EP0714976B2 - Compositions détergentes contenant un agent tensioactif cationique et procédé pour leur fabrication - Google Patents

Compositions détergentes contenant un agent tensioactif cationique et procédé pour leur fabrication Download PDF

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Publication number
EP0714976B2
EP0714976B2 EP94308960A EP94308960A EP0714976B2 EP 0714976 B2 EP0714976 B2 EP 0714976B2 EP 94308960 A EP94308960 A EP 94308960A EP 94308960 A EP94308960 A EP 94308960A EP 0714976 B2 EP0714976 B2 EP 0714976B2
Authority
EP
European Patent Office
Prior art keywords
weight
composition
anionic
cationic surfactant
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP94308960A
Other languages
German (de)
English (en)
Other versions
EP0714976A1 (fr
EP0714976B1 (fr
Inventor
Anthony Dovey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8217930&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0714976(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP94308960A priority Critical patent/EP0714976B2/fr
Priority to DE69424551T priority patent/DE69424551T3/de
Priority to AT94308960T priority patent/ATE193051T1/de
Priority to TR95/01509A priority patent/TR199501509A2/xx
Priority to CA002206326A priority patent/CA2206326A1/fr
Priority to AU43714/96A priority patent/AU4371496A/en
Priority to BR9509843A priority patent/BR9509843A/pt
Priority to PCT/US1995/015548 priority patent/WO1996017042A1/fr
Priority to CN95197503.XA priority patent/CN1174566A/zh
Priority to JP8519046A priority patent/JPH10511713A/ja
Priority to MX9704078A priority patent/MX9704078A/es
Priority to ZA9510227A priority patent/ZA9510227B/xx
Priority to MA24083A priority patent/MA23734A1/fr
Publication of EP0714976A1 publication Critical patent/EP0714976A1/fr
Publication of EP0714976B1 publication Critical patent/EP0714976B1/fr
Application granted granted Critical
Publication of EP0714976B2 publication Critical patent/EP0714976B2/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/047—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
    • C11D11/0082—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
    • C11D11/02—Preparation in the form of powder by spray drying
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Claims (7)

  1. Composition ou composant détergent(e) granulaire comprenant un agent tensioactif anionique ou un hydrotrope anionique, un agent tensioactif cationique soluble dans l'eau ayant dans sa forme pure une CMC (concentration critique en micelles) de plus de 200 ppm à 30 °C dans de l'eau distillée, et moins de 10% en poids d'un polymère anionique, caractérisé(e) en ce que l'agent tensioactif cationique est présent à un niveau d'au moins 20 % en poids de la composition ou du composant et le rapport molaire de l'agent tensioactif anionique et/ou de l'hydrotrope anionique à l'agent tensioactif cationique est inférieur à 1:1, et la composition ou le composant comprend 10 % à 69 % en poids d'un adjuvant détergent choisi dans le groupe constitué d'un aluminosilicate, d'un silicate, d'un carbonate, d'un citrate, d'un phosphate ou de leurs mélanges, pourvu que n'importe quel phosphate dans la composition ou composant soit choisi parmi le tripolyphosphate, le pyrophosphate et le métaphosphate polymère de sodium et de potassium ayant un degré de polymérisation de 6 à 21.
  2. Composition ou composant détergent(e) granulaire selon la revendication 1, dans laquelle ou lequel l'agent tensioactif cationique est présent à un niveau d'au moins 30 % en poids de la composition ou du composant et l'agent tensioactif anionique est présent à un niveau de 1 % à 20 % en poids de la composition ou du composant et le rapport molaire de l'agent tensioactif anionique à l'agent tensioactif cationique est inférieur à 0,5:1.
  3. Composition ou composant détergent(e) granulaire selon la revendication 2, qui est sensiblement exempt(e) d'un polymère anionique, comprenant :
    (a) 35 % à 50 % en poids d'un agent tensioactif cationique soluble dans l'eau,
    (b) 1 % à 5 % en poids d'un agent tensioactif anionique, et
    (c) 40 % à 60 % en poids d'aluminosilicate de sodium.
  4. Procédé de préparation de la composition ou du composant selon l'une quelconque des revendications 1 à 3, comprenant les étapes consistant :
    (i) à mélanger une solution aqueuse comprenant un agent tensioactif cationique soluble dans l'eau ayant dans sa forme pure une CMC (concentration critique en micelles) de plus de 200 ppm à 30 °C dans de l'eau distillée, un agent tensioactif anionique ou un hydrotrope anionique, de préférence un agent tensioactif anionique, et moins de 10 % en poids d'un polymère anionique,
    (ii) à sécher le mélange pour former une solution concentrée ayant une teneur en solides d'au moins 50 % en poids, et
    (iii) à granuler la solution concentrée,
       caractérisé en ce que l'agent tensioactif cationique est présent à un niveau d'au moins 20 % en poids de la composition ou du composant et le rapport molaire de l'agent tensioactif anionique et/ou de l'hydrotrope anionique à l'agent tensioactif cationique est inférieur à 1:1, et la composition ou le composant comprend 10 % à 69 % en poids d'un adjuvant détergent choisi dans le groupe constitué d'un aluminosilicate, d'un silicate, d'un carbonate, d'un citrate, d'un phosphate ou de leurs mélanges, pourvu que n'importe quel phosphate dans la composition ou composant soit choisi parmi le tripolyphosphate, le pyrophosphate et le métaphosphate polymère de sodium et de potassium ayant un degré de polymérisation de 6 à 21.
  5. Procédé selon la revendication 4, dans lequel un agent suppresseur de mousse est ajouté à l'étape de mélange (i).
  6. Procédé selon l'une quelconque des revendications 4 ou 5, dans lequel l'étape de séchage est effectuée au moyen d'une étape d'évaporation et l'étape de granulation est ensuite effectuée en mélangeant la solution concentrée avec un adjuvant détergent choisi dans le groupe constitué d'un aluminosilicate, d'un silicate, d'un carbonate, d'un citrate, d'un phosphate ou de leurs mélanges.
  7. Procédé selon la revendication 4 dans lequel les étapes de séchage et de granulation sont effectuées simultanément, de préférence par séchage par pulvérisation.
EP94308960A 1994-12-02 1994-12-02 Compositions détergentes contenant un agent tensioactif cationique et procédé pour leur fabrication Expired - Lifetime EP0714976B2 (fr)

Priority Applications (13)

Application Number Priority Date Filing Date Title
EP94308960A EP0714976B2 (fr) 1994-12-02 1994-12-02 Compositions détergentes contenant un agent tensioactif cationique et procédé pour leur fabrication
DE69424551T DE69424551T3 (de) 1994-12-02 1994-12-02 Kationisches Tensid enthaltende Waschmittelzusammensetzungen sowie deren Herstellung
AT94308960T ATE193051T1 (de) 1994-12-02 1994-12-02 Kationisches tensid enthaltende waschmittelzusammensetzungen sowie deren herstellungsverfahren
TR95/01509A TR199501509A2 (tr) 1994-12-02 1995-11-29 Katyonik yüzey aktif cismi iceren deterjan bilesimleri ve bilesimin hazirlanmasi icin bir islem.
CN95197503.XA CN1174566A (zh) 1994-12-02 1995-11-30 含有阳离子表面活性剂的洗涤剂组合物及其制备方法
AU43714/96A AU4371496A (en) 1994-12-02 1995-11-30 Detergent compositions comprising cationic surfactant and process for making the composition
BR9509843A BR9509843A (pt) 1994-12-02 1995-11-30 Composição detergente compreendendo tensoatívo catiónico e processo para sua fabricação
PCT/US1995/015548 WO1996017042A1 (fr) 1994-12-02 1995-11-30 Compositions detergentes comprenant un agent tensioactif cationique et processus de fabrication
CA002206326A CA2206326A1 (fr) 1994-12-02 1995-11-30 Compositions detergentes comprenant un agent tensioactif cationique et processus de fabrication
JP8519046A JPH10511713A (ja) 1994-12-02 1995-11-30 カチオン界面活性剤を含んでなる洗剤組成物およびその製造方法
MX9704078A MX9704078A (es) 1994-12-02 1995-11-30 Composiciones detergentes que comprenden agente tensioactivo cationico y procedimiento para hacer la composicion.
ZA9510227A ZA9510227B (en) 1994-12-02 1995-12-01 Detergent compositions comprising cationic surfactant and process for making the composition
MA24083A MA23734A1 (fr) 1994-12-02 1995-12-01 Compositions detegentes comprenant un agent tensioactif cationique et procede pour fabriquer ladite composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP94308960A EP0714976B2 (fr) 1994-12-02 1994-12-02 Compositions détergentes contenant un agent tensioactif cationique et procédé pour leur fabrication

Publications (3)

Publication Number Publication Date
EP0714976A1 EP0714976A1 (fr) 1996-06-05
EP0714976B1 EP0714976B1 (fr) 2000-05-17
EP0714976B2 true EP0714976B2 (fr) 2005-03-23

Family

ID=8217930

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94308960A Expired - Lifetime EP0714976B2 (fr) 1994-12-02 1994-12-02 Compositions détergentes contenant un agent tensioactif cationique et procédé pour leur fabrication

Country Status (13)

Country Link
EP (1) EP0714976B2 (fr)
JP (1) JPH10511713A (fr)
CN (1) CN1174566A (fr)
AT (1) ATE193051T1 (fr)
AU (1) AU4371496A (fr)
BR (1) BR9509843A (fr)
CA (1) CA2206326A1 (fr)
DE (1) DE69424551T3 (fr)
MA (1) MA23734A1 (fr)
MX (1) MX9704078A (fr)
TR (1) TR199501509A2 (fr)
WO (1) WO1996017042A1 (fr)
ZA (1) ZA9510227B (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19721885A1 (de) † 1997-05-26 1998-12-03 Henkel Kgaa Verfahren zur Herstellung kationtensidhaltiger Granulate
EP0971030A1 (fr) * 1998-07-10 2000-01-12 The Procter & Gamble Company Agglomérats tensio-actifs
GB0009029D0 (en) 2000-04-12 2000-05-31 Unilever Plc Laundry wash compositions
GB0009877D0 (en) * 2000-04-20 2000-06-07 Unilever Plc Granular detergent component and process for its preparation
DE102004018751A1 (de) * 2004-04-17 2005-11-03 Clariant Gmbh Verfahren zur Herstellung von quaternären Hydroxyalkylammonium Granulaten
US20080262129A1 (en) * 2007-04-06 2008-10-23 Kao Corporation Process for producing powder
JP5669049B2 (ja) * 2010-05-14 2015-02-12 ユケン工業株式会社 水系洗浄剤組成物
EP2821474A1 (fr) * 2011-01-12 2015-01-07 The Procter and Gamble Company Procédé de contrôle de la plastification d'un film hydrosoluble
CN115895790A (zh) * 2022-11-30 2023-04-04 四川科宏达集团有限责任公司 一种阴-阳离子表面活性剂复配清洗剂及制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE833077A (fr) † 1974-09-06 1975-12-31 Composition d'assouplissement des tissus contenant un tamis moleculaire zeolitique
US3936537A (en) † 1974-11-01 1976-02-03 The Procter & Gamble Company Detergent-compatible fabric softening and antistatic compositions
EP0011333A1 (fr) † 1978-11-16 1980-05-28 THE PROCTER & GAMBLE COMPANY Additif pour détergent sous forme de particules contenant un complexe adoucissant anionique-cationique insoluble et des compositions détergentes contenant l'additive
US4292035A (en) † 1978-11-13 1981-09-29 The Procter & Gamble Company Fabric softening compositions
GB2185752A (en) † 1986-01-23 1987-07-29 Procter & Gamble Detergent composition comprising suds control prills

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2449354B2 (de) * 1974-10-17 1979-08-23 Basf Ag, 6700 Ludwigshafen Verwendung von Orthophosphorsäureestern als Schaumdämpfer in kationischen Tensidformulierungen
EP0002084A1 (fr) * 1977-11-17 1979-05-30 THE PROCTER & GAMBLE COMPANY Compositions détergentes granulaires pour l'enlèvement amélioré de taches graisseuses
JPS598392B2 (ja) * 1979-06-29 1984-02-24 花王株式会社 洗浄剤組成物
DE3069767D1 (en) * 1979-09-29 1985-01-17 Procter & Gamble Detergent compositions
JPS57137397A (en) * 1981-02-20 1982-08-24 Kao Corp Detergent composition
US4430244A (en) * 1982-03-04 1984-02-07 Colgate-Palmolive Company Silicate-free bleaching and laundering composition
US4622173A (en) * 1984-12-31 1986-11-11 Colgate-Palmolive Co. Non-aqueous liquid laundry detergents containing three surfactants including a polycarboxylic acid ester of a non-ionic
US4637890A (en) * 1986-01-23 1987-01-20 The Procter & Gamble Company Detergent composition providing rinse cycle suds and turbidity control containing a soap, quaternary ammonium salt and a silicone
US5071594A (en) * 1989-10-02 1991-12-10 Ethyl Corporation Free flowing granular laundry detergent comprising tert-amine oxide dihydrate
AU662780B2 (en) * 1991-12-18 1995-09-14 Colgate-Palmolive Company, The Free-flowing powder fabric softening composition and process for its manufacture

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE833077A (fr) † 1974-09-06 1975-12-31 Composition d'assouplissement des tissus contenant un tamis moleculaire zeolitique
US3936537A (en) † 1974-11-01 1976-02-03 The Procter & Gamble Company Detergent-compatible fabric softening and antistatic compositions
US4292035A (en) † 1978-11-13 1981-09-29 The Procter & Gamble Company Fabric softening compositions
EP0011333A1 (fr) † 1978-11-16 1980-05-28 THE PROCTER & GAMBLE COMPANY Additif pour détergent sous forme de particules contenant un complexe adoucissant anionique-cationique insoluble et des compositions détergentes contenant l'additive
GB2185752A (en) † 1986-01-23 1987-07-29 Procter & Gamble Detergent composition comprising suds control prills

Also Published As

Publication number Publication date
MX9704078A (es) 1997-08-30
ZA9510227B (en) 1996-06-12
DE69424551D1 (de) 2000-06-21
BR9509843A (pt) 1997-11-25
DE69424551T3 (de) 2005-12-29
JPH10511713A (ja) 1998-11-10
CN1174566A (zh) 1998-02-25
WO1996017042A1 (fr) 1996-06-06
TR199501509A2 (tr) 1996-07-21
MA23734A1 (fr) 1996-07-01
EP0714976A1 (fr) 1996-06-05
CA2206326A1 (fr) 1996-06-06
AU4371496A (en) 1996-06-19
DE69424551T2 (de) 2001-01-18
EP0714976B1 (fr) 2000-05-17
ATE193051T1 (de) 2000-06-15

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