EP0830325A1 - A method of slowing the setting rate of magnesium phosphate cements - Google Patents
A method of slowing the setting rate of magnesium phosphate cementsInfo
- Publication number
- EP0830325A1 EP0830325A1 EP96911867A EP96911867A EP0830325A1 EP 0830325 A1 EP0830325 A1 EP 0830325A1 EP 96911867 A EP96911867 A EP 96911867A EP 96911867 A EP96911867 A EP 96911867A EP 0830325 A1 EP0830325 A1 EP 0830325A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- magnesium
- compound
- cement
- potassium
- phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B9/00—Magnesium cements or similar cements
- C04B9/04—Magnesium cements containing sulfates, nitrates, phosphates or fluorides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B12/00—Cements not provided for in groups C04B7/00 - C04B11/00
- C04B12/02—Phosphate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/06—Oxides, Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/08—Acids or salts thereof
- C04B22/10—Acids or salts thereof containing carbon in the anion
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0094—Agents for altering or buffering the pH; Ingredients characterised by their pH
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/20—Retarders
- C04B2103/22—Set retarders
Definitions
- This invention relates to a method of slowing the setting rate of hydrated
- the most commonly used hydrated cement is portland cement formed by
- portland cement has
- alkaline cement reaction products carbonate to calcium carbonate reducing its
- magnesium ammonium phosphate (NH 4- vlgPO 4 .6H 2 O), commonly known as struvite, as a hydrated cement is well documented. This
- ammonium phosphate cements have an initial setting time of about 1 to 5 minutes.
- borax or halides such as sodium chloride or
- Borax has disadvantages including in that it is
- Chlorides in general are not desirable additives
- Barium salts are not desirable in view of cost and toxicity problems.
- this invention consists in a method for slowing the setting
- the invention consists in a cementitious article formed
- Suitable magnesium phosphate cements include ammonium magnesium phosphate cements and potassium magnesium phosphate cements (MgKPO 4 nH 2 O).
- the cement is chosen depending on its end application.
- magnesium phosphate cement is ammonium magnesium
- a suitable base is ammonia.
- the cement in order to prepare the cement, the
- ammonia is added to mono ammonium phosphate to which magnesium oxide is
- the ratio of ammonia to phosphate is 0.5-2.0: 1 , most
- the ratio of magnesium to phosphate is 7-1 : 1 , most preferably 3:1.
- Ratios of ammonia to phosphate above 2:1 tend to produce crumbly cements.
- magnesium phosphate cement is a potassium magnesium
- phosphate cement a suitable base is potassium hydroxide or potassium carbonate.
- the base is preferably added to mono
- potassium to phosphate is 0.5-2.0:1, most preferably 1:1 and the ratio of
- magnesium to phosphate is 7- 1 : 1 , most preferably 3:1. Ratios of magnesium to phosphate greater than 7: 1 tend to result in cements having reduced setting times and
- the invention consists in a method of slowing the setting
- the invention consists in a method of slowing the
- ammonium phosphate compound is preferably mono ammonium
- the potassium compound is preferably potassium carbonate and the
- magnesium compound is preferably magnesium oxide. It will be apparent, however, that other materials may be used as the source of phosphate, potassium and
- the setting time of the hydrated cement according to this invention can be
- the pH of the cement is controlled by adjusting the pH of the cement at the time of setting.
- the pH of the cement is controlled by adjusting the pH of the cement at the time of setting.
- the pH is preferably controlled by using
- potassium carbonate is used as it has some
- the hydrated cement prepared by the method of the invention can be any suitable material.
- density modifiers such as flyash, expanded polystyrene beads,
- cenospheres vermiculite, perlite or predigested calcium silicate hydrate.
- additives can include fibre reinforcements such as cellulose, glass, polymer or
- the hydrated cement can be prepared as a foam cement.
- the magnesium potassium phosphate cement prepared by the method of this
- the hydrated cement prepared according to this invention may be readily
- the hydrated cement prepared according to this invention may be formed, for
- the setting time may be further delayed by the addition of yet more water to
- the method can form cements with various levels of hydration in terms of
- the cement has a
- oxide as the source of magnesium other materials may be used or the materials may be used.
- the mole ratio of K 2 C0 3 :NH 4 H 2 PO 4 :MgO:H 2 O is suitably 1:2:6:6.
- the purity of the raw materials is not crucial to the formation of the cement
- the dry raw materials can be pre-packaged in
- cements a two component hydrated cement mix comprising a first
- water can be achieved by use of a meter or fixed volume containers.
- cooling in a dissicator has been measured to be about 2% of the original length.
- the pH of the cured magnesium potassium phosphate cement is suitably
- magnesium potassium phosphate cement is not subject to any known reaction with
- the applications of the cement according to this invention include:-
- Example 1 Retarding an ammonium magnesium phosphate cement containing flvash.
- This formulation corresponds to a mole ratio of NH 3 :NH 4 H 2 PO 4 :MgO:H 2 O
- the mono ammonium phosphate, ammonia and water were first mixed
- Example 2 Retarding a potassium magnesium phosphate cement optionally
- the formulation used in this example was as follows:
- This formulation corresponds to a mole ratio of K 2 CO 3 :NH 4 H 2 PO 4 :MgO:H 2 O
- the mono ammonium phosphate was mixed with water and the potassium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
A method for slowing the setting rate of a magnesium phosphate cement comprising adding a suitable base to an uncured or partially cured aqueous mix of the magnesium phosphate cement in an amount sufficient to raise the pH and minimise MgO/Mg(OH)2 dissolution. Suitable magnesium phosphate cements include ammonium magnesium phosphate cements and potassium magnesium phosphate cements.
Description
A METHOD OF SLOWING THE SETTING RATE OF MAGNESIUM PHOSPHATE CEMENTS
FIELD OF THE INVENTION
This invention relates to a method of slowing the setting rate of hydrated
cements.
BACKGROUND OF THE INVENTION
The most commonly used hydrated cement is portland cement formed by
burning a mixture of clay and limestone. In some applications portland cement has
properties that render it less than ideal. These include situations where the cement is
required to be rapid setting or in which the product concerned is likely to be exposed
to high temperatures. Additionally, when cured concrete made from ordinary portland
cement is subjected to carbonation due to atmospheric carbon dioxide exposure the
alkaline cement reaction products carbonate to calcium carbonate reducing its
alkalinity and eventually causing micro-cracking of the concrete. This leads to
corrosion of reinforcing steel where there is inadequate concrete cover over the steel.
The use of magnesium ammonium phosphate (NH4-vlgPO4.6H2O), commonly known as struvite, as a hydrated cement is well documented. This
compound occurs as a natural mineral or may be synthesised. Known magnesium
ammonium phosphate cements have an initial setting time of about 1 to 5 minutes.
This time is too short in many specialised applications such as fabrication and it would
be desirable to slow the setting time down. Previous methods to slow down the
setting time have involved the addition of borax or halides (such as sodium chloride or
barium salts) as setting rate retardants. Borax has disadvantages including in that it is
very soluble in water and in order to slow the setting time, a substantial amount of
borax must be added with consequent loss of strength of the final product. Halides are
also not desired setting retardants. Chlorides in general are not desirable additives
since materials containing them are liable to give off hydrogen chloride gas at high
temperatures and their retarding effects occurring within a couple of minutes is not
very significant. Barium salts are not desirable in view of cost and toxicity problems.
Magnesium ammonium phosphate cements have the additional disadvantage
of inadequate mechanical properties and moisture resistance compared to portland
cement for general purpose use. Despite the problems struvite cements have been
used in applications requiring rapid set times such as the repair of cracks in concrete
roads and have also been used in the manufacture of furnace lining boards.
OBJECT OF THE INVENTION
It is an object of this invention to substantially ameliorate at least some of the
disadvantages of the prior art.
DISCLOSURE OF THE INVENTION
In a first aspect, this invention consists in a method for slowing the setting
rate of a magnesium phosphate cement comprising adding a suitable base to an
uncured or partially cured aqueous mix of the magnesium phosphate cement in an
amount sufficient to raise the pH and minimise MgO/Mg(OH)2 dissolution.
In another aspect, the invention consists in a cementitious article formed
using the method of the first aspect.
PREFERRED EMBODIMENTS OF THE INVENTION Suitable magnesium phosphate cements include ammonium magnesium phosphate cements and potassium magnesium phosphate cements (MgKPO4 nH2O).
The cement is chosen depending on its end application.
When the magnesium phosphate cement is ammonium magnesium
phosphate, a suitable base is ammonia. Preferably, in order to prepare the cement, the
ammonia is added to mono ammonium phosphate to which magnesium oxide is
subsequently added. Preferably the ratio of ammonia to phosphate is 0.5-2.0: 1 , most
preferably 1 : 1 and the ratio of magnesium to phosphate is 7-1 : 1 , most preferably 3:1.
Ratios of ammonia to phosphate above 2:1 tend to produce crumbly cements.
When the magnesium phosphate cement is a potassium magnesium
phosphate cement, a suitable base is potassium hydroxide or potassium carbonate.
Similarly in order to prepare the cement the base is preferably added to mono
ammonium phosphate prior to the addition of magnesium oxide. Preferably the ratio
of potassium to phosphate is 0.5-2.0:1, most preferably 1:1 and the ratio of
magnesium to phosphate is 7- 1 : 1 , most preferably 3:1. Ratios of magnesium to
phosphate greater than 7: 1 tend to result in cements having reduced setting times and
increased viscosity and are generally unworkable.
In a preferred aspect, the invention consists in a method of slowing the setting
rate of an ammonium magnesium phosphate cement comprising the steps of reacting
ammonia with an arnmonium phosphate compound in the presence of water and
subsequently reacting the mixture with a magnesium compound to form a compound
having the formula NH MgPO4.nH2O, wherein the amount of ammonia used is
sufficient to raise the pH and minimise MgO/Mg(OH)2 dissolution.
In another preferred aspect, the invention consists in a method of slowing the
setting rate of potassium magnesium phosphate cement comprising the steps of
reacting an ammonium phosphate compound with a potassium compound in the
presence of water and subsequently reacting the mixture with a magnesium compound
to form a compound having the formula:
MgKPO4.nH2O
wherein the amount of potassium compound used is sufficient to raise the pH and
minimise MgO/Mg(OH)2 dissolution.
It is found by adding the potassium compound to the ammonium phosphate
compound prior to addition of magnesium oxide that the rate of set is slowed to such
an extent that the cement is suitable for fabrication.
The ammonium phosphate compound is preferably mono ammonium
phosphate, the potassium compound is preferably potassium carbonate and the
magnesium compound is preferably magnesium oxide. It will be apparent, however,
that other materials may be used as the source of phosphate, potassium and
magnesium.
The setting time of the hydrated cement according to this invention can be
controlled by adjusting the pH of the cement at the time of setting. Preferably the pH
is raised to a value between 4 to 10, more preferably to a value between 8 and 9. For
potassium magnesium phosphate cements, the pH is preferably controlled by using
potassium carbonate or potassium hydroxide as a source of potassium in the
preparation of the compound. Preferably potassium carbonate is used as it has some
buffering effect. It has also been found that the setting time of the hydrated cement
may be further delayed by the gradual addition of excess water to the final mixture or by mechanical agitation and working of the mix.
Although there is no limit on the amount of water used in order to maximise
strength, it is desirable to use only a slight excess from that stoichiometrically required
to form the desired hydrated cement so as to form a smooth paste before setting. Once the cement has started to set any amount of water can be added to slow the setting time with either none or minimal loss of strength.
The hydrated cement prepared by the method of the invention can
additionally contain density modifiers such as flyash, expanded polystyrene beads,
cenospheres, vermiculite, perlite or predigested calcium silicate hydrate. Other
additives can include fibre reinforcements such as cellulose, glass, polymer or
wollastonite fibres.
The hydrated cement can be prepared as a foam cement.
The magnesium potassium phosphate cement prepared by the method of this
invention has been found to have a high strength at ambient temperature, to retain
shape without distortion at high temperatures, exhibit low shrinkage at high
temperatures, to have low water permeability and is crystalline in appearance.
The hydrated cement prepared according to this invention may be readily
formed from commercially available raw materials and a high degree of purity is not
required for reliable manufacture of the product.
The invention will now be described, by way of example only, with reference
to specific examples.
The hydrated cement prepared according to this invention may be formed, for
example, in a conventional concrete mixer using the following method:-
(1) Dry mono ammonium phosphate NH4H2PO4 is mixed with potassium
carbonate K2CO3 in approximately stoichiometric quantities and a controlled
amount of water added.
(2) Magnesium oxide is then added to these materials and a further controlled
amount of water added. The cement will now react and set.
(3) The setting time may be further delayed by the addition of yet more water to
the mixture which displays thixotropic properties during the setting process.
The method can form cements with various levels of hydration in terms of
water molecules bound to the compound. If no excess water is added then when the
compound sets, there is no surplus water to cause drying shrinkage, the cement has a
very low porosity, and there is no need to dry excess water from articles formed from
the cement.
For a rapid or slightly delayed set, minimal quantities of water are added,
forming cements with the minimal quantities of bound water. For a further delayed
set larger quantities of water are added, forming compounds up to the maximum level
of bound water. For magnesium potassium phosphate cements the chemical reactions which
occur can be represented as follows:-
NH4H2PO4 + K2CO3 → K2HPO4 + CO2 + NH3 + H2O
MgO + H2O → Mg(OH)2
Mg(OH)2 + 2H+ → Mg2+ + 2H2O
Mg2+ + K+ + PO^ + nH2O → MgKPO4.nH2O
Although the above reactions are depicted around mono ammonium
phosphate as the source of phosphate, potassium carbonate as the source potassium
and the method of controlling the pH and consequently setting time, and magnesium
oxide as the source of magnesium, other materials may be used or the materials may
be used in other combinations.
A typical formulation for preparing a magnesium potassium cement
according to the method of the invention is:-
NH4H2PO4 42 kilograms
K2CO3 25 kilograms
MgO 45 kilograms
H2O 20 litres (minimum) or an
amount adjusted to suit
The mole ratio of K2C03:NH4H2PO4:MgO:H2O is suitably 1:2:6:6. Using
such a mole ratio the pH is raised from a pH of 4 to 5 (corresponding to the pH of a
saturated solution of NH4H2PO4) to a pH of 8 to 9.
The purity of the raw materials is not crucial to the formation of the cement
and the normal commercial purity of bulk commodity raw materials is of sufficient
quality for reliable manufacture of this invention. The batching accuracy of the raw
materials is not critical to the formation of the cement and normal site mortar mixing
accuracy of around 10% is adequate. The dry raw materials can be pre-packaged in
approximately stoichiometric quantities. For potassium magnesium phosphate
cements a two component hydrated cement mix can be provided comprising a first
component containing a mixture of mono ammonium phosphate and potassium
carbonate and a second component containing magnesium oxide. Accurate addition of
water can be achieved by use of a meter or fixed volume containers.
Using commercially available grades of the raw materials cured magnesium
potassium phosphate cement made in accordance with the above typical formulation,
has been found to exhibit strengths of about 50% of that obtained from cured
specimens of ordinary portland cement and to exhibit a pore structure which is
relatively impermeable to water. The linear shrinkage of cured magnesium potassium
phosphate cement specimens subjected by heating to temperatures of about 1000°C
then cooling in a dissicator has been measured to be about 2% of the original length.
No distortion is evident in such specimens.
The pH of the cured magnesium potassium phosphate cement is suitably
alkaline such that reinforcing steel bound by concrete formed from the cement will be
passivated and therefore not subject to corrosion, and the permeability of the cement is
such that the ingress of water to corrode the steel is inhibited. Additionally, cured
magnesium potassium phosphate cement is not subject to any known reaction with
atmospheric carbon dioxide in the same way as ordinary portland cement. Thus
concrete formed using the cement of this invention is expected to be dimensionally
stable with age and to maintain its non corrosive features to reinforcing steel
indefinitely.
The applications of the cement according to this invention include:-
a raw material in the manufacture of refractory materials;
a binding cement in the installation of refractory materials;
a binding cement in structural concrete;
a binding cement in extruded and pressed mortar articles;
a binding cement for fibre reinforced articles such as those containing fibres
including cellulose, glass, wollastonite and/or polymers; and
a rapid setting concrete for use in marine environments.
Example 1 - Retarding an ammonium magnesium phosphate cement containing flvash.
The formulation used in this Example was as follows:
concentrated aqueous ammonia (25%) 23mls
mono ammonium phosphate 36g
flyash 25g
magnesium oxide 38g
and water 14mls
This formulation corresponds to a mole ratio of NH3:NH4H2PO4:MgO:H2O
of 1.0:1.0:3.0:5.3.
The mono ammonium phosphate, ammonia and water were first mixed
together thoroughly, the flyash was then blended into the mixture and magnesium
oxide was then added resulting in a hexahydrated ammonium phosphate cement.
Example 2 - Retarding a potassium magnesium phosphate cement optionally
containing flvash.
The formulation used in this example was as follows:
potassium carbonate 22g
mono ammonium phosphate 36g
(flyash) 25g
magnesium oxide 38g
and water 17ml
This formulation corresponds to a mole ratio of K2CO3:NH4H2PO4:MgO:H2O
of 1:2:6:6.
The mono ammonium phosphate was mixed with water and the potassium
carbonate gradually added, with agitation to allow the CO2 evolved in the reaction to
excape. The mono ammonium phosphate and potassium carbonate particle size was
<500μm. (Slight warming can be used at this stage to aid the further removal of CO2
but intense heating is detrimental as it results in loss of ammonia). The mixing
resulted in the formation of a white slurry (weighing ~70g). The magnesium oxide
was then added to the slurry and stirred to form a smooth paste which could be cast
after lmin, but also could be kept workable up to 15mins by continual agitation. If
longer set times were required, water was added gradually, as stiffening occurred. A
gradual addition of a further 10ml of water extended working time to 60mins. When
the cement was made with flyash (added to the slurry prior to the addition of the
magnesium oxide) then a further addition of 31ml of water extended workability to
60mins.
The foregoing describes only some aspects of the present invention and
modifications made thereto without departing from the scope of the invention.
Claims
1. A method for slowing the setting rate of a magnesium phosphate cement
comprising adding to a suitable base to an uncured or partially cured aqueous mix of
the magnesium phosphate cement in an amount sufficient to raise the pH and
minimise MgO/Mg(OH)2 dissolution.
2. A method according to claim 1 wherein the magnesium phosphate cement is
an ammonium magnesium phosphate cement and the base is ammonia.
3. A method according to claim 1 wherein the magnesium phosphate cement is
a potassium magnesium phosphate cement and the base is potassium hydroxide or
potassium carbonate.
4. A method of slowing the setting rate of an ammonium magnesium phosphate
cement comprising the steps of reacting ammonia with an ammonium phosphate
compound in the presence of water and subsequently reacting the mixture with a
magnesium compound to form a compound having the formula NH4MgPO4.nH2O,
wherein the amount of ammonia used is sufficient to raise the pH and minimise
MgO/Mg(OH)2 dissolution.
5. A method according to claim 4 wherein the ammonium compound is mono
ammonium phosphate, and the magnesium compound is magnesium oxide.
6. A method of slowing the setting rate of potassium magnesium phosphate
cement comprising the steps of reacting an ammonium phosphate compound with a
potassium compound in the presence of water and subsequently reacting the mixture
with a magnesium compound to form a compound having the formula:
MgKPO4.nH2O - 13 - wherein the amount of potassium compound used is sufficient to raise the pH and
minimise MgO/Mg(OH)2 dissolution.
7. A method according to claim 6 wherein the ammonium phosphate compound
is mono ammonium phosphate, the potassium compound is potassium carbonate and
the magnesium compound is magnesium oxide.
8. A method according to any one of the preceding claims further comprising
delaying the setting time by adding excess water and/or mechanically agitating the
mix.
9. A method according to any one of the preceding claims wherein the cement
additionally contains fibres and/or fillers.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AUPN2911A AUPN291195A0 (en) | 1995-05-10 | 1995-05-10 | A hydrated composition |
AUPN2911/95 | 1995-05-10 | ||
PCT/AU1996/000284 WO1996035647A1 (en) | 1995-05-10 | 1996-05-09 | A method of slowing the setting rate of magnesium phosphate cements |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0830325A1 true EP0830325A1 (en) | 1998-03-25 |
EP0830325A4 EP0830325A4 (en) | 1999-07-21 |
Family
ID=3787259
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96911867A Withdrawn EP0830325A4 (en) | 1995-05-10 | 1996-05-09 | A method of slowing the setting rate of magnesium phosphate cements |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0830325A4 (en) |
JP (1) | JPH11505204A (en) |
KR (1) | KR19990014664A (en) |
AU (1) | AUPN291195A0 (en) |
WO (1) | WO1996035647A1 (en) |
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US6136088A (en) * | 1997-10-09 | 2000-10-24 | Mbt Holding Ag | Rapid setting, high early strength binders |
KR100322856B1 (en) * | 1999-06-30 | 2002-02-09 | 노재연 | Retarder for Gypsum Plaster and Cement |
FR2809724B1 (en) * | 2000-06-05 | 2003-05-09 | Rhodia Chimie Sa | NEW PHOSPHOMAGNESIAN HYDRAULIC BINDER, AND MORTAR OBTAINED FROM THIS BINDER |
DE10032220A1 (en) * | 2000-07-03 | 2002-01-24 | Sanatis Gmbh | Magnesium ammonium phosphate cements, their manufacture and use |
US6518212B1 (en) | 2000-09-18 | 2003-02-11 | The University Of Chicago | Chemically bonded phospho-silicate ceramics |
JP2004522688A (en) | 2001-08-10 | 2004-07-29 | セラテック,インコーポレイテッド | Composite materials and methods of making and using the composite materials |
KR100523886B1 (en) | 2003-05-27 | 2005-10-26 | 엘지석유화학 주식회사 | Hydrocarbon Steam Cracking Catalyst Method for Preparing the Same and Method for Preparing Light Olefin by Using the Same |
US7036588B2 (en) * | 2003-09-09 | 2006-05-02 | Halliburton Energy Services, Inc. | Treatment fluids comprising starch and ceramic particulate bridging agents and methods of using these fluids to provide fluid loss control |
AU2011205780B2 (en) | 2010-01-14 | 2015-11-12 | Engineered Arresting Systems Corporation | Cellular phosphate ceramics and methods of manufacture and use |
CN113562998A (en) * | 2021-08-24 | 2021-10-29 | 北京科技大学 | Method for preparing magnesium phosphate cement paste by using magnesium ore powder |
CN115724643B (en) * | 2022-11-01 | 2024-02-20 | 辽宁科技大学 | High-fire-resistance magnesium phosphate cement-based material capable of controlling hydration reaction and prolonging setting time and preparation method thereof |
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US4436555A (en) * | 1982-09-23 | 1984-03-13 | The United States Of America As Represented By The United States Department Of Energy | Magnesium phosphate glass cements with ceramic-type properties |
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US2522548A (en) * | 1946-10-03 | 1950-09-19 | Thoger G Jungersen | Method of making a phosphate gel and mold with phosphate gel binder |
US3960580A (en) * | 1974-11-21 | 1976-06-01 | W. R. Grace & Co. | Magnesium phosphate concrete compositions |
US4444594A (en) * | 1982-12-09 | 1984-04-24 | Armstrong World Industries, Inc. | Acid cured inorganic binder compositions which are compatible with mineral wool |
US4836854A (en) * | 1984-06-27 | 1989-06-06 | J. R. Simplot Co. | Stabilization of setting times of phosphate-bonded magnesia cements |
CA1277343C (en) * | 1985-10-15 | 1990-12-04 | Stauffer Chemical Company Division Of Rhone-Poulenc, Inc. | Magnesium phosphate fast-setting cementitious compositions containing set retardants |
US4786328A (en) * | 1987-07-16 | 1988-11-22 | American Stone-Mix, Inc. | Magnesium phosphate cement systems |
-
1995
- 1995-05-10 AU AUPN2911A patent/AUPN291195A0/en not_active Abandoned
-
1996
- 1996-05-09 EP EP96911867A patent/EP0830325A4/en not_active Withdrawn
- 1996-05-09 WO PCT/AU1996/000284 patent/WO1996035647A1/en not_active Application Discontinuation
- 1996-05-09 KR KR1019970708005A patent/KR19990014664A/en not_active Application Discontinuation
- 1996-05-09 JP JP8533606A patent/JPH11505204A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4436555A (en) * | 1982-09-23 | 1984-03-13 | The United States Of America As Represented By The United States Department Of Energy | Magnesium phosphate glass cements with ceramic-type properties |
US4756762A (en) * | 1987-07-16 | 1988-07-12 | American Stone-Mix, Inc. | Magnesium phosphate cement systems |
Non-Patent Citations (1)
Title |
---|
See also references of WO9635647A1 * |
Also Published As
Publication number | Publication date |
---|---|
JPH11505204A (en) | 1999-05-18 |
EP0830325A4 (en) | 1999-07-21 |
AUPN291195A0 (en) | 1995-06-01 |
KR19990014664A (en) | 1999-02-25 |
WO1996035647A1 (en) | 1996-11-14 |
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