EP0657503A3 - Fluoromodified polyesters having improved processability. - Google Patents

Fluoromodified polyesters having improved processability. Download PDF

Info

Publication number
EP0657503A3
EP0657503A3 EP94119005A EP94119005A EP0657503A3 EP 0657503 A3 EP0657503 A3 EP 0657503A3 EP 94119005 A EP94119005 A EP 94119005A EP 94119005 A EP94119005 A EP 94119005A EP 0657503 A3 EP0657503 A3 EP 0657503A3
Authority
EP
European Patent Office
Prior art keywords
improved processability
fluoromodified
polyesters
compositions
preparing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP94119005A
Other languages
German (de)
French (fr)
Other versions
EP0657503B1 (en
EP0657503A2 (en
Inventor
Claudio Tonelli
Francesco Pilati
Maurizio Toselli
Antonio Turturro
Ercole Gattiglia
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay Specialty Polymers Italy SpA
Original Assignee
Ausimont SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ausimont SpA filed Critical Ausimont SpA
Publication of EP0657503A2 publication Critical patent/EP0657503A2/en
Publication of EP0657503A3 publication Critical patent/EP0657503A3/en
Application granted granted Critical
Publication of EP0657503B1 publication Critical patent/EP0657503B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/88Post-polymerisation treatment
    • C08G63/90Purification; Drying
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/682Polyesters containing atoms other than carbon, hydrogen and oxygen containing halogens
    • C08G63/6824Polyesters containing atoms other than carbon, hydrogen and oxygen containing halogens derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6826Dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds

Abstract

Thermoplastic polyester compositions comprising polyester resin modified by introducing perfluoropolyether blocks in the polymeric chain characterized by high crystallization rate of the melted mass and therefore by an improved processability. In particular the use of such compositions in a process for preparing molded thermoplastic articles allows working at lower temperatures of the mold and with shorter molding times. Process for preparing modified resins.
EP94119005A 1993-12-06 1994-12-02 Fluoromodified polyesters having improved processability Expired - Lifetime EP0657503B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI932578 1993-12-06
IT93MI002578A IT1265261B1 (en) 1993-12-06 1993-12-06 FLUOROMODIFIED POLYESTERS WITH IMPROVED PROCESSABILITY

Publications (3)

Publication Number Publication Date
EP0657503A2 EP0657503A2 (en) 1995-06-14
EP0657503A3 true EP0657503A3 (en) 1997-08-13
EP0657503B1 EP0657503B1 (en) 2000-05-17

Family

ID=11367305

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94119005A Expired - Lifetime EP0657503B1 (en) 1993-12-06 1994-12-02 Fluoromodified polyesters having improved processability

Country Status (5)

Country Link
US (1) US5686522A (en)
EP (1) EP0657503B1 (en)
AT (1) ATE193035T1 (en)
DE (1) DE69424510T2 (en)
IT (1) IT1265261B1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7320829B2 (en) * 1998-03-05 2008-01-22 Omnova Solutions Inc. Fluorinated polymer and amine resin compositions and products formed therefrom
US7214452B2 (en) * 2002-11-07 2007-05-08 Intel Corporation Using perfluoropoly-ethers to form pellicles
DE102008028617A1 (en) * 2008-06-18 2009-12-24 Teijin Monofilament Germany Gmbh Monofilaments modified with perfluoropolyethers
EP3087119B1 (en) 2013-12-24 2019-02-27 Solvay Specialty Polymers Italy S.p.A. Polyamides modified with (per)fluoropolyether segments
CN104448277A (en) * 2014-12-12 2015-03-25 东华大学 Perfluoropolyether modified antifouling droplet-preventing copolyester and preparation method thereof
CN104451937B (en) * 2014-12-12 2016-06-08 东华大学 A kind of multi-functional copolyester fiber of antifouling fire-retardant anti-molten droplet and preparation method thereof
CN104451938B (en) * 2014-12-12 2016-08-24 东华大学 A kind of antifouling fire-retardant anti-molten droplet polyester fiber and preparation method thereof
CN104530407A (en) * 2014-12-12 2015-04-22 东华大学 Perfluoropolyether modified anti-flouring molten drop prevention copolyester fiber and preparation method thereof
WO2017076767A1 (en) 2015-11-05 2017-05-11 Solvay Specialty Polymers Italy S.P.A. Method for the manufacture of (per)fluoropolyether modified polyamides and polyamides obtainable with such method
WO2018197341A1 (en) 2017-04-24 2018-11-01 Solvay Specialty Polymers Italy S.P.A. Aromatic sulfone polymers comprising (per)fluoropolyether segments

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987003608A1 (en) * 1985-12-05 1987-06-18 Ausimont S.P.A. Fluorinated polyesters
EP0545451A1 (en) * 1991-11-18 1993-06-09 ENICHEM S.p.A. Elastomeric segmented copolyether-esters endowed with high technological characteristics

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE756074A (en) * 1969-09-11 1971-03-11 Hoechst Ag THERMOPLASTIC MOLDING MATERIALS BASED ON POLYESTERS
US4212791A (en) * 1979-02-23 1980-07-15 Rohm And Haas Poly(alkyleneterephthalate) molding compositions containing oligomeric polyester and segmented copolyester-polyether elastomer
US4425470A (en) * 1982-08-06 1984-01-10 E. I. Du Pont De Nemours And Company Alkali metal salts of low molecular weight polyethylene terephthalate as nucleating agents for polyethylene terephthalates
US4996269A (en) * 1987-03-13 1991-02-26 The Goodyear Tire & Rubber Company Polyester composition which is particularly suitable for use in thermoforming thin walled articles

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987003608A1 (en) * 1985-12-05 1987-06-18 Ausimont S.P.A. Fluorinated polyesters
EP0545451A1 (en) * 1991-11-18 1993-06-09 ENICHEM S.p.A. Elastomeric segmented copolyether-esters endowed with high technological characteristics

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PILATI F. ET AL: "Preparation of poly(ethylene terephthalate) in the presence of a telechelic perfluoropolyether", J. POLYMER SCI. : PART A : POLYMER SCIENCE, vol. 27, 1989, pages 951 - 962, XP000045516 *
PILATI F. ET AL: "Synthesis of polyesters -polyfluoropolyethers block copolymers.", POLYMER BULLETIN, vol. 28, no. 2, April 1992 (1992-04-01), pages 151 - 157, XP000264602 *

Also Published As

Publication number Publication date
EP0657503B1 (en) 2000-05-17
EP0657503A2 (en) 1995-06-14
DE69424510D1 (en) 2000-06-21
DE69424510T2 (en) 2001-01-18
ITMI932578A1 (en) 1995-06-06
IT1265261B1 (en) 1996-10-31
ATE193035T1 (en) 2000-06-15
US5686522A (en) 1997-11-11
ITMI932578A0 (en) 1993-12-06

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