EP1173322A1

EP1173322A1 - Method for fabricating composite pressure vessels and products fabricated by the method

Info

Publication number: EP1173322A1
Application number: EP00912013A
Authority: EP
Inventors: James C. Murphy; Gerald S. Boyce; Erik Coeckelbergs
Original assignee: Pentair Inc
Current assignee: Pentair Inc
Priority date: 2000-02-28
Filing date: 2000-02-28
Publication date: 2002-01-23
Anticipated expiration: 2020-02-28
Also published as: DE60013801T2; CA2370658A1; IL146203A0; ATE276090T1; AU3381400A; PT1173322E; DE60013801D1; EP1173322B1; AU777216B2; KR100466299B1; WO2001064427A1; ES2228478T3; KR20020029861A; DK1173322T3

Abstract

A process, and the product thereof, for making a composite vessel having at least one closed end, the process including the steps of: fabricating a thermoplastic liner for the vessel; overlaying onto the liner a layer of commingled fiber and thermoplastic material to obtain a composite intermediate structure (112); pressing and heating the composite intermediate structure to effect at least partial consolidation in apparatus which includes upper (113) and lower (111) silicon rubber bags, the bags having dimensions such that, during operation, their facing peripheral regions about to encompass the composite intermediate structure; then placing the composite intermediate structure in a mold; heating the composite intermediate structure in the mold while applying a force, such as internal gas pressure, tending to urge the composite intermediate structure against and into the shape of the interior walls of the mold until the thermoplastic liner and the overlaid layer fully consolidate; coding the mold and composite vessel until the composite vessel is solidified; and removing the formed composite vessel from the mold. The commingled fiber and thermoplastic material may either be wound onto the liner or laid on the liner in the form of fabric woven from the fiber and threads of the thermoplastic material.

Description

METHOD FOR FABRICATING COMPOSITE PRESSURE VESSELS AND PRODUCTS FABRICATED BY THE METHOD

Field of the Invention

This invention relates to the art of fabricating pressure vessels and, more particularly, to improved methods for fabricating composite pressure vessels and to composite pressure vessels made in accordance with the improved methods. Background of the Invention

Pressure vessels, such as hot water heaters, boilers, pressurized gas tanks and the like, have traditionally been fabricated from metal such as steel. However, in recent years, the use of composite pressure vessels has become more prevalent. These composite pressure vessels have typically been fabricated by a filament winding process which utilizes thermoset plastic resins such as epoxies, polyesters and vinylesters. Briefly, this technology is the process of impregnating dry fibers, such as fiberglass strands, with catalyzed resin prior to application to a mandrel. Preimpregnated fibers ("prepreg") may also be used. The mandrel and applied composite are then cured, at ambient temperature or with heat, to set-up the laminate and obtain a hard resin and fiber laminate shell. This shell is either removed from the mandrel or the mandrel itself becomes part of the finished product. Although the specific product application determines the exact function of the resin, in all cases, in all cases it serves as the support structure for keeping the continuous fiber strands in position. The thermoset resins used in these processes can be categorized as of the low temperature commodity type which are characterized by their relative ease of use, low cost and availability. These resins have long served to meet the performance requirements of a wide range of pressure vessel products. However, these resin systems have-well known drawbacks which may include their limited temperature capabilities, unsatisfactory finished product aesthetics, lack of extended durability, lack of appropriateness for recycling and manufacturing related issues such as downtime due to clean-up and material handling costs. Further, there are environmental concerns arising from worker exposure to vapor, overspray, emissions, etc. encountered during the fabrication processes. Some engineered thermoset resins improve performance through higher temperature capability, but unacceptable material costs are associated with them. In addition, because of the materials and processes employed, composite pressure vessels prepared according to the prior art processes inherently have residual and significant internal stresses which, along with certain temperature sensitive incompatibilities of the materials, limit the pressure and temperature ranges in which the pressure vessels find use.

Thus, increasing performance demands, environmental issues, manufacturing issues and new market opportunities have emphasized the limitations of the use of thermoset resins in the manufacture of composite pressure vessels. Composite pressure vessels with higher temperature and pressure capabilities, improved appearance and greater durability and impact resistant characteristics and which, as to fabrication, are more environmentally-friendly, more cost effective and present fewer manufacturing issues, are accordingly highly desirable. Therefore, it will be recognized by those skilled in the art that a process for fabricating composite pressure vessels which achieves improvement in all these areas requires a fundamentally different philosophy. It is to the provision of such a fundamentally improved process, and to pressure vessels made by such process that the present invention is directed and by which the following characteristics are obtained: improved contact at higher temperatures between the fiber and resin, better control over reinforcement/matrix ratio, scrap materials which can be effectively recycled, diminished regulation issues caused by emissions, higher processing speeds for the winding (or other overlaying mode) and curing steps, potential labor savings due to less material handling, floor space reduction, adaptability to automation, a safer environment for employees, simplification of processing lines and of material storage and handling, faster changeover times, faster startups, lower training costs, lower energy costs, etc. Therefore, pressure vessels fabricated according to the process are substantially stress relieved and exhibit improved performance over the prior art pressure vessels in that, inter alia, they can withstand higher pressures and temperatures, are more impact resistant and also have a significantly better finish. Objects of the Invention It is therefore a broad object of this invention to provide an improved process for fabricating a composite pressure vessel.

It is more particular an object of this invention to provide such an improved process which enjoys advantages including, as opposed to prior art processes of fabricating composite pressure vessels: better control over reinforcement/matrix ratio, scrap materials which can be effectively recycled, diminished regulation issues caused by emissions, higher processing speeds for the winding (or alternatives to winding) and curing steps, substantial labor savings due to less material handling, floor space reduction, susceptibility to automation, a safer environment for employees, simplification of processing lines and of material storage and handling, faster changeover times, faster startups, lower training costs, lower energy costs, etc. In another aspect, it is an object of this invention to provide a process for fabricating composite pressure vessels which, in use, enjoys long term performance at least as good as that of traditional pressure vessels.

In yet another aspect, it is an object of this invention to provide high quality composite pressure vessels fabricated according to new processes. In still yet another aspect, it is an object of this invention to provide high quality composite pressure vessels which have improved durability, impact resistance and corrosion resistance as well as higher temperature and pressure handling characteristics and which also have good machinabi ty attnbutes and can therefore readily be welded, cut, drilled, threaded, stamped or the like as may be desired to produce a high quality finished product Summary of the Invention

Briefly, these and other objects of the invention are achieved by a process for fabricating a composite vessel which includes A) fabricating a thermoplastic liner for the vessel, B) overlaying onto the thermoplastic liner a commingled layer of fiber (such as fiberglass) and a thermoplastic material to obtain a composite intermediate structure, C) pressing and heating the composite intermediate structure to effect at least partial consolidation of the components thereof in apparatus which includes an upper silicon rubber bag and a lower silicon rubber bag, the bags having dimensions such that, when in operative pressing and heating mutual positions, their facing peripheral regions abut to substantially encompass the composite intermediate structure, D) placing the at least partially consolidated composite intermediate structure in a mold, E) heating the composite intermediate structure in the mold while applying at least one force, such as internal gas pressure, thereto tending to urge the composite intermediate structure against and into the shape of the interior walls of the mold, F) continuing step E) until the thermoplastic liner and the overlaid layer fully consolidate to form a composite vessel, G) cooling the mold and composite vessel until the composite vessel is solidified, and H) removing the formed composite vessel from the mold The commingled fiber and thermoplastic material may either be wound onto the liner or laid on the liner m the form of fabric woven from the fiber and threads of the thermoplastic material

In a vaπant embodiment of the invention, the process for making a composite vessel includes the steps of A) fabricating a thermoplastic preform including a layer comprising commingled fiber and thermoplastic material, B) pressing and heating the preform to effect consolidation of the components thereof m pressing and heating apparatus which includes 1) an inner membrane disposed on a first side of the thermoplastic preform, 2) an outer membrane disposed on a second side of the thermoplastic preform, 3) a vacuum source and conduit for evacuating the space between the inner and outer membranes to thereby apply force to the preform, 4) an inner shaped contact heater placed in contact with said inner membrane to apply consolidating heat to the first side of the preform, and 5) an outer shaped contact heater placed in contact with said outer membrane to apply consolidating heat to the second side of the preform, C) after the preform has become fluid, placing the inner and outer membranes and the fluid consolidated preform disposed therebetween in a cold mold, D) applying at least one force to the fluid consolidated preform to urge the walls thereof against said inner and outer membranes and into the shape of the inteπor walls of the mold to form a composite vessel, and E) removing the formed composite vessel from the mold Description of the Drawing

The subject matter of the invention is particularly pointed out and distinctly claimed in the concluding portion of the specification The invention, however, both as to organization and method of operation, may best be understood by reference to the following description taken in con_junction with the subjoined claims and the accompanying drawing of which

FIG 1 is a pictorial view of a liner/mandrel employed in practicing a first inventive embodiment,

FIG 2 is a cross sectional view taken along the lines 2 - 2 of FIG 1 , FIG 3 is a pictorial view of the liner/mandrel shown in FIGs 1 and 2 being overlaid with a layer of a commingled thermoplastic fiber material,

FIG 4 is a view of the liner after being overlaid with the layer of commingled thermoplastic fiber material and includes an enlarged fragmentary cross sectional view,

FIGs 5A, 5B and 5C are cross sectional views taken along the lines 5 - 5 of FIG 3 illustrating three variants of a first type of material which can be wound onto the thermoplastic liner to effect the overlayer,

FIGs 6A and 6B are cross sectional views taken along the lines 6 - 6 of FIG 3 illustrating a second type of material, a roving (FIG 6A) or yarn (FIG 6B) of any one of the three variants illustrated in FIGs 5A, 5B and 5C, which can be wound onto the thermoplastic liner to effect the overlayer,

FIG 7 is a cross sectional view taken along the lines 18 - 18 of FIG 3 illustrating a third type of mateπal, a yarn of the second type of material, which can be wound onto the thermoplastic liner to effect the overlayer,

FIG 8 is a phantom view of a mold showing the modified liner enclosed m a mold in which it is subjected to heat and at least one force tending to urge the modified liner into the shape defined by the inner surface of the mold,

FIG 9 is an enlarged partial cross sectional view of the modified liner illustrating the effects of the heat and force thereon,

FIG 10 is a view similar to FIG 8 showing the modified liner enclosed in a different type of mold,

FIG 11 is a cross sectional view of an open mold containing a preformed thermoplastic component of a pressure vessel fabπcated according to a second inventive embodiment,

FIG 12 is a view similar to FIG 11 illustrating a step in the second inventive embodiment in which a paπson of fluid thermoplastic mateπal is introduced into the inteπor of the preformed component as a second component of a composite pressure vessel to be formed, FIG 13 is a cross sectional view similar to FIGs 11 and 12, but with the mold closed and the components of the pressure vessel being subjected to a force which forms the pressure vessel against the interior wall of the mold,

FIG 14 is a cross sectional view of an open mold containing a preformed thermoplastic component of a pressure vessel fabricated according to a third inventive embodiment and also a thermoplastic liner component disposed in the interior of the first component,

FIG 15 is a cross sectional view similar to FIG 14, but with the mold closed and the components of the pressure vessel being subjected to a force which forms the pressure vessel against the interior wall of the mold, FIG 16 is a cross sectional view of the completed composite pressure vessel prepared by the process shown in FIGs 14 and 15,

FIG 17 is a cross sectional view of an open mold containing a preformed thermoplastic component of a pressure vessel fabricated according to a fourth inventive embodiment and also an outer liner component disposed exteπor to the first component and an inner liner component disposed in the interior of the first component,

FIG 18 is a view similar to FIG 17, but with the mold closed and force producing components coupled to the mold,

FIG 19 is a view similar to FIG 18 showing the pressure vessel being formed in the mold under the influence of heat and one or more forces which urge the pressure vessel components to conform to the contours of the inner wall of the mold,

FIG 20 is a cross sectional view of the completed composite pressure vessel prepared by the process shown in FIGs 17, 18 and 19,

FIG 21 is a cross sectional view of a mold containing a preformed thermoplastic component of a pressure vessel already provided with a thermoplastic liner, the pressure vessel to be fabricated according to a fifth inventive embodiment,

FIG 22 is a view similar to FIG 21 showing the pressure vessel being formed in the mold under the influence of heat and one or more forces which urge the pressure vessel components to conform to the contours of the inner wall of the mold,

FIG 23 is a cross sectional view of the completed composite pressure vessel prepared by the process shown in FIGs 21 and 22,

FIG 24A is a cross sectional view illustrating a preliminary step in preparing a composite pressure vessel in accordance with a sixth inventive embodiment,

FIG 24B is a cross sectional view taken along the lines 24B - 24B of FIG 24A,

FIG 24C is a cross sectional view similar to FIG 24B illustrating a further step in the process which results in an intermediate preform for the composite pressure vessel under formation, FIG. 25 is a cutaway view showing the interior of a mold into which the intermediate preform has been introduced for further processing according to the invention;

FIG. 26 is a partially phantom, partially cross sectional view similar to FIG. 25 illustrating the further processing which results in a completed composite pressure vessel; FIG. 27 A is a longitudinal cross sectional view of the completed composite pressure vessel;

FIG. 27B is a cross sectional view of the completed composite pressure vessel taken along the lines 27B - 27B of FIG. 27A;

FIG. 27C is a cross sectional view of the completed composite pressure vessel taken along the lines 27C - 27C of FIG. 27A; FIG. 28 A is a cross sectional view illustrating a preliminary step in preparing a composite pressure vessel in accordance with a variant of the sixth inventive embodiment in which upper and lower membranes are used in the consolidation process for a commingled preform;

FIG. 28B is a cross sectional view showing a vacuum being applied between the membranes to supply a consolidating atmospheric pressure force to the preform; FIG. 29 A is a cross sectional view showing the membrane assembly enclosing the preform being prepared for a heating step;

FIG. 29B is a cross sectional view showing heat being applied to the preform through the preform to bring about consolidation and render the preform fluid;

FIG. 30A is a cross sectional view of the fluid, consolidated preform being placed in a cold mold; and

FIG. 30 B is a cross sectional view of the formed pressure vessel in the cold mold. Description of the Preferred Embodiment(s)

Referring first to FIGs. 1 and 2, there is shown a thermoplastic liner/mandrel 1 for a composite pressure vessel to be fabricated according to a first inventive embodiment. In the exemplary embodiment, the liner/mandrel 1 is a generally elongated preformed structure terminating at each end in a dome shape 2, 3 having a central, axial opening 4, 5. Thermoplastic liner 1 may, for example, be made of polypropylene, polyethylene, polybutylene terephthalate, polyethylene terephthalate or fiber (e.g., fiberglass) impregnated polypropylene, polyethylene, polybutylene terephthalate or polyethylene terephthalate or another thermoplastic material with appropriate characteristics and can be prepared by any suitable conventional process such as molding a combination of chopped fiber, directional, woven and/or knitted fiber fabric sewn or welded together in the shape of the vessel and commingled with thermoplastic material.

As shown in FIG. 3, a filament, roving, yarn or tape 6 of fiber (e.g., fiberglass, carbon fiber, boron fiber, etc.) and a thermoplastic material is methodically wound onto the outer surface of the thermoplastic liner 1 to form a substantially uniform overlay 7 as shown in the enlarged partial cross section in FIG 4 This step may be earned out, for example, by mounting the thermoplastic lmer 1 onto a mandrel 8 and rotating the lmer as indicated by the arrow 9 while methodically feeding the fιlament(s), roving, yarn or tape 6 from a laterally and reciprocally traversing source as represented by the double arrow 10 and continuing this procedure until the overlay 7 has reached the desired thickness The mateπal 6 may be wound "cold" onto the thermoplastic liner 1 or may be passed through a heater 12 which, in some applications, results in a more uniform overlay 7 (FIG 4) with better functional and/or aesthetic characteπstics The resulting structure 11 is then processed further as will be descπbed m detail below

It has been found to be desirable to suitably vary the feed rate in the regions of the domes and end pieces so that a substantially uniform thickness of the overlay throughout the length of the liner 1 is obtained Alternative winding techniques for achieving a satisfactory uniform overlay are well known in the pπor art, and reference may be taken, for example, to US Patent 3,282,757 entitled METHOD OF MAKING A FILAMENT REINFORCD PRESSURE VESSEL by Richard C Brussee, incorporated by reference herein and disclosing vaπous winding techniques which may be employed in the practice of the present invention

However, the form, and especially the type, of the fiber and thermoplastic mateπal 6 is of significant importance to the practice of the invention such that attention is briefly directed to FIGs 5A, 5B, 5C, 6A, 6B and 7 which illustrate suitable vaπants of the material 6 which may be employed in the practice of the invention In FIG 5 A, separate strands of thermoplastic mateπal 13A and fiber 12A are wound together or separately, but more or less contiguously, as indicated at 6A, onto the liner/mandrel 1 Suitable types of thermoplastic mateπal 13A which may be used in the practice of the invention for this purpose include, but are not limited to, polyethylene, polypropylene, polybutylene terephthalate and polyethylene terephthalate

FIG 5B shows a cross section of a second variant 6B for the material 6 in which the fiber filament 12B is coated with the thermoplastic material 13B by, for example, double extrusion or by any other suitable preliminary process Similarly, FIG 5C shows a cross section of a third variant 6B for the material 6 in which the fiber filament 12C is coated with a powder of the thermoplastic material 13C

Preferably, however, the fiber 12 and thermoplastic mateπal 13 (in any of the forms shown in FIGs 5 A, 5B, 5C), before winding onto the liner/mandrel 1, are first commingled into a roving 6D as shown in FIG 6A or into a yarn 6E of such rovings as shown m FIG 6B Another preferred configuration for the mateπal 6 is shown in FIG 7 as a tape 6F of commingled fiber and thermoplastic mateπal Suitable rovings, yarns and tapes of commingled fiber, e g , fiberglass, and thermoplastic mateπal are commercially available, and one product family which has been found to be well suited for use in the present invention is distπbuted under the trademark Twintex^® by Vetrotex Twintex is prepared by a propπetary process which involves commingling filaments of fiberglass (e g , 17 micrometers in diameter) with filaments (e g , 20 micrometers in diameter) of thermoplastic (e g , polyethylene or polypropylene) duπng the continuous production of rovings, yarns and tapes which are available as such and also m the form of fabπcs Thus, merely by way of example, the thermoplastic liner/mandrel 1 may, itself, be fabricated from Twintex^® fabric which is sewn or welded together and suitably heat treated, for example in a mold, to obtain the preform which is subsequently wound with the fiber and thermoplastic material 6 to obtain the intermediate structure 11

Referπng now to FIG 8, after the intermediate structure 11 has been prepared as descπbed or in any suitable manner, it is placed in a mold 13 (two-piece in the example) The mold is then heated, for example, by embedded resistance heaters represented by the heater 15B controllably dπven from a source E 15A and/or by circulating hot oil, heated by a source H 14A, through coils 14B and/or any other suitable conventional mold-heatmg expedient In addition, at least one force is applied to the mold 13 and/or the inteπor of the intermediate structure 11 which tends to cause the exterior surface of the intermediate structure to conform to the inner surface 13 A (FIG 9) of the mold when the applied heat Q causes the thermoplastic lmer 1 and the wound overlay 7 to fuse together and flow against the mold The force or forces may be generated by applying external compression to the mold halves so as to urge them together as indicated by the aπows designated "F" and/or by pressurizing the intenor of the thermoplastic liner 1 by, for example, using gas pressure from a suitable source 16 conveyed into the liner 1 through a conduit 18 If pressuπzation is employed, caps (threaded or permanent) 19 serve to seal the ends of the intermediate structure 11

The heat is then removed from the mold 13 allowing the now formed composite pressure vessel to harden and to be removed by opening the mold in the conventional manner

In practice, two important optional considerations may be taken into account First, it has been found that the mold should be vented, as represented by the peripherally distπbuted vents 17 shown in FIG 8, to allow the trapped air to escape as the pressure vessel forms against the inner wall of the mold and thus achieve a particularly fine finish to the outer surface of the pressure vessel which requires little, if any, further surface finish Second, in order to be assured of complete fusion between the thermoplastic lmer 1 and the wound overlay 7, it has been found preferable to select respective mateπals with somewhat different melting temperatures for the lmer and the overlay More particularly, the best results are obtained if the heating rate is controlled and the melting point of the liner is selected to be above that of the overlay in order that the thermoplastic mateπal effectively melts around the fiber while the liner is softened, but not fully melted duπng the molding process For example, as well known in the art, the melting point range of polypropylene is 300°F to 330°F while that of polyethylene is 120°F to 140°F As shown in FIG 10, the composite pressure vessel can be fabπcated according to a similar process in which a two-piece mold 20, provided with mating flanges 21, 22 which bolt together, is used, thus fully defining a predetermined three dimensional shape for the inteπor surface of the assembled mold In this configuration, the intermediate structure 11 is placed into the mold which is assembled Then, heat Q is applied as descπbed above while the inteπor of the intermediate structure is pressurized to form the composite pressure vessel In this variant, there is no need to apply external compressive forces to the mold Preferably, vents 17 are provided for the reasons noted above

FIGs 11, 12 and 13 illustrate a different, but related, process for fabπcatmg a composite pressure vessel For claπty, these FIGs are shown in cross section Referπng to FIG 1 1 , a preform 31 is placed in a two-piece mold 30A, 30B The preform 31 , which will serve as an outer shell for the composite pressure vessel to be fabπcated, may be prepared in the manner previously descπbed for the thermoplastic liner 1, but alternatively may be prepared in the manner previously descπbed for the intermediate structure 11, l e , the thermoplastic liner 1 wound with the overlay 7 of fiber and a thermoplastic mateπal As shown m FIG 12, a paπson 32 of molten thermoplastic mateπal, such as polyethylene, polypropylene, polybutylene terephthalate and polyethylene terephthalate, is extruded as an elongated tube through an axial opening 37 in the upper end of the preform 31 The material of the parison 32 is selected to form a good bond with a given preform 31 An insert 33, which may be threaded or permanent, is juxtaposed with respect to the axial opening 37 and within the parison 32 Similarly, if the preform 31 includes a second axial opening 38, another insert 34 is juxtaposed in the second opening

It will be understood by those skilled in the art that the molten parison 32 stores a great deal of latent heat Thus, referring now to FIG 13, the mold halves 30A, 30B are closed, and the interior of the parison is pressurized from a source 35 of pressurized gas via conduit 36 such that the thermoplastic mateπal 32A in the parison not only flows against the inner surface of the preform 31 A, but also imparts sufficient heat to the preform 31A so as to render it fluid Consequently, the outer surface of the preform 31 A flows to conform to the inner surface of the mold, the inserts 33A, 34A melding with the remainder of the structure or defining removable inserts as may be intended

If, in a given configuration, there is insufficient latent heat in the parison to bring about complete consolidation of the preform and the thermoplastic material and the intended conformance of the outer surface of the preform to the interior surface of the mold, then additional heat Q can be applied to the mold to complete the formation of the pressure vessel 37 The mold can then be allowed to cool (or be conventionally force cooled) and opened such that the completed pressure vessel can be removed FIGs 14, 15 and 16 (shown in cross section) illustrate another molding process for forming a preform 41 into a pressure vessel 41A. Refeπing first to FIG. 14, the preform 41 may be prepared according to any of the corresponding processes previously described including the process described in conjunction with FIGs. 1 - 10 which involves winding commingled fiber and a thermoplastic material onto a thermoplastic liner which may, itself, have been prepared by welding or sewing together components of commingled fiber and a thermoplastic material. Or, the preform 41 may be relatively roughly molded from a suitable thermoplastic material such as polyethylene, polypropylene, polybutylene terephthalate and polyethylene terephthalate.

The preform 41, which, in the example, has axial openings 44, 46, is introduced into a two- piece mold 40A, 40B. Then, threaded inserts 43, 45 are juxtaposed in the openings 44, 46. (Of course, inserts such as those 33, 34 employed in the process illustrated in FIGs. 11 - 13 or some other insert type could alternatively be employed depending upon the precise configuration of the pressure vessel sought.) If threaded inserts are employed, their material is selected to have a melting point which is well above the melting point of the preform 41. At least one of the inserts includes an opening for admitting a silicone rubber inflatable bag 42 into the interior of the preform 48. In addition, a heater 48 is disposed within the inflatable bag 42 which is selected to have heat handling capabilities higher than the melting point of the preform 41. A suitable silicone rubber for the inflatable bag 42 is Mosites 1453D supplied by Mosites Rubber in the United States and Aerovac Systems (Keighley) Ltd. in the United Kingdom.

The heater 48 may be of any suitable type such as a resistance electrical heater, power also being supplied by conductors (not shown) which extend through the opening in the threaded insert 43 and are coupled to a suitable controllable power source (not shown). In addition, provision may be made, if necessary or desirable, for separately preheating the preform 41 such as by providing an array of heaters, represented by the electrical resistance heaters 47 A, 47B, proximate the walls of the preform. Power to the heaters 47 A, 47B may be supplied via conductors (not shown) which extend through one or the other or both of the axial openings 44, 46 in the preform 41 and are coupled to a suitable controllable power source (not shown). The mold 40A, 40B, itself may also be conventionally preheated and or heated during the molding process.

If the preform 41 is to be preheated (typically to increase the throughput of the process), this step is carried out to render the preform near fluid and the heaters 47 A, 47B are withdrawn from the mold 40A, 40B which is then closed. Refeπing now to FIG. 15, the inflatable silicone rubber bag 42 is inflated by a source 49 of gas under pressure via a conduit 50 while the heater 48 heats the preform 41 to a fluid state through the bag such that bag exerts outwardly directed forces on the preform which therefore flows to conform to the interior surface of the mold 40A, 40B to form the pressure vessel 41A. It will be noted that, in the example, the axial opening regions of the preform flow to conform to the threads of the inserts 43, 45. The application of heat is then ceased, and when the mold 40A, 40B and formed pressure vessel 41 A have sufficiently cooled, the mold is opened, the threaded inserts 43, 45 are unscrewed and the silicone rubber bag 42 and heater 48 are withdrawn leaving the formed pressure vessel It will be noted that, as represented at 51 , internal threads have been formed, as intended in the example, in the axial openings of the formed composite pressure vessel

In the preparation of some composite pressure vessels, such as household water heaters, the color of the finished product may be of importance It is, of course, possible to prepare a preform according to any of the previously descπbed processes using mateπal(s) which are already colored However, there are two potential objections to this straightforward approach, viz the precolored raw mateπals are more expensive, and a limited number of colois are available in the precolored raw mateπals However, using the pπnciples of the present invention, color may be imparted to a finished pressure vessel in a different and highly satisfactory manner

Similarly, there are applications for pressure vessels, such as ultra-pure water storage, gas (e g , propane, butane, natural gas, etc ) storage and food storage, in which it is desirable to provide an integral impermeable inner liner within a composite pressure vessel Again, a process for providing such an integral impermeable inner liner may be developed according to the present invention For convenience, an example, shown in FIGs 17 - 20, treats both the provision of a desired external color to a composite pressure vessel as well as the provision of an integral impermeable inner lmer It will be understood that either feature can be individually provided Thus, referπng to FIG 17, an assembly including a preform 63 (fabπcated according to any of the previously descπbed methods), suπounded by a film 67 of thermoplastic mateπal of the desired product color, is introduced into a two-piece mold 60A, 60B If an integral impermeable inner liner is to be implemented, a thermoplastic film 66 having the desired characteπstics is introduced into the inteπor of the preform 63 before inserts 64, 65 are suitably juxtaposed The mold 60A, 60B includes respective facing relieved sections 61A, 61B and 62A, 62B which, when the mold is closed, provides passages into the mold inteπor

Referπng now to FIG 18, the mold 60A, 60B is closed, and the inteπor of the mold is coupled to a vacuum source 68 via a conduit 69 Alternatively, or additionally, the inteπor of the inner liner 66 (or the inteπor of the preform 63 if no inner liner is to be incorporated) is coupled to a source 70 of gas under pressure via a conduit 71 As shown in FIG 19, heat Q is applied to the mold order to bπng all the constituents of the composite pressure vessel to be formed to a fluid state while the inteπor of the mold is evacuated as represented by the arrows 72 and the inteπor of the inner liner 66 (or of the preform 63 if there is no inner liner) is pressuπzed as represented by the arrows 73 Consequently, the three (or two) components consolidate and the outer surface of the colored film 67 conforms to the shape of the inteπor of the mold 60A, 60B After the mold has been allowed to cool (or force cooled) and has been opened, the resulting composite pressure vessel 74, shown in FIG 20 (as a cross section slice), is ready for any subsequent processing As previously noted, of course, the inserts 64, 65, can be threaded for subsequent removal leaving one or two axial openings as may be appropπate for the intended purpose of the composite pressure vessel A similar process for fabricating a pressure vessel is illustrated in FIGs 21 - 23 FIG 21 shows a two-piece mold 80A, 80B which may be, for example, a simple sheet metal mold such that a number of pressure vessels may be formed simultaneously The mold, which is shown emplaced in a suitable oven 81 , has been loaded with a preform 82 fabπcated according to any of the methods and of any of the mateπals and/or combinations of mateπals previously described above and having at least one opening for access to the interior thereof A thermoplastic film bag 83, which is intended to function as an integral l er in the completed pressure vessel, is introduced into the inteπor of the preform 82 before the mold 80A, 80B is closed

Referπng now to FIG 22, as heat Q is transferred from the oven 81 to the mold 80A, 80B, gas pressure P (from any suitable source, not shown) is applied to the inteπor of the thermoplastic film bag 83, thereby biasing it toward the inner surface of the preform 82 In addition, vacuum V (from any suitable source, not shown) is pulled on the mteπor of the mold 80A, 80B and thus exteπor to the preform 82 This state is continued until the plastic materials of the preform 82 and plastic film bag consolidate and the outer surface of the composite structure assumes the shape of the inteπor of the mold Then, the mold is taken from the oven 81 , allowed to cool and opened to remove the completed composite pressure vessel 85 which is shown in FIG 23 as made up of the integral structure including the molded preform 82A and the plastic film liner 83A which has fused to the inteπor of the composite pressure vessel

Attention is now directed to FIGs 24A - 27C which illustrate a further inventive embodiment that is particularly well suited for fabricating closed end composite pressure vessels As shown in FIGs 24A and 24B, a flexible thermoplastic mandrel/liner 90 is overlaid with a layer 91 of material constituting a thermoplastic combined with a fiber material as previously described For example, layer 91 may constitute Twintex^® fabric having a +/-54⁰ knit Another exemplary material for the layer 91 is a commingled winding of thermoplastic material and fiber as also previously described In order to increase hoop strength with a wound preform, it is desirable to provide more winding turns (for example, double the number) in the hoop direction as in the longitudinal direction or to wind the thermoplastic material and fiber at suitable angles (which may vary during the winding process) to obtain the desired hoop strength appropriate for the contemplated use of the completed composite pressure vessel

Still referring to FIGs 24A and 24B, upper 92A and lower 92B press plates respectively carry inflatable silicon rubber bags 93A, 93B which, as particularly shown in FIG 24B, may enclose heaters 94A, 94B. The silicon rubber bags 93 A, 93B may be fabricated, for example, from Mosites 1453D which has been identified above. As also shown in FIG. 24B, additional heaters 95 A, 95B may be provided to afford supplementary preheat of the layer 91 and the underlying thermoplastic mandrel 90 which are to be preformed. A tube 96, which will be used to provide access to the interior of the preform later in the process, is emplaced at one end of the preliminary structure of thermoplastic and fiber as shown in FIGs. 24A and 24B.

Thus, the flexible thermoplastic mandrel 90 overlaid with the layer 91 as shown in FIGs. 24A and 24B, is uniformly preheated by the heaters 94A, 94B, 95A, 95B to institute the process of consolidation of the thermoplastic and fiber elements in the structure. When the consolidation process has proceeded to a point at which the thermoplastic/fiber layer 91 and thermoplastic mandrel 90 have sufficiently fused for the successive step shown in FIG. 24C, one or both of the press plates 92A, 92B are moved toward one another until the outboard portions of the bags 93A, 93B abut in the regions 97 A, 97B which, in effect, extend continuously about the facing peripheral regions of the bags so that the mandrel 90 and layer 91 are completely encompassed. The bladders 93 A, 93B may be permanently or controllably pressurized to ensure effective operation.

While the apparatus is in the position shown in FIG. 24C, the heating operation continues from heaters 94A, 94B until the consolidation of the thermoplastic material and fiber has been fully completed such that the material 91 and mandrel 90, once cooled, constitute a closed preform except for the opening in one end provided by the presence of the tube 96. Refeπing now to FIG. 25 which shows one-half of a mold 99, the consolidated preform 98

(shown in cross section) has been placed in the interior of the mold with the tube 96 extending through a seal member 100 (shown in cross section). The interior surface of the mold 99, when both halves are mated, defines the outer surface of the composite pressure vessel being fabricated. The mold 99 also includes vents 101 as previously described. FIG. 26 shows the mold 99 closed with heat Q applied, if necessary, to maintain sufficient fluidity of the preform for the molding step. Pressure is introduced into the interior of the preform through the tube 96 such that the preform expands outwardly until its outer surface engages the inner surface of the mold to thus establish the outer surface of the composite pressure vessel 102. Air in the mold outboard the preform escapes through the vents 101 as the preform expands under pressure during the expansion step. As explained above with respect to other invention embodiments, vacuum may be asserted through the vents 101 or otherwise introduced into the interior of the mold 00 outboard the preform 98 to supplement or replace the pressure introduced into the interior of the preform.

After the composite pressure vessel 102 (the fully expanded preform 98) has been formed in the mold 99, the mold is sufficiently cooled or allowed to cool to permit opening and removal of the pressure vessel which is illustrated in FIGs. 27 A, 27B, 27C after the tube 26 has been removed. Thus, the end of the composite pressure vessel shown in FIG. 27C is closed whereas the end shown in FIG. 27B has only the small opening left after the removal of the tube 96. It will be understood that this opening may be sealed or threaded or subjected to such other operations as may be appropriate for the intended use of the completed composite pressure vessel. Further, the size of the tube 96 may be selected to facilitate such finishing operations. If desired, the composite pressure vessel 102 may also be further processed to add exterior and/or interior liners in the manner previously described.

FIGs. 28A, 28B, 29, 30A and 30B show a variant process to that shown in FIGs. 24A 27C. Referring first to FIG. 28A, a commingled thermoplastic preform 112, such as a flexible thermoplastic mandrel/liner overlaid with a layer of material constituting a thermoplastic combined with a fiber material as previously described, is positioned between an inner membrane 1 1 1 and an outer membrane 113. The inner membranel l l and outer membrane 113 may be fabricated, for example, from the silicone rubber material previously identified. Then, as shown in FIG. 28B, a vacuum is pulled, via tube 114, between the membranes 111, 113 to remove air and apply an atmospheric consolidation pressure A to the preform 112.

Referring now to FIG. 29A, an inner shaped contact heater 115A and an outer shaped contact heater 115B are positioned, respectively, facing the inner membrane 112 and outer membrane 1 13. Then, as shown in FIG. 29B, the contact heaters 115A, 115B are brought into contact, respectively, with the outer surfaces of the inner membrane 111 and the outer membrane 1 13. Sufficient heat is transfeπed from the contact heaters 114 A, 114B to the membranes 111, 113 to raise the temperature of the preform to about 185°C - 195°C in order to melt the commingled thermoplastic preform 112 and render the preform fluid.

While the working contours of the contact heaters 115 A, 115 B in the example are illustrated as respectively concave and convex, it will be understood that any suitable working contour for each contact heater may be selected for processing a commingled thermoplastic given preform.

As shown in FIG. 30A the fluid and consolidated preform 112 is next placed into a cold mold 116A, 116B. The cold mold is then closed, FIG. 30B, and gas pressure is introduced into the interior of the fluid preform, via tube 117 (or by evacuating the exterior of the preform) to cause its walls to expand outwardly against the inner surfaces of the membranes 111, 113 until the outer surfaces of the membranes confirm to the contours of the inner wells of the cold mold 116A, 116B. As a result, the preform 112 is simultaneously formed and cooled (by heat transfer to the cold mold 116A, 1 16B) to effect the pressure vessel 118 which can be removed from the cold mold and finished as may be desired in accordance with the foregoing descriptions.

Composite pressure vessels fabricated in accordance with all the processes disclosed above have performance and aesthetic characteristics significantly improved over those fabricated with the pπor art processes More particularly, they can withstand higher pressures and temperatures, are more impact resistant and exhibit a significantly better finish They also have good machinabihty attributes and can therefore readily be welded, cut, drilled, threaded, stamped or the like as may be desired to produce a high quality finished product

Thus, while the principles of the invention have now been made clear in illustrative embodiments, there will be immediately obvious to the those skilled in the art many modifications of structure and components used in the practice of the invention which are particularly adapted for specific environments and operating requirements without departing from those pπnciples

Claims

WHAT IS CLAIMED IS

1 The process for making a composite vessel, having at least one closed end, comprising the steps of

A) fabricating a thermoplastic lmer for the vessel, B) overlaying onto the thermoplastic liner a layer comprising commingled fiber and thermoplastic material to obtain a composite intermediate structure,

C) pressing and heating the composite intermediate structure to effect at least partial consolidation of the components thereof in pressing and heating apparatus comprising

1) an upper bag, and 2) a lower bag,

3) the upper and lower bags being of such dimensions that, when in operative pressing and heating mutual positions, their facing peripheral regions abut to substantially encompass the composite intermediate structure,

D) placing the at least partially consolidated composite intermediate structure in a mold, E) heating the composite intermediate structure in a mold while applying at least one force thereto tending to urge the composite intermediate structure against and into the shape of the inteπor walls of the mold,

F) continuing step E) until the thermoplastic liner and the overlaid layer fully consolidate to form a composite vessel, G) cooling the mold and composite vessel until the composite vessel is solidified, and

H) removing the formed composite vessel from the mold

2 The process of Claim 1 in which the upper and lower bags of the pressing and heating apparatus are fabricated from silicone rubber and in which each of the upper and lower bags contain heaters

3 The process of Claim 1 in which the pressing and heating apparatus comprises the upper and lower bags respectively earned in facing relationship by upper and lower press components

4 The process of Claim 3 in which the upper and lower bags of the pressing and heating apparatus are fabricated from silicone rubber and in which each of the upper and lower bags contain heaters

5 The process of Claim 1 in which, duπng step B), the fiber and thermoplastic material are wound onto the thermoplastic liner to obtain the composite intermediate structure

6. The process of Claim 2 in which, during step B), the fiber and thermoplastic material are wound onto the thermoplastic liner to obtain the composite intermediate structure.

7. The process of Claim 3 in which, during step B) the fiber and thermoplastic material are wound onto the thermoplastic liner to obtain the composite intermediate structure.

8. The process of Claim 4 in which, during step B) the fiber and thermoplastic material are wound onto the thermoplastic liner to obtain the composite intermediate structure.

9. The process of Claim 1 in which the fiber and thermoplastic material constitute are commingled in a fabric prior to being overlaid onto the thermoplastic liner.

10. The process of Claim 2 in which the fiber and thermoplastic material constitute are commingled in a fabric prior to being overlaid onto the thermoplastic liner.

11. The process of Claim 3 in which the fiber and thermoplastic material constitute are commingled in a fabric prior to being overlaid onto the thermoplastic liner.

12. The process of Claim 4 in which the fiber and thermoplastic material constitute are commingled in a fabric prior to being overlaid onto the thermoplastic liner.

13. The process of Claim 1 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

14. The process of Claim 2 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

15. The process of Claim 3 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

16. The process of Claim 4 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

17 The process of Claim 5 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure

18 The process of Claim 6 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure

19 The process of Claim 7 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure

20 The process of Claim 8 in which the at least one force applied during step E) is obtained b> introducing gas pressure into the interior of the composite intermediate structure

21 The process of Claim 9 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure

22 The process of Claim 10 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure

23 The process of Claim 11 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure

24 The process of Claim 12 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure

25 A composite vessel, having at least one closed end, fabπcated by the process of

A) fabricating a thermoplastic lmer for the vessel,

B) overlaying onto the thermoplastic liner a layer comprising commingled fiber and thermoplastic material to obtain a composite intermediate structure, C) pressing and heating the composite intermediate structure to effect at least partial consolidation of the components thereof in pressing and heating apparatus comprising

1) an upper bag, and

2) a lower bag, 3) the upper and lower bags being of such dimensions that, when in operative pressing and heating mutual positions, their facing peripheral regions abut to substantially encompass the composite intermediate structure;

D) placing the at least partially consolidated composite intermediate structure in a mold; E) heating the composite intermediate structure in a mold while applying at least one force thereto tending to urge the composite intermediate structure against and into the shape of the interior walls of the mold;

F) continuing step E) until the thermoplastic liner and the overlaid layer fully consolidate to form a composite vessel; G) cooling the mold and composite vessel until the composite vessel is solidified; and

H) removing the formed composite vessel from the mold.

26. A composite vessel fabricated by the process set forth in Claim 25 in which the upper and lower bags of the pressing and heating apparatus are fabricated from silicone rubber and in which each of the upper and lower bags contain heaters.

27. A composite vessel fabricated by the process set forth in Claim 25 in which the pressing and heating apparatus comprises the upper and lower bags respectively carried in facing relationship by upper and lower press components.

28. A composite vessel fabricated by the process set forth in Claim 27 in which the upper and lower bags of the pressing and heating apparatus are fabricated from silicone rubber and in which each of the upper and lower bags contain heaters.

29. A composite vessel fabricated by the process set forth in Claim 25 in which, during step B), the fiber and thermoplastic material are wound onto the thermoplastic liner to obtain the composite intermediate structure.

30. A composite vessel fabricated by the process set forth in Claim 26 in which, during step B), the fiber and thermoplastic material are wound onto the thermoplastic liner to obtain the composite intermediate structure.

31. A composite vessel fabricated by the process set forth in Claim 27 in which, during step B) the fiber and thermoplastic material are wound onto the thermoplastic liner to obtain the composite intermediate structure.

32. A composite vessel fabricated by the process set forth in Claim 28 in which, during step B) the fiber and thermoplastic material are wound onto the thermoplastic liner to obtain the composite intermediate structure.

33. A composite vessel fabricated by the process set forth in Claim 25 in which the fiber and thermoplastic material constitute are commingled in a fabric prior to being overlaid onto the thermoplastic liner.

34. A composite vessel fabricated by the process set forth in Claim 26 in which the fiber and thermoplastic material constitute are commingled in a fabric prior to being overlaid onto the thermoplastic liner.

35. A composite vessel fabricated by the process set forth in Claim 27 in which the fiber and thermoplastic material constitute are commingled in a fabric prior to being overlaid onto the thermoplastic liner.

36. A composite vessel fabricated by the process set forth in Claim 28 in which the fiber and thermoplastic material constitute are commingled in a fabric prior to being overlaid onto the thermoplastic liner.

37. A composite vessel fabricated by the process set forth in Claim 25 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

38. A composite vessel fabricated by the process set forth in Claim 26 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

39. A composite vessel fabricated by the process set forth in Claim 27 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

40. A composite vessel fabricated by the process set forth in Claim 28 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

41. A composite vessel fabricated by the process set forth in Claim 29 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

42. A composite vessel fabricated by the process set forth in Claim 30 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

43. A composite vessel fabricated by the process set forth in Claim 31 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

44. A composite vessel fabricated by the process set forth in Claim 32 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

45. A composite vessel fabricated by the process set forth in Claim 33 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

46. A composite vessel fabricated by the process set forth in Claim 34 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure.

47. A composite vessel fabricated by the process set forth in Claim 35 in which the at least one force applied during step E) is obtained by introducing gas pressure into the interior of the composite intermediate structure. 48 A composite vessel fabricated by the process set forth in Claim 36 in which the at least one force applied during step E) is obtained by introducing gas pressure into the inteπor of the composite intermediate structure

49 The process for making a composite vessel, having at least one closed end, comprising the steps of

A) fabricating a thermoplastic preform including a layer comprising commingled fiber and thermoplastic material, B) pressing and heating the preform to effect consolidation of the components thereof in pressing and heating apparatus comprising

1) an inner membrane disposed on a first side of the thermoplastic preform,

2) an outer membrane disposed on a second side of the thermoplastic preform,

3) means for evacuating the space between the inner and outer membranes to thereby apply force to the preform,

4) an inner shaped contact heater placed in contact with said inner membrane to apply consolidating heat to the first side of the preform, and

5) an outer shaped contact heater placed in contact with said outer membrane to apply consolidating heat to the second side of the preform, C) after the preform has become fluid, placing the inner and outer membranes and the fluid consolidated preform disposed therebetween in a cold mold,

D) applying at least one force to the fluid consolidated preform to urge the walls thereof against said inner and outer membranes and into the shape of the inteπor walls of the mold to form a composite vessel, and E) removing the formed composite vessel from the mold

50 The process of Claim 49 in which the inner and outer membranes of the pressing and heating apparatus are fabricated from silicon rubber

51 The process of Claim 49 in which the at least one force applied during step D) is obtained by introducing gas pressure into the interior of the preform

52 The process of Claim 50 in which the at least one force applied during step D) is obtained by introducing gas pressure into the interior of the preform

53 A composite vessel fabπcated by the process of

A) fabricating a thermoplastic preform including a layer comprising commingled fiber and thermoplastic material,

B) pressing and heating the preform to effect consolidation of the components thereof in pressing and heating apparatus comprising

1) an inner membrane disposed on a first side of the thermoplastic preform,

2) an outer membrane disposed on a second side of the thermoplastic preform, 3) means for evacuating the space between the inner and outer membranes to thereby apply force to the preform,

5) an outer shaped contact heater placed in contact with said outer membrane to apply consolidating heat to the second side of the preform,

C) after the preform has become fluid, placing the inner and outer membranes and the fluid consolidated preform disposed therebetween in a cold mold,

D) applying at least one force to the fluid consolidated preform to urge the walls thereof against said inner and outer membranes and into the shape of the interior walls of the mold to form a composite vessel, and

E) removing the formed composite vessel from the mold

54 A composite vessel fabricated by the process of Claim 53 in which the inner and outer membranes of the pressing and heating apparatus are fabricated from silicon rubber

55 A composite vessel fabricated by the process of Claim 53 in which the at least one force applied during step D) is obtained by introducing gas pressure into the interior of the preform

56 A composite vessel fabπcated by the process of Claim 54 in which the at least one force applied during step D) is obtained by introducing gas pressure into the interior of the preform