EP0906404A2

EP0906404A2 - Thickening agent for aqueous hydrogen peroxide solutions

Info

Publication number: EP0906404A2
Application number: EP97927126A
Authority: EP
Inventors: Nuria Bonastre; Rafael Pi Subirana
Original assignee: Henkel AG and Co KGaA
Current assignee: BASF Personal Care and Nutrition GmbH
Priority date: 1996-06-13
Filing date: 1997-06-04
Publication date: 1999-04-07
Anticipated expiration: 2017-06-04
Also published as: ES2161468T3; ATE204321T1; WO1997047718A2; DE19623571A1; DE19623571C2; WO1997047718A3; DE59704318D1; EP0906404B1; PT906404E

Abstract

The proposal is for novel thickening agents for aqueous hydrogen peroxide solutions, containing, in relation to the active substance content of the agent, (a) 10 to 90 wt % fatty acid alkanolamides, (b) 5 to 20 wt % alkyl ether sulphates, (c) 0 to 5 wt % alkyl ether phosphates and (d) 0 to 60 wt % alkyl polyglycol ether, with the proviso that the weights add up to 100 wt %. The agents ensure a reliable and permanent viscosity setting and make the inclusion of perfumes easier without the risk of turbidity. 00000

Description

Thickener for aqueous hydrogen peroxide solutions

Field of the Invention

The application relates to thickeners for aqueous hydrogen peroxide solutions, containing fatty acid alkanolamides, alkyl ether sulfates and, if appropriate, alkyl ether phosphates and / or alkyl polyglycol ethers and the use of the mixtures as thickeners for aqueous hydrogen peroxide solutions.

State of the art

In the past, such bleaching agents based on hydrogen peroxide have proven themselves in the areas of hygiene and disinfection, which have a remarkable viscosity and are therefore suitable for the treatment of horizontal as well as inclined and, above all, vertical surfaces. The viscosity of these agents has the effect that the contact time between them and the surfaces to be treated is considerably longer than in the case of commercially available liquid products which flow off rapidly from the surface. In addition, however, there is also a need for low-viscosity, water-like consistency products that run off quickly and completely from the treatment surfaces.

A number of bleaching and cleaning agents are known from the prior art, but they primarily have a higher viscosity. From German Offenlegungsschrift DE-OS 15 67 570 (Henkel), for example, liquid or pasty concentrates containing active oxygen are known, which are obtained by reacting phosphorus pentoxide with low molecular weight alcohols and hydrogen peroxide. From the German patent application DE-A1 42 02 720 (Henkel) formulations for simultaneous desizing, boiling and bleaching of cellulose-containing textile materials are lien known that contain anionic surfactants, ethoxylated fatty alcohols and hydrogen peroxide. However, the agents are unsuitable for cleaning hard surfaces. According to German Offenlegungsschrift DE-A1 44 18 847 (Henkel), viscous bleaching agents can be prepared by adding fatty alcohol polyglycol ethers and ethoxylated phosphoric acid esters to hydrogen peroxide solutions.

Despite the extensive state of the art, which can only be reproduced here as an example, the products on the market are still not completely satisfactory in terms of their performance: The viscosity is often too high and changes during storage, the surfactant component is not sufficiently stable to active oxygen, loosened dirt is repositioned on the surface and makes it appear dull, after all perfumes cannot be incorporated without the risk of undesirable clouding

The object of the invention was then to provide new additives for aqueous bleaching agents based on hydrogen peroxide, with the aid of which the disadvantages described can be reliably overcome

Description of the invention

The invention relates to thickeners for aqueous hydrogen peroxide solutions containing - based on the active substance content of the agents -

(a) 10 to 90, preferably 40 to 80% by weight of fatty acid alkanolamides,

(b) 5 to 20, preferably 8 to 16% by weight of alkyl ether sulfates,

(c) 0 to 5, preferably 1 to 4% by weight of alkyl ether phosphates and

(d) 0 to 60, preferably 4 to 50% by weight alkyl polyglycol ether

with the proviso that the weight details add up to 100% by weight

Surprisingly, it has been found that the agents give aqueous bleaches based on hydrogen peroxide a sufficiently high and stable viscosity and thereby enable the incorporation of perfumes without clouding. The surfactant component proves to be stable against active oxygen compounds and reliably prevents redeposition of dirt particles once they have been dissolved. Fatty acid alkanolamides

Fatty acid alkanolamides which form component (a) follow the formula (I),

R ²

IR ¹ CON (CH ₂ ) nOH (I)

in which R ¹ CO represents an aliphatic, saturated or unsaturated acyl radical having 6 to 22 carbon atoms, R ^{2 represents} hydrogen or an optionally hydroxyl-substituted alkyl radical having 1 to 4 carbon atoms and n represents numbers from 2 to 4. The Alkanoiamide, acidic, for example, condensation products of caproic acid, caprylic acid, 2-ethylhexanoic acid, Capπnsäure, Launnsäure, Isotridecansaure, myristic acid, palmitic acid, Palmolemsaure, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, Linoiensaure, Elaeosteannsaure, arachic acid, gadoleic, ßehensaure and Represent erucic acid and its technical mixtures with mono- or diethanoiamine. Coconut or stearic acid fatty acid aikanolamides are preferably used.

Alkyl ether sulfates

Alkyl ether sulfates ("ether sulfates"), which form component (b), are known anionic surfactants which are produced on an industrial scale by SO ₃ - or chlorosulfonic acid (CSA) sulfation of alkyl polyglycol ethers and subsequent neutralization. For the purposes of the invention, ether sulfates are suitable which follow the formula (II)

R30- (CH ₂ CH2θ) mS0 ₃ X (II)

in R ³ for a linear or branched alkyl and / or alkenyl radical having 6 to 22 carbon atoms, n for numbers from 1 to 10 and X for an alkali and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium stands. Typical examples are the sulfates of addition products with an average of 1 to 10 and in particular 2 to 5 moles of ethylene oxide with capron alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, oleyl alcohol, isostyl alcohol, isostyl alcohol hol, petroselmyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures, in the form of their sodium and / or magnesium salts. The ether sulfates can be either a conventional or a restricted homolog distribution exhibit. It is particularly preferred to use ether sulfates based on adducts of on average 2 to 3 mol ethylene oxide with technical C12 / 14 or C12 / 18 coconut oil alcohol fractions in the form of their sodium and / or magnesium salts.

Alkyl ether phosphates

Alkyl ether phosphates which form component (c) are also known anionic surfactants which are usually prepared by reacting ethoxylated fatty alcohols with phosphorus pentoxide. Depending on the use ratio of the components, technical mixtures are obtained which predominantly contain mono- and dialkyl esters, in addition to triesters, phosphoric acid and unreacted alcohol. Overviews on this topic are available from R.S. Cooper and G.lmokawa in J.Am.Oil.Chem.Soc. 41, 337 (1964) and 55, 839 (1978), H.Distler in Tenside Detergents 12, 263 (1975) and O'Lennick in Soap, Cosm.Chem.Spec. 7, 26 (1986). The alkyl ether phosphates preferably follow the formula (III)

OX

IR ⁴ (OCH ₂ CH ₂ ) pO-P-OR5 (III)

II 0

in which R ^{4 is} a linear or branched alkyl radical having 6 to 12 carbon atoms, R ^{5 is} a group R ⁴ (OCH2CH2) _P or X, p is a number from 1 to 5 and X is hydrogen, an alkali and / or alkaline earth metal . Typical examples of ethoxylated phosphoric acid esters which are considered as component (c) in the sense of the invention are mono- and / or dialkyl esters based on adducts of 1 to 10, preferably 2 to 8, moles of ethylene oxide with capronalcohol, caprylic alcohol , 2-ethylhexyl alcohol, capric alcohol and / or lauryl alcohol. The degree of esterification can be 1 to 2.5 and preferably 1.3 to 2.1. Particular preference is given to ethoxylated phosphoric acid esters of the formula (III) in which R ^{4 is} a 2-ethylhexyl radical, R ^{5 is} X, p is a number from 1 to 3 and X is hydrogen. The use of alkyl ether phosphates is particularly advantageous for the production of opacifying agents. Alkyl polyglycol ether

Finally, the thickeners can contain, as optional component (d), alkyl polyglycol ethers of the formula (IV)

R <O (CH ₂ CH ₂ 0) _q H (IV)

in which R ^{6 represents} an alkyl and / or alkenyl radical having 6 to 22 carbon atoms and q represents numbers from 1 to 10. Typical examples of suitable nonionic surfactants of the formula (IV) are addition products of average 1 to 10 and in particular 5 to 8 moles of ethylene oxide with 1 mole of capron alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol and cetyl alcohol , Palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures. Addition products of 5 to 8 moles of ethylene oxide with fatty alcohols having 12 to 18 and in particular 16 to 18 carbon atoms are preferably used, which can have a conventional, but preferably a narrow, homolog distribution. The use of component (d) is of particular advantage with regard to the incorporation of perfumes and the peroxide stability.

Industrial applicability

The agents according to the invention impart a sufficiently high and stable viscosity to aqueous bleaching agents based on peroxide. The agents are preferably in the form of aqueous preparations which have a non-aqueous content of 10 to 50 and preferably 20 to 40% by weight. Another object of the invention relates to their use as thickeners for aqueous hydrogen peroxide solutions. The aqueous hydrogen peroxide solutions are preferably aqueous bleaches on the market which accordingly generally have an active substance content of 1 to 10 and preferably 5 to 8% by weight. The agents are usually used in amounts of 1 to 5 and preferably 2 to 4% by weight, based on their non-aqueous content and the aqueous hydrogen peroxide solutions. Auxiliaries and additives

The aqueous hydrogen peroxide solutions may contain, as auxiliaries and additives, further peroxide-stable surfactants or hydrotropes, such as, for example, alkyl sulfates, alkyl sulfonates, alkylbenzenesulfonates, xylene sulfonates, sarcosinates, taurides, isethionates, sulfosuccinates, ether carboxylic acids, betaines, sugar esters, amine oxides and alkyl oligoglyides. The sum of these additional surfactants preferably makes up at most 10% by weight of the total amount of surfactants in the formulation. In addition, the agents can contain peroxide-stable fragrances, optical brighteners, dyes and pigments in a total amount of 0.01 to 0.5% by weight, based on the agents. The fragrances known as peroxide-resistant include, for example, monocyclic and bicyclic monoterpene alcohols and their esters with acetic or propionic acid (for example isobomeal, dihydroterpene oil, isobornyl acetate, dihydroterpenyl acetate). The optical brighteners can be, for example, the potassium salt of 4,4'-bis (1,2,3-triazolyl) - (2 -) - stilbin-2,2-sulfonic acid, which is sold under the brand name Phorwite® BHC 766 is distributed. Possible color pigments include green chlorophthalocyanines (Pigmosol® Green, Hostaphine® Green) or yellow Solar Yellow BG 300 (Sandoz). The agents according to the invention are produced by stirring. If necessary, the product obtained can be decanted or filtered to remove foreign bodies and / or agglomerates.

Examples

An aqueous hydrogen peroxide solution with a peroxide content of 7% by weight and a content of 0.1 perfume (isoborneol) was mixed with 3% by weight of the thickeners R1 to R3 of the comparison products R4 and R5 in the form of 30% by weight solutions transferred. The viscosity of the solutions was determined using the Brookfield method in an RVT viscometer (20 ° C., 10 rpm, spindle 2). The peroxide content and the visual appearance were determined after storage for 4 weeks. The results are summarized in Table 1 (quantitative data relate to the active substance content and are understood as% by weight).

Table 1 Viscosity and storage stability

^* ) Crafol® AP-60

Claims

claims

1. Thickener for aqueous hydrogen peroxide solutions, containing - based on the active substance content of the agent -

(a) 10 to 90% by weight of fatty acid alkanolamides,

(b) 5 to 20% by weight of alkyl ether sulfates,

(c) 0 to 5% by weight of alkyl ether phosphates and

(d) 0 to 60% by weight alkyl polyglycol ether

with the proviso that the weight details add up to 100% by weight.

2 compositions according to claim 1, characterized in that they contain fatty acid alkanolamides of the formula (I),

R ²

I.

RiCON (CH ₂ ) "OH (I)

in which R ¹ CO represents an aliphatic, saturated or unsaturated acyl radical having 6 to 22 carbon atoms, R ^{2 represents} hydrogen or an optionally hydroxyl-substituted alkyl radical having 1 to 4 carbon atoms and n represents numbers from 2 to 4.

3 compositions according to claims 1 and 2, characterized in that they contain alkyl ether sulfates of the formula (II),

R ³ 0- (CH ₂ CH ₂ 0) mSθ3X (II)

in which R ^{3 is} a linear or branched alkyl and / or alkenyl radical having 6 to 22 carbon atoms, n is a number from 1 to 10 and X is an alkali metal and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium

4. Composition according to claims 1 to 3, characterized in that they contain alkyl ether phosphates of the formula (III),

OX

I.

R * (0CH ₂ CH ₂ ) _P 0.P.0R5 (III)

in which R ^{4 is} a linear or branched alkyl radical having 6 to 12 carbon atoms, R ^{5 is} a group R ⁴ (OCH2CH2) _P or X, p is a number from 1 to 5 and X is hydrogen, an alkali and / or alkaline earth metal .

5. Compositions according to claims 1 to 4, characterized in that they contain alkyl polyglycol ethers of the formula (IV),

R <O (CH ₂ CH ₂ 0) _q H (IV)

in which R ^{6 represents} an alkyl and / or alkenyl radical having 6 to 22 carbon atoms and q represents numbers from I to 10.

6. Use of agents according to claims 1 to 5 as thickeners for aqueous hydrogen peroxide solutions.

7. Use according to claim 6, characterized in that the agents are added to aqueous hydrogen peroxide solutions with an active substance content of 1 to 10% by weight.

8. Use according to claims 6 and 7, characterized in that the agents are used in amounts of 1 to 5% by weight, based on the aqueous hydrogen peroxide solutions.