EP0967952A1 - Article absorbant jetable extensible et/ou flexible pouvant etre fixe solidement par adhesif topique sur la peau d'un utilisateur - Google Patents

Article absorbant jetable extensible et/ou flexible pouvant etre fixe solidement par adhesif topique sur la peau d'un utilisateur

Info

Publication number
EP0967952A1
EP0967952A1 EP97952545A EP97952545A EP0967952A1 EP 0967952 A1 EP0967952 A1 EP 0967952A1 EP 97952545 A EP97952545 A EP 97952545A EP 97952545 A EP97952545 A EP 97952545A EP 0967952 A1 EP0967952 A1 EP 0967952A1
Authority
EP
European Patent Office
Prior art keywords
rad
adhesive
sec
disposable absorbent
absorbent article
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP97952545A
Other languages
German (de)
English (en)
Inventor
Italo Corzani
Michael Divo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP96120740A external-priority patent/EP0850621A1/fr
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP97952545A priority Critical patent/EP0967952A1/fr
Publication of EP0967952A1 publication Critical patent/EP0967952A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/45—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
    • A61F13/47—Sanitary towels, incontinence pads or napkins
    • A61F13/474—Sanitary towels, incontinence pads or napkins adjustable
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/56—Supporting or fastening means
    • A61F13/5605—Supporting or fastening means specially adapted for sanitary napkins or the like
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/56—Supporting or fastening means
    • A61F13/66—Garments, holders or supports not integral with absorbent pads
    • A61F13/82—Garments, holders or supports not integral with absorbent pads with means for attaching to the body
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials

Definitions

  • Extensible and/or flexible disposable absorbent article for secure topical adhesive attachment to the skin of a wearer
  • the present invention relates to disposable absorbent articles particularly sanitary napkins, pantiliners, adult incontinence products or sweat pads.
  • the present invention relates to such disposable absorbent articles which are worn by direct attachment to the skin of the wearer in the area were absorption of bodily liquids is desired.
  • the topical adhesive attachment of such articles needs to be secure and pleasing upon application and during use of such articles, yet cause no discomfort upon removal of the article.
  • they are adaptable, preferably elastically adaptable.
  • the present invention does not relate to wound covering absorbent articles but relates to absorbent articles for absorption of body liquids which naturally emanate from a body without a wound.
  • absorbent articles for absorption of body liquids which naturally emanate from a body without a wound.
  • sanitary napkins or pantiliners for use in the genital region are such articles.
  • incontinence devices which are worn e.g. in the genital region or sweat pads which are worn in the arm pit region of a person are the subject of the present invention.
  • Such articles are applied to the skin of a wearer in a region were typically a considerable amount of hair grows such that the criteria of easy and painless removal of the article is of key importance.
  • Such articles have generally been disclosed in US statutory invention registration H1602 or WO 96/33683. Some more details of such articles have been considered for example in PCT application WO 95/16424.
  • sanitary articles having a body adhesive which is applied on the wearer facing side of a sanitary napkin along the entire periphery are disclosed. The problem underlying this document is primarily the safe attachment to the skin but mentions also the problems of detachment of such articles after use without causing undue pain to a wearer.
  • WO 95/16424 includes a detailed analysis of the criteria for the body adhesive in respect to rheological criteria.
  • rheological criteria taught include epilatory, i.e. hair removal, compositions which are commercially available such as STREP MIELE (TM) sold in Italy by Laboratori Vaj S.p.A.
  • the adhesives for topical attachment mentioned in WO 95/16424 include also today's pressure sensitive adhesives which are used to attach sanitary napkins to undergarments. Further, this document only identifies static rheological characteristics but is silent as to the dynamic rheological behaviour of a body adhesive.
  • This WLF equation is empirical and only valid within certain limits e.g. it cannot be used to extrapolate to temperatures below the glass transition temperature of a polymeric adhesive also the WLF cannot be used on the basis of values obtained below the glass transition temperature. Details about the WLF equation and its applicability can be found in "Principles of Polymer processing" by Z.
  • European Patent Application EP-638 303 discloses the use of a body adhesive on side cuffs of sanitary napkins in order to keep the cuffs in an upright position.
  • Swiss publication CH-643730 discloses the use of a very long sanitary napkin having chamfered outer edges with a body adhesive at the four corners of the outer edges in order to provide a body adhesive area well outside the region of pubic hair growth.
  • the present invention relates to disposable absorbent articles for topical adhesive attachment to a wearer of such articles.
  • the article typically has a wearer facing surface and an outside surface also called garment facing surface in the context of articles worn underneath clothing.
  • the article has a longitudinal axis separating the article as it is worn into right and left side.
  • the article also has a transverse axis which is perpendicular to the longitudinal axis.
  • the article comprises an absorbent core structure between the wearer facing surface and the garment facing surface for absorbing liquids naturally emanating from a wearer.
  • the disposable absorbent article according to the present invention comprises on at least part of the wearer facing surface an adhesive for topical adhesive attachment of the article to the skin of the wearer.
  • the article is adaptable in at least one direction, preferably two directions, parallel to the longitudinal and/or the transverse axis.
  • the adaptability is provided in that the article is corrugated or pleated. This can be provided either parallel to the longitudinal axis or parallel to the transverse axis or in a combination of both. Also corrugating or pleating parallel to both axis can be considered which results in articles being adaptable in both directions.
  • the article is contractible which will allow adaptability when some part of the skin surface covered by the absorbent article is reduced in size and be elastically extensible in which case the article extends together with an extending surface (e.g. in the arm pit region when the arm is lifted) while it has the ability to return at least to some extend to the original size.
  • This elasticity can be provided by rendering the various components of the absorbent article elastic or rendering some portions of the components of the absorbent article elastic.
  • the viscous behaviour of a body adhesive can be interpreted to represent an indication of the ability of the adhesive to quickly attach and securely adhere.
  • the elastic behaviour can be interpreted as an indication of the "hardness" behaviour of the adhesive. Its value is also critical for good initial attachment. Their combination is believed to be an indicator of the required force upon removal.
  • the relation between elastic and viscous modulus is considered to be an indication which fraction of the removal energy will be dissipated within the adhesive and which fraction is available to trigger the actual removal.
  • the adhesive has an elastic modulus at a temperature of 37°C (100° Fahrenheit) abbreviated G'37 and a viscous modulus at a temperature of 37°C (100° Fahrenheit) of G"37.
  • the adhesive further has a dynamic elastic behaviour defined as _ G'37 which is the difference of G'37 a a frequency of 100 rad/sec and G'37 at a frequency of 1 rad/sec and a dynamic viscous behaviour _ G"37 which is the difference of G"37 at a frequency of 100 rad/sec and G"37 at a frequency of 1 rad/sec.
  • the articles according to the present invention comprise a topical adhesive satisfying the following conditions.
  • o G'37 (1 rad/sec) is in the range 1500 Pa to 20000 Pa, preferably 1500 Pa to 15000 Pa, most preferably 3000 Pa to 10000 Pa.
  • o G"37 (1 rad/sec) is in the range 100 Pa to 15000 Pa, preferably 100 Pa to 10000 Pa, most preferably 300 Pa to 5000 Pa.
  • the ratio of G'37 (1 rad/sec) / G"37 (1 rad/sec) is in the range of 2 to 50, preferably 3 to 30.
  • G'37 (1 rad/sec) • - C'37 (1 rad/sec) is not less than 0.5, preferably in the range
  • _ G'37/G'37 (1 rad/sec) is not greater than 1.5, preferably not greater than unity and most preferably not greater than 0.8, or _ G'37 is not greater than 10000 Pa, preferably less than 5000 Pa, most preferably less than 2000 Pa, or both.
  • o the value of the ratio G'37/G"37 at least for the frequency range from above 1 rad/s up to 100 rad/s should preferably be 2 or above, more preferably 3.3 or above, while not exceeding about 50, preferably 30, anywhere in the frequency interval.
  • Tg should preferably be less than -15°C, more preferably less than - 20°C and most preferably less than -25°C.
  • the specific heat capacity of the topical adhesive is less than 4 J/g/K, more preferably less than 3 J/g/K and most preferably less than 2 J/g/K.
  • the specific heat conductivity is more than 0.1 W/m/K, preferably more than 0.6 W/m/K and most preferably more than 1 W/m/K.
  • Adhesive compositions which satisfy the above criteria can be used as topical adhesives for disposable absorbent articles provided they also satisfy the common requirements of being safe for use on human skin during use and generally after disposal of the article.
  • the criteria of hygienic appearance and pleasant feel upon contact are important such that adhesive composition which are transparent or white, and which prevent a cold, unpleasant feeling upon application are preferred.
  • the above rheological criteria and other considerations can be satisfied by adhesive compositions where the composition comprises from 51 % to 99.5 % of a plasticising compound or composition which is liquid at 20°C, from 0.5 to 20 %, preferably 5 % to 15 %, of a polymeric compound or composition which is soluble or swellable in the plasticising compound or composition and with a tackifying resin in an amount in the range from 0 % to 600 % by weight of the polymeric compound.
  • the plasticising compound or composition is preferably selected from the group consisting of water, alcohols (preferably glycerol), glycols, polyglycols, liquid polybutenes, oil or combinations thereof.
  • the polymeric compound or composition is preferably selected from the group consisting of block-copolymer-thermoplastic-elastomers, styrene-block- copolymers and hydrogenated styrene-block-copolymers.
  • This invention relates to disposable absorbent articles which are applied directly to the skin of a user.
  • the article exhibits absorbency for bodily fluids, the protection of the user's garments from soiling, improved physical comfort to the user, and is easy to produce and to package.
  • the disposable absorbent article is described below by reference to a sanitary napkin or catamenial, however panty liners, adult incontinence articles or sweat pads are also included under the term disposable absorbent articles.
  • sanitary napkin refers to an article which is worn by females adjacent to the pudendal region and which is intended to absorb and contain the various body fluids which are discharged from the body (e.g., vaginal discharges, menses, and/or urine) and which is intended to be discarded after a single use.
  • the disposable absorbent article is preferably thin, more preferably between 1 and 5 mm thick and either substantially flat prior to use or in a preshaped form.
  • a sanitary napkin of the present invention comprises a liquid pervious topsheet, a liquid impervious backsheet joined to the topsheet, and an absorbent core intermediate the topsheet and the backsheet.
  • the sanitary napkin has two main surfaces, a body contacting or wearer facing surface, and a garment facing or contacting surface.
  • the present invention is concerned with the adaptability of the product.
  • the degree of adaptability is determined by the selection of the materials for the components of the product as mentioned above, their respective quantity and to which extend they have been treated to provide adaptability. It will be apparent to those skilled in the art that, in order to achieve the adaptability according to the present invention, the selection of kind, quantity and treatment of raw materials has to be balanced with other desired characteristics of the absorbent product such as for example absorbent capacity, absorption speed and surface dryness on the outside of the topsheet during use, and so on.
  • the absorbent articles according to a preferred embodiment of the present invention are elastically stretchable.
  • the term 'elastically stretchable' means that when the stretching forces are removed, the article will tend to return toward its unextended or unstretched (or Original') dimensions. It need not return all the way to its unstretched dimensions, however. If the absorbent article is elastically stretchable it may be stretchable in one or two directions (which are not-parallel) within the plane of the product i.e. topographically parallel to the wearer facing surface.
  • Materials for contractible and elastically stretchable articles can be elastically stretchable per se or be treated so as to provide elastic stretchablility.
  • elastic backsheet material, elastic topsheet material, filamentary materials combined with elastic strands, threads or webs as well as shirring, pleating or ring rolling of the materials may be employed in this context.
  • Suitable material and methods are known in the art and e.g. disclosed in detail in US application 08/192240 of February 4, 1994 specifically referred to in order to facilitate selection of materials if elastically stretchable absorbent articles according to the present invention are made.
  • the absorbent core typically includes the following components: (a) optionally a primary fluid distribution layer; (b) optionally, but preferably, a secondary fluid distribution layer; (c) a fluid storage layer; (d) optionally a fibrous (“dusting") layer underlying the storage layer; and (e) other optional components.
  • One optional component of the absorbent cores according to the present invention is the primary fluid distribution layer.
  • This primary distribution layer typically underlies the topsheet and is in fluid communication therewith.
  • the topsheet transfers the acquired menstrual fluid to this primary distribution layer for ultimate distribution to the storage layer. This transfer of fluid through the primary distribution layer occurs not only in the thickness, but also along the length and width directions of the absorbent product.
  • a preferred component of the absorbent cores according to the present invention is a secondary fluid distribution layer.
  • This secondary distribution layer typically underlies the primary distribution layer and is in fluid communication therewith. The purpose of this secondary distribution layer is to readily acquire fluid from the primary distribution layer and transfer it rapidly to the underlying storage layer. This helps the fluid capacity of the underlying storage layer to be fully utilized.
  • Fluid Storage Layer Positioned in fluid communication with, and typically underlying the primary or secondary distribution layers, is a fluid storage layer comprising certain absorbent gelling materials and/or other absorbent materials, which can form the carrier matrix for the absorbent gelling materials.
  • Absorbent gelling materials are usually referred to as “hydrogels,” “superabsorbent” “hydrocolloid” materials.
  • Absorbent gelling materials are those materials that, upon contact with aqueous fluids, especially aqueous body fluids, imbibes such fluids and thus form hydrogels. These absorbent gelling materials are typically capable of absorbing large quantities of aqueous body fluids, and are further capable of retaining such absorbed fluids under moderate pressures. These absorbent gelling materials are typically in the form of discrete, nonfibrous particles.
  • the fluid storage layer can comprise solely absorbent gelling materials, or these absorbent gelling materials can be dispersed homogeneously or non- homogeneously in a suitable carrier or it can comprise solely an absorbent carrier material.
  • Suitable carriers include cellulose fibers, in the form of fluff, tissues or paper such as is conventionally utilized in absorbent cores. Modified cellulose fibers such as the stiffened cellulose fibers can also be used. Synthetic fibers can also be used and include those made of cellulose acetate, polyvinyl fluoride, polyvinylidene chloride, acrylics (such as Orion), polyvinyl acetate, non-soluble polyvinyl alcohol, polyethylene, polypropylene, polyamides (such as nylon), polyesters, bicomponent fibers, tricomponent fibers, mixtures thereof and the like.
  • Preferred synthetic fibers have a denier of from about 3 denier per filament to about 25 denier per filament, more preferably from about 5 denier per filament to about 16 denier per filament. Also preferably, the fiber surfaces are hydrophilic or are treated to be hydrophilic.
  • the storage layer can also include filler materials, such as Perlite, diatomaceous earth, Vermiculite, etc., that lower rewet problems.
  • the storage layer can be locally homogeneous, i.e. have a distribution gradient in one or several directions within the dimensions of the storage layer.
  • Non-homogeneous distribution can also refer to laminates of carriers enclosing absorbent gelling materials partially or fully. If laminates are used they can be formed with or without absorbent gelling particles.
  • thermally bonded air laid fibrous sheets or laminates and/or thermally bonded wet laid sheets or laminates have been found useful, especially in the context of panty liners when no absorbent gelling material is used.
  • the storage layer comprises from about 15 to 100% absorbent gelling materials and from 0 to about 85% carrier. More preferably, the storage layer comprises from about 30 to 100 %, most preferably from about 60 to 100% absorbent gelling materials and from 0 to about 70 %, most preferably from 0 to about 40 %, carrier.
  • Suitable absorbent gelling materials for use herein will most often comprise a substantially water-insoluble, slightly crosslinked, partially neutralized, polymeric gelling material. This material forms a hydrogel upon contact with water.
  • Such polymer materials can be prepared from polymerizable, unsaturated, acid- containing monomers. Suitable unsaturated acidic monomers for use in preparing the polymeric absorbent gelling material used in this invention include those listed in U.S. Patent 4,654,039 and reissued as RE 32,649. Preferred monomers include acrylic acid, methacrylic acid, and 2-acrylamido-2-methyl propane sulfonic acid. Acrylic acid itself is especially preferred for preparation of the polymeric gelling material.
  • the polymeric component formed from the unsaturated, acid-containing monomers can be grafted onto other types of polymer moieties such as starch or cellulose.
  • Polyacrylate grafted starch materials of this type are especially preferred.
  • Preferred polymeric absorbent gelling materials that can be prepared from conventional types of monomers include hydrolyzed acrylonitrile grafted starch, polyacrylate grafted starch, polyacrylates, maleic anhydride-based copolymers and combinations thereof. Especially preferred are the polyacrylates and polyacrylate grafted starch.
  • absorbent gelling materials are typically in particle form, it is also contemplated that the absorbent gelling material can be in the form of macrostructures such as fibers, sheets or strips.
  • An optional component for inclusion in the absorbent cores according to the present invention is a fibrous layer adjacent to, and typically underlying the storage layer.
  • This underlying fibrous layer is typically referred to as a "dusting” layer since it provides a substrate on which to deposit absorbent gelling material in the storage layer during manufacture of the absorbent core. Indeed, in those instances where the absorbent gelling material is in the form of laminates or of macrostructures such as fibers, sheets or strips, this fibrous "dusting" layer need not be included. However, because this "dusting" layer provides some additional fluid-handling capabilities such as rapid wicking of fluid along the length of the pad, its inclusion is typically preferred in absorbent cores according to the present invention.
  • the absorbent cores according to the present invention can include other optional components normally present in absorbent webs.
  • a reinforcing scrim can be positioned within the respective layers, or between the respective layers, of the absorbent cores.
  • Such reinforcing scrims should be of such configuration as to not form interfacial barriers to fluid transfer, especially if positioned between the respective layers of the absorbent core.
  • reinforcing scrims are usually not required for the absorbent structures according to the present invention. If used however they have to allow the desired contractability.
  • odor control agents are odor control agents. These can be selected from active carbon or coated active carbon to conceal the color, suitable zeolite or clay materials, are optionally incorporated in the absorbent core also absorbent gelling material in combination with certain zeolites have been found useful. These components can be incorporated in any desired form but often are included as discrete, non-fibrous particles.
  • the topsheet is compliant, soft feeling, and non-irritating to the wearer's skin.
  • the topsheet also can have elastic characteristics allowing it to be stretched in one or two directions in portions of the topsheet or throughout its extension. Further, the topsheet is fluid pervious permitting fluids (e.g., menses and/or urine) to readily penetrate through its thickness.
  • a suitable topsheet can be manufactured from a wide range of materials such as woven and non woven materials; polymeric materials such as apertured formed thermoplastic films, apertured plastic films, and hydroformed thermoplastic films; and thermoplastic scrims.
  • Suitable woven and non woven materials can be comprised of natural fibers (e.g., wood or cotton fibers), synthetic fibers (e.g., polymeric fibers such as polyester, polypropylene, or polyethylene fibers) or from a combination of natural and synthetic fibers or bi-/multi-component fibers.
  • natural fibers e.g., wood or cotton fibers
  • synthetic fibers e.g., polymeric fibers such as polyester, polypropylene, or polyethylene fibers
  • Preferred topsheets for use in the present invention are typically selected from high loft nonwoven topsheets and apertured formed film topsheets.
  • Apertured formed films are especially preferred for the topsheets because they are pervious to body exudates and yet non absorbent and have a reduced tendency to allow fluids to pass back through and rewet the wearer's skin.
  • the surface of the formed film that is in contact with the wearer remains dry, thereby reducing body soiling and creating a more comfortable feel for the wearer.
  • Suitable formed films are described in U.S. Patent 3,929,135; U.S. Patent 4,324,246; U.S. Patent 4,342,314; U.S. Patent 4,463,045; and U.S. Patent 5,006,394.
  • a preferred topsheet for the present invention comprises the formed film described in one or more of the above patents and marketed on sanitary napkins by The Procter & Gamble Company of Cincinnati, Ohio as "DRI-WEAVE".
  • Topsheets having not a homogeneous distribution of liquid passage ways but only a portion of the topsheet comprising liquid passage ways are also contemplated by the present invention. Typically such topsheets would have the liquid passage ways oriented such that they result in a centrally permeable and peripherally impermeable topsheet for liquids.
  • the wearer facing surface of the formed film topsheet can be hydrophilic so as to help liquid to transfer though the topsheet faster than if the body surface was not hydrophilic.
  • surfactant is incorporated into the polymeric materials of the formed film topsheet such as is described in PCT- publication WO 93/09741.
  • the wearer facing surface of the topsheet can be made hydrophilic by treating it with a surfactant such as is described in U.S. 4,950,254.
  • hybrid topsheets which incorporate fibrous and film like structures particularly useful embodiments of such hybrid topsheets are disclosed in PCT publications WO 93/09744; WO 93/11725 or WO 93/11726.
  • topsheet When referring to the topsheet a multi layer structure or a mono layer structure is contemplated.
  • the hybrid topsheet mentioned above is such a multi layer design but other multi layer topsheets such as primary and secondary topsheet designs are also considered.
  • the backsheet primarily prevents the exudates absorbed and contained in the absorbent structure from wetting articles that contact the absorbent product such as underpants, pants, pyjamas and undergarments.
  • the backsheet is preferably impervious to liquids (e.g. menses and/or urine) and is preferably manufactured from a thin plastic film, although other flexible liquid impervious materials can also be used.
  • liquids e.g. menses and/or urine
  • the term "flexible” refers to materials that are compliant and will readily conform to the general shape and contours of the human body.
  • the backsheet also can have elastic characteristics allowing it to stretch in one or two directions.
  • the backsheet typically extends across the whole of the absorbent structure and can extend onto and form part of the topsheet by folding around the absorbent structure.
  • a topsheet configuration as disclosed in US 4,342,314, column 16, lines 47 - 62 can be achieved without the requirement to selectively aperture the topsheet.
  • the backsheet can comprise a woven or nonwoven material, polymeric films such as thermoplastic films of polyethylene or polypropylene, laminates of such materials or composite materials such as a film-coated nonwoven material.
  • the backsheet is a polyethylene film having a thickness of from about 0.012 mm (0.5 mil) to about 0.051 mm (2.0 mils).
  • Exemplary polyethylene films are manufactured by Clopay Corporation of Cincinnati, Ohio, under the designation P18-1401 and by Ethyl Corporation, Visqueen Division, of Terre Haute, Indiana, under the designation XP-39385.
  • the backsheet is preferably embossed and/or matte finished to provide a more clothlike appearance.
  • the backsheet also provides breathability to the absorbent article by being at least water vapour permeable, preferably air permeable, however, without compromising the main function of the backsheet.
  • the backsheet can be a laminate material e.g. of a combination of microporous film, non-woven material, and/or apertured formed film. Breathability if desired can be limited to the periphery of the backsheet or it can be across the whole backsheet.
  • Adaptability incompasses the characteristics of contractability, extensibility, and combinations thereof. Adaptability usually refers to the ability to adapt in the size in one or both directions of a sanitary napkin.
  • Adaptability according to the present invention can be provided by creating a series of corrugations or pleats in the direction perpendicular to the direction in which the product is desired to be adaptable.
  • a thin sanitary article having corrugations or pleats in longitudinal direction will provide the ability to be stretched in transverse direction in order to accommodate a crotch width change of the article upon application of the article or during use.
  • These corrugations or pleats can also provide the ability to enlarge or reduce the width of the article in order to result in the usual wearing position for wearers of differing crotch width.
  • the ability to adapt to the desired extend can be provided in longitudinal or transverse direction. It can be employed to provide synergistic effects together with elastically extensible materials in the construction of the absorbent article. It is of course also possible to use inherent material adaptability with the structural adaptability provided by corrugations or pleats.
  • corrugated or corrugations designates the existence of a series of continuous changes of the normal direction of a plain of a sheet.
  • the "normal direction” of a plain is the direction perpendicular to that plain. While corrugations are a continuous change of the normal direction in the plain of a sheet the term “pleats” or pleated” as used herein refers to foldings along a specific line or, in other words, an uprupt change in the normal direction of a plain of a sheet. A series of pleats can also be used to simulate corrugations.
  • ring-rolling can be employed upon the whole product to provide structural corrugations allowing for adaptability of the product as desired.
  • Such ring-rolling at least in a high speed manufacturing operation does require the materials to be carefully selected by a man skilled in the art which however is no problem given the above material choices and a desired adaptability in mind.
  • Ring-rolling of individual materials prior to combination can also be useful in order to provide products in addition to their adaptability having a flexibility and softness improvement over usual products.
  • corrugating is well-known and will be easily usable for those skilled in the art. Corrugations may be present in both longitudinal and transverse direction of the absorbent article, however, corrugation techniques have been developed to provide corrugations which are transverse to the direction of material transport during manufacturing of an article. Hence a ring-rolling operation can be considered to provide corrugation in the direction of transport of a material during manufacturing while a corrugation process would typically provide only corrugation in the perpendicular direction.
  • corrugations or pleats does refer to the result of ring-rolling or corrugating irrespective of whether the process was used in the direction of transport of a material during manufacturing or perpendicular thereto.
  • corrugation or pleats can easily be defined by simple trial and error to accommodate the required adaptability. It will depend on the combined thickness and flexibility of the article. Those skilled in the art will also realize that the same corrugation or pleats can be provided such that they allow different extends of adaptability depending on whether they have been partially flatened out again.
  • transport to the product supply locations and personal handling of the article prior to attaching it to the skin This can be achieved for example by stabilising or freezing the product in its corrugated or pleated state by affixing it in that state to a rigid substrate such as for example a release paper or adhesive protection means for the body adhesive.
  • sanitary napkins are applied in the genital region of a typically female user around the area of liquid discharge.
  • the word "skin" according to the present invention does not only relate to the specific derma of the user but include the mucous tissue as well as the hair which is typically found in the genital region of users of sanitary napkins.
  • the body adhesive is provided along the peripheral edge of the topsheet such that a central area of the article is left without adhesive. This will most appropriately facilitate placing the article such that the liquid permeable topsheet without adhesive on it is placed adjacent the bodily liquid emanating orifice such that emanating liquid is immediately transported into the absorbent structure of the absorbent article without the possibility of leakage or spillage.
  • the body adhesive is provided in a closed circle around the periphery of the topsheet but it can be provided in incremental areas such as dots or discrete lines such that decoupling between the different places of attachment is providing additional comfort to the wearer of such articles in conjunction with the adaptability of the articles. Since the adhesive strength and other characteristics of a body adhesive will be influenced by the adaptability it is generally appropriate to provide the absorbent article prior to selecting a body adhesive. In particular the area coverage of the body adhesive needs to be carefully defined in order to maintain the desirable benefits from the adaptable article, e.g. when the article is corrugated the adhesive should usually not immobilise the corrugate.
  • PSA typical pressure sensitive adhesive
  • materials useful as body adhesives according to the present invention have rheological characteristics which are measured at a reference temperature of 37°C as body temperature and in a range of frequencies. It has been found that upon application of an article with a body adhesive the adhesive contact is formed at a low frequency, while debonding happens at the speed of removing the article. This speed is expressed as a frequency of 100 rad/s while the low frequency of forming the adhesive bond has been found to be on the order of 1 rad/s. Therefore, the frequency range for use according to the present invention is between 1 and 100 rad/s.
  • G' and G" at the application frequency of 1 rad/s are taken at a temperature of 37°C.
  • the actual storage temperature of the article and hence the temperature of the body adhesive upon application varies widely.
  • storage in a hot bathroom near a radiator could reach up to about 37°C
  • storage in a storage room or in a bathroom without heating but with an open window during winter could be close to 0°C.
  • the article according to the present invention is used directly on skin and the man skilled in the art is directed to select the adhesive composition to have a small specific heat capacity (e.g.
  • the adhesive bonding characteristics are selected most appropriately at body temperature.
  • the absolute values of the elastic modulus should not be too high, otherwise the adhesive is too hard and it is not able to intimately join or mold to the surface to which it is expected to adhere. It is also important to have a low absolute value of G" in order to have good cohesion which is particularly valuable for a direct application on the human body while the material remains soft and capable of gently adhering to the skin.
  • the ratio of G'37 (1 rad/sec) over C37 (1 rad/sec) is important to ensure that these two values are balanced upon application of the disposable absorbent article to the skin.
  • the absolute changes of G'37 needs to be limited within the range of frequencies considered.
  • a value for the ration of _ G'37 i.e. G'37 (100 rad/sec) - G'37 (1 rad/sec)
  • G'37 (1 rad/sec) i.e. G'37 (100 rad/sec) - G'37 (1 rad/sec)
  • This can also be expressed in absolute terms by keeping the _ G'37 below certain values.
  • o G'37 (1 rad/sec) is in the range 1500 Pa to 20000 Pa, preferably 1500 Pa to 15000 Pa, most preferably 3000 Pa to 10000 Pa.
  • o G"37 (1 rad/sec) is in the range 100 Pa to 15000 Pa, preferably 100 Pa to 10000 Pa, most preferably 300 Pa to 5000 Pa.
  • o the ratio of G'37 (1 rad/sec) / C'37 (1 rad/sec) is in the range of 2 to 50, preferably 3 to 30.
  • G'37 (1 rad/sec) - C'37 (1 rad/sec) is not less than 0.5, preferably in the range 0.7 to 3, most preferably in the range 1 to 1.8.
  • either the ratio of _ C37/C37 (1 rad/sec) is not greater than 1.5, preferably not greater than unity and most preferably not greater than 0.8,
  • or _ G'37 is not greater than 10000 Pa, preferably less than 5000 Pa, most preferably less than 2000 Pa, or both.
  • the value of the ratio C37/G"37 at least for the frequency range from above 1 rad/s up to 100 rad/s should preferably be 2 or above, more preferably 3.3 or above, while not exceeding about 50, preferably 30, anywhere in the frequency interval.
  • the rheological behaviour can also be related to the values of the Glass Transition Temperature Tg.
  • Tg should preferably be less than -15°C, more preferably less than - 20°C and most preferably less than -25°C.
  • the rheological behaviour and acceptance of a disposable article comprising a topical adhesive can also be related to the specific heat capacity.
  • the specific heat capacity of the topical adhesive is less than 4 J/g/K, more preferably less than 3 J/g/K and most preferably less than 2 J/g/K.
  • the specific heat conductivity is more than 0.1 W/m/K, preferably more than 0.6 W/m/K and most preferably more than 1 W/m/K.
  • compositions which satisfy the requirements of the above rheological and physical characteristics of a body adhesive the following formulation criteria can be used in addition. It should be noted that the most of the compositions useful as body adhesive have a substantially gel-like structure and are preferably gels. This derives from the fact that:
  • the plasticiser which is a material liquid at room temperature
  • a macromolecular or polymeric component is present in minor quantities vs the plasticiser. It forms, in the preferred embodiments, a three dimensional network caused by physical or chemical links between the molecules. Particularly useful physical links are the ones present in systems containing Block Thermoplastic Elastomers.
  • compositions typically comprise:
  • macromolecular or polymeric substances can be natural and/or synthetic such as natural gums or derivatives such as natural gums and gelatines, their derivatives and alginates; polyacrilics; polyvinyl alcohol; polyethylene oxide; polyvinylpyrrolidon (PVP) or polyvinylethers, their copolymers and derivatives; cellulose derivatives; Block Copoiymer Thermoplastic Elastomers and preferably Styrenic Block Copolymers and more preferably the hydrogenated grades Styrol/Ethylene-Butylene/Styrol (SEBS), Styrene/lsoprene/Styrene (SIS), and Styrol/Ethylene-Propylene/Styrol (SEPS).
  • SEBS Styrol/Ethylene-Butylene/Styrol
  • SIS Styrene/lsoprene/Styrene
  • SEPS Styrol/Ethylene-Propylene/Styrol
  • plasticising substance or a mixture of plasticising substances, which are liquid at room temperature.
  • the plasticiser can be water, various alcohols (like in particular glycerol), glycols and their eithers, polyglycols, liquid polybutenes, esters such phtalates, adipates, stearates, palmitates, sebacates, or myristates, natural or synthetic oils such as vegetable oils, mineral oils, or combinations thereof.
  • hydrophilic or hydrophobic liquid plasticisers may be for oily systems, e.g. the fatty acids of C ⁇ to C 22 , their metallic salts and their polyoxo-derivatives; lanolin derivatives; silica; bentonite, montmorillonite and their derivatives; polyamides, waxes or mixtures thereof.
  • additives known in the art as preservatives, antioxidants, anti UV, pigments, mineral fillers, rheology modifiers etc. can also be comprised in quantities up to 10 % each.
  • a crosslinking agent can be present preferably in quantities up to 5 % by weight.
  • Chemical crosslinking can be formed also by mutual neutralisation of polymers having different functionalities as in the reaction between acid polyacrylics and polysaccharides.
  • compositions for body adhesives can be divided into three families according to the nature of the main component, i.e. the liquid plasticiser(s): 1) Hydrophobic compositions in which the plasticiser is typically an oil or blend of oils of vegetable or mineral origin and the polymer is usually a synthetic polymer, preferably an elastomer, soluble or swellable in oil(s).
  • both hydrophobic and hydrophilic components possibly in both plasticisers and polymers, form two or more separate phases.
  • an emulsifier/surfactant is preferably present at a suitable level to form stable emulsions between the incompatible phases.
  • the hydrophobic components are prevailing vs. the hydrophilic ones.
  • Hydrophilic compositions in which typically the plasticiser is water/glycerol/glycols and the like and/or mixtures thereof and the polymeric phase is of synthetic (e.g. polyacrilics) or natural (e.g. natural gums) origin or mixtures thereof.
  • hydrophilic compositions are not preferred while the hydrophobic and mixed phases compositions 1) and 2) are preferred in the applications of the present invention.
  • hydrophilic compositions used in the medical field show too low elastic character and cohesion for being useful in the present application.
  • the other reason to prefer hydrophobic or mixed phase compositions is that the application of the present invention in particular in the sanitary napkin field will include a probability of contacting the body adhesive with the liquid to be absorbed. Since the liquid to be absorbed are all of a general aqueous kind contact with a hydrophilic body adhesive would result in a certain absorption of the bodily liquids into the body adhesives.
  • hydrophilic body adhesive also tend to be perceived as cold and wet which upon application of a fresh sanitary napkin or an underarm sweat pad is not in line with typical consumer expectation. Additional problems result from the fact that in particular body adhesives comprising water as the plasticiser have a tendency to dry out unless they are sealed into an impermeable package.
  • Absorbent articles according to the present invention can be made by any of the ways usual in the art.
  • the application of the adhesive to the topsheet side of the absorbent article should not cause major problems to those skilled in the art since it can be provided by similar techniques as is commonly used for a panty fastening adhesive.
  • the total area of the wearer facing surface of the absorbent article which is covered by body adhesive should be not more than 20 %, preferably not more than 10 %.
  • the adhesive is close to the periphery of the absorbent article and in the case of film topsheets (or when the backsheet is folded onto the topsheet) the adhesive is preferably on a portion of the film which is not permeable to liquids.
  • the body adhesive on the article (as is also common with panty fastening adhesives) needs to be protected prior to use.
  • This protection can be provided by a release liner such as a siliconised or surfactant treated paper, provided this paper is a good release surface for the particularly selected body adhesive.
  • the absorbent article according to the present invention is supported on the wearer by the body adhesive and does not require additional support to remain in place.
  • the body adhesive it is possible to provide for example a sanitary napkin with a skid resistant coating on the backsheet side in order to prevent the sanitary napkin form gradually migrating out of position.
  • panty fastening adhesives are not desired and hence not preferred according to the present invention they are not strictly speaking excluded in the context of the present invention.
  • EXAMPLE 1 An oil based composition useful on sanitary napkins according to the present invention was prepared using 9.9 % by weight of Kraton G-1651 , a Styrene/Ethylene-Butylene/Styrene block copolymer containing 33% by weight styrene and available from Shell Co, and 59.3 % by weight of Kaydol, a paraffinic mineral oil available from Witco Co.
  • composition contained 301 parts of tackifying resin per 100 parts of Kraton polymer.
  • the tackifying resin was Escorez 5300, a hydrogenated resin available from Exxon Co.
  • Magnesium Stearate available from Carlo Erba S.p.A., was used a co-gelifying agent for oil at a level of 0.7 % by weight.
  • Irganox 1010 an antioxidant available from Ciba-Geigy, was added at a level of 0.3 % by weight.
  • the composition showed the following rheological properties at 37°C.
  • a componotine oil based composition was compounded using 7.1 % by weight of Kraton G-1651 , a Styrene/Ethylene-Butylene/Styrene block copolymer containing 33% by weight styrene and available from Shell Co, and 41.9 % by weight of Kaydol, a paraffinic mineral oil available from Witco Co.
  • composition contained 704 parts of tackifying resin per 100 parts of Kraton polymer.
  • the tackifying resin was Regalrez 3102, a hydrocarbon resin available from Hercules Co.
  • Magnesium Stearate available from Carlo Erba S.p.A., was used a co-gelifying agent for oil at a level of 0.7 % by weight.
  • Irganox 1010 an antioxidant available from Ciba-Geigy, was added at a level of 0.3 % by weight.
  • the composition showed the following rheological properties at 37°C.

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  • Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Vascular Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne des articles absorbants jetables, en particulier des serviettes hygiéniques, des protège-slips, des produits contre l'incontinence adulte ou des coussinets antisudation. La présente invention concerne plus précisément les articles absorbants jetables qu'on fixe directement sur la peau de l'utilisateur, dans la zone où l'on souhaite l'absorption de liquides corporels. De tels articles doivent être fixés par adhésif topique de manière solide et procurer une sensation agréable, aussi bien lors de leur mise en place, que pendant leur utilisation, sans causer de gêne au moment de leur retrait. Afin que les articles de la présente invention soient plus confortables, ils sont adaptables, de préférence, de manière élastique.
EP97952545A 1996-12-23 1997-12-22 Article absorbant jetable extensible et/ou flexible pouvant etre fixe solidement par adhesif topique sur la peau d'un utilisateur Withdrawn EP0967952A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP97952545A EP0967952A1 (fr) 1996-12-23 1997-12-22 Article absorbant jetable extensible et/ou flexible pouvant etre fixe solidement par adhesif topique sur la peau d'un utilisateur

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
EP96120740 1996-12-23
EP96120740A EP0850621A1 (fr) 1996-12-23 1996-12-23 Article absorbant jetable extensible ou flexible pourvu d'un adhésive pour la fixation d'article sur la peau
EP97110732A EP0850626A1 (fr) 1996-12-23 1997-07-01 Article absorbant jetable extensible ou flexible pourvu d'un adhesif pour la fixation d'article sur la peau
EP97110732 1997-07-01
EP97952545A EP0967952A1 (fr) 1996-12-23 1997-12-22 Article absorbant jetable extensible et/ou flexible pouvant etre fixe solidement par adhesif topique sur la peau d'un utilisateur
PCT/US1997/023475 WO1998027915A1 (fr) 1996-12-23 1997-12-22 Article absorbant jetable extensible et/ou flexible pouvant etre fixe solidement par adhesif topique sur la peau d'un utilisateur

Publications (1)

Publication Number Publication Date
EP0967952A1 true EP0967952A1 (fr) 2000-01-05

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EP97110732A Pending EP0850626A1 (fr) 1996-12-23 1997-07-01 Article absorbant jetable extensible ou flexible pourvu d'un adhesif pour la fixation d'article sur la peau
EP97952545A Withdrawn EP0967952A1 (fr) 1996-12-23 1997-12-22 Article absorbant jetable extensible et/ou flexible pouvant etre fixe solidement par adhesif topique sur la peau d'un utilisateur

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP97110732A Pending EP0850626A1 (fr) 1996-12-23 1997-07-01 Article absorbant jetable extensible ou flexible pourvu d'un adhesif pour la fixation d'article sur la peau

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EP (2) EP0850626A1 (fr)
JP (1) JP2000505706A (fr)
KR (1) KR20000069661A (fr)
AU (1) AU5613098A (fr)
BR (1) BR9714844A (fr)
CA (1) CA2275881A1 (fr)
ID (1) ID23798A (fr)
WO (1) WO1998027915A1 (fr)

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US6716204B1 (en) 1998-10-28 2004-04-06 The Procter & Gamble Company Absorbent article with improved feces containment characteristics
US6258076B1 (en) * 1999-05-26 2001-07-10 Confab Services Ag Disposable absorbent article with waist barrier including skin-friendly adhesive
US6489534B1 (en) 2000-04-28 2002-12-03 Kimberly-Clark Worldwide, Inc. Disposable personal articles which conform and adhere
US6918900B2 (en) 2001-10-25 2005-07-19 Paragon Trade Brands, Inc. Absorbent article with friction-inducing substances and methods for preparing same
US7476447B2 (en) 2002-12-31 2009-01-13 Kimberly-Clark Worldwide, Inc. Elastomeric materials
US8246593B2 (en) 2003-07-03 2012-08-21 The Procter & Gamble Company Sanitary napkin for dynamic body fit
US7927322B2 (en) 2006-06-13 2011-04-19 Kimberly-Clark Worldwide, Inc. Body-adhering personal care product
US8251969B2 (en) 2007-08-03 2012-08-28 Kimberly-Clark Worldwide, Inc. Body adhering absorbent article
US8292862B2 (en) 2007-08-03 2012-10-23 Kimberly-Clark Worldwide, Inc. Dynamic fitting body adhering absorbent article
US8672911B2 (en) 2007-08-03 2014-03-18 Kimberly-Clark Worldwide, Inc. Body adhering absorbent article
US8734413B2 (en) 2007-08-03 2014-05-27 Kimberly-Clark Worldwide, Inc. Packaged body adhering absorbent article
US7947027B2 (en) 2007-12-28 2011-05-24 Kimberly-Clark Worldwide, Inc. Body adhering absorbent article
US11147722B2 (en) 2008-11-10 2021-10-19 Kimberly-Clark Worldwide, Inc. Absorbent article with a multifunctional acrylate skin-adhesive composition
US10022468B2 (en) 2009-02-02 2018-07-17 Kimberly-Clark Worldwide, Inc. Absorbent articles containing a multifunctional gel
US8758547B2 (en) 2011-02-08 2014-06-24 Kimberly-Clark Worldwide, Inc. Method of manufacturing a body adhering absorbent article orientated in the cross-machine direction with reduced curl
US8764922B2 (en) 2011-02-08 2014-07-01 Kimberly-Clark Worldwide, Inc. Method of manufacturing a body adhering absorbent article orientated in the machine direction with reduced curl

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Also Published As

Publication number Publication date
CA2275881A1 (fr) 1998-07-02
BR9714844A (pt) 2000-10-17
JP2000505706A (ja) 2000-05-16
KR20000069661A (ko) 2000-11-25
AU5613098A (en) 1998-07-17
EP0850626A1 (fr) 1998-07-01
WO1998027915A1 (fr) 1998-07-02
ID23798A (id) 2000-05-11

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