Classifications

• • G—PHYSICS
  • G01—MEASURING; TESTING
  • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
  • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
  • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
  • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
  • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
  • G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
  • G01N21/3504—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
  • G01N21/3518—Devices using gas filter correlation techniques; Devices using gas pressure modulation techniques
• • G—PHYSICS
  • G01—MEASURING; TESTING
  • G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
  • G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
  • G01J3/12—Generating the spectrum; Monochromators
  • G01J2003/1226—Interference filters
  • G01J2003/1234—Continuously variable IF [CVIF]; Wedge type
• • G—PHYSICS
  • G01—MEASURING; TESTING
  • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
  • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
  • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
  • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
  • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
  • G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
  • G01N21/3504—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
  • G01N2021/3531—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis without instrumental source, i.e. radiometric
• • G—PHYSICS
  • G01—MEASURING; TESTING
  • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
  • G01N2201/00—Features of devices classified in G01N21/00
  • G01N2201/12—Circuits of general importance; Signal processing
  • G01N2201/127—Calibration; base line adjustment; drift compensation
  • G01N2201/12723—Self check capacity; automatic, periodic step of checking

Definitions

• the present invention generally relates to the identification of chemical vapors by means of infrared (IR) radiation emission and absorption and particularly to the performance of such detection at a location remote from the vapors detected.
• IR infrared
• the present invention provides an infrared radiometer, comprising means for collecting infrared energy, means for filtering the collected energy over a f ilter bandwidth including f ilter means for bandpassing only a fractional bandwidth of the f i lt er bandwidth at any one t ime and means f or repeatedly scanning the f ilter bandwidth with the passed fract ional bandwidth, means f or measuring infrared energy passed by the filter means and for producing an output s ignal in response thereto , and means for repeatedly nulling the output s ignal in relation to the repeated scanning o f the f ilter bandwidth.
• the present invention provides an apparatus for detecting the presence of substance vapors having known infrared spectral characteristics against a background having contrasting infrared spectral characteristics relative to the known infrared characteristics of the substance vapors , comprising means for collecting infrared energy emissions from the background and any vapors pre s ent be tween the background and the means for collecting, means for measuring the infrared energy levels collected both in a first plurality of wavelength bands known to contain 1 infrared characteristics of the substance vapors and in
• the present invention covers a
• FIG. 1 is a representational diagram of a remote detection environment in which the present invention is intended to operate
• Fig. 2 is a schematic block diagram of a vapor detection apparatus constructed in accordance with one embodiment of the present invention
• Fig. 3 is an infrared spectral diagram of an infrared filter designed to function in accordance with the embodiment of Fig. 2
• Fig. 4 is a flow chart of signal processing performed by the apparatus of Fig. 2.
• DETAILED DESCRIPTION OF THE DRAWINGS Fig. 1 shows a typical infrared (IR) detection environment 10 in which the apparatus and method of the present invention are intended to operate.
• IR infrared
• the environment 10 generally includes a background 14 having measurable infrared emission/absorption/ reflection characteristics, and a non- imaging infrared detector 16.
• Detector 16 is aimed in the direction of arrow 18 toward the background 14 to detect for the possible presence of selectable chemical vapors 20 as may pass in the area 12 between the background 14 and the detector 16.
• Area 12 may also include normal atmospheric air 12 capable of sustaining human and other forms of life.
• the background 14 is selected so that it has a different temperature from the vapors being detected.
• This contrast may alternatively include the detection of warm vapors against a cool background or the detection of cool vapors against a warm background. The contrast provides the basis for a detectable infrared difference.
• the background 14 either may be man-made such as a surface or wall, or may be opportunistically selected such as a hillside or sky. Background 14 does not have to have a stable temperature, so long as its temperature generally contrasts that of vapors 20.
• Fig. 2 shows a schematic block diagram of an apparatus 19 constructed in accordance with one embodiment of the present invention and capable of performing the detection of selectable chemical vapors such as 20 in the environment 10 of Fig. 1.
• Apparatus 19 generally includes the detector 16 of Fig . 1 and a processor section 21. The detector 16 is directed so that infrared energy emanating f rom the background 14 traverses through the chemical vapors 20 and is collected .by the aperture of an objective lens 24 .
• the chemical vapors 20 s elec t ive ly abs orb or radiate IR energy in accordance with their own unique IR characteristics and in response to the relative differential temperature between the background 14, the vapors 20 and any air or gasses present in the testing environment .
• the IR energy co llected by the obj ective lens 24 pas s es through a rotating , continuous ly varying infrared spectral bandpass filter 26, a slit 28 and a field lens 30.
• the field lens 30 collects the energy onto an IR detector 32.
• the filter 26 is rotated at a fixed rate with motor 34 and causes the detector 32 to see repeated scans of inf rared wavelengths .
• This IR spectral radiometer may be constructed to cover any partial bandwidth of the IR spectrum which is of interest .
• This design aspect depends primarily upon the rotating filter 26.
• Filter 26 is circular and allows the passage therethrough of a continuously varying wavelength of IR energy.
• the wavelength varies in accordance with the rotational angle of the filter over a predetermined filter bandwidth.
• the wavelength varies continuously from (6) to (11.4) microns, both increasing and decreasing the passed wavelength so that the (6) to (11.4) micron filter bandwidth is scanned a total of four (4) times in one rotation of the filter.
• Each scan of the bandwidth may also be thought of as a frame.
• the IR energy passed at any point around the filter is only a fractional bandwidth of the overall filter bandwidth. In the above example, this fractional bandwidth is (0.2) microns.
• the filter bandwidth of a detector may be tailored so that the detection apparatus may be dedicated for the long term monitoring of either a single vapor or a group of vapors having suf f iciently proximate IR characteristics.
• the IR energy level that impinges on the detector 32 is detected or measured causing the detector 32 to produce an output signal which is amplified by a preamplifier 36 and an amplifier 38.
• the amplified output signal from amplifier 38 is then coupled to the processor section 21 which may be constructed either integral with or separate from detector 16.
• the output s ignal f rom ampl i f ier 38 which corresponds to the IR energy detected is then chopped or nulled by a null circuit 40.
• Null circuit 40 causes the signal from amplif ier 38 to be shorted to ground between each bandwidth scan of f ilter 26 . This prevents scan to scan propagation of 1/f noise by producing a deep signal null between successive scans .
• the f i lter bandwidth is scanned a total of four times during each rotation of the filter 26, it is possible to use one or more of the f i l t er bandwidth s cans produced per rotation and to null the signal during the unused scans or between adjacent scans .
• the output signal is nulled at the same rate that the filter bandwidth is scanned. Nulling the signal just prior to the scan enables a stable starting point for the output signal, and nulling the signal after the end of the scan reduces the unpredictable response caused by 1/f noise . Synchronization of this nulling is described below. This reduction of 1/f noise enables improved performance for the entire detection apparatus . Where conventional approaches might use a lower scan rate and a separate high frequency modulator to limit the 1/f noise effect, this variation of the present invention allows a higher scan rate, providing more data for more accurate signal processing.
• the resultant signal out of null circuit 40 is buffered by a buffer amplifier 42 and filtered by a low pass filter 44.
• the filtered analog signal is sampled by a sample and hold circuit 46 and converted to a digital format by an analog to digital (A/D) converter 48.
• a digital signal processor 50 processes the digitally formatted data using an algorithm described below, and outputs the results to a display 52.
• the sample and hold circuit 46 and null circuit 40 are synchronized to the circular filter 26 by means of a phase-locked loop 54. This synchronization enables effective nulling and identification, for processing purposes of the filter position and therefore the IR wavelength of each sample taken. Any other suitable means may alternatively be used for synchronizing the nulling and/or the sampling to the wavelength position of filter 26.
• An example, in the form of a reflecting detector 55, is optionally shown.
• Such a detector may be made to respond either directly to the filter or otherwise to the motor 24 drive shaft.
• the analog data is over sampled, by sample and hold circuit 46, at a rate which is nominally ten times the rate of change of filter 26.
• the filter bandwidth extends from (6.0) to (11.4) microns for a total of (5.4) microns, and the fractional bandwidth passed by filter 26 at any point in time is (0 .2 ) microns .
• the sampling is controlled to produce a sample every ( 0. 02 ) micron of wavelength change and therefore produces a total of (270 ) samples per scan of the bandwidth. It is these (270 ) samples produced by every scan of the bandwidth that are digitized and used by the processor 50.
• Processor 50 processes the digitized samples in accordance wi th the f low chart 6 0 o f F ig . 3 .
• Filter Calculation step 62 uses the samples to calculate (54) separate filter values evenly spaced across the scanned f ilter bandwidth. These filter values are taken by the Filter Correction step 64 and individually corrected for the transfer function of the detector 16 .
• the adjusted f ilter values are then adjusted by subtraction of an estimated background temperature by the Background Subtraction step 66 . with the background temperature subtracted, the filter values are then integrated for a multiplicity of filter bandwidth scans by Integration step 68 for the purpose of removing noise. Once data for a sufficient number of scans is accumulated, the integrated filter values are then tested for the known IR spectral characteristics of the compounds of interest by Detection step 70.
• Filter Calculation step 62 takes the (270) samples and forms (54) overlapping spectral bandpass filters that are the average of ten samples and are separated by five samples.
• the over sam ling rate of 10 is nominal, and generally the number of samples may be any suitable multiple of the filter bandwidth (5.4) divided by the fractional pass bandwidth (0.2) for purposes of computational ease.
• Fig. 4 shows an example of sample grouping which may be used to calculate a set of narrow band filter values.
• Each of the points in the left hand column represents a sample value from A/D converter 48.
• Each of the actual wavelength values appearing in the right hand column represents the center wavelength of a narrow band filter value.
• the wavelength of each of the samples in the left hand column may be read or interpolated from the values appearing in the right hand column.
• Each of the narrow band filter values is calculated by summing (or averaging) the ten (10) nearest sample values.
• the (6.1) micron filter value is calculated by summing the values for samples (6.0) through (6.2); the (6.2) filter value is summed from samples (6.1) through (6.3); and so on.
• This method produces (54) narrow band filter values over the bandwidth of filter 26.
• Each narrow band filter is (0.2) microns wide, which corresponds to the bandpass characteristics of filter 26, and each narrow band filter is separated from adjacent filters by (0.1) microns. Because of this relationship, the samples included in the computation of each filter value represent potential infrared energy passed by the filter with the wavelength of the respective filter valu .
• the Filter Correction step 62 next corrects each calculated f ilter value for the system transfer function at each wavelength by multiplying each filter value by a unique coeff icient determined by system calibration.
• the Background Subtraction step 66 next uses the filter values to calculate the level of an estimated or equivalent background temperature across the filter bandwidth and subtracts the calculated temperature level from each of the filter values .
• the background temperature may be calculated by any suitable method . In one method, " clear" filter values are determined either by just looking at wavelengths not affected by the compound of interest or by otherwise examining the filter values. From these "clear" filter values, a temperature value for all filters is estimated by minimizing a mean square error criteria to find an equivalent blackbody temperature which best fits the measured values in the "clear" filters.
• the estimated temperature value in all filters is subtracted from the measured signal in all filters to normalize the data.
• This normalization including estimation, is performed every frame or scan of the filter bandwidth and is the basis for detecting the substance vapors 20 against the contrasting background 14.
• the equivalent blackbody temperature which is determined, is the background temperature against which the vapors 20 are contrasted. In the instance where cold vapors are detected against a warm background, subtracting the background temperature results in a negative number at the wavelengths of interest. Other negative numbers are also generated due to noise in the measurements .
• the resulting values, both negative and positive, are then used by the Integration step 68.
• the Integration step 68 accumulates data for successive frames or full filter bandwidth scans .
• Detection of compounds of interest may be accomplished by any suitable means.
• a microprocessor may be used to logically and mathematically examine the filter values, comparing them against known "footprints" or IR spectral characteristics of the compound of interest. This approach affords programmability of the system for the detection of one or more of a variety of substances thereby reducing adaptation costs for each different application.
• a neural network device/processor can be used to make the classification/detection decision. Such an approach would be used for detecting a large variety of substances . Again this detection process is intended to find differences between the IR energy measured at wavelengths having known spectral characteristics for the substances of interest. These detected differences may be either positive or negative depending upon the relative temperature differences between the background and the vapors to be detected . After detection, any desirable information may be passed to the display 52. This might include the substance name, concentration, temperature, etc. or something as simple as an indicator signal that a specific substance is present or has exceeded a specific concentration level. This data can also be transmitted for distant monitoring, collection, analysis, etc.
• the present invention provides a unique apparatus and method which is readily adaptable for the detection of a wide variety of substances in gaseous form.
• the present invention may be applied to any situation in which a contrasting IR background is available and against which a gaseous volume may be monitored.
• the invention thereby provides remote monitoring which affords an extremely wide range of applications along with inexpensive, convenient and fast testing of an infinite number of potential sources of gasses or vapors.
• Potential applications include the monitoring of border crossings for the detection of substances which must be declared or which may not be legally imported, methane monitoring in mining operations and the outdoor monitoring of combustion products, to name just a few.
• the ready programmability of the apparatus combines the low production cost of uniformity with the convenient modification for most applications. Cost savings and simple operation enhance distribution and use.

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• Physics & Mathematics (AREA)
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• Investigating Or Analysing Materials By Optical Means (AREA)

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• 1992
  • 1992-12-03 WO PCT/US1992/010401 patent/WO1993011424A1/fr not_active Application Discontinuation
  • 1992-12-03 CA CA 2125038 patent/CA2125038A1/fr not_active Abandoned
  • 1992-12-03 EP EP93900783A patent/EP0615613A1/fr not_active Withdrawn

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