EP1188814A1 - Die Verwendung einer geräuschreduzierenden Schmierfettzusammensetzung - Google Patents

Die Verwendung einer geräuschreduzierenden Schmierfettzusammensetzung Download PDF

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Publication number
EP1188814A1
EP1188814A1 EP01203189A EP01203189A EP1188814A1 EP 1188814 A1 EP1188814 A1 EP 1188814A1 EP 01203189 A EP01203189 A EP 01203189A EP 01203189 A EP01203189 A EP 01203189A EP 1188814 A1 EP1188814 A1 EP 1188814A1
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EP
European Patent Office
Prior art keywords
grease
noise
thickener
use according
dithiocarbamate
Prior art date
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EP01203189A
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English (en)
French (fr)
Inventor
Stefan Daegling
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Shell Internationale Research Maatschappij BV
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Shell Internationale Research Maatschappij BV
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Priority to EP01203189A priority Critical patent/EP1188814A1/de
Publication of EP1188814A1 publication Critical patent/EP1188814A1/de
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    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
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Definitions

  • the present invention relates to the use of a grease composition to reduce noise, particularly in bearing applications.
  • Grease compositions consist primarily of a fluid lubricant, such as an oil, and a thickener and are widely used to lubricate mechanical components such as joints and bearings.
  • a fluid lubricant such as an oil
  • a thickener is widely used to lubricate mechanical components such as joints and bearings.
  • greases are employed in applications where high pressures exist, where oil drip is undesirable or where the motion of the contacting surfaces is discontinuous so that it is difficult to maintain a separating film in a joint or bearing.
  • Bearings are supports provided to locate a revolving or reciprocating shaft and are widely used in industrial, automotive and household applications.
  • bearings When in use bearings may be subjected to extreme rotational forces which can lead to noise or vibrations. Such noise is detrimental to the condition of a bearing and can lead equipment comprising the bearing to suffer from shake or judder and to make acoustic beating noises. Such noise associated problems can prevent the use of bearings in low vibration applications.
  • WO 96/02615 relates to a grease composition for constant velocity joints which comprises (a) a base oil; (b) a lithium-containing thickener selected from the group consisting of lithium soap and lithium complex soap; (c) an organic molybdenum compound selected from the group consisting of molybdenum dithiophosphates and molybdenum dithiocarbamates; and (d) a zinc dithiophosphate.
  • US-A-4648985 describes two- and three-component extreme pressure lubricant additive systems.
  • the two-component system comprises a metal organophosphate and a dithiocarbamate of formulae described therein.
  • the three-component system comprises a dithiocarbamate, a metal compound and a phosphate compound of formulae described therein.
  • Example 11 of US-A-4648985 relates to a lubricating grease comprising mineral oil, inorganic clay thickener, 4.0% copper octoate, ("12.0% Copper Cem-All", Mooney Chemicals, Inc., Cleveland, Ohio), 4.0% methylene bis (dibutyl dithiocarbamate) (Vanlube 7723), and 9.5% zinc diarene phosphorodithioate (OLOA 260).
  • US-A-5922654 relates to lubricant compositions which are said to be suitable for application to parts required to have load bearing properties and extreme pressure properties or parts susceptible to wear, for example to bearings and constant velocity joints.
  • Example 2 in Table 3 of US-A-5922654 describes a urea grease comprising piperidine pentamethylenedithiocarbamate (2%), tellurium diethyldithiocarbamate (1.5%) and zinc dialkyldithiophosphate (1%).
  • Example 3 in Table 3 of US-A-5922654 concerns a urea grease comprising piperidine pentamethylene dithiocarbamate (1.5%), antimony dialkyldithiocarbamate (1.5%), molybdenum dialkyldithiocarbamate (0.5%) and zinc dialkyl dithiophosphate (0.5%).
  • GB-A-2255103 describes a grease composition for use in constant velocity joints which is said to reduce wear, control vibrations and improve durability.
  • the grease compositions described in GB-A-2255103 comprise a lubricating oil, urea thickener, (A) 1 - 5% wt. of molybdenum sulfide dialkyldithiocarbamate, (B) 0.2 - 1% wt of molybdenum disulfide, (C) 0.5 - 3% wt. of an extreme pressure additive of zinc dithiophosphate represented by the following general formula: (wherein R is an alkyl or an aryl group) and (D) 0.5 - 5% wt. of an oiliness agent composed of at least one of vegetable oils and fats as an essential component, provided that a weight ratio of component (B) to component (A) is 0.04-0.5.
  • the present invention provides the use of a grease composition comprising a base oil of mineral and/or synthetic origin, a thickener, a zinc dithiophosphate, and an ashless dithiocarbamate as a noise-reducing grease composition.
  • the grease composition used in the present invention preferably comprises at least 75% by weight of a base oil based on total composition.
  • Base oils for use in the greases employed in the present invention may typically be the same as base oils which would normally be selected for oil lubrication.
  • the base oil may be of mineral and/or synthetic origin.
  • Base oils of mineral origin may be mineral oils, for example those produced by solvent refining or hydroprocessing.
  • Base oils of synthetic origin may typically be mixtures of C 10 -C 50 hydrocarbon polymers, for example liquid polymers of alpha-olefins, ester type synthetic oils or ether type synthetic oils. They may also be a mixture of these oils.
  • the base oil is of mineral origin.
  • mineral oils examples include those sold by member companies of the Royal Dutch/Shell Group under the designations "HVI”, “MVIN”, or “HMVIP”.
  • the grease compositions used in the present invention preferably comprise from 2 to 20%, more preferably 5 to 20%, and most preferably 5 to 12% by weight of a thickener based on total composition.
  • Thickeners which may be used in the grease compositions employed in the present invention include simple thickeners, for example fatty acid soaps of lithium, calcium, sodium, aluminium and barium; complex thickeners i.e. simple thickeners additionally comprising a complexing agent; clays; and urea type compounds.
  • urea-type compound When used as a thickener it may be a mono-, di-, tri- and tetra urea compound or a compound containing a urea e.g. a urea-urethane and/or a urea-imide compound.
  • Preferred thickeners according to the present invention are soap thickeners more preferably lithium soap thickeners.
  • lithium soap thickeners it is meant both simple and complex lithium soap thickeners.
  • Simple lithium soaps are derived from C 10-24 , preferably C 15-18 , saturated or unsaturated fatty acids or derivatives thereof.
  • One preferred fatty acid derivative is hydrogenated castor oil, which is the glyceride of 12-hydroxystearic acid.
  • 12-Hydroxystearic acid is a particularly preferred fatty acid.
  • Complex lithium soap thickeners are thickeners wherein a complexing agent has been incorporated into a simple lithium soap.
  • Commonly used complexing agents include a low to medium molecular weight acid or dibasic acid or one of its salts, such as benzoic acid or boric acid or a lithium borate.
  • the thickener employed in the grease compositions used in the present invention is a simple lithium soap thickener.
  • the grease composition used in the present invention preferably comprises from 0.1 to 5%; more preferably 0.1 to 2% and most preferably 0.2 to 1% by weight of a zinc dithiophosphate, based on total composition.
  • the grease composition may comprise a single zinc dithiophosphate or a combination of two or more zinc dithiophosphates, the or each zinc dithiophosphate being selected from zinc dialkyl-, diaryl- or alkylaryl-dithiophosphates.
  • a preferred zinc dithiophosphate according to the present invention is a zinc dialkyl dithiophosphate.
  • the alkyl moieties of a zinc dialkyl dithiophosphate employed in the present invention may be straight chain or branched chain and preferably contain from 1 to 20 carbons, more preferably contain from 8 to 20 carbon atoms and most preferably contain from 8 to 12 carbon atoms.
  • Examples of preferred zinc dithiophosphates are 2-ethylhexyl zinc dithiophosphate obtainable from Rhein Chemie Rheinau GmbH. under the designation “Additin RC 3180” and a long chain zinc dithiophosphate obtainable from Rhein Chemie Rheinau GmbH. under the designation “Additin RC 3212", ("Additin” is a trade mark of Rhein Chemie Rheinau GmbH.).
  • the grease compositions used in the present invention preferably comprise from 0.1 to 5%, more preferably from 0.1 to 2% and most preferably from 0.2 to 1% by weight of an ashless dithiocarbamate based on total composition.
  • the grease composition may comprise a single ashless dithiocarbamate or a combination of two or more ashless dithiocarbamates, the or each ashless dithiocarbamate being selected from ashless dialkyl-, diaryl- or alkylaryl- dithiocarbamates.
  • a preferred ashless dithiocarbamate according to the present invention is an ashless dialkyldithiocarbamate more preferably a methylene-bis-dialkyldithiocarbamate.
  • the alkyl moieties of an ashless dialkyl dithiocarbamate employed in the present invention may be straight or branched chain and preferably contain from 1 to 12 carbon atoms, most preferably 2 to 6 carbon atoms.
  • An example of a preferred ashless dithiocarbamate is methylene-bis-dibutyl-dithiocarbamate obtainable from Rhein Chemie Rheinau GmbH under the designation "Additin RC 6340".
  • the grease composition used in the present invention may further comprise conventional grease additives, in amounts normally used in the art, to impart certain desirable characteristics to the grease such as oxidation stability, tackiness, extreme pressure properties, corrosion inhibition and to reduce friction and wear.
  • the aryl group is preferably a phenyl group; where the term aralkyl is used, the aralkyl group is preferably a benzyl group.
  • Grease compositions used in the present invention may be prepared either by pre-mixing the zinc dithiophosphate, ashless dithiocarbamate and any further additive to be incorporated in base oil and adding the mixture to a base grease comprising base oil and thickener, or by incorporating each additive into the base grease individually. This may be achieved via hot or cold mixing followed by homogenisation to ensure uniform dispersion of additive components.
  • Grease compositions used in the present invention display exceptionally low noise and have been found to be very effective in bearing applications. Accordingly, the present invention further provides for the use of a grease composition according to the invention to reduce noise in bearing applications.
  • a simple lithium soap base grease was prepared by adding a slurry of 1.12 % w LiOH.H 2 O and water in the proportions of 1 part LiOH.H 2 O to 5 parts water to 9.15% w hydrogenated castor oil fatty acid in cold paraffinic base oil having a viscosity of 75mm 2 /s (obtainable from member companies of the Royal Dutch/Shell Group under the designation "HMVIP 105") and heating the mix in a sealed autoclave to 150 °C. Steam was vented off and heating continued to 220 °C before the reaction mass was cooled at a rate of 1 to 3 °C per minute and the product homogenised to yield a base grease comprising approximately 8% wt. Li 12-hydroxystearate and 92% wt. paraffinic base oil.
  • Example greases according to the invention and Comparative greases were obtained by incorporating additives into the base grease.
  • New bearings of type 608 as described in DIN 623 were cleaned thoroughly in analysis quality n-hexane and then dried in a drying cabinet. Immediately after cooling the bearings were filled with grease. After removal of grease from outside the bearing cage each bearing contained approximately 0.31 to 0.35 g of grease.
  • the bearing to be tested was placed on the shaft's arbour; and the outer bearing ring held in place and axially loaded, the degree of axial loading being adjustable.
  • the shaft was then turned by an electric motor acting through flexible drive belts until a preselected speed of rotation is reached.
  • an acceleration sensor with a polished probe tip, the acceleration sensor being flexibly secured to a sliding carriage whose inherent weight presses the sensor onto the bearing.
  • the acceleration signals were preamplified in a 2626 charge amplifier as supplied by Brüel & Kjaer GmbH.; prefiltered and then processed in an IBM-compatible 486/50 PC fitted with a A/D converter with integral Microstar DAP 2400/e4 signal processor ("Microstar" is a trade name). From the processed acceleration signals an average line for vibrations occurring in a frequency range of 50-20000 Hz was obtained. From this data the amount of noise produced in each test may be compared with that of a calibration grease or a earlier measurement; the difference in noise being expressed as a difference in decibel (dB) level.
  • dB decibel
  • the grease compositions of Examples 1-6 were prepared by mixing a zinc dithiophosphate and an ashless dithiocarbamate in a paraffinic base oil and then adding the resultant mixture to the simple lithium soap base grease.
  • the components of the prepared greases are shown in Table 1.
  • the grease composition of Comparative Example A was prepared in a similar way to those of Examples 1-6, employing molybdenum dithiocarbamate instead of an ashless dithiocarbamate.
  • the greases were subjected to noise testing according to the above procedure and the results compared with that of a calibration grease.
  • the performance of the calibration grease and each of grease compositions of Examples 1-6 and Comparative Example A was tested in 3-5 bearings at a temperature of 25 °C with the mean measurement being used.
  • the difference in noise between grease compositions of Examples 1-6 and the calibration grease is shown in Table 1, a negative change in decibel (dB) level indicating a reduction in noise level when compared with the calibration grease.
  • dB decibel
  • the difference in noise between the grease composition of Comparative Example A and the calibration grease is also shown in Table 1.
  • the calibration grease was a commercially available lubricating grease known to have good noise performance obtainable from member companies of the Royal Dutch/Shell Group under the trade name "Alvania RS" ("Alvania" is a trade mark).
  • Grease compositions 7-10 and Comparative Examples B-G were prepared by incorporating additives directly into the simple lithium base soap grease.
  • the components of the prepared greases are shown in Table 2.
  • Grease compositions 7 - 10 and Comparative Examples B-G were subjected to a high temperature performance test wherein a bearing containing a test grease is subjected to noise testing at a temperature of 25 °C to give a calibration reading for that grease, the bearing is then heated to a temperature of 100 °C and operated under the test conditions for 3 hours after which time a further noise measurement is made of the hot bearing and the increase in decibel (dB) level from the calibration measurement recorded. The bearing is then allowed to cool to 25°C and a further noise measurement taken of the cooled bearing and the difference between the calibration measurement again being recorded. Results are shown in Table 2 together with the result obtained for this procedure using commercially available grease "Alvania RS".
  • grease compositions according to the invention show performance superior to greases comprising a molybdenum dithiocarbamate in combination with an ashless dithiocarbamate (Comparative Example B) and are at least as effective as compositions comprising a molybdenum dithiocarbamate and a zinc dithiophosphate (Comparative Example E).

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
EP01203189A 2000-08-23 2001-08-23 Die Verwendung einer geräuschreduzierenden Schmierfettzusammensetzung Withdrawn EP1188814A1 (de)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111303966A (zh) * 2020-03-25 2020-06-19 青岛中科润美润滑材料技术有限公司 一种电机轴承润滑脂及其制备方法
CN112195054A (zh) * 2019-12-23 2021-01-08 新协同(宁波)油脂有限公司 一种低噪音轴承润滑脂及其制备方法

Citations (4)

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Publication number Priority date Publication date Assignee Title
US4648985A (en) * 1984-11-15 1987-03-10 The Whitmore Manufacturing Company Extreme pressure additives for lubricants
US5133888A (en) * 1990-09-28 1992-07-28 Amoco Corporation Cruise missile engine bearing grease
WO1996002615A1 (en) * 1994-07-15 1996-02-01 Kyodo Yushi Co., Ltd. Grease composition for constant velocity joints
JPH08176578A (ja) * 1994-12-27 1996-07-09 Ntn Corp 転がり軸受封入用グリース組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4648985A (en) * 1984-11-15 1987-03-10 The Whitmore Manufacturing Company Extreme pressure additives for lubricants
US5133888A (en) * 1990-09-28 1992-07-28 Amoco Corporation Cruise missile engine bearing grease
WO1996002615A1 (en) * 1994-07-15 1996-02-01 Kyodo Yushi Co., Ltd. Grease composition for constant velocity joints
JPH08176578A (ja) * 1994-12-27 1996-07-09 Ntn Corp 転がり軸受封入用グリース組成物

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DATABASE WPI Section Ch Week 199637, Derwent World Patents Index; Class A97, AN 1996-368541, XP002184627 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112195054A (zh) * 2019-12-23 2021-01-08 新协同(宁波)油脂有限公司 一种低噪音轴承润滑脂及其制备方法
CN111303966A (zh) * 2020-03-25 2020-06-19 青岛中科润美润滑材料技术有限公司 一种电机轴承润滑脂及其制备方法

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