EP0968702A1 - Composition pulvérulente moussante solide à hydratrer pour le soin ou le nettoyage de la peau - Google Patents
Composition pulvérulente moussante solide à hydratrer pour le soin ou le nettoyage de la peau Download PDFInfo
- Publication number
- EP0968702A1 EP0968702A1 EP99401135A EP99401135A EP0968702A1 EP 0968702 A1 EP0968702 A1 EP 0968702A1 EP 99401135 A EP99401135 A EP 99401135A EP 99401135 A EP99401135 A EP 99401135A EP 0968702 A1 EP0968702 A1 EP 0968702A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- composition according
- skin
- binder
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/90—Block copolymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/0279—Porous; Hollow
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
Definitions
- the present invention relates to a foaming powder composition for deep cleaning and / or skin care with a deformable solid.
- This composition can be applied to both face than on the human body and is very soft. This dry feel composition should be hydrated before use.
- the invention also relates to a cosmetic process for cleaning and / or skin care, as well as a process for manufacturing the composition powdery.
- Skin cleansing compositions are usually available under in the form of solid breads like soaps or in the form of liquids more or less viscous.
- soap To clean themselves with soap, consumers generally use the whole soap. This soap tends to soften as it uses, due to its contact with water, and to age badly. In addition, it is frequent breakage and consumers end up with small hard to use soap scraps. In addition, wet soap is generally slippery, which makes it difficult to use, especially for young children. As a result, it has become common to use liquid cleaners instead of soaps. Unfortunately, the more liquid the compositions, the more difficult it is to dose them, especially because they tend to escape between the fingers, the more they tend to escape from their conditioning, which can be very annoying when they come into contact with clothing, when moving.
- cleaning masks for cleaning in face depth.
- These masks are generally in the form of gel or cream to be applied as a thin layer to the skin, containing powders able to absorb fatty substances produced by the skin such as sebum.
- These masks may optionally contain cosmetic active ingredients or dermatological of the skin to perfect the cleaning and / or bring good to be skinned.
- Such masks are described in particular in the documents US-A-5,690,945 and WO-A-86/05394. These masks are often heavy to wear, uncomfortable (tightness) and cleaning is not always felt as effective. In addition, these masks are difficult to rinse.
- the subject of the present invention is precisely a new composition for the cleansing and / or skin care, in particular to remedy disadvantages mentioned above.
- This composition is a composition foaming, easy to apply, very light and very softness, giving a well-being effect after application. It also has the advantage of rinsing remarkably and presenting a texture quite unusual fact.
- the invention relates to a foaming powder composition with moisturize for cleaning and / or skin care, containing a binder cosmetically acceptable, and a pulverulent filler insoluble in this binder and in sufficient quantity to structure said composition and give it a aspect of deformable solid in which the binder is trapped, the filler pulverulent comprising solid particles of thermoplastic polymer and at least one surfactant in powder form, said composition being capable of lather during hydration.
- This composition is intended more specifically for cleaning and / or caring for the face of a human being. It is in the form of a deformable solid or malleable, dry, non-staining and marshmallow-like (see document US-A-3,682,659 for the consistency of marshmallow). This solid can be shaped like children's play dough. It can be broken easily by hand in order to withdraw only the necessary quantity of product.
- this composition can be packaged in the form of monodose, particularly advantageous from a hygienic point of view, and by example in the form of small cubes, marbles or berlingots.
- the composition of the invention does not risk escape from its packaging, especially during transport.
- this composition is very easy to grip and does not flow between the fingers; its dosage is much simpler than that of cleaners usual liquids and the problem of wear of hard soaps does not arise.
- its application is easy, light and pleasant.
- its storage does not no problem and its pollution by the environment and / or handling by the consumer is relatively small and in any event very lower than those of comparable products of the prior art. In particular, it it is not necessary to introduce a preservative to ensure its protection antimicrobial.
- the particles of the invention it is in particular possible to obtain a homogeneous structure (deformable solid) for constituents leading normally with two distinct phases (immiscible components for example oil / water).
- the texturing agent of the invention has the particularity of being easily removed of the skin by simple dilution. It actually plays the role of vehicle or tank for the cosmetic binder. It also makes it possible to recover the binder and in particular the asset (s), trapped in the deformable solid, when necessary by simple dilution with water. This is probably due to the fact that the support cosmetic is housed in the interparticle spaces of the solid and not in the particles.
- particles with a particle size of 1 ⁇ m to 300 ⁇ m for example 5 ⁇ m at 200 ⁇ m and preferably from 10 ⁇ m to 100 ⁇ m and better still from 15 ⁇ m to 40 ⁇ m.
- particles are advantageously used hollow filled with a gas.
- This gas can be air, nitrogen, isobutane, isopentane, etc.
- the particles are in the form of beads. It is however possible to use particles having the form of fibers.
- These particles can be made of different inert materials which not chemically reacting with the cosmetically acceptable binder; in especially these particles do not react with oils, surfactants, water and the various other constituents of the composition, such as the active ingredients.
- the powder of the invention imparting the texture of a deformable solid, has the particularity of disintegrating easily by simple dilution in a solvent such as water possibly loaded with salts or trace elements.
- the inert particles are advantageously made of materials thermoplastics such as polyamides such as nylon, polymers or copolymers of acrylonitrile, vinylidene chloride, vinyl chloride and / or of acrylic or styrenic monomer, optionally expanded.
- the monomer acrylic is for example a methyl or ethyl acrylate or methacrylate.
- the styrenic monomer is for example ⁇ -methyl-styrene or styrene.
- nylon particles it is possible to use the "Orgasol" particles sold by the company Atochem. These particles are solid, porous spheres of diameter ranging from 5 ⁇ m to 60 ⁇ m.
- the particles are deformable hollow particles of expanded copolymer of vinylidene chloride and acrylonitrile or chloride vinylidene, acrylonitrile and methacrylate.
- a copolymer containing from 0% to 60% of units derived from chloride of vinylidene, from 20% to 90% of units derived from acrylonitrile and from 0% to 50% of units derived from an acrylic or styrenic monomer, the sum of percentages (by weight) being equal to 100.
- These hollow particles may for example be those formed from a terpolymer of vinylidene chloride, acrylonitrile and methacrylate, sold under the brand Expancel by the company Nobel Casco under the references 551 DE 12 (particle size of approximately 12 ⁇ m and mass density 40 kg / m 3 ), 551 DE 20 (particle size of approximately 30 ⁇ m and density 65 kg / m 3 ), 551 DE 50 (particle size of approximately 40 ⁇ m).
- hollow polymeric particles which can be used in the invention, may also mention the polymers and copolymers obtained from esters or acids, itaconic, citraconic, maleic, fumaric, acetate or lactate vinyl (see JP-A-2-112304 for this purpose), or even particles of unexpanded copolymer of vinylidene chloride and acrylonitrile or vinylidene chloride, acrylonitrile and methacrylate, sold under the Expancel brand with reference 551 WU.
- the particles of corn starch, fumed silica, polyethylene, polyurethane or unexpanded polyester do not allow to obtain a solid composition which removes well from the skin during rinsing.
- CPVC critical pigment charge volume
- the structuring powdery charge represents up to 80% in volume of the composition, 60% of which advantageously represents particles with a density less than 1.
- the binder represents up to 20% by volume of the composition.
- particles with a density less than 1 represents from 2 to 20% and better still from 3 to 7% of the total weight of the composition.
- Another subject of the invention is the cosmetic use of the defined composition. previously for cleaning and / or caring for human skin.
- the subject of the invention is also a cosmetic process for cleaning and / or skin care, consisting in hydrating a composition as defined above, lather, apply it to the skin, and finally rinse the skin.
- composition of the invention contains, in addition to the polymer particles, a surfactant in powder form, in an effective amount during hydration of composition.
- a surfactant in powder form, in an effective amount during hydration of composition.
- This type of agent has the particularity of reacting chemically with water and the structuring agent to form a foam easily applied to the skin.
- composition according to the invention can advantageously contain one or more cleaning and / or foaming surfactants in powder form, which can be nonionic, anionic, cationic and / or amphoteric surfactants. They can be used in an amount ranging for example from 10% to 80% of the total weight of the composition, and preferably from 30% to 60%.
- the surfactant (s) in powder form have a particle size ranging from 5 to 50 ⁇ m and better still from 10 to 20 ⁇ m.
- composition of the invention can advantageously contain, in addition, one or several liquid surfactants which can represent from 20 to 88% of the total weight of the composition and better from 33 to 67%. These liquid surfactants are part of the binder and may even constitute the entire binder.
- nonionic surfactants which can be used in the invention, mention may be made of: example condensates of alkylene oxides and alkyl phenols such as octyl ethoxylated phenol such as that sold under the name Triton X45 by the company Rohm and Hass being in an anhydrous puverulent form, the oxide condensates ethylene, propylene oxide and ethylene diamine, the alkylpolyglucosides, ethers of fatty alcohol and polyols such as for example Polyglyceryl-3 hydroxylauryl Ether (CTFA name) sold under the name Chimexane NF by the Chimex Company.
- CTFA name Polyglyceryl-3 hydroxylauryl Ether
- anionic surfactants there may be mentioned, for example, polyalkylenes alcohol ether glycols, taurates, acyl lactylates such as stearoyl sodium lactylate (for example Pationic SSL, powdery surfactant sold by Maprecos), alkyl sulfates such as sodium lauryl sulfate (Sipon LCS, powdery surfactant sold by the company Henkel), alkyl sulfates polyoxyethylenated, alkyl ether sulfates such as lauryl ether sulfate monoethanolamine, in particular that sold at 28% in water by the company Henkel (Sipon LEM 235), alkyl ethers carboxylates, monoalkyl or dialkyl phosphates such as monohexyl-2-decyl phosphate of argine (C6C10 MAP-1-ARG, powder sold by the company Kao Chemicals), alkyl phosphate ethoxylated, N
- Nikkol Sarcosinate MN powder sold by the company Nikko
- N-acyl glutamates such as sodium lauroyl glutamate (by example Amisoft LS11, powder sold by Ajinomoto)
- acyl isethionates such as sodium cocoyl isethionate (sold in particular by Rhône-Poulenc (Gerapon AC78) or the powder sold by the company Jordan (Jordapon Cl)
- polysorbates succinamates, soaps like laurate, myristate, palmitate or potassium stearate, mixtures thereof.
- amphoteric surfactants or zwitterions mention may be made, for example, of betaines and derivatives of betaines, sultaines and derivatives of sultaines, imidazolinium derivatives, such as disodium cocoamphodiacetate (Miranol C2M concentrate sold by Rhone-Poulenc).
- cationic surfactants which can be used in the invention, mention may be made of: pyrrolidone carboxylate derivatives such as PCA ethyl cocoyl arginate (Cation CAE, powder sold by Ajinomoto).
- composition according to the invention can, in addition, contain oils which can be used in an amount ranging from 0% to 30% by weight, and preferably from 0% to 10% of the total weight of the composition. Oils are an integral part of binder.
- oils which can be used in the compositions according to the invention can be chosen from mineral oils such as paraffin oil and petroleum jelly; oils of animal origin such as perhydrosqualene; the oils of vegetable origin such as sweet almond, avocado, castor oil, olive oil, jojoba, sesame, peanut, grape seed, rapeseed, copra, hazelnuts, palm, apricot kernel, calophyllum, rice bran, corn germ, wheat germ, soybean, sunflower, safflower, passionflower, rye and shea butter and its liquid fraction; oils from synthesis such as fatty esters such as butyl myristate or isopropyl, hexadecyl, isopropyl, octyl or isodecyl stearate, decyl oleate, hexyl laurate, propylene glycol dicaprylate, lanolic acid esters such as isopropyl lanolate and lanolate isocetyl
- the composition may, in addition, contain one or more other ingredients conventionally used in cleaning and / or care compositions.
- These ingredients are filters, fragrances, preservatives, antioxidants, pH regulating agents, sequestrants, fillers, dyes, cosmetic or dermatological active ingredients.
- These adjuvants are used in usual proportions of cleaning compositions, for example from 0.01 to 10% of the total weight of the composition. These adjuvants must be of a nature and used in such quantities that they do not disturb the desired properties for the composition of the invention.
- active agents which can be used in the invention, there may be mentioned antibacterials like octopirox and triclosan, keratolytic agents like acid salicylic, essential oils, vitamins.
- composition according to the invention can be prepared by any known means of those skilled in the art, and in particular by simply mixing the different components and molding in a suitable mold. However, so advantageous, it is prepared by mixing followed by kneading and then extrusion in an extruder, preferably a twin-screw extruder such as those described in documents EP-A-605284 and FR-A-2,715,306, and in which the two screws rotate in the same direction. You can also use the process described in document EP-A-651991.
- the various constituents of the composition are introduced, at the entry of the twin-screw extruder, in the supply area at room temperature, preferably around 20 ° C.
- the solid constituents are introduced in head of the extruder then the liquid constituents are introduced laterally.
- the everything is mixed in various areas of the extruder, kept at a temperature ranging, preferably, from 15 to 25 ° C; the mass obtained is transported to the extruder outlet and extruded through a die.
- the screw rotation speed is around 400 to 1000 rpm, preferably between 550 and 650 revolutions / minute.
- the extruded mass leaves the die in the form of tubes of given diameter depending on the sector used, which can then be cut and shaped, in particular, in the form of a stick or solid bread.
- Other forms may of course be carried out by choosing appropriate channels and end product shaping devices, adapted to the desired shape.
- the invention also relates to a method of manufacturing a powder composition for cleaning and / or caring for the skin, containing a cosmetically acceptable binder, and a powdery filler insoluble in this binder and in sufficient quantity to structure said composition and give it an aspect of deformable solid in which the binder is trapped, the filler pulverulent comprising solid particles of thermoplastic polymer and at least one surfactant in powder form, said composition being capable of foam during hydration, consisting in introducing into a blender extruder, preferably cold, the binder then the filler, then to shape the composition from the extruder mixer in a desired shape die.
- the extruded mass can also be dehydrated and / or ground and / or compacted. Dehydration is advantageously used when the ingredients of the composition are introduced in the form of a solution or dispersion in an aqueous medium.
- heat-sensitive ingredients can be introduced into any area of the extruder (head, middle or end) since no deterioration due to heat is to be feared. This is in particularly advantageous for the introduction of structuring agents of the type Expancel.
- Example 1 Powdered foaming mask for oily skin with tendency acne
- the procedure consists of cold introduction of the surfactants at the top extruder, then to introduce laterally into the different stages of the twin-screw extruder, the active ingredients, the preservatives, the perfume and, ultimately, the Expancel.
- the mixture is cold extruded until a homogeneous paste is obtained, which is then shaped in an appropriate die to obtain a sausage that we cut into sticks.
- the mask obtained is a white paste, not sticky, easily moldable, easily wettable or hydratable, easy to apply and remove, gentle to the touch and having good foaming power.
- This mask can then be hydrated, then kneaded until it foams especially in the palm of your hand.
- the foam obtained is then applied in thin layer on the skin of the face.
- the amount of water can represent from 6 to 10 times the volume of the sample taken for cleaning.
- Example 2 The procedure is the same as for Example 1 and a paste is obtained having similar properties.
- Example 2 The procedure is the same as for Example 1 and a paste is obtained having similar properties.
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Abstract
Description
- ajout de particules déterminées dans de l'eau contenant un colorant classiquement utilisé dans le domaine nettoyant tel que le sel disodique de bleu brillant FCF codifié dans le Color Index sous la référence Cl 42090, jusqu'à l'obtention d'une pâte colorée,
- versement d'une goutte d'eau sur la pâte.
- Cocoyl iséthionate de sodium (Jordapon Cl vendu par la société Jordan) (tensioactif anionique sous forme pulvérulente) 42,5 %
- Lauryl éther sulfate de monoéthanolamine vendu à 28 % dans l'eau par la société Henkel (Sipon LEM 235) 51 %
- Conservateur qs
- Octopirox 0,1 %
- Parfum qs
- Acide salicylique 0,5 %
- Expancel 551 DE 20 5,5 %
- Cocoyl iséthionate de sodium (Jordapon Cl vendu par la société Jordan) (tensioactif anionique sous forme pulvérulente) 40 %
- Expancel 551 DE 20 6 %
- Lauryl éther sulfate de monoéthanolamine vendu à 28 % dans l'eau par la société Henkel (Sipon LEM 235) 54 %
- Cocoyl iséthionate de sodium (Jordapon Cl vendu par la société Jordan) (tensioactif anionique sous forme pulvérulente) 35 %
- Lauryl éther sulfate de monoéthanolamine vendu à 28 % dans l'eau par la société Henkel (Sipon LEM 235) 60 %
- Huile d'amande douce 1 %
- Microsphères EL 23 5 %
Claims (21)
- Composition moussante pulvérulente à hydrater pour le nettoyage et/ou le soin de la peau, contenant un liant cosmétiquement acceptable et une charge pulvérulente insoluble dans ce liant et en quantité suffisante pour structurer ladite composition et lui conférer un aspect de solide déformable dans lequel le liant est emprisonné, la charge pulvérulente comprenant des particules solides de polymère thermoplastique et au moins un tensioactif sous forme pulvérulente, la dite composition étant apte à mousser lors de son hydratation.
- Composition selon la revendication 1, caractérisée en ce que les particules de polymère ont une granulométrie de 1 µm à 300 µm.
- Composition selon la revendication 1 ou 2, caractérisée en ce que les particules de polymère ont une granulométrie de 10 µm à 100 µm.
- Composition selon l'une des revendications précédentes, caractérisée en ce que les particules de polymère ont une densité inférieure à 0,09.
- Composition selon l'une des revendications précédentes, caractérisée en ce que les particules de polymère ont une densité inférieure à 0,04.
- Composition selon l'une des revendications précédentes, caractérisée en ce que la charge est présente en une concentration au moins égale à la charge pigmentaire volumique critique.
- Composition selon l'une des revendications précédentes, caractérisée en ce que les particules de polymère sont creuses.
- Composition selon l'une des revendications précédentes, caractérisée en ce que les particules de polymère sont réalisées en un matériau choisi parmi les polymères et copolymères de chlorure de vinylidène, de chlorure de vinyle, d'acrylonitrile et/ou d'un monomère acrylique ou styrénique.
- Composition selon l'une des revendications précédentes, caractérisée en ce que les particules de polymère sont des particules creuses de copolymère de chlorure de vinylidène, d'acrylonitrile et/ou d'un monomère acrylique ou styrénique.
- Composition selon l'une des revendications précédentes, caractérisée en ce qu'elle contient, en outre, au moins un tensioactif liquide moussant et/ou nettoyant faisant partie du liant.
- Composition selon l'une des revendications précédentes, caractérisée en ce que le tensioactif liquide est lauryl éther sulfate de monoéthanolamine.
- Composition selon la revendication 10 ou 11, caractérisée en ce que le tensioactif liquide est présent en une quantité allant de 20 à 88 % du poids total de la composition.
- Composition selon l'une des revendications précédentes, caractérisée en ce que le tensioactif sous forme pulvérulente est présent en une quantité allant de 10 à 80 % du poids total de la composition.
- Composition selon l'une des revendications précédentes, caractérisée en ce que le tensioactif sous forme pulvérulente est présent en une quantité allant de 30 à 60 % du poids total de la composition.
- Composition selon l'une des revendications précédentes, caractérisée en ce que le tensioactif sous forme pulvérulente est le cocoyl iséthionate de sodium.
- Composition selon l'une des revendications 11 à 15, caractérisée en ce que le tensioactif liquide est présent à raison de 33 % à 67 % du poids total de la composition.
- Composition selon l'une des revendications précédentes, caractérisée en ce qu'elle contient, en outre, au moins un ingrédient choisi parmi les filtres, les parfums, les conservateurs, les antioxydants, les agents régulateurs de pH, les séquestrants, les charges, les colorants, les actifs cosmétiques ou dermatologiques, leurs mélanges.
- Composition selon l'une des revendications précédentes, caractérisée en ce qu'elle est obtenue par extrusion à froid.
- Utilisation cosmétique de la composition selon l'une des revendications précédentes pour le nettoyage et/ou le soin de la peau d'êtres humains.
- Procédé cosmétique de nettoyage et/ou de soin de la peau, consistant à hydrater une composition selon l'une des revendications 1 à 18, à la faire mousser, puis à l'appliquer sur la peau et enfin à rincer la peau.
- Procédé de fabrication d'une composition pulvérulente pour le nettoyage et/ou le soin de la peau, contenant un liant cosmétiquement acceptable, et une charge pulvérulente insoluble dans ce liant et en quantité suffisante pour structurer ladite composition et lui conférer un aspect de solide déformable dans lequel le liant est emprisonné, la charge pulvérulente comprenant des particules solides de polymère thermoplastique et au moins un tensioactif sous forme pulvérulente, la dite composition étant apte à mousser lors de son hydratation, consistant à introduire dans un mélangeur extrudeur, le liant puis la charge, puis à mettre en forme la composition issue du mélangeur extrudeur dans une filière de forme voulue.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9807519A FR2779650B1 (fr) | 1998-06-15 | 1998-06-15 | Composition pulverulente moussante solide a hydrater pour le soin ou le nettoyage de la peau |
FR9807519 | 1998-06-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0968702A1 true EP0968702A1 (fr) | 2000-01-05 |
EP0968702B1 EP0968702B1 (fr) | 2000-12-06 |
Family
ID=9527400
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99401135A Expired - Lifetime EP0968702B1 (fr) | 1998-06-15 | 1999-05-07 | Composition pulvérulente moussante solide à hydratrer pour le soin ou le nettoyage de la peau |
Country Status (8)
Country | Link |
---|---|
US (1) | US6245343B1 (fr) |
EP (1) | EP0968702B1 (fr) |
JP (1) | JP3430456B2 (fr) |
KR (1) | KR100342449B1 (fr) |
CA (1) | CA2274738A1 (fr) |
DE (1) | DE69900037T2 (fr) |
ES (1) | ES2154502T3 (fr) |
FR (1) | FR2779650B1 (fr) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000191510A (ja) * | 1998-12-28 | 2000-07-11 | Kao Corp | 皮膚洗浄剤組成物 |
US20040120915A1 (en) * | 2002-12-19 | 2004-06-24 | Kaiyuan Yang | Multifunctional compositions for surface applications |
US20090318557A1 (en) * | 2003-12-22 | 2009-12-24 | Stockel Richard F | Dermatological compositions |
US20050244212A1 (en) * | 2004-04-30 | 2005-11-03 | Kimberly-Clark Worldwide, Inc. | Foam generating article |
FR2881348B1 (fr) * | 2005-01-31 | 2008-12-26 | Oreal | Composition cosmetique nettoyante sous forme solide |
US20060177505A1 (en) * | 2005-01-31 | 2006-08-10 | L'oreal | Cleaning composition in solid form |
JP2014513076A (ja) | 2011-04-04 | 2014-05-29 | ザ プロクター アンド ギャンブル カンパニー | パーソナルケア物品 |
WO2012138716A2 (fr) * | 2011-04-04 | 2012-10-11 | The Procter & Gamble Company | Compositions d'hygiène personnelle solubles |
WO2013025760A1 (fr) | 2011-08-15 | 2013-02-21 | The Procter & Gamble Company | Articles de soins personnels ayant de multiples zones contenant des compositions de soins personnels conformes |
CN104202987B (zh) | 2011-08-15 | 2017-09-01 | 宝洁公司 | 个人护理方法 |
FR3001147B1 (fr) * | 2013-01-18 | 2015-07-17 | Oreal | Composition cosmetique solide souple, comprenant des tensioactifs anio-niques et des particules solides, et procede de traitement cosmetique |
FR3001144B1 (fr) * | 2013-01-18 | 2015-07-17 | Oreal | Composition cosmetique solide souple comprenant des tensioactifs anioniques et des agents conditionneurs polymeriques, et procede de traitement cosmetique |
CN105324157B (zh) | 2013-06-27 | 2019-01-29 | 宝洁公司 | 个人护理组合物和制品 |
KR102200185B1 (ko) | 2014-10-30 | 2021-01-08 | (주)아모레퍼시픽 | 세정제 조성물 |
KR102453888B1 (ko) * | 2015-09-30 | 2022-10-11 | (주)아모레퍼시픽 | 성형이 가능한 모발 케어용 조성물 |
WO2024089643A1 (fr) * | 2022-10-27 | 2024-05-02 | Johnson & Johnson Consumer Inc. | Compositions de nettoyage solides |
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DE4420880A1 (de) * | 1994-06-15 | 1995-12-21 | Wella Ag | Festigendes Haarreinigungsmittel |
EP0745379A1 (fr) * | 1995-05-29 | 1996-12-04 | L'oreal | Composition solide expansée amidonné contenant des particules de polyamide sphéroidales calibrées et utilisations en application topique |
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FR2658720B1 (fr) * | 1990-02-28 | 1994-09-09 | Oreal | Composition cosmetique sous forme de poudre compactee contenant des microspheres creuses en materiau synthetique thermoplastique. |
FR2700952B1 (fr) * | 1993-01-29 | 1995-03-17 | Oreal | Nouvelles compositions cosmétiques ou dermopharmaceutiques sous forme de gels aqueux modifiés par addition de microsphères expansées. |
FR2722092B1 (fr) * | 1994-07-11 | 1996-08-14 | Oreal | Composition capillaire solide contenant un agent structurant particulaire |
FR2722096A1 (fr) * | 1994-07-11 | 1996-01-12 | Oreal | Composition nettoyante solide pour la peau contenanr un agent structurant particulaire |
AU705449B2 (en) * | 1994-08-26 | 1999-05-20 | Procter & Gamble Company, The | Personal cleansing compositions |
FR2740334B1 (fr) * | 1995-10-25 | 1997-12-05 | Oreal | Composition cosmetique contenant un monoester d'acide en c4-c10 et d'alcool en c16-c18 et des particules creuses |
FR2755369B1 (fr) * | 1996-11-04 | 1998-12-04 | Oreal | Composition moussante pour le nettoyage de la peau sous la forme d'un gel transparent |
WO1998028398A1 (fr) * | 1996-12-23 | 1998-07-02 | Quest International B.V. | Particules contenant des liquides absorbes et procedes de fabrication de ces particules |
-
1998
- 1998-06-15 FR FR9807519A patent/FR2779650B1/fr not_active Expired - Fee Related
-
1999
- 1999-05-07 DE DE69900037T patent/DE69900037T2/de not_active Expired - Lifetime
- 1999-05-07 EP EP99401135A patent/EP0968702B1/fr not_active Expired - Lifetime
- 1999-05-07 ES ES99401135T patent/ES2154502T3/es not_active Expired - Lifetime
- 1999-06-09 KR KR1019990021429A patent/KR100342449B1/ko not_active IP Right Cessation
- 1999-06-14 JP JP16749399A patent/JP3430456B2/ja not_active Expired - Fee Related
- 1999-06-14 CA CA002274738A patent/CA2274738A1/fr not_active Abandoned
- 1999-06-15 US US09/332,901 patent/US6245343B1/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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DE4420880A1 (de) * | 1994-06-15 | 1995-12-21 | Wella Ag | Festigendes Haarreinigungsmittel |
EP0745379A1 (fr) * | 1995-05-29 | 1996-12-04 | L'oreal | Composition solide expansée amidonné contenant des particules de polyamide sphéroidales calibrées et utilisations en application topique |
Also Published As
Publication number | Publication date |
---|---|
ES2154502T3 (es) | 2001-04-01 |
FR2779650A1 (fr) | 1999-12-17 |
JP3430456B2 (ja) | 2003-07-28 |
DE69900037T2 (de) | 2001-04-12 |
KR20000006050A (ko) | 2000-01-25 |
FR2779650B1 (fr) | 2000-07-21 |
EP0968702B1 (fr) | 2000-12-06 |
US6245343B1 (en) | 2001-06-12 |
KR100342449B1 (ko) | 2002-06-28 |
JP2000007553A (ja) | 2000-01-11 |
CA2274738A1 (fr) | 1999-12-15 |
DE69900037D1 (de) | 2001-01-11 |
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