EP0618854A1

EP0618854A1 - Process for manufacturing fibre or particle boards

Info

Publication number: EP0618854A1
Application number: EP93919235A
Authority: EP
Inventors: Jürgen Dr. Kramer
Original assignee: KRAMER JUERGEN DR GLUNZ AG; Kramer Juergen Dr; Glunz AG
Current assignee: KRAMER, JUERGEN, DR.
Priority date: 1992-09-03
Filing date: 1993-09-01
Publication date: 1994-10-12
Also published as: DE4229396A1; WO1994005475A1; CA2122368A1; DE4229396C2

Abstract

Selon un procédé de fabrication de panneaux de fibres ou d'agglomérés, on ajoute à un liant contenant des groupes NCO un catalyseur accélérant la réaction du polyuréthanne. On colle avec ce liant des fibres ou des agglomérés contenant de la lignocellulose, avec lesquels on façonne ensuite une natte qui est comprimée sous effet de la chaleur jusqu'à former un panneau de fibres ou d'agglomérés.According to a process for manufacturing fiberboard or chipboard, a catalyst is added to a binder containing NCO groups, which accelerates the reaction of the polyurethane. Fibers or agglomerates containing lignocellulose are glued with this binder, with which a mat is then shaped which is compressed under the effect of heat until a fiber or agglomerate panel is formed.

Description

Process for the production of chipboard or fiberboard

The invention relates to a process for the production of chipboard or fiberboard, in which lignose-cellulose-containing chips or fibers are glued with a binder containing NCO groups, shaped into a mat and pressed under the action of heat to the chipboard or fiberboard.

It is already known from AT-PS 270189 to produce particleboard and fiberboard using a binder having NCO groups as reactive groups. Here, an isocyanate solution is applied to lignocellulose-containing chips or fibers. A mat is then formed from the chips or fibers, which is hot-pressed to the particle board or fiberboard under the action of heat. A particle board or fiber board bonded with a binder containing NCO groups advantageously has excellent moisture resistance and no formaldehyde emission resulting from binder. It turns out to be disadvantageous, however, that binders containing NCO groups have a lower adhesive effect than other binders, which also has to be activated by comparatively high temperatures and long pressing times when the chipboard or fiberboard is hot-pressed. Accordingly, in the production of particle board and fiberboard using a binder containing NCO groups, the costs for a high binder content in the end product and a low output of the hot presses and a relatively high scrap have a negative impact. It is noteworthy that there are limits to an increase in the pressing temperatures, in order to reach the temperatures required for curing the binder faster inside the mat, so that when the mat is hot pressed, vaporized substances, in particular water vapor, very quickly affect the quality of the chip or Affect fiber mat.

REPLACEMENT LEAF The invention is therefore based on the object of further developing a method of the type described at the outset such that stable chipboard or fiberboard can be obtained with a lower binder content and / or that the pressing times can be shortened and / or that the pressing temperatures can be reduced.

In the production of a resin-bonded chipboard and fiber board, it is common to use various catalysts, in particular acids, in order to accelerate the curing of the amino resin. For example, according to DE-OS 27 45 809, the use of sulfide waste liquor with a pH of 4.0 in a solids content of about 10% by weight of the aminoplast resin is known.

No catalysts have so far been used in the production of particleboard and fiberboard using a binder containing NCO groups. In view of the long period over which this process has been known, this is initially surprising and is probably due to the fear that a possible catalyst would lead to difficulties in connection with the open storage time of the glued chips or fibers between the glue and the hot pressing. Hardening of the binder during the open storage period, which is typically in the range from 15 to 30 minutes, reduces its adhesive effect. This is remarkable in particular in the case of the comparatively low adhesive effect of a binder having NCO groups.

When carrying out the polyurethane reaction for the production of polyurethane foams from polyol and isocyanate, the use of catalysts is common. According to the leaflet "Bayer Polyurethane", issue 1.97, tertiary amines and organotin compounds are commonly used as activators for the polyurethane reaction. Here, tertiary amines with NCO

REPLACEMENT LEAF reactive groups in that they are chemically incorporated into the polyurethane foam and thus inactivated after the polyurethane reaction has been carried out.

The use of catalysts, the use of which is customary in the implementation of the polyurethane reaction to obtain polyurethane foams, appears fundamentally impossible to the person skilled in the art in the production of particle board or fiber board using a binder containing NCO groups. It should be noted here that the polyurethane reaction is a rapid reaction which, in the course of polyurethane foam production, begins immediately, even at low temperatures, when the polyol is mixed with the isocyanate in the presence of the catalyst. This leads to fears that if a binder containing NCO groups is added with the addition of catalysts accelerating a polyurethane reaction, the glued chips or fibers can no longer be pressed into a stable chipboard or fiberboard after an open storage period of a few minutes, since the adhesive effect of the binder largely, if not completely, d. H. would be used up.

In the production of particle board or fiberboard, tertiary amines are not known as catalysts which accelerate the hardening of the binder during hot pressing.

The US-PS 47 72 442 discloses a method of the type described above for the production of chipboard or fiberboard using a binder containing NCO groups, wherein a fatty substance is used as a release agent for the hot-pressed chipboard or fiberboard from the press plates of the hot press becomes. In one embodiment, the detaching aid is applied in an aqueous emulsion, to which triethanolamine is added as an emulsifier. US Pat. No. 4,772,442 does not report any catalytic effects of triethanolamine with regard to the binder.

REPLACEMENT LEAF From DE-OS 34 38 735 a binder additive for the production of aminoplast resin-bound chipboard and fibreboard is known. The addition of the binder is said to improve the flame-retardant properties of the particle board or fiberboard without impairing its stability. In addition to boric acid, constituents of the binder additive are, for example, a water-soluble amine or polyamine and a further water-soluble compound with at least one organically bound hydroxyl group or a liquid alcohol. It is also possible to add isocyanate as the binder component containing NCO groups to the binder consisting essentially of aminoplast resin. A person skilled in the art from DE-OS 34 38 735 cannot infer a catalytic effect of the amines or polyamines as such on the hardening of the binder. In particular, this does not result in a direct link between the amines and binders containing NCO groups, insofar as they are used solely as binders.

For these reasons, it is surprising that the object of the invention is achieved by adding a catalyst which accelerates a polyurethane reaction to the binder containing NCO groups. Contrary to all expectations, various known catalysts which accelerate the polyurethane reaction in the production of polyurethane foams are suitable as an additive to the binder containing NCO groups used in the production of chipboard or fiberboard as reactive groups. In particular, the maintenance of the adhesive effect of the binder during the open storage period of the glued chips or fibers, which was previously regarded as critical, has proven to be largely problem-free. Open storage times of up to 30 minutes and above, with careful selection of the catalyst from the commercially available auxiliaries which accelerate a polyurethane reaction, show no appreciable influence on the efficiency of the binder mixed with the catalyst during hot pressing. At the same time, the pressing times can be reduced by up to approx. 30%

REPLACEMENT LEAF shorten without noticeable loss of quality. Rather, an improvement in the mechanical properties of the particle board or fiber board is observed. This is due to the fact that the catalyst, when the glued chips are hot-pressed, preferably forms urethane bonds between the lignocellulose-containing chips or fibers and the binder containing NCO groups, while the proportion of binder-internal polyurea bonds decreases accordingly. As an alternative or in parallel with the shortening of the pressing time, a lowering of the pressing temperature of up to approx. 30 K is possible. This leads to a noticeable reduction in rejects due to water vapor damage.

It goes without saying that not all catalytic converters accelerating a polyurethane reaction are equally suitable as an additive to the binder in the production of particle board and fiberboard using a binder containing NCO groups. In principle, however, all known types of catalysts which accelerate a polyurethane reaction appear to be usable. Taking into account the embodiments of the process for the production of chipboard or fiberboard described below, a particularly suitable catalyst can be selected without any problems.

The binder can be applied to the chips or fibers in an aqueous suspension and / or emulsion, the catalyst being dissolved in the water. A water-soluble catalyst has the particular advantage that it can be distributed finely and uniformly in the binder. Lower amounts of the generally high-priced catalyst are sufficient than if the catalyst is water-insoluble and has to be dispersed in the water. The application of the binder containing NCO groups to the chips or fibers in the form of an aqueous suspension or emulsion is a common method in the production of chipboard and fiberboard. Likewise, the use of suspensions or emulsions is up

REPLACEMENT LEAF the base of toluene in use. Here the catalyst would have to be added to the binder via the toluene.

The catalyst can have a hydroxyl group. The hydroxyl group of the catalyst is u. a. an indication of the water solubility of the catalyst.

The catalyst can be chemically incorporated into the particle board or fiberboard during pressing. A catalyst firmly integrated after hot pressing is chemically activated. This is of particular importance since the catalysts which accelerate a polyurethane reaction have almost completely irritating, in some cases even toxic, properties in the unbound state. However, this irritating or even toxic effect no longer comes into play after the catalytic converter has been chemically installed in the particle board or fiberboard.

The catalyst can be a tertiary amine. Amines are the best known group of catalysts which accelerate a polyurethane reaction. It is precisely the tertiary amines which are found to be advantageous in the production of particleboard and fiberboard using a binder containing NCO groups. When the glued chips are hot-pressed, they are firmly built into the resulting bonds and thereby chemically inactivated if they have an NCO-reactive group. Secondary and primary amines are always bound in the binder containing NCO groups by means of an NH / NCO reaction.

The ether and aliphatic amines appear particularly suitable for carrying out the invention.

Should there be problems in individual cases with conventional, commercially available catalysts for a polyurethane reaction with regard to the open storage time in the production of chipboard or fiberboard using an NCO group

REPLACEMENT LEAF If binding agents occur, these can be eliminated by using a blocked catalyst which can be activated by supplying heat. Such catalysts are also known per se to those skilled in the art for accelerating a polyurethane reaction.

A blocked catalyst which can be activated by the supply of heat can be achieved particularly simply by masking the catalyst with an acid. With a suitable choice of the acid, the resulting reaction product with the catalyst disintegrates above the temperature which is characteristic of the open storage time, but is in the lower range of the temperatures reached during the hot pressing of the chips or fibers.

The catalyst can be used in a concentration between 2.0 and 0.001% by weight, based on the binder. In particular, concentrations between 0.5 and 0.005% by weight have proven to be suitable in the production of particle board and fiberboard using a binder containing NCO groups. The low proportions in which the catalyst accelerating a polyurethane reaction is sufficient to ignite the desired effect make it clear that, although it may be chemically incorporated into the reaction product, it is a true catalyst in the classic sense and is not an actual reaction partner. The low concentrations required are also a prerequisite for the production of particle board and fiberboard using the catalyst to have economic advantages. It would be nonsensical if the achievable pressing time reduction of about 30% or the achievable pressing temperature reduction of about 30 K or the binder saving were more or completely offset by an increased financial use for the catalyst.

REPLACEMENT LEAF The binder can be a polyisocyanate, in particular polymeric 4,4'-methylene diisocyanate (PMDI). The PMDI currently used in the production of particle board and fiberboard using an NCO group-containing binder is in itself unchanged composition suitable for the production of particle board and fiberboard using a catalyst which accelerates a polyurethane reaction.

The invention is explained below with reference to an exemplary embodiment in greater detail, game ^'and described.

In a conventional production plant for the production of particle board using a binder containing NCO groups, a commercially available catalyst which accelerated a polyurethane reaction was added to the binder. The binder, a polymeric 4-methylene diisocyanate (PMDI), was in an aqueous emulsion. The ratio of the proportions of water and PMDI was 1: 1. The binder was a commercially available, unmodified polyisocyanate (Desmodur 1520 A, Bayer Leverkusen AG). The catalyst which accelerated a polyurethane reaction was a water-soluble, tertiary amine (TEXACAT-DPA, Texaco-Chemical Deutschland GmbH) and was added to the water content of the binder emulsion in a concentration which corresponded to 0.5% by weight of the PMDI content of the emulsion. The binder emulsion thus enriched was used to glue chips in the usual way. After the formation of a mat from the chips and the pressing of the mat into a chipboard under the influence of heat, the quality of the resulting chipboard was examined as a function of the pressing time. Even when the pressing time falls below the usual pressing time by approx. 25%, no drops in quality impairing the commercial ability of the particle board have been observed. Instead, there were improved mechanical properties of the chipboard assessed, which still occurred significantly below the usual pressing time. With regard to the open storage time, up to 30

REPLACEMENT LEAF Minutes, no significant reduction in the adhesive effect of the binder was found. This covers the entire range of the usual open storage times. Overall, it turns out that the new process for the production of chipboard or fiberboard using a binder containing NCO groups and a catalyst which accelerates a polyurethane reaction can be carried out on conventional production plants and, with the quality of the products remaining the same, can reduce the output of these production plants by increases to a third. In view of the achievable advantages, the financial use to be made of the catalyst for this purpose is comparatively low.

REPLACEMENT LEAF

Claims

PATENT CLAIMS:

1. A process for the production of chipboard or fiberboard, wherein lignocellulose-containing chips or fibers are glued with a binder containing NCO groups, formed into a mat and pressed under the action of heat to the chipboard or fiberboard, characterized in that the binder a catalyst accelerating a polyurethane reaction is added.

2. The method according to claim 1, characterized in that the binder is applied to the chips or fibers in an aqueous suspension or emulsion, the catalyst being dissolved in the water.

3. The method according to claim 1 or 2, characterized in that the catalyst has a hydroxyl group.

4. The method according to any one of claims 1 to 3, characterized in that the catalyst is chemically incorporated into the particle board or fiberboard during pressing.

5. The method according to any one of claims 1 to 4, characterized in that the catalyst is a tertiary amine.

6. The method according to claim 5, characterized in that the catalyst is an ether or an aliphatic amine.

7. The method according to any one of claims 1 to 6, characterized in that the catalyst is a blocked, heat-activated catalyst.

8. The method according to claims 3 and 7, characterized gekenn¬ characterized in that the catalyst is masked by an acid.

REPLACEMENT LEAF

9. The method according to any one of claims 1 to 8, characterized in that the catalyst in a concentration between 2.0 and 0.001 wt .-%, in particular between 0.5 and 0.005 wt .-% based on the NCO group-containing binder is used.

10. The method according to any one of claims 1 to 9, characterized in that the binder having NCO groups is a polyisocyanate, in particular polymeric 4,4'-methylene diisocyanate (PMDI).

REPLACEMENT LEAF