EP0781359A1 - Use of solvent-resistant textile binders - Google Patents
Use of solvent-resistant textile bindersInfo
- Publication number
- EP0781359A1 EP0781359A1 EP95932751A EP95932751A EP0781359A1 EP 0781359 A1 EP0781359 A1 EP 0781359A1 EP 95932751 A EP95932751 A EP 95932751A EP 95932751 A EP95932751 A EP 95932751A EP 0781359 A1 EP0781359 A1 EP 0781359A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- vinyl
- alkoxymethyl
- copolymer
- meth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/425—Cellulose series
- D04H1/4258—Regenerated cellulose series
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
- D06M15/29—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides containing a N-methylol group or an etherified N-methylol group; containing a N-aminomethylene group; containing a N-sulfidomethylene group
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/3188—Next to cellulosic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
Definitions
- the invention relates to the use of N- (alkoxymethyl) - (meth) acrylamide-functional textile binders to improve the solvent resistance in the finishing and strengthening of fiber materials, and to a method for producing solvent-resistant fiber structures.
- aqueous copolymer dispersions as binders for solidifying and coating fiber structures such as fabrics, nonwovens and wadding made of textile fibers or textile yarns.
- copolymer dispersions of (meth) acrylate or vinyl ester copolymers which contain self-crosslinking comonomer units with N-methylol or N-methylol ether functions to improve the strength, usually up to 10% by weight % N-methylol- (meth) acrylic id (NMA or NMMA) copolymerized.
- NMA or NMMA N-methylol- (meth) acrylic id copolymerized.
- a disadvantage of these binders is the release of formaldehyde by hydrolytic cleavage of the N-methylol function and the low solvent resistance of the materials solidified or coated with them. It is known to improve the resistance to solvents by incorporating pre-crosslinking, polyethylenically unsaturated comonomer units. However, this measure frequently leads to problems
- thermally self-crosslinking copolymers which contain 2 to 10% by weight of N-Me- contain thylol- (meth) acrylamide or their N-methylol ether.
- a disadvantage is that in the copolymers containing N-methylol-acrylamide used therein, the tempered copolymer films show good solvent resistance, but not the nonwovens bonded with them.
- EP-B 205862 relates to textile binders based on vinyl acetate-ethylene copolymers which contain 1 to 5% by weight of N-methylol (meth) acrylamide units or their ethers.
- N-methylol (meth) acrylamide units or their ethers In order to improve the wet strength when using a copolymer binder with a low NMA content, it is proposed to additionally use melamine formaldehyde resins.
- EP-A 261378 teaches to improve the heat resistance of fiber mats bonded with N-methylol-functional copolymers by using copolymers in which the N-methylol functions are wholly or partly etherified as binders are.
- WO-A 92/08835 describes textile binders based on vinyl acetate / ethylene copolymer emulsions which, instead of N-methylol- (meth) acrylamide units, exclusively N- (n-butoxymethy1) acrylamide to reduce the release of formaldehyde -Units included.
- EP-A 86889 (AU-A 8310718) relates to a process for producing a textile coating composition which, under the action of water, shows no white swelling and no white break.
- the coating agent consists of an aqueous copolymer emulsion which is obtained by emulsion copolymerization of (meth) acrylates with N-methylol- (meth) acrylamide, the N-methylol- (meth) crylamides being at least 20 Mol% are etherified with an alcohol and the emulsion polymerization takes place in the presence of a fatty alcohol having 10 to 20 carbon atoms.
- the solvent resistance textile binders are not discussed.
- the invention was based on the object of providing binders based on aqueous copolymer dispersions or copolymer powders which, in addition to high dry and wet strength, impart high solvent resistance to textiles finished therewith.
- the invention relates to the use of N- (alkoxymethyl) - (meth) acrylamide-functional textile binders to improve the solvent resistance in the finishing and solidification of fiber materials with textile binders, characterized in that an aqueous copolymer dispersion or a redispersible material is used as the textile binder Copolymer powder of copolymers with a Tg of -60 * C to + 60 * C, containing a) one or more monomer units from the group of the vinyl esters of unbranched or branched carboxylic acids with 1 to 12 C atoms, the esters acrylic acid and methacrylic acid with unbranched or branched alcohols having 1 to 12 carbon atoms, vinyl aromatics, vinyl halides and ⁇ -olefins, and b) 0.3 to 10% by weight, based on the total weight of the copolymer, of one or more N.
- Methylol methacrylamide in a weight ratio of N- Methylol compound to N- (alkoxymethyl) compound of at most 5: 1 is used.
- N- (alkoxymethyl) - (meth) acrylamides are N- (isobutoxymethyl) acrylamide (IBMA), N- (isobutoxymethyl) methacrylamide (IBMMA), N- (n-butoxymethyl) acrylamide (NBMA) and N- (n-butoxymethyl) methacrylamide (NBMMA).
- the copolymers preferably contain 0.5 to 3.0% by weight, based on the total weight of the copolymer, of N- (alkoxy-methyl) acrylamides or N- (alkoxymethyl) methacrylamides with a C ⁇ _- to Cg-alkyl radical or mixtures of these N- (alkoxy ⁇ methyl) - (meth) acrylamides with N-methylolacrylamide (NMA) and / or N-methylolmethacrylamide (NMMA).
- NMA N-methylolacrylamide
- NMMA N-methylolmethacrylamide
- copolymers which, in the proportions by weight mentioned, mixtures of the N- (alkoxymethyl) - (meth) acrylamides with N-methylolacrylamide or N-methylolmethacrylamide in a weight ratio of N-methylol compound to N- (alkoxymethyl) compound from 5: 1 to 1:10 included.
- copolymers in particular 0.5 to 3.0% by weight, based on the total weight of the copolymer, of a mixture of NMA and IBMA (IBMMA) in a weight ratio of NMA / IBMA (IBMMA) of 3: 1 to 1: 5 from 1: 1 to 1: 5 included.
- vinyl esters are vinyl acetate, vinyl propionate, vinyl butyrate, vinyl 2-ethylhexanoate, vinyl laurate, l-methyl vinyl acetate, vinyl pivalate and vinyl esters of a-branched monocarboxylic acids with 9 to 10 carbon atoms, for example VeoVa9 R or VeoVal0 R. Vinyl acetate is particularly preferred.
- Preferred methacrylic acid esters or acrylic acid esters are methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl ethacrylate, n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate.
- Methyl acrylate, methyl methacrylate, n-butyl acrylate and 2-ethylhexyl acrylate are particularly preferred.
- the vinyl ester copolymers may optionally contain from 1.0 to 50% by weight, based on the total weight of the comonomer phase, of o-olefins such as ethylene or propylene and / or vinyl aromatics such as styrene and / or vinyl halides such as vinyl chloride and / or acrylic acid esters or methacrylic acid esters of alcohols 1 to 12 carbon atoms, such as methyl acrylate Methylmeth ⁇ , ethyl acrylate, ethyl methacrylate, Pr 'opylacrylat, pylmethacrylat product, n-butyl acrylate, n-butyl methacrylate, hexyl acrylate 2-ethyl and / or ethylenically unsaturated esters and their Dicarbonsau ⁇ Derivatives such as diisopropyl fumarate, which contain dimethyl, dibutyl and diethyl esters of maleic acid or
- the (meth) acrylic ester copolymers may optionally contain 1.0 to 50% by weight, based on the total weight of the comonomer phase, of ⁇ -olefins such as ethylene or propylene and / or vinyl aromatics such as styrene and / or vinyl halides such as vinyl chloride and / or ethylenically unsaturated Dicarboxylic acid esters or their derivatives, such as diisopropyl fumarate, which contain dimethyl, dibutyl and diethyl esters of maleic acid or fumaric acid, or maleic anhydride.
- the selection from the mentioned monomers is preferably made in such a way that copolymers with a glass transition temperature Tg of -30 ° C. to + 30 ° C. are obtained.
- the vinyl ester copolymers and the (meth) acrylic ester copolymers may also contain 0.05 to 3.0% by weight, based on the total weight of the comonomer mixture, one or more auxiliary monomers from the group of ethylenically unsaturated carboxylic acids, preferably acrylic acid or methacrylic acid, from the group of ethylenically unsaturated carboxylic acid amides, preferably acrylamide and 2-acrylic amidopropanesulfonic acid, from the group of ethylenically unsaturated sulfonic acids or their Salts, preferably vinylsulfonic acid, and / or from the group of the polyethylenically unsaturated comonomers, for example divinyladipath, 1,9-decadiene, allyl methacrylate, triallyl cyanurate and crosslinking comonomers such as acrylamidoglycolic acid (AGA), methyl acrylamidoglycolic acid methyl ester (
- Preferred vinyl ester copolymers contain as comonomer units a), in each case based on the total weight of the
- vinyl ester in particular vinyl acetate, and 1 to 30% by weight of acrylic acid ester, in particular n-butyl acrylate or 2-ethylhexyl acrylate;
- vinyl acetate 50 to 75% by weight of vinyl acetate, 1 to 30% by weight of acrylic acid ester, in particular n-butyl acrylate or 2-ethylhexyl acrylate, and
- VeoVal0 R 1 to 30% by weight acrylic acid ester, especially n- Butyl acrylate or 2-ethylhexyl acrylate, and 10 to 40% by weight of ethylene;
- Preferred (meth) acrylic acid ester copolymers contain as comonomer units a), in each case based on the total weight of the copolymer:
- the vinyl ester copolymers or the (meth) acrylic ester copolymers are preferably prepared by the emulsion polymerization process.
- the polymerization can be carried out batchwise or continuously, with or without the use of seed latices, with presentation of all or individual constituents of the reaction mixture, or with partial presentation and subsequent metering of the or individual constituents of the reaction mixture, or according to the metering process without presentation . All doses are preferably made to the extent of the consumption of the respective component.
- comonomers a) 10 to 25% by weight are initially introduced and the remainder is metered in together with the comonomers b) in emulsion.
- abs is preferably at a pressure of 20 to 100 bar. worked.
- the polymerization is carried out in a temperature range from 40.degree. C. to 80.degree. C. and initiated using the methods usually used for emulsion polymerization.
- the initiation is carried out using the customary water-soluble Ra Dical formers, which are preferably used in amounts of 0.01 to 1.0% by weight, based on the total weight of the monomers. Examples include ammonium and potassium persulfate, alkyl hydroperoxides, such as tert-butyl hydroperoxide; Hydrogen peroxide.
- the radical initiators mentioned can also be combined in a known manner with 0.01 to 0.5% by weight, based on the total weight of the monomers, of reducing agents. For example, formaldehyde sulfoxylate salts, sodium bisulfite or ascorbic acid are suitable.
- redox catalyst components are preferably metered in during the polymerization.
- emulsifiers and protective colloids conventionally used in emulsion polymerization can be used as dispersants.
- anionic surfactants such as alkyl sulfates with a chain length of 8 to 18 carbon atoms, alkyl and alkylaryl ether sulfates with 8 to 18 carbon atoms in the hydrophobic radical and up to 40 ethylene or propylene oxide units, alkyl or alkylaryl sulfonates are suitable with 8 to 18 carbon atoms, esters and half esters of sulfosuccinic acid with monohydric alcohols or alkylphenols.
- Suitable nonionic surfactants are, for example, alkyl polyglycol ethers or alkylaryl polyglycol ethers with 8 to 40 ethylene oxide units.
- protective colloids preferably in amounts of up to 4% by weight, based on the total weight of the monomers.
- examples of these are vinyl alcohol / vinyl acetate copolymers with a content of 80 to 100 mol% of vinyl alcohol units, polyvinyl pyrrolidones with a molecular weight of 5,000 to 400,000, hydroxyethyl celluloses with a degree of substitution range of 1.5 to 3.
- the pH range desired for the polymerization which is generally between 3 and 7, can be set in a known manner using acids, bases or conventional buffer salts, such as alkali metal phosphates or alkali metal carbonates.
- the regulators typically used for example mercaptans, aldehydes and chlorinated hydrocarbons, can be added during the polymerization.
- the solids content of the aqueous dispersions is preferably 30 to 65% by weight.
- the dispersion is dried, preferably spray-dried or freeze-dried, particularly preferably spray-dried.
- Known devices such as spraying through multi-component nozzles or with the disk, in a possibly heated dry gas flow, can be used here. In general, temperatures above 250'C are not used. The optimum temperature of the drying gas can be determined in a few experiments; temperatures above 60 ° C. have often proven particularly useful.
- antiblocking agents for example aluminum silicates, diatomaceous earth, calcium carbonate
- defoamers for example based on silicone or hydrocarbons
- spraying aids for example polyvinyl alcohols or water-soluble melamine-formaldehyde condensation products, can optionally be added to the dispersion.
- the dispersion powders still contain 0 to 30% by weight, particularly preferably 1 to 15 % By weight, based on the base polymer, polyvinyl alcohol with a degree of hydrolysis of 85 to 94 mol%, and / or 0 to 10% by weight vinyl alcohol copolymers with 5 to 35% by weight 1-methyl-vinyl alcohol units, and / or 0 to 30% by weight, particularly preferably 4 to 20% by weight, based on the total weight of polymeric constituents, antiblocking agents and optionally up to 2% by weight, based on the base polymer, defoamer.
- the aqueous copolymer dispersions or the redispersible dispersion powders are suitable for finishing and solidifying natural or synthetic " fiber materials.
- fiber materials include wood fiber, cellulose fiber, wool, cotton, mineral fibers, ceramic fibers, synthetic fibers based on fiber-forming polymers such as Viscose fiber, polyethylene, polypropylene, polyester, polyamide, polyacrylonitrile or carbon fiber, fibers of homo- or copolymerizates of vinyl chloride or fibers of homo- or copolyme- risates of tetrafluoroethylene Copolymer dispersions or the dispersible polymer powders for finishing and solidifying cellulose fiber materials.
- Another object of the invention is a process for the production of solvent-resistant fiber structures, characterized in that an aqueous copolymer dispersion or a redispersible copolymer powder of copolymers with a Tg of -60'C to + 60 * C, containing a) one or more monomer units from the Group of the vinyl esters of unbranched or branched carboxylic acids with 1 to 12 C atoms, the esters of acrylic acid and methacrylic acid with unbranched or branched alcohols with 1 to 12 C atoms, vinyl aromatics, vinyl halides and ⁇ -olefins and b ) 0.3 to 10% by weight, based on the total weight of the copolymer, one or more N- (alkoxymethyl) acrylamides or N- (alkoxymethyl) methacrylamides with a C 1 -C 6 -alkyl radical or mixtures of these N- (alkoxymethyl) - (meth) acrylamides with N-methylol
- the fibers are spread out over a large area.
- the methods for this are known and primarily depend on the application in which the solidified fiber material goes.
- the fibers can be laid out by means of an air-laying, wet-laying, direct spinning or carding device. If necessary, the flat structures can be mechanically solidified with binding agent prior to solidification, for example by cross-laying, needling or water jet hardening.
- the aqueous copolymer dispersions are customarily impregnated, foam-impregnated, sprayed, slapped. Brushed or printed applied. If necessary after separating off the excess binder by, for example, squeezing, the textile structures are dried at temperatures from 80 to 200 ° C., preferably between 120 and 180 ° C. Depending on the area of application, the amount of binder required to solidify the fiber material is between 5 and 50% by weight of binder, based on the weight of the fiber.
- the powdered binder is sprinkled in a manner known per se onto the, if appropriate mechanically pre-consolidated, fiber material. sprinkled in (e.g. with carded wadding), shaken in or mixed directly with the fiber.
- the textile structures at temperatures of 80 to 200 'C, preferably zwi ⁇ rule 120 and 180 * C and dried.
- the amount of binder required to solidify the fiber material is between 5 and 50% by weight of binder, based on the weight of the fiber.
- Pigments, antioxidants, dyes, plasticizers, film-forming aids, fillers, flame retardants, foam-forming aids, foam inhibitors, wetting agents, thermosensitizers, antistatic agents, biocides, grip improvers, additional crosslinking agents or catalysts to accelerate the crosslinking reaction, if necessary, can also be added to the binder according to the invention in the usual amounts for this purpose.
- the solvent-resistant textile binder is preferably suitable for the consolidation of nonwovens, for example in the household and hygiene area and for industrial wipes. Another area of application is the anti-slip finishing of fabrics.
- a cellulose fiber fleece was solidified by means of a full bath impregnation with 20% by weight copolymer dispersion (solid based on fiber). The excess binder was squeezed between two rollers and the fleece was dried for 3 minutes at 150 ° C. in a drum dryer.
- Solvent resistance of the nonwovens was determined by measuring the maximum tensile force (HZK) of nonwoven strips with a width of 1.5 cm and a length of 15 cm.
- the nonwovens were stored in a standard atmosphere at T-23'C and 50% RH (DIN 50014) for at least 24 hours.
- the nonwovens were stored in water for 1 minute immediately before the measurement.
- the nonwovens were stored in isopropanol for 1 minute immediately before the measurement.
- the maximum tensile force was measured using a Zwick tensile testing machine, the tensile measurement being carried out at a constant rate of expansion of 100 mm / min. The maximum tensile force is determined for each measurement and the measurement ends when the force has dropped to 40% of the maximum tractive force. 5 non-woven strips per sample were clamped together. The average of two series of measurements was determined.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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DE19944432945 DE4432945A1 (en) | 1994-09-15 | 1994-09-15 | Solvent resistant textile binder |
DE4432945 | 1994-09-15 | ||
PCT/EP1995/003623 WO1996008597A1 (en) | 1994-09-15 | 1995-09-14 | Solvent-resistant textile binder |
Publications (2)
Publication Number | Publication Date |
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EP0781359A1 true EP0781359A1 (en) | 1997-07-02 |
EP0781359B1 EP0781359B1 (en) | 1998-05-06 |
Family
ID=6528336
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19950932751 Expired - Lifetime EP0781359B1 (en) | 1994-09-15 | 1995-09-14 | Use of solvent-resistant textile binders |
Country Status (6)
Country | Link |
---|---|
US (1) | US5763022A (en) |
EP (1) | EP0781359B1 (en) |
DE (2) | DE4432945A1 (en) |
ES (1) | ES2118623T3 (en) |
FI (1) | FI971068A (en) |
WO (1) | WO1996008597A1 (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19631935A1 (en) | 1996-08-08 | 1998-02-12 | Wacker Chemie Gmbh | Solvent-resistant textile binder |
DE19716352A1 (en) * | 1997-04-18 | 1998-10-22 | Wacker Chemie Gmbh | Hard and hydrophobic binding and coating agent for textile fabrics |
US6638319B2 (en) | 2001-04-04 | 2003-10-28 | Healthtex Apparel Corp. | Polymer for printed cotton |
US6645255B2 (en) | 2001-04-04 | 2003-11-11 | Healthtex Apparel Corp. | Polymer-grafted stretchable cotton |
US6645256B2 (en) | 2001-04-04 | 2003-11-11 | Healthtex Apparel Corp. | Polymer grafted cotton |
DE10332621A1 (en) † | 2003-07-17 | 2005-02-03 | Wacker Polymer Systems Gmbh & Co. Kg | Process for the preparation of polyvinyl alcohol-free, aqueous polymer dispersions |
US7264377B2 (en) * | 2004-02-10 | 2007-09-04 | Halo Sun, Llc | Sensor-activated audible story lamp |
US7649067B2 (en) | 2005-10-19 | 2010-01-19 | Wacker Polymers, L.P. | Process of making a vinyl ester based polymer latex composition |
DE102012202843A1 (en) | 2012-02-24 | 2013-08-29 | Wacker Chemie Ag | Process for the preparation of vinyl ester-ethylene-acrylic acid amide copolymers |
WO2016055128A1 (en) | 2014-10-06 | 2016-04-14 | Siniat International | Improved mat and related gypsum boards suitable for wet or humid areas |
WO2019115392A1 (en) | 2017-12-13 | 2019-06-20 | Heiq Materials Ag | Soil release formulations for textile applications |
US20220220646A1 (en) * | 2020-02-06 | 2022-07-14 | Wacker Chemie Ag | Formaldehyde-free binder composition |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE539963A (en) * | 1954-07-23 | |||
FR1260307A (en) * | 1959-06-24 | 1961-05-05 | Bayer Ag | Aqueous dispersions of self-crosslinking copolymers |
NL124333C (en) * | 1959-06-24 | |||
FR2003769A1 (en) * | 1968-03-13 | 1969-11-14 | Basf Ag | |
DE2512589C2 (en) * | 1975-03-21 | 1990-07-12 | Wacker-Chemie GmbH, 8000 München | Thermally self-crosslinking copolymers |
US4044197A (en) * | 1975-03-21 | 1977-08-23 | Wacker-Chemie Gmbh | Thermally self-cross-linkable ethylene/vinyl acetate copolymers |
US4092303A (en) * | 1975-05-27 | 1978-05-30 | American Cyanamid Company | Polyacrylate elastomers with improved elasticity |
DE3205904A1 (en) * | 1982-02-19 | 1983-09-01 | Chemische Fabrik Pfersee Gmbh, 8900 Augsburg | METHOD FOR EMULSION COPOLYMERISATION, THE EMULSION COPOLYMERISATE PRODUCED BY THE METHOD AND THE USE THEREOF |
JPS59125972A (en) * | 1983-01-07 | 1984-07-20 | 伴 実 | Treatment for modifying silk fiber |
US4610920A (en) * | 1985-06-27 | 1986-09-09 | National Starch And Chemical Corporation | Binders for nonwovens |
US4859508A (en) * | 1986-09-26 | 1989-08-22 | National Starch And Chemical Corporation | Heat resistant binders |
JPH01168971A (en) * | 1987-12-23 | 1989-07-04 | Nisshin Kagaku Kogyo Kk | Elastic processing agent for fiber and feeling-improving agent |
EP0510153A1 (en) * | 1990-11-14 | 1992-10-28 | Vinamul Ltd. | Improvements in or relating to non-woven fibrous materials |
-
1994
- 1994-09-15 DE DE19944432945 patent/DE4432945A1/en not_active Withdrawn
-
1995
- 1995-09-14 ES ES95932751T patent/ES2118623T3/en not_active Expired - Lifetime
- 1995-09-14 US US08/793,320 patent/US5763022A/en not_active Expired - Fee Related
- 1995-09-14 DE DE59502125T patent/DE59502125D1/en not_active Expired - Fee Related
- 1995-09-14 WO PCT/EP1995/003623 patent/WO1996008597A1/en active IP Right Grant
- 1995-09-14 EP EP19950932751 patent/EP0781359B1/en not_active Expired - Lifetime
-
1997
- 1997-03-14 FI FI971068A patent/FI971068A/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO9608597A1 * |
Also Published As
Publication number | Publication date |
---|---|
EP0781359B1 (en) | 1998-05-06 |
FI971068A0 (en) | 1997-03-14 |
US5763022A (en) | 1998-06-09 |
WO1996008597A1 (en) | 1996-03-21 |
DE59502125D1 (en) | 1998-06-10 |
FI971068A (en) | 1997-03-14 |
DE4432945A1 (en) | 1996-03-21 |
ES2118623T3 (en) | 1998-09-16 |
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