EP0795418B2 - Use of a support for laser printing - Google Patents

Use of a support for laser printing Download PDF

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Publication number
EP0795418B2
EP0795418B2 EP19960810154 EP96810154A EP0795418B2 EP 0795418 B2 EP0795418 B2 EP 0795418B2 EP 19960810154 EP19960810154 EP 19960810154 EP 96810154 A EP96810154 A EP 96810154A EP 0795418 B2 EP0795418 B2 EP 0795418B2
Authority
EP
Grant status
Grant
Patent type
Prior art keywords
use
characterised
support
support according
fine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP19960810154
Other languages
German (de)
French (fr)
Other versions
EP0795418B1 (en )
EP0795418A1 (en )
Inventor
Erwin Pasbrig
Dietrich Bubeck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3A Technology and Management AG
Original Assignee
3A Technology and Management AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Grant date
Family has litigation

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5218Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24893Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495Thickness [relative or absolute]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/251Mica
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254Polymeric or resinous material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/259Silicic material

Description

  • Die Erfindung betrifft die Verwendung eines Trägers zum Bedrucken mittels Laserdruck. The invention relates to the use of a support for printing by means of laser printing. Im Rahmen der Erfindung liegt auch eine geeignete Lackzubereitung zur Grundierung eines Trägers sowie die Verwendung eines bedruckten Trägers. In the present invention, a suitable coating formulation for priming a support as well as the use of a printed carrier is.
  • Aluminium- und Kunststoff-Deckfolien für Blisterverpackungen werden fast immer mit dekorativen Drucken versehen. Aluminum and plastic cover sheets for blister packs are almost always provided with decorative printing. Für grosse Serien eigenen sich das Flexo- und Tiefdruckverfahren, kleinere Serien bzw. Etiketten werden inline an der Anlage bedruckt. For large series own the flexo and gravure printing process, smaller series and labels are printed inline on the system. Stetig von Druckbild zu Druckbild wechselnde kleinere Bildelemente, wie EAN- und Zahlencodes, können diesen Druckbildern über Laser- bzw. Inkjetdruck hinzugefügt werden. Steadily from print image to print image changing smaller pixels as EAN and number codes, these printed images can be added via laser or inkjet printing. Der weit überwiegende Teil dieser Drucke wird aus Gründen der Gleitfähigkeit, des Substratschutzes und der Haftungsvermittlung für die Druckfarbe auf einer dünnen Grundlackschicht aufgebracht. The vast majority of these prints is applied for reasons of lubricity of the substrate protection and adhesion promotion for the printing ink on a thin base coat layer. Diese muss zusätzlich beständig gegen die beim Verschliessen von Blisterverpackungen übliche Heissversiegelung mit Temperaturen bis zu 260°C sein und darf dabei nicht an den blanken oder beschichteten metallischen, heissen Siegelwerkzeugen ankleben. This must also be resistant to the customary blister packs during closure of heat sealing at temperatures up to 260 ° C and must not stick to the bare or coated metallic, hot sealing tools. Es kommen deshalb hier nur Lacke mit möglichst geringer Thermoplastizität in Frage. so here there are only paints with the smallest possible thermoplasticity in question.
  • In jüngster Zeit wurde zusätzlich zu den vorgenannten Verfahren ein neues Druckverfahren entwickelt, welches bei ähnlicher Druckbildgrösse wie bei Flexo- und Tiefdruck die Möglichkeit bietet, mit praktisch vernachlässigbarer Zeitverzögerung das Druckmotiv von Druck zu Druck vollständig zu ändern. Recently, a new printing process was developed in addition to the aforementioned method, which as with flexo and gravure printing offers the opportunity for a similar print image size, with virtually negligible delay, the print motif from print to print to completely change. Dies kann extern oder inline an den Abpackanlagen erfolgen. This can be done externally or inline to the packaging lines. Die Arbeitsweise ist ähnlich dem Laserdruck. The operation is similar to laser printing. Ein Toner wird über eine laseraktivierte Clichéewalze übertragen und wird durch die Wärmeenergie eines Lichtblitzes zB einer Xenonbogenlampe am Druckträger fixiert. A toner is transferred via a laser activated Clichéewalze and is fixed by the thermal energy of a light flash such as a xenon arc lamp on the print carrier. Diese ist im Vergleich mit der Hitzeaktivierung des Laserdruckes um ein Vielfaches geringer. This is lower by a multiple compared with the heat activation of laser printing. Die bisher üblichen Druckvorlacke führten unter diesen Bedingungen nur zu ungenügender Haftung des Toners. The usual Druckvorlacke led under these conditions only to inadequate adhesion of the toner. Durch Anpassung der Lackformulierung an die Bindemittelbasis des Toners konnte die Haftung des Toners auf dem Druckvorlack nur unwesentlich verbessert werden. the adhesion of the toner on the printing undercoat could be only marginally improved by adjusting the coating formulation to the base of the toner binder. Die The EP-A-0 672 539 EP-A-0672539 offenbart Papiere für den Tintenstrahldruck mit einer feinkörnige Bestandteile enthaltenden Grundlackschicht. discloses paper for ink jet printing with a fine-grained components containing base coat layer. Angesichts dieser Gegebenheiten haben sich die Erfinder die Aufgabe gestellt, einen für den laserdruck geeigneten Träger Bzw. Given these circumstances, the inventors have set the task, one for laser printing suitable carrier Respectively eine zu dessen Herstellung geeignete Lackzubereitung zu schaffen, mit der die Haftung zwischen Grundlackierung und Druckfarbe (Toner) auf einfache Weise verbessert werden kann. to provide a suitable for producing the coating formulation, with the adhesion between the base coat and ink (toner) can be improved in a simple manner. Der Träger soll insbesondere die Anwendung von Laserdruck Verfahren auch bei niedriger Wärmeenergie zur Aktivierung des Toners als Druckfarbe ermöglichen. The support should allow in particular the use of laser printing process even at a low thermal energy to activate the toner as a printing ink.
  • Zur erfindungsgemässen Lösung der Aufgabe führt die Verwendung eines Trägers nach Anspruch 1 bzw. einer Lackzubereitung nach Anspruch 6. Die Grundlackschicht kann feinkörnige Bestandteile wie hochdisperse Kieselsäure, Talkum, Kieselerde, natürliche oder oberflächenvorbehandelte Glimmer und/oder organische Partikel enthalten. For the inventive solution of the problem using a carrier according to claim 1 or a coating formulation according to claim 6. The base coat layer leads can fine-grained components such as highly disperse silicic acid, talc, silica, natural or surface pre-treated mica and / or organic particles. Die organischen Partikel können auch organische Zusätze, Harze oder Polymere sein, welche sich in der Lackformulierung nicht auflösen und damit die Oberfläche in gleicher Weise wie die organischen Füllstoffe erhöhen. The organic particles may also be organic additives, resins or polymers which do not dissolve in the coating formulation, thereby increasing the surface in the same way as the organic fillers.
  • Bevorzugte Träger umfassen eine Folie aus Metall, Kunststoff, Papier oder daraus hergestellte Verbundmaterialien. Preferred supports include a film made of metal, plastic, paper or composite materials produced therefrom.
  • Der Gehalt an feinkörnigen Bestandteilen in der Grundlackschicht bzw. in der Lackzubereitung liegt vorzugsweise zwischen 0,3 und 10 Gew.-%. The content of fine grained constituents in the base coat layer or in the coating formulation is preferably between 0.3 and 10 wt .-%.
  • Es hat sich gezeigt, dass als Basis für eine zur Grundierung des Trägers geeignete Lackzubereitung eine Vielzahl der heute üblichen Lackbindemittel verwendet werden können. It has been shown that a variety of commonly used today paint binders may be used as the basis for a suitable primer for the carrier coating formulation. Eine gute Haftung zwischen Druckvorlack und Druckfarbe ergibt sich beispielsweise mit einer Lackzubereitung auf der Basis Melamin bzw. mit Harnstoffharzen vernetzbarer Polyester oder Polystyrolacrylate, nicht vernetzbarer Cellulosenitrate oder polyadditionsvernetzender Systeme, insbesondere Systeme auf Isocyanat-, Isocyanurat-, gehärteter Lacke auf Polyester- oder Polyacrylatbasis, ggf. in Abmischung mit nicht härtbaren Anteilen. A good adhesion between printing undercoat and print color results, for example with a lacquer composition based on melamine or urea resins, crosslinkable polyester or Polystyrolacrylate, non-crosslinkable cellulose nitrates or polyadditionsvernetzender systems, in particular systems on isocyanate, isocyanurate, cured coatings based on polyester or polyacrylate, possibly in admixture with non-curable components.
  • Ein bevorzugter Anwendungsbereich eines bedruckten erfindungsgemässen Trägers aus Aluminium, Kunststoff oder einem Aluminium/Kunststoff-Verbundmaterial liegt in dessen Einsatz als heissiegelbare Verpackungsfolie, insbesondere als Folie zum Verschliessen von Blisterverpackungen durch Heissversiegelung oder für Beutel. A preferred application of a printed carrier according to the invention made of aluminum, plastic or an aluminum / plastic composite material is in its use as packaging film heissiegelbare, in particular as a film for closing blister packs by heat-sealing or for bags.
  • Weitere Vorteile, Merkmale und Einzelheiten der Erfindung ergeben sich aus der nachfolgenden Beschreibung bevorzugter Ausführungsbeispiele. Further advantages, features and details of the invention will become apparent from the following description of preferred embodiments.
  • Beispiel 1 example 1
  • Eine Lackrezeptur der Zusammensetzung A paint formulation of the composition
    35 Gew.-% 35 wt .-% vernetzbares Polyesterharz curable polyester resin
    7 Gew.-% % 7 wt .- Melaminharz melamine resin
    3 Gew.-% 3 wt .-% Epoxidharz epoxy resin
    4 Gew.-% 4 wt .-% Katalysatorlösung catalyst solution
    51 Gew.-% 51 wt .-% Lösungsmittel solvent
    führte bei einer Schichtdicke der Grundlackschicht von 1 bis 2 µm zu einer sehr mangelhaften Bedruckbarkeit mit einem Laserdrucksystem. resulted in a layer thickness of the base coat layer of 1 to 2 microns to a very poor printability with a laser printing system. Eine Zugabe von 0,1 bis 20 Gew.-% hochdisperser Kieselsäure von geringer Korngrösse zu obiger Lackrezeptur führte zu einem einwandfreien Druckergebnis. An addition of 0.1 to 20 wt .-% of highly dispersed silica of small grain size to the above paint formulation led to a satisfactory printing result.
  • Beispiel 2 example 2
  • Eine Lackrezeptur der Zusammensetzung A paint formulation of the composition
    30 Gew.-% 30 wt .-% Cellulosenitrat cellulose nitrate
    2 Gew.-% 2 wt .-% Polymerweichmacher polymeric plasticizers
    68 Gew.-% 68 wt .-% Lösungsmittel solvent
    zeigte eine schlechte Bedruckbarkeit mit einem Laserdrucksystem. showed poor printability with a laser printing system. Durch Zugabe eines pulverförmigen, im verwendeten Lösungsmittel nicht löslichen PU-Harzes wurde die Bedruckbarkeit erheblich verbessert. the printability was improved considerably by the addition of a powdery, non-soluble in the solvent used PU resin.

Claims (9)

  1. Use of a support with a primer coat containing 0.1 to 20 % by weight fine particle constituents as an adherent surface for toner for laser printing.
  2. Use of a support according to claim 1, characterised in that the primer coat contains highly dispersed silicic acid, talc, silica, natural or surface-treated mica and/or organic particles as the fine-particle constituents.
  3. Use of a support according to claim 1 or claim 2, characterised in that the constituents are not soluble in the primer coat or in the solvent of the primer.
  4. Use of a support according to one of claims 1 to 3, characterised in that the primer coat contains 0.3 to 10 % by weight fine-particle constituents.
  5. Use of a support according to one of claims 1 to 4, characterised in that it includes a film made of metal, plastic, paper or composite materials produced therefrom.
  6. Use of a coating preparation containing 0.1 to 20 % by weight highly dispersed silicic acid, talc, silica, natural or surface treated mica and/or organic particles as the fine particle constituents for priming a support as an adherent surface for toner for laser printing.
  7. Use of a coating preparation according to claim 6, characterised in that it contains 0.3 to 10% by weight fine-particle constituents.
  8. Use of a coating preparation according to claim 6 or claim 7, characterised in that it is based on melamine or polyesters or polystyrene acrylates which can be crosslinked with urea resins, non-crosslinkable cellulose nitrates or polyaddition-crosslinking systems, in particular systems based on isocyanate, isocyanurate or cured coatings based on polyester or polyacrylate, possibly mixed with non-curing fractions.
  9. Use of a laser-printed support according to claim 5 consisting of aluminium, plastic or an aluminium/ plastic composite material as a heat-sealable packaging film, in particular as a film for closing blister packs by heat-sealing or for bags.
EP19960810154 1996-03-13 1996-03-13 Use of a support for laser printing Expired - Lifetime EP0795418B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP19960810154 EP0795418B2 (en) 1996-03-13 1996-03-13 Use of a support for laser printing

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
EP19960810154 EP0795418B2 (en) 1996-03-13 1996-03-13 Use of a support for laser printing
ES96810154T ES2148714T5 (en) 1996-03-13 1996-03-13 Using a laser printing support
DE1996505593 DE59605593D1 (en) 1996-03-13 1996-03-13 Use of a support for printing by means of laser printing
CA 2199219 CA2199219A1 (en) 1996-03-13 1997-03-05 Substrate with an undercoat for printing purposes
US09182697 US6221466B1 (en) 1996-03-13 1998-10-29 Laser-printed substrate comprising a particle-filled receptive layer
US09326852 US6201041B1 (en) 1996-03-13 1999-06-07 Substrate with an undercoat for printing purposes

Publications (3)

Publication Number Publication Date
EP0795418A1 true EP0795418A1 (en) 1997-09-17
EP0795418B1 EP0795418B1 (en) 2000-07-12
EP0795418B2 true EP0795418B2 (en) 2012-08-08

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP19960810154 Expired - Lifetime EP0795418B2 (en) 1996-03-13 1996-03-13 Use of a support for laser printing

Country Status (5)

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US (2) US6221466B1 (en)
EP (1) EP0795418B2 (en)
CA (1) CA2199219A1 (en)
DE (1) DE59605593D1 (en)
ES (1) ES2148714T5 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1080880A1 (en) * 1999-08-20 2001-03-07 Alusuisse Technology & Management AG Package materials with partially disposed application of material
US6500890B2 (en) * 2000-12-15 2002-12-31 Wellman, Inc. Polyester bottle resins having reduced frictional properties and methods for making the same
US7759449B2 (en) * 2000-12-15 2010-07-20 Wellman, Inc. Methods for introducing additives into polyethylene terephthalate
US20030039783A1 (en) * 2001-03-30 2003-02-27 Stafford Steven Lee Polyesters and polyester containers having a reduced coefficient of friction and improved clarity
USH2132H1 (en) 2001-06-29 2005-11-01 Eastman Chemical Company Polyester containers having a reduced coefficient of friction
US20040086737A1 (en) * 2002-11-01 2004-05-06 Yockey A. James Product packaging with improved printed paper and method of making the same
US7490548B2 (en) * 2005-03-18 2009-02-17 Shih-Hung Cheng Method for manufacturing water-based laser hologram paper
JP4850254B2 (en) * 2005-10-27 2012-01-11 ヒューレット−パッカード デベロップメント カンパニー エル.ピー.Hewlett‐Packard Development Company, L.P. Printing on conductive substrate

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0135976A1 (en) 1983-09-13 1985-04-03 Mizusawa Industrial Chemicals Ltd. Filler for heat-sensitive recording paper
EP0507998A1 (en) 1991-04-12 1992-10-14 Moore Business Forms, Inc. A coated substrate and method of making same

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5610354B2 (en) * 1974-06-13 1981-03-07
US4247676A (en) * 1979-08-13 1981-01-27 The Goodyear Tire & Rubber Company Storable flowable polyurethane adhesive composition
US4346149A (en) * 1980-05-19 1982-08-24 Gulfko Incorporated Water based aluminum paint
GB8521646D0 (en) * 1985-08-30 1985-10-02 English Clays Lovering Pochin Inorganic fillers
US5250591A (en) * 1988-02-20 1993-10-05 Somar Corporation Curable adhesive composition
US5036118A (en) * 1988-10-17 1991-07-30 The Dow Chemical Company Reinforced polymer compositions having improved distinctness of image
JP3198164B2 (en) * 1992-09-09 2001-08-13 三菱製紙株式会社 Ink-jet recording sheet
DE4322179C2 (en) * 1993-07-03 1997-02-13 Schoeller Felix Jun Papier Recording material for ink-jet printing method
JP3451718B2 (en) * 1993-07-08 2003-09-29 ソニー株式会社 The image forming method of printing paper, using the dye receptor layer forming composition for the manufacture and their
DE4405210A1 (en) * 1994-02-18 1995-08-24 Wolff Walsrode Ag Emulsifier-free lacquer binder in the form of granules and their preparation
DE69516744T2 (en) * 1994-02-24 2000-10-05 Canon Kk Printing medium, its manufacturing method of the same, and ink jet printing method using
DE69514946D1 (en) * 1994-03-01 2000-03-16 Asahi Glass Co Ltd Ink jet printing method
US5573825A (en) * 1994-07-14 1996-11-12 Permar Systems, Inc. Laser imprintable data-tag system
US5584922A (en) * 1994-09-14 1996-12-17 Ciba-Geigy Corporation Stir-in organic pigments
JPH08178417A (en) * 1994-12-28 1996-07-12 Tokyo Gas Co Ltd Hot water supplying apparatus and method for bath
EP0782933A1 (en) * 1996-01-08 1997-07-09 Nippon Kayaku Kabushiki Kaisha Laser marking article and laser marking method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0135976A1 (en) 1983-09-13 1985-04-03 Mizusawa Industrial Chemicals Ltd. Filler for heat-sensitive recording paper
EP0507998A1 (en) 1991-04-12 1992-10-14 Moore Business Forms, Inc. A coated substrate and method of making same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"Sylobloc in Kunststoffen", June 1990, KATALOG DER FIRMA GRACE, pages: DECKBLÄT - 4,9

Also Published As

Publication number Publication date Type
US6201041B1 (en) 2001-03-13 grant
ES2148714T5 (en) 2012-11-02 grant
US6221466B1 (en) 2001-04-24 grant
CA2199219A1 (en) 1997-09-13 application
ES2148714T3 (en) 2000-10-16 grant
EP0795418B1 (en) 2000-07-12 grant
EP0795418A1 (en) 1997-09-17 application
DE59605593D1 (en) 2000-08-17 grant

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