EP1114956B1 - An overpressure valve - Google Patents

An overpressure valve Download PDF

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Publication number
EP1114956B1
EP1114956B1 EP00830002A EP00830002A EP1114956B1 EP 1114956 B1 EP1114956 B1 EP 1114956B1 EP 00830002 A EP00830002 A EP 00830002A EP 00830002 A EP00830002 A EP 00830002A EP 1114956 B1 EP1114956 B1 EP 1114956B1
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EP
European Patent Office
Prior art keywords
connection
obturator
valve
valve body
cursor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP00830002A
Other languages
German (de)
French (fr)
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EP1114956A1 (en
Inventor
Andrea Storci
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oil Control SpA
Original Assignee
Oil Control SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oil Control SpA filed Critical Oil Control SpA
Priority to AT00830002T priority Critical patent/ATE266829T1/en
Priority to EP00830002A priority patent/EP1114956B1/en
Priority to DE60010641T priority patent/DE60010641T2/en
Publication of EP1114956A1 publication Critical patent/EP1114956A1/en
Application granted granted Critical
Publication of EP1114956B1 publication Critical patent/EP1114956B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16KVALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
    • F16K17/00Safety valves; Equalising valves, e.g. pressure relief valves
    • F16K17/02Safety valves; Equalising valves, e.g. pressure relief valves opening on surplus pressure on one side; closing on insufficient pressure on one side
    • F16K17/04Safety valves; Equalising valves, e.g. pressure relief valves opening on surplus pressure on one side; closing on insufficient pressure on one side spring-loaded
    • F16K17/10Safety valves; Equalising valves, e.g. pressure relief valves opening on surplus pressure on one side; closing on insufficient pressure on one side spring-loaded with auxiliary valve for fluid operation of the main valve
    • F16K17/105Safety valves; Equalising valves, e.g. pressure relief valves opening on surplus pressure on one side; closing on insufficient pressure on one side spring-loaded with auxiliary valve for fluid operation of the main valve using choking or throttling means to control the fluid operation of the main valve

Definitions

  • the overpressure valve of the invention is made according to the specifications in the preamble to the first claim.
  • valves of this type connect a pressurised environment with a discharge when the pressure in the environment exceeds a predetermined pressure P max .
  • these valves are safety valves acting so as to limit the pressure in an environment at risk of overpressure; they open automatically when pressure P max is reached in the environment.
  • Prior-art valves of this type have the drawback that on opening there is a certain and considerable increase in the pressure due to the increase in fluid head passing through the valve. Owing to this phenomenon, represented clearly in the curve denoted by A in figure 1, the various structural components connected to the valve (pipes, actuators, other valves etc.) have to be oversized with respect to maximum pressure P max at which the valve opens, in order to cope with overpressure ⁇ p.
  • the main aim of the present invention is to obviate the above-mentioned drawback in the prior art by providing a valve, of the type described, in which the overpressure ⁇ p caused on valve opening is considerably lower than that found in prior-art valves.
  • An advantage of the invention is that it has relatively low hysteresis.
  • Another advantage of the invention is that it provides a simple, economical, extremely reliable and very stable valve.
  • a further aim of the invention is to provide a safety device for controlling the lowering of a load, in which, when the valve opens due to an overload situation arising, the pressure increase (with respect to rated P max valve opening) on valve opening is relatively contained.
  • a control device can be made which enables the load-lowering manoeuvre to begin gradually and smoothly.
  • Figure 1 shows two curves, denoted by A and B, relating to the progress of pressure p according to the head Q present in a direct overpressure valve of known type (curve A); and in a valve according to the invention (curve B).
  • the overpressure ⁇ p A (with respect to maximum rated pressure P max for valve opening) in the known valve is decidedly higher than that for overpressure ⁇ p B of the valve of the invention.
  • the hysteresis in the valve of the invention is considerably lower than that in the known valve.
  • valve body 2 having a first connection 3 for inlet of a pressurised fluid, and a second connection 4 for discharge of the fluid to the outside.
  • the valve 1 comprises a first obturator 5, internal of the valve body 2, operating between the first and second connections 3 and 4, and being axially mobile.
  • a spring 6 acts directly on the obturator 5 to close it while the pressurised fluid present in the first connection 3 acts to open it.
  • the first obturator 5, normally closed by the spring 6, is destined on to open by effect of exceeding a predetermined maximum pressure P max of the fluid at the first connection 3.
  • the valve 1 is provided with a cursor 7, internally of the valve body 2, which is mobile coaxially and solidly with the first obturator 5 and has an end surface 7a facing in the opposite direction to the opening side of the first obturator 5 (in figure 4, the first obturator 5 opens left side, while the end surface 7a faces right).
  • the cursor 7 is solidly connected to the first obturator 5 by means of a coaxial stem 8 internal of the valve body 2.
  • valve body 2 Inside the valve body 2 is located at least one pilot conduit 9, 9' which places the first connection 3 in communication with the cursor end surface 7a.
  • a safety valve V is predisposed in the pilot conduit 9, 9'; the safety valve V is provided with a second obturator 10, which obturator 10 is located internally of the valve body 2 and is normally closed by action of an adjustable spring 11, and will open by effect of a predetermined pressure p 1 of the fluid at the first connection 3, which pressure p 1 will not be higher than pressure P max at which the first obturator 5 opens.
  • the springs 6 and 11 of the first and second obturators are calibrated so that the opening pressure p 1 of the second obturator 10 is lower than the opening pressure P max of the first obturator 5.
  • the valve body 2 externally exhibits a third connection 12, for connection with a pilot pressure.
  • the third connection 12 communicates through a first choke section 13 with a tract 9' of the pilot conduit comprised between the second obturator 10 and the cursor end surface 7a.
  • a second choke section 14 is present in the tract 9' of pilot conduit, situated at a point comprised between the first choke section 13 and the cursor end surface 7a.
  • a single-acting valve 15 is located inside the valve body 2 and is predisposed parallel to the first obturator 5 in order to enable a flow from the second connection 4 to the first connection 3.
  • FIG. 5 is a diagram of a second embodiment of the overpressure valve of the invention, denoted by 1', in which the same elements also present in the valve of figures 2, 3 and 4 are indicated by the same numbers.
  • the valve 1' comprises a first obturator 5 closed by a spring 6 and opened by the pressure present in a first connection 3 or inlet.
  • the valve 1' is opened by means of a pilot conduit 9 which reads the pilot pressure at the first connection 3; a valve V acts on the pilot conduit 9, which valve V is equipped with a second obturator 10 closed by a spring calibrated to a lower pressure with respect to the first obturator 5.
  • Constructionally the valve 1' of figure 5 comprises all of the elements of the valve in figures 3 and 4 numbered from 2 to 11. It does not comprise the third pilot connection 12, the two choke sections 13 and 14, and the single-acting valve 15.
  • a valve 1" comprises all the elements of the valve 1' of figure 5 and also includes a discharge conduit 16 which connects the pilot conduit 9 with the second connection 4. At least one choke section 17 is predisposed along the discharge conduit 16, to guarantee reclosing of the first obturator 5 with a relatively small hysteresis.
  • Figure 7 schematically shows a device for controlling lowering of a load, which could be applied for example to the arm of a crane, which device comprises at least one hydraulic linear actuator P having a first chamber 18 which is operatively associated to the lifting of a load and a second chamber 19 operatively associated to the lowering of a load.
  • the device comprises a hydraulic transmission circuit of an operative fluid provided with at least one distributor 20 having a first branch 21 which connects the distributor 20 to the first chamber 18 and a second branch 22 which connects the distributor 20 to the second chamber 19.
  • the overpressure valve 1 of figures 2, 3 and 4 is predisposed on the first branch 21; the first connection 3 is connected to the first chamber 18, the second connection 4 is connected to the distributor 20 and the third connection 12 is connected through a pilot branch 23 to the second branch 22 of the hydraulic transmission circuit.
  • the second choke section 14 of the overpressure valve 1 is preferable but not necessary.
  • Figure 8 shows a device for controlling the descent of a load (borne for example by a crane arm or another load lifting vehicle) comprising a direct overpressure valve 1'", made according to a fourth embodiment, in which a discharge conduit 24 connects a tract 9' of the pilot conduit comprised between the second obturator 10 and the end surface 7a of the cursor to the second connection 4; at least one choke section 25 and a single-acting valve 26 are predisposed along the discharge conduit 24.
  • valves 1 and 1' through connection with the pilot conduit 23, act as normal balance valves, with the second obturator 10 closed.
  • anomalous situations such as overpressure due to external causes, causing overpressure in the first chamber 18
  • the valves 1 and 1'" function as previously described, with overpressure ⁇ p B and hysteresis greatly reduced.
  • the invention thus enables an externally-piloted (though the conduit 23) balance valve to be realised, for control of load lowering and able most efficiently to protect the system against undesired overpressures.

Abstract

An overpressure valve exhibits a first connection (3) for inlet of a pressurised fluid and a second connection (4) for discharge, between which a first, axially-mobile obturator (5) is located and piloted to close by a spring (6) and to open by the pressurised fluid at the first connection (3). The first obturator is solidly connected, by a stem (8), to a coaxial cursor (7) having an end surface (7a) which is connected, through a pilot conduit (9, 9') to the first connection (3). A second obturator (10), predisposed on the pilot conduit (9, 9'), opens by effect of a predetermined fluid pressure at the first connection (3) which pressure is lower than the maximum opening pressure of the first obturator (5). The valve enables overpressure on opening of the first obturator (5) to be considerably reduced. <IMAGE>

Description

  • The overpressure valve of the invention is made according to the specifications in the preamble to the first claim.
  • As is well known, valves of this type connect a pressurised environment with a discharge when the pressure in the environment exceeds a predetermined pressure Pmax. In other words, these valves are safety valves acting so as to limit the pressure in an environment at risk of overpressure; they open automatically when pressure Pmax is reached in the environment. Prior-art valves of this type, however, have the drawback that on opening there is a certain and considerable increase in the pressure due to the increase in fluid head passing through the valve. Owing to this phenomenon, represented clearly in the curve denoted by A in figure 1, the various structural components connected to the valve (pipes, actuators, other valves etc.) have to be oversized with respect to maximum pressure Pmax at which the valve opens, in order to cope with overpressure Δp.
  • The main aim of the present invention is to obviate the above-mentioned drawback in the prior art by providing a valve, of the type described, in which the overpressure Δp caused on valve opening is considerably lower than that found in prior-art valves.
  • An advantage of the invention is that it has relatively low hysteresis.
  • Another advantage of the invention is that it provides a simple, economical, extremely reliable and very stable valve.
  • A further aim of the invention is to provide a safety device for controlling the lowering of a load, in which, when the valve opens due to an overload situation arising, the pressure increase (with respect to rated Pmax valve opening) on valve opening is relatively contained.
  • Thanks to the invention, a control device can be made which enables the load-lowering manoeuvre to begin gradually and smoothly.
  • These aims and advantages and more besides are all attained by the present invention, as it is characterised in the appended claims.
  • Further characteristics and advantages of the present invention will better emerge from the detailed description that follows of some preferred but non-exclusive embodiments of the invention, illustrated purely by way of a nonlimiting example in the accompanying figures of the drawings, in which:
  • figure 1 shows two curves A and B which describe the progress of the pressure levels in the valve according to the head crossing through the valve, respectively for a known valve and for the valve of the invention;
  • figure 2 is a diagram of a first embodiment of the valve according to the present invention;
  • figure 3 is a partially-sectioned lateral view of the valve of figure 2;
  • figure 4 is section IV-IV of figure 3;
  • figure 5 is a diagram of a second embodiment of the valve of the invention;
  • figure 6 is a diagram of a third embodiment of the valve of the invention;
  • figure 7 is a safety device for controlling the descent of a load, comprising the valve of figures 2, 3 and 4;
  • figure 8 is a safety device for controlling the descent of a load, comprising a fourth embodiment of the valve of the invention.
  • Figure 1 shows two curves, denoted by A and B, relating to the progress of pressure p according to the head Q present in a direct overpressure valve of known type (curve A); and in a valve according to the invention (curve B). The overpressure ΔpA (with respect to maximum rated pressure Pmax for valve opening) in the known valve is decidedly higher than that for overpressure ΔpB of the valve of the invention. Furthermore, the hysteresis in the valve of the invention is considerably lower than that in the known valve.
  • With reference to figures 2, 3 and 4, 1 denotes in its entirety an overpressure valve, comprising a valve body 2 having a first connection 3 for inlet of a pressurised fluid, and a second connection 4 for discharge of the fluid to the outside.
  • The valve 1 comprises a first obturator 5, internal of the valve body 2, operating between the first and second connections 3 and 4, and being axially mobile. A spring 6 acts directly on the obturator 5 to close it while the pressurised fluid present in the first connection 3 acts to open it. The first obturator 5, normally closed by the spring 6, is destined on to open by effect of exceeding a predetermined maximum pressure Pmax of the fluid at the first connection 3.
  • The valve 1 is provided with a cursor 7, internally of the valve body 2, which is mobile coaxially and solidly with the first obturator 5 and has an end surface 7a facing in the opposite direction to the opening side of the first obturator 5 (in figure 4, the first obturator 5 opens left side, while the end surface 7a faces right). The cursor 7 is solidly connected to the first obturator 5 by means of a coaxial stem 8 internal of the valve body 2.
  • Inside the valve body 2 is located at least one pilot conduit 9, 9' which places the first connection 3 in communication with the cursor end surface 7a.
  • A safety valve V is predisposed in the pilot conduit 9, 9'; the safety valve V is provided with a second obturator 10, which obturator 10 is located internally of the valve body 2 and is normally closed by action of an adjustable spring 11, and will open by effect of a predetermined pressure p1 of the fluid at the first connection 3, which pressure p1 will not be higher than pressure Pmax at which the first obturator 5 opens. Preferably the springs 6 and 11 of the first and second obturators are calibrated so that the opening pressure p1 of the second obturator 10 is lower than the opening pressure Pmax of the first obturator 5.
  • The valve body 2 externally exhibits a third connection 12, for connection with a pilot pressure. The third connection 12 communicates through a first choke section 13 with a tract 9' of the pilot conduit comprised between the second obturator 10 and the cursor end surface 7a. A second choke section 14 is present in the tract 9' of pilot conduit, situated at a point comprised between the first choke section 13 and the cursor end surface 7a.
  • A single-acting valve 15 is located inside the valve body 2 and is predisposed parallel to the first obturator 5 in order to enable a flow from the second connection 4 to the first connection 3.
  • Figure 5 is a diagram of a second embodiment of the overpressure valve of the invention, denoted by 1', in which the same elements also present in the valve of figures 2, 3 and 4 are indicated by the same numbers.
  • The valve 1' comprises a first obturator 5 closed by a spring 6 and opened by the pressure present in a first connection 3 or inlet. The valve 1' is opened by means of a pilot conduit 9 which reads the pilot pressure at the first connection 3; a valve V acts on the pilot conduit 9, which valve V is equipped with a second obturator 10 closed by a spring calibrated to a lower pressure with respect to the first obturator 5. Constructionally the valve 1' of figure 5 comprises all of the elements of the valve in figures 3 and 4 numbered from 2 to 11. It does not comprise the third pilot connection 12, the two choke sections 13 and 14, and the single-acting valve 15.
  • In a third embodiment illustrated in figure 6, a valve 1" comprises all the elements of the valve 1' of figure 5 and also includes a discharge conduit 16 which connects the pilot conduit 9 with the second connection 4. At least one choke section 17 is predisposed along the discharge conduit 16, to guarantee reclosing of the first obturator 5 with a relatively small hysteresis.
  • Figure 7 schematically shows a device for controlling lowering of a load, which could be applied for example to the arm of a crane, which device comprises at least one hydraulic linear actuator P having a first chamber 18 which is operatively associated to the lifting of a load and a second chamber 19 operatively associated to the lowering of a load.
  • The device comprises a hydraulic transmission circuit of an operative fluid provided with at least one distributor 20 having a first branch 21 which connects the distributor 20 to the first chamber 18 and a second branch 22 which connects the distributor 20 to the second chamber 19.
  • The overpressure valve 1 of figures 2, 3 and 4 is predisposed on the first branch 21; the first connection 3 is connected to the first chamber 18, the second connection 4 is connected to the distributor 20 and the third connection 12 is connected through a pilot branch 23 to the second branch 22 of the hydraulic transmission circuit. In figure 7 the second choke section 14 of the overpressure valve 1 is preferable but not necessary.
  • Figure 8 shows a device for controlling the descent of a load (borne for example by a crane arm or another load lifting vehicle) comprising a direct overpressure valve 1'", made according to a fourth embodiment, in which a discharge conduit 24 connects a tract 9' of the pilot conduit comprised between the second obturator 10 and the end surface 7a of the cursor to the second connection 4; at least one choke section 25 and a single-acting valve 26 are predisposed along the discharge conduit 24.
  • During operation of all of the above-described overpressure valves, 1, 1', 1", 1'", when the pressurised environment connected to the first connection 3 reaches the calibrated pressure of the spring 11 (due to a situation causing overpressure), the second obturator 10 opens automatically and the end surface 7a of the cursor comes into communication with the first connection 3 through the pilot conduit 9, 9'. When the pressure rises to reach the spring 6 calibration setting value, the first obturator 5 opens, setting the first connection 3 in communication with the second (discharge) connection 4. It has been found that when the obturator 5 opens, the pressure p in the valve in relation to the head Q of fluid is as described by curve B in figure 1. Thanks to the invention both initial overpressure ΔpB and hysteresis are reduced.
  • During normal operation of the devices illustrated in figures 7 and 8, the valves 1 and 1'", through connection with the pilot conduit 23, act as normal balance valves, with the second obturator 10 closed. In anomalous situations (such as overpressure due to external causes, causing overpressure in the first chamber 18) the valves 1 and 1'" function as previously described, with overpressure ΔpB and hysteresis greatly reduced.
  • The invention thus enables an externally-piloted (though the conduit 23) balance valve to be realised, for control of load lowering and able most efficiently to protect the system against undesired overpressures.

Claims (8)

  1. An overpressure valve, comprising:
    a valve body (2) having a first connection (3) for inlet of a pressurised fluid and a second connection (4) for discharge of a fluid from the valve;
    a first obturator (5), axially mobile internal of the valve body (2) and operating between the first connection (3) and the second connection (4); a spring (6) closing the first obturator (5) and the pressurised fluid at the first connection (3) opening the first obturator (5); the first obturator (5) being destined to open by effect of a predetermined maximum pressure (Pmax) of the pressurised fluid at the first connection (3);
    characterised in that it further comprises:
    a cursor (7), internal of the valve body (2) and mobile coaxially and solidly with the first obturator (5), having an end surface (7a) facing in an opposite direction with respect to a direction of opening of the first obturator (5); at least one pilot conduit (9, 9'), internal of the valve body (2),
    a second obturator (10), internal of the valve body (2), predisposed in the pilot conduit (9, 9'), which second obturator (10) is normally closed thereby preventing communication between the first connection (3) and the end surface (7a) of the cursor (7), and is destined to open by effect of a predetermined pressure (pi) of the pressurised fluid present at the first connection (3) which predetermined pressure (p1) is not greater than the maximum pressure (Pmax) of opening of the first obturator (5) thereby enabling communication between the first connection (3) and the end surface (7a) of the cursor (7)
  2. The valve of claim 1, characterised in that the cursor (7) is solidly connected to the first obturator (3) by a coaxial stem (8) which is internal of the valve body (2).
  3. The valve of claim 1 or 2, characterised in that the second obturator (10) is predisposed to open by effect of a pressure (p1) which is lower than a maximum opening pressure (Pmax) of the first obturator (5).
  4. The valve of any one of the preceding claims, characterised in that it comprises a discharge conduit (16) which connects the pilot conduit (9) with the second connection (4); at least one choke section (17) being predisposed along the discharge conduit (16).
  5. The valve of any one of the preceding claims, characterised in that the valve body (2) is externally provided with a third connection (12), which is a pilot connection and communicates through a first choke section (13) with a tract (9') of the pilot conduit (9) comprised between the second obturator (10) and the end surface (7a) of the cursor (7).
  6. The valve of claim 5, characterised in that it comprises a second choke section (14) predisposed on the pilot conduit (9') at a point thereof comprised between the first choke section (13) and the end surface (7a) of the cursor (7).
  7. The valve of claim 5 or 6, characterised in that it comprises a discharge conduit (24) which connects a tract (9') of the pilot conduit comprised between the second obturator (10) and the end surface (7a) of the cursor (7) with the second connection (4); at least one choke section (25) and a single-acting valve (26) being predisposed along the discharge conduit (24).
  8. A device for controlling lowering of a load, comprising:
    at least one hydraulic actuator (P) having a first chamber (18) associated to a lifting of a load and a second chamber (19) associated to a lowering of a load;
    an operative fluid transmission circuit provided with at least one distributor (20) having a first branch (21) connecting the distributor (20) with the first chamber (18) and having a second branch (22) connecting the distributor (20) with the second chamber (19);
    an overpressure valve (1, 1"') predisposed on the first branch (21), comprising:
    a valve body (2) having a first connection (3) to the first chamber (18) and a second connection (4) to the distributor (20); a first obturator (5), internal of the valve body (2), operating between the first connection (3) and the second connection (4), being axially mobile and being closed by a spring (6) and opened by pressurised fluid at the first connection (3); the first obturator (5) being destined to open by effect of a predetermined maximum pressure (Pmax) of the pressurised fluid at the first connection (3);
    a single-acting valve (15), internal of the valve body (2), predisposed parallel to the first obturator (5) in order to enable flow from the second connection (4) to the first connection (3);
    characterised in that:
    the overpressure valve (1, 1''') is made according to any one of the claims from 5 to 7, in which the third and pilot connection (12) is connected to the second branch (22) of the hydraulic transmission circuit.
EP00830002A 2000-01-04 2000-01-04 An overpressure valve Expired - Lifetime EP1114956B1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AT00830002T ATE266829T1 (en) 2000-01-04 2000-01-04 PRESSURE VALVE
EP00830002A EP1114956B1 (en) 2000-01-04 2000-01-04 An overpressure valve
DE60010641T DE60010641T2 (en) 2000-01-04 2000-01-04 Pressure relief valve

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP00830002A EP1114956B1 (en) 2000-01-04 2000-01-04 An overpressure valve

Publications (2)

Publication Number Publication Date
EP1114956A1 EP1114956A1 (en) 2001-07-11
EP1114956B1 true EP1114956B1 (en) 2004-05-12

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP00830002A Expired - Lifetime EP1114956B1 (en) 2000-01-04 2000-01-04 An overpressure valve

Country Status (3)

Country Link
EP (1) EP1114956B1 (en)
AT (1) ATE266829T1 (en)
DE (1) DE60010641T2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2317191B1 (en) 2009-10-29 2012-12-12 Bosch Rexroth Oil Control S.p.A. A valve for support and control of a load comprising an obturator
GB2506655A (en) * 2012-10-05 2014-04-09 Sev Glocon Ltd Pressure relief valve

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2619112A (en) * 1946-06-12 1952-11-25 Denison Eng Co Pressure relief valve
DE1256494B (en) * 1966-07-22 1967-12-14 Exnii Metallorezh Stankov Pilot operated safety valve that opens against the direction of flow
US3613716A (en) * 1970-04-13 1971-10-19 Bosch Gmbh Robert Pressure-responsive control valve

Also Published As

Publication number Publication date
DE60010641D1 (en) 2004-06-17
ATE266829T1 (en) 2004-05-15
EP1114956A1 (en) 2001-07-11
DE60010641T2 (en) 2005-04-28

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