EP0996752B1 - Alloy for corrosion-resistant coatings or surface coatings - Google Patents
Alloy for corrosion-resistant coatings or surface coatings Download PDFInfo
- Publication number
- EP0996752B1 EP0996752B1 EP98929635A EP98929635A EP0996752B1 EP 0996752 B1 EP0996752 B1 EP 0996752B1 EP 98929635 A EP98929635 A EP 98929635A EP 98929635 A EP98929635 A EP 98929635A EP 0996752 B1 EP0996752 B1 EP 0996752B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- metal
- alloy
- yttrium
- main group
- cobalt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/07—Alloys based on nickel or cobalt based on cobalt
Definitions
- the present invention relates to an alloy for anti-corrosive coatings or surface coatings which are resistant up to 1100°C.
- Such surface coatings can be obtained by the following thermal spraying methods:
- Said alloy is resistant to corrosion and guarantees a service life of 1000 hours if used for the coating of components which operate in the presence of sodium-, vanadium-, sulphur- and chlorine-containing hydrocarbon combustion products.
- a first disadvantage is that this alloy does not guarantee sufficient corrosion resistance if employed at temperatures above 700°C.
- Said second alloy is used for coating components with a superalloy material.
- the presence of silicon in the coating matrix provides resistance against the formation of oxides and sulphides on the surface layer.
- this second alloy has a low yttrium content, which is insufficient for ensuring corrosion resistance in the presence of products containing substantial amounts of sulphur, chlorine and vanadium.
- a third alloy is known from US 4,585,481, which describes an alloy based on cobalt and containing chromium, aluminium, yttrium and silicon in the following proportions: Chromium (Cr) 5.0 - 40.0% Aluminium (Al) 8.0 - 35.0% Yttrium (Y) 0.1 - 2.0% Silicon (Si) 0.1 - 7.0% Cobalt (Co) remaining percentage.
- this alloy results in a reduction of the plasticity of the coating, making it impossible to use it for the coating of apparatuses or objects which must withstand substantial changes in temperature.
- a further disadvantage is that, during application of the coating or surface coating by the plasma method, oxidation of yttrium and silicon may take place.
- This third alloy is unable to guarantee the corrosion resistance required in the presence of combustion products containing substantial amounts of sulphur, chlorine and vanadium.
- the alloys mentioned above can usually be used at temperatures not exceeding 900°C. since all of them are based on cobalt.
- RU-A-2051196 teaches an alloy for corrosion-resistant coatings or surface coatings, containing of cobalt, chromium, aluminium, yttrium, silicon, and a metal from the second main group, together with the corresponding oxide, in the following proportions: Chromium (Cr) 26.0 - 30.0% Aluminium (Al) 6.0 - 8.0% Yttrium (Y) 0.3 - 1.5% Silicon (Si) 1.5 - 4.5% Metal from the second main group (magnesium, calcium, barium, strontium) 0.1 - 0.5% Oxide of the corresponding metal from the second main group 0.1 - 1.0% Cobalt (Co) remaining percentage.
- This alloy resists only up to 800°C.
- the object of the present invention is to eliminate the abovementioned disadvantages and provide an alloy with excellent performance even at high temperatures, in particular even above 1000°C.
- alloy for corrosion-resistant coatings or surface coatings and which is characterized by the composition defined in claim 1, with preferred embodiments in claims 2 and 3.
- the Applicant has realized that the disadvantages of the known alloys based on cobalt and containing chromium, aluminium, yttrium and silicon can be avoided by adding one the metals from the second main group (magnesium, calcium, barium, strontium), both in free form and in the form of the oxide.
- the alloy according to the present invention is an alloy for anti-corrosive surface coatings which is based on cobalt and contains chromium, aluminium, yttrium, silicon, and a metal from the second main group, together with the. corresponding oxide, in the following proportions: Chromium (Cr) 22.0 - 31.0% Aluminium (Al) 5.5 -13.0% Yttrium (Y) 0.3 - 1.5% Silicon (Si) 1.5 - 10.0% Metal from the second main group (Mg, Ca, Ba, Sr) 0.1 - 2.0% Oxide of the corresponding metal (Mg, Ca, Ba, Sr) from the second main group 0.1 - 2.0% Tantalum (Ta) 0.5 - 4.0% Me remaining percentage where Me denotes a metal which can be nickel (Ni) or iron (Fe) or cobalt (Co) or a composition consisting of Ni-Fe-Co, Ni-Fe, Fe-Co, NI-Co.
- rhenium (Re) is envisaged as being present in a percentage of 2.0 - 11.0.
- yttrium (Y) by an yttrium/hafnium (Y/Hf) composition having the same percentage (0.3 -1.5%), relative to the total of the components, achieves better adhesion of the alumina, Al 2 O 3 , to the surface of the coating.
- the combination of silicon with the metal from the second main group and its oxide makes it possible to maintain the operational capacity of the surface coating obtained when applied by plasma spraying in air or by high-velocity flame spraying.
- the presence of the metal from the second main group (Mg, Ca, Ba, Sr) in the proportions mentioned prevents the yttrium and silicon from being oxidized during application of the coating or surface coating.
- a lower content of silicon, of the metal from the second main group and its oxide in the alloy based on nickel, iron and cobalt according to the present invention does not increase the corrosion resistance of the coating.
- a higher content of silicon, yttrium, metal from the second main group and its oxide in the alloy according to the present invention produces a deterioration in the mechanical characteristics of the coating obtained, increases the fragility, reduces the coefficient of thermal expansion, and thus causes the coating to form cracks and to flake and therefore lowers the protection with respect to corrosion caused by sulpho-oxidation.
- the addition of tantalum and/or rhenium furthermore results in a significantly improved performance at oxidation temperature levels above temperatures of 1000°C.
Abstract
Description
Chromium | (Cr) | 8.0 - 30.0% |
Aluminium | (Al) | 5.0 - 15.0% |
Yttrium | (Y) | 0 - 1.0% |
Cobalt | (Co) | remaining percentage |
Chromium | (Cr) | 12.5 - 20.0% |
Aluminium | (Al) | 2.0 - 8.0% |
Yttrium | (Y) | 0- 0.25% |
Silicon | (Si) | 2.0 - 6.0% |
Cobalt | (Co) | remaining percentage |
Chromium | (Cr) | 5.0 - 40.0% |
Aluminium | (Al) | 8.0 - 35.0% |
Yttrium | (Y) | 0.1 - 2.0% |
Silicon | (Si) | 0.1 - 7.0% |
Cobalt | (Co) | remaining percentage. |
Chromium | (Cr) | 26.0 - 30.0% |
Aluminium | (Al) | 6.0 - 8.0% |
Yttrium | (Y) | 0.3 - 1.5% |
Silicon | (Si) | 1.5 - 4.5% |
Metal from the second main group (magnesium, calcium, barium, strontium) | 0.1 - 0.5% | |
Oxide of the corresponding metal from the second main group | 0.1 - 1.0% | |
Cobalt | (Co) | remaining percentage. |
Chromium | (Cr) | 22.0 - 31.0% |
Aluminium | (Al) | 5.5 -13.0% |
Yttrium | (Y) | 0.3 - 1.5% |
Silicon | (Si) | 1.5 - 10.0% |
Metal from the second main group (Mg, Ca, Ba, Sr) | 0.1 - 2.0% | |
Oxide of the corresponding metal (Mg, Ca, Ba, Sr) from the second main group | 0.1 - 2.0% | |
Tantalum | (Ta) | 0.5 - 4.0% |
Me | remaining percentage |
Claims (3)
- Alloy for corrosion-resistant coatings or surface coatings, comprising chromium, aluminium, yttrium, hafnium, silicon, and a metal from the second main group, together with the corresponding oxide, tantalum (if necessary) and one or more metals from Ni, Fe and Co, in the following proportions in weight:
Chromium (Cr) 22.0 - 31.0% Aluminium (Al) 5.5 - 13.0% Yttrium+Hafnium composition (Y+Hf) 0.3 - 1.5% Silicon (Si) 1.5 - 10.0% Metal from the second main group Mg, Ca, Ba, Sr 0.1 - 2.0% Oxide of the corresponding metal Mg, Ca, Ba, Sr from the second main group 0.1 - 2.0% with the addition of Tantalum (Ta) 0.5 - 4.0% and/or Rhenium (Re) 2.0 - 11.0% Me remaining percentage in weight - Alloy according to Claim 1, wherein the alloy can be applied through plasma spraying in air (APS) or in vacuum (VPS).
- Protective anticorrosive coating, characterized in that it is prepared by using an alloy according to any one of the preceding claims.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITPR970039 | 1997-07-10 | ||
IT97PR000039A IT1294098B1 (en) | 1997-07-10 | 1997-07-10 | CORROSION RESISTANT ALLOY OR COATINGS. |
PCT/IT1998/000167 WO1999002745A1 (en) | 1997-07-10 | 1998-06-19 | Alloy for corrosion-resistant coatings or surface coatings |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0996752A1 EP0996752A1 (en) | 2000-05-03 |
EP0996752B1 true EP0996752B1 (en) | 2002-05-02 |
Family
ID=11396108
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98929635A Expired - Lifetime EP0996752B1 (en) | 1997-07-10 | 1998-06-19 | Alloy for corrosion-resistant coatings or surface coatings |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0996752B1 (en) |
AT (1) | ATE217032T1 (en) |
DE (1) | DE69805179T2 (en) |
IT (1) | IT1294098B1 (en) |
WO (1) | WO1999002745A1 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19926669A1 (en) * | 1999-06-08 | 2000-12-14 | Abb Alstom Power Ch Ag | Coating containing NiAl beta phase |
US6346134B1 (en) * | 2000-03-27 | 2002-02-12 | Sulzer Metco (Us) Inc. | Superalloy HVOF powders with improved high temperature oxidation, corrosion and creep resistance |
JP4166977B2 (en) * | 2001-12-17 | 2008-10-15 | 三菱重工業株式会社 | High temperature corrosion resistant alloy material, thermal barrier coating material, turbine member, and gas turbine |
AU2003200835A1 (en) | 2002-01-18 | 2003-07-30 | Alstom Technology Ltd | High-temperature protective coating |
DE502005010521D1 (en) * | 2005-11-24 | 2010-12-23 | Siemens Ag | Alloy, protective layer and component |
KR101753094B1 (en) * | 2015-08-25 | 2017-07-04 | 한국기계연구원 | Co-Cr BASED DENTAL ALLOY WITH EXCELLENT MACHINABILITY, OXIDATION RESISTANCE AND AESTHETICS |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4585481A (en) * | 1981-08-05 | 1986-04-29 | United Technologies Corporation | Overlays coating for superalloys |
DE3246504A1 (en) * | 1982-12-16 | 1984-06-20 | BBC Aktiengesellschaft Brown, Boveri & Cie., Baden, Aargau | HIGH TEMPERATURE PROTECTIVE LAYER |
DE3842300A1 (en) * | 1988-12-16 | 1990-06-21 | Asea Brown Boveri | Protective high-temperature layer |
RU2051196C1 (en) * | 1993-11-26 | 1995-12-27 | Совместное Российско-Итальянское предприятие "Интеркоут Турбинсервис" | Cobalt-based alloy |
DE59505454D1 (en) * | 1994-10-14 | 1999-04-29 | Siemens Ag | PROTECTIVE LAYER FOR PROTECTING A COMPONENT AGAINST CORROSION, OXIDATION AND THERMAL OVERLOAD AND METHOD FOR THEIR PRODUCTION |
-
1997
- 1997-07-10 IT IT97PR000039A patent/IT1294098B1/en active IP Right Grant
-
1998
- 1998-06-19 EP EP98929635A patent/EP0996752B1/en not_active Expired - Lifetime
- 1998-06-19 AT AT98929635T patent/ATE217032T1/en not_active IP Right Cessation
- 1998-06-19 DE DE69805179T patent/DE69805179T2/en not_active Expired - Lifetime
- 1998-06-19 WO PCT/IT1998/000167 patent/WO1999002745A1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
ATE217032T1 (en) | 2002-05-15 |
WO1999002745A1 (en) | 1999-01-21 |
EP0996752A1 (en) | 2000-05-03 |
ITPR970039A0 (en) | 1997-07-10 |
DE69805179T2 (en) | 2002-11-14 |
ITPR970039A1 (en) | 1999-01-10 |
DE69805179D1 (en) | 2002-06-06 |
IT1294098B1 (en) | 1999-03-22 |
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