EP0750784A1 - Method and plant for cleaning lightly radioactive waste incineration gases - Google Patents
Method and plant for cleaning lightly radioactive waste incineration gasesInfo
- Publication number
- EP0750784A1 EP0750784A1 EP95912311A EP95912311A EP0750784A1 EP 0750784 A1 EP0750784 A1 EP 0750784A1 EP 95912311 A EP95912311 A EP 95912311A EP 95912311 A EP95912311 A EP 95912311A EP 0750784 A1 EP0750784 A1 EP 0750784A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fumes
- aqueous solution
- radioactive
- temperature
- cooling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/02—Treating gases
Definitions
- the invention relates to the purification of smoke from the incineration of weakly radioactive waste, in particular but not exclusively the treatment of smoke from a fusion incinerator and vitrification of waste, such as waste generated by the nuclear industry, hospitals or universities.
- the incineration of weakly radioactive waste produces fumes containing water vapor, acid pollutants such as hydrogen halides, solid particles, some of which are soluble, and radioactive heavy metals, which must be extracted. fumes before they are released into the atmosphere.
- acid pollutants such as hydrogen halides, solid particles, some of which are soluble, and radioactive heavy metals, which must be extracted. fumes before they are released into the atmosphere.
- a known treatment of the fumes consists in cooling them by means of a heat recovery unit to a temperature compatible with their passage through a filter capable of retaining the solid particles, and then in treating the dedusted fumes in a gas washing installation to extract acid pollutants and some of the gaseous heavy metals, before the smoke is released into the atmosphere.
- the fumes from waste fusion and vitrification incinerators have a high temperature, up to 1250 ° C, and the heat recovery unit must be specially designed and made of materials resistant to temperature and corrosion, therefore expensive. It has been proposed to overcome this drawback of cooling the fumes by dilution effect by injecting air into them, but this solution has the drawback of increasing the quantity of gases to be treated.
- the cooling of the fumes, before being sent to the filters causes adsorption of the radioactive heavy metals on the solid particles which then require, once extracted from the fumes, special precautions for their packaging and handling.
- Known installations thus produce a large volume of radioactive solid residues whose handling and storage are costly.
- the solid particles having adsorbed the radioactive particulate heavy metals contaminate all the installations located upstream of the filter, while the radioactive gaseous heavy metals contaminate the gas washing equipment, and these installations then constitute, in the event of replacement, sources of radioactivity requiring special precautions when dismantling, transporting and disposing of them.
- the present invention aims to reduce the cost of smoke treatment, to increase its performance by minimizing the content residual in pollutants from purified smoke, and it achieves this thanks to an installation characterized in that it comprises:
- a cooler-condenser capable of cooling the fumes to a temperature below their dew point temperature, so as to capture the radioactive heavy metals in the condensates at the same time as the acid pollutants and as soluble solid particles contained in the fumes,
- a heater to raise the temperature of the flue gases at their outlet from the cooler-condenser, so as in particular to avoid the rejection of liquid effluent by the installation, - a filter to recover the solid particles downstream of the heater, before the rejection of the purified fumes in the atmosphere,
- a condensate treatment unit capable of precipitating radioactive heavy metals to recover a radioactive precipitate and an aqueous solution
- a crystallization unit to crystallize the salts contained in said aqueous solution and recover water to be recycled in l 'installation.
- the solid particles conveyed by the fumes are thus recovered by the filter after the fumes have been freed from the radioactive heavy metals, so that these solid particles, which are not or only slightly radioactive, do not require any particular precautions for their handling and can be sent back to the incinerator to be melted and vitrified.
- the crystallization of neutralized and treated condensate salts makes it possible to eliminate any liquid discharge by producing salts capable of being industrially valued and water to be recycled in the smoke circuit.
- the ultimate waste resulting from the treatment of the fumes is thus limited to the precipitate, and the handling and storage of this ultimate waste is thus facilitated compared to the known installations which produce a larger volume of waste.
- the number of equipment contaminated by smoke is less than that of known installations because the radioactive heavy metals are eliminated in the cooler-condenser, that is to say the first link in the treatment.
- the subject of the invention is therefore a process for purifying fumes from a weakly radioactive waste incinerator, these fumes containing water vapor, acid pollutants, solid particles and radioactive heavy metals, characterized in that that it comprises the stages consisting in cooling the fumes in a cooler-condenser below their dew point in order to capture the radioactive heavy metals in condensates together with acid pollutants and soluble solid particles contained in the fumes, to heat the fumes from the cooler-condenser so as to avoid the rejection of liquid effluent by the installation, then to send the fumes to a filter capable of recovering solid particles before discharging the purified fumes into the atmosphere, the condensates being treated to precipitate the radioactive heavy metals and recover an aqueous solution which is sent to a crystallization unit, in order to recover salts and the water to be recycled in the installation.
- the cooling of the fumes is carried out by contact with an aqueous solution dispersed in a cooling enclosure to a temperature close to their dew point temperature, then by contact with a heat exchanger at condensation to a temperature below their dew point temperature.
- the fumes are cooled by contact with an aqueous solution dispersed in a cooling chamber to a temperature close to their dew point temperature and then by direct contact of the fumes with an aqueous solution dispersed in a spray column, this aqueous solution being maintained, by means of a heat exchanger, at a temperature below said dew point temperature of the fumes, so that the heavy metals are extracted from the fumes by condensation by mixing at the same time as the capture of the acid pollutants and of soluble particles contained in the fumes.
- FIG. 1 is an overall view of a purification installation equipped with a condenser per surface, in accordance with a first embodiment of the invention
- FIG. 1 is intended for the treatment of a flow 1 of fumes from an incinerator 3 of low radioactive waste, for example waste generated by the nuclear industry, hospitals or universities.
- This incinerator 3 is preferably of the type comprising a pocket for melting waste under the action of a plasma torch or an electroburner, with a view to their vitrification.
- the fumes to be treated carry solid particles and radioactive heavy metals. They contain water vapor formed during the combustion of waste and acidic pollutants such as hydrogen halides and organic pollutants. The temperature of the fumes is high, reaching 1250 ° C.
- the stream 1 of fumes is sent to a cooler-condenser comprising a cooling enclosure 6 in which an aqueous solution is sprayed to rapidly cool the fumes to a temperature close to their dew point temperature.
- a condenser 100 After passing through the cooling enclosure 6, the flue gases are sent to "a condenser 100 where they are cooled to a temperature below their dew point temperature, so that the radioactive heavy metals are extracted from the fumes during the condensation of the water vapor contained therein, at the same time as the capture of acid pollutants and soluble solid particles carried by the fumes.
- the condenser 100 is a condenser of the condenser type by surface, comprising a heat exchanger 106 able to carry out a heat exchange between the fumes and a refrigerant leaving at 101 a refrigeration installation. 102 to supply the exchanger 106 at a temperature below the dew point of the smoke, and then returning at 103 to the refrigeration installation 102.
- the condensation products which form on contact with the exchanger 106 are sent by a circuit 104 in the cooling enclosure 6 in contact with the fumes passing through the latter, to suddenly reduce their temperature, that is to say to carry out a quenching, down to a temperature close to their dew point temperature.
- the circuit 104 advantageously includes a clarifier making it possible to collect at 108 solid particles which are preferably returned to the incinerator to be melted and vitrified there.
- a purge circuit 105 is provided for withdrawing the condensation products when the concentration of radioactive heavy metals or other pollutants is high, in order to send them to a treatment unit 30, receiving at 31, via a valve 32 , reagents 33, for example sodium hydroxide, flocculants and insolubilizers, intended to precipitate radioactive heavy metals. The precipitate is extracted by filtration to recover irradiated filter cakes at 34.
- the aqueous solution freed from the precipitate contains salts formed during the neutralization of acid pollutants and soluble particles dissolved in the condensates.
- This aqueous solution is directed at 35 to a salt crystallization unit 36, making it possible to recover water at 37, sent to a distribution network 38 to be recycled in installation 2.
- crystallized salts are recovered 41 likely to be valued industrially.
- the filter cakes 34 are packaged for storage at 43.
- the crystallization unit advantageously comprises two stages, the first being constituted by a concentrator with forced circulation and the second by an evaporator-crystallizer.
- the fumes leaving the condenser 100 purified pass through a heater 300, in the example described a heater comprising a propane burner 301, to be brought to a temperature such that, on the one hand, the solid particles which they convey are dried and to absorb, on the other hand, the water produced during the crystallization of the salts, which is reinjected into the enclosure 6 by a supply 22 connected to the network 38; thus the installation 2 does not reject any liquid effluent.
- the fumes advantageously pass through a heat exchanger 400 and are then sent to a filter 200.
- the heat exchanger 400 is able to carry out a heat exchange between the hot fumes leaving in 302 the heater 300 and the purified fumes having passed through the filter 200, before the latter are released into the atmosphere.
- This heat exchanger 400 makes it possible on the one hand to avoid temperature fluctuations which risk damaging the filter 200 located downstream of the heater 300 and on the other hand makes it possible to avoid the formation of a white plume during rejection, by a chimney, purified fumes in the atmosphere.
- the filter 200 adapted to retain the solid particles conveyed in the fumes, is an absolute filter, for example a very high efficiency two-stage filter.
- Solid particles, almost free of heavy metals radioactive, retained by the filter 200 are recovered in 201 and are advantageously returned to the incinerator 3 to be melted and vitrified. Thanks to the heater 300, the solid particles which reach the filter 200 are no longer wet, which makes it possible to avoid clogging of the latter.
- the purified fumes are preferably sent to a desulphurization unit 500 receiving in 501 recycled water coming from the distribution network 38, and in 502 basic additives, for example sodium hydroxide, so known per se, to form a basic washing solution.
- the purified fumes leave in 503 the desulfurization unit 500 towards the exchanger 400 to be discharged by a fan 505 into the atmosphere after passing through it while a purge of deconcentration of the basic washing solution is conveyed in 504 to processing unit 30.
- the condenser 100 comprises a heat exchanger 106 capable of cooling the fumes by contact with the surface of the latter.
- a mixing condenser comprising a spraying column 7 in which the fumes are sent in direct contact with a dispersed aqueous solution, the temperature of which is kept below the dew point temperature of the fumes, so that the heavy metals are extracted from the fumes by condensation by mixing, at the same time as the capture of the acid pollutants and of soluble solid particles contained in the fumes.
- aqueous solution 8 initially originating from the distribution network 38 and the temperature of which is kept below the dew point temperature of the fumes is sprayed into column 7 against the current of the fumes. More specifically, the aqueous solution 8 is sprayed by means of nozzles 9 arranged in a stepped manner to create sheets of liquid in the column 7, in a manner known per se.
- the fumes pass successively through the layers of sprayed aqueous solution and the water vapor which they contain condenses on contact with the fine droplets of aqueous solution 8, with absorption of the acid pollutants. Almost all of the radioactive heavy metals are thus captured in the acid condensates formed.
- the elimination of radioactive heavy metals is facilitated by the acidity of the aqueous solution, due to the dissolution in the latter of the acid gases contained in the fumes.
- the nozzles 9 are supplied by a supply circuit 12 comprising a pump 11 for withdrawing at 10 the aqueous solution at the base of the column 7 and a heat exchanger 13 located downstream of the pump 11.
- Valves 14 are placed in series with the nozzles 9 so as to adjust the flow rate of each of them to the desired value.
- the heat exchanger 13 is adapted to carry out a heat exchange between the aqueous solution circulating in the supply circuit 12 and water from a secondary cooling circuit 15, the temperature of which is of course lower than the temperature desired for the aqueous solution to be sprayed.
- Column 7 is equipped, in a manner known per se, at its upper part, with a demister 20 intended for retaining the droplets of liquid entrained by the fumes leaving it at 21. This demister 20 is cleaned, when the loss of load at its crossing is greater than a given threshold, by precipitation of water by means of a nozzle 41, connected via a valve 42, to the distribution network 38.
- the cooling enclosure 6 allows the use, for the construction of the column 7, of a material withstanding at a lower temperature than that required for the enclosure 6, subjected to fumes of higher temperature. The overall cost of the installation is thus reduced.
- An aqueous solution is sprayed into the enclosure 6 by means of one or more nozzles 16.
- these nozzles 16 are supplied by a circuit 29 comprising a pump 17 for withdrawing the aqueous solution 8 from the column 7 to the bottom of the latter at 18, at a point located at the bottom of the column 7, below the level of the abovementioned sampling point 10, so as to entrain the solid residues accumulated at the bottom of the column 7.
- a clarifier 45 is placed upstream of the pump 17 to recover these solid residues at 46, which are returned to the incinerator 3 to be melted and vitrified.
- the cooled flue gases leave at 19 the enclosure 6, with the solution sprayed by the nozzles 16, to emerge tangentially in the column 7 under the nozzles 9.
- the aqueous solution 8 circulates for the most part in a closed circuit.
- a purging circuit 23 makes it possible to draw off overflow when the concentration of the latter in radioactive heavy metals or other pollutants extracted from the smoke is high, and the supply of recycled water 22 makes it possible to rescue if necessary l nozzle 16 supply.
- This supply 22, connected on one side to the distribution network 38, is connects the other, via a valve 24, at a point 25 located on the circuit 23 upstream of the nozzles 16 and isolated from the pump 17 by a non-return valve 26.
- the purge circuit 23, opening into column 7 above the level of the sampling points 10 and 18, makes it possible to draw off the acid pollutants and heavy metals extracted from the fumes, as well as, where appropriate, the hydrocarbons and suspended solids.
- the nozzle 41 is supplied with recycled water coming from the supply network 38 to compensate for the losses in aqueous solution in the column 7, in particular in the case where the quantities withdrawn are greater than the quantity of water vapor, contained in the fumes , which is condensed.
- the bottom of the column, sloping, is equipped with a ramp 27, supplied via a valve 28 with compressed air of low pressure to agitate the aqueous solution 8 before the start of the installation.
- the invention makes it possible to efficiently remove acidic pollutants, solid particles and radioactive heavy metals by minimizing the quantity of radioactive solid residues resulting from the treatment of the fumes.
- the counter-current spray column 7 can be replaced by a co-current spray column.
- the installation according to the invention also advantageously reduces the risks of pollution transfer by avoiding the rejection of liquid effluent, thanks to the crystallization unit 36 which makes it possible to recover the water to be recycled and to the heater 300 which allows to remove excess water, in the form of vapor, from the atmosphere.
- the rapid cooling of the fumes in the cooling enclosure 6 makes it possible to avoid the adsorption of radioactive heavy metals on the solid particles and the formation of organic pollutants such as dioxins or furans.
- the installation also has a high yield for the capture of pollutants such as gaseous mercury, due to the low outlet temperature of the fumes from the condenser-cooler, typically of the order of 30 ° C.
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9402924 | 1994-03-14 | ||
FR9402924A FR2717297B1 (en) | 1994-03-14 | 1994-03-14 | Process and installation for the purification of fumes from the incineration of weakly radioactive waste. |
PCT/FR1995/000300 WO1995025332A1 (en) | 1994-03-14 | 1995-03-14 | Method and plant for cleaning lightly radioactive waste incineration gases |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0750784A1 true EP0750784A1 (en) | 1997-01-02 |
EP0750784B1 EP0750784B1 (en) | 1998-12-09 |
Family
ID=9460994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95912311A Expired - Lifetime EP0750784B1 (en) | 1994-03-14 | 1995-03-14 | Method and plant for cleaning lightly radioactive waste incineration gases |
Country Status (8)
Country | Link |
---|---|
US (1) | US5771473A (en) |
EP (1) | EP0750784B1 (en) |
JP (1) | JPH09510295A (en) |
CN (1) | CN1146254A (en) |
AU (1) | AU1954095A (en) |
DE (1) | DE69506529T2 (en) |
FR (1) | FR2717297B1 (en) |
WO (1) | WO1995025332A1 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1098526C (en) * | 1999-04-30 | 2003-01-08 | 中国辐射防护研究院 | Radioactive combustible waste incineration disposing process and its special equipment |
RU2505341C1 (en) * | 2012-06-15 | 2014-01-27 | Общество с ограниченной ответственностью "НПО Пылеочистка" | Method of gas cleaning |
CN103070445A (en) * | 2013-01-18 | 2013-05-01 | 山东鲁丰食品科技股份有限公司 | Red jujube drink |
KR101296243B1 (en) * | 2013-06-27 | 2013-08-13 | 이성헌 | Wet type dust collector for air purifying |
JP6115959B2 (en) | 2013-12-11 | 2017-04-19 | 株式会社フィルテック | Fluid heat exchange device |
CN104733067B (en) * | 2015-03-12 | 2017-06-16 | 中广核研究院有限公司 | A kind of radioactivity mixes the feed arrangement and method of organic liquid waste heat treatment system |
KR102006385B1 (en) * | 2018-04-20 | 2019-08-01 | 주식회사 진우이앤티 | Integrated reflow system with built-in heat recovery system and ductless air purifier |
CN109300564B (en) * | 2018-09-20 | 2022-11-18 | 中国辐射防护研究院 | Device and method for simulating steam blocking and corrosion of filter |
JP7178335B2 (en) * | 2019-08-28 | 2022-11-25 | 日立Geニュークリア・エナジー株式会社 | Gas processing system |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS565960B2 (en) * | 1972-12-27 | 1981-02-07 | ||
GB1594370A (en) * | 1977-11-08 | 1981-07-30 | Energy Inc | Treatment of waste |
US4666490A (en) * | 1986-02-12 | 1987-05-19 | Drake Ronald N | Aqueous waste vitrification process and apparatus |
DE3639289A1 (en) * | 1986-11-17 | 1988-05-26 | Joachim Prof Dr In Tischendorf | Air purification method |
JPH071320B2 (en) * | 1987-09-01 | 1995-01-11 | 日本碍子株式会社 | How to dispose of radioactive waste |
-
1994
- 1994-03-14 FR FR9402924A patent/FR2717297B1/en not_active Expired - Fee Related
-
1995
- 1995-03-14 US US08/716,157 patent/US5771473A/en not_active Expired - Fee Related
- 1995-03-14 JP JP7523882A patent/JPH09510295A/en not_active Ceased
- 1995-03-14 AU AU19540/95A patent/AU1954095A/en not_active Abandoned
- 1995-03-14 WO PCT/FR1995/000300 patent/WO1995025332A1/en active IP Right Grant
- 1995-03-14 DE DE69506529T patent/DE69506529T2/en not_active Expired - Fee Related
- 1995-03-14 EP EP95912311A patent/EP0750784B1/en not_active Expired - Lifetime
- 1995-03-14 CN CN95192580A patent/CN1146254A/en active Pending
Non-Patent Citations (1)
Title |
---|
See references of WO9525332A1 * |
Also Published As
Publication number | Publication date |
---|---|
CN1146254A (en) | 1997-03-26 |
US5771473A (en) | 1998-06-23 |
DE69506529D1 (en) | 1999-01-21 |
FR2717297A1 (en) | 1995-09-15 |
AU1954095A (en) | 1995-10-03 |
JPH09510295A (en) | 1997-10-14 |
DE69506529T2 (en) | 1999-06-02 |
WO1995025332A1 (en) | 1995-09-21 |
EP0750784B1 (en) | 1998-12-09 |
FR2717297B1 (en) | 1996-05-31 |
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