless steel capsule becomes dam- aged, with the result that within a very short time the magnet system ceases to work.
In the article by Kiyoshi atanabe, published in Materials Transactions, JIM, Vol. 32, No. 3 (1991), pp 292 to 298, it is reported that iron-platinum alloys with the addition of niobium possess good hard-magnetic properties. It is, however, not possible with the method according to said article, to realize soft-magnetic properties. The importance of this will be explained later.
DE-A-4027681 discloses a method of fixing a den- tal prosthesis where a magnet is located in the dental
prosthesis and interacting with that, a head piece in the dental root. The magnet known from this publication comprises 33 to 47 atom% of platinum, rest iron, while the head piece is comprised of soft-magnetic stainless steel. The magnet further comprises preferably 0.1 to 10 atom% of an element selected from the group Ti , Mo, Nb, Ta, W, Cr and V. In this construction the implant may exhibit corrosion because the material of the magnet is nobler.
It is the object of the invention to provide a ferromagnetic material that is suitable for fixing a prosthesis in or on the body of a user, and which provides a sufficiently strong attachment of the prosthesis. It is desirable to be able to provide both material that has soft -magnetic properties and material that has hard- magnetic properties. The soft-magnetic material may then suitably be used as implant, while the prosthesis itself may then suitably the made in one piece from hard-magnetic materials. Soft -magnetic behaviour combined with highly spontaneous magnetisation and low remanence of the implant are important to create good adhesion.
The possibility of using the same material for both the implant and the prosthesis, while these only differ with regard to the type of the magnetic properties, provides the further advantage that in the presence of body fluids no difference in the electrochemical potential can arise which could cause nerve irritation, or corrosion.
To realize these objectives and advantages, the method according to the invention is characterized in that the alloy is melted in an oxidation- inhibiting atmosphere, avoiding any contact of the melt with surfaces that have a temperature in the region of or higher than the alloy' s fusion temperature. The material obtained according to this method of the invention, which material is based on a conventional alloy of iron and platinum, having a platinum content above 30 atom%, is very corrosion-resistant and may be implanted in the body without protective encapsulation. In this respect the material obtained by the method
according to the invention differs from the material known from DE-A-4027681, which may indeed have the same general composition but which suffers from impurities that have a negative effect on the intended application as implant of soft-magnetic material.
The method according to the invention effectively prevents the diffusion of material between melt and said surfaces, for example, a crucible, so that the melt stays as much as possible free from impurities. The inven- tors believe that such impurities, if not avoided, will form so-called pinning centres for magnetic domeins or Bloch walls.
As oxidation-inhibiting atmosphere for melting the alloy, it is convenient to use an argon atmosphere. In a first embodiment of the method according to the invention, the melting step preferably involves welding arc fusion in a cold crucible. The person skilled in the art is quite familiar with this form of fusion and it requires no further explanation. The temperature of the crucible is preferably approximately 100°C below the fusion temperature of the alloy. More preferably the temperature difference is at least approximately 200°C.
A second preferred embodiment of the method according to the invention is characterized in that the al- loy is molten by means of levitation fusion. Again, the person skilled in the art requires no further explanation. Levitation fusion ensures that there is no contact between the melt and the crucible.
Basically the method according to the invention differs from the known method as described in the above- mentioned article by atanabe and in DE-A-4026781 , in that the manner of operation is completely clean. For example in the known prior art, fusion may be carried out in aluminium crucibles and the product is subsequently poured into quarts ampoules, which results in undesirable contamination of the product obtained by said method.
In order to obtain the desired qualities it is further favourable after fusion to carry out an annealing
treatment at a temperature in the vicinity of 1300°C. Preferably the annealing treatment takes approximately one hour. It is further desirable to subsequently cool the alloy to room temperature at a rate of at least approxi- mately 1000°C/minute . This provides a reproducibly homogenous solid solution of the components in the face-centred cubic gamma-iron structure of the alloy. The practically contamination- free material obtained by this method is magnetically soft, mechanically strong and very corrosion- resistant, and is especially suitable for use as implant. A further elaboration of the method according to the invention is characterized in that a recrystallization treatment is carried out; in order to conveniently control the speed of the recrystallization treatment it is desir- able that the non-ferro metal be selected from the group Nb, Zr, Ga and Ti and that the amount be approximately 1 atom% . After the alloy is cooled down, the recrystallization is performed in a first preferred embodiment by heating for 20 to 80 hours in the range of 575-650°, preferably approximately 625°C. In this way a face-centred tetragonal phase is provided, making the material obtained by the method magnetically hard, mechanically strong and very corrosion resistant. This material is especially suitable to be applied in or as the prosthesis. To optimize the speed of the recrystallization treatment the non-ferro metal advantageously is 0.1 to 0.4 atom% Al, preferably 0.25 atom%, so that after cooling, the recrystallization treatment can be carried out by heating the alloy to approximately 525°C for approximately 20 hours. The recrystallization treatment may be further accelerated by placing the alloy during the recrystallization treatment under at least approximately 2 bars of uni- axial pressure, and by heating the alloy at a maximum temperature of approximately 450°C for 2 to 3 hours. This also provides a very energy-efficient recrystallization treatment .
In order to maintain the properties of the alloy obtained by the method according to the invention, it is desirable that after melting and before cooling, the alloy be cast into a predetermined form by means of vacuum cast- ing. A casting produced in this manner is very corrosion- resistant, is easy to polish, is mechanically strong, has a Vickers hardness of approximately 400, and, depending on whether or not it has undergone the above-mentioned recrystallization treatment, may have both soft- and hard- magnetic properties.
The invention is also embodied in a permanent (hard) -magnetic product and a soft-magnetic product obtained by the method according to the invention.
To the person skilled in the art it will be ob- vious that within the framework of the invention diverse variants are possible, whose limitation is determined solely by the appended claims. Therefore the preceding specification is to be understood as elucidation of the appended claims without limiting these in any way whatso- ever.
Claims
1. A method for manufacturing a permanent iron- platinum magnet suitable for fixing a prosthesis in or on a body, wherein an alloy is molten, which comprises at least 30 atom% of platinum, 0-5 atom% of a non-ferro metal, remainder iron, is cooled, after which it is op- tionally subjected to a recrystallization process, characterized in that the alloy is melted in an oxidation- inhibiting atmosphere, avoiding any contact of the melt with surfaces that have a temperature in the region of or higher than the alloy's fusion temperature.
2. A method according to claim 1, characterized in that the alloy is molten by means of welding arc fusion in a cold crucible.
3. A method according to claim 1, characterized in that melting the alloy involves levitation fusion.
4. A method according to one of the claims 1-3, characterized in that after fusion an annealing treatment is carried out at a temperature in the vicinity of 1300°C.
5. A method according to claim 4 or 5, characterized in that the annealing treatment takes approximately one hour.
6. A method according to claim 4, characterized in that subsequent to the annealing treatment, the alloy is cooled to room temperature at a rate of at least approximately 1000°C/minute.
7. A method according to one of the preceding claims, characterized in that the non-ferro metal is selected from the group Nb, Zr, Ga and Ti and that the amount is approximately 1 atom% .
8. A method according to one of the claims 1-7, characterized in that after cooling down, the recrystallization treatment is performed by heating the alloy for 20 to 80 hours in the range of 575-650°, preferably approximately 625°C.
9. A method according to one of the claims 1-6, characterized in that the non-ferro metal is 0.1 to 0.4 atom% Al, preferably 0.25 atorr.% .
10. A method according to claim 9, characterized in that the recrystallization treatment is carried out by after cooling, heating the alloy to approximately 525°C for approximately 20 hours.
11. A method according to claim 9, characterized in that during the recrystallization treatment the alloy is placed under at least approximately 2 bars of uni-axial pressure, and by heating the alloy at a maximum temperature of approximately 450°C for 2 to 3 hours.
12. A method according to one of the preceding claims, characterized in that after melting and before cooling, the alloy is cast into a predetermined form by means of vacuum casting.
13. A permanently magnetic product obtained by the method according to one of the claims 1-7 and 8, or one of the claims 9-11.
14. A soft-magnetic product obtained by the method according to one of the claims 1-7 and 12.
15. A moulded dental prosthesis product fabricated from material obtained merely by the method according to one of the claims 1-12.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1013264A NL1013264C2 (en) | 1999-10-11 | 1999-10-11 | Method for manufacturing a permanent iron-platinum magnet, and the product obtained from it. |
| NL1013264 | 1999-10-11 | ||
| PCT/NL2000/000722 WO2001027944A1 (en) | 1999-10-11 | 2000-10-06 | METHOD FOR MANUFACTURING A PERMANENT Fe-Pt MAGNET, AND THE PRODUCT OBTAINED THEREBY |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1226591A1 true EP1226591A1 (en) | 2002-07-31 |
Family
ID=19770030
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP00971891A Withdrawn EP1226591A1 (en) | 1999-10-11 | 2000-10-06 | METHOD FOR MANUFACTURING A PERMANENT Fe-Pt MAGNET, AND THE PRODUCT OBTAINED THEREBY |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP1226591A1 (en) |
| AU (1) | AU1063301A (en) |
| NL (1) | NL1013264C2 (en) |
| WO (1) | WO2001027944A1 (en) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2513679B2 (en) * | 1987-04-30 | 1996-07-03 | 財団法人 電気磁気材料研究所 | Ultra-high coercive force permanent magnet with large maximum energy product and method for manufacturing the same |
| DE4027681C2 (en) * | 1989-09-04 | 1997-08-21 | Japan Energy Corp | Fastening device for at least one artificial tooth |
-
1999
- 1999-10-11 NL NL1013264A patent/NL1013264C2/en not_active IP Right Cessation
-
2000
- 2000-10-06 WO PCT/NL2000/000722 patent/WO2001027944A1/en not_active Ceased
- 2000-10-06 EP EP00971891A patent/EP1226591A1/en not_active Withdrawn
- 2000-10-06 AU AU10633/01A patent/AU1063301A/en not_active Abandoned
Non-Patent Citations (1)
| Title |
|---|
| See references of WO0127944A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| NL1013264C2 (en) | 2001-04-17 |
| AU1063301A (en) | 2001-04-23 |
| WO2001027944A1 (en) | 2001-04-19 |
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