EP1032792B1 - Prefabricated set for making a cooking surface - Google Patents

Prefabricated set for making a cooking surface Download PDF

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Publication number
EP1032792B1
EP1032792B1 EP99943030A EP99943030A EP1032792B1 EP 1032792 B1 EP1032792 B1 EP 1032792B1 EP 99943030 A EP99943030 A EP 99943030A EP 99943030 A EP99943030 A EP 99943030A EP 1032792 B1 EP1032792 B1 EP 1032792B1
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EP
European Patent Office
Prior art keywords
frame
elastomer
assembly according
plate
assembly
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Expired - Lifetime
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EP99943030A
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German (de)
French (fr)
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EP1032792A1 (en
Inventor
Pablo Vilato
Frédéric Drujon
Jean-François Mikoda
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Eurokera SNC
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Eurokera SNC
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/68Heating arrangements specially adapted for cooking plates or analogous hot-plates
    • H05B3/74Non-metallic plates, e.g. vitroceramic, ceramic or glassceramic hobs, also including power or control circuits
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24CDOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
    • F24C15/00Details
    • F24C15/10Tops, e.g. hot plates; Rings
    • F24C15/102Tops, e.g. hot plates; Rings electrically heated

Definitions

  • the invention relates to a prefabricated assembly, intended for the production of hobs, including a hob ceramic.
  • Such hobs may include, among other things, heating elements such as radiant or halogen fireplaces and regulating means for varying the power thereof.
  • the assembly of these hobs ends with the installation glass ceramic plate on the metal structure.
  • the assembly of the ceramic hob and the frame is carried out by bonding using a silicone adhesive, which is suitable for such use.
  • the silicone glue fulfills functions of natures different and complementary.
  • silicone glue Another function of the silicone glue is to seal between the metal frame and the ceramic hob.
  • the sub-assembly formed by the plate and the frame must, on the one hand, have a good seal so that water, for example used to clean the visible surface of the ceramic hob, do not not enter inside and may create a short circuit.
  • water for example used to clean the visible surface of the ceramic hob
  • a plate used for preparation food avoid any risk of fouling in areas difficult to access and impossible to clean so as not to see the appearance of germ development.
  • silicone glue Another function still fulfilled by silicone glue is to cushion mechanical shock. It thus avoids direct contact between the frame metal and the ceramic hob and also can compensate the expansions of the metal frame, the ceramic hob having practically zero expansion.
  • An advantageous feature silicone glue is to have good temperature resistance. Although silicone glue is only used in the peripheral part of the ceramic hob and therefore at a certain distance from the areas of heating, this resistance to temperature must be high.
  • a heated container such as a pan, can be placed on the edge of the plate and therefore subjects the frame to a high temperature.
  • a final function of the silicone glue is aesthetic: at minus part of the glue being deposited from above, it is important to be able to smooth it so as to give it a beautiful appearance because the less a part can remain visible.
  • the inventors then set themselves the goal of providing a set prefabricated of the type mentioned above, that is to say comprising a plate ceramic hob and a frame that allows, once assembled in cooktop, the latter to have a clear interface with the work plan for which it is intended.
  • the invention relates to a prefabricated assembly, intended for the production of a hob, comprising a plate of glass ceramic cooking and a frame consisting of a part extending to the periphery of the plate and of another part extending in a plane substantially vertical to the plate, characterized in that at least one of the two parts of the frame has an elastomer overmolding, this topping comprising legs to immobilize the frame in the workplan.
  • the prefabricated assembly thus proposed by the invention satisfies the problem.
  • the overmolding in the outer peripheral part of the frame ensures a clear interface with the upper part of the work plan, in particular from a sealing point of view.
  • Nature elastic of the elastomer allows the profile to marry the form of the work plan, which can be particularly effective when it is not plumb and / or when its surface condition is not regular.
  • the frame according to the invention is preferably made of plastic. he is advantageously molded. Preferably again, it is made of resin polymer resistant to temperatures of at least 180 ° C.
  • connection between the hob glass ceramic and the frame it can be chosen to overmold the frame directly on the plate instead of bonding them together by a joint in elastomer, silicone type.
  • the frame advantageously has holes opening through which are molded elastomer buttons.
  • the overmolding is a profile.
  • each of the two parts of the above-mentioned frame advantageously comprises an elastomer profile.
  • the elastomer profile of the part of the frame extending in the substantially vertical plane of the plate consists of legs, preferably having indentations.
  • the Flexible “legs” of the overmolded profile allow, according to this variant, to immobilize the hob perfectly in the worktop, even if it has not been cut within the tolerances desired. This way, we avoid leaving an important game between the vertical walls of the frame and the worktop, play that cannot be compensated in this case only by the presence of parts of setting tricky to set up.
  • Another advantage provided by this variant of the invention is the guarantee not to damage the worktop when setting the table of cooking assembled in the latter.
  • the elastomer profile of the part of the frame extending to the periphery of the plate preferably has a lip, which allows further avoid the risk of fouling.
  • this lip participates, with the elements of flexible supports mentioned above, in support of the frame on the worktop.
  • the molding elastomer according to the invention is advantageously silicone.
  • the invention also relates to a hob incorporating a prefabricated assembly previously defined in claims 1 to 12, the frame of which is fixed to a base supporting heating elements, such as radiant elements or halogen and / or at least one burner with atmospheric gas and / or minus a means of induction heating.
  • a base supporting heating elements such as radiant elements or halogen and / or at least one burner with atmospheric gas and / or minus a means of induction heating.
  • the advantages provided by the invention are numerous. First of all the fact that the elastomer is injected and then polymerized, it no longer has to be smoothed by hand as could be the case according to the prior art, its state of surface is no longer penalizing for the decorative aspect. Similarly, in injecting the elastomer onto an already shaped frame, it is possible to from frames of various shapes and / or colors. Such varieties help to give an aesthetic appearance to the hob.
  • the various shapes also allow the integration of equipment usually integrated into the plate such as the controls heating elements which most of the time require careful drilling of the plate.
  • the frame used according to the process of the invention is preferably made of plastic.
  • the elastomer used is advantageously silicone.
  • step e) of high frequency polymerization According to a very advantageous characteristic of the process, one realizes step e) of high frequency polymerization.
  • the milk to polymerize the elastomer according to the invention by high frequency also saves considerable time during manufacturing.
  • the tool used is usually a elastomer. Therefore, the flexible contact between the tool, in particular the mold, and the different parts making up the prefabricated assembly according to the invention does not risk altering the materials, in particular the glass ceramic constituting the hob.
  • Figure 1 is a sectional view showing a table of cooking 1, carried out in accordance with the invention, integrated into a plan of work 2 of a kitchen.
  • This hob 1 essentially consists of a plate of vitroceramic cooking 3 and a prefabricated assembly according to the invention 4 fixed to a metal base 5, of rectangular section, by means of screws not represented.
  • This frame 6 essentially comprises three parts, namely the sides vertical 61, 62, the outer peripheral portion 63 which surrounds the vitroceramic cooking plate 3 by being directly in contact with it and a flat part 64 which extends substantially in the main plane of the ceramic glass hob 3.
  • This flat part 64 has openings whose function will be explained below.
  • a silicone profile 7 extends over the entire periphery of the frame 6. This has the shape of a lip 71 for the part directly in contact with the upper part of the worktop. This lip 71 has the function ensure a clear interface between frame 6 and the upper part of the work surface, i.e., among other things, a liquid tightness and foods likely to come nearby.
  • the curved shape of the lip 71 gives it an appearance aesthetic.
  • the silicone profile 7 has, in its vertical part, tabs 72, 73 in contact, on the one hand, with the entire height of the vertical flanks 61, 62 of the frame 6 and, on the other hand, with the entire height of the plane of job.
  • the elastic nature of the silicone allows these tabs 72, 73 to be deformed when the hob is inserted into the hob work and therefore ensure perfect immobilization without play between these two elements.
  • Removing the hob is also very easy, without risk damage frame 6 and / or work surface 2.
  • the flat part 64 of the frame meanwhile, has two openings circular 65 and a rectangular opening 66.
  • buttons in silicone 67 which allow, once pressed, to trigger the operation of the heating members not shown.
  • a display digital type which allows viewing the programmed time and / or duration a heating cycle of at least one of the heating members. he can also indicate which heater is in operation if the plate is under electric voltage, the temperature of the organ (s) of heated...
  • Figures 2a and 2e represent the different successive stages the manufacturing process of a second prefabricated assembly according to the invention.
  • the prefabricated assembly 4 and the plate glass ceramic cooking plates 3 are linked together by means of a silicone seal 8.
  • Figure 2a relates to the initial stage of setting up a frame molded 6 in a punch 9.
  • This molded frame 6 is of a chemical nature and similar in shape to that of FIG. 1.
  • Figure 2b shows the glass ceramic plate 3 placed in the punch 9, so as to be slightly raised relative to the frame 6 and leaves an empty space 10.
  • Silicone is then injected inside these channels 12 at by means of an appropriate device.
  • the injection is stopped and proceeds to a polymerization of this same material using a high frequency technique for a time of 0.5 to 2 min, in depending on the mass of silicone to be transformed.
  • the die 11 is then unlocked from the punch 9 and the ejection of the prefabricated assembly is produced, as shown in Figure 2e.
  • Such a method has the advantage of being simple to implement and fast. It is also advantageous since the production of new series with new molded frame shapes can be easily carried out at no additional production cost, the creation of new die and / or punch tools being easy.
  • So brand new plastic of the molded frame may be suitable as long as it withstands high temperatures, typically above 250 ° C.
  • the plastic of the frame conforms to the invention may be chosen from polybutyleneterephthalate (PBT), polyphenylene sulfide (PPS), polyetheretherketone (PEEK), polyacrylate (PAR), polyethersulfone (PES), polyetherimide (PEI), polyamideimlide (PAI), liquid crystal polymer (LCP), polytetrafluoroethylene (PTFE), polyetherethersulfone (PEES), polyepoxides (EP) and, optionally, polysulfone (PSF), fluoropolymer resins (FEP such as for example PTEFE, PFA, ETFE, etc.), polythioethersulfone (PTES), thermoplastic poyimide (TPI), cross linked polyimide (CLPI), polyetherketone (PEK), polyethermitrile (PEN), polycyclohexyleneterephthalate (PCT), polyphthalamide (PPA).
  • PBT polybutyleneterephthalate
  • PPS polyphenylene
  • the frame may be chosen advantageously among polyester resins (UP).
  • any other equivalent profile that can be injected in accordance with the invention is included within the scope of the invention in the provided that silicone-like features such as elasticity and high temperature resistance are fulfilled.

Description

L'invention est relative à un ensemble préfabriqué, destiné à la réalisation de tables de cuisson, comportant une plaque de cuisson vitrocéramique.The invention relates to a prefabricated assembly, intended for the production of hobs, including a hob ceramic.

De telles tables de cuisson peuvent comporter, entre autres, des éléments chauffants tels que des foyers radiants ou halogènes et des moyens de régulation pour faire varier la puissance de ceux-ci.Such hobs may include, among other things, heating elements such as radiant or halogen fireplaces and regulating means for varying the power thereof.

Ces différents éléments sont, de manière usuelle, disposés dans une structure habituellement métallique appelée « caisson » et recouverts par une plaque vitrocéramique équipée d'un cadre métallique qui ferme la structure.These various elements are usually arranged in a usually metallic structure called "box" and covered by a ceramic hob fitted with a metal frame which closes the structure.

Le montage de ces tables de cuisson se termine par la mise en place de la plaque vitrocéramique sur la structure métallique. Au préalable, l'assemblage de la plaque vitrocéramique et du cadre est réalisé par collage à l'aide d'une colle silicone, qui est adaptée pour une telle utilisation. En effet la colle silicone remplit des fonctions de natures différentes et complémentaires.The assembly of these hobs ends with the installation glass ceramic plate on the metal structure. Beforehand, the assembly of the ceramic hob and the frame is carried out by bonding using a silicone adhesive, which is suitable for such use. Indeed the silicone glue fulfills functions of natures different and complementary.

Tout d'abord, elle permet de maintenir la plaque vitrocéramique sur le cadre selon une position définie ; une table de cuisson ainsi réalisée peut être facilement transportée, tous les éléments la constituant étant fixés les uns aux autres, après le montage sur le caisson. First of all, it keeps the ceramic hob on the frame in a defined position; a hob thus produced can be easily transported, all the elements constituting it fixed to each other, after mounting on the box.

Une autre fonction de la colle silicone est d'assurer l'étanchéité entre le cadre métallique et la plaque vitrocéramique.Another function of the silicone glue is to seal between the metal frame and the ceramic hob.

Le sous-ensemble formé par la plaque et le cadre doit, d'une part, présenter une bonne étanchéité de manière à ce que l'eau, par exemple utilisée pour nettoyer la surface apparente de la plaque vitrocéramique, ne pénètre pas à l'intérieur et risque de créer un court-circuit. D'autre part, d'un point de vue hygiénique, une telle plaque servant à la préparation d'aliments, il faut éviter tout risque d'encrassement dans les zones difficiles d'accès et impossibles à nettoyer pour ne pas voir apparaítre des développements de germes.The sub-assembly formed by the plate and the frame must, on the one hand, have a good seal so that water, for example used to clean the visible surface of the ceramic hob, do not not enter inside and may create a short circuit. On the other hand, from a hygienic point of view, such a plate used for preparation food, avoid any risk of fouling in areas difficult to access and impossible to clean so as not to see the appearance of germ development.

Une autre fonction encore remplie par la colle silicone est d'amortir les chocs mécaniques. Elle évite ainsi un contact direct entre le cadre métallique et la plaque vitrocéramique et, également, elle peut compenser les dilatations du cadre métallique, la plaque de cuisson vitrocéramique ayant une dilatation pratiquement nulle. Une caractéristique avantageuse de la colle silicone est de présenter une bonne résistance à la température. Bien que la colle silicone ne soit utilisée qu'en partie périphérique de la plaque vitrocéramique et donc à une certaine distance des zones de chauffe, cette résistance à la température doit être importante.Another function still fulfilled by silicone glue is to cushion mechanical shock. It thus avoids direct contact between the frame metal and the ceramic hob and also can compensate the expansions of the metal frame, the ceramic hob having practically zero expansion. An advantageous feature silicone glue is to have good temperature resistance. Although silicone glue is only used in the peripheral part of the ceramic hob and therefore at a certain distance from the areas of heating, this resistance to temperature must be high.

Ainsi, la périphérie de la plaque subit tout de même une élévation de température lorsqu'un ou plusieurs foyers sont en état de marche. De plus, un récipient chauffé, tel qu'une casserole, peut être déposé sur le bord de la plaque et soumet donc le cadre à une température élevée.So the periphery of the plate is still elevated by temperature when one or more fireplaces are in working order. Of more, a heated container, such as a pan, can be placed on the edge of the plate and therefore subjects the frame to a high temperature.

Une dernière fonction de la colle silicone est d'ordre esthétique : au moins une partie de la colle étant déposée par le dessus, il est important de pouvoir lisser celle-ci de manière à lui conférer un bel aspect car au moins une partie peut rester apparente.A final function of the silicone glue is aesthetic: at minus part of the glue being deposited from above, it is important to be able to smooth it so as to give it a beautiful appearance because the less a part can remain visible.

Par contre, le montage consistant à coller la plaque vitrocéramique sur le cadre métallique à l'aide d'une colle du type évoqué ci-dessus présente plusieurs inconvénients.On the other hand, the assembly consisting in sticking the ceramic hob on the metal frame using an adhesive of the type mentioned above has several drawbacks.

En premier lieu, la quantité de colle nécessaire étant relativement importante, le coût de ce produit l'est également. Un autre inconvénient est lié au temps de polymérisation qui augmente avec la quantité de matière, ce qui conduit à augmenter les coûts de fabrication. First, the amount of glue required is relatively important, the cost of this product is also important. Another downside is related to the polymerization time which increases with the amount of material, which leads to increased manufacturing costs.

Enfin, un dernier inconvénient réside dans le montage proprement dit. En effet, les plaques vitrocéramiques sont, de manière usuelle, livrées telles quelles aux fabricants de tables de cuisson qui se chargent de l'assemblage. A priori, un tel assemblage en usine ne présente pas de problèmes insurmontables dans la mesure où les ouvriers disposent des outils nécessaires. Par contre, cela apparaít beaucoup plus délicat pour un artisan qui doit remonter une plaque vitrocéramique sur un cadre métallique après avoir effectué une réparation de nature électrique ou bien pour changer cette plaque qui a pu subir des dommages. En effet, il paraít délicat pour l'artisan de fixer la plaque vitrocéramique car il doit, à la fois disposer la colle silicone à la périphérie de la plaque sur la face interne et sur les bords, lisser la colle en zone apparente et maintenir la plaque bien centrée tout en la pressant durant les opérations précédentes et pendant le temps de polymérisation de la colle qui est relativement long, comme évoqué précédemment.Finally, a last drawback lies in the proper mounting said. In fact, the ceramic hobs are usually delivered as such to the cooktop manufacturers who are responsible for assembly. A priori, such assembly in the factory does not present any insurmountable problems insofar as the workers have the necessary tools. By cons, it appears much more difficult for a craftsman who must reassemble a ceramic hob on a frame metallic after performing an electrical repair or to change this plate that may have suffered damage. Indeed, it seems delicate for the craftsman to fix the ceramic hob because he must, at the same time place the silicone adhesive on the periphery of the plate on the inside and around the edges, smooth the glue in the visible area and hold the plate well centered while pressing it during the previous operations and during the curing time of the glue which is relatively long, as previously mentioned.

La dépose d'une telle plaque vitrocéramique n'est également pas aisée. L'artisan doit effectuer une découpe de la colle silicone par le dessous, c'est-à-dire côté face inférieure de la plaque vitrocéramique, et une découpe par le dessus, c'est-à-dire sur le bord de la plaque. Ces deux opérations qui doivent être effectuées sur toute la périphérie ne sont pas simples car les deux lignes de découpe doivent se rejoindre pour bien désolidariser les deux éléments : plaque vitrocéramique et cadre métallique. De plus, et plus particulièrement lors de la découpe côté face interne de la plaque vitrocéramique, il n'est pas aisé d'effectuer cette découpe sans risquer de rayer la face inférieure de la plaque qui est la face la plus fragile de la plaque.The removal of such a ceramic hob is also not Easy. The craftsman must cut the silicone glue using the below, that is to say on the underside of the ceramic hob, and a cut from above, that is to say on the edge of the plate. These two operations that must be performed on the entire periphery are not simple because the two cutting lines must meet for good separate the two elements: ceramic hob and frame metallic. In addition, and more particularly when cutting on the face side internal of the ceramic hob, it is not easy to perform this cut without risking scratching the underside of the plate which is the face the most fragile of the plate.

Ce risque de rayure peut conduire à un risque de fissurations lors de contraintes et donc à une casse de la plaque. Un démontage d'une plaque vitrocéramique, en vue de remonter celle-ci ultérieurement, apparaít donc impossible ou presque à réaliser sans détériorer la plaque.This risk of scratching can lead to a risk of cracking during constraints and therefore a breakage of the plate. A disassembly of a glass-ceramic plate, with a view to reassembling it later, therefore appears almost impossible to achieve without damaging the plate.

De plus, pour la refixer sur le cadre, il est nécessaire d'éliminer au maximum les traces de colle silicone du précédent montage, ce qui risque également d'entraíner des rayures avec les mêmes conséquences que précédemment. In addition, to reattach it to the frame, it is necessary to eliminate maximum traces of silicone glue from the previous assembly, which risks also cause scratches with the same consequences as previously.

Pour remédier à ces inconvénients, il a déjà été proposé selon le brevet FR 2 744 201 de munir la plaque vitrocéramique d'un profilé thermodurcissable surmoulé en partie périphérique inférieure, profilé qui par l'intermédiaire de moyens de fixation adéquats permet la fixation de la plaque à un cadre métallique sans contact direct entre les deux.To remedy these drawbacks, it has already been proposed according to the FR 2 744 201 patent to provide the ceramic hob with a profile thermosetting overmolded in the lower peripheral part, profiled by means of suitable fixing means allows the fixing of the plate to a metal frame without direct contact between the two.

Il a également été proposé, notamment dans le brevet EP 0 449 347, de surmouler directement, par une technique de double injection, un cadre en matière plastique à la périphérie de la plaque vitrocéramique, le cadre en matière plastique étant alors fixé à un socle métallique, support des divers éléments chauffants.It has also been proposed, in particular in patent EP 0 449 347, to directly overmold, by a double injection technique, a plastic frame on the periphery of the ceramic hob, the plastic frame then being fixed to a metal base, support various heating elements.

Cette solution n'est pas pleinement satisfaisante. Le cadre en plastique étant directement en contact avec la partie supérieure du plan de travail, l'interface entre ces deux parties n'est pas nette, en particulier d'un point de vue de l'étanchéité. De ce fait, les risques d'encrassement sont importants.This solution is not fully satisfactory. The frame in plastic being directly in contact with the upper part of the plan working, the interface between these two parts is not clear, in particular from a sealing point of view. Therefore, the risk of fouling are important.

Un ensemble selon le préambule de le revendication 1 et un procédé selon le préamble de la revendication 1 sont connus du EP-A-748 676.An assembly according to the preamble of claim 1 and a method according to the preamble of claim 1 are known from EP-A-748 676.

Les inventeurs se sont alors donné pour but de fournir un ensemble préfabriqué du type évoqué ci-dessus, c'est-à-dire comportant une plaque de cuisson vitrocéramique et un cadre qui permette, une fois assemblé en table de cuisson, à cette dernière d'avoir une interface bien nette avec le plan de travail pour laquelle elle est destinée.The inventors then set themselves the goal of providing a set prefabricated of the type mentioned above, that is to say comprising a plate ceramic hob and a frame that allows, once assembled in cooktop, the latter to have a clear interface with the work plan for which it is intended.

Pour ce faire, l'invention a pour objet un ensemble préfabriqué, destiné à la réalisation de table de cuisson, comportant une plaque de cuisson vitrocéramique et un cadre constitué d'une partie s'étendant à la périphérie de la plaque et d'une autre partie s'étendant dans un plan substantiellement vertical à la plaque, caractérisé en ce qu'au moins une des deux parties du cadre comporte un surmoulage en élastomère, ce surmontage comprenant des pattes à immobiliser le cadre dans le plan de travail.To do this, the invention relates to a prefabricated assembly, intended for the production of a hob, comprising a plate of glass ceramic cooking and a frame consisting of a part extending to the periphery of the plate and of another part extending in a plane substantially vertical to the plate, characterized in that at least one of the two parts of the frame has an elastomer overmolding, this topping comprising legs to immobilize the frame in the workplan.

L'ensemble préfabriqué ainsi proposé par l'invention satisfait au problème posé.The prefabricated assembly thus proposed by the invention satisfies the problem.

En effet, le surmoulage en partie périphérique extérieure du cadre permet d'assurer une interface bien nette avec la partie supérieure du plan de travail, en particulier d'un point de vue étanchéité. La nature élastique de l'élastomère permet en effet au profilé d'épouser au mieux la forme du plan de travail, ce qui peut s'avérer efficace en particulier lorsque celui-ci n'est pas bien d'aplomb et/ou lorsque son état de surface n'est pas régulier.Indeed, the overmolding in the outer peripheral part of the frame ensures a clear interface with the upper part of the work plan, in particular from a sealing point of view. Nature elastic of the elastomer allows the profile to marry the form of the work plan, which can be particularly effective when it is not plumb and / or when its surface condition is not regular.

Le cadre selon l'invention est, de préférence, en matière plastique. Il est avantageusement moulé. De préférence encore, il est en résine polymère résistant à des températures d'au moins 180°C.The frame according to the invention is preferably made of plastic. he is advantageously molded. Preferably again, it is made of resin polymer resistant to temperatures of at least 180 ° C.

Pour ce qui est de la liaison entre la plaque de cuisson vitrocéramique et le cadre, il peut être choisi de surmouler le cadre directement sur la plaque au lieu de les lier ensemble par un joint en élastomère, du type silicone.Regarding the connection between the hob glass ceramic and the frame, it can be chosen to overmold the frame directly on the plate instead of bonding them together by a joint in elastomer, silicone type.

Un tel choix pourra être fait notamment en fonction de la géométrie de la technique de fabrication inhérente au cadre.Such a choice could be made in particular according to the geometry of the manufacturing technique inherent in the frame.

De manière à intégrer les commandes des éléments chauffants, autres moyens de chauffe tels que les brûleurs à gaz et/ou autres éléments fonctionnels de la plaque vitrocéramique, tels qu'une horloge, le cadre comporte avantageusement des trous débouchant au travers desquels sont surmoulés des boutons en élastomère.In order to integrate the heating element controls, other heating means such as gas burners and / or others functional elements of the ceramic hob, such as a clock, the frame advantageously has holes opening through which are molded elastomer buttons.

Selon une caractéristique très avantageuse de l'invention, le surmoulage est un profilé.According to a very advantageous characteristic of the invention, the overmolding is a profile.

Selon cette même caractéristique, chacune des deux parties du cadre précitées, comporte avantageusement un profilé en élastomère.According to this same characteristic, each of the two parts of the above-mentioned frame, advantageously comprises an elastomer profile.

D'une manière très avantageuse, le profilé en élastomère de la partie du cadre s'étendant dans le plan substantiellement vertical de la plaque est constitué de pattes, de préférence présentant des échancrures. Les « pattes » flexibles du profilé surmoulé permettent, selon cette variante, d'immobiliser parfaitement la table de cuisson dans le plan de travail, même si la découpe de celui-ci n'a pas été réalisée dans les tolérances souhaitées. On évite, de cette façon, de laisser subsister un jeu important entre les parois verticales du cadre et le plan de travail, jeu qui ne peut être compensé dans ce cas uniquement par la présence de pièces de calage délicates à mettre en place.Very advantageously, the elastomer profile of the part of the frame extending in the substantially vertical plane of the plate consists of legs, preferably having indentations. The Flexible “legs” of the overmolded profile allow, according to this variant, to immobilize the hob perfectly in the worktop, even if it has not been cut within the tolerances desired. This way, we avoid leaving an important game between the vertical walls of the frame and the worktop, play that cannot be compensated in this case only by the presence of parts of setting tricky to set up.

Un autre avantage apporté par cette variante de l'invention est la garantie de ne pas détériorer le plan de travail lors de la pose de la table de cuisson assemblée dans ce dernier.Another advantage provided by this variant of the invention is the guarantee not to damage the worktop when setting the table of cooking assembled in the latter.

Le profilé en élastomère de la partie du cadre s'étendant à la périphérie de la plaque comporte, de préférence, une lèvre, ce qui permet d'éviter de manière accrue, le risque d'encrassement.The elastomer profile of the part of the frame extending to the periphery of the plate preferably has a lip, which allows further avoid the risk of fouling.

De par son élasticité, cette lèvre participe, avec les éléments de maintien flexibles précités, à l'appui du cadre sur le plan de travail.By its elasticity, this lip participates, with the elements of flexible supports mentioned above, in support of the frame on the worktop.

L'élastomère du surmoulage selon l'invention est avantageusement en silicone.The molding elastomer according to the invention is advantageously silicone.

L'invention concerne également une table de cuisson incorporant un ensemble préfabriqué précédemment défini dans les revendications 1 à 12 dont le cadre est fixé à un socle supportant des éléments chauffants, tels que des éléments radiant ou halogène et/ou au moins un brûleur à gaz atmosphérique et/ou au moins un moyen de chauffage par induction.The invention also relates to a hob incorporating a prefabricated assembly previously defined in claims 1 to 12, the frame of which is fixed to a base supporting heating elements, such as radiant elements or halogen and / or at least one burner with atmospheric gas and / or minus a means of induction heating.

L'invention concerne enfin un procédé de fabrication d'un ensemble préfabriqué selon au moins une des revendications 1 à 12. Selon ce procédé, on réalise les étapes suivantes :

  • a) on introduit un cadre moulé dans un poinçon de forme telle qu'on puisse injecter un élastomère à la surface d'au moins une des deux parties du cadre ;
  • b) on place une plaque de cuisson vitrocéramique dans le poinçon en légère surélévation par rapport au cadre moulé ;
  • c) on ferme l'ensemble ainsi constitué au moyen d'une matrice de forme au moins en partie complémentaire au poinçon ;
  • d) on injecte un élastomère dans les canaux formés par l'espace libre entre le poinçon et la matrice ;
  • e) on polymérisé l'élastomère ;
  • f) puis, on éjecte l'ensemble ainsi constitué.
  • Finally, the invention relates to a method for manufacturing a prefabricated assembly according to at least one of claims 1 to 12. According to this method, the following steps are carried out:
  • a) a molded frame is introduced into a punch of such shape that an elastomer can be injected onto the surface of at least one of the two parts of the frame;
  • b) a ceramic hob is placed in the punch slightly raised relative to the molded frame;
  • c) the assembly thus closed is closed by means of a matrix of shape at least partially complementary to the punch;
  • d) an elastomer is injected into the channels formed by the free space between the punch and the die;
  • e) the elastomer is polymerized;
  • f) then the assembly thus ejected.
  • Les avantages procurés par l'invention sont nombreux. Tout d'abord du fait que l'élastomère est injecté puis polymérisé, il n'a plus à être lissé à la main comme cela pouvait être le cas selon l'art antérieur, son état de surface n'est plus pénalisant pour l'aspect décoratif. De même, en injectant l'élastomère sur un cadre déjà mis en forme, il est possible de partir de cadres de formes et/ou couleurs variées. De telles variétés contribuent à conférer un aspect esthétique à la table de cuisson.The advantages provided by the invention are numerous. First of all the fact that the elastomer is injected and then polymerized, it no longer has to be smoothed by hand as could be the case according to the prior art, its state of surface is no longer penalizing for the decorative aspect. Similarly, in injecting the elastomer onto an already shaped frame, it is possible to from frames of various shapes and / or colors. Such varieties help to give an aesthetic appearance to the hob.

    Les formes variées permettent également d'intégrer au cadre des équipements habituellement intégrés à la plaque tels que les organes de commande des éléments de chauffe qui nécessitent, la plupart du temps, un perçage minutieux de la plaque.The various shapes also allow the integration of equipment usually integrated into the plate such as the controls heating elements which most of the time require careful drilling of the plate.

    Pour des raisons de coût de fabrication, le cadre utilisé selon le procédé de l'invention est, de préférence, en matière plastique.For reasons of manufacturing cost, the frame used according to the process of the invention is preferably made of plastic.

    L'élastomère utilisé est, avantageusement, du silicone.The elastomer used is advantageously silicone.

    Selon une caractéristique très avantageuse du procédé, on réalise l'étape e) de polymérisation à haute fréquence.According to a very advantageous characteristic of the process, one realizes step e) of high frequency polymerization.

    Le lait de polymériser l'élastomère selon l'invention par haute fréquence permet aussi un gain de temps considérable à la fabrication. De plus, dans un tel procédé, l'outillage utilisé est de manière usuelle un élastomère. De ce fait, le contact souple entre l'outillage, en particulier le moule, et les différentes parties constituant l'ensemble préfabriqué conforme à l'invention ne risque pas d'altérer les matériaux, notamment la vitrocéramique constituant la plaque de cuisson.The milk to polymerize the elastomer according to the invention by high frequency also saves considerable time during manufacturing. Of more, in such a process, the tool used is usually a elastomer. Therefore, the flexible contact between the tool, in particular the mold, and the different parts making up the prefabricated assembly according to the invention does not risk altering the materials, in particular the glass ceramic constituting the hob.

    Ainsi, en production industrielle, le risque de rebut est diminué.Thus, in industrial production, the risk of scrap is reduced.

    D'autres détails et caractéristiques avantageux ressortiront ci-après à la lecture d'exemples détaillés conformes à l'invention faite en référence aux figures 1 à 2e qui représentent respectivement :

  • figure 1 : une table de cuisson incorporant un premier ensemble préfabriqué conforme à l'invention et placée dans un plan de travail ;
  • figures 2a à 2e : les différentes étapes du procédé de fabrication d'un deuxième ensemble préfabriqué conforme à l'invention.
  • Other details and advantageous characteristics will emerge below on reading detailed examples according to the invention made with reference to FIGS. 1 to 2e which represent respectively:
  • Figure 1 : a hob incorporating a first prefabricated assembly according to the invention and placed in a work surface;
  • Figures 2a to 2e : the different stages of the manufacturing process for a second prefabricated assembly according to the invention.
  • La figure 1 est une vue de section représentant une table de cuisson 1, réalisée conformément à l'invention, intégrée dans un plan de travail 2 d'une cuisine.Figure 1 is a sectional view showing a table of cooking 1, carried out in accordance with the invention, integrated into a plan of work 2 of a kitchen.

    Cette table de cuisson 1 se compose essentiellement d'une plaque de cuisson vitrocéramique 3 et d'un ensemble préfabriqué selon l'invention 4 fixé à un socle métallique 5, de section rectangulaire, au moyen de vis non représentées.This hob 1 essentially consists of a plate of vitroceramic cooking 3 and a prefabricated assembly according to the invention 4 fixed to a metal base 5, of rectangular section, by means of screws not represented.

    Sur ce socle 5 sont fixés, de manière connue en soi, des éléments chauffants non représentés.On this base 5 are fixed, in a manner known per se, elements heaters not shown.

    L'association ensemble préfabriqué selon l'invention avec le socle métallique se substitue donc, au moins du point de vue de la fonction enceinte, à un bâti métallique utilisé selon l'état de l'art. Un cadre en plastique chargé notamment de fibres de verre 6, comme éventuellement les matières plastiques énumérées ci-dessous, constitue l'armature de l'ensemble préfabriqué conforme à l'invention.The association of a prefabricated assembly according to the invention with the base metallic therefore substitutes, at least from the point of view of function enclosure, to a metal frame used according to the state of the art. A frame in plastic loaded in particular with glass fibers 6, as possibly the plastics listed below, constitute the framework for the prefabricated assembly according to the invention.

    Ce cadre 6 comporte essentiellement trois parties, à savoir les flancs verticaux 61, 62, la partie périphérique extérieure 63 qui entoure la plaque de cuisson vitrocéramique 3 en étant directement à son contact et une partie plane 64 qui s'étend sensiblement dans le plan principal de la plaque de cuisson vitrocéramique 3.This frame 6 essentially comprises three parts, namely the sides vertical 61, 62, the outer peripheral portion 63 which surrounds the vitroceramic cooking plate 3 by being directly in contact with it and a flat part 64 which extends substantially in the main plane of the ceramic glass hob 3.

    Cette partie plane 64 comporte des ouvertures dont la fonction sera explicitée ci-après.This flat part 64 has openings whose function will be explained below.

    Sur toute la périphérie du cadre 6 s'étend un profilé en silicone 7. Celui-ci a la forme d'une lèvre 71 pour la partie directement en contact avec la partie supérieure du plan de travail. Cette lèvre 71 a pour fonction d'assurer une interface bien nette entre le cadre 6 et la partie supérieure du plan de travail, c'est-à-dire entre autres, une étanchéité aux liquides et aux aliments susceptibles de venir à proximité.A silicone profile 7 extends over the entire periphery of the frame 6. This has the shape of a lip 71 for the part directly in contact with the upper part of the worktop. This lip 71 has the function ensure a clear interface between frame 6 and the upper part of the work surface, i.e., among other things, a liquid tightness and foods likely to come nearby.

    Qui plus est, la forme incurvée de la lèvre 71 lui confère un aspect esthétique.What is more, the curved shape of the lip 71 gives it an appearance aesthetic.

    Le profilé en silicone 7 présente, dans sa partie verticale, des pattes 72, 73 en contact, d'une part, avec toute la hauteur des flancs verticaux 61, 62 du cadre 6 et, d'autre part, avec toute la hauteur du plan de travail. La nature élastique du silicone permet à ces pattes 72, 73 d'être déformées lors de l'introduction de la table de cuisson dans le plan de travail et donc d'assurer une parfaite immobilisation sans jeu entre ces deux éléments.The silicone profile 7 has, in its vertical part, tabs 72, 73 in contact, on the one hand, with the entire height of the vertical flanks 61, 62 of the frame 6 and, on the other hand, with the entire height of the plane of job. The elastic nature of the silicone allows these tabs 72, 73 to be deformed when the hob is inserted into the hob work and therefore ensure perfect immobilization without play between these two elements.

    Le retrait de la table de cuisson est également très aisé, sans risque de détériorer le cadre 6 et/ou le plan de travail 2.Removing the hob is also very easy, without risk damage frame 6 and / or work surface 2.

    La partie plane 64 du cadre, quant à elle, comporte deux ouvertures circulaires 65 et une ouverture rectangulaire 66.The flat part 64 of the frame, meanwhile, has two openings circular 65 and a rectangular opening 66.

    A travers les deux ouvertures circulaires 65 sont clipsés ou, préférentiellement surmoulés sur le cadre, des boutons de commande en silicone 67 qui permettent, une fois enfoncés, de déclencher le fonctionnement des organes de chauffe non représentés.Through the two circular openings 65 are clipped or, preferably overmolded on the frame, control buttons in silicone 67 which allow, once pressed, to trigger the operation of the heating members not shown.

    En dessous de l'ouverture rectangulaire 66 est disposé un afficheur de type digital qui permet de visualiser l'heure et/ou la durée programmée d'un cycle de chauffe d'au moins un des organes de chauffe. Il peut également indiquer quel est l'organe de chauffe en fonctionnement si la plaque est sous tension électrique, la température de(s) l'organe(s) de chauffe...Below the rectangular opening 66 is arranged a display digital type which allows viewing the programmed time and / or duration a heating cycle of at least one of the heating members. he can also indicate which heater is in operation if the plate is under electric voltage, the temperature of the organ (s) of heated...

    Enfin, sous cette partie plane, en regard des ouvertures décrites, est encapsulé, à l'aide de silicone, un support 68 sur lequel sont gravées des pistes conductrices par lesquelles l'alimentation électrique des différents organes est établie.Finally, under this flat part, opposite the openings described, is encapsulated, using silicone, a support 68 on which are engraved conductive tracks through which the electrical supply of the different organs is established.

    Les figures 2a et 2e représentent les différentes étapes successives du procédé de fabrication d'un deuxième ensemble préfabriqué selon l'invention.Figures 2a and 2e represent the different successive stages the manufacturing process of a second prefabricated assembly according to the invention.

    Selon cette deuxième variante, l'ensemble préfabriqué 4 et la plaque de cuisson vitrocéramique 3 sont liés ensemble par l'intermédiaire d'un joint en silicone 8.According to this second variant, the prefabricated assembly 4 and the plate glass ceramic cooking plates 3 are linked together by means of a silicone seal 8.

    La figure 2a est relative à l'étape initiale de mise en place d'un cadre moulé 6 dans un poinçon 9. Ce cadre moulé 6 est de nature chimique et de forme analogue à celui de la figure 1.Figure 2a relates to the initial stage of setting up a frame molded 6 in a punch 9. This molded frame 6 is of a chemical nature and similar in shape to that of FIG. 1.

    La figure 2b montre la plaque vitrocéramique 3 mise en place dans le poinçon 9, de manière à être en légère surélévation par rapport au cadre 6 et laisse un espace vide 10.Figure 2b shows the glass ceramic plate 3 placed in the punch 9, so as to be slightly raised relative to the frame 6 and leaves an empty space 10.

    Une fois les deux parties précitées mises en place dans le poinçon 9, une matrice 11 est appliquée contre le poinçon 9 et, à certains endroits, contre la plaque 3 et le cadre 6 de telle sorte que des canaux d'injection 12 fermés soient créés, tels que représentés à la figure 2c.Once the two aforementioned parts are in place in punch 9, a die 11 is applied against the punch 9 and, in certain places, against the plate 3 and the frame 6 so that injection channels 12 closed are created, as shown in Figure 2c.

    De la silicone est alors injectée à l'intérieur de ces canaux 12 au moyen d'un dispositif approprié.Silicone is then injected inside these channels 12 at by means of an appropriate device.

    Une fois que les canaux 12 sont complètement remplis de matière silicone (comme il est représenté à la figure 2d), l'injection est arrêtée et on procède à une polymérisation de cette même matière à l'aide d'une technique à haute fréquence pendant un temps de 0,5 à 2 min, en fonction de la masse de silicone à transformer.Once the channels 12 are completely filled with material silicone (as shown in Figure 2d), the injection is stopped and proceeds to a polymerization of this same material using a high frequency technique for a time of 0.5 to 2 min, in depending on the mass of silicone to be transformed.

    La matrice 11 est alors déverrouillée du poinçon 9 et l'éjection de l'ensemble préfabriqué est réalisée, tel que représenté à la figure 2e.The die 11 is then unlocked from the punch 9 and the ejection of the prefabricated assembly is produced, as shown in Figure 2e.

    Un tel procédé présente l'avantage d'être de mise en oeuvre simple et rapide. Il est également avantageux dans la mesure où la production de séries nouvelles avec de nouvelles formes de cadre moulé peut être réalisée aisément sans surcoût productif, la réalisation de nouveaux outillages matrice et/ou poinçon étant aisée.Such a method has the advantage of being simple to implement and fast. It is also advantageous since the production of new series with new molded frame shapes can be easily carried out at no additional production cost, the creation of new die and / or punch tools being easy.

    Il va de soi que de nombreuses modifications peuvent être apportées sans pour autant sortir du cadre de l'invention. Ainsi, toute nouvelle matière plastique du cadre moulé peut convenir dans la mesure où il résiste à des hautes températures, typiquement supérieures à 250°C.It goes without saying that many modifications can be made without departing from the scope of the invention. So brand new plastic of the molded frame may be suitable as long as it withstands high temperatures, typically above 250 ° C.

    Ainsi, par exemple, la matière plastique du cadre conforme à l'invention pourra être choisi parmi le polybutylènetéréphtalate (PBT), le polyphenylène sulfide (PPS), le polyétherétherkétone (PEEK), le polyacrylate (PAR), le polyéthersulfone (PES), le polyétherimide (PEI), le polyamideimlide (PAI), le liquid crystal polymer (LCP), le polytétrafluoréthylène (PTFE), le polyétheréthersulfone (PEES), les polyépoxydes (EP) et, éventuellement, le polysulfone (PSF), les fluoropolymères résines (FEP comme par exemple PTEFE, PFA, ETFE, etc.), le polythioéthersulfone (PTES), le thermoplastique poyimide (TPI), le cross linked polyimide (CLPI), le polyéthercétone (PEK), le polyéthermitrile (PEN), le polycyclohexylènetéréphtalate (PCT), le polyphtalamide (PPA).So, for example, the plastic of the frame conforms to the invention may be chosen from polybutyleneterephthalate (PBT), polyphenylene sulfide (PPS), polyetheretherketone (PEEK), polyacrylate (PAR), polyethersulfone (PES), polyetherimide (PEI), polyamideimlide (PAI), liquid crystal polymer (LCP), polytetrafluoroethylene (PTFE), polyetherethersulfone (PEES), polyepoxides (EP) and, optionally, polysulfone (PSF), fluoropolymer resins (FEP such as for example PTEFE, PFA, ETFE, etc.), polythioethersulfone (PTES), thermoplastic poyimide (TPI), cross linked polyimide (CLPI), polyetherketone (PEK), polyethermitrile (PEN), polycyclohexyleneterephthalate (PCT), polyphthalamide (PPA).

    Pour des raisons de coût de matière, le cadre pourra être choisi avantageusement parmi les résines polyester (UP).For reasons of material cost, the frame may be chosen advantageously among polyester resins (UP).

    De même, tout autre profilé équivalent pouvant être injecté conformément à l'invention, est compris dans le cadre de l'invention à la condition que les caractéristiques analogues à la silicone telles que l'élasticité et la résistance à haute température soient remplies.Similarly, any other equivalent profile that can be injected in accordance with the invention, is included within the scope of the invention in the provided that silicone-like features such as elasticity and high temperature resistance are fulfilled.

    Les élastomères, respectivement commercialisés sous la dénomination VITON et KALREZ par la société DUPONT DE NEMOURS, conviennent ainsi parfaitement.The elastomers, respectively marketed under the denomination VITON and KALREZ by the company DUPONT DE NEMOURS, thus fit perfectly.

    De même, les élastomères commercialisés sous les dénominations commerciales FLUOREL et CHEMRAZ, respectivement par les sociétés 3M et GREEN TWIN, sont parfaitement adaptés.Similarly, the elastomers marketed under the names FLUOREL and CHEMRAZ, respectively by 3M companies and GREEN TWIN, are perfectly suited.

    Claims (17)

    1. Prefabricated assembly (4), intended for producing a hob, comprising a glass-ceramic hotplate (3) and a frame (6) comprising a part extending at the periphery of the plate (63) and another part extending in a plane substantially vertical to the plate (61, 62), characterised in that at least one of the two parts (61, 62) of the frame comprises an elastomer overmoulding (7, 8), this overmoulding comprising lugs (72, 73) able to immobilise the frame in the work surface.
    2. Assembly according to Claim 1, characterised in that the frame is made from plastics material.
    3. Assembly according to Claim 1 or 2, characterised in that the frame is moulded.
    4. Assembly according to one of Claims 2 or 3, characterised in that the frame is made from polymer resin resistant to temperatures of at least 180°C.
    5. Assembly according to one of Claims 1 to 4, characterised in that the plastic frame is directly moulded onto the glass-ceramic hotplate.
    6. Assembly according to one of Claims 1 to 4, characterised in that the frame and glass-ceramic hotplate are connected together by an elastomer seal, of the silicone type (8).
    7. Assembly according to one of the preceding claims, characterised in that the frame comprises through holes, through which elastomer knobs (67, 68) are moulded on.
    8. Assembly according to any one of the preceding claims, characterised in that the overmoulding is a profiled member (72, 73).
    9. Assembly according to Claim 8, characterised in that each of the two parts of the frame comprises an elastomer profiled member.
    10. Assembly according to Claim 8 or Claim 9, characterised in that the lugs on the elastomer profiled member have indentations.
    11. Assembly according to Claim 8 or Claim 9, characterised in that the elastomer profiled member of the part of the frame extending at the periphery of the plate comprises a lip (71).
    12. Assembly according to any one of the preceding claims, characterised in that the elastomer of the overmoulding is made from silicone.
    13. Hob incorporating a prefabricated assembly according to one of Claims 1 to 12, the frame of which is fixed to a base supporting heating elements, such as radiant or halogen elements and/or at least one atmospheric gas burner and/or at least one means of heating by induction.
    14. Method of manufacturing a prefabricated assembly (4), intended for producing a hob according to at least one of Claims 1 to 12, comprising a glass-ceramic hotplate (3) and a frame (6) formed from a part extending at the periphery of the plate and another part extending in a plane substantially vertical to the plate (61, 62), characterised in that the following steps are performed:
      a) a moulded frame (6) is introduced into a punch (9) with a shape such that it is possible to inject an elastomer on the surface of at least one of the two parts of the frame and so that the elastomer injected forms lugs (72, 73) able to immobilise the frame in the work surface;
      b) a glass-ceramic hotplate is placed in the punch slightly raised with respect to the moulded frame;
      c) the assembly thus formed is closed by means of a die (11) with a shape at least partly complementary to the punch;
      d) an elastomer is injected into the channels (12) formed by the free space between the punch and the die;
      e) the elastomer is polymerised;
      f) then the assembly thus formed is ejected.
    15. Method according to Claim 14, characterised in that the frame is made from plastics material.
    16. Method according to Claim 14 or Claim 15, characterised in that the elastomer is silicone.
    17. Method according to Claim 15 or Claim 16, characterised in that the polymerisation step e) is carried out at high frequency.
    EP99943030A 1998-09-23 1999-09-23 Prefabricated set for making a cooking surface Expired - Lifetime EP1032792B1 (en)

    Applications Claiming Priority (3)

    Application Number Priority Date Filing Date Title
    FR9811841A FR2783596B1 (en) 1998-09-23 1998-09-23 PREFABRICATED ASSEMBLY FOR MAKING COOKING TABLES
    FR9811841 1998-09-23
    PCT/FR1999/002259 WO2000017579A1 (en) 1998-09-23 1999-09-23 Prefabricated set for making a cooking surface

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    EP1032792A1 EP1032792A1 (en) 2000-09-06
    EP1032792B1 true EP1032792B1 (en) 2004-06-23

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    EP (1) EP1032792B1 (en)
    JP (1) JP3808704B2 (en)
    AU (1) AU5631999A (en)
    DE (1) DE69918257T2 (en)
    ES (1) ES2222723T3 (en)
    FR (1) FR2783596B1 (en)
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    JP2002525549A (en) 2002-08-13
    US6492623B1 (en) 2002-12-10
    FR2783596B1 (en) 2001-03-09
    AU5631999A (en) 2000-04-10
    DE69918257D1 (en) 2004-07-29
    JP3808704B2 (en) 2006-08-16
    FR2783596A1 (en) 2000-03-24
    EP1032792A1 (en) 2000-09-06
    WO2000017579A1 (en) 2000-03-30
    ES2222723T3 (en) 2005-02-01
    DE69918257T2 (en) 2005-07-14

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