EP0860215A1 - Continuous metal manufacturing method and apparatus therefor - Google Patents

Continuous metal manufacturing method and apparatus therefor Download PDF

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Publication number
EP0860215A1
EP0860215A1 EP98301246A EP98301246A EP0860215A1 EP 0860215 A1 EP0860215 A1 EP 0860215A1 EP 98301246 A EP98301246 A EP 98301246A EP 98301246 A EP98301246 A EP 98301246A EP 0860215 A1 EP0860215 A1 EP 0860215A1
Authority
EP
European Patent Office
Prior art keywords
rolling
stage
state
steel
strip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98301246A
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German (de)
French (fr)
Inventor
Mike Clark
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kvaerner Clecim Continuous Casting Ltd
Kvaerner Metals Continuous Casting Ltd
Original Assignee
Kvaerner Clecim Continuous Casting Ltd
Kvaerner Metals Continuous Casting Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9703651.1A external-priority patent/GB9703651D0/en
Application filed by Kvaerner Clecim Continuous Casting Ltd, Kvaerner Metals Continuous Casting Ltd filed Critical Kvaerner Clecim Continuous Casting Ltd
Publication of EP0860215A1 publication Critical patent/EP0860215A1/en
Withdrawn legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/46Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
    • B21B1/463Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting in a continuous process, i.e. the cast not being cut before rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • B21B1/24Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
    • B21B1/26Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process by hot-rolling, e.g. Steckel hot mill
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
    • C21D8/1216Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
    • C21D8/1227Warm rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B13/00Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories
    • B21B13/02Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories with axes of rolls arranged horizontally
    • B21B13/023Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories with axes of rolls arranged horizontally the axis of the rolls being other than perpendicular to the direction of movement of the product, e.g. cross-rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B2201/00Special rolling modes
    • B21B2201/02Austenitic rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B2201/00Special rolling modes
    • B21B2201/04Ferritic rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/16Control of thickness, width, diameter or other transverse dimensions
    • B21B37/24Automatic variation of thickness according to a predetermined programme

Definitions

  • the present invention relates to a continuous metal manufacturing method and apparatus therefor and in particular of steel.
  • US-A-5018569 discloses a method of measuring and adjusting the roll speeds of rolls in a continuous casting line in order to monitor the onset of solidification to ensure that the point of solidification is maintained at essentially the same position. Whilst this is useful in maintaining the quality of the finished product it does not assist in control of the subsequent rolling of the cast slab.
  • EP-A-0666122 discloses a method of hot rolling of discrete slabs and specifically that the stock is re-heated between the first and second rolling stages. There is a high risk of cobbling with this process. Also with this method rolling in the austenitic phase only is provided for there is no provision for rolling in the ferritic phase which has to be carried out in a separate operation.
  • WO 92/00815 discloses a continuous casting and rolling process for the production of steel strip. With this process hot rolling is followed by heating then further hot rolling then cooling and finally ferritic rolling. Therefore when it is not required to roll ferritically the last stands are redundant.
  • An objective of the invention is to remove the need for a buffer stock and reduce the amount of material in any particular production run.
  • a consequential objective of the invention is to reduce the assets tied up in the casting and rolling processes and decrease the minimum optimum order size and to increase the flexibility of production and to reduce processing time.
  • a method for the manufacture of steel, in the form of rod, bar or strip, from the molten metal to the final rolled product comprising a casting process and a rolling process, wherein the rolling process includes a first rolling stage followed by a second rolling stage, the first and second rolling stages each comprising between one and six rolling stands, wherein the casting process and the rolling process are continuous and the flow rate of the molten metal into the casting process is balanced with the flow rate of the strip throughout the rolling process, and wherein a temperature controlling stage is arranged between the first and second rolling stages, characterised in that, the temperature controlling stage comprises a first state in which it operates to prepare the steel for rolling in the subsequent second rolling stage in the austenitic phase, and an alternative second state in which the temperature controlling stage operates to prepare the steel for the subsequent rolling stage in the ferritic phase, said temperature controlling stage being selectively operable between the first state and the second state, such that the steel passes through the same subsequent second rolling stage, correspondingly in the austenitic phase or alternatively the ferr
  • the temperature controlling means comprises a heat retaining means which in the first state encloses the steel to retain heat therein and is openable to form the second state in which the steel is exposed to the surrounding cooling air.
  • the temperature controlling means comprises a heat providing or retaining means and a separate heat removing or cooling means.
  • the heat providing or retaining means and heat removing means are arranged in parallel, and in the first state, the heat providing or retaining means is arranged in-line with first and second rolling stages and the heat removing means are arranged off-line, and in the second state the heat removing means are arranged in-line with the first and second rolling stages and the heat providing or retaining means is arranged off-line.
  • the heat providing or retaining means and heat removing means are arranged in series in-line with each other, and in the first state, the heat providing or retaining means is switched to an operating state and the heat removing means is switched to an off state, and in the second state the heat removing means is switched to an on state and the heat providing or retaining means is switched to an off state.
  • the temperature controlling stage preferably includes a cooling stage which is preferably provided by forced cooling, such as by water cooling.
  • the temperature controlling stage preferably includes a heating stage which may be by induction heating.
  • the casting speed is of the order of 6 metres/minute with a slab thickness of 70 mm and a corresponding range of final thin gauge strip from 0.75 mm to 5 mm the cast slab thickness is in the range of 55 to 85 mm and the continuous casting slab speed is in the range of 4.8 to 7.2 metres/minute.
  • the steel is preferably maintained with a flow rate product of at least 0.315 metres 2 /minute.
  • the gauge and shape of the strip may be changed continuously without interruption to the combined casting and rolling process, by controlling the roll gaps and the speed of the whole casting and rolling process in a synchronous way, at least one of the first and second rolling stages comprising at least one rolling stand comprising at least one dynamic shape actuated shell roll.
  • an apparatus for the manufacture of steel, in the form of rod, bar or strip, from the molten metal to the final rolled product comprising a casting stage and first and second rolling stages, the first and second rolling stages each comprising between one and six rolling stands, wherein the casting stage and the rolling stages are continuous and the flow rate of the molten metal into the casting stage is balanced with the flow rate of the strip throughout the rolling stages, and wherein a temperature controlling stage is arranged between the first and second rolling stages, characterised in that, the temperature controlling stage comprises a first state in which it operates to prepare the steel for rolling in the subsequent second rolling stage in the austenitic phase, and an alternative second state in which the temperature controlling stage operates to prepare the steel for the subsequent rolling stage in the ferritic phase, said temperature controlling stage being selectively operable between the first state and the second state, such that the steel passes through the same subsequent second rolling stage, correspondingly in the austenitic phase or alternatively the ferritic phase.
  • FIG. 1 shows one embodiment of the apparatus which comprises a casting process 2 and a rolling process 3 for the production of steel strip.
  • Molten steel enters the continuous casting process stage 2 where it solidifies.
  • a continuous slab 5 is formed with a slab thickness starting at 90 mm and reducing to 70 mm by the stage where the casting or solidification process is complete.
  • the continuous slab 5 is then guided to a descaling section 8 before going on to a first rolling stand 10a of the rolling process 4.
  • the continuous slab continues through the second, third and fourth stands 10a, 10b, 10c of the rolling process 4 resulting in a reduction in the thickness of the slab to 2 mm.
  • This 2 mm thickness at this stage is shown for a particular example of a required final gauge of strip.
  • the thickness of the strip could be as high as 5 mm depending on the desired final gauge.
  • the slab 5 we shall refer to the slab 5 as strip 6 because this is a more accurate description of the steel with now much reduced thickness dimensions.
  • the velocity of the slab/strip 5/6 has correspondingly increased from 0. 1 m/s to 3.5 m/s.
  • the strip 6 then enters a re-heating and homogenisation stage 11b to restore the strip to the desired temperature for the subsequent rolling operations and in particular the edges of the strip which will have cooled down much more than the centre during the first rolling stage 10.
  • This restores or maintains the steel of the strip in the austenitic phase to avoid the phase change to the ferritic phase.
  • This enables further rolling to take place in the austenitic phase.
  • the volume changes associated with the phase change from austenitic to ferritic prevent satisfactory rolling from taking place during the phase change, and the metallurgical properties of the resulting strip would not be of the required specification.
  • the heating stage includes an electrical induction heater.
  • the strip 6 passes through a second descaling stage 12 before proceeding to two further rolling stands 13a, 13b and has then achieved the desired thickness of 0.75 mm.
  • the velocity of the strip has correspondingly increased to 9.3 m/s.
  • the final thickness again could be as high as 5 mm according to the required final product specification and the fmal velocity would be correspondingly lower.
  • the strip then passes through a cooling section 14 which in this embodiment is merely an extended distance between the last rolling stage 13 and the coiling stage 15. This distance in this case is 50 metres. Again this distance may be varied according to the requirements of any particular product specification within the scope of the invention.
  • the strip then meets the final coiling stage 15 where the strip is coiled into conveniently sized coils.
  • This coiling station preferably includes a cutting stage as well as an automatic means of re-starting a new coil.
  • the re-heating and homogenisation stage 11b is replaced with an additional cooling means 11a which actually speeds up the conversion from the austenitic. phase to the ferritic phase so that the conversion to the ferritic phase is essentially complete before the strip reaches subsequent rolling stands.
  • the final rolling stages take place with the strip in the ferritic phase.
  • any rolling of the strip whilst the conversion of the steel strip from the austenitic phase to the ferritic phase is taking place is avoided. It may be sufficient to just turn off the re-heater 9 to achieve the required cooling to convert the steel strip to the ferritic phase without any need for additional cooling means.
  • the essence of the invention is the two stage rolling process in which the first and second rolling stages are separated to ensure that either the steel is maintained in the austenitic phase before the second stage by re-heating or that the steel is converted to the ferritic phase before the second rolling stage if necessary by forced cooling.
  • the first rolling stage has four rolling stands and the second rolling stage has two rolling stands, the first rolling stage could have between two and four rolling stands and the second rolling stage could have between one and three rolling stands.
  • a slab shearing device is incorporated at the exit of the caster to divide the strip in the event of certain delays or disturbances in the upstream or downstream process.
  • a buffer is created which may alleviate the need to stop the caster and therefore moderating the extent of production loss due to the delay or disturbance of the rolling stage.
  • the shearing means is arranged to operate intermittently only since such shearing will only be required in the event of delay or disturbances in the process.
  • the shearing means is preferably a mechanical shearing device.
  • the specific thickness, corresponding velocity and the length are shown for each of the stages in figure 4. All these values will vary according to the type of steel produced and in particular the desired size of the finished strip.
  • the required mass flow of the cast material can be used to define the as cast slab thickness as well as the as cast slab speed.
  • Figure 2 shows how this can be done.
  • the mass flow curve A of the as cast slab is plotted as a product of the slab speed and the slab thickness which are the respective axes.
  • the horizontal line B is a simplified representation of the upper limit of the as cast slab thickness for a given number of rolling mill passes.
  • the vertical line C is a simplified representation of the upper limit for the as cast slab speed which is determined by operational criteria of the casting process.
  • the desired cast speed and thickness can be chosen from the area to the right and above curve A within the limits of lines B and C. Within these limits it is desirable, when in the steady state, to maximise the throughput and therefore be as close as possible to the cross over of lines B and C.
  • the flow rate will be reduced from the maximum due, for example, to changeovers in various wear components of the casting process, such as the submerged entry nozzles, and it is necessary to ensure that none of these events cause the flow rate to be reduced to such an extent that either the cast velocity or the product thickness falls below curve A on figure 2.
  • Band B shows the preferred range for optimum finished quality, additionally taking into account other factors such as the optimum wear on the components in the casting process having an impact on the overall costs of the process.
  • Line D shows a thickness reduction from 50 to 0.7
  • line E from 60 to 0.7
  • line F from 70 to 0.7
  • line G from 80 to 0.7
  • line H from 90 to 0.7
  • line J from 100 to 0.7
  • line K from 110 to 0.7
  • the final desired thickness in this example is 0.7 mm.
  • the optimum casting speed should be of the order of 6 metres/minute with a slab thickness of 70 mm. Satisfactory results can be achieved for a corresponding range of final thin gauge strip from 0.75 mm to 5 mm with a cast slab thickness in the range of 55 to 85 mm and a continuous casting slab speed of 4.8 to 7.2 metres/minute.
  • the critical parameters may be simplified in the flow rate product which is the product of the thickness and the speed. This flow rate is itself a critical parameter and according to the invention it has been determined that this should be at least 0.315 metres 2 /minute. This linear flow rate lower limit can be applied for any width of strip.
  • molten steel is formed into the final finished strip by means of the combined casting process stage 2, a first re-heating and homogenisation furnace 3, a rolling process stage 4 and a final coiling stage 5.
  • the strand length then enters the re-heating and homogenisation furnace which is preferably a tunnel furnace 3.
  • the purpose of the tunnel furnace is to ensure that the strand is at the required temperature across the whole profile of the strand for the subsequent rolling operation.
  • the required temperature of the strand depends therefore on the further processing requirements of the final strip and thus additional heating may be required as well as maintenance of the desired temperature by means soaking requiring the addition of heat or possibly merely by heat insulation.
  • a second continuous cast strand could be introduced from a separate casting unit so that the generally slower throughput of the casting unit can be balanced with the generally higher throughput of the rolling process so that the throughput capacity of the rolling process is more fully utilised.
  • the second continuous cast strand can be switched into the line when the first casting line is paused.
  • the next stage of the strip-making apparatus is a descaling stage 8, shown on fig. 4, 5.
  • An edging stage (not shown) may optionally be provided at this stage before the rolling operation.
  • the strand now enters the rolling process stage 4 which in this embodiment includes a first rolling stage 10 which in this embodiment includes four rolling stands 10 and a second rolling stage 13 which in this embodiment includes two rolling stands separated by a temperature controlling stage 11 between them.
  • a further scale suppression stage or de-scaling unit 12 is also provided between them.
  • the temperature controlling stage 11 comprises both a reheating/homogenisation function 11b or alternatively a cooling function 11a.
  • this stage is required to be a cooling stage 11a which is required for certain types of steel strip to allow the transformation of the steel from the austenitic phase to the ferritic phase so that the transformation takes place before further rolling rather than during subsequent rolling.
  • the cooling unit 11a and the re-heating /homogenisation unit 11b of the temperature controlling stage are arranged side by side so that desired unit for the function that is required for a particular subsequent rolling operation.
  • the cooling unit 11a is arranged to line with the path of the strip.
  • the cooling unit 11a is moved sideways out off line and the re-heating/homogenisation unit is moved sideways into line with the path of the strip.
  • Rolling stage 13 is the finishing rolling stage with, in this embodiment, two rolling stands, although more stages may be required. Also the first rolling stage could have an alternative number of stands typically having from two to six stands. Preferably low inertia hydraulic loopers may be provided (not shown) and also optional scale suppression between each stand.
  • the rolled strip is then fed to a run out table 14 which may also be provided with optional cooling 14a, in addition to normal air cooling.
  • the coiling stage may include a first pinch roll which is provided in front of a shear which is followed by a separate optional pinch roll and then the coiling stage, all of which enable the desired final strip lengths to be cut and coiled whilst being continuously fed from the mill.
  • the apparatus includes a control system with means for measuring the speed of the strip and the strands, as well as the profile, shape, thickness and width of the strip and also the lateral position of the strip.
  • the control system is also linked to temperature measuring sensors in numerous places along the whole apparatus as well as tension measurement in the rolling process.
  • the control system is linked to an actuating system which varies all of these parameters.
  • the speed and tension of the strip is controlled by the roll speeds, and the profile, shape, gauge, width and lateral alignment is controlled by the mould, the roll gap, actuating means such as dynamic shape rolls (DRS) rolls and by guide rolls.
  • the temperature is adjusted by the heating means in the tunnel furnace as well as cooling at the casting unit and/or by temperature modifications at the re-heating/homogenisation/cooling stage 11 and/or at each or some of the rolling stands.
  • the gauge of the strip may be changed during the rolling process by controlling the roll gaps and the speed of the whole casting and rolling process in a synchronous way.
  • each strand As each strand enters the rolling process it has to be threaded through the rolling stands and this occurs at a threading speed which is lower than the desired final rolling speed.
  • This lower threading speed is equivalent to the speed as is presently used in the conventional rolling of strip from slabs or strand lengths rolled from cast slabs but at the highest possible practical speed or this conventional rolling.
  • the speed is increased significantly and tension can be induced in the strip.
  • the strand is very long, compared to conventional single cast slab strands, and rolling can thus take place at this higher speed in conditions which are very near steady state conditions.
  • the temperature of the strip during rolling is higher than during threading or during rolling of conventional cast slab lengths. This allows thinner gauges to be produced.
  • edge guidance is provided by roll tilting which is itself based on measurements of the lateral position of the strip.
  • the width/thickness ratio is higher and it is more difficult to achieve good flatness quality.
  • cooling unit 11a arranged in-line with the re-heating/homogenisation unit 11b.
  • the cooling unit 11a is activated and the re-heat/homogenisation unit 11b is de-activated.
  • the cooling unit 11a is de-activated and the re-heating/homogenisation unit 11b is activated and the austenitic rolling can then occur through the same rolling stage 13.
  • cooling stage 11a is provided by allowing the strip to pass through a sufficient distance to permit cooling to take place by air circulation and radiation.
  • the re-heating unit is of course de-activated but also has the tops of the unit raised to permit cooling by air circulation through the heating unit in the cooling mode. Cooling could be provided by forced air or nitrogen flow cooling in the re-heater or in the extended distance or both.

Abstract

The invention relates to a method for the manufacture of steel, in the form of rod, bar or strip, from the molten metal to the final rolled product comprising a casting (2) process and a rolling process coupled together with a balanced mass flow rate, wherein the rolling process includes a first rolling stage (10A,10B,10C,10D) followed by a second rolling stage (13), and wherein a temperature controlling stage is arranged between the first and second rolling stages, which comprises a first state in which it operates to prepare the steel for rolling in the austenitic phase, and an alternative second state in which the temperature controlling stage operates to prepare the steel for rolling in the ferritic phase, said temperature controlling stage being selectively operable between the first state and the second state, such that the steel passes through the same subsequent second rolling stage, correspondingly in the austenitic phase or alternatively the ferritic phase. The temperature controlling means may comprises a heat retaining means which, in the first state encloses the steel to retain heat therein, and is openable to form the second state, in which the steel is exposed to the surrounding cooling air. Alternatively, it may comprises a heat providing or retaining means (11b) and a separate heat removing or cooling means (11a) arranged either in parallel with the selected temperature control means, being arranged in-line or in series, on-line.

Description

The present invention relates to a continuous metal manufacturing method and apparatus therefor and in particular of steel.
Conventionally steel strip, rod or bar has been made by casting discrete slabs of steel in the foundry or steel making plant and transferring the slabs to a rolling mill where they are progressively rolled in a series of rolling mill stages or stands. The slabs will typically be re-heated before the rolling commences. The slab may be passed back and forth through a first rolling stand before the required reduction in thickness is achieved before proceeding to the next rolling stand. As the slab is progressively rolled its section is reduced and its length increased and in the later rolling stands the slab becomes a long strip and will enter the subsequent rolling stand before leaving the previous stage. The speeds of these rolling stands will therefore have to be matched. A degree of looping of the strip between the stages is conveniently permitted in order that there is some tolerance in the matching of the speeds of the respective stages. For strip, the final strip of the desired thickness and width is coiled at a coiling stage and each coil will correspond to the respective slab from which it was made.
With the recent development of continuous casting, conventionally the casting and rolling operations have continued to be separate discontinuous processes. This is convenient because the processing speeds for the casting and rolling processes are different. The output of a rolling mill is typically faster than the output of the casting process. Also down time for the rolling mill is usually much more frequent than that for the casting process and the caster machine is generally able to continue operating for a larger number of producing hours per year than a rolling mill. These differences in rates are typically managed by the holding of a small buffer stock between the caster and the mill. This buffer stock is part of the total amount of work in progress which contributes to the assets tied up in the process. It also adds to the total amount of material tied up in a particular order for a particular size and type of material strip, and also requires significant energy input to maintain the slabs at the required temperature for rolling.
US-A-5018569 discloses a method of measuring and adjusting the roll speeds of rolls in a continuous casting line in order to monitor the onset of solidification to ensure that the point of solidification is maintained at essentially the same position. Whilst this is useful in maintaining the quality of the finished product it does not assist in control of the subsequent rolling of the cast slab.
EP-A-0666122 discloses a method of hot rolling of discrete slabs and specifically that the stock is re-heated between the first and second rolling stages. There is a high risk of cobbling with this process. Also with this method rolling in the austenitic phase only is provided for there is no provision for rolling in the ferritic phase which has to be carried out in a separate operation.
WO 92/00815 discloses a continuous casting and rolling process for the production of steel strip. With this process hot rolling is followed by heating then further hot rolling then cooling and finally ferritic rolling. Therefore when it is not required to roll ferritically the last stands are redundant.
It is an objective of the invention to provide a method of continuously coupled casting and rolling of steel strip enabling rolling in the austenitic phases as well as the ferritic phase with the minimum number of rolling stands and minimum line length.
It is an objective of the invention to provide a method of the continuous coupled casting arid rolling of steel strip, wherein the flow of material through the rolling mill is coupled with the flow from the casting machine so that the combined process is continuous. An objective of the invention is to remove the need for a buffer stock and reduce the amount of material in any particular production run. A consequential objective of the invention is to reduce the assets tied up in the casting and rolling processes and decrease the minimum optimum order size and to increase the flexibility of production and to reduce processing time.
It is also an objective of the invention to provide an apparatus and a method of continuous coupled casting and rolling or strip, in particular of thin gauge metal strip, which has a low energy consumption.
According to the invention there is provided a method for the manufacture of steel, in the form of rod, bar or strip, from the molten metal to the final rolled product comprising a casting process and a rolling process, wherein the rolling process includes a first rolling stage followed by a second rolling stage, the first and second rolling stages each comprising between one and six rolling stands, wherein the casting process and the rolling process are continuous and the flow rate of the molten metal into the casting process is balanced with the flow rate of the strip throughout the rolling process, and wherein a temperature controlling stage is arranged between the first and second rolling stages, characterised in that, the temperature controlling stage comprises a first state in which it operates to prepare the steel for rolling in the subsequent second rolling stage in the austenitic phase, and an alternative second state in which the temperature controlling stage operates to prepare the steel for the subsequent rolling stage in the ferritic phase, said temperature controlling stage being selectively operable between the first state and the second state, such that the steel passes through the same subsequent second rolling stage, correspondingly in the austenitic phase or alternatively the ferritic phase.
Preferably the temperature controlling means comprises a heat retaining means which in the first state encloses the steel to retain heat therein and is openable to form the second state in which the steel is exposed to the surrounding cooling air.
Alternatively, the temperature controlling means comprises a heat providing or retaining means and a separate heat removing or cooling means. Preferably the heat providing or retaining means and heat removing means are arranged in parallel, and in the first state, the heat providing or retaining means is arranged in-line with first and second rolling stages and the heat removing means are arranged off-line, and in the second state the heat removing means are arranged in-line with the first and second rolling stages and the heat providing or retaining means is arranged off-line. Alternatively, the heat providing or retaining means and heat removing means are arranged in series in-line with each other, and in the first state, the heat providing or retaining means is switched to an operating state and the heat removing means is switched to an off state, and in the second state the heat removing means is switched to an on state and the heat providing or retaining means is switched to an off state.
The temperature controlling stage preferably includes a cooling stage which is preferably provided by forced cooling, such as by water cooling.
The temperature controlling stage preferably includes a heating stage which may be by induction heating.
Preferably the casting speed is of the order of 6 metres/minute with a slab thickness of 70 mm and a corresponding range of final thin gauge strip from 0.75 mm to 5 mm the cast slab thickness is in the range of 55 to 85 mm and the continuous casting slab speed is in the range of 4.8 to 7.2 metres/minute.
The steel is preferably maintained with a flow rate product of at least 0.315 metres2/minute.
The gauge and shape of the strip may be changed continuously without interruption to the combined casting and rolling process, by controlling the roll gaps and the speed of the whole casting and rolling process in a synchronous way, at least one of the first and second rolling stages comprising at least one rolling stand comprising at least one dynamic shape actuated shell roll.
According to the invention there is provided an apparatus for the manufacture of steel, in the form of rod, bar or strip, from the molten metal to the final rolled product comprising a casting stage and first and second rolling stages, the first and second rolling stages each comprising between one and six rolling stands, wherein the casting stage and the rolling stages are continuous and the flow rate of the molten metal into the casting stage is balanced with the flow rate of the strip throughout the rolling stages, and wherein a temperature controlling stage is arranged between the first and second rolling stages, characterised in that, the temperature controlling stage comprises a first state in which it operates to prepare the steel for rolling in the subsequent second rolling stage in the austenitic phase, and an alternative second state in which the temperature controlling stage operates to prepare the steel for the subsequent rolling stage in the ferritic phase, said temperature controlling stage being selectively operable between the first state and the second state, such that the steel passes through the same subsequent second rolling stage, correspondingly in the austenitic phase or alternatively the ferritic phase.
There now follows a more detailed description of a specific embodiment of the method and apparatus according to the invention with the aid of the attached drawings in which:
  • Fig. 1 is a plan view of the stages of the apparatus according to one embodiment of the invention,
  • Fig. 2 is a graph of the as cast product thickness against the as cast product velocity,
  • Fig. 3 is a graph of the casting speed against the finishing rolling mill speed,
  • Fig. 4 is a side view of the apparatus of a further embodiment of the invention shown in schematic form in re-heating mode including the corresponding parameters of the strip for each stage,
  • Fig. 5 is a side view of the apparatus of a further embodiment of the invention in cooling mode,
  • Fig. 6 is a side view of the apparatus of a further embodiment of the invention,
  • Fig. 7 is a side view of the apparatus of a further embodiment of the invention.
  • Referring to the figures embodiments of the invention are shown of a method and apparatus for the manufacture of steel strip, from the molten metal to the final strip comprising a casting process and a rolling process. Figure 1 shows one embodiment of the apparatus which comprises a casting process 2 and a rolling process 3 for the production of steel strip. Molten steel enters the continuous casting process stage 2 where it solidifies. During the solidification in the casting process 2 a continuous slab 5 is formed with a slab thickness starting at 90 mm and reducing to 70 mm by the stage where the casting or solidification process is complete. The continuous slab 5 is then guided to a descaling section 8 before going on to a first rolling stand 10a of the rolling process 4. After the first rolling stand 10a, the continuous slab continues through the second, third and fourth stands 10a, 10b, 10c of the rolling process 4 resulting in a reduction in the thickness of the slab to 2 mm. This 2 mm thickness at this stage is shown for a particular example of a required final gauge of strip. At this stage the thickness of the strip could be as high as 5 mm depending on the desired final gauge. At this stage we shall refer to the slab 5 as strip 6 because this is a more accurate description of the steel with now much reduced thickness dimensions. As the whole process is continuous the velocity of the slab/strip 5/6 has correspondingly increased from 0. 1 m/s to 3.5 m/s.
    In one mode of the embodiment shown after the strip exits the first rolling stage the strip 6 then enters a re-heating and homogenisation stage 11b to restore the strip to the desired temperature for the subsequent rolling operations and in particular the edges of the strip which will have cooled down much more than the centre during the first rolling stage 10. This restores or maintains the steel of the strip in the austenitic phase to avoid the phase change to the ferritic phase. This enables further rolling to take place in the austenitic phase. The volume changes associated with the phase change from austenitic to ferritic prevent satisfactory rolling from taking place during the phase change, and the metallurgical properties of the resulting strip would not be of the required specification. Preferably the heating stage includes an electrical induction heater.
    Following the re-heating and temperature homogenisation stage 11b, the strip 6 passes through a second descaling stage 12 before proceeding to two further rolling stands 13a, 13b and has then achieved the desired thickness of 0.75 mm. The velocity of the strip has correspondingly increased to 9.3 m/s. The final thickness again could be as high as 5 mm according to the required final product specification and the fmal velocity would be correspondingly lower.
    The strip then passes through a cooling section 14 which in this embodiment is merely an extended distance between the last rolling stage 13 and the coiling stage 15. This distance in this case is 50 metres. Again this distance may be varied according to the requirements of any particular product specification within the scope of the invention. The strip then meets the final coiling stage 15 where the strip is coiled into conveniently sized coils. This coiling station preferably includes a cutting stage as well as an automatic means of re-starting a new coil.
    In an alternative mode of the embodiment the re-heating and homogenisation stage 11b is replaced with an additional cooling means 11a which actually speeds up the conversion from the austenitic. phase to the ferritic phase so that the conversion to the ferritic phase is essentially complete before the strip reaches subsequent rolling stands. In this case the final rolling stages take place with the strip in the ferritic phase. Importantly any rolling of the strip whilst the conversion of the steel strip from the austenitic phase to the ferritic phase is taking place is avoided. It may be sufficient to just turn off the re-heater 9 to achieve the required cooling to convert the steel strip to the ferritic phase without any need for additional cooling means.
    Thus it will be seen that the essence of the invention is the two stage rolling process in which the first and second rolling stages are separated to ensure that either the steel is maintained in the austenitic phase before the second stage by re-heating or that the steel is converted to the ferritic phase before the second rolling stage if necessary by forced cooling. Thus although in the embodiment shown the first rolling stage has four rolling stands and the second rolling stage has two rolling stands, the first rolling stage could have between two and four rolling stands and the second rolling stage could have between one and three rolling stands.
    In an alternative embodiment a slab shearing device is incorporated at the exit of the caster to divide the strip in the event of certain delays or disturbances in the upstream or downstream process. By this means and due to the relatively slow speed of the slab at the caster exit, a buffer is created which may alleviate the need to stop the caster and therefore moderating the extent of production loss due to the delay or disturbance of the rolling stage. The shearing means is arranged to operate intermittently only since such shearing will only be required in the event of delay or disturbances in the process. The shearing means is preferably a mechanical shearing device.
    The specific thickness, corresponding velocity and the length are shown for each of the stages in figure 4. All these values will vary according to the type of steel produced and in particular the desired size of the finished strip. In order to produce the final desired strip from this continuous casting and rolling process of the invention it is necessary to balance the casting mass flow with the mass flow of the strip. Thus the required mass flow of the cast material can be used to define the as cast slab thickness as well as the as cast slab speed. Figure 2 shows how this can be done. The mass flow curve A of the as cast slab is plotted as a product of the slab speed and the slab thickness which are the respective axes. The horizontal line B is a simplified representation of the upper limit of the as cast slab thickness for a given number of rolling mill passes. The vertical line C is a simplified representation of the upper limit for the as cast slab speed which is determined by operational criteria of the casting process. Thus the desired cast speed and thickness can be chosen from the area to the right and above curve A within the limits of lines B and C. Within these limits it is desirable, when in the steady state, to maximise the throughput and therefore be as close as possible to the cross over of lines B and C. During production there will be a number of times when the flow rate will be reduced from the maximum due, for example, to changeovers in various wear components of the casting process, such as the submerged entry nozzles, and it is necessary to ensure that none of these events cause the flow rate to be reduced to such an extent that either the cast velocity or the product thickness falls below curve A on figure 2.
    In order to achieve the desired quality of strip product it is also necessary to optimise a number of other factors with have a critical effect on the final product quality. Two important factors are the casting speed of the as cast slab and the finishing speed of the final strip. Referring to figure 3, these are plotted one on each of the axes, the casting speed as the y-axis in metres/minute and the finishing speed as the x-axis in metres/second. Band A shows the preferred range of the finishing speed for optimum finished quality of the product. It also determines the ranges for the optimum stability of the rolling operation with the minimum risk of "cobbling". Cobbling is the term used to describe the piling up of strip resulting in the breakdown of the whole rolling process. Cobbling therefore results in a large scrap loss and also considerable down time whilst the spent strip is removed from the rolling stands. Cobbling is therefore something which should be avoided if at all possible and managing the risk of cobbling is therefore an important factor in the operational parameters. It is even more important with the present invention wherein the casting process is coupled to the rolling process because the casting operation may have to be stopped and restarted as well. Band A will therefore be chosen to encompass a lower risk of cobbling than for conventional rolling mills.
    Band B shows the preferred range for optimum finished quality, additionally taking into account other factors such as the optimum wear on the components in the casting process having an impact on the overall costs of the process. Plotted on the graph are various alternatives for the thickness reduction. Line D shows a thickness reduction from 50 to 0.7, line E from 60 to 0.7, line F from 70 to 0.7, line G from 80 to 0.7, line H from 90 to 0.7, line J from 100 to 0.7, line K from 110 to 0.7 and line L f 120 to 0.7. In each case, in this embodiment, the final desired thickness in this example is 0.7 mm. Thus by means of a graph such as this, it is possible to determine the most desired casting and finishing speeds and in turn the corresponding thicknesses on the casting process 2 and all the stages of the rolling process 3.
    According to the invention it has been determined that the optimum casting speed should be of the order of 6 metres/minute with a slab thickness of 70 mm. Satisfactory results can be achieved for a corresponding range of final thin gauge strip from 0.75 mm to 5 mm with a cast slab thickness in the range of 55 to 85 mm and a continuous casting slab speed of 4.8 to 7.2 metres/minute.
    The critical parameters may be simplified in the flow rate product which is the product of the thickness and the speed. This flow rate is itself a critical parameter and according to the invention it has been determined that this should be at least 0.315 metres2/minute. This linear flow rate lower limit can be applied for any width of strip.
    Referring to figs. 1, 4 and 5 an apparatus comprising the alternative modes of cooling and re-heating between the first and second rolling stages of one embodiment of the invention is shown. The molten steel is formed into the final finished strip by means of the combined casting process stage 2, a first re-heating and homogenisation furnace 3, a rolling process stage 4 and a final coiling stage 5.
    The strand length then enters the re-heating and homogenisation furnace which is preferably a tunnel furnace 3. The purpose of the tunnel furnace is to ensure that the strand is at the required temperature across the whole profile of the strand for the subsequent rolling operation. The required temperature of the strand depends therefore on the further processing requirements of the final strip and thus additional heating may be required as well as maintenance of the desired temperature by means soaking requiring the addition of heat or possibly merely by heat insulation. Also at the tunnel furnace a second continuous cast strand could be introduced from a separate casting unit so that the generally slower throughput of the casting unit can be balanced with the generally higher throughput of the rolling process so that the throughput capacity of the rolling process is more fully utilised. The second continuous cast strand can be switched into the line when the first casting line is paused.
    The next stage of the strip-making apparatus is a descaling stage 8, shown on fig. 4, 5. An edging stage (not shown) may optionally be provided at this stage before the rolling operation.
    The strand now enters the rolling process stage 4 which in this embodiment includes a first rolling stage 10 which in this embodiment includes four rolling stands 10 and a second rolling stage 13 which in this embodiment includes two rolling stands separated by a temperature controlling stage 11 between them. A further scale suppression stage or de-scaling unit 12 is also provided between them.
    The temperature controlling stage 11 comprises both a reheating/homogenisation function 11b or alternatively a cooling function 11a. When this stage is required to be a cooling stage 11a which is required for certain types of steel strip to allow the transformation of the steel from the austenitic phase to the ferritic phase so that the transformation takes place before further rolling rather than during subsequent rolling.
    It can be seem that in this embodiment the cooling unit 11a and the re-heating /homogenisation unit 11b of the temperature controlling stage are arranged side by side so that desired unit for the function that is required for a particular subsequent rolling operation. For the subsequent rolling in the ferritic phase, the cooling unit 11a is arranged to line with the path of the strip. When it is desired to change to austenitic rolling in the subsequent the cooling unit 11a is moved sideways out off line and the re-heating/homogenisation unit is moved sideways into line with the path of the strip.
    Rolling stage 13 is the finishing rolling stage with, in this embodiment, two rolling stands, although more stages may be required. Also the first rolling stage could have an alternative number of stands typically having from two to six stands. Preferably low inertia hydraulic loopers may be provided (not shown) and also optional scale suppression between each stand.
    The rolled strip is then fed to a run out table 14 which may also be provided with optional cooling 14a, in addition to normal air cooling.
    The coiling stage may include a first pinch roll which is provided in front of a shear which is followed by a separate optional pinch roll and then the coiling stage, all of which enable the desired final strip lengths to be cut and coiled whilst being continuously fed from the mill.
    The apparatus includes a control system with means for measuring the speed of the strip and the strands, as well as the profile, shape, thickness and width of the strip and also the lateral position of the strip. The control system is also linked to temperature measuring sensors in numerous places along the whole apparatus as well as tension measurement in the rolling process.
    The control system is linked to an actuating system which varies all of these parameters. The speed and tension of the strip is controlled by the roll speeds, and the profile, shape, gauge, width and lateral alignment is controlled by the mould, the roll gap, actuating means such as dynamic shape rolls (DRS) rolls and by guide rolls. The temperature is adjusted by the heating means in the tunnel furnace as well as cooling at the casting unit and/or by temperature modifications at the re-heating/homogenisation/cooling stage 11 and/or at each or some of the rolling stands.
    Most of these parameters are interdependent and the control system has to take into account consequential effects on the other parameters. The gauge of the strip may be changed during the rolling process by controlling the roll gaps and the speed of the whole casting and rolling process in a synchronous way.
    As each strand enters the rolling process it has to be threaded through the rolling stands and this occurs at a threading speed which is lower than the desired final rolling speed. This lower threading speed is equivalent to the speed as is presently used in the conventional rolling of strip from slabs or strand lengths rolled from cast slabs but at the highest possible practical speed or this conventional rolling. With the present invention, however, after the strand has been threaded, through the rolling stands the speed is increased significantly and tension can be induced in the strip. Also the strand is very long, compared to conventional single cast slab strands, and rolling can thus take place at this higher speed in conditions which are very near steady state conditions. As a result of this higher speed and shorter processing time the temperature of the strip during rolling is higher than during threading or during rolling of conventional cast slab lengths. This allows thinner gauges to be produced.
    The guidance of thin strip cannot be achieved in the same way as for thicker strip by means of physical edge guidance because it is not effective and it damage the edges of the strip. Instead, according to the invention, edge guidance is provided by roll tilting which is itself based on measurements of the lateral position of the strip.
    Also, for thin gauge strip for a given strip width the width/thickness ratio is higher and it is more difficult to achieve good flatness quality.
    Also, the tolerance for crown on very thin strip is more demanding. Additionally when a gauge change during rolling is undertaken there is a requirement for a larger dynamic range of crown control actuation. This control is provided by DSR, crossed roll arrangements where the rolls are crossed to change the effective roll crown or other actuating means.
    Also, when rolling very thin strip very small forces are required to generate the necessary strip tensions which are an integral part of the control of the whole process. Special loopers (not shown) are used between the rolling stages 13 to generate the required tension. The loopers must be of low inertia in order to apply the necessary small forces in a controllable way in conjunction with a fast time control system. Hydraulically actuated loopers together with load cell measurement of the forces provides an effective means of controlling the tension for very thin strip.
    Referring now to figure 6 a further embodiment is shown with the cooling unit 11a arranged in-line with the re-heating/homogenisation unit 11b. Thus when subsequent ferritic rolling is required in the second rolling stage 13 the cooling unit 11a is activated and the re-heat/homogenisation unit 11b is de-activated. similarly for subsequent austenitic rolling the cooling unit 11a is de-activated and the re-heating/homogenisation unit 11b is activated and the austenitic rolling can then occur through the same rolling stage 13.
    Referring to figure 7 a further embodiment is shown in which the cooling stage 11a is provided by allowing the strip to pass through a sufficient distance to permit cooling to take place by air circulation and radiation. In additional in the cooling mode the re-heating unit is of course de-activated but also has the tops of the unit raised to permit cooling by air circulation through the heating unit in the cooling mode. Cooling could be provided by forced air or nitrogen flow cooling in the re-heater or in the extended distance or both.
    Thus for certain strip specifications rolling in the ferritic phase can be achieved with the same rolling stage as for austenitic rolling. It is advantageous to be able to roll either in the austenitic phase or the ferritic phase to minimise the line length of the apparatus which minimises the costs of the instalation as well as the running costs. The strip therefore has to be cooled to transform it to the ferritic phase but this must be undertaken in a very short length of strip in order to still be able to roll in the austenitic phase when cooling is not applied. Air mist cooling, a mixture of air and water, achieves the desired rapid and homogenous cooling which is needed to maintain the good shape of the strip. A subsequent extraction unit is provided (not shown) which then removes surplus water and steam from the sprayed area to prevent uncontrolled cooling of the product and unwanted steam discharges in the area of the product.

    Claims (11)

    1. A method for the manufacture of steel, in the form of rod, bar or strip, from the molten metal to the final rolled product comprising a casting process and a rolling process, wherein the rolling process includes a first rolling stage followed by a second rolling stage, the first and second rolling stages each comprising between one and six rolling stands, wherein the casting process and the rolling process are continuous and the flow rate of the molten metal into the casting process is balanced with the flow rate of the strip throughout the rolling process, and wherein a temperature controlling stage is arranged between the first and second rolling stages, characterised in that, the temperature controlling stage comprises a first state in which it operates to prepare the steel for rolling in the subsequent second rolling stage in the austenitic phase, and an alternative second state in which the temperature controlling stage operates to prepare the steel for the subsequent rolling stage in the ferritic phase, said temperature controlling stage being selectively operable between the first state and the second state, such that the steel passes through the same subsequent second rolling stage, correspondingly in the austenitic phase or alternatively the ferritic phase.
    2. A method for the manufacture of steel according to claim 1, characterised in that the temperature controlling means comprises a heat retaining means which, in the first state encloses the steel to retain heat therein, and is openable to form the second state, in which the steel is exposed to the surrounding cooling air.
    3. A method for the manufacture of steel according to claim 1, characterised in that the temperature controlling means comprises a heat providing or retaining means and a separate heat removing or cooling means.
    4. A method for the manufacture of steel according to claim 3, characterised in that the heat providing or retaining means and heat removing means are arranged in parallel relationship to each other, and in the first state, the heat providing or retaining means is arranged in-line with first and second rolling stages and the heat removing means are arranged off-line, and in the second state the heat removing means are arranged in-line with the first and second rolling stages and the heat providing or retaining means is arranged off-line.
    5. A method for the manufacture of steel according to claim 3, characterised in that the heat providing or retaining means and heat removing means are arranged in series, in-line with each other, and in the first state, the heat providing or retaining means is switched to an operating state and the heat removing means is switched to a non-operating state, and in the second state the heat removing means is switched to an operating state and the heat providing or retaining means is switched to a non-operating state.
    6. A method according to claim 1, characterised in that the temperature controlling stage includes, in the second state, means to provide cooling by forced cooling, such as by water cooling.
    7. A method according to claim 1, characterised in that the temperature controlling stage includes, in the first state, an induction heating stage.
    8. A method according to claim 1, characterised in that for a corresponding range of final thin gauge strip from 0.75 mm to 5 mm the cast slab thickness is in the range of 55 to 85 mm and the continuous casting slab speed is in the range of 4.8 to 7.2 metres/minute.
    9. A method according to claim 1, characterised in that the steel is maintained with a flow rate product of at least 0.315 metres2/minute.
    10. A method according to claim 1, characterised in that the gauge and shape of the strip may be changed continuously without interruption to the combined casting and rolling process, by controlling the roll gaps and the speed of the whole casting and rolling process in a synchronous way, at least one of the first and second rolling stages comprising at least one rolling stand comprising at least one dynamic shape actuated shell roll.
    11. An apparatus for the manufacture of steel, in the form of rod, bar or strip, from the molten metal to the final rolled product comprising a casting stage and first and second rolling stages, the first and second rolling stages each comprising between one and six rolling stands, wherein the casting stage and the rolling stages are continuous and the flow rate of the molten metal into the casting stage is balanced with the flow rate of the strip throughout the rolling stages, and wherein a temperature controlling stage is arranged between the first and second rolling stages, characterised in that, the temperature controlling stage comprises a first state in which it operates to prepare the steel for rolling in the subsequent second rolling stage in the austenitic phase, and an alternative second state in which the temperature controlling stage operates to prepare the steel for the subsequent rolling stage in the ferritic phase, said temperature controlling stage being selectively operable between the first state and the second state, such that the steel passes through the same subsequent second rolling stage, correspondingly in the austenitic phase or alternatively the ferritic phase.
    EP98301246A 1997-02-21 1998-02-19 Continuous metal manufacturing method and apparatus therefor Withdrawn EP0860215A1 (en)

    Applications Claiming Priority (4)

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    GBGB9703651.1A GB9703651D0 (en) 1997-02-21 1997-02-21 Continuous metal strip manufacturing method and apparatus therefore
    GB9703651 1997-02-21
    GB9715360A GB9715360D0 (en) 1997-02-21 1997-07-21 Continuous metal manufacturing method and apparatus therefor
    GB9715360 1997-07-21

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    Also Published As

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    GB2322320A (en) 1998-08-26
    JPH10277715A (en) 1998-10-20
    CA2230013A1 (en) 1998-08-21
    GB9802317D0 (en) 1998-04-01
    CN1195585A (en) 1998-10-14

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