EP0934927A1 - Procédé et dispositif pour la production d'urée à haute conversion et basse consommation d'énergie - Google Patents

Procédé et dispositif pour la production d'urée à haute conversion et basse consommation d'énergie Download PDF

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Publication number
EP0934927A1
EP0934927A1 EP98200321A EP98200321A EP0934927A1 EP 0934927 A1 EP0934927 A1 EP 0934927A1 EP 98200321 A EP98200321 A EP 98200321A EP 98200321 A EP98200321 A EP 98200321A EP 0934927 A1 EP0934927 A1 EP 0934927A1
Authority
EP
European Patent Office
Prior art keywords
carbamate
urea
aqueous solution
ammonia
carbon dioxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98200321A
Other languages
German (de)
English (en)
Inventor
Giorgio Pagani
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Casale SA
Original Assignee
Urea Casale SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Urea Casale SA filed Critical Urea Casale SA
Priority to EP98200321A priority Critical patent/EP0934927A1/fr
Priority to IDP990027D priority patent/ID21856A/id
Priority to CN99100989A priority patent/CN1228416A/zh
Priority to CA002259872A priority patent/CA2259872A1/fr
Priority to PL99331162A priority patent/PL188569B1/pl
Priority to KR1019990003311A priority patent/KR19990072354A/ko
Priority to BR9900520-4A priority patent/BR9900520A/pt
Priority to MXPA99001236A priority patent/MXPA99001236A/es
Publication of EP0934927A1 publication Critical patent/EP0934927A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/02—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/02—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
    • C07C273/04—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Definitions

  • the present invention relates to a process for urea production.
  • the invention relates to a process for urea production of the type comprising the following steps:
  • the invention also relates to a plant for carrying out the aforesaid process as well as to a method for modernizing an existing urea plant, obtaining thereby a plant according to the invention.
  • modernizing it is understood to mean the on-site modification of a pre-existing plant in order to improve its performance and to obtain, for instance, greater production capacity and/or greater conversion yield, as well as a reduction in energy consumption.
  • the plant for carrying out a process of this type comprises a urea recovery section downstream to a reaction space, to separate the unreacted substances to be recycled from the urea solution.
  • the synthesis reaction in the reaction space is performed at high pressures, generally higher than 200 bar (220-240 bar), and with high NH 3 /CO 2 mole ratios comprised between 3,6-4,0, with a conversion yield ranging from 64% and 70%.
  • the urea synthesis reaction is performed according to these processes at pressures generally comprised between 140-160 bar and with NH 3 /CO 2 molar ratios lower than 3,2, which values are substantially lower than the working values of the processes to which the present invention refers.
  • the technical problem underlying the present invention is accordingly to conceive and provide a process for urea production at high conversion yield, technically simple to carry out and requiring low energy consumption and operating costs.
  • concentrated carbamate in aqueous solution it is understood to mean a carbamate solution having a very low water content (only a few percent points).
  • At least a part of the carbamate and free ammonia in aqueous solution leaving the urea recovery section is advantageously submitted to a partial decomposition treatment that allows to separate unreacted ammonia and carbon dioxide from a solution rich in water and comprising residual carbamate.
  • the unreacted substances to be recycled have a very low water content, and it is therefore possible to drastically limit the amount of water fed to the reaction space, allowing a high conversion yield.
  • the conversion yield achievable thanks to the process according to the invention is not only higher than the conversion yield achievable by the process disclosed in EP-A-0 479 103, but is even higher than the typical conversion yields of processes operating with high NH 3 /CO 2 molar ratios and at pressures higher than 200 bar, described hereinabove with reference to the prior art.
  • At least a part of the carbon dioxide fed to the reaction space is previously utilised as stripping agent during the step of partial decomposition of carbamate and partial separation of free ammonia.
  • this particular utilisation of carbon dioxide to be fed to the reaction space advantageously allows - independently on the working pressure that can be therefore even very high - to improve the step of decomposition of carbamate and separation of free ammonia coming from the urea recovery section, and facilitates consequently the separation of water from the unreacted substances recycled to the reaction space.
  • At least 60% of the carbon dioxide fed to the reaction space is previously utilised as stripping agent during the step of partial decomposition of carbamate and partial separation of free ammonia.
  • the reaction between ammonia and carbon dioxide is advantageously carried out in the reaction space at a pressure comprised between 170 and 250 bar, preferably between 180 and 240 bar.
  • the decomposition and partial separation treatment is preferably carried out at a pressure substantially corresponding to the pressure of the reaction space.
  • the flow comprising residual carbamate in aqueous solution resulting from the treatment of partial decomposition of carbamate and partial separation of free ammonia is advantageously fed to such recovery section.
  • a plant designed to implement the above mentioned urea production process comprising:
  • the plants intended for carrying out the urea production process may be provided either new or by modifying pre-existing plants so as to obtain a production capacity expansion and at the same time improved performance from the energy consumption viewpoint.
  • the present invention accordingly makes available a method for modernizing a urea production plant of the type comprising:
  • urea production plant of the total recycling type, i.e. wherein reagents are recycled to the reaction space.
  • plant 1 comprises a urea synthesis reactor 2 (or reaction space), a recovery section 3 of the urea produced, comprising in turn several apparatuses working at both high and low pressure - which will be described more in detail later on - and a carbamate decomposition and condensation section 4.
  • the urea production process according to the present invention allows to obtain in the urea synthesis reactor 2 a yield comprised between 70% and 78%.
  • An example of operating conditions of the urea synthesis reactor 2 obtainable with the present invention are: NH 3 /CO 2 molar ratio 3,8, H 2 O/CO 2 molar ratio 0,1, conversion yield 75%, pressure 220 bar, temperature 195°C.
  • Figure 1 does not show the vacuum section, which is an integrating part of the urea recovery section 3, and the sections of treatment and finishing of the concentrated urea solution, which are located downstream of section 3, said sections being of a known type and ininfluential for the purposes of the present invention
  • the urea recovery section 3 comprises a carbamate decomposer 5 and a condensation unit 6 at medium pressure (about 18 bar), a carbamate decomposer 7 and a condensation unit 8 at low pressure (about 4 bar), and an ammonia distillation column.
  • Section 4 of carbamate decomposition and condensation comprises in its turn a high pressure (170-250 bar) stripping unit or stripper 10 for the partial decomposition of carbamate and partial separation of free ammonia in aqueous solution coming from the urea recovery section 3, as well as a carbamate decomposer 11 (optional) and a carbamate condenser 12 for the decomposition of a flow comprising residual carbamate in aqueous solution coming from stripper 10 and for the absorption of vapours leaving the latter, respectively.
  • a high pressure (170-250 bar) stripping unit or stripper 10 for the partial decomposition of carbamate and partial separation of free ammonia in aqueous solution coming from the urea recovery section 3, as well as a carbamate decomposer 11 (optional) and a carbamate condenser 12 for the decomposition of a flow comprising residual carbamate in aqueous solution coming from stripper 10 and for the absorption of vapours leaving the latter, respectively.
  • duct 14 From duct 14, a duct - indicated by 15 - branches off to feed a gas flow comprising carbon dioxide to the low pressure carbamate decomposer 7.
  • Carbon dioxide feeding reactor 2 is advantageously fed through ducts 14a and 14b to the stripping unit 10 and to the carbamate condenser 12, respectively.
  • Duct 14b is entirely optional as - according to an embodiment of the invention - all the carbon dioxide to be sent to reactor 2 may be advantageously fed to stripper 10, and is therefore represented in Figure 1 by a broken line.
  • Reactor 2 is connected - at a bottom end and through ducts 16 and 17 - with the carbamate condenser 12, wherefrom a flow comprising concentrated carbamate in aqueous solution comes out, and with the condensation unit 6, wherefrom a flow comprising carbamate and free ammonia in aqueous solution comes out.
  • Reactor 2 is also connected - at the opposite top end and through duct 18 - with the high pressure carbamate decomposer 5, to which a reaction mixture comprising urea, carbamate and free ammonia in aqueous solution is fed.
  • vapours comprising substantially water, ammonia and carbon dioxide obtained in the carbamate decomposer 5 are sent to the respective condensation unit 6 through duct 19, while the resulting urea solution is sent to the second carbamate decomposer 7 through duct 20.
  • the urea solution is further concentrated and sent through duct 21 to the vacuum section, not shown.
  • the vapours obtained by this second decomposition are fed to the respective condensation unit 8 through duct 22.
  • the flow comprising carbamate and free ammonia in aqueous solution obtained in unit 8 is sent to the condensation unit 6 through duct 23, passing through the ammonia distillation column 9, wherefrom it is recycled, together with the flow comprising carbamate and free ammonia in aqueous solution obtained by condensation of the vapours coming from decomposer 5, through duct 17 to reactor 2 and advantageously through duct 24 to the carbamate decomposition and condensation section 4, and more precisely to stripper 10.
  • the flow comprising carbamate and free ammonia in aqueous solution advantageously fed through duct 24 to stripper 10 is submitted to a treatment of partial decomposition of carbamate and partial separation of free ammonia.
  • a flow comprising ammonia and carbon dioxide in vapour phase which is fed through duct 31 to the carbamate condenser 12, and a flow comprising residual carbamate in aqueous solution preferably recycled to the urea recovery section 3.
  • a flow comprising residual carbamate in aqueous solution coming from stripper 10 is suitably fed through duct 32 to the carbamate decomposer 11, obtaining thereby a gas flow comprising CO 2 and NH 3 recycled through ducts 33 and 19 to the condensation unit 6, and a flow comprising very diluted carbamate in aqueous solution fed through duct 34 to the vacuum section, not shown.
  • the flow comprising ammonia and carbon dioxide in vapour phase is advantageously condensed - at least partly - obtaining thereby a flow comprising concentrated carbamate in aqueous solution fed to reactor 2 through duct 16.
  • the high conversion yield obtained in reactor 2 also involves a reduction in the amount of carbamate produced and therefore - advantageously - a lightening of downstream sections, in particular the urea recovery section, which can therefore run in operating conditions much less heavy than design conditions, with ensuing high energy savings.
  • At least a part of the carbamate and free ammonia in aqueous solution obtained in the urea recovery section 3 is submitted (section 4, stripping unit 10) to a treatment of partial decomposition of carbamate and partial separation of free ammonia, obtaining thereby a flow comprising ammonia and carbon dioxide in vapour phase and a flow comprising residual carbamate in aqueous solution.
  • the flow comprising ammonia and carbon dioxide in vapour phase is then submitted (section 4, condenser 12) to an at least partial condensation, obtaining thereby a flow comprising concentrated carbamate in aqueous solution, which is advantageously fed to the reaction space (reactor 2)
  • At least a part of the carbon dioxide fed to the reaction space (reactor 2) is previously utilised as stripping agent during the step of partial decomposition of carbamate and partial separation of free ammonia (section 4, stripping unit 10).
  • the carbamate decomposition and condensation section 4 is advantageously caused to work at the same pressure as that of the reaction space.
  • the plant of Figure 1 may be a new plant or - according to a preferred embodiment of the invention - it may be realised by modernizing a pre-existing urea production plant.
  • the modernizing of a urea production plant of the type comprising a urea synthesis reactor 2 and a recovering section 3 of a reaction mixture comprising urea, carbamate and free ammonia in aqueous solution coming from reactor 2 to separate urea from carbamate and the free ammonia in aqueous solution, is characterised by the steps of:
  • the modernizing method comprises the further step of providing means (14a) for feeding at least a part of the carbon dioxide to be fed to the synthesis reactor (2) to the stripping unit (10).
  • such a method also comprises the step of:

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP98200321A 1998-02-04 1998-02-04 Procédé et dispositif pour la production d'urée à haute conversion et basse consommation d'énergie Withdrawn EP0934927A1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EP98200321A EP0934927A1 (fr) 1998-02-04 1998-02-04 Procédé et dispositif pour la production d'urée à haute conversion et basse consommation d'énergie
IDP990027D ID21856A (id) 1998-02-04 1999-01-14 Proses dan pabrik untuk produksi urea dengan hasil konversi yang tinggi dan pemakaian energi yang rendah
CN99100989A CN1228416A (zh) 1998-02-04 1999-01-21 高转化率低能耗的尿素生产方法和装置
CA002259872A CA2259872A1 (fr) 1998-02-04 1999-01-22 Procede et installation de production d'uree a haut rendement de conversion eta faible consommation d'energie
PL99331162A PL188569B1 (pl) 1998-02-04 1999-02-02 Sposób wytwarzania mocznika i instalacja do wytwarzania mocznika
KR1019990003311A KR19990072354A (ko) 1998-02-04 1999-02-02 고전환율과저에너지소모로요소를제조하는방법및장치
BR9900520-4A BR9900520A (pt) 1998-02-04 1999-02-03 Processo e instalação para produção de uréia com alto rendimento de conversão e baixo consumo de energia.
MXPA99001236A MXPA99001236A (es) 1998-02-04 1999-02-03 Proceso y planta para la produccion de urea con alto rendimiento de conversion y bajo consumo de energia.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP98200321A EP0934927A1 (fr) 1998-02-04 1998-02-04 Procédé et dispositif pour la production d'urée à haute conversion et basse consommation d'énergie

Publications (1)

Publication Number Publication Date
EP0934927A1 true EP0934927A1 (fr) 1999-08-11

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Family Applications (1)

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EP98200321A Withdrawn EP0934927A1 (fr) 1998-02-04 1998-02-04 Procédé et dispositif pour la production d'urée à haute conversion et basse consommation d'énergie

Country Status (8)

Country Link
EP (1) EP0934927A1 (fr)
KR (1) KR19990072354A (fr)
CN (1) CN1228416A (fr)
BR (1) BR9900520A (fr)
CA (1) CA2259872A1 (fr)
ID (1) ID21856A (fr)
MX (1) MXPA99001236A (fr)
PL (1) PL188569B1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9346016B2 (en) 2005-03-09 2016-05-24 Stamicarbon B.V. Process for the preparation of a urea-comprising aqueous stream

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3766865A1 (fr) * 2019-07-18 2021-01-20 Casale Sa Procédé de synthèse de l'urée
EP3896031A1 (fr) * 2020-04-17 2021-10-20 Casale Sa Modernisation d'une installation d'ammoniac-urée

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0624571A1 (fr) * 1993-05-14 1994-11-17 Urea Casale S.A. Procédé et installation pour la fabrication d'urée dans espaces de réaction avec des rendements différents
WO1996020170A1 (fr) * 1994-12-23 1996-07-04 Urea Casale S.A. Technique et installation de production d'uree avec espaces de reaction a rendement differencie

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0624571A1 (fr) * 1993-05-14 1994-11-17 Urea Casale S.A. Procédé et installation pour la fabrication d'urée dans espaces de réaction avec des rendements différents
WO1996020170A1 (fr) * 1994-12-23 1996-07-04 Urea Casale S.A. Technique et installation de production d'uree avec espaces de reaction a rendement differencie

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9346016B2 (en) 2005-03-09 2016-05-24 Stamicarbon B.V. Process for the preparation of a urea-comprising aqueous stream

Also Published As

Publication number Publication date
CA2259872A1 (fr) 1999-08-04
BR9900520A (pt) 2000-05-09
PL188569B1 (pl) 2005-02-28
ID21856A (id) 1999-08-05
MXPA99001236A (es) 2005-04-28
PL331162A1 (en) 1999-08-16
CN1228416A (zh) 1999-09-15
KR19990072354A (ko) 1999-09-27

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