EP1178366B1

EP1178366B1 - Imaging apparatus and intermediate transfer blanket therefor

Info

Publication number: EP1178366B1
Application number: EP01204162A
Authority: EP
Inventors: Alon c/o Indigo Ltd. Gazit; David c/o Indigo Ltd. Idan; Hanni c/o Indigo Ltd Inbar; Ilan c/o Indigo Ltd. Kandar; Eli c/o Indigo Ltd. Kritchman; Benzion c/o Indigo Ltd. Landa; Amiran c/o Indigo Ltd. Lavon; Moshe c/o Indigo Ltd. Levanon; Ishaiau c/o Indigo Ltd. Lior; Jan c/o Indigo Ltd. Van Mil; Yehuda c/o Indigo Ltd. Niv; Avner c/o Indigo Ltd. Schneider; Aron c/o Indigo Ltd. Shmaiser; Hanis c/o Indigo Ltd. Younes
Original assignee: Hewlett Packard Indigo BV
Current assignee: HP Indigo BV
Priority date: 1994-10-11
Filing date: 1995-06-06
Publication date: 2008-10-29
Anticipated expiration: 2015-06-06
Also published as: EP1178366A2; EP1179757A2; EP1178366A3; EP1179757A3; EP1179757B1

Description

FIELD OF THE INVENTION

The present invention relates to image forming and image transfer apparatus especially for use in electrostatic imaging using an intermediate transfer blanket.

BACKGROUND OF THE INVENTION

The use of an intermediate transfer member in electrostatic imaging is well known.
Various types of intermediate transfer members are known and are described, for example in U.S. Patents 3,862,848 , 4,684,238 , 4,690,539 and 4,531,825 and in the RELATED APPLICATIONS listed above.
Belt-type intermediate transfer members for use in electrophotography are known in the art and are described, inter alia, in U.S. Patents 3,893,761 , 4,684,238 and 4,690,539 .
GB 2056883A describes an intermediate transfer member with an ink receptive transfer layer, a hard rubber layer and a foamed rubber layer.
US 4,015,046 describes a printinig blanket having a compressible layer with voids and a binder layer to provide adhesion between the base structure of the blanket and the surface layer. In order to protect the binder layer from wicking effects that may introduce fluid or liquid against the binder layer a barrier between the base structure and the binder layer is provided.
The use of intermediate transfer members and members including transfer blankets for offset ink printing is also well known. Such blankets have characteristics which are suitable for ink transfer but are generally not usable, per se, for liquid toner imaging.

SUMMARY OF THE INVENTION

There is provided in accordance with an embodiment of the invention, an intermediate transfer member for the transfer of liquid toner images, comprising:

a transfer surface adapted to receive the images from a first surface and to transfer them to a second surface; and
a void free resilient layer underlying the transfer surface;
characterized in that:
a barrier layer, that is substantially impervious to one or both of liquid hydrocarbon and gasses, is situated intermediate the resilient layer and the transfer surface.

There is further provided an imaging apparatus for performing an imaging process, comprising:

an imagaing surface having a liquid toner image comprising toner particles and carrier liquid formed thereon; and
an intermediate transfer member according to the present invention which receives the toner image from the imaging surface and from which it is subsequently transferred.

BRIEF DESCRIPTION OF THE DRAWINGS

The present invention will be understood and appreciated more fully from the following detailed description, taken in conjunction with the drawings in which:

Fig. 1 is a simplified sectional illustration of electrostatic imaging apparatus constructed and operative in accordance with a preferred embodiment of the present invention;
Fig. 2 is a simplified enlarged sectional illustration of the apparatus of Fig. 1;
Fig. 3A is a simplified, cross-sectional side view of an intermediate transfer member, including a removable intermediate transfer blanket mounted on a drum, in accordance with a preferred embodiment of the invention;
Fig. 3B is a partially cut-away top view of the intermediate transfer member of Fig. 3A;
Figs. 4A and 4B are respective top and side views of an intermediate transfer blanket in accordance with a preferred embodiment of the invention;
Fig. 4C shows details of the layered construction of the intermediate transfer blanket in accordance with a preferred embodiment of the invention;
Fig. 4D is a cut-away expanded view of a securing mechanism on the intermediate transfer blanket of Figs 4A and 4B; and
Fig. 5 is a simplified cross-sectional illustration of a portion of an intermediate transfer member, including a removable intermediate transfer blanket mounted on a drum in accordance with another preferred embodiment of the invention.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

Reference is now made to Figs. 1 and 2 which illustrate a multicolor electrostatic imaging system. As seen in Figs. 1 and 2 there is provided an imaging sheet, preferably an organic photoreceptor 12, typically mounted on a rotating drum 10. Drum 10 is rotated about its axis by a motor or the like (not shown), in the direction of arrow 18, past charging apparatus 14, preferably a corotron, scorotron or roller charger or other suitable charging apparatus known in the art and which is adapted to charge the surface of sheet photoreceptor 12. The image to be reproduced is focused by an imager 16 upon the charged surface 12 at least partially discharging the photoconductor in the areas struck by light, thereby forming the electrostatic latent image. Thus, the latent image normally includes image areas at a first electrical potential and background areas at another electrical potential.
Photoreceptor sheet 12 may use any suitable arrangement of layers of materials as is known in the art, however, certain of the layers may be removed from the ends of the sheet to facilitate its mounting on drum 10.
This preferred photoreceptor sheet and preferred methods of mounting it on drum 10 are described in a copending U.S. Patent application of Belinkov et al., IMAGING APPARATUS AND PHOTORECEPTOR THEREFOR, filed September 7, 1994, assigned serial number 08/301,775 , and on applications filed in other countries claiming priority therefrom. Alternatively, photoreceptor 12 may be deposited on the drum 10 and may form a continuous surface. Furthermore, photoreceptor 12 may be a non-organic type photoconductor based, for example, on a compound of Selenium.
Imaging apparatus 16 may be a modulated laser beam scanning apparatus, an optical focusing device for imaging a copy on a drum or other imaging apparatus such as is known in the art.
Also associated with drum 10 and photoreceptor sheet 12, in the preferred embodiment of the invention, are a multicolor liquid developer spray assembly 20, a developing assembly 22, color specific cleaning blade assemblies 34, a background cleaning station 24, an electrified squeegee 26, a background discharge device 28, an intermediate transfer member 30, cleaning apparatus 32, and, optionally, a neutralizing lamp assembly 36.
Developing assembly 22 preferably includes a development roller 38. Development roller 38 is preferably spaced from photoreceptor 12 thereby forming a gap therebetween of typically 40 to 150 micrometers and is charged to an electrical potential intermediate that of the image and background areas of the image. Development roller 38 is thus operative, when maintained at a suitable voltage, to apply an electric field to aid development of the latent electrostatic image.
Development roller 38 typically rotates in the same sense as drum 10 as indicated by arrow 40. This rotation provides for the surface of sheet 12 and development roller 38 to have opposite velocities at the gap between them.
Multicolor liquid developer spray assembly 20, whose operation and structure is described in detail in U.S. Patent 5,117,263 , may be mounted on axis 42 to allow assembly 20 to be pivoted in such a manner that a spray of liquid toner containing electrically charged pigmented toner particles can be directed either onto a portion of the development roller 38, a portion of the photoreceptor 12 or directly into a development region 44 between photoreceptor 12 and development roller 38. Alternatively, assembly 20 may be fixed. Preferably, the spray is directed onto a portion of the development roller 38.
Color specific cleaning blade assemblies 34 are operatively associated with developer roller 38 for separate removal of residual amounts of each colored toner remaining thereon after development. Each of blade assemblies 34 is selectably brought into operative association with developer roller 38 only when toner of a color corresponding thereto is supplied to development region 44 by spray assembly 20. The construction and operation of cleaning blade assemblies is described in PCT Publication WO 90/14619 and in US patent 5,289,238 .
Each cleaning blade assembly 34 includes a toner directing member 52 which serves to direct the toner removed by the cleaning blade assemblies 34 from the developer roller 38 to separate collection containers 54, 56, 58, and 60, for each color to prevent contamination of the various developers by mixing of the colors. The toner collected by the collection containers is recycled to a corresponding toner reservoir (55, 57, 59 and 61). A final toner directing member 62 always engages the developer roller 38 and the toner collected thereat is supplied into collection container 64 and thereafter to reservoir 65 via separator 66 which is operative to separate relatively clean carrier liquid from the various colored toner particles. The separator 66 may be typically of the type described in U.S. Patent 4,985,732 , the disclosure of which is incorporated herein by reference.
In a preferred embodiment of the invention, as described in U.S. Patent 5,255,058 , the disclosure of which is incorporated herein by reference, where the imaging speed is very high, a background cleaning station 24 typically including a reverse roller 46 and a fluid spray apparatus 48 is provided. Reverse roller 46 which rotates in a direction indicated by arrow 50 is electrically biased to a potential intermediate that of the image and background areas of photoconductive drum 10, but different from that of the development roller. Reverse roller 46 is preferably spaced apart from photoreceptor sheet 12 thereby forming a gap therebetween which is typically 40 to 150 micrometers.
Fluid spray apparatus 48 receives liquid toner from reservoir 65 via conduit 88 and operates to provide a supply of preferably non-pigmented carrier liquid to the gap between sheet 12 and reverse roller 46. The liquid supplied by fluid spray apparatus 48 replaces the liquid removed from drum 10 by development assembly 22 thus allowing the reverse roller 46 to remove charged pigmented toner particles by electrophoresis from the background areas of the latent image. Excess fluid is removed from reverse roller 46 by a liquid directing member 70 which continuously engages reverse roller 46 to collect excess liquid containing toner particles of various colors which is in turn supplied to reservoir 65 via a collection container 64 and separator 66.
The apparatus embodied in reference numerals 46, 48, 50 and 70 is not required for low speed systems, but is preferably included in high speed systems.
An electrically biased squeegee roller 26 is urged against the surface of sheet 12 and is operative to remove liquid carrier from the background regions and to compact the image and remove liquid carrier therefrom in the image regions. Squeegee roller 26 may be formed of resilient slightly conductive polymeric material as is well known in the art, and may be charged to a potential of several hundred to a few thousand volts with the same polarity as the polarity of the charge on the toner particles.
The squeegee roller may be made by molding a soft polyurethane rubber coating onto a metal core, coating the molded core with a conductive lacquer and coating the lacquer with a low conductivity elastomer. Alternatively, the molded coating can be made of an elastomer with a controlled conductivity and the lacquer can be omitted. As a further alternative, a single coating of controlled conductivity elastomer is used and the outer layer is omitted.
Discharge device 28 is operative to flood the sheet 12 with light which discharges the voltage remaining on sheet 12, mainly to reduce electrical breakdown and improve transfer of the image to intermediate transfer member 30. Operation of such a device in a write black system is described in U.S. Patent 5,280,326 .
Figs. 1 and 2 further show that multicolor toner spray assembly 20 receives separate supplies of colored toner typically from four different reservoirs 55, 57, 59 and 61. Figure 1 shows four different colored toner reservoirs 55, 57, 59 and 61 typically containing the colors Yellow, Magenta, Cyan and, optionally, Black respectively. Pumps 90, 92, 94 and 96 may be provided along respective supply conduits 98, 101, 103 and 105 for providing a desired amount of pressure to feed the colored toner to multicolor spray assembly 20. Alternatively, multicolor toner spray assembly 20, which is preferably a three level spray assembly, receives supplies of colored toner from up to six different reservoirs (not shown) which allows for custom colored toner in addition to the standard process colors.
A preferred type of toner for use with the present invention is that described in Example 1 of U.S. Patent 4,794,651 , or variants thereof as are well known in the art. For colored liquid developers, carbon black is replaced by color pigments as is well known in the art. Other toners may alternatively be employed, including liquid toners and, as indicated above, including powder toners.
Another preferred embodiment of the toner for use in the invention is prepared using the following method:

1) Solubilizing 1400 grams of Nucrel 925 (ethylene copolymer by Dupont) and 1400 g of Isopar L (Exxon) are thoroughly mixed in an oil heated Ross Double Planetary Mixer at least 24 RPM for 1.5 hours, with the oil temperature at 130°C. 1200 g of preheated Isopar L is added and mixing is continued for an additional hour. The mixture is cooled to 45°C, while stirring is continued over a period of several hours, to form a viscous material.
2) Milling and Grinding 762 grams of the result of the Solubilizing step are ground in a 1S attritor (Union Process Inc. Akron Ohio), charged with 3/16" carbon steel balls at 250 RPM, together with 66.7 grams of Mogul L carbon black (Cabot), 6.7 grams of BT 583D (blue pigment produced by Cookson), 5 grams of aluminum tri stearate and an additional 1459.6 grams of Isopar L for eight hours at 30°C.
3) Continuation of Grinding 34.5 grams of ACumist A-12 (a micronised polyethylene wax produced by Allied Signal) is added and grinding is continued for an additional 4 hours. The resulting particles are fibrous particles have a measured diameter in the range of 1-3 micrometers.

The resulting material is diluted with additional Isopar L and Marcol 82 to give a working developer in which the dry solids portion is about 1.7% and in which the overall ratio of Isopar L to Marcol is between about 50:1 and 500:1, more preferably between about 100:1 and 200:1. Charge director as described in US patent application 07/915,291 (utilizing lecithin, BBP and ICIG3300B) and in WO 94/02887 , in an amount equal to 40 mg/gm of solids, is added to charge the toner particles. Other charge directors and additional additives as are known in the art may also be used.
The above described process produces a black toner. Cyan, magenta and yellow toners can be produced by using a different mix of materials for step 2). For Cyan toner, 822g of the solubilized material, 21.33 grams each of BT 583D and BT 788D pigments (Cookson), 1.73 grams of D1355DD pigment (BASF), 7.59 grams of aluminum tri stearate and 1426 grams of Isopar L are used in step 2. For Magenta toner, 810 grams of solubilized material, 48.3 grams of Finess Red F2B, 6.81 grams of aluminum tri-stearate and 1434.2 grams of Isopar L are used in step 2. For yellow toner 810 grams of solubilized material, 49.1 grams of D1355DD pigment, 6.9 grams of aluminum tri-stearate and 1423 grams of Isopar L are used in step 2.
Intermediate transfer member 30, an especially preferred embodiment of which is described in detail below (in conjunction with Figs. 3 and 4), may, for some embodiments of the invention, be any suitable intermediate transfer member having a multilayered transfer portion such as those described below or in US Patents 5,089,856 or 5,047,808 or in the applications of which this application is a continuation in part, and by other structures known in the art. Member 30 is maintained at a suitable voltage and temperature for electrostatic transfer of the image thereto from the image bearing surface. Intermediate transfer member 30 is preferably associated with a pressure roller 71 for transfer of the image onto a final substrate 72, such as paper, preferably by heat and pressure. For the especially preferred toner described above, an image temperature of about 95°C at the inception of fusing is preferred.
Cleaning apparatus 32 is operative to scrub clean the surface of photoreceptor 12 and preferably includes a cleaning roller 74, a sprayer 76 to spray a non-polar cleaning liquid to assist in the scrubbing process and a wiper blade 78 to complete the cleaning of the photoconductive surface. Cleaning roller 74 which may be formed of any synthetic resin known in the art for this purpose is driven in the same sense as drum 10 as indicated by arrow 80, such that the surface of the roller scrubs the surface of the photoreceptor. Any residual charge left on the surface of photoreceptor sheet 12 may be removed by flooding the photoconductive surface with light from optional neutralizing lamp assembly 36, which may not be required in practice.
In accordance with a preferred embodiment of the invention, after developing each image in a given color, the single color image is transferred to intermediate transfer member 30. Subsequent images in different colors are sequentially transferred in alignment with the previous image onto intermediate transfer member 30. When all of the desired images have been transferred thereto, the complete multi-color image is transferred from transfer member 30 to substrate 72. Impression roller 71 only produces operative engagement between intermediate transfer member 30 and substrate 72 when transfer of the composite image to substrate 72 takes place. Alternatively, each single color image is separately transferred to the substrate via the intermediate transfer member. In this case, the substrate is fed through the machine once for each color or is held on a platen and contacted with intermediate transfer member 30 for composite image transfer. Alternatively, the intermediate transfer member is omitted and the developed single color images are transferred sequentially directly from drum 10 to substrate 72.
Figs. 3A, 3B and 4A-4D illustrate a preferred embodiment of intermediate transfer member 30 in accordance with a preferred embodiment of the invention. Fig 3A shows an intermediate transfer blanket 100 mounted on a drum 102. Transfer blanket 100 (whose details are shown in Figs. 4C and 4D) comprises a preferably layered transfer portion 104 and a mounting fitting 106.
As shown most clearly in Fig. 4C, transfer portion 104 comprises a release layer 109 which is outermost on the blanket when it is mounted on drum 102. Underlying layer 109 is a conforming layer 111 preferably of a soft elastomer, preferably of polyurethane and preferably having a Shore A hardness of less than about 65, more preferably, less than about 55, but preferably more than about 35. A suitable hardness value is between 45-55, preferably about 50. Underlying layer 111 is a conductive layer 114 which overlays a thin barrier layer 115. Barrier layer 115 overlays a blanket body 116 comprising a top layer 118, a compressible layer 120 and a fabric layer 122. Underlying the fabric layer is preferably an adhesive layer 126 which is in contact with drum 102.
Drum 102 is preferably heated by an internal halogen lamp heater or other heater to aid transfer of the image to and from the release layer 109 to a final substrate as is well known in the art. Other heating methods, or no heating at all, may also be used in the practice of some aspects of the invention. The degree of heating will depend on the characteristics of the toner and or ink used in conjunction with the invention.
As shown in Figs. 4A, 4B and 4D, mounting fitting 106 comprises an elongate electrically conducting bar 108, for example of a metal such as aluminum formed with a series of L-shaped mounting legs 110 (in the form of finger-like extensions) which are also conducting, preferably of the same material as bar 108, and preferably formed integrally therewith. In particular, bar 108 is formed with a slot into which the end of layered transfer portion 104 is inserted. Preferably, the end of the layered portion which is inserted into the mounting bar does not have a release layer 109 or conforming layer 111, whereby conducting layer 114 is exposed and is therefore in electrical contact with bar 108. Alternatively, the bar 108 can be formed with sharp internal projections which pierce the outer layers of the blanket and contact the conducting layer.
Optionally, each of the layers beneath the conducting layer 114 may be partially conducting (for example, by the addition of conductive carbon black or metal fibers) and the adhesive layer may be conductive, such that current also flows directly from the drum surface to the conducting layer.
In one preferred embodiment of the invention, fitting 106 is formed of a single sheet of metal, wherein the legs are partially cut from the metal which is bent into a U shape to form the slot into which the layered portion is inserted. After insertion, the outer walls of the slot are forced against the layered portion to secure the layered portion in the slot. The partially cut out portion is bent to form the mounting legs.
In the preferred embodiment of the invention shown in Figs. 1-3, drum 102 is maintained at a potential suitable for transferring images to the intermediate transfer member, for example at 500 volts, which voltage is applied, via mounting fitting 106 to conductive layer 114. Thus, the source of transfer voltage is very near the outer surface of portion 104 which allows for a lower transfer potential on the drum.
In a preferred embodiment of the invention, Transfer portion 104 is fabricated by the following procedure:

1- The starting structure for blanket construction is a blanket body 116 generally similar to that generally used for printing blankets. One suitable body is MCC-1129-02 manufactured and sold by Reeves SpA, Lodi Vecchio (Milano), Italy. Other preferred blanket types are described in US Patents 5,047,808 ; 4,984,025 ; 5,335,054 and PCT publications WO 91/03007 ; WO 91/14393 ; WO 90/14619 ; and WO 90/04216 . In a preferred embodiment of the invention, body 116 comprises a fabric layer 122, preferably of woven NOMEX material and having a thickness of about 200 micrometers, a compressible layer 120, preferably comprising about 400 micrometers of saturated nitrile rubber loaded with carbon black to increase its thermal conductivity. Layer 120 preferably contains small voids (about 40 - 60 % by volume) and a top layer 118 preferably comprised of the same material as the compressible layer, but without voids. Layer 109 is preferably about 100 micrometers thick. The blanket body is produced by manufacturing methods as are generally used for the production of offset printing blankets for ink offset printing.
Blanket body 116 is preferably sized to a relatively exact thickness by abrading portions of the surface of top layer 118. A preferred thickness for the finished body 116 is about 700 micrometers, although other thicknesses are useful, depending on the geometry of the printing system in which it is used and the exact materials used in the blanket body.
2- The fabric side of blanket body 116 is preferably coated with a 30 micrometer thick coating of silicone based adhesive (preferably, Type D 66 manufactured by Dow Corning). The adhesive is covered with a sheet of mylar coated with a fluorosilicone material, such as DP 5648 Release Paper (one side coat) distributed by H.P. Smith Inc., Bedford Park, IL. This adhesive is characterized by its good bond to the surface of drum 102 and is resistant to the carrier liquid used in the liquid toner. The blanket may be removed from the drum, when its replacement is desired, by cutting the blanket along the edge of fitting 106 and removing the blanket and fitting.
An adhesive is used to assure good thermal contact between the back of the blanket and the drum on which it is mounted. A silicone adhesive is used since adhesives normally used in attachment of blankets deteriorate under the heat which is generated in the underlying drum in the preferred apparatus. While the temperature of the drum varies, depending on the thermal resistance of the blanket and the desired surface temperature of the blanket (which in turn depends on the toner used in the process and the details of transfer of the toner to the final substrate), the drum temperature may reach 80°C, 100°C, 120°C or 150°C or more.
3- Top layer 118 is preferably coated with a sub-micron layer of primer before being coated with additional layers. A preferred primer is Dow Corning 1205 Prime Coat. The type of primer depends on the properties of the top layer and of the conductive layer. Preferably, 0.3 micron of primer is coated onto a clean top layer with a No. 0 bar in a wire-rod coating apparatus and is allowed to dry before applying the conductive layer.
4- Since blanket body 116 may contain materials such as anti-oxidants, anti-ozonants or other additives which may migrate through the upper layers of the blanket, for example as a gas when the blanket is heated during the imaging process and/or in the presence of carrier liquid such as Isopar L, barrier layer 115 is preferably coated onto top layer 118 (or more exactly onto the primer). This barrier layer should be substantially impervious to such materials in the blanket body which may migrate and/or to the carrier liquid which is used.
If this layer is omitted, under certain circumstances the additive materials can cause deterioration of the photoreceptor. In particular, it was found that the imaging process may become humidity dependent.
In a preferred embodiment of the invention, a 4-11 micrometer layer of polyvinyl alcohol (88% hydrolyzed) is coated onto the primer layer covering top layer 118.
Polyvinyl alcohol, 88% hydrolyzed, having an average molecular weight preferably between 85,000 and 145,000 (Aldrich Chemical Co. Inc., Milwaukee, WI) is dissolved in water at 90°C by continuously stirring the mixture in a reflux system for 30 minutes. After 30 minutes, a quantity of ethanol equal to twice the quantity of water is added to the solution, the resulting polyvinyl alcohol concentration being preferably less than 10%. Higher concentration solutions can be used; however, they give a more viscous solution which is hard to spread evenly.
The solution is deposited on layer 118 of body 116 using a fine wire rod or knife inclined at 30-45° to the direction of movement of the knife or body. The solvent is evaporated either by drying at room temperature or by blowing hot air on the layer.
One or more coating passes are employed to give the required thickness.
Too thin a layer will result in some transfer of material from body 116, which has been correlated with reduced transfer efficiency from the photoreceptor to the intermediate transfer blanket, which is believed to be caused by photoreceptor deterioration. While four micrometers of material appears to be sufficient to avoid leaching, a somewhat larger thickness is preferably used.
Other barrier materials and other thicknesses may be used depending on the carrier liquid used for the toner or the gasses omitted by body 116. Other barrier materials may require lesser or greater thickness depending on their resistance to the carrier liquid or the gasses released by body 116. Alternatively, if body 116 resists leaching by the carrier liquid or does not contain materials which are released (especially when body 116 is heated) or any anti-oxidants and/or anti-ozonants, layer 115 may be omitted.
Polyvinyl alcohol is a thermoplastic crystalline material having a melting point which is higher than the temperature of the blanket during operation. Polyvinyl alcohol is also believed to form a layer which is impervious to gasses and to the hydrocarbon carrier liquid used in the liquid toner.
5- Conductive layer 114 is preferably formed of acrylic rubber loaded with conductive carbon black. In a preferred embodiment of the invention, only 2-3 micrometers of conductive coating are required. The conductive layer is formed by first compounding 300 grams of Hytemp 4051EP (Zeon Chemicals) with 6 grams of Hytemp NPC 50 and 9 grams of sodium stearate in a two-roll mill for 20 minutes; and then dissolving 150 grams of the compounded material in 2000 grams of methyl ethyl ketone (MEK) by stirring for 12 hours at room temperature.
40 grams of conductive carbon black, such as, for example, Printex XE2 (Degussa) are added to the solution and the mixture is ground in a 01 attritor (Union Process) loaded with 3/16" steel balls. Grinding proceeds at 10°C for 4 hours after which time the material is diluted by the addition of MEK to a concentration of 7.5-8% solids and discharged from the grinder in the form of a conductive lacquer.
The blanket (after step 3 or step 4) is overcoated with about 3 micrometers of the conductive lacquer (three passes using a No. 0 rod) and allowed to dry for 5 minutes at room temperature.
An additional coating of primer is added over the conductive lacquer (except for the portion which is to be inserted into bar 108) before the soft elastomeric conforming layer is applied.
The resistance of the conductive layer should preferably be more than about 20 kohms/square and preferably less than about 50 kohm/square. This value will depend on the resistivity of the layers above the conducting layer and on the aspect ratio of the blanket. In general, the resistance should be low enough so that the current flowing on the conducting layer (to supply leakage current through the overlying layers) should not cause a substantial variation of voltage along the surface of the blanket. The resistance of the conducting layer and, more importantly, the resistance of the overlying layers control the current flowing through the overlying layers. Generally speaking, the conductive layer has a relatively low resistance and resistivity, the conforming layer (layer 111) has a higher resistivity and the overlying release layer (layer 109) has a still higher resistivity.
6- One kg of pre-filtered Fomrez-50 polyester resin (Hagalil Company, Ashdod, Israel) is dehydrated and degassed under vacuum at 60°C. 600 grams of the degassed material is mixed with 1.4 grams of di-butyl-tin-diluarate (Aldrich) and degassed at room temperature for 2 hours. 30 grams of the resulting material, 3.15 grams of RTV Silicone 118 (General Electric) and 4.5 grams of Polyurethane cross-linker, DESMODUR 44V20 (Bayer) are stirred together. A 100 micrometer layer of the material is coated over the primed conductive layer using a No. 3 wire rod with several passes under clean conditions, preferably, class 100 conditions. The coating is cured for two hours at room temperature under a clean hood to form a polyurethane layer.
Other methods of forming suitable conforming layers are shown and described in the parents of this application. Alternatively, the conductive layer may be omitted and layer 118 made conductive.
Layer 111 which is thus formed should have a resistance of the order of about 10⁹ ohm-cm, good thermal stability at the working temperature of the blanket surface, which is preferably about 100°C or less.
The function of the conforming layer is to provide good conformation of the blanket to the image forming surface (and the image on the image forming surface) at the low pressures used in transfer of the image from the image forming surface to the blanket. The layer should have a Shore A hardness preferably of between 25 or 30 and 65, more preferably about 50. While a thickness of 100 micrometers is preferred, other thicknesses, between 50 micrometers and 300 micrometers can be used, with 75 to 125 micrometers being preferred.
7- 12 grams of RTV silicone 236 (Dow Corning) release material preferably diluted with 2 grams of Isopar L (Exxon) and 0.72 grams of Syl-off 297 (Dow Corning) are mixed together. A wire rod (bar No. 1) coating system is used, with five or six passes, under clean conditions to achieve an 8 micrometer release layer thickness. The material is cured at 140°C for two hours. The cured release material has a resistivity of approximately 10¹⁴ to 10¹⁵ ohm-cm.

In order to mount blanket 100 on drum 102, mounting legs 110 are inserted into a plurality of mounting holes 130 formed in drum 102, preferably without removing the mylar sheet from the adhesive layer (the back of the blanket). As can be seen most clearly in Fig. 3A, 3B and 4D, mounting legs 110 each have a tip portion 132 and a back portion 134. Tips 132 are inserted into slots formed in the far sidewalls of mounting holes 130 and the back portion 134 rests against the opposite sidewall of the hole. In this way the end of the blanket is accurately positioned. The edge of the mylar sheet closest to the legs is removed and the remainder of the mylar sheet is progressively removed while making sure that the successive portions of the blanket which are thus attached to the drum by the adhesive lie flat against the drum.
The present inventors have found that this method of mounting is far superior to either adhesive mounting alone or to grippers at both ends of the blanket in providing a stable transfer surface.
As an alternative to, or additional to, the adhesive layer 126, a very soft conforming layer may be used at the back of the blanket. A soft layer of this type will allow for good thermal contact between the blanket and the heated drum 102 so that the temperature of the drum need not be excessive in order for the outer surface of the blanket to reach its operating temperature. Furthermore, such a very soft layer will cause the blanket to "cling" to the drum obviating the use of adhesive under certain circumstances. Furthermore, when the blanket is replaced there is no adhesive residue on the drum to be removed.
A very soft layer may be produced by the following method:

1- 100g of Hi-Temp 4051 EP (Zeon) acrylic resin is mixed with 2g NPC-50 crosslinker (Zeon) and 3g sodium stearate and dissolved in toluene to give a solution of 15% non-volatile solids. Optionally, up to about 40g of carbon black Pearls 130 (Cabot) is added.
2- A thin layer of the solution is coated onto release coated mylar and dried. This process is repeated several times until a thickness of preferably 20-30 micrometers is achieved.
3- The uncured resin is laminated to the adhesive layer of a blanket produced in accordance with the invention, or directly to the fabric layer. This step is preferably carried out prior to the cure of the release layer.
4- The laminated structure is cured together with the release layer and the release coated mylar is removed.

The layer has a Shore A hardness of about 20-24 without carbon black and about 40-45 with carbon black. Softer materials are also suitable; however, substantially harder materials do not adhere well to the drum surface. Optionally, the adhesive layer at the trailing end of the blanket is not coated with the very soft layer to improve coherence of the blanket and the drum. This is especially desirable for harder layers.
The acrylic material may be replaced by other soft elastomer materials such as soft polyurethane or nitrile rubber. Other heat improving fillers which have a smaller effect on the hardness of the final product may be used instead of carbon black, such as Fe₂O₃ or alpha aluminum oxide.
Fig. 5 shows an alternative, preferred embodiment of the invention in which somewhat different shaped holes 130' are used. In this embodiment the back portion 134 rests against a protrusion 150 formed on one side of the hole while a surface 154 of leg 110 rests against the bottom 156 of a protrusion formed on the other side of the hole.
While the preferred electrical connection between the conductive layer and the mounting bar is preferably achieved by removing (or not forming) the layers which overlay an end portion of the conductive layer, piercing the overlying layers, for example, by crimping and/or piercing the mounting bar, for example, at points marked 160 in Fig. 4D. Crimping can also be used to hold the blanket in the mounting bar.
While the adhesive layer preferably covers the back of the blanket, alternatively the adhesive layer may cover only a portion of the back such as the edge farthest away from the bracket (the trailing edge of the blanket); or may, for some embodiments of the invention and under certain circumstances, be omitted.
It should be understood that some aspects of the invention are not limited to the specific type of image forming system used and some aspects of the present invention are also useful with any suitable imaging system which forms a liquid toner image on an image forming surface and, for some aspects of the invention, with powder toner systems. Some aspects of the invention are also useful in systems such as those using other types of intermediate transfer members such as belt or continuous coated drum type transfer members. Some aspects of the invention are suitable for use with offset printing systems. The specific details given above for the image forming system are included as part of a best mode of carrying out the invention; however, many aspects of the invention are applicable to a wide range of systems as known in the art for electrophotographic and offset printing and copying.
It will be appreciated by persons skilled in the art that the present invention is not limited by the description and example provided hereinabove. Rather, the scope of this invention is defined only by the claims which follow:

Claims

An intermediate transfer member for the transfer of liquid toner images, comprising:
a transfer surface adapted to receive the images from a first surface and to transfer them to a second surface; and

a void free resilient layer (118) underlying the transfer surface;
characterized in that:
a barrier layer (115), that is substantially impervious to one or both of liquid hydrocarbon and gasses, is situated intermediate the resilient layer and the transfer surface.
An intermediate transfer member according to claim 1 wherein the barrier layer (115) is substantially impervious to liquid hydrocarbon.
An intermediate transfer member according to claim 2 wherein the resilient layer (118) comprises a material which is at least partly leachable by the liquid hydrocarbon.
An intermediate transfer member according to claim 2 or claim 3 wherein the member is adapted for the transfer of liquid toner images comprising toner particles and carrier liquid and wherein the liquid hydrocarbon is the carrier liquid.
An intermediate transfer member according to claim 1 wherein the resilient layer releases gases and the barrier layer (115) is substantially impervious to said gases.
An intermediate transfer member according to any of the preceding claims wherein the barrier layer (115) comprises at least partially hydrolyzed polyvinyl alcohol.
An intermediate transfer member according to any of the preceding claims comprising:
a conforming layer (111) operatively associated with the transfer surface and having a Shore A hardness of less than about 65 overlaying the resilient layer (118).
An intermediate transfer member according to claim 7 wherein the material has a Shore A hardness of less than about 50.
An intermediate transfer member according to claim 7 or claim 8 wherein the material has a Shore A hardness of more than about 30.
An intermediate transfer member according to any of the preceding claims wherein intermediate transfer member is in the form of a substantially rectangular blanket.
An intermediate transfer blanket according to claim 10 comprising a soft layer, having a Shore A hardness of less than 90, on the surface of the layered transfer portion opposite to the transfer surface.
An intermediate transfer blanket according to claim 1 wherein the soft layer has a Shore A hardness of less than about 45.
An intermediate transfer blanket according to claim 12 wherein the soft layer has a Shore A hardness of less than about 25.
An intermediate transfer blanket according to claim 11 wherein the soft layer has a Shore A hardness of about 45.
An intermediate transfer blanket according to any of claims 11-14 wherein the soft layer comprises an acrylic elastomer.
An intermediate transfer blanket according to claim 10 wherein the blanket comprises an adhesive layer (126) on a face thereof opposite to the transfer surface.
An intermediate transfer blanket according to claim 16 wherein the adhesive layer is stable at a temperature of at least 80°C.
An intermediate transfer blanket according to claim 17 wherein the adhesive layer is stable at a temperature above 100°C.
An intermediate transfer blanket according to claim 17 wherein the adhesive layer is stable at a temperature above 120 degrees.
An intermediate transfer blanket according to claim 17 wherein the adhesive layer is stable at a temperature above 150°C.
Imaging apparatus for performing an imaging process, comprising:
an imaging surface (12) having a liquid toner image comprising toner particles and carrier liquid formed thereon; and

an intermediate transfer member according to any of the preceding claims, which receives the toner image from the imaging surface and from which it is subsequently transferred.